JPH10509206A - 水性自己架橋共重合体分散物の2段階製造方法およびその塗料への使用 - Google Patents
水性自己架橋共重合体分散物の2段階製造方法およびその塗料への使用Info
- Publication number
- JPH10509206A JPH10509206A JP8517141A JP51714196A JPH10509206A JP H10509206 A JPH10509206 A JP H10509206A JP 8517141 A JP8517141 A JP 8517141A JP 51714196 A JP51714196 A JP 51714196A JP H10509206 A JPH10509206 A JP H10509206A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- mol
- copolymer dispersion
- meth
- aqueous self
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/283—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing one or more carboxylic moiety in the chain, e.g. acetoacetoxyethyl(meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.単量体組成が (Aa)3乃至35重量%、好ましくは8乃至15重量%、のアセトアセチル 基を含む(メタ)アクリル酸エステル単量体、 (Ab)1乃至20重量%、好ましくは3乃至16重量%、のα,β−エチレ ン系不飽和カルボン酸、好ましくは(メタ)アクリル酸、 (Ac)11乃至96重量%、好ましくは30乃至70重量%、の(メタ)ア クリル酸アルキルエステルおよび、所望であれば、マレイン酸またはフマル酸の ジエステル、及び (Ad)0乃至40重量%、好ましくは0乃至25重量%、のビニル芳香族化 合物、ビニルエステル、(メタ)アクリル酸ヒドロキシアルキル、(メタ)アク リルアミドのような他の遊離基重合性単量体、 であり、成分(Aa)乃至(Ad)のパーセントの合計は必須に100であり 、分散物が架橋剤として働くポリアミンにより中和されている水性自己架橋共重 合体分散物の製造方法において、 A)2段階遊離基乳化重合を実施し、ただし第1段階においては、単量体(A a)乃至(Ad)の混合物60乃至90重量%を、第2段階においては、単量体 (Aa)乃至(Ad)の混合物10乃至40重量%を共重合し、上記パーセント の合計は必須に100であり、アクリル酸エステル共重合体(A)がアセトアセ チル基を0.2乃至1.7mol/kg、好ましくは0.4乃至0.8mol/kg、の量 で、カルボキシル基を0.15乃至1.6mol/kg、好ましくは0.4乃至0. 75mol/kg、の量で含み、そしてカルボキシル基をアセトアセチル基に対し5 0乃至95mol%、好ましくは80乃至90mol%、の量で存在する条件を保持し 、 そしてついで B)共重合体分散物(A)のカルボキシル基を分子中に少なくとも2個の第1 級アミノ基を含むポリアミンと、全第1級アミノ基に対し50乃至100mol% 、好ましくは90乃至100mol%、の割合で、塩を形成しながら、反応する、 工程を含むことを特徴とする水性自己架橋共重合体分散物の製造方法。 2.請求の範囲1の製造方法によって製造された水性自己架橋共重合体分散物。 3.請求の範囲1の製造方法によって製造された水性自己架橋共重合体分散物の 室温または高温で架橋する貯蔵安定な1成分塗料の結合剤としての使用。 4.共重合体分散物対ポリイソシアネートの比が固体基準で90:10乃至60 :40に選ばれた低分子量ポリイソシアネートと組み合わせて、請求の 範囲1の製造方法によって製造された水性自己架橋共重合体分散物の2成分コー ティング材料の結合剤としての使用。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT221094A AT402504B (de) | 1994-11-29 | 1994-11-29 | Verfahren zur herstellung von wässrigen, selbstvernetzenden copolymerisatdispersionen und ihre verwendung als bindemittel für lagerstabile einkomponentenlacke |
AT2210/94 | 1995-11-08 | ||
AT1833/95 | 1995-11-08 | ||
AT183395A AT403478B (de) | 1995-11-08 | 1995-11-08 | Verwendung von wässrigen, nach einem zweistufigen verfahren hergestellten, selbstvernetzenden copolymerisatdispersionen als bindemittel für zweikomponentenlacke |
PCT/AT1995/000227 WO1996016998A1 (de) | 1994-11-29 | 1995-11-23 | Verfahren zur zweistufigen herstellung von wässrigen, selbstvernetzenden copolymerisatdispersionen und deren verwendung für lacke |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH10509206A true JPH10509206A (ja) | 1998-09-08 |
JP3455225B2 JP3455225B2 (ja) | 2003-10-14 |
Family
ID=25596931
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP51714196A Expired - Fee Related JP3455225B2 (ja) | 1994-11-29 | 1995-11-23 | 水性自己架橋共重合体分散物の2段階製造方法およびその塗料への使用 |
Country Status (11)
Country | Link |
---|---|
US (1) | US5939482A (ja) |
EP (1) | EP0794970B1 (ja) |
JP (1) | JP3455225B2 (ja) |
AT (1) | ATE170883T1 (ja) |
CA (1) | CA2203103A1 (ja) |
DE (1) | DE59503548D1 (ja) |
DK (1) | DK0794970T3 (ja) |
ES (1) | ES2122695T3 (ja) |
NO (1) | NO308954B1 (ja) |
PL (1) | PL320422A1 (ja) |
WO (1) | WO1996016998A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011137151A (ja) * | 2009-12-30 | 2011-07-14 | Rohm & Haas Co | 低臭気スチレン系ポリマー分散物 |
JP2012224840A (ja) * | 2011-04-18 | 2012-11-15 | Rohm & Haas Co | 水白化耐性コーティングのためのコポリマー分散物 |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19609509B4 (de) * | 1996-03-11 | 2006-11-02 | Celanese Emulsions Gmbh | Wäßrige Polymerdispersionen als Bindemittel für elastische block- und kratzfeste Beschichtungen |
ES2166079T3 (es) * | 1996-05-10 | 2002-04-01 | Du Pont | Compuestos polimeros acrilicos. |
US6417267B1 (en) | 1996-05-28 | 2002-07-09 | Eastman Chemical Company | Adhesive compositions containing stable amino-containing polymer latex blends |
AU729319B2 (en) | 1996-05-28 | 2001-02-01 | Eastman Chemical Company | Surfactant-containing acetoacetoxy-functional and enamine-functional polymers |
US5998543A (en) * | 1996-05-28 | 1999-12-07 | Eastman Chemical Company | Stable amino-containing polymer latex blends |
US6028155A (en) * | 1997-05-21 | 2000-02-22 | Eastman Chemical Company | Surfactant-containing acetoacetoxy-functional and enamine-functional polymers |
US5891950A (en) * | 1996-05-28 | 1999-04-06 | Eastman Chemical Company | Use of stable amino-functional latexes in water-based inks |
US5962556A (en) * | 1996-10-22 | 1999-10-05 | Eastman Chemical Company | Functional latexes resistant to hydrolysis |
US6262169B1 (en) | 1998-05-14 | 2001-07-17 | Eastman Chemical Company | Protonated amines for controlled crosslinking of latex polymers |
JP4242930B2 (ja) * | 1997-05-21 | 2009-03-25 | イーストマン ケミカル カンパニー | フィルム形成まで化学的及び物理的に安定な反応性ラテックスブレンドを調製する方法 |
US6649679B1 (en) | 1997-09-18 | 2003-11-18 | Eastman Chemical Company | Stable waterborne polymer compositions containing poly(alkylenimines) |
AT407045B (de) * | 1998-10-19 | 2000-11-27 | Vianova Kunstharz Ag | Wässrige, selbstvernetzende copolymerisatdispersionen, ein verfahren zu ihrer herstellung und ihre verwendung in bindemitteln für lacke |
JP3654820B2 (ja) * | 2000-06-20 | 2005-06-02 | 大日本塗料株式会社 | 水性塗料用樹脂組成物 |
AU2002301310B2 (en) | 2001-10-17 | 2007-12-20 | Rohm And Haas Company | Polymer composition |
US20030134973A1 (en) * | 2002-01-15 | 2003-07-17 | Chen Robert Gow-Sheng | Waterborne latexes for anti-corrosive and solvent-resistant coating compositions |
MXPA05010454A (es) * | 2003-04-02 | 2005-11-04 | Valspar Sourcing Inc | Dispersiones y recubrimientos acuosos. |
US8465844B2 (en) * | 2004-02-13 | 2013-06-18 | Henkel Ag & Co. Kgaa | Elastic attachment adhesive containing radial block copolymer |
US20050182194A1 (en) * | 2004-02-13 | 2005-08-18 | Qiwei He | Adhesive containing radial block copolymer |
BR122016007793B1 (pt) * | 2004-10-20 | 2018-11-06 | Valspar Sourcing, Inc. | método para preparar uma lata de alumínio para bebida |
BRPI1014965B1 (pt) | 2009-04-09 | 2019-09-17 | Swimc Llc | Artigo, e, composição para revestimento |
US8486574B2 (en) * | 2009-07-14 | 2013-07-16 | Ford Global Technologies, Llc | Method and system for power control in an automotive vehicle |
US8754614B2 (en) * | 2009-07-17 | 2014-06-17 | Tesla Motors, Inc. | Fast charging of battery using adjustable voltage control |
EP3208289A1 (en) | 2009-07-17 | 2017-08-23 | Valspar Sourcing, Inc. | Coating composition and articles coated therewith |
BR112012006038B8 (pt) | 2009-09-18 | 2020-10-13 | Eng Polymer Solutions Inc | "método de revestimento de bobina, artigo, e, método de formar um artigo" |
DE102010029930A1 (de) | 2010-06-10 | 2011-12-15 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Acetoacetoxyalkyl(meth)acrylat |
BR112015032814B1 (pt) | 2013-07-02 | 2021-12-14 | Swimc Llc | Artigo, e, métodos para fazer uma composição de revestimento e para formar um revestimento curado |
CN105377703B (zh) | 2013-07-02 | 2017-09-08 | 威士伯采购公司 | 用于包装制品诸如食品和饮料容器的涂料组合物 |
CN105085788B (zh) * | 2015-09-07 | 2018-01-30 | 山东天庆科技发展有限公司 | 一种水性非离子丙烯酸树脂及其合成方法 |
US9796873B2 (en) | 2016-02-02 | 2017-10-24 | Ennis Paint, Inc. | Linear polyglycidyl amine additives for controlled crosslinking of latex polymers |
CA3017548A1 (en) | 2016-03-18 | 2017-09-21 | Basf Se | Finely divided aqueous multistage polymer dispersion, method for the production thereof, and use thereof as a binder |
WO2018063095A1 (en) * | 2016-09-29 | 2018-04-05 | Nipsea Technologies Pte Ltd | Crosslinking agent for polymer emulsions |
CN108299594A (zh) * | 2016-09-30 | 2018-07-20 | 广东华润涂料有限公司 | 用于甲醛清除的水分散性共聚物 |
CN110317502B (zh) * | 2019-06-04 | 2021-05-14 | 嘉宝莉化工集团股份有限公司 | 一种水性木器封闭底漆及其制备方法 |
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US4997772A (en) * | 1987-09-18 | 1991-03-05 | Eastman Kodak Company | Water-insoluble particle and immunoreactive reagent, analytical elements and methods of use |
US5116895A (en) * | 1988-12-30 | 1992-05-26 | Union Oil Company Of California | Polymer systems and methods for their production |
US5055506A (en) * | 1988-12-30 | 1991-10-08 | Union Oil Company Of California | Polymer systems and methods for their production |
DE3902103A1 (de) * | 1989-01-25 | 1990-08-02 | Roehm Gmbh | Bindemittel fuer waessrige glanzfarben |
US5391624A (en) * | 1992-02-10 | 1995-02-21 | S. C. Johnson & Son, Inc. | Thermosettable compositions |
AT396934B (de) * | 1992-02-14 | 1993-12-27 | Vianova Kunstharz Ag | Verfahren zur herstellung von wässrigen, selbstvernetzenden polymerdispersionen und ihre verwendung als bindemittel für lagerstabile einkomponentenlacke |
GB9221222D0 (en) * | 1992-10-09 | 1992-11-25 | Ici Plc | Coating composition |
US5369163A (en) * | 1992-11-13 | 1994-11-29 | Rohm And Haas Company | Process for preparing large dimension emulsion polymer particles, polymer product and uses thereof |
US5306744A (en) * | 1992-12-18 | 1994-04-26 | Rohm And Haas Company | Functionalized multistage polymers |
US5308890A (en) * | 1993-02-26 | 1994-05-03 | Rohm And Haas Company | Emulsion polymer blend of a multi-stage latex and a non-film forming latex |
-
1995
- 1995-11-23 DE DE59503548T patent/DE59503548D1/de not_active Expired - Lifetime
- 1995-11-23 JP JP51714196A patent/JP3455225B2/ja not_active Expired - Fee Related
- 1995-11-23 AT AT95937711T patent/ATE170883T1/de not_active IP Right Cessation
- 1995-11-23 US US08/836,304 patent/US5939482A/en not_active Expired - Fee Related
- 1995-11-23 ES ES95937711T patent/ES2122695T3/es not_active Expired - Lifetime
- 1995-11-23 PL PL95320422A patent/PL320422A1/xx unknown
- 1995-11-23 EP EP95937711A patent/EP0794970B1/de not_active Expired - Lifetime
- 1995-11-23 CA CA002203103A patent/CA2203103A1/en not_active Abandoned
- 1995-11-23 WO PCT/AT1995/000227 patent/WO1996016998A1/de active IP Right Grant
- 1995-11-23 DK DK95937711T patent/DK0794970T3/da active
-
1997
- 1997-05-22 NO NO972352A patent/NO308954B1/no unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011137151A (ja) * | 2009-12-30 | 2011-07-14 | Rohm & Haas Co | 低臭気スチレン系ポリマー分散物 |
JP2012224840A (ja) * | 2011-04-18 | 2012-11-15 | Rohm & Haas Co | 水白化耐性コーティングのためのコポリマー分散物 |
Also Published As
Publication number | Publication date |
---|---|
ATE170883T1 (de) | 1998-09-15 |
US5939482A (en) | 1999-08-17 |
DE59503548D1 (de) | 1998-10-15 |
EP0794970A1 (de) | 1997-09-17 |
NO972352L (no) | 1997-05-22 |
JP3455225B2 (ja) | 2003-10-14 |
EP0794970B1 (de) | 1998-09-09 |
WO1996016998A1 (de) | 1996-06-06 |
NO972352D0 (no) | 1997-05-22 |
PL320422A1 (en) | 1997-09-29 |
CA2203103A1 (en) | 1996-06-06 |
DK0794970T3 (da) | 1999-06-07 |
NO308954B1 (no) | 2000-11-20 |
ES2122695T3 (es) | 1998-12-16 |
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