JPS58112792A - 光情報記録部材 - Google Patents
光情報記録部材Info
- Publication number
- JPS58112792A JPS58112792A JP56209931A JP20993181A JPS58112792A JP S58112792 A JPS58112792 A JP S58112792A JP 56209931 A JP56209931 A JP 56209931A JP 20993181 A JP20993181 A JP 20993181A JP S58112792 A JPS58112792 A JP S58112792A
- Authority
- JP
- Japan
- Prior art keywords
- binder
- substrate
- film
- optical information
- information recording
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/245—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing a polymeric component
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/253—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
め要約のデータは記録されません。
Description
【発明の詳細な説明】
本発明は塗布方式によって製造さｎるスクアリリウム色
素含有有機酵ａを有する、高密度エネルギービームによ
って状態変化を生じさせて記録再生可能な光情報記録部
材に関する・従来、この柚の記録媒体としてはカルコケ
ナイト系非晶質ガラス、テルル酸化物、フルオレセイン
などを用いるものが知らｎている。
素含有有機酵ａを有する、高密度エネルギービームによ
って状態変化を生じさせて記録再生可能な光情報記録部
材に関する・従来、この柚の記録媒体としてはカルコケ
ナイト系非晶質ガラス、テルル酸化物、フルオレセイン
などを用いるものが知らｎている。
しかしながら、カルコゲナイド系非晶賞カラスは光学記
録用材料として蒸着膜の状態で用いられ、この際所定の
成分を真９中で固溶させて急冷し均一な原材料を得ると
いう製造過程を必畏とするという問題がある。また、成
分元本が多いことから組成の均一なｉ料ｔ−―製して薄
膜化することが困難である。１次、テルル酸化物の薄膜
はカルコゲナイド系非晶質ガラスに比べ感度は高いが蒸
着条件によって薄膜の組成が変化して均一な薄膜の製造
はかなシ困麹である。
録用材料として蒸着膜の状態で用いられ、この際所定の
成分を真９中で固溶させて急冷し均一な原材料を得ると
いう製造過程を必畏とするという問題がある。また、成
分元本が多いことから組成の均一なｉ料ｔ−―製して薄
膜化することが困難である。１次、テルル酸化物の薄膜
はカルコゲナイド系非晶質ガラスに比べ感度は高いが蒸
着条件によって薄膜の組成が変化して均一な薄膜の製造
はかなシ困麹である。
さらに、フルオレセインの薄膜は蒸着によって得られテ
ルル酸化物と同等の感度分解能を有するが、吸収波長が
４１３Ｑｎｍの可視部にあるため書込み、読み出しの光
源が限定さｎ記録再生装置の小型化に適している牛導体
レーザの発振波長く対応できないという問題がある・ 本発明は上記問題点に鑑みてなされたもので、比叡的長
波長帝に光吸収能のあるスクアリリウム色素を結着材と
組合せて蒸着によらずに塗布方式によっで基板上に薄膜
として形成させた光情報記録部材管提供することである
。
ルル酸化物と同等の感度分解能を有するが、吸収波長が
４１３Ｑｎｍの可視部にあるため書込み、読み出しの光
源が限定さｎ記録再生装置の小型化に適している牛導体
レーザの発振波長く対応できないという問題がある・ 本発明は上記問題点に鑑みてなされたもので、比叡的長
波長帝に光吸収能のあるスクアリリウム色素を結着材と
組合せて蒸着によらずに塗布方式によっで基板上に薄膜
として形成させた光情報記録部材管提供することである
。
すなわち、本発明の光情報記録部材は基板上に、一般式
（式中ｓ ｘｌａ発色団を示す）で表わされるスクアリ
リウム色素と結着材とを主成分とする有機薄膜を設けた
仁とｔ％徴とするものである。
リウム色素と結着材とを主成分とする有機薄膜を設けた
仁とｔ％徴とするものである。
本発明において用いられる上記一般式のスクアリリウム
色素はスクアリック酸（３，４−ジヒドロキシ−５−シ
クロブテン−１，２−ジオン）とフェノール類と芳香族
第５アミンとの８０生成物である。スクアリリウム色素
の具体例Ｆｉ９１１えば米国特許第４．１７翫９５６号
明細書に記載さｔているが、その代表的な例を以下の表
に示す。
色素はスクアリック酸（３，４−ジヒドロキシ−５−シ
クロブテン−１，２−ジオン）とフェノール類と芳香族
第５アミンとの８０生成物である。スクアリリウム色素
の具体例Ｆｉ９１１えば米国特許第４．１７翫９５６号
明細書に記載さｔているが、その代表的な例を以下の表
に示す。
−−〇 ！ε ｊε上述し友ように
、本発明はスクアリリウム色素を結着材中に分散させて
基体に適用することを％黴とするが、基体に適用後結着
材のガラス転移温度以上に加熱するとブロンズ光沢ｔ−
不し反射幕を高め書き込みの際に焦点制御が容易になる
という効果をも発揮子る・スクアリリウム色素は通常の
蒸着ではブロンズ光沢を示さない・ただ基板を液体窒素
温度にして蒸着するとブロンズ光沢を示すが装置が大が
かシとな夛またコスト高になる。さらに蒸着はバッチ方
式なので量産性が悪い。本発明ではそのようなことはな
く単に塗布方式で簡単にブロンズ光沢を示す薄ＩＩが得
らｎるという利点がある。ブロンズ光沢を示すと強い反
射ＷＡを示し書き込み読み出しのさいの光学系の制御情
報となシ均一なかつ明瞭なる穴をあけることができる。
、本発明はスクアリリウム色素を結着材中に分散させて
基体に適用することを％黴とするが、基体に適用後結着
材のガラス転移温度以上に加熱するとブロンズ光沢ｔ−
不し反射幕を高め書き込みの際に焦点制御が容易になる
という効果をも発揮子る・スクアリリウム色素は通常の
蒸着ではブロンズ光沢を示さない・ただ基板を液体窒素
温度にして蒸着するとブロンズ光沢を示すが装置が大が
かシとな夛またコスト高になる。さらに蒸着はバッチ方
式なので量産性が悪い。本発明ではそのようなことはな
く単に塗布方式で簡単にブロンズ光沢を示す薄ＩＩが得
らｎるという利点がある。ブロンズ光沢を示すと強い反
射ＷＡを示し書き込み読み出しのさいの光学系の制御情
報となシ均一なかつ明瞭なる穴をあけることができる。
本発明における結着材はスクア９１Ｊウム色累の構造式
との関係で適宜選択使用できるが例えばポリビニルブチ
ラール橡脂ま友はニトロセルローズまたはそｎらの５１
曾物を用いることができる。さらに、本発明においては
スクアリリウム色素と結着剤の他に必要に応じ各種添加
剤を適宜選択使用できる。ここで「ブロンズ光沢」とは
、色素が特定の光波長域で示す金属様の反射であって、
実際には反射率２０％以上のものが適しておシそして３
０％のものが好ましい。ブロンズ光ｆＩ金属の反射と真
なシ４Ｉｆの着色をもっているが、記録再生用のレーザ
光の波長に対しては高い反射率を持たせることができる
のでｔ情報読出光量を多くすることができ読出信号の８
７Ｍを向上させることができる。
との関係で適宜選択使用できるが例えばポリビニルブチ
ラール橡脂ま友はニトロセルローズまたはそｎらの５１
曾物を用いることができる。さらに、本発明においては
スクアリリウム色素と結着剤の他に必要に応じ各種添加
剤を適宜選択使用できる。ここで「ブロンズ光沢」とは
、色素が特定の光波長域で示す金属様の反射であって、
実際には反射率２０％以上のものが適しておシそして３
０％のものが好ましい。ブロンズ光ｆＩ金属の反射と真
なシ４Ｉｆの着色をもっているが、記録再生用のレーザ
光の波長に対しては高い反射率を持たせることができる
のでｔ情報読出光量を多くすることができ読出信号の８
７Ｍを向上させることができる。
通常、本発明における有機薄膜はスクアＩＪ ＩＪウム
色木を適当な溶媒と結着材中に分散させた溶液を基板上
に塗布することＫよって形成するール、エタノール、ア
セトン、メチレンジクロライドｔたはそれらの混合物な
どｔｆ用できる。
色木を適当な溶媒と結着材中に分散させた溶液を基板上
に塗布することＫよって形成するール、エタノール、ア
セトン、メチレンジクロライドｔたはそれらの混合物な
どｔｆ用できる。
塗布はスプレー、ローラーコーティング、ディッピング
およびスピンユングなどの慣用のコーティング法によっ
て行なわれる。スクアリリウム色素線結着材１重量部＃
Ｍシα１〜１重量部の割付で使用するのが適当である。
およびスピンユングなどの慣用のコーティング法によっ
て行なわれる。スクアリリウム色素線結着材１重量部＃
Ｍシα１〜１重量部の割付で使用するのが適当である。
ｔた、有機薄膜はα１μｍ〜５ｍμの膜厚で形成さｎる
。
。
本発明において使用さｎる基板材料は当業者には既知の
ものでアシ、便用レーザー光に対して透明または不透明
のいずれでもよい。基板材料の材買としては、ガラス、
石英、セラミック、プラスチックス、紙、板状ｔｘは箔
状の金員などの一般に使用されている記録材料の支持体
でよい・ 本発明の光情報配録部材に適用さｎるレーザ光は色素の
吸収波長に応じて選択する必要がある。従って、そｎぞ
ｎの色素に応じて１２． Ｈｅセ、ムｒ ％ Ｈｅ −
Ｎｅ ％ルビー、色素、半導体レーザな−どが選択さｎ
る・ さらに、スクアリリウム色素はその種類によりその有機
色素特有の吸収帯を有するので、配置用光源の種類、波
長に応じてスクアリリウム色素を選択することＫよシ非
常に大きな薄膜の吸収係数が得られ、したがって従来の
材料に比軟して感度の向上と信号／雑音（ｓ７ｍ ）比
の向上を達成できる。
ものでアシ、便用レーザー光に対して透明または不透明
のいずれでもよい。基板材料の材買としては、ガラス、
石英、セラミック、プラスチックス、紙、板状ｔｘは箔
状の金員などの一般に使用されている記録材料の支持体
でよい・ 本発明の光情報配録部材に適用さｎるレーザ光は色素の
吸収波長に応じて選択する必要がある。従って、そｎぞ
ｎの色素に応じて１２． Ｈｅセ、ムｒ ％ Ｈｅ −
Ｎｅ ％ルビー、色素、半導体レーザな−どが選択さｎ
る・ さらに、スクアリリウム色素はその種類によりその有機
色素特有の吸収帯を有するので、配置用光源の種類、波
長に応じてスクアリリウム色素を選択することＫよシ非
常に大きな薄膜の吸収係数が得られ、したがって従来の
材料に比軟して感度の向上と信号／雑音（ｓ７ｍ ）比
の向上を達成できる。
次に、本発明を以下の実施例によって訳明するが、こｎ
Ｋなんら限定さｎるもので鉱ない。
Ｋなんら限定さｎるもので鉱ない。
実施例 １
ポリビニルブチラール（積木化学 １ｔ
ニスレックスＢＭ−５） エタノール−メチレンジクロライド（１：１） １
５ａｄ上配成分からなる組成物をボールミル（ガラスポ
ール）で１０時間分散した後こｎをアクリル基板（三菱
レイヨンアクリライトムＲ）上にスピナー（１０００ｒ
ｐｍ）で塗布乾燥い直１１ａ厚１６μ！＋１）。次に％
１００℃で３０分間加熱を行うと表面に金属光沢を有す
る均一なｌ１ｌＩ展が得らＡｆｃ。
ニスレックスＢＭ−５） エタノール−メチレンジクロライド（１：１） １
５ａｄ上配成分からなる組成物をボールミル（ガラスポ
ール）で１０時間分散した後こｎをアクリル基板（三菱
レイヨンアクリライトムＲ）上にスピナー（１０００ｒ
ｐｍ）で塗布乾燥い直１１ａ厚１６μ！＋１）。次に％
１００℃で３０分間加熱を行うと表面に金属光沢を有す
る均一なｌ１ｌＩ展が得らＡｆｃ。
かくして作製した光情報記録部材に図に示す装置（−転
数３００ ｒｐｍ ）を用いて光源として８５０ｎｍの
半導体レーザを用いビーム径１．５μ、照射面ノセワー
４ｍＷで書き込み管行ったところ照射部分に均一かつ明
瞭な穴があい次、Ｓβ比はα５ ＭＨｚで４０ｄＢであ
つ７ｔ（工！バンド−３ＱＫＨｇで測定）・ 実施例 ２ ニトロセルロース（ダ（−ｋＡ４Ｒ８’＋６）
１ を上記成分からなる組成物をボールイルで１０時
間分散した後アクリル基板（アクリライトＡＲ）上にス
ピナー（２０００ｒｐｍ）で塗布乾燥し７ｔＣｊｌｌ厚
１３μ）。次に８０℃で一１時間加熱を行うと表面に金
属光沢を有する均一な薄膜が得らｔ’ｌ−ｆＣ。
数３００ ｒｐｍ ）を用いて光源として８５０ｎｍの
半導体レーザを用いビーム径１．５μ、照射面ノセワー
４ｍＷで書き込み管行ったところ照射部分に均一かつ明
瞭な穴があい次、Ｓβ比はα５ ＭＨｚで４０ｄＢであ
つ７ｔ（工！バンド−３ＱＫＨｇで測定）・ 実施例 ２ ニトロセルロース（ダ（−ｋＡ４Ｒ８’＋６）
１ を上記成分からなる組成物をボールイルで１０時
間分散した後アクリル基板（アクリライトＡＲ）上にス
ピナー（２０００ｒｐｍ）で塗布乾燥し７ｔＣｊｌｌ厚
１３μ）。次に８０℃で一１時間加熱を行うと表面に金
属光沢を有する均一な薄膜が得らｔ’ｌ−ｆＣ。
かくして作製した光情報記録部材に図に示す装置（１転
数１８０ Ｏｒｐｍ）を用い光源としてＢｅ −Ｎｅレ
ーザを用いビーム径２．４μｍ１記録面ノワー８ｍＷで
書き込みを行ったところ照射部分に良好な穴があい皮。
数１８０ Ｏｒｐｍ）を用い光源としてＢｅ −Ｎｅレ
ーザを用いビーム径２．４μｍ１記録面ノワー８ｍＷで
書き込みを行ったところ照射部分に良好な穴があい皮。
８Ａ比は５ＱｔｌＢであり几。
添付図面は本発明に用いる情報記録再生装置を示す。
１・・・レーザ光源、２・・・偏光ビームスプリッタ、
３・・・猛波長板、４・・・集光レンズ、５・・・光検
出器、６・・・モータ、７・・・有機薄膜、８・・・基
板。
３・・・猛波長板、４・・・集光レンズ、５・・・光検
出器、６・・・モータ、７・・・有機薄膜、８・・・基
板。
Claims (1)
- 【特許請求の範囲】 基板上に、一般式 （式中、Ｘは発色団を示す）で表わされるスクアリリウ
ム色素と結着材とを主成分とする有機ａｍを設けたこと
を特徴とする、高−密度エネルギービームによって状態
変化を生じさせて記録再生可能な光情報記録部材。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56209931A JPS58112792A (ja) | 1981-12-28 | 1981-12-28 | 光情報記録部材 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56209931A JPS58112792A (ja) | 1981-12-28 | 1981-12-28 | 光情報記録部材 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS58112792A true JPS58112792A (ja) | 1983-07-05 |
Family
ID=16581021
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56209931A Pending JPS58112792A (ja) | 1981-12-28 | 1981-12-28 | 光情報記録部材 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58112792A (ja) |
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