JPH06112255A - 半導体素子用ボンディング線 - Google Patents

半導体素子用ボンディング線

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Publication number
JPH06112255A
JPH06112255A JP4262219A JP26221992A JPH06112255A JP H06112255 A JPH06112255 A JP H06112255A JP 4262219 A JP4262219 A JP 4262219A JP 26221992 A JP26221992 A JP 26221992A JP H06112255 A JPH06112255 A JP H06112255A
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Japan
Prior art keywords
added
wire
bonding
purity
amount
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JP3090549B2 (ja
Inventor
Kazumitsu Itabashi
一光 板橋
Takeshi Kujiraoka
毅 鯨岡
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Tanaka Denshi Kogyo KK
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Tanaka Denshi Kogyo KK
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Abstract

(57)【要約】 【目的】Pdの添加によりAu線の強度向上を図ると同
時に、ボンディング時における低ループ化を実現して、
LSIパッケージの小型,軽量化に対応するに極めて有
用な半導体素子用ボンディング線を提供する。 【構成】高純度Auに、Pdを1〜40wt%含有せしめる
と共に、Sc,Y,希土類元素の中から少なくとも1種
を0.0001〜0.05wt%含有せしめ、さらにBe,Ca,G
e,Ni,Fe,Co,Agの中から1種以上を0.0001
〜0.05wt%含有せしめて溶解鋳造し、次に溝ロール加工
を施し、その途中で焼なまし処理を施した後に線引加工
し、更に十分な応力除去を行って線径25μmの母線を成
形した。

Description

【発明の詳細な説明】
【0001】
【産業上の利用分野】本発明は、半導体素子のチップ電
極と基板上の外部リードとを接続するために用いられる
半導体素子用ボンディングAu線、特にワイヤボンディ
ング法及びバンプ接続法に好適なものに関する。
【0002】
【従来の技術】従来から、例えばキャピラリーの先端に
垂下せしめたAu線の先端を電気トーチにより溶融させ
てボールを形成し、このボールをチップ上のAl又はA
l合金からなる電極に圧着・切断してバンプ電極を形成
するバンプ接続法や、前記ボールをチップ電極に圧着,
接合せしめた後、ループ状に外部リードまで導いて該外
部リードに圧着・切断することにより、チップ電極と外
部リードを接続させるワイヤボンディング法が知られて
いる。
【0003】また、この種ボンディングに用いるに有用
なAu線として、特公昭62−23455号,特開平2
−91944号に開示されるように、Pdと、Be,C
a,Ge,La,Ceの中から1種以上とを添加してな
るものがある。
【0004】
【発明が解決しようとする課題】上記従来のボンディン
グ線では、前記各元素の添加によってAu線における強
度の向上は図れるものの、ボール形成時に熱影響を受け
て再結晶する領域が比較的長くなる結果、ボンディング
時におけるループ高さが高くなる。よって、近年におけ
るLSIパッケージの小型,軽量化に伴う低ループ(例
えば150μm以下)の要求を満足し得るものではなか
った。
【0005】本発明はこのような従来事情に鑑みてなさ
れたものであり、その目的とするところは、Pdの添加
によりAu線の強度向上を図ると同時に、ループ高さを
低くできるAu線を提供することにある。
【0006】
【課題を解決するための手段】以上の目的を達成するた
めに、本発明の半導体素子用ボンディング線は、高純度
Auに、高純度Pdを1〜40wt%含有せしめると共
に、Sc,Y,希土類元素の中から1種以上を0.00
01〜0.05wt%含有せしめてなることを特徴とす
る。
【0007】また、後述の理由から、前記の配合に加え
て、Be,Ca,Ge,Ni,Fe,Co,Agの中か
ら1種以上を0.0001〜0.05wt%含有せしめる
ことが有用である。
【0008】
【作用】上記の構成によれば、Pdの所定量の添加によ
ってAu線の破断強度が向上すると同時に、Sc,Y,
希土類元素の中から少なくとも1種を同時添加すること
でボール形成時の再結晶領域を短くでき、ボンディング
の際のループ高さが低くなる。
【0009】また、Be,Ca,Ge,Ni,Fe,C
o,Agの同時添加によって、前記破断強度をさらに高
レベルなものにすると共に、ループ高さをより低くし得
る。
【0010】しかし乍ら、Pdの添加量が1wt%未満で
は満足な破断強度が得られず、Pdの添加量が40wt%
を越えると伸線加工が困難になるので好ましくない。
【0011】また、Sc,Y,希土類元素の添加量が
0.0001wt%未満だと前述の低ループ効果を得られ
ず、また、これら添加元素の添加量が0.05wt%を越
えると、ボール形成時におけるボール形状が安定せず、
ボールとチップ電極との接合強度が低下してA点剥がれ
の発生率が高くなる。
【0012】さらに、Be,Ca,Ge,Ni,Fe,
Co,Agの添加量が0.0001wt%未満では上記の
効果を得られず、同添加量が0.05wt%を越えるとボ
ール形成時におけるボール形状が安定せず、ボールとチ
ップ電極との接合強度が低下するので好ましくない。
【0013】従って、Pdの添加量を1〜40wt%の範
囲に、Sc,Y,希土類元素の添加量を0.0001〜
0.05wt%の範囲に、Be,Ca,Ge,Ni,F
e,Co,Agの添加量を0.0001〜0.05wt%
の範囲に、夫々設定した。
【0014】
【実施例】以下、具体的な実施例と比較例について説明
する。高純度Au(99.99%以上)に、Pd,S
c,Y,La,Ce、Be,Ca,Ge,Ni,Fe,
Co,Agを表1中に示す含有率に基づき添加して溶解
鋳造し、次に溝ロール加工を施し、その途中で焼なまし
処理を施した後に線引加工で線径25μmの母線に成形
し、更に十分な応力除去を行うことにより各試料とし
た。
【0015】表1中の試料No.1〜8は高純度Auに
Pd(以下、添加元素Iという)を添加すると共に、S
c,Y,希土類元素(以下、添加元素IIという)の中か
ら少なくとも1種を添加した本発明実施品である。ま
た、試料No.9〜12は、前記の配合に加えてさらに
Be,Ca,Ge,Ni,Fe,Co,Ag(以下、添
加元素III という)の中から少くとも1種を同時添加し
た本発明実施品である。
【0016】また、表1中の試料No.13,14は高
純度AuにPdのみを添加した比較品、試料No.15
〜18は高純度AuにPdを添加すると共に、上記添加
元素III の代表としてBe,Ca,Geを選んで1種ま
たは2種添加し、添加元素IIを添加しない比較品、試料
NO.19は高純度Auに何も添加しない比較品であ
る。
【0017】尚、表1では希土類元素の代表としてE
u,Gd,Dyを選んだが、これ以外の希土類元素はE
u,Gd,Dyと同質性のため省略した。
【0018】上記のようにして作製した各試料を熱処理
により所定の伸び率に合わせた後、破断強度及びループ
高さを測定した。
【0019】破断強度は、各試料を標点間距離100m
mにて引張速度10mm/minで引張り試験を行った
時の破断荷重を測定した。
【0020】ループ高さは、各試料をAl薄膜(0.8
μm厚)のチップ電極上に所定条件にてボンディングし
た後、測定顕微鏡にて測定した。これらの結果も表1中
に示す。
【0021】
【表1】
【0022】而して、試料No.1〜8の測定結果か
ら、高純度Auに添加元素I(Pd)を1〜40wt%の
範囲内で添加すると共に、添加元素II(Sc,Y,希土
類元素)の中から夫々少なくとも1種を同時添加すれ
ば、破断強度の改善が得られると同時に、ループ高さを
低くできることが確認できた。
【0023】また、試料No.9〜12の測定結果か
ら、上記の配合に加えて添加元素III(Be,Ca,G
e,Ni,Fe,Co,Ag)の中から夫々少なくとも
1種を同時添加すれば、より高レベルな破断強度が得ら
れると同時に、ループ高さをさらに低くできることが確
認できた。
【0024】また、試料No.13,14の測定結果、
並びに試料No.15〜18の測定結果から、Pdのみ
の添加、若しくはPdと添加元素III の添加では、所定
の破断強度は得られるものの、ループ高さが高くなるこ
とが確認できた。さらに、試料No.19の測定結果か
ら、Pdの添加がない場合は所定の破断強度が得られな
いと共に、ループ高さが極めて高いことが確認できた。
【0025】
【発明の効果】本発明に係る半導体素子用ボンディング
線は以上説明したように構成したので、Pdの添加によ
る破断強度の向上効果はそのまま維持しつつ、その添加
量を所定の範囲内に限定すると共にSc,Y,希土類元
素を同時添加することで、ボンディング時におけるルー
プ高さを低くし得た。
【0026】従って、ボンディング後における所定のワ
イヤ強度を得ると同時に低ループ化を実現して、LSI
パッケージの小型,軽量化に対応するに極めて有用な半
導体素子用ボンディング線を提供できた。
【0027】さらに、Be,Ca,Ge,Ni,Fe,
Co,Agを所定量添加することで、より高レベルな破
断強度を得ると共に、低ループ化をさらに促進すること
ができた。

Claims (2)

    【特許請求の範囲】
  1. 【請求項1】 高純度Auに、高純度Pdを1〜40wt
    %含有せしめると共に、Sc,Y,希土類元素の中から
    1種以上を、0.0001〜0.05wt%含有せしめて
    なる半導体素子用ボンディング線。
  2. 【請求項2】 高純度Auに、高純度Pdを1〜40wt
    %含有せしめると共に、Sc,Y,希土類元素の中から
    1種以上を、0.0001〜0.05wt%含有せしめ、
    且つ、Be,Ca,Ge,Ni,Fe,Co,Agの中
    から1種以上を0.0001〜0.05wt%含有せしめ
    てなる半導体素子用ボンディング線。
JP04262219A 1992-09-30 1992-09-30 半導体素子用ボンディング線 Expired - Lifetime JP3090549B2 (ja)

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JP3090549B2 JP3090549B2 (ja) 2000-09-25

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US5945065A (en) * 1996-07-31 1999-08-31 Tanaka Denshi Kogyo Method for wedge bonding using a gold alloy wire
US6159420A (en) * 1996-05-28 2000-12-12 Tanaka Denshi Kogyo K.K. Gold alloy wire and method for making a bump
CN104785957A (zh) * 2015-04-08 2015-07-22 广州先艺电子科技有限公司 一种金锡合金丝材热轧方法
CN105063407A (zh) * 2015-05-30 2015-11-18 汕头市骏码凯撒有限公司 一种led封装用银合金键合丝及其制造方法

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Cited By (5)

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Publication number Priority date Publication date Assignee Title
US6159420A (en) * 1996-05-28 2000-12-12 Tanaka Denshi Kogyo K.K. Gold alloy wire and method for making a bump
US6213382B1 (en) 1996-05-28 2001-04-10 Tanaka Denshi Kogyo K.K. Method for making a bump
US5945065A (en) * 1996-07-31 1999-08-31 Tanaka Denshi Kogyo Method for wedge bonding using a gold alloy wire
CN104785957A (zh) * 2015-04-08 2015-07-22 广州先艺电子科技有限公司 一种金锡合金丝材热轧方法
CN105063407A (zh) * 2015-05-30 2015-11-18 汕头市骏码凯撒有限公司 一种led封装用银合金键合丝及其制造方法

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