JPH0582943B2 - - Google Patents
Info
- Publication number
- JPH0582943B2 JPH0582943B2 JP61021020A JP2102086A JPH0582943B2 JP H0582943 B2 JPH0582943 B2 JP H0582943B2 JP 61021020 A JP61021020 A JP 61021020A JP 2102086 A JP2102086 A JP 2102086A JP H0582943 B2 JPH0582943 B2 JP H0582943B2
- Authority
- JP
- Japan
- Prior art keywords
- carrier
- toner
- developer
- image
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920005989 resin Polymers 0.000 claims description 45
- 239000011347 resin Substances 0.000 claims description 45
- 239000002245 particle Substances 0.000 claims description 44
- 238000011161 development Methods 0.000 claims description 42
- 239000000178 monomer Substances 0.000 claims description 42
- 238000000034 method Methods 0.000 claims description 26
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 22
- 239000011230 binding agent Substances 0.000 claims description 18
- 229920001225 polyester resin Polymers 0.000 claims description 16
- 239000004645 polyester resin Substances 0.000 claims description 16
- 229920001577 copolymer Polymers 0.000 claims description 15
- 229910000859 α-Fe Inorganic materials 0.000 claims description 14
- -1 acrylic ester Chemical class 0.000 claims description 13
- 230000005684 electric field Effects 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 11
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 11
- 230000005415 magnetization Effects 0.000 claims description 10
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 7
- 239000000969 carrier Substances 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 7
- 230000001105 regulatory effect Effects 0.000 claims description 7
- 229930185605 Bisphenol Natural products 0.000 claims description 6
- 229920000098 polyolefin Polymers 0.000 claims description 5
- 239000001384 succinic acid Substances 0.000 claims description 5
- 238000011144 upstream manufacturing Methods 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 70
- 238000003756 stirring Methods 0.000 description 20
- 150000001338 aliphatic hydrocarbons Chemical group 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 7
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 229920001451 polypropylene glycol Polymers 0.000 description 5
- 239000000523 sample Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000011247 coating layer Substances 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 239000001530 fumaric acid Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- 108091008695 photoreceptors Proteins 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 3
- UAJRSHJHFRVGMG-UHFFFAOYSA-N 1-ethenyl-4-methoxybenzene Chemical compound COC1=CC=C(C=C)C=C1 UAJRSHJHFRVGMG-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- YLAXZGYLWOGCBF-UHFFFAOYSA-N 2-dodecylbutanedioic acid Chemical compound CCCCCCCCCCCCC(C(O)=O)CC(O)=O YLAXZGYLWOGCBF-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920007962 Styrene Methyl Methacrylate Polymers 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000006249 magnetic particle Substances 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 2
- CFQZKFWQLAHGSL-FNTYJUCDSA-N (3e,5e,7e,9e,11e,13e,15e,17e)-18-[(3e,5e,7e,9e,11e,13e,15e,17e)-18-[(3e,5e,7e,9e,11e,13e,15e)-octadeca-3,5,7,9,11,13,15,17-octaenoyl]oxyoctadeca-3,5,7,9,11,13,15,17-octaenoyl]oxyoctadeca-3,5,7,9,11,13,15,17-octaenoic acid Chemical compound OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\OC(=O)C\C=C\C=C\C=C\C=C\C=C\C=C\C=C\C=C CFQZKFWQLAHGSL-FNTYJUCDSA-N 0.000 description 1
- XVOUMQNXTGKGMA-OWOJBTEDSA-N (E)-glutaconic acid Chemical compound OC(=O)C\C=C\C(O)=O XVOUMQNXTGKGMA-OWOJBTEDSA-N 0.000 description 1
- BJQFWAQRPATHTR-UHFFFAOYSA-N 1,2-dichloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1Cl BJQFWAQRPATHTR-UHFFFAOYSA-N 0.000 description 1
- QOVCUELHTLHMEN-UHFFFAOYSA-N 1-butyl-4-ethenylbenzene Chemical compound CCCCC1=CC=C(C=C)C=C1 QOVCUELHTLHMEN-UHFFFAOYSA-N 0.000 description 1
- KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 description 1
- DMADTXMQLFQQII-UHFFFAOYSA-N 1-decyl-4-ethenylbenzene Chemical compound CCCCCCCCCCC1=CC=C(C=C)C=C1 DMADTXMQLFQQII-UHFFFAOYSA-N 0.000 description 1
- WJNKJKGZKFOLOJ-UHFFFAOYSA-N 1-dodecyl-4-ethenylbenzene Chemical compound CCCCCCCCCCCCC1=CC=C(C=C)C=C1 WJNKJKGZKFOLOJ-UHFFFAOYSA-N 0.000 description 1
- OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical compound CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- WHFHDVDXYKOSKI-UHFFFAOYSA-N 1-ethenyl-4-ethylbenzene Chemical compound CCC1=CC=C(C=C)C=C1 WHFHDVDXYKOSKI-UHFFFAOYSA-N 0.000 description 1
- LCNAQVGAHQVWIN-UHFFFAOYSA-N 1-ethenyl-4-hexylbenzene Chemical compound CCCCCCC1=CC=C(C=C)C=C1 LCNAQVGAHQVWIN-UHFFFAOYSA-N 0.000 description 1
- LUWBJDCKJAZYKZ-UHFFFAOYSA-N 1-ethenyl-4-nonylbenzene Chemical compound CCCCCCCCCC1=CC=C(C=C)C=C1 LUWBJDCKJAZYKZ-UHFFFAOYSA-N 0.000 description 1
- HLRQDIVVLOCZPH-UHFFFAOYSA-N 1-ethenyl-4-octylbenzene Chemical compound CCCCCCCCC1=CC=C(C=C)C=C1 HLRQDIVVLOCZPH-UHFFFAOYSA-N 0.000 description 1
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 1
- URMOYRZATJTSJV-UHFFFAOYSA-N 2-(10-methylundec-1-enyl)butanedioic acid Chemical compound CC(C)CCCCCCCC=CC(C(O)=O)CC(O)=O URMOYRZATJTSJV-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- JTWBYEWVFCYRSF-UHFFFAOYSA-N 2-(6-methylheptyl)butanedioic acid Chemical compound CC(C)CCCCCC(C(O)=O)CC(O)=O JTWBYEWVFCYRSF-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- DEGZUQBZHACZKW-UHFFFAOYSA-N 2-(methylamino)ethyl 2-methylprop-2-enoate Chemical compound CNCCOC(=O)C(C)=C DEGZUQBZHACZKW-UHFFFAOYSA-N 0.000 description 1
- ULEVTQHCVWIDPC-UHFFFAOYSA-N 2-(methylamino)ethyl prop-2-enoate Chemical compound CNCCOC(=O)C=C ULEVTQHCVWIDPC-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- WOPLHDNLGYOSPG-UHFFFAOYSA-N 2-butylbutanedioic acid Chemical compound CCCCC(C(O)=O)CC(O)=O WOPLHDNLGYOSPG-UHFFFAOYSA-N 0.000 description 1
- WHBAYNMEIXUTJV-UHFFFAOYSA-N 2-chloroethyl prop-2-enoate Chemical compound ClCCOC(=O)C=C WHBAYNMEIXUTJV-UHFFFAOYSA-N 0.000 description 1
- QDCPNGVVOWVKJG-UHFFFAOYSA-N 2-dodec-1-enylbutanedioic acid Chemical compound CCCCCCCCCCC=CC(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- HFCUBKYHMMPGBY-UHFFFAOYSA-N 2-methoxyethyl prop-2-enoate Chemical compound COCCOC(=O)C=C HFCUBKYHMMPGBY-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- FPOGSOBFOIGXPR-UHFFFAOYSA-N 2-octylbutanedioic acid Chemical compound CCCCCCCCC(C(O)=O)CC(O)=O FPOGSOBFOIGXPR-UHFFFAOYSA-N 0.000 description 1
- MFZOUWVHEQAVLP-UHFFFAOYSA-N 3-(10-methylundec-1-enyl)oxolane-2,5-dione Chemical compound CC(C)CCCCCCCC=CC1CC(=O)OC1=O MFZOUWVHEQAVLP-UHFFFAOYSA-N 0.000 description 1
- WVRNUXJQQFPNMN-VAWYXSNFSA-N 3-[(e)-dodec-1-enyl]oxolane-2,5-dione Chemical compound CCCCCCCCCC\C=C\C1CC(=O)OC1=O WVRNUXJQQFPNMN-VAWYXSNFSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- NQSLZEHVGKWKAY-UHFFFAOYSA-N 6-methylheptyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C(C)=C NQSLZEHVGKWKAY-UHFFFAOYSA-N 0.000 description 1
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 1
- 235000010893 Bischofia javanica Nutrition 0.000 description 1
- 240000005220 Bischofia javanica Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 1
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- OZCRKDNRAAKDAN-UHFFFAOYSA-N but-1-ene-1,4-diol Chemical compound O[CH][CH]CCO OZCRKDNRAAKDAN-UHFFFAOYSA-N 0.000 description 1
- LOGBRYZYTBQBTB-UHFFFAOYSA-N butane-1,2,4-tricarboxylic acid Chemical compound OC(=O)CCC(C(O)=O)CC(O)=O LOGBRYZYTBQBTB-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000012050 conventional carrier Substances 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
- WTNDADANUZETTI-UHFFFAOYSA-N cyclohexane-1,2,4-tricarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)C(C(O)=O)C1 WTNDADANUZETTI-UHFFFAOYSA-N 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001595 flow curve Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- GWCHPNKHMFKKIQ-UHFFFAOYSA-N hexane-1,2,5-tricarboxylic acid Chemical compound OC(=O)C(C)CCC(C(O)=O)CC(O)=O GWCHPNKHMFKKIQ-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 229920005684 linear copolymer Polymers 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 229940002712 malachite green oxalate Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- WRYWBRATLBWSSG-UHFFFAOYSA-N naphthalene-1,2,4-tricarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC(C(O)=O)=C21 WRYWBRATLBWSSG-UHFFFAOYSA-N 0.000 description 1
- LATKICLYWYUXCN-UHFFFAOYSA-N naphthalene-1,3,6-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC2=CC(C(=O)O)=CC=C21 LATKICLYWYUXCN-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- WDAISVDZHKFVQP-UHFFFAOYSA-N octane-1,2,7,8-tetracarboxylic acid Chemical compound OC(=O)CC(C(O)=O)CCCCC(C(O)=O)CC(O)=O WDAISVDZHKFVQP-UHFFFAOYSA-N 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- HDBWAWNLGGMZRQ-UHFFFAOYSA-N p-Vinylbiphenyl Chemical compound C1=CC(C=C)=CC=C1C1=CC=CC=C1 HDBWAWNLGGMZRQ-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- 229940051201 quinoline yellow Drugs 0.000 description 1
- 235000012752 quinoline yellow Nutrition 0.000 description 1
- 239000004172 quinoline yellow Substances 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- XOSXWYQMOYSSKB-LDKJGXKFSA-L water blue Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC(C=C2)=CC=C2S([O-])(=O)=O)=C(\C=C2)/C=C/C\2=N\C(C=C2)=CC=C2S([O-])(=O)=O)=CC(S(O)(=O)=O)=C1N.[Na+].[Na+] XOSXWYQMOYSSKB-LDKJGXKFSA-L 0.000 description 1
Description
〠ç£æ¥äžã®å©çšåé
æ¬çºæã¯éé»æœåã®çŸåæ¹æ³ã«é¢ããç¹ã«é»å
åçæ³ã«ãããŠåæ æäœäžã®æœåãçŸåããæ¹æ³
ã«é¢ãããã®ã§ããã ã åŸæ¥æè¡ åŸæ¥ãé»ååçè€åè£ çœ®çã«ãããŠåæ æäœã
äŸãã°æå äœãã©ã äžã®æœåãçŸåããæ¹æ³ãšã
ãŠã¯ããããŒèªèº«ã«ç£æ§ãä»äžããŠãã€ãªã¢ãäž
èŠãšããäžæåçŸåå€ãçšããå Žåãšãéç£æ§ã
ããŒåã¯ãããã«ç£æ§ãä»äžããããããŒãšç£æ§
ãã€ãªã¢ãšããæãäºæåçŸåå€ãçšããå Žåãš
ãããããåŸè ã®äºæåçŸåå€ã¯ãããŒã®æ©æŠåž¯
é»ã®å¶åŸ¡ã容æã§ãã€ãŠçŸåæ§ããããããã€ã
ããŒã«ä»»æã®è²ãä»äžã§ãããšããç¹åŸŽãããã
åºãçšããããŠããããããçŸåå€ã«ãããŠãåŸ
ãããç»åé¢ã®è§£åååã³é調åçŸæ§ããã®ä»ã®
å šè¬çãªç»è³ªã®æ¹è¯ãèšãããããã€ãªã¢åã³ã
ããŒã®ç²åŸãå°ãªããããè©Šã¿ããªãããŠããã äŸãã°ãæ¬åºé¡äººãå ã«ææ¡ããç¹é¡æ58â
57746å·ãå58â96900ãïŒå·ãå58â97973å·ç
ã®æ现æžã«ã¯ãåŸæ¥ã®80ã500ÎŒïœãšãã倧ç²åŸ
ã®ãã€ãªã¢ã«ä»£ããŠ50ÎŒïœä»¥äžã®å°ç²åŸãã€ãªã¢
ãšããæ··åããããããŒã®ç²åŸã20ÎŒïœä»¥äžãšã
ãçŸåå€ãçšããŠãéæ¥è§Šã§çŸåããæè¡ãèšèŒ
ãããŠããã äœããçŸåå€äžã®ãã€ãªã¢ãå°ç²åŸãšããå Ž
åããããŒãšãã€ãªã¢ã®æ©æŠåž¯é»æ§ãå£åããã
ãã«ããã€ãªã¢ãšçŸåå€æ¬éæ äœïŒäŸãã°çŸåã¹
ãªãŒãïŒåã³ãããŒãšã®éé»æ°çåã³ç©çççµå
åã匱ããªããå圢æã®éçšã§åèšãã€ãªã¢åã³
ãããŒãé£æ£ããŠè£ 眮å éšãæ±æããããç»åé¢
ã«ãããŒãä»çããŠãã¶ããçãããããã€ãªã¢
ãä»çïŒä»¥éããã€ãªã¢ä»çãšç§°ãïŒãããã
ãŠãé®®æãªç»åãåŸãããªãçã®åé¡ãæ®ãããŠ
ããã ãŸãããã€ãªã¢ãå°ç²åŸãšããå ŽåãçŸåå€æ¬
éæ äœäžã«çŸåå€ã®èå±€ã圢æããããããã€äž
åäžãªçŸåå€å±€ãšãªãããã«ãç»åã«ã ã©ãç»å
ã¬ããçãããããŠãé®®æãªç»åãåŸããé£ããª
ããæŽã«ãå€æ°æè€åãè¡ãªã€ãå ŽåãçŸåå€æ¬
éæ äœäžã«çŸåå€ã®èå±€ã圢æããéçšã«ãããŠ
匷ãå§åãå ããããã«ããããŒããã€ãªã¢ãžç©
ççã«åŒ·ãä»çãããšããæè¬ãã€ã«ãã³ã°çŸè±¡
ãå¢å ãããããŒãšãã€ãªã¢ãæå¹ã«æ©æŠåž¯é»ã§
ããªããªã€ãŠããã¶ãããããŒé£æ£ãçãããã
ãããŒããã€ã«ãã³ã°ãããã€ãªã¢ãçŸåãããŠ
ãã€ãªã¢ä»çãçãããããããã¯è¯å¥œãªèå±€ã
圢æã§ããªãã€ããããŠãé®®æãªç»åãåŸããé£
ãçã®åé¡ãããã ãã¶ããé€å»ããã«ã¯ãåæ æäœãšçŸåå€æ¬é
æ äœãšã®ééã倧ããããã°ããããçŸåé»æ¥µå¹
æã匱ããªã€ãŠãããŒã«ããçŸåãè¡ãªããã«ã
ããªããåæ æäœãšçŸåå€æ¬éæ äœãšã®éã«å€§ã
ãªæ¯åé»å Žãçºçãããã°çŸåæ§ã¯åäžãããã
éç»åéšãžã®ãããŒã®ãã¶ãããã€ãªã¢é£æ£ãå€
ããªããšãšãã«ãçŸåè£ çœ®ãé»æ°çã«çµ¶çžããã
ãšãèšèšäžéèŠãªé害ã«ãªã€ãŠããã æŽã«ãŸããããªãšã¹ãã«æš¹èã¯ã«ã«ããã«åºå
ã³æ°Žé žåºãå€æ°æããããã«åžæ°Žæ§ãæããŠã
ãããã®ãããªããªãšã¹ãã«æš¹èããã€ã³ããŒãš
ãããããŒã«ãããŠã¯é«æž©é«æ¹¿ã®ç°å¢æ¡ä»¶äžã§ã¯
ããªãã®æ°ŽåããããŒè¡šé¢ã«ååšããããšãšãª
ãããã®ããã«ãçŸåæã«æ¯åé»çãå°å ãã
ãšãæ°Žåã®åœ±é¿ã«ãããæ©æŠåž¯é»ã«ããèªèµ·ãã
ããããŒè¡šé¢ã®é»è·ããªãŒã¯ãããããªãããã®
çµæãšããŠç»åãã±çã®åé¡ãçºçããã ã çºæã®ç®ç æ¬çºæã®ç®çã¯ããã€ãªã¢åã³ãããŒã®é£æ£ã«
ããè£ çœ®å éšã®æ±æããç»åé¢ã«åèšé£æ£ãã€ãª
ã¢åã³ãããŒçãä»çããŠãã€ãªã¢ä»çããã¶ã
ãçºçããçã®åé¡ãçããããã€åèšãã€ãªã¢
åã³ãããŒéã«ã¯é©åœãªæ©æŠåž¯é»ãä»äžãããŠè¯
奜ãªçŸåãéæããããã®çµæã解åååã³é調
åçŸæ§ã«ããããé®®æãªç»å圢æãå¯èœã§ããçŸ
åæ¹æ³ãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯ãåäžã§è¯å¥œãªèå±€ã圢æ
ã§ãããã€ãŠç»åã ã©ãç»åã¬ãçã®ãªãé®®æãª
ç»åã®åŸãããçŸåæ¹æ³ãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯ãå€æ°æè€åã«ãããŠãã
è¯å¥œãªèå±€ã圢æã§ããŠããã€ãªã¢ä»çããã¶ã
çã®åé¡ãçºçããããã€åèšãã€ãªã¢åã³ãã
ãŒéã«ã¯é©åœãªæ©æŠåž¯é»ãä»äžãããŠçŸåãéæ
ããããã®çµæãããããé®®æãªç»å圢æãå¯èœ
ãªçŸåæ¹æ³ãæäŸããããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãé«æž©é«æ¹¿ã®ç°å¢æ¡ä»¶
äžã«ãããŠãç»åæãçã®åé¡ãçºçããªããé®®
æãªç»åã®åŸãããçŸåæ¹æ³ãæäŸããããšã«ã
ãã ã çºæã®æ§æåã³ãã®äœçšå¹æ å³ã¡ãæ¬çºæã¯ãçŸåå€æ¬éæ äœãžäº€æµãã€ã¢
ã¹ãå°å ããŠçŸåé åã«æ¯åé»çãçããããå
æ æäœäžã«åœ¢æãããæœåãçŸåå€æ¬éæ äœäžã®
ãã€ãªã¢åã³ãããŒå«æçŸåå€å±€ã§çŸåããã«é
ããŠãåèšçŸåå€å±€ãè局圢æéšæã«ããèŠå¶ã
ãŠåæ æäœãšéæ¥è§Šãšãªãããã«çŸåå€æ¬éæ äœ
äžã«10ã500ÎŒïœã®èå±€ã圢æããåèšè局圢æ
éšæã¯äžç«¯ãåºå®ããã匟æ§æ¿ã§ãããåœè©²åŒŸæ§
æ¿ã®å 端ãçŸåå€æ¬éæ äœã®å転æ¹åã®äžæµåŽã
åããåœè©²åŒŸæ§æ¿ã®å 端ãšçŸåå€æ¬éæ äœãšã®é
ãã0.1mm以äžãïŒmmæªæºãšããããã«çŸåå€æ¬
éæ äœã«å¯ŸãæŒå§ããŠåœè©²åŒŸæ§æ¿ã®ç«¯éšã«è¿ãé¢
ã®éšåã§å§æ¥ããŠãçŸåå€æ¬éæ äœãšåŒŸæ§æ¿ã®æ¥
觊äœçœ®ã«ãããŠãã€ãªã¢ãïŒåãã€ééãããã
ãã«æ¬ééãèŠå¶ããåèšãããŒããšãŒãã«åã
ã¹ããšããŒã«åéäœããžã«ã«ãã³é žåéäœãé žæ
åå šäœã«å¯ŸããŠïŒã30ã¢ã«ïŒ ã®ïŒäŸ¡ä»¥äžã®å€äŸ¡ã«
ã«ãã³é žåéäœãåã³åéäœæåå šäœã«å¯ŸããŠ10
ã30ã¢ã«ïŒ ã®åŽéã«ççŽ æ°ïŒã12ã®èèªæçåæ°Ž
çŽ åäœãæããã³ãã¯é žãšãå«ãåéäœæåã®é
åã«ãã€ãŠåŸãããç«ç·ç¶ããªãšã¹ãã«æš¹èãã
ãªããã€ã³ããŒæš¹èãšåèšãã€ã³ããŒæš¹è100é
ééšã«å¯ŸããŠïŒã10éééšã®ããªãªã¬ãã€ã³ãå«
æãããããŒã§ãããåèšãã€ãªã¢ç²åãã¹ãã¬
ã³ç³»åéäœãšã¢ã¯ãªã«é žãšã¹ãã«åéäœåã³ïŒå
ã¯ã¡ã¿ã¯ãªã«é žãšã¹ãã«åéäœãå«ãåéäœæå
ãéåããŠåŸãããå ±éåäœïŒStïŒAEåã³ïŒå
ã¯MAEïŒïŒïŒïŒãïŒïŒïŒã®ééçµææ¯ïŒãããª
ãæš¹èãå¹³åèåã0.3ã4ÎŒïœãšãªãããã«ããš
ã©ã€ãã«è¢«èŠããçç¶ã®æš¹è被èŠãã€ãªã¢ã§ãã
ã®å¹³åç²åŸãïŒã50ÎŒïœãç£åã20ã50emuïŒïœã
åºææµæã1013Ωã»cm以äžã§ããããšãç¹åŸŽãšã
ãéé»æœåã®çŸåæ¹æ³ã«ä¿ããã®ã§ããã æ¬çºæã«ããã°ãçšããããçŸåå€äžã®ãããŒ
ã¯ãåŽéã«ïŒ£æ°ïŒã22ã®èèªæçåæ°ŽçŽ åäœãæ
ããããªãšã¹ãã«æš¹èããã€ã³ããŒãšããŠå«æã
ããããŒã§ããããã硬質ã§çµ¶çžæ§ãé«ããæ©æŠ
垯é»æ§ãè¯å¥œã§ããããã®ããã«ãç¹ã«æš¹è被èŠ
ãã€ãªã¢ãšæå¹ã«æ©æŠåž¯é»ããªããããã€ãªã¢ã¯
ãããŒåã³çŸåå€æ¬éæ äœãšã®éé»æ°åã匷ããª
ãããã®çµæãšããŠããã€ãªã¢é£æ£åã³ãããŒé£
æ£ãé²æ¢ã§ãããã¶ãããã€ãªã¢ä»çã®ãªãé®®æ
ãªç»åãåŸããããšèããããããŸããåèšãã
ç¹å®ã®ããªãšã¹ãã«æš¹èããã€ã³ããŒãšããŠå«æ
ãããããŒã¯æµåæ§ãé«ãããã€ãªã¢ãšæ··åãã
çŸåå€ã®æµåæ§ããåäžãããå¹æãæããŠã
ãããã®ããã«ãçŸåå€æ¬éæ äœäžã«åäžãªçŸå
å€å±€ã圢æã§ããç»åã ã©ãç»åã¬ããé²æ¢ã§ã
ããšèãããããæŽã«ãŸããå€æ°æè€åããããª
ã€ãŠããåèšããªãšã¹ãã«æš¹èããã€ã³ããŒãšã
ãŠå«æãããããŒã¯ãæš¹è被èŠãã€ãªã¢ã®æš¹èãš
èçæ§ã瀺ãããé¢åæ§ãè¯å¥œã§ãããããèå±€
圢æã«ãã€ãŠåŒ·ãå§åãåããŠããããŒãšãã€ãª
ã¢ã¯ç©ççã«ä»çããããããŒã®ãã€ãªã¢ãžã®ã
ã€ã«ãã³ã°ãçºçããçµæãšããŠãã¶ãããããŒ
é£æ£ããã€ãªã¢ä»ççã®ãªããèä¹ æ§ãè¯å¥œã§é®®
æãªç»åãåŸããããšèããããã æŽã«ãŸããæ¬çºæã«åºããåŽéã«é·éèèªæç
åæ°ŽçŽ åäœãæããããªãšã¹ãã«æš¹èããã€ã³ã
ãŒãšãããããŒã¯ãé·éèèªæçåæ°ŽçŽ ã®çæ°Žæ§
ã®å¹æã«ãããé«æž©é«æ¹¿äžã«ãããŠæ¯åé»çãå°
å ãããŠãé»è·ã®ãªãŒã¯ãçºçãããç»åæãã®
ãªãé®®æãªç»åãåŸããããã®ãšèããããã ãã®ããªãšã¹ãã«æš¹èãšããŠãåŽéã«ççŽ æ°ïŒ
以äžã®èèªæçåæ°ŽçŽ åäœãæããããªãšã¹ãã«
æš¹èãçšãããšãåŸããããããŒã¯åžæ°Žæ§ãæã
ãŠãããç¹ã«é«æž©é«æ¹¿ã®ç°å¢æ¡ä»¶äžã«ãããŠãæ¯
åé»çãå°å ããããšé»è·ããªãŒã¯ãããããã
ã¶ããç»åãã±ã®å€ãç»åãšãªã€ãŠããŸããäž
æ¹ãççŽ æ°13以äžã®èèªæçåæ°ŽçŽ åäœãæãã
ããªãšã¹ãã«æš¹èãçšãããšãçæ°Žæ§ã¯ååã§ã
ããããããŒãè»è³ªåããããã«ããã€ãªã¢ãžã
ã€ã«ãã³ã°ããããšãšãªããçŸåå€ãšããŠã®çšã
ãªããªããªã€ãŠããŸãã ããã«ãŸãæµåæ§ã®è¯å¥œãªãããŒã«ããçŸåå€
æ¬éæ äœäžã«çŸåå€ã®èå±€ã圢æã§ããããã«ã
çŸåå€ã®ãã€ãªã¢ãšãããŒã®çµååããã€ãªã¢ãš
çŸåå€æ¬éæ äœã®çµååã匱ãå Žåã§ãã€ãŠãçŸ
åå€å±€ã極ãèãã§ãããããçŸåå€æ¬éæ äœ
ïŒä»¥éã¹ãªãŒããšç§°ããïŒã«åååºçãããããš
ãšãªãã ãªãããããŒã®ãã€ã³ããŒæš¹èã¯ãããªãšã¹ã
ã«æš¹èã®ä»ã«ãäŸãã°åæ£åºŠåäžã®ããã«ä»ã®é
åäœãæ··åããŠãããã ãŸããäžèšã®æš¹èã§è¢«èŠãããæš¹è被èŠãã€ãª
ã¢ã¯æš¹è被èŠãã»ã©ããããŠããããã«ãçç¶ã§
æ»ãããªè¡šé¢ç¶æ ãæããããšãšãªãããã®ãã
ã«ããããŒãšæå¹ã«æ©æŠåž¯é»ããªããããããŒå
ã³çŸåå€æ¬éæ äœãšã®éé»æ°ççµååã匷ããª
ãããã®çµæãšããŠããã€ãªã¢é£æ£åã³ãããŒé£
æ£ãé²æ¢ã§ãããã¶ãããã€ãªã¢ä»çãé²æ¢ã
ããé®®æãªç»åãåŸããããšèããããããŸãã
æš¹è被èŠãã€ãªã¢ãšããããšã§ãå°ç²åŸãã€ãªã¢
ã§ãã€ãŠãçŸåå€ã®æµåæ§ãè¯å¥œã§ãããçŸåå€
æ¬éæ äœäžã«åäžãªçŸåå€ã®èå±€ã圢æã§ããç»
åã ã©ãç»åã¬ããé²æ¢ã§ãããšèãããããã
ãã«ãŸããå€æ°æè€åããããªã€ãŠããäžèšãã
ç¹å®ã®æš¹è被èŠãã»ã©ããããšã«ãããé¢åæ§ã
è¯å¥œã§ãã€ãŠã匷ãå§åãåããŠããããŒãšç©ç
çã«åŒ·ãä»çããããããŒã®ãã€ãªã¢ãžã®ãã€ã«
ãã³ã°ãçºçãããçµæãšããŠããã¶ãããããŒ
é£æ£ããã€ãªã¢ä»ççã®ãªããèä¹ æ§ãè¯å¥œã§é®®
æãªç»åãåŸããããã®ãšèããããã ç¹ã«ããã€ãªã¢ã®æš¹è被èŠã«çšããæš¹èãšã
ãŠã硬質æåãšããŠã®ã¹ãã¬ã³ç³»åéäœãšã匷é
ã§æè»ãªæ©èœãåããã¢ã¯ãªã«é žïŒåã¯ã¡ã¿ã¯ãª
ã«é žïŒåã¯ãã®ãšã¹ãã«ãšã®éåã«ãã€ãŠåŸãã
ãå ±éåäœã䜿çšãããšããããäž¡åéäœæåã®
ãã€ç¹é·ãçºæ®ããªãããåæã«ãã®æ¬ ç¹ã解æ¶
ã§ãããã€ãŸããã¹ãã¬ã³ç³»ã«ããèãã¯ã¢ã¯ãª
ã«ïŒåã¯ã¡ã¿ã¯ãªã«ïŒé žåã¯ãã®ãšã¹ãã«ã«ãã€
ãŠè§£æ¶ããããã€åŸè ã«ããæè»ããä¿æããªã
ãã¹ãã¬ã³ç³»æåã§é©åºŠãªç¡¬ããä»äžããããšã
ã§ãããããããç©æ§ããäžèšããããã«é¢åæ§
ã®åäžããããŒãšã®ä»çé²æ¢çããããããã®ã§
ããã ããã«ãŸããæ¬çºæã«ããã°ãæš¹è被èŠãã€ãª
ã¢ã«ãããçŸåå€æ¬éæ äœäžã«çŸåå€ã®èå±€ã圢
æã§ããããã«ãçŸåå€ã®ãã€ãªã¢ãšãããŒã®çµ
ååããã€ãªã¢ãšçŸåå€æ¬éæ äœã®çµååã匱ã
å Žåã§ãã€ãŠããçŸåå€å±€ã極ãèãã§ããã
ããçŸåå€æ¬éæ äœïŒä»¥éãã¹ãªãŒããšç§°ããïŒ
ã«åååºçãããããšãšãªãã æ¬çºæã«ãããŠãäžèšã®ãèå±€ããšã¯ãçŸåé
åã«ãããŠåã¿ã10ã500ÎŒïœãšãããåŸæ¥ã«ãª
ãèãçŸåå€å±€ã§ããã®ãæãŸããããã®èå±€ã«
ãããæ¯åé»çäžã§ãçŸåå€æ¬éæ äœäžã®çŸåå€
ãåæ æäœãšéæ¥è§Šã§ãã€ãŠãåæ æäœïŒä»¥äžã
å圢æäœãšèšãããšããããïŒãšçŸåå€æ¬éæ äœ
ã®ééãå°ããããŠçŸåããã®ãããã ããã§çŸåé åãšã¯ãçŸåå€æ¬éæ äœã«ããæ¬
éããããããŒãå圢æäœã«éé»çãªåãåããŠ
移è¡ãããé åãããããã®é åå ã«ãããå圢
æäœãšçŸåå€æ¬éæ äœãšã®æè¿æ¥è·é¢ãçŸåéé
ãšããã æ¬çºæã«ãããŠãã¹ãªãŒãäžã®èå±€äžã®ãããŒ
ãçŸåã«ãã倱ãªãããŠããçŽã¡ã«ååãªãããŒ
ãèå±€ã«äŸçµŠãããã°çŸåæ§ã«åœ±é¿ã¯ãªãããã®
ããã«ã¯ãã¹ãªãŒãäžã®ç£ç³ãé«éã§å転ããã
ããšã奜ãŸããã 次ã«ãçŸååã«æ¬éãããå°ãªãçŸåå€ãæ倧
éã®å¹çã§çŸåããããã«ã¯ã (1) ç£æ°ããŒã«ã®é«éå転 (2) ã¹ãªãŒããžã®äº€æµãã€ã¢ã¹ã®å°å (3) åæ æäœãšã¹ãªãŒããšã®ééãå°ããããã
ãš ãªã©ã®æ段ããšãããšã奜ãŸããã æ¬çºæã§æ¡çšãããéæ¥è§ŠçŸåæ³ã«ãããŠãçŸ
åå€å±€ãèãããã°åæ æäœãšã¹ãªãŒããšã®éé
ãå°ããããããšãã§ãããããŒãé£ç¿ãããã«
èŠããæ¯åé»çã圢æããã«èŠããçŸåãã€ã¢ã¹
ã®é»å§ãäœãããããšãã§ãããåŸã€ãŠãåèšã
ããŒé£æ£ã¯ãã®ç¹ããã軜æžãããå€ãã¹ãªãŒã
é¢ããã®çŸåãã€ã¢ã¹ã«åºã¥ããªãŒã¯æŸé»çãå¶
埡ãããå©ç¹ããããããã«åãåæ æäœãšã¹ãª
ãŒããšã®ééãå°ããããå Žåãããã«ãæœåã«
ããçŸååã«åœ¢æãããé»ç匷床ã倧ãããªãã
ãã®çµæãé調ã®åŸ®åŠãªå€åã现ããªãã¿ãŒã³ã
ããçŸåã§ããããã«ãªãã èå±€ãèãããã°ãäžè¬ã«ãçŸååã«æ¬éãã
ããããŒã®éã¯å°ãªããªããçŸåéã¯å°ãããª
ããæ¬ééã倧ããããã«ã¯ãã¹ãªãŒããé«éã§
å転ãããããšãå¹æçã§ããããã ããå圢æ
äœãšã¹ãªãŒããšã®ç·é床æ¯ãïŒïŒ10ã«ãªããšãçŸ
åããããããŒãæœåé¢ã«å¯ŸããŠæã€å¹³è¡ãªé床
æåã倧ãããªããçŸåã«æ¹åæ§ãçŸãããç»è³ª
ãå£åããã ãã®ããšãããèå±€ã®äžéãšããŠãã¹ãªãŒãé¢
äžã«åœ¢æãããçŸåå€å±€äžã«ãå°ãªããšã0.04
mgïŒcm2çšåºŠã®å¯åºŠã§ãããŒãå«ãŸããŠããç¶æ ã§
ããããšãå¿ èŠã§ãããäžè¬ã«ã¯ãã¹ãªãŒãã®ç·
é床ãVslãå圢æäœã®ç·é床ãVdãã¹ãªãŒãäž
ã®èå±€äžã®ãããŒéãmtãšãããšãã ïœVslïŒVdïœã»mtâ§0.4ãmgïŒcm2ã ïœVslïŒVdïœâŠ10 ãšããæ¡ä»¶ãæºããå¿ èŠãããã çŸåå¹çãèæ ®ããã° ïœVslïŒVdïœã»mtâ§0.5ãmgïŒcm2ã ïœVslïŒVdïœâŠïŒ ãšããã®ã奜ãŸãããããã«å®éšäºå®ããã¯ã ïœVslïŒVdïœã»mtâ§0.5ãmgïŒcm2ã ïœVslïŒVdïœâŠïŒ ã§ããããšããã奜ãŸããããšãããã€ãã ãã®æã®çŸåå€äžã®ãããŒãšãã€ãªã¢ã®æ¯ã¯ã
åäœäœç©äžã®ãããŒãšãã€ãªã¢ã®ç·è¡šé¢ç©ãšã®æ¯
ã0.5ãïŒãšãªãã®ã奜ãŸããã 以äžã®ãããªæ¡ä»¶ã«èšå®ããã°ãèå±€äžã®ãã
ãŒãå¹çããçŸåããããšãã§ããçŸåæ§ã¯å®å®
ããŠãããè¯å¥œãªç»è³ªãåŸãããšãã§ããã åèšèå±€ã®çŸåå€å±€ã圢æããæ段ãšããŠã¯ã
çŸåå€äžã«å«ãŸãã塵åãç¹ç¶ãçŽç²åã¯ãããŒ
åã¯ãã€ãªã¢ã®åéäœçã®äžçŽç©ãæé€ããäž
ã§ãã¹ãªãŒãã«å¯ŸããŠåŒŸæ§çã«è»œåºŠã«å§æ¥ããã
å§æ¥æ¿ããæãè局圢æéšæã奜ãŸããçšããã
ãã ãã®è局圢æéšæã¯ãã¹ãªãŒãã«å¯Ÿããå 端ã
ã¹ãªãŒãå転ã®äžæµãåãããã«æŒå§ããã匟æ§
æ¿ã§ãçŸåå€ãã¹ãªãŒããšåŒŸæ§æ¿ã®éãããæã
ãããããšã«ããèå±€ã圢æããã ããã§ãè局圢æéšæïŒåŒŸæ§æ¿ïŒã®å 端ãçŸå
å€æ¬éæ äœã®å転æ¹åã®äžæµåŽãåãããã«æ§æ
ãããŠãããšã匟æ§æ¿ã®å 端ãšçŸåå€æ¬éæ äœãš
ã®éããè¶ããé«ãã®çŸåå€ã¯éãå Žããªãã匟
æ§æ¿äžã«çŸåå€ãã©ãã©ãéã蟌ãŸããé床ã«å§
çž®ãããªããèŠå¶ãããå¯åºŠã®é«ãçŸåå€å±€ãšãª
ã€ãŠããŸãããããŠããã®ããšããããããŒãã
ã€ãªã¢è¡šé¢ã«ãã€ã«ãã³ã°ããã°ããããå€æ°æ
è€åãç¹°ãè¿ãããŠãããšããã€ãªã¢ç²åå士ã
ãã€ã«ãã³ã°ãããããŒãä»ããŠçŸåå€èªäœãå
éããç»åã ã©ãç»åæããšãã€ãç»åäžè¯ãèµ·
ããŠããŸãã ããã«å¯ŸããŠãæ¬çºæã«ãã€ãŠã¯ãè局圢æéš
æïŒåŒŸæ§æ¿ïŒã¯ã匟æ§æ¿ã®å 端ãçŸåå€æ¬éæ äœ
ã®å転æ¹åã®äžæµåŽãåãããã«æ§æãããŠãã
ããã匟æ§æ¿ã®å 端ãšçŸåå€æ¬éæ äœãšã®éãã«
çžåœããçŸåå€ã ããééã§ããåèšéããè¶ã
ãé«ãã®çŸåå€ã¯åŒŸæ§æ¿ã®äžåŽã«éãããçŸåå€
ã¯å§çž®ãããã®ã軜æžããããåŸã€ãŠã匟æ§æ¿ã®
å 端ãçŸåå€æ¬éæ äœã®å転æ¹åã®äžæµåŽãåã
ããã«æ§æãããå Žåã«èµ·ããäžèšã®æ¬ é¥ãé²æ¢
ããããã®ãšãªãã ãããããã®æ¹å床ã¯ã 匟æ§æ¿ã®å 端ãçŸåå€æ¬éæ äœã®å転æ¹åã®
äžæµåŽãåãããã«æ§æãããããšã ãããŒããšãŒãã«åãã¹ããšããŒã«åéäœã
ãžã«ã«ãã³é žåéäœãé žæåå šäœã«å¯ŸããŠïŒã
30ã¢ã«ïŒ ã®ïŒäŸ¡ä»¥äžã®å€äŸ¡ã«ã«ãã³é žåéäœã
åã³åéäœæåå šäœã«å¯ŸããŠ10ã30ã¢ã«ïŒ ã®åŽ
éã«ççŽ æ°ïŒã12ã®èèªæçåæ°ŽçŽ åäœãæã
ãã³ãã¯é žãšãå«ãåéäœæåã®éåã«ãã€ãŠ
åŸãããéç·ç¶ããªãšã¹ãã«æš¹èãããªããã€
ã³ããŒæš¹èãšåèšãã€ã³ããŒæš¹è100éééšã«
察ããŠïŒã10éééšã®ããªãªã¬ãã€ã³ãå«æã
ããããŒã§ããããšã ãã€ãªã¢ç²åãã¹ãã¬ã³ç³»åéäœãšã¢ã¯ãªã«
é žãšã¹ãã«åéäœåã³ïŒåã¯ã¡ã¿ã¯ãªã«é žãšã¹
ãã«åéäœãå«ãåéäœæåãéåããŠåŸãã
ãå ±éåäœïŒStïŒAEåã³ïŒåã¯MAEïŒïŒïŒïŒ
ãïŒïŒïŒã®ééçµææ¯ïŒãããªãæš¹èãå¹³åè
åã0.3ã4ÎŒïœãšãªãããã«ããšã©ã€ãã«è¢«èŠ
ããçç¶ã®æš¹è被èŠãã€ãªã¢ã§ããã®å¹³åç²åŸ
ãïŒã50ÎŒïœãç£åã20ã50emuïŒïœãåºææµ
æã1013Ωã»cm以äžã§ããããš ãšãã€ãæ§æèŠä»¶ãææ©çã«çµåããŠããããšã«
ãã€ãŠäžå±€å¹æçã«éæããããã®ãšãªãã å³ã¡ãé«æž©å€æ¹¿ãšãã€ããããªç°å¢äžã«ãã€ãŠ
ã¯ãåèšç»åã ã©ãç»åæããšãã€ãç»åäžè¯ã
ããäžå±€èµ·ãæãã®ã§ããããäžèšã®ãããªæ§æ
èŠä»¶ãææ©çã«çµåãããããšã«ãã€ãŠãç»åã
ã©ãç»åæããšãã€ãç»åäžè¯ãããäžå±€èµ·ãé£
ããªã€ãã®ã§ããã 第ïŒå³ã¯åŒŸæ§æ¿ã®å 端ãšã¹ãªãŒããšã®ééïŒïŒ
éå£é¢ç©ïŒãšã¹ãªãŒãäžã«ä»çããŠããçŸåå€é
ãšã®é¢ä¿ã§ããããã®å³ãããééãäžå®å€ä»¥äž
ã«ãªã€ããšããã¹ãªãŒãäžã®çŸåå€éã¯ãããã®
å€åã«å¯Ÿãå®å®ããããšããããããã®å®å®ç¶æ
ã«ãããŠã¯ãå ã«è¿°ã¹ãçŸåã«å¿ èŠãªãããŒã¯å
åã«æ¬éã§ãããä»ã®å®éšãããå±€ã®åããã»ãš
ãã©å€åããªãããšãä»ã®ãã©ã¡ãŒã¿ããã®å®å®
ç¶æ ã®åºçŸã«ã»ãšãã©åœ±é¿ããªãããšãæããã«
ãªã€ãã ãããã€ãŠãå 端ã®ééã0.08mm以äžãšãã
ãšãåä»ã粟床ãæ©æ¢°ç粟床ã®ãã©ã€ãã«å¯Ÿãå®
å®ã«äžå®éã®ãããŒãæ¬éããããšãã§ãããã
ãã«ãå 端ã®ééã0.1mm以äžãšããã°ãå®å®åºŠ
ãå¢ã ãã¡ãããåèšå 端ã®ééãåŸãã«å€§ãããšã
ããšã¯æãŸããããšã§ã¯ãªããééãïŒmm以äžã«
ãããšãå±€ã®åäžæ§ã厩ããã®ã芳å¯ãããã 第ïŒå³ã«ã¯ãæ¬çºæã®çŸåæ¹æ³ãè¡ãäžã§å¥œé©
ãªçŸåè£ çœ®ã®æé¢å³ã瀺ããããå³äžïŒïŒã¯å圢
æäœãïŒã¯ããŠãžã³ã°ãïŒã¯ã¹ãªãŒããïŒã¯ïŒ®ã
S8極ãæããç£æ°ããŒã«ãïŒã¯è局圢æéšæã
ïŒã¯è©²éšæã®åºå®éšæãïŒã¯ç¬¬ïŒæ¹æéšæãïŒã¯
第ïŒæ¹æéšæã§ãããïŒåã³ïŒïŒã¯åèšæ¹æéšæ
ïŒåã³ïŒã®å転軞ãïŒïŒã¯è£çµŠãããŒå®¹åšãïŒïŒ
ã¯ãããŒè£çµŠããŒã©ãïŒïŒã¯çŸåå€æºããïŒïŒã¯
çŸåãã€ã¢ã¹é»æºãïŒïŒã¯çŸåé åãã¯ãã
ãŒãã¯çŸåå€ãè¡šãããããçŸåè£ çœ®ã«ãã
ãŠãçŸåå€æºãïŒïŒå ã®çŸåå€ïŒ€ã¯ç¢å°æ¹åã«å
転ãã第ïŒæ¹æéšæïŒãšããããšå察æ¹åã§äºã
ã«éè€ããããã«å転ãã第ïŒæ¹æéšæïŒãšã«ã
ãå åæ¹ææ··åãããç¢å°æ¹åã«å転ããã¹ãªãŒ
ãïŒãšãããšå察æ¹åã«å転ããç£æ°ããŒã«ïŒã®
æ¬éåã«ãããåèšã¹ãªãŒãïŒã®è¡šé¢ã«ä»çæ¬é
ããããåèšã¹ãªãŒãïŒè¡šé¢ã«ã¯ããŠãžã³ã°ïŒã
ã延ã³ãåºå®éšæïŒã«ããä¿æãããè局圢æéš
æïŒã端éšã«è¿ãé¢ã®éšåã§å§æ¥ãããŠããŠãå
è¿°ã®ããã«ããŠæ¬éãããçŸåå€ïŒ€ã®å±€åãèŠå¶
ããããã®çŸåå€å±€ã¯çŸåé åïŒïŒã«ãããŠç¢å°
æ¹åã«å転ããå圢æäœïŒïŒäžã®æœåãééããž
ã ãŠãŠéæ¥è§Šã§çŸåãããããŒåã圢æãããçŸ
åæã«ã¯é»æºïŒïŒãã亀æµæåãå«ãçŸåãã€ã¢
ã¹ãåèšã¹ãªãŒãïŒã«å°å ããããã®çµæã¹ãŒã
ïŒäžã®çŸåå€äžã®ãããŒã®ã¿ãéžæçã«åèšæœå
ã®é¢ã«ç§»è¡ããŠä»çãããããªããçŸåå€ã®å±€å
ã¯äŸãã°ä»¥äžã®ããã«ããã°æž¬å®ã§ãããããã
ã¡ãæ¥æ¬å åŠ(æ ª)補ãã³ã³ãããã€ãŒã«ãããžãšã¯
ã¿ãŒãçšããã¹ãªãŒãã®ã¹ã¯ãªãŒã³ã®æ圱åãšã
ã¹ãªãŒãã«èå±€ã圢æããç¶æ ã®æ圱åãšã®äœçœ®
ãšã®æ¯èŒã«ããå±€åãæ±ããããã åèšè局圢æéšæïŒã¯ãåºå®éšæïŒã«ããäžç«¯
ãåºå®ãããŠåŒŸæ§ãä»äžããããäŸãã°ç£æ§åã¯
éç£æ§ã®éå±ãéå±ååç©ããã©ã¹ããã¯ããŽã
çããæã極ããŠåäžã«æ圢ãããèæ¿ã§ããã
ãã®åãã¯50ã500ÎŒïœãšãããã åèšã®ããã«äžç«¯ãåºå®ãããè局圢æéšæã®
ä»ç«¯ã«è¿ãé¢ã®éšåã§ã¹ãªãŒãïŒã«åŒŸæ§çã«æŒå§
ããã¹ãªãŒãïŒãšèæ¿ã®æ¥è§Šäœçœ®ã«ãããŠãã€ãª
ã¢ãïŒåãã€ééãããããã«ããŠæ¬ééãèŠå¶
ãããçŸåå€ïŒ€äžã®äžçŽç©ããã€ãªã¢åã¯ãããŒ
ã®åéç©ãªã©ã¯èŠå¶äœçœ®ãééã§ããªããåŸã€
ãŠãçŸåé åïŒïŒã«å°ãçŸåå€å±€ãåžžã«èå±€ã«ã
ãŠåäžãã€å®å®ãããã®ãåŸãããã æ¬çºæã®çŸåæ¹æ³ã®åŠããç¹å®ã®æš¹è被èŠãã€
ãªã¢ãçšããå Žåãå°ç²åŸãã€ãªã¢ã§ãã€ãŠãæµ
åæ§ãè¯å¥œã§ãããããè局圢æéšæã«ããå±€å
ãèŠå¶ãããŠãçŸåå€æ¬éæ äœäžã«åäžãªçŸåå€
å±€ã圢æã§ãããŸããé¢åæ§ãè¯å¥œã§ãã€ãŠåŒ·ã
å§åãåããŠããããŒã®ãã€ãªã¢ãžã®ãã€ã«ãã³
ã°ãçºçããªãã ãªããçŸåé åïŒïŒã«å°ãçŸåå€ã®æ¬ééã¯ã
åèšè局圢æéšæïŒã®ã¹ãªãŒãïŒã«å¯ŸããæŒæ¥å
ãæ¥è§Šè§ãå€ããããšã«ããå¶åŸ¡ãããã çŸåå€ãæ§æãããã€ãªã¢åã³ãããŒãå°ç²åŸ
ã®æ¹ãç»è³ªã®è§£åååã³é調åçŸæ§ã®ç¹ããæå©
ãšããããäŸãã°ãçŸåå€å±€ã®ãããŒç²åŸã5ÎŒ
ïœä»¥äžããã€ãªã¢ã®ç²åŸã50ÎŒïœä»¥äžãããã«ã¯
30ÎŒïœä»¥äžã®å°ç²åŸãšããå Žåã§ãåèšããèå±€
圢æéšæïŒã®ãããªæ段ãçšããããšã«ããçŸå
å€äžã®äžçŽç©ãç²å¡çãèªåçã«æé€ããŠåäžãª
èå±€ã圢æããããšãã§ãããããã«ãåèšãã€
ãªã¢ããããŒãšåçšåºŠã®å°ç²åŸãšãããå Žåã§ã
åæ§äžçŽç©ã®æ··å ¥ãæé€ãããŠåäžãªè局圢æã
å¯èœãšãããã éã«ãå圢æäœã®ãã€ãªã¢ä»çãé²æ¢ãããã
ã«ã¯ããã€ãªã¢ç²åŸã倧ããæ¹ã匷ãç£åãåã
ãããšãã奜ãŸãããäŸãã°ããã€ãªã¢ç²åŸã50
ã100ÎŒïœçšåºŠã«ãªã€ãŠãåèšã®æ¹æ³ã«ããã°å
äžãªèå±€ã圢æã§ããããªãããã€ãªã¢ç²åŸã倧
ãããªããšãèå±€äžã®ãã€ãªã¢ã®ç©é«ã倧ãããª
ããšãšãã«å±€ãç²ããªããçŸåæ§ã¯æªããªããã
ã®ç¹ãããã€ãªã¢ã¯å°ç²åŸã§ç£åãäŸãã°10ã
200ã奜ãŸããã¯20ã100ãæŽã«å¥œãŸããã¯20ã
50emuïŒïœãæãŸãããç£åã10emuïŒïœæªæºã§
ãããšæå®ã®ç£æ°ãã©ã·ã圢æã§ããããŸã
200emuïŒïœãè¶ ãããšç£åã倧ããããŠæ¯åé»
çäžã§çŸåãè¯å¥œã«è¡ãªããããè¯å¥œãªç»åãåŸ
ãããªããªãã åèšçŸåè£ çœ®ã«çµã¿èŸŒãŸããæ¹æéšæïŒåã³ïŒ
ã®å ·äœçæ§é ã瀺ãæèŠå³åã³æ£é¢å³ãã第ïŒå³
ã€åã³ãã«ç€ºããããå³äžïŒïœïŒïŒïœïŒïŒïœã¯ç¬¬
ïŒæ¹æéšæã®æ¹æçŸœæ ¹ãïŒïœïŒïŒïœïŒïŒïœãã¯ç¬¬
ïŒæ¹æéšæã®æ¹æçŸœæ ¹ã§ãè§æ¿çŸœæ ¹ãåæ¿çŸœæ ¹ã
æ¥åæ¿çŸœæ ¹çåçš®ã®æ æ§ããããããããå転軞
ïŒåã³ïŒïŒã«äºãã«ç°ãªãè§åºŠåã³ïŒåã¯äœçœ®ã§
åºå®ãããŠãããåèšïŒã€ã®æ¹æéšæïŒåã³ïŒ
ã¯ãæ¹æçŸœæ ¹ãäºãè¡çªããããšãªãæ¹æé åã
ãªãŒãã©ããããããã«æ§æãããŠãããããå·Š
å³æ¹åïŒç¬¬ïŒå³ïŒã®æ¹æãååã«è¡ãªããããšå ±
ã«ãæ¹ææ¿ã®åŸæïŒç¬¬ïŒå³ïŒã®ããååŸæ¹åïŒç¬¬
ïŒå³ïŒã®æ¹æãååã«è¡ãªãããã åãè£çµŠããŒã©ïŒïŒãä»ããŠãããïŒïŒããè£
絊ããããããŒïŒŽãçæéã§çŸåå€ïŒ€äžã«åäžæ··
åãããã 以äžã®ããã«ååã«æ¹æããæãŸããæ©æŠåž¯é»
ãä»äžãããçŸåå€ïŒ€ã¯ãã¹ãªãŒãïŒäžã«ä»çæ¬
éãããéçšã§åèšè局圢æéšæïŒã«ãããèŠå¶
ãã極ããŠèããã€åäžãªçŸåå€å±€ã圢æãã
ãããã®çŸåå€å±€ã¯ã¹ãªãŒãïŒã®å転ã«ããäžæ¹
åã«æ¬éããããšå ±ã«ãç£æ°ããŒã«ïŒã®å察æ¹å
ãžã®å転ã«ããæ¯åæåããã€ç£æ°çãã€ã¢ã¹ã
åããåèšã¹ãªãŒãïŒäžã§äŸãã°ããŒãªã³ã°çã®
è€éãªéåãããã®ã§ãçŸåé åïŒïŒã«éããŠå
圢æäœïŒã®æœåãéæ¥è§Šã§çŸåãããšã該æœåé¢
ã«åããŠãããŒãå¹æçã«äŸçµŠããããã«ãªãã
åèšçŸåå€å±€ã¯åèšããããã«500ÎŒïœã10ÎŒïœãš
極ããŠèå±€ãªããšããããšãã§ããã®ã§ãå圢æ
äœïŒãšã¹ãªãŒãïŒãšã®ã®ã€ãããå³ã¡çŸåã®ã€ã
ããäŸãã°500ÎŒïœãŸã§çãããŠãéæ¥è§ŠçŸåã
ååã«å¯èœãšãªãããã®ããã«çŸåã®ã€ãããç
ããããšçŸåé åïŒïŒã®é»çã倧ãããªãã®ã§ã
ã¹ãªãŒãïŒã«å°å ããçŸåãã€ã¢ã¹ãå°ãããŠã
ååãªçŸåãéæãããçŸåãã€ã¢ã¹ã®ãªãŒã¯æŸ
é»çã軜æžãããå©ç¹ããããããã«ã¯æœåã®ã³
ã³ãã©ã¹ãã倧ãããªããããçŸåããŠåŸããã
ç»åã®è§£ååãã®ä»ç»è³ªãå šè¬çã«åäžããã åãæ¬çºæã®æ æ§ã®å¹æãšããŠã¯ãçŸåæ¹æ³ã
éæ¥è§ŠçŸåãšããããããŒã®ã¿ãæœåé¢ã«åãã€
ãŠéžæçã«é£ç¿ããŠçŸåãããã®ã§ãæœåé¢ãžã®
ãã€ãªã¢ä»çãé²æ¢ããããåãæœåé¢ãæºæŠã
ãªãã®ã§å圢æäœè¡šé¢ãæå·ããããå·ãç®ã圢
æãããããããšããªãã解åååã³é調åçŸæ§
ãè¯å¥œã§ãããååãªéã®ãããŒãæœåé¢ã«ä»ç
ãããããšãã§ãããããã«åããããŒåã圢æ
ãããå圢æäœäžã«éããŠçŸåããããšãã§ãã
ã®ã§å€è²çŸåã«å¥œé©ã§ããã ãªããæ¬çºæã®çŸåæ¹æ³ã«ãããå®å®ããçŸå
æ¡ä»¶ãšããŠã¯ãçŸåå€å±€ã10ã500ÎŒïœçŸåã®ã€
ããã200ÎŒïœã2000ÎŒïœãšãããã¹ãªãŒãïŒã®å
転é床ãå圢æïŒã®å転é床ãã¹ãªãŒãäžã®ãã
ãŒä»çéã®é¢ä¿ã¯åè¿°ã®ãããªåŒãæºãããã®ã§
ããããšã奜ãŸããã 次ã«ãæ¬çºæã®çŸåæ¹æ³ã«é©çšãããçŸåå€ã®
æ§æã¯ä»¥äžã®ããã§ããã æ¬çºæã®ãããŒã¯ããšãŒãã«åãã¹ããšããŒã«
ãšãžã«ã«ãã³é žãšã®ãšã¹ãã«æ§é ãåºæ¬éªšæ Œã«æ
ããéç·ç¶ããªãšã¹ãã«ã§ãã€ãŠãåŽéã«ççŽ æ°
ïŒã12ã®é£œåãããã¯äžé£œåã®é·éèèªæçåæ°Ž
çŽ åäœãæããããªãšã¹ãã«æš¹èããã€ã³ããŒæš¹
èãšããŠå«æãããã®ãããŒäžã«çè²å€ããã®ä»
å¿ èŠã«å¿ããŠæ·»å ãããæåãããªãã æ¬çºæã«ãããŠãã€ã³ããŒãæ§æããããªãšã¹
ãã«æš¹èïŒéç·ç¶å ±éåäœïŒã®åæã«çšãããã
åéäœæåã¯ã (ã€) å ±éåäœã®åºæ¬éªšæ Œãæ§æããæåãšããŠ
ã®ããšãŒãã«åãã¹ããšããŒã«ãäž»äœãšããïŒ
䟡ã®ã¢ã«ã³ãŒã«åéäœããã³ïŒäŸ¡ã®ã«ã«ãã³é ž
åéäœã (ã) å ±éåäœã®éç·ç¶åãããªãã¡ãã©ã³ãåãª
ããã¯ç¶²ç¶åã«é¢äžããïŒäŸ¡ä»¥äžã®å€äŸ¡ã«ã«ã
ã³é žåéäœã (ã) å ±éåäœã®åŽéã«ççŽ æ°ïŒã12ã®é£œåããã
ã¯äžé£œåã®é·éèèªæçåæ°ŽçŽ åäœãå°å ¥ãã
ããã®ãåœè©²çåæ°ŽçŽ åäœãæããã³ãã¯é žã
ãæ§æãããå¿ èŠã«å¿ãä»ã®åéäœãå«ãããš
ãã§ããã äžèš(ã€)ã®ãšãŒãã«åãã¹ããšããŒã«ãšããŠã¯ã
ããªãªãã·ãããã¬ã³ïŒïŒïŒïŒïŒâïŒïŒïŒâãã¹
ïŒïŒâããããã·ããšãã«ïŒãããã³ãããªãªã
ã·ãšãã¬ã³(2)âïŒïŒïŒâãã¹ïŒïŒâããããã·ã
ãšãã«ïŒãããã³ãããªãªãã·ãããã¬ã³(6)â
ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒããã
ã³ãããªãªãã·ãããã¬ã³ïŒïŒïŒïŒïŒâïŒïŒïŒâ
ãã¹ïŒïŒâããããã·ããšãã«ïŒãããã³ãçã
äŸç€ºããããšãã§ããããã®ä»ã®ïŒäŸ¡ã®ã¢ã«ã³ãŒ
ã«åéäœãšããŠã¯ããšãã¬ã³ã°ãªã³ãŒã«ããžãšã
ã¬ã³ã°ãªã³ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ãïŒïŒ
ïŒâãããã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâãããã¬ã³
ã°ãªã³ãŒã«ãïŒïŒïŒâãã¿ã³ãžãªãŒã«ãããªãã³
ãã«ã°ãªã³ãŒã«ãïŒïŒïŒâããã³ãžãªãŒã«çã®ãž
ãªãŒã«é¡ãïŒïŒïŒâãã¹ïŒããããã·ã¡ãã«ïŒã·
ã¯ããããµã³ãåã³ãã¹ããšããŒã«ïŒ¡ãæ°ŽçŽ æ·»å
ãã¹ããšããŒã«ïŒ¡çãäŸç€ºããããšãã§ããã ãŸããïŒäŸ¡ã®ã«ã«ãã³é žåéäœãšããŠã¯ããã¬
ã€ã³é žããããŒã«é žãã¡ãµã³ã³é žãã·ãã©ã³ã³
é žãã€ã¿ã³ã³é žãã°ã«ã¿ã³ã³é žããã¿ã«é žãã€ãœ
ãã¿ã«é žããã¬ãã¿ã«é žãã·ã¯ããããµã³ãžã«ã«
ãã³é žãã³ãã¯é žãã¢ãžãã³é žãã»ããã³é žãã
ãã³é žããããã®é žã®ç¡æ°Žç©çãäŸç€ºããããšã
ã§ããããããïŒäŸ¡ã®ã«ã«ãã³é žåéäœã®äœ¿çšé
ã¯ãé žæåå šäœã«å¯Ÿã10ã90ã¢ã«ïŒ ã奜ãŸããã¯
20ã60ã¢ã«ïŒ å«æãããã åèš(ã)ã«ãããïŒäŸ¡ä»¥äžã®å€äŸ¡ã«ã«ãã³é žåé
äœãšããŠã¯ãäŸãã°ãïŒïŒïŒïŒïŒâãã³ãŒã³ããª
ã«ã«ãã³é žãïŒïŒïŒïŒïŒâãã³ãŒã³ããªã«ã«ãã³
é žãïŒïŒïŒïŒïŒâã·ã¯ããããµã³ããªã«ã«ãã³
é žãïŒïŒïŒïŒïŒâããã¿ã¬ã³ããªã«ã«ãã³é žã
ïŒïŒïŒïŒïŒâããã¿ã¬ã³ããªã«ã«ãã³é žãïŒïŒ
ïŒïŒïŒâãã¿ã³ããªã«ã«ãã³é žãïŒïŒïŒïŒïŒâã
ããµã³ããªã«ã«ãã³é žãïŒïŒïŒâãžã«ã«ããã·ã«
âïŒâã¡ãã«âïŒâã¡ãã¬ã³ã«ã«ããã·ã«ããã
ã³ãããã©ïŒã¡ãã¬ã³ã«ã«ããã·ã«ïŒã¡ã¿ã³ã
ïŒïŒïŒïŒïŒïŒïŒâãªã¯ã¿ã³ããã©ã«ã«ãã³é žããš
ã³ããŒã«äžéäœé žããããã®é žã®ç¡æ°Žç©ãªã©ãæ
ããããšãã§ãããïŒäŸ¡ä»¥äžã®å€äŸ¡ã«ã«ãã³é žå
éäœã®äœ¿çšå²åã¯ãé žæåå šäœã«å¯ŸãïŒã30ã¢ã«
ïŒ ã§ããã äžèš(ã)ã®ççŽ æ°ïŒã12ã®é£œåãããã¯äžé£œåã®
é·éèèªæçåæ°ŽçŽ åäœãåŽéã«æããã³ãã¯é ž
ãšããŠã¯ïœâããã»ãã«ãã¯ãé žãã€ãœããã»ã
ã«ãã¯ãé žãïœâããã·ã«ãã¯ãé žãã€ãœâãã
ã·ã«ãã¯ãé žãã€ãœâãªã¯ãã«ãã¯ãé žãïœâãª
ã¯ãã«ã³ãã¯é žïœâããã«ãã¯ãé žçã奜é©ãªã
ã®ãšããŠäŸç€ºããããšãã§ãã䜿çšéã¯åéäœæ
åå šäœã«å¯Ÿã10ã30ã¢ã«ïŒ ã§ããã æ¬çºæã®ãããŒã¯ã以äžã®ãããªãã€ã³ããŒäž
ã«çè²å€åã³å¿ èŠã«å¿ããŠæ·»å ãããç¹æ§æ¹è¯å€
ãå«æããŠæããã®ã§ããã çè²å€ãšããŠã¯ãã«ãŒãã³ãã©ãã¯ããã°ãã·
ã³ææïŒC.I.No.50415BïŒãã¢ããªã³ãã«ãŒïŒC.I.No.
50405ïŒãã«ã«ã³ãªã€ã«ãã«ãŒïŒC.I.No.azoec
Bleu3ïŒãã¯ãã ã€ãšããŒïŒC.I.No.14090ïŒããŠã«ã
ã©ããªã³ãã«ãŒïŒC.I.No.77103ïŒãããŠãã³ãªã€ã«
ã¬ããïŒC.I.No.26105ïŒããããªã³ã€ãšããŒïŒC.I.
No.47005ïŒãã¡ãã¬ã³ãã«ãŒã¯ãã©ã€ãïŒC.I.No.
52015ïŒããã¿ãã·ã¢ãã³ãã«ãŒïŒC.I.No.74160ïŒã
ãã©ã«ã€ãã°ãªãŒã³ãªã¯ãµã¬ãŒãïŒC.I.No.
42000ïŒãã©ã³ããã©ãã¯ïŒC.I.No.77266ïŒããŒãº
ãã³ã¬ã«ïŒC.I.No.45435ïŒããããã®æ··åç©ããã®
ä»ãæããããšãã§ããããããçè²å€ã¯ãåå
ãªæ¿åºŠã®å¯èŠåã圢æãããã«ååãªå²åã§å«æ
ãããããšãå¿ èŠã§ãããéåžžãã€ã³ããŒ100é
ééšã«å¯ŸããŠïŒã20éééšçšåºŠã§ããã ãŸãããã€ãªã¢ãžã®ä»çãæŽã«é²æ¢ããããã«
䜿çšããããšãã§ããã åèšããªãªã¬ãã€ã³ãšããŠã¯ãäŸãã°ããªãã
ãã¬ã³ãããªãšãã¬ã³ãããªããã³çã®æš¹èã§ã
ã€ãŠJIS  2531â1960ã«èŠå®ãããç°çæ³ã§æž¬
å®ãããšãã®è»åç¹ã80ã180âã奜ãŸããã¯100
ã160âã®ãã®ã§ããã ããªãªã¬ãã€ã³ã®äœ¿çšéã¯ãåèšãã€ã³ããŒæš¹
è100éééšã«å¯ŸããŠïŒã10éééšã§ããã æ¬çºæã«ãããŠäœ¿çšãããæš¹è被èŠãã€ãªã¢ã®
æš¹èãšããŠã¯ãã¹ãã¬ã³ç³»åéäœãšã¢ã¯ãªã«é žå
ã¯ãã®ãšã¹ãã«åéäœããã³ïŒãŸãã¯ã¡ã¿ã¯ãªã«
é žåã¯ãã®ãšã¹ãã«åéäœãå«ãåéäœæåãé
åããŠåŸãããå ±éåäœãå«æããæš¹èã§ããã
åèšã¹ãã¬ã³ç³»åéäœãšããŠã¯ãã¹ãã¬ã³ãïœâ
ã¡ãã«ã¹ãã¬ã³ãïœâã¡ãã«ã¹ãã¬ã³ãïœâã¡ã
ã«ã¹ãã¬ã³ãαâã¡ãã«ã¹ãã¬ã³ãïœâãšãã«ã¹
ãã¬ã³ãïŒïŒïŒâãžã¡ãã«ã¹ãã¬ã³ãïœâïœâã
ãã«ã¹ãã¬ã³ãïœâtertâããã«ã¹ãã¬ã³ãïœâ
ïœâããã·ã«ã¹ãã¬ã³ãïœâïœâãªã¯ãã«ã¹ãã¬
ã³ãïœâïœâããã«ã¹ãã¬ã³ãïœâïœâãã·ã«ã¹
ãã¬ã³ãïœâïœâããã·ã«ã¹ãã¬ã³ãïœâã¡ãã
ã·ã¹ãã¬ã³ãïœâããšãã«ã¹ãã¬ã³ãïœâã¯ãã«
ã¹ãã¬ã³ãïŒïŒïŒâãžã¯ãã«ã¹ãã¬ã³ãªã©ãæã
ãããšãã§ãããããã®ãã¡ã¹ãã¬ã³ãæã奜ãŸ
ããã åèšã¹ãã¬ã³ç³»ã¢ãããŒãšå ±éåãããã¢ã¯ãª
ã«é žãšã¹ãã«ããã³ã¡ã¿ã¯ãªã«é žãšã¹ãã«ãšããŠ
ã¯ãã¡ãã«ã¢ã¯ãªã¬ãŒãããšãã«ã¢ã¯ãªã¬ãŒãã
ïœâãããã«ã¢ã¯ãªã¬ãŒããisoâãããã«ã¢ã¯
ãªã¬ãŒããïœâããã«ã¢ã¯ãªã¬ãŒããisoâãã
ã«ã¢ã¯ãªã¬ãŒããtertâããã«ã¢ã¯ãªã¬ãŒããïŒ
âãšãã«ããã·ã«ã¢ã¯ãªã¬ãŒããã·ã¯ãããã·ã«
ã¢ã¯ãªã¬ãŒããïœâãªã¯ãã«ã¢ã¯ãªã¬ãŒããiso
âãªã¯ãã«ã¢ã¯ãªã¬ãŒããïœâããã·ã«ã¢ã¯ãªã¬
ãŒããïŒâããããã·ãšãã«ã¢ã¯ãªã¬ãŒããïŒâ
ã¡ããã·ãšãã«ã¢ã¯ãªã¬ãŒããïŒâã¯ãã«ãšãã«
ã¢ã¯ãªã¬ãŒãããã³ãžã«ã¢ã¯ãªã¬ãŒããïœâã¡ã
ã«ã¢ãããšãã«ã¢ã¯ãªã¬ãŒãããžã¡ãã«ã¢ãããš
ãã«ã¢ã¯ãªã¬ãŒãçã®ã¢ã¯ãªã«é žãšã¹ãã«ããã
ã³ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãããšãã«ã¡ã¿ã¯ãªã¬ãŒ
ããïœâãããã«ã¡ã¿ã¯ãªã¬ãŒããisoâããã
ã«ã¡ã¿ã¯ãªã¬ãŒããïœâããã«ã¡ã¿ã¯ãªã¬ãŒãã
isoâããã«ã¡ã¿ã¯ãªã¬ãŒããtertâããã«ã¡ã¿
ã¯ãªã¬ãŒããïŒâãšãã«ããã·ã«ã¡ã¿ã¯ãªã¬ãŒ
ããã·ã¯ãããã·ã«ã¡ã¿ã¯ãªã¬ãŒããïœâãªã¯ã
ã«ã¡ã¿ã¯ãªã¬ãŒããisoâãªã¯ãã«ã¡ã¿ã¯ãªã¬ãŒ
ããïœâããã·ã«ã¡ã¿ã¯ãªã¬ãŒããïŒâãããã
ã·ã¡ã¿ã¯ãªã¬ãŒãããã³ãžã«ã¡ã¿ã¯ãªã¬ãŒããïœ
âã¡ãã«ã¢ãããšãã«ã¡ã¿ã¯ãªã¬ãŒãããžã¡ãã«
ã¢ãããšãã«ã¡ã¿ã¯ãªã¬ãŒãçã®ã¡ã¿ã¯ãªã«é žãš
ã¹ãã«ãæããããšãã§ãããããã®ãã¡ãã¡ã
ã«ã¡ã¿ã¯ãªã¬ãŒããæã奜ãŸããã äžèšå ±éåäœã¯éåžžçšãããããä¹³åéåãå¡
ç¶éåãæžæ¿éåããããã¯æº¶æ¶²éåãªã©ã«ãã€
ãŠè£œé ããããšãã§ããã ãŸããåèšå ±éåäœã®ååéã¯ãééå¹³ååå
éïŒMwïŒãïŒäžä»¥äžãæ°å¹³åååéïŒMnïŒã
2000以äžãMwïŒMnã2.0以äžã奜ãŸããééå¹³
åååéïŒäžæªæºãæ°å¹³åååé2000æªæºã
MwïŒMn2.0æªæºã®å Žåãèãããã«è¢«èŠæš¹èã
ã¯ããæããèä¹ æ§ãäžè¯ãšãªãæããæŽã«ãå
èšå ±éåäœã®ã¬ã©ã¹è»¢ç§»æž©åºŠïŒTgïŒã¯60â以äž
ã§ããããšã奜ãŸããã60âæªæºã§ãããšç²çæ§
ãæããããšãšãªããããŒãä»çããŠãã€ã«ãã³
ã°ãçºçãæããªãã ãŸãã被èŠããæš¹èã®å¹³åèåã¯0.3ã4ÎŒã奜
ãŸããã¯0.3ã2.0ÎŒã§ããã0.3ÎŒæªæºã®å Žåã¯çµ¶çž
æ§ãæªãè¯å¥œãªçŸåæ§ãåŸããé£ãããŸãã4ÎŒ
ãè¶ ãããšãã€ãªã¢ã®ç£åãå°ãããªãéããŠã
ã€ãªã¢ä»çãçºçãæãã æ¬çºæã«ãããŠäœ¿çšãããæš¹è被èŠãã€ãªã¢ã®
æš¹èã¯ãã¹ãã¬ã³ç³»ã¢ãããŒïŒStïŒãšã¢ã¯ãªã«é ž
ãšã¹ãã«ïŒAEïŒããã³ïŒãŸãã¯ã¡ã¿ã¯ãªã«é žãš
ã¹ãã«ïŒMAEïŒãæ§ææåãšããå ±éåäœã§ã
ããã¹ãã¬ã³ç³»æåã¯ãæš¹èã硬ããå¹çããæ©
æŠåž¯é»ããå¹æãæããã¢ã¯ãªã«é žãšã¹ãã«ãã
ã³ã¡ã¿ã¯ãªã«é žãšã¹ãã«æåã¯æš¹èã匷ããã«ã
ãå¹æãæããäž¡è ã®çžä¹å¹æã«ãã硬ããŠåŒ·ã
ããªæš¹èãšãªãèä¹ æ§ã®è¯å¥œãªãã€ãªã¢ãšããã
ãšãã§ããããã®ããã«ãå ±éåäœã®ééçµææ¯
ã¯StïŒAEããã³ïŒãŸãã¯MAEïŒïŒïŒïŒãïŒïŒïŒ
ã§ãããå¹æãšããŠãæåæ¯ãå€åãããããšã«
ããä»»æã®åž¯é»éã®èª¿æŽã容æãšãªãã æ¬çºæã«ãããæš¹è被èŠãã€ãªã¢ã®ç£æ§äœææ
ãšããŠã¯ãç£å Žã«ãã€ãŠãã®æ¹åã«åŒ·ãç£åãã
ããšã©ã€ãã䜿çšãããããšã©ã€ããšã¯ãããã§
ã¯éãå«æããç£æ§é žåç©ãç·ç§°ããŠããã
MOã»Fe2O3ïŒïŒã¯ïŒäŸ¡ã®éå±ïŒã®ååŠåŒã§ç€ºãã
ãã¹ããã«åããšã©ã€ãã«éå®ããªããããšã©ã€
ãã¯å«æéå±æåã®çµæãå€ããããšã«ããçš®ã
ã®ç£æ°ç¹æ§ãåŸãããããã«ãæ¬çºæã®ç®çã«å
ã€ããã€ãªã¢ãåŸãããšãã§ããã ãŸããããšã©ã€ãã¯é žåç©ã§ããããããã®æ¯
éãéç²ãããã±ã«ç²çã®éå±ç²ããå°ãããŠè»œ
éã§ããããããããŒãšã®æ··åãæ¹æã容æã«ãª
ããåäžãªãããŒæ¿åºŠã垯é»éãå®çŸããäžã§å¥œ
é©ã§ãããããããããšã©ã€ãã¯ãéç²ãããã±
ã«ç²ãã³ãã«ãç²çã«æ¯ã¹ãŠé»æ°æµæã倧ããã
ãïŒ108ã1012ΩâcmïŒãè¡šé¢ã®æš¹è絶çžå±€ã®èå
ã0.5ÎŒïœçšåºŠã®èèãšããŠããçŸåã®ã€ããã«é«
ããã€ã¢ã¹é»çãå°å ãããçŸåæ¹æ³ã«åå䜿çš
å¯èœãªçµ¶çžæ§ãã€ãªã¢ãå®çŸã§ãããšããé·æã
æããã ããšã©ã€ãåç¬ã§ã¯ãã®é»æ°æµæã¯æãé«ãã
ã®ã§ãé«ã 1012ΩâcmçšåºŠã§ããããã亀çªé»ç
äžã§ã¯ããã€ãªã¢ã®æå 端ãŸã§é»è·ãèªèµ·ããã
æããããããã®çºãé«çµ¶çžæ§ïŒ1014Ωâcm以
äžïŒãšããããšã奜ãŸãããããšã©ã€ãè¡šé¢ã«æš¹
è被èŠããããšãå®å®ãªçŸåãè¡ãªãããã«ã¯å¿
èŠã§ããã åèšããšã©ã€ãã¯ãå€éšç£å Ž1000Oeäžã«ãã
ã飜åç£åã10ã40emuïŒïœãä¿ç£åã0.1ã
100Oeã§ããããšã奜ãŸããããŸãæµæçãïŒÃ
106ãïŒÃ1011Ωâcmãæ¯éã4.0ã5.5ã空éçã
1.0ã10ïŒ ã奜ãŸããã æ¬çºæã«äœ¿çšãããæš¹è被èŠãã€ãªã¢ã®è£œé æ¹
æ³ã¯ã被èŠæš¹èããã³å¿ èŠã«å¿ããŠå ããããä»
ã®æš¹èæåãææ©æº¶å€ã«æº¶è§£ããŠè¢«èŠæ¶²ã調æŽ
ããäŸãã°ã¹ãã¬ãŒãã©ã€æ³ã«ãããã€ãªã¢è¡šé¢
ã«è¢«èŠå±€ã圢æããããšãã§ããããããã¯ãäŸ
ãã°æµååãããè£ çœ®ã«ãããŠãäžæããå å§ã¬
ã¹æµã«ãããã€ãªã¢ã®ç£æ§äœç²åã平衡ã®é«ããŸ
ã§äžæãããã次ã«åèšç£æ§äœç²åãåã³èœäžã
ãæãŸã§ã«åèšè¢«èŠæ¶²ãã¹ãã¬ãŒå¡åžããããã®
å¡åžãããè¿ãè¡ãªãã被èŠå±€ã圢æããããšã
ã§ããã æ¬çºæã«ãããŠãããã«å¥œãŸããç»åãåŸãã
ãã«ããããŒç²åŸïŒééå¹³åïŒã¯20ÎŒïœæªæºãç¹
ã«15ã1ÎŒïœã®ç¯å²ã§ããããšãæãŸããã 15ÎŒïœãè¶ ããå Žåé«è§£ååã§ããããé調å
çŸæ§ãåŸããã«ãããç¹ã«20ÎŒïœä»¥äžã§çŽ°åã®è§£
ååãäœäžãããå1ÎŒïœæªæºã§ã¯ããã¶ããã
ãŒã®é£æ£ãçºçããŠé®®æãªç»åãåŸãããªãã æ¬çºæã«ãããæš¹è被èŠãã€ãªã¢ã¯è§£ååãé
調åçŸæ§ãåäžããããããçç¶ã§ãããééå¹³
åç²åŸãïŒã50ÎŒïœã®ãã®ã奜é©ã§ãããããã§
ãã€ãªã¢ç²ååŸã50ÎŒïœãè¶ ãããšçŸåå€å±€ã®è
å±€åãé»å®³ããçŸåæ§ãæªããªããç»è³ªãäœäžã
ããå5ÎŒïœæªæºã ãšçŸåå€ã®çŸåæ§ãæ©æŠåž¯é»
æ§ãæµåæ§çãæªããªãããã€ãã€ãªã¢é£æ£ãç
ãæããªãã ãŸãããã€ã¢ã¹é»å§ã«ãã€ãŠé»è·ãæ³šå ¥ãããŠ
æå äœé¢ã«ãã€ãªã¢ãä»çããããæœåã圢æã
ãé»è·ãæ¶å€±ãããããã®ãé²ãããããã€ãªã¢
ã®æµæçã¯1013Ωcm以äžã奜ãŸããã¯1014Ωcm以
äžã®çµ¶çžæ§ã®ãã®ãããã ãªããæ¬çºæã§ãããããŒåã³ãã€ãªã¢ã®ç²
åŸãåã¯å¹³åç²åŸã¯ééå¹³åç²åŸãæå³ãã該é
éå¹³åç²åŸã¯ã³ãŒã«ã¿ãŒã«ãŠã³ã¿ïŒã³ãŒã«ã¿ç€Ÿ
補ïŒã§æž¬å®ãããå€ã§ããããŸãç²åã®åºææµæ
ïŒæµæçïŒã¯ãç²åã0.50cm2ã®æé¢ç©ãæãã容
åšã«å ¥ããŠã¿ããã³ã°ããåŸãè©°ããããç²åäž
ã«ïŒKgïŒcm2ã®è·éããããŠåããïŒmmçšåºŠãšãã
è·éãšåºé¢é»æ¥µãšã®éã«102ã105VïŒcmã®é»çã
çºçãããŠãã®ãšãæµããé»æµå€ããæ±ããã
ãã äžè¿°ã®ãããŒãšãã€ãªã¢ããåè¡šé¢ç©ã®ç·åã
çãããªãçšåºŠã®æ¯ã§æ··åããããšã奜ãŸããã
äŸãã°ãããŒã®å¹³åç²åŸã10ÎŒïœããã€ãªã¢ã®å¹³
åç²åŸã20ÎŒïœã§ãããšãããããŒæ¿åºŠïŒçŸåå€
ã«å ãããããŒã®ééæ¯ïŒãïŒã40wlïŒ ã奜ãŸ
ããã¯ïŒã25wlïŒ ã«èšå®ããã®ãé©åœã§ããã å³ã¡æ¬çºæã®çŸåå€ã«ãããŠã¯ãåŸæ¥ã®å€§ç²åŸ
ãã€ãªã¢ã®å€åšã«å€æ°ã®å°ç²åŸãããŒãä»çããŠ
æãçŸåå€ãšã¯ç°ãªãããã€ãªã¢ã®ç²åŸãå°ãã
ãããŒã®ç²åŸã«è¿ããã®ãšãããŠãããããäž¡è
ã®è¡šé¢ç©ã®ç·åãã»ãŒçãããªãçšåºŠã®æ··åæ¯ã
奜ãŸãããã®ãšãããã æ¬æ现æžã«ãããŠãè»åç¹ãšã¯ãé«ååŒãããŒ
ãã¹ã¿ãŒãCFTâ500åãïŒå³¶æŽ¥è£œäœæ補ïŒãçš
ããŠã枬å®æ¡ä»¶ãè·é20KgïŒcm2ãããºã«ã®çŽåŸïŒ
mmãããºã«ã®é·ãïŒmmãäºåå ç±80âã§10åéã
ææž©é床ïŒâïŒåãšãããµã³ãã«éïŒcm3ïŒçæ§æ¯
éÃïŒcm3ã§è¡šããããééïŒãšããŠæž¬å®èšé²ãã
ãšãããããŒãã¹ã¿ãŒã®ãã©ã³ãžã€ãŒéäžéâæž©
床æ²ç·ïŒè»åæµåæ²ç·ïŒã«ãããåæ²ç·ã®é«ã
ãïœãšãããšããïœïŒïŒã®ãšãã®æž©åºŠãããã ãŸãã¬ã©ã¹è»¢ç§»ç¹ãšã¯ã瀺差走æ»ç±éèšãäœæž©
DSCãïŒçåŠé»æ°ç€Ÿè£œïŒãçšããææž©é床10âïŒ
åã§æž¬å®ããéã«ãã¬ã©ã¹è»¢ç§»é åã«ããã
DSCãµãŒã¢ã°ã©ã ã®ã¬ã©ã¹è»¢ç§»ç¹ä»¥äžã®ããŒã¹
ã©ã€ã³ã®å»¶é·ç·ãšããŒã¯ã®ç«äžããéšåããããŒ
ã¯ã®é ç¹ãŸã§ã®éã§ã®æ倧åŸæã瀺ãæ¥ç·ãšã®äº€
ç¹ã®æž©åºŠãã¬ã©ã¹è»¢ç§»ç¹ãšå®ãããšãã®å€ãã
ãã éåäœã«ãããæ°å¹³åååéMnåã³ééå¹³å
ååéMwã®å€ã¯çš®ã ã®æ¹æ³ã«ãã€ãŠæž¬å®ããã
ãšãã§ãã枬å®æ¹æ³ã«ãã€ãŠè¥å¹²ã®å€åãããã
æ¬æ现æžã«ãããŠã¯ãMnåã³Mwããäžèšã®æž¬
å®æ³ã«ãã€ãŠåŸãããå€ãšå®çŸ©ããã å³ã¡ããããã®åå€ã¯ãäœããã²ã«ã»ããŒããš
ãŒã·ãšã³ã»ã¯ãããã°ã©ãã€ãŒïŒGPCïŒã«ãã€
ãŠä»¥äžã«èšãæ¡ä»¶ã§æž¬å®ãããå€ãšããã枩床40
âã«ãããŠã溶åªïŒããã©ããããã©ã³ïŒãæ¯å
1.2mlã®æµéã§æµããæ¿åºŠ15mlïŒïŒmlã®ããã©ã
ãããã©ã³è©Šæ溶液ãè©Šæééæç®ã§ïŒmgæ³šå ¥ã
ãŠæž¬å®ãè¡ãªããè©Šæã®ååé枬å®ã«éããŠã¯ã
該詊æã®æããååéããæ°çš®ã®ååæ£ããªã¹ã
ã¬ã³æšæºè©Šæã«ããäœæãããæ€éç·ã®ååéã®
察æ°ãšã«ãŠã³ãæ°ãçŽç·ãšãªãç¯å²å ã«å å«ãã
ã枬å®æ¡ä»¶ãéžæããã ãªããæ¬æž¬å®ã«åœããä¿¡é Œæ§ããäžè¿°ã®æž¬å®æ¡
件ã§è¡ãªã€ãNBS706ããªã¹ãã¬ã³æšæºè©Šæã
ãMnïŒ13.7Ã104ãMwïŒ28.8Ã104ããšãªãããš
ã«ãã確èªããã ã å®æœäŸ 以äžãå®æœäŸã«ã€ããŠæ¬çºæãå ·äœçã«èª¬æã
ãã 第ïŒå³ã¯äœ¿çšããå圢æè£ çœ®ã®æ§é ã瀺ãæé¢
å³ã§ãåçš¿å°ã移åããããšã«ãããç §æå æºïŒ
ïŒã§ç §å°ãããåçš¿åããã©ãŒïŒïŒãã¬ã³ãºïŒïŒ
ãä»ããŠå圢æäœïŒïŒäžã«ç §å°ãããããã®ãã
ã«ããŠéé»æœåã圢æãããããã®éé»æœåã¯çŸ
åè£ çœ®ïŒ¡ã«ããçŸåãããã ãã®ããã«ããŠåŸããããããŒåã¯ãé²å ã©ã³
ãïŒïŒã«ããé€é»ãããŠè»¢åããæããããåŸã
転å極ïŒïŒã«ããèšé²çŽïŒ°ã«è»¢åããããèšé²çŽ
ã¯åé¢æ¥µïŒïŒã«ããå圢æäœïŒïŒããåé¢ã
ããå®çåšïŒïŒã§å®çããããäžæ¹ãå圢æäœïŒ
ïŒã¯é€é»æ¥µïŒïŒãšã¯ãªãŒãã³ã°è£ 眮ïŒïŒã«ããæž
æãããã ã¯ãªãŒãã³ã°è£ 眮ïŒïŒã¯ã¯ãªãŒãã³ã°ãã¬ãŒã
ïŒïŒãæãããïŒïŒã¯ãã¬ãŒãïŒïŒã§æ»ãåãã
ããããŒãæéããããŒã©ã§ããã 第ïŒå³ã®è€åè£ çœ®ã«ããåèšå圢æããã»ã¹ã«
ãããŠã¯ãäžèšåŠæ¹ã®çŸåå€ãçšããŠçŸåããã
第ïŒè¡šã®äœåæ¡ä»¶ã«ããå圢æãè¡ãªãããã ããã€ã³ããŒã®è£œé ã ïŒåŽéã«ççŽ æ°ïŒã12ã®é·éçåæ°ŽçŽ é£éãæã
ãããªãšã¹ãã«ïŒ (1) ãã€ã³ããŒïŒ¡ ããªãªãã·ãããã¬ã³ïŒïŒïŒïŒïŒâïŒïŒïŒâã
ã¹ïŒïŒâããããã·ããšãã«ïŒãããã³ 700ïœ ããã«é ž 150ïœ ïœâããã»ãã«ç¡æ°Žãã¯ãé ž 55.4ïœ ãã€ããããã³ 0.1ïœ ä»¥äžã®ç©è³ªãã枩床èšãã¹ãã³ã¬ã¹ã¹ããŒã«
補æ¹æåšãã¬ã©ã¹è£œçªçŽ ã¬ã¹å°å ¥ç®¡ãåã³æ»Žäž
åŒã³ã³ãã³ãµãåãã容éïŒã®äžžåºãã©ã¹ã³
å ã«å ¥ãããã®ãã©ã¹ã³ããã³ãã«ããŒã¿ãŒã«
ã»ããããçªçŽ ã¬ã¹å°å ¥ç®¡ããçªçŽ ã¬ã¹ãå°å ¥
ããŠãã©ã¹ã³å ãäžæŽ»æ§é°å²æ°ã«ä¿ã€ãç¶æ ã§
枩床230âã«ææž©ãããæ¹æäžã«ãããŠåå¿ã
è¡ã€ããããã«ãïŒïŒïŒïŒïŒâãã³ãŒã³ããªã«
ã«ãã³é žã®ç¡æ°Žç©65.4ïœãå ããŠçŽïŒæéã«ã
ãã€ãŠåå¿ãããé žäŸ¡ã20ã«ãªã€ãæç¹ã§åå¿
ãçµäºãããããã®ããã«ããŠåŸããããããª
ãšã¹ãã«æš¹èã®è»åç¹ã¯120âã§ãã€ãã (2) ãã€ã³ããŒïŒ¢ ããªãªãã·ãšãã¬ã³(2)âïŒïŒïŒâãã¹ïŒïŒâã
ãããã·ããšãã«ïŒãããã³ 650ïœ ããã«é ž 120ïœ ã€ãœããã»ãã«ç¡æ°Žãã¯ãé ž 55.4ïœ ä»¥äžã®ç©è³ªããæš¹èã®å Žåãšåæ§ã®è£ 眮ã
çšããŠæž©åºŠ220âã«ãããŠåå¿ãããããåå¿
ã«ããçæããæ°Žãæµåºããªããªã€ãæç¹ã§é ž
䟡ã枬å®ãããš1.5ã§ãã€ãã ããã«ãïŒïŒïŒïŒïŒâãã³ãŒã³ããªã«ã«ãã³
é žã®ç¡æ°Žç©79ïœãå ãã枩床200âã«ãããŠå
å¿ãããè»åç¹ã120âã«éããæç¹ã§åå¿ã
çµäºãããã (3) ãã€ã³ããŒïŒ£ïŒæ¯èŒçšïŒ ããªãªãã·ãããã¬ã³ïŒïŒïŒïŒïŒâïŒïŒïŒâã
ã¹ïŒïŒâããããã·ããšãã«ïŒãããã³ 211ïœ ãã¬ãã¿ã«é ž 299ïœ ãã³ã¿ãšãªã¹ãªããŒã« 82ïœ ä»¥äžã®ç©è³ªããæš¹èã®å Žåãšåæ§ã®è£ 眮ã
çšããŠææž©ããããã«ãžããã«é«ãªãã·ã0.05
ïœãå ããŠæž©åºŠ200âã«ãããŠåå¿ããããè»
åç¹ã131âã«éããæç¹ã§åå¿ãçµäºãããã ããããŒã®è£œé ã åèšãã€ã³ããŒïŒ¡ãC100éééšãã«ãŒãã³ã
ã©ãã¯ïŒã¢ãŒã¬ã«ïŒ¬ïŒãã€ããã瀟補ïŒ10éé
éšãããªãããã¬ã³ïŒãã¹ã³ãŒã«660PïŒäžæŽå
補瀟補ïŒïŒéééšããã³ã·ãšã«ãããµãŒã§äºåæ··
åããåŸããšã¯ã¹ãã«ãŒããŒã§æº¶èæ··ç·Žããå·åŽ
åŸããžãšãããã«ã«ãŠåŸ®ç²ç ããŠåçŽããå¹³åç²
åŸ12ÎŒïœã®ãããŒïŒ¡ãã補é ããã ããã€ãªã¢ã®è£œé ã ãã€ãªã¢ïŒ¡ïŒ ã¹ãã¬ã³ãšã¡ãã«ã¡ã¿ã¯ãªã¬ãŒããšã®åéäœçµ
ææ¯ã30ïŒ70ã®ã¹ãã¬ã³âã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã
å ±éåäœ15ïœãã¡ãã«ãšãã«ã±ãã³300mlã«æº¶è§£
ããŠè¢«èŠæ¶²ã調補ãããã®è¢«èŠæ¶²ã«ããçç¶ã®ã
ãšã©ã€ããã¹ãã©ã³ãŒã¿ãŒïŒå²¡ç°ç²Ÿå·¥ç€Ÿè£œïŒãçš
ããŠè¢«èŠããå¹³åèå1.0ÎŒïœã®è¢«èŠå±€ãæããã
ã€ãªã¢ã補é ããããããããã€ãªã¢ïŒ¡ããšã
ãããã®ãã€ãªã¢ïŒ¡ã®ééå¹³åç²åŸã¯30ÎŒïœãç£
åã¯25emuïŒïœãåºææµæã¯1014Ωâcmãæ¯é5.2
ïœïŒcm3ã§ãã€ãã ãã€ãªã¢ïŒ¢ïŒ ãã€ãªã¢ïŒ¡ã«ããã被èŠæ¶²ã調補ããããã«çš
ããå ±éåäœã®ãããã«ãã¹ãã¬ã³ãšã¡ãã«ã¡ã¿
ã¯ãªã¬ãŒããšã®åéäœçµææ¯ã60ïŒ40ã®ã¹ãã¬ã³
âã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãå ±éåäœåã³å¥ã®çç¶ã®
ããšã©ã€ããçšããã»ãã¯ããã€ãªã¢ïŒ¡ãšåæ§ã«
ããŠè¢«èŠå±€ã®å¹³åèå1.5ÎŒïœã®ãã€ãªã¢ã補é ã
ãããããããã€ãªã¢ïŒ¢ããšããããã®ãã€ãªã¢
ã®ééå¹³åç²åŸã¯35ÎŒïœãç£åã¯20emuïŒïœã
åºææµæã¯1014Ωâcmãæ¯é5.4ïœïŒcm3ã§ãã€ãã ïŒçŸåå€ã®äœè£œïŒ ãã€ãªã¢ïŒ¡ãåã³ãããŒïŒ¡ãããããŒæ¿åºŠ
12ééïŒ ã§æ··åããŠæ¬çºæã®çŸåå€ã調補ããã
ãã®çŸåå€ãçšããŠã第ïŒè¡šã«ç€ºãæ¡ä»¶ã§çŸåã
è¡ãªããæŽã«ïŒäžæã®è€åãè¡ãªããè©äŸ¡ããã
çµæãè¡šâïŒãè¡šâïŒã«ç€ºããã第ïŒè¡š çŸåæ¡ä»¶ïŒæ£èŠçŸåïŒ å圢æäœ Seæå äœïŒ100Ïãã©ã ïŒ ç·é床 100mmïŒïœ è¡šé¢é»äœ ïŒ800VïŒæéšïŒã0VïŒæéšïŒ ã¹ãªãŒãåŸ 25mm ã¹ãªãŒãç·é床 250mmïŒïœïŒé æ¹åïŒ ç£æ°ããŒã«æ¥µæ° ïŒæ¥µ ç£æ°ããŒã«å転é床 1200r.p.m. çŸåã®ã€ãã 500ÎŒïœ çŸåå€å±€å 400ÎŒïœïŒæ倧å€ïŒ çŸåå€ãããŒæ¿åºŠ 12wtïŒ ã¹ãªãŒãäžã®çŸåå€äžã®ãããŒå«æé0.3mgïŒcm2 DCãã€ã¢ã¹ ïŒãïŒ100V ACãã€ã¢ã¹ 0.5ã2kVp-pïŒ2kHzïŒ
åçæ³ã«ãããŠåæ æäœäžã®æœåãçŸåããæ¹æ³
ã«é¢ãããã®ã§ããã ã åŸæ¥æè¡ åŸæ¥ãé»ååçè€åè£ çœ®çã«ãããŠåæ æäœã
äŸãã°æå äœãã©ã äžã®æœåãçŸåããæ¹æ³ãšã
ãŠã¯ããããŒèªèº«ã«ç£æ§ãä»äžããŠãã€ãªã¢ãäž
èŠãšããäžæåçŸåå€ãçšããå Žåãšãéç£æ§ã
ããŒåã¯ãããã«ç£æ§ãä»äžããããããŒãšç£æ§
ãã€ãªã¢ãšããæãäºæåçŸåå€ãçšããå Žåãš
ãããããåŸè ã®äºæåçŸåå€ã¯ãããŒã®æ©æŠåž¯
é»ã®å¶åŸ¡ã容æã§ãã€ãŠçŸåæ§ããããããã€ã
ããŒã«ä»»æã®è²ãä»äžã§ãããšããç¹åŸŽãããã
åºãçšããããŠããããããçŸåå€ã«ãããŠãåŸ
ãããç»åé¢ã®è§£åååã³é調åçŸæ§ããã®ä»ã®
å šè¬çãªç»è³ªã®æ¹è¯ãèšãããããã€ãªã¢åã³ã
ããŒã®ç²åŸãå°ãªããããè©Šã¿ããªãããŠããã äŸãã°ãæ¬åºé¡äººãå ã«ææ¡ããç¹é¡æ58â
57746å·ãå58â96900ãïŒå·ãå58â97973å·ç
ã®æ现æžã«ã¯ãåŸæ¥ã®80ã500ÎŒïœãšãã倧ç²åŸ
ã®ãã€ãªã¢ã«ä»£ããŠ50ÎŒïœä»¥äžã®å°ç²åŸãã€ãªã¢
ãšããæ··åããããããŒã®ç²åŸã20ÎŒïœä»¥äžãšã
ãçŸåå€ãçšããŠãéæ¥è§Šã§çŸåããæè¡ãèšèŒ
ãããŠããã äœããçŸåå€äžã®ãã€ãªã¢ãå°ç²åŸãšããå Ž
åããããŒãšãã€ãªã¢ã®æ©æŠåž¯é»æ§ãå£åããã
ãã«ããã€ãªã¢ãšçŸåå€æ¬éæ äœïŒäŸãã°çŸåã¹
ãªãŒãïŒåã³ãããŒãšã®éé»æ°çåã³ç©çççµå
åã匱ããªããå圢æã®éçšã§åèšãã€ãªã¢åã³
ãããŒãé£æ£ããŠè£ 眮å éšãæ±æããããç»åé¢
ã«ãããŒãä»çããŠãã¶ããçãããããã€ãªã¢
ãä»çïŒä»¥éããã€ãªã¢ä»çãšç§°ãïŒãããã
ãŠãé®®æãªç»åãåŸãããªãçã®åé¡ãæ®ãããŠ
ããã ãŸãããã€ãªã¢ãå°ç²åŸãšããå ŽåãçŸåå€æ¬
éæ äœäžã«çŸåå€ã®èå±€ã圢æããããããã€äž
åäžãªçŸåå€å±€ãšãªãããã«ãç»åã«ã ã©ãç»å
ã¬ããçãããããŠãé®®æãªç»åãåŸããé£ããª
ããæŽã«ãå€æ°æè€åãè¡ãªã€ãå ŽåãçŸåå€æ¬
éæ äœäžã«çŸåå€ã®èå±€ã圢æããéçšã«ãããŠ
匷ãå§åãå ããããã«ããããŒããã€ãªã¢ãžç©
ççã«åŒ·ãä»çãããšããæè¬ãã€ã«ãã³ã°çŸè±¡
ãå¢å ãããããŒãšãã€ãªã¢ãæå¹ã«æ©æŠåž¯é»ã§
ããªããªã€ãŠããã¶ãããããŒé£æ£ãçãããã
ãããŒããã€ã«ãã³ã°ãããã€ãªã¢ãçŸåãããŠ
ãã€ãªã¢ä»çãçãããããããã¯è¯å¥œãªèå±€ã
圢æã§ããªãã€ããããŠãé®®æãªç»åãåŸããé£
ãçã®åé¡ãããã ãã¶ããé€å»ããã«ã¯ãåæ æäœãšçŸåå€æ¬é
æ äœãšã®ééã倧ããããã°ããããçŸåé»æ¥µå¹
æã匱ããªã€ãŠãããŒã«ããçŸåãè¡ãªããã«ã
ããªããåæ æäœãšçŸåå€æ¬éæ äœãšã®éã«å€§ã
ãªæ¯åé»å Žãçºçãããã°çŸåæ§ã¯åäžãããã
éç»åéšãžã®ãããŒã®ãã¶ãããã€ãªã¢é£æ£ãå€
ããªããšãšãã«ãçŸåè£ çœ®ãé»æ°çã«çµ¶çžããã
ãšãèšèšäžéèŠãªé害ã«ãªã€ãŠããã æŽã«ãŸããããªãšã¹ãã«æš¹èã¯ã«ã«ããã«åºå
ã³æ°Žé žåºãå€æ°æããããã«åžæ°Žæ§ãæããŠã
ãããã®ãããªããªãšã¹ãã«æš¹èããã€ã³ããŒãš
ãããããŒã«ãããŠã¯é«æž©é«æ¹¿ã®ç°å¢æ¡ä»¶äžã§ã¯
ããªãã®æ°ŽåããããŒè¡šé¢ã«ååšããããšãšãª
ãããã®ããã«ãçŸåæã«æ¯åé»çãå°å ãã
ãšãæ°Žåã®åœ±é¿ã«ãããæ©æŠåž¯é»ã«ããèªèµ·ãã
ããããŒè¡šé¢ã®é»è·ããªãŒã¯ãããããªãããã®
çµæãšããŠç»åãã±çã®åé¡ãçºçããã ã çºæã®ç®ç æ¬çºæã®ç®çã¯ããã€ãªã¢åã³ãããŒã®é£æ£ã«
ããè£ çœ®å éšã®æ±æããç»åé¢ã«åèšé£æ£ãã€ãª
ã¢åã³ãããŒçãä»çããŠãã€ãªã¢ä»çããã¶ã
ãçºçããçã®åé¡ãçããããã€åèšãã€ãªã¢
åã³ãããŒéã«ã¯é©åœãªæ©æŠåž¯é»ãä»äžãããŠè¯
奜ãªçŸåãéæããããã®çµæã解åååã³é調
åçŸæ§ã«ããããé®®æãªç»å圢æãå¯èœã§ããçŸ
åæ¹æ³ãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯ãåäžã§è¯å¥œãªèå±€ã圢æ
ã§ãããã€ãŠç»åã ã©ãç»åã¬ãçã®ãªãé®®æãª
ç»åã®åŸãããçŸåæ¹æ³ãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯ãå€æ°æè€åã«ãããŠãã
è¯å¥œãªèå±€ã圢æã§ããŠããã€ãªã¢ä»çããã¶ã
çã®åé¡ãçºçããããã€åèšãã€ãªã¢åã³ãã
ãŒéã«ã¯é©åœãªæ©æŠåž¯é»ãä»äžãããŠçŸåãéæ
ããããã®çµæãããããé®®æãªç»å圢æãå¯èœ
ãªçŸåæ¹æ³ãæäŸããããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãé«æž©é«æ¹¿ã®ç°å¢æ¡ä»¶
äžã«ãããŠãç»åæãçã®åé¡ãçºçããªããé®®
æãªç»åã®åŸãããçŸåæ¹æ³ãæäŸããããšã«ã
ãã ã çºæã®æ§æåã³ãã®äœçšå¹æ å³ã¡ãæ¬çºæã¯ãçŸåå€æ¬éæ äœãžäº€æµãã€ã¢
ã¹ãå°å ããŠçŸåé åã«æ¯åé»çãçããããå
æ æäœäžã«åœ¢æãããæœåãçŸåå€æ¬éæ äœäžã®
ãã€ãªã¢åã³ãããŒå«æçŸåå€å±€ã§çŸåããã«é
ããŠãåèšçŸåå€å±€ãè局圢æéšæã«ããèŠå¶ã
ãŠåæ æäœãšéæ¥è§Šãšãªãããã«çŸåå€æ¬éæ äœ
äžã«10ã500ÎŒïœã®èå±€ã圢æããåèšè局圢æ
éšæã¯äžç«¯ãåºå®ããã匟æ§æ¿ã§ãããåœè©²åŒŸæ§
æ¿ã®å 端ãçŸåå€æ¬éæ äœã®å転æ¹åã®äžæµåŽã
åããåœè©²åŒŸæ§æ¿ã®å 端ãšçŸåå€æ¬éæ äœãšã®é
ãã0.1mm以äžãïŒmmæªæºãšããããã«çŸåå€æ¬
éæ äœã«å¯ŸãæŒå§ããŠåœè©²åŒŸæ§æ¿ã®ç«¯éšã«è¿ãé¢
ã®éšåã§å§æ¥ããŠãçŸåå€æ¬éæ äœãšåŒŸæ§æ¿ã®æ¥
觊äœçœ®ã«ãããŠãã€ãªã¢ãïŒåãã€ééãããã
ãã«æ¬ééãèŠå¶ããåèšãããŒããšãŒãã«åã
ã¹ããšããŒã«åéäœããžã«ã«ãã³é žåéäœãé žæ
åå šäœã«å¯ŸããŠïŒã30ã¢ã«ïŒ ã®ïŒäŸ¡ä»¥äžã®å€äŸ¡ã«
ã«ãã³é žåéäœãåã³åéäœæåå šäœã«å¯ŸããŠ10
ã30ã¢ã«ïŒ ã®åŽéã«ççŽ æ°ïŒã12ã®èèªæçåæ°Ž
çŽ åäœãæããã³ãã¯é žãšãå«ãåéäœæåã®é
åã«ãã€ãŠåŸãããç«ç·ç¶ããªãšã¹ãã«æš¹èãã
ãªããã€ã³ããŒæš¹èãšåèšãã€ã³ããŒæš¹è100é
ééšã«å¯ŸããŠïŒã10éééšã®ããªãªã¬ãã€ã³ãå«
æãããããŒã§ãããåèšãã€ãªã¢ç²åãã¹ãã¬
ã³ç³»åéäœãšã¢ã¯ãªã«é žãšã¹ãã«åéäœåã³ïŒå
ã¯ã¡ã¿ã¯ãªã«é žãšã¹ãã«åéäœãå«ãåéäœæå
ãéåããŠåŸãããå ±éåäœïŒStïŒAEåã³ïŒå
ã¯MAEïŒïŒïŒïŒãïŒïŒïŒã®ééçµææ¯ïŒãããª
ãæš¹èãå¹³åèåã0.3ã4ÎŒïœãšãªãããã«ããš
ã©ã€ãã«è¢«èŠããçç¶ã®æš¹è被èŠãã€ãªã¢ã§ãã
ã®å¹³åç²åŸãïŒã50ÎŒïœãç£åã20ã50emuïŒïœã
åºææµæã1013Ωã»cm以äžã§ããããšãç¹åŸŽãšã
ãéé»æœåã®çŸåæ¹æ³ã«ä¿ããã®ã§ããã æ¬çºæã«ããã°ãçšããããçŸåå€äžã®ãããŒ
ã¯ãåŽéã«ïŒ£æ°ïŒã22ã®èèªæçåæ°ŽçŽ åäœãæ
ããããªãšã¹ãã«æš¹èããã€ã³ããŒãšããŠå«æã
ããããŒã§ããããã硬質ã§çµ¶çžæ§ãé«ããæ©æŠ
垯é»æ§ãè¯å¥œã§ããããã®ããã«ãç¹ã«æš¹è被èŠ
ãã€ãªã¢ãšæå¹ã«æ©æŠåž¯é»ããªããããã€ãªã¢ã¯
ãããŒåã³çŸåå€æ¬éæ äœãšã®éé»æ°åã匷ããª
ãããã®çµæãšããŠããã€ãªã¢é£æ£åã³ãããŒé£
æ£ãé²æ¢ã§ãããã¶ãããã€ãªã¢ä»çã®ãªãé®®æ
ãªç»åãåŸããããšèããããããŸããåèšãã
ç¹å®ã®ããªãšã¹ãã«æš¹èããã€ã³ããŒãšããŠå«æ
ãããããŒã¯æµåæ§ãé«ãããã€ãªã¢ãšæ··åãã
çŸåå€ã®æµåæ§ããåäžãããå¹æãæããŠã
ãããã®ããã«ãçŸåå€æ¬éæ äœäžã«åäžãªçŸå
å€å±€ã圢æã§ããç»åã ã©ãç»åã¬ããé²æ¢ã§ã
ããšèãããããæŽã«ãŸããå€æ°æè€åããããª
ã€ãŠããåèšããªãšã¹ãã«æš¹èããã€ã³ããŒãšã
ãŠå«æãããããŒã¯ãæš¹è被èŠãã€ãªã¢ã®æš¹èãš
èçæ§ã瀺ãããé¢åæ§ãè¯å¥œã§ãããããèå±€
圢æã«ãã€ãŠåŒ·ãå§åãåããŠããããŒãšãã€ãª
ã¢ã¯ç©ççã«ä»çããããããŒã®ãã€ãªã¢ãžã®ã
ã€ã«ãã³ã°ãçºçããçµæãšããŠãã¶ãããããŒ
é£æ£ããã€ãªã¢ä»ççã®ãªããèä¹ æ§ãè¯å¥œã§é®®
æãªç»åãåŸããããšèããããã æŽã«ãŸããæ¬çºæã«åºããåŽéã«é·éèèªæç
åæ°ŽçŽ åäœãæããããªãšã¹ãã«æš¹èããã€ã³ã
ãŒãšãããããŒã¯ãé·éèèªæçåæ°ŽçŽ ã®çæ°Žæ§
ã®å¹æã«ãããé«æž©é«æ¹¿äžã«ãããŠæ¯åé»çãå°
å ãããŠãé»è·ã®ãªãŒã¯ãçºçãããç»åæãã®
ãªãé®®æãªç»åãåŸããããã®ãšèããããã ãã®ããªãšã¹ãã«æš¹èãšããŠãåŽéã«ççŽ æ°ïŒ
以äžã®èèªæçåæ°ŽçŽ åäœãæããããªãšã¹ãã«
æš¹èãçšãããšãåŸããããããŒã¯åžæ°Žæ§ãæã
ãŠãããç¹ã«é«æž©é«æ¹¿ã®ç°å¢æ¡ä»¶äžã«ãããŠãæ¯
åé»çãå°å ããããšé»è·ããªãŒã¯ãããããã
ã¶ããç»åãã±ã®å€ãç»åãšãªã€ãŠããŸããäž
æ¹ãççŽ æ°13以äžã®èèªæçåæ°ŽçŽ åäœãæãã
ããªãšã¹ãã«æš¹èãçšãããšãçæ°Žæ§ã¯ååã§ã
ããããããŒãè»è³ªåããããã«ããã€ãªã¢ãžã
ã€ã«ãã³ã°ããããšãšãªããçŸåå€ãšããŠã®çšã
ãªããªããªã€ãŠããŸãã ããã«ãŸãæµåæ§ã®è¯å¥œãªãããŒã«ããçŸåå€
æ¬éæ äœäžã«çŸåå€ã®èå±€ã圢æã§ããããã«ã
çŸåå€ã®ãã€ãªã¢ãšãããŒã®çµååããã€ãªã¢ãš
çŸåå€æ¬éæ äœã®çµååã匱ãå Žåã§ãã€ãŠãçŸ
åå€å±€ã極ãèãã§ãããããçŸåå€æ¬éæ äœ
ïŒä»¥éã¹ãªãŒããšç§°ããïŒã«åååºçãããããš
ãšãªãã ãªãããããŒã®ãã€ã³ããŒæš¹èã¯ãããªãšã¹ã
ã«æš¹èã®ä»ã«ãäŸãã°åæ£åºŠåäžã®ããã«ä»ã®é
åäœãæ··åããŠãããã ãŸããäžèšã®æš¹èã§è¢«èŠãããæš¹è被èŠãã€ãª
ã¢ã¯æš¹è被èŠãã»ã©ããããŠããããã«ãçç¶ã§
æ»ãããªè¡šé¢ç¶æ ãæããããšãšãªãããã®ãã
ã«ããããŒãšæå¹ã«æ©æŠåž¯é»ããªããããããŒå
ã³çŸåå€æ¬éæ äœãšã®éé»æ°ççµååã匷ããª
ãããã®çµæãšããŠããã€ãªã¢é£æ£åã³ãããŒé£
æ£ãé²æ¢ã§ãããã¶ãããã€ãªã¢ä»çãé²æ¢ã
ããé®®æãªç»åãåŸããããšèããããããŸãã
æš¹è被èŠãã€ãªã¢ãšããããšã§ãå°ç²åŸãã€ãªã¢
ã§ãã€ãŠãçŸåå€ã®æµåæ§ãè¯å¥œã§ãããçŸåå€
æ¬éæ äœäžã«åäžãªçŸåå€ã®èå±€ã圢æã§ããç»
åã ã©ãç»åã¬ããé²æ¢ã§ãããšèãããããã
ãã«ãŸããå€æ°æè€åããããªã€ãŠããäžèšãã
ç¹å®ã®æš¹è被èŠãã»ã©ããããšã«ãããé¢åæ§ã
è¯å¥œã§ãã€ãŠã匷ãå§åãåããŠããããŒãšç©ç
çã«åŒ·ãä»çããããããŒã®ãã€ãªã¢ãžã®ãã€ã«
ãã³ã°ãçºçãããçµæãšããŠããã¶ãããããŒ
é£æ£ããã€ãªã¢ä»ççã®ãªããèä¹ æ§ãè¯å¥œã§é®®
æãªç»åãåŸããããã®ãšèããããã ç¹ã«ããã€ãªã¢ã®æš¹è被èŠã«çšããæš¹èãšã
ãŠã硬質æåãšããŠã®ã¹ãã¬ã³ç³»åéäœãšã匷é
ã§æè»ãªæ©èœãåããã¢ã¯ãªã«é žïŒåã¯ã¡ã¿ã¯ãª
ã«é žïŒåã¯ãã®ãšã¹ãã«ãšã®éåã«ãã€ãŠåŸãã
ãå ±éåäœã䜿çšãããšããããäž¡åéäœæåã®
ãã€ç¹é·ãçºæ®ããªãããåæã«ãã®æ¬ ç¹ã解æ¶
ã§ãããã€ãŸããã¹ãã¬ã³ç³»ã«ããèãã¯ã¢ã¯ãª
ã«ïŒåã¯ã¡ã¿ã¯ãªã«ïŒé žåã¯ãã®ãšã¹ãã«ã«ãã€
ãŠè§£æ¶ããããã€åŸè ã«ããæè»ããä¿æããªã
ãã¹ãã¬ã³ç³»æåã§é©åºŠãªç¡¬ããä»äžããããšã
ã§ãããããããç©æ§ããäžèšããããã«é¢åæ§
ã®åäžããããŒãšã®ä»çé²æ¢çããããããã®ã§
ããã ããã«ãŸããæ¬çºæã«ããã°ãæš¹è被èŠãã€ãª
ã¢ã«ãããçŸåå€æ¬éæ äœäžã«çŸåå€ã®èå±€ã圢
æã§ããããã«ãçŸåå€ã®ãã€ãªã¢ãšãããŒã®çµ
ååããã€ãªã¢ãšçŸåå€æ¬éæ äœã®çµååã匱ã
å Žåã§ãã€ãŠããçŸåå€å±€ã極ãèãã§ããã
ããçŸåå€æ¬éæ äœïŒä»¥éãã¹ãªãŒããšç§°ããïŒ
ã«åååºçãããããšãšãªãã æ¬çºæã«ãããŠãäžèšã®ãèå±€ããšã¯ãçŸåé
åã«ãããŠåã¿ã10ã500ÎŒïœãšãããåŸæ¥ã«ãª
ãèãçŸåå€å±€ã§ããã®ãæãŸããããã®èå±€ã«
ãããæ¯åé»çäžã§ãçŸåå€æ¬éæ äœäžã®çŸåå€
ãåæ æäœãšéæ¥è§Šã§ãã€ãŠãåæ æäœïŒä»¥äžã
å圢æäœãšèšãããšããããïŒãšçŸåå€æ¬éæ äœ
ã®ééãå°ããããŠçŸåããã®ãããã ããã§çŸåé åãšã¯ãçŸåå€æ¬éæ äœã«ããæ¬
éããããããŒãå圢æäœã«éé»çãªåãåããŠ
移è¡ãããé åãããããã®é åå ã«ãããå圢
æäœãšçŸåå€æ¬éæ äœãšã®æè¿æ¥è·é¢ãçŸåéé
ãšããã æ¬çºæã«ãããŠãã¹ãªãŒãäžã®èå±€äžã®ãããŒ
ãçŸåã«ãã倱ãªãããŠããçŽã¡ã«ååãªãããŒ
ãèå±€ã«äŸçµŠãããã°çŸåæ§ã«åœ±é¿ã¯ãªãããã®
ããã«ã¯ãã¹ãªãŒãäžã®ç£ç³ãé«éã§å転ããã
ããšã奜ãŸããã 次ã«ãçŸååã«æ¬éãããå°ãªãçŸåå€ãæ倧
éã®å¹çã§çŸåããããã«ã¯ã (1) ç£æ°ããŒã«ã®é«éå転 (2) ã¹ãªãŒããžã®äº€æµãã€ã¢ã¹ã®å°å (3) åæ æäœãšã¹ãªãŒããšã®ééãå°ããããã
ãš ãªã©ã®æ段ããšãããšã奜ãŸããã æ¬çºæã§æ¡çšãããéæ¥è§ŠçŸåæ³ã«ãããŠãçŸ
åå€å±€ãèãããã°åæ æäœãšã¹ãªãŒããšã®éé
ãå°ããããããšãã§ãããããŒãé£ç¿ãããã«
èŠããæ¯åé»çã圢æããã«èŠããçŸåãã€ã¢ã¹
ã®é»å§ãäœãããããšãã§ãããåŸã€ãŠãåèšã
ããŒé£æ£ã¯ãã®ç¹ããã軜æžãããå€ãã¹ãªãŒã
é¢ããã®çŸåãã€ã¢ã¹ã«åºã¥ããªãŒã¯æŸé»çãå¶
埡ãããå©ç¹ããããããã«åãåæ æäœãšã¹ãª
ãŒããšã®ééãå°ããããå Žåãããã«ãæœåã«
ããçŸååã«åœ¢æãããé»ç匷床ã倧ãããªãã
ãã®çµæãé調ã®åŸ®åŠãªå€åã现ããªãã¿ãŒã³ã
ããçŸåã§ããããã«ãªãã èå±€ãèãããã°ãäžè¬ã«ãçŸååã«æ¬éãã
ããããŒã®éã¯å°ãªããªããçŸåéã¯å°ãããª
ããæ¬ééã倧ããããã«ã¯ãã¹ãªãŒããé«éã§
å転ãããããšãå¹æçã§ããããã ããå圢æ
äœãšã¹ãªãŒããšã®ç·é床æ¯ãïŒïŒ10ã«ãªããšãçŸ
åããããããŒãæœåé¢ã«å¯ŸããŠæã€å¹³è¡ãªé床
æåã倧ãããªããçŸåã«æ¹åæ§ãçŸãããç»è³ª
ãå£åããã ãã®ããšãããèå±€ã®äžéãšããŠãã¹ãªãŒãé¢
äžã«åœ¢æãããçŸåå€å±€äžã«ãå°ãªããšã0.04
mgïŒcm2çšåºŠã®å¯åºŠã§ãããŒãå«ãŸããŠããç¶æ ã§
ããããšãå¿ èŠã§ãããäžè¬ã«ã¯ãã¹ãªãŒãã®ç·
é床ãVslãå圢æäœã®ç·é床ãVdãã¹ãªãŒãäž
ã®èå±€äžã®ãããŒéãmtãšãããšãã ïœVslïŒVdïœã»mtâ§0.4ãmgïŒcm2ã ïœVslïŒVdïœâŠ10 ãšããæ¡ä»¶ãæºããå¿ èŠãããã çŸåå¹çãèæ ®ããã° ïœVslïŒVdïœã»mtâ§0.5ãmgïŒcm2ã ïœVslïŒVdïœâŠïŒ ãšããã®ã奜ãŸãããããã«å®éšäºå®ããã¯ã ïœVslïŒVdïœã»mtâ§0.5ãmgïŒcm2ã ïœVslïŒVdïœâŠïŒ ã§ããããšããã奜ãŸããããšãããã€ãã ãã®æã®çŸåå€äžã®ãããŒãšãã€ãªã¢ã®æ¯ã¯ã
åäœäœç©äžã®ãããŒãšãã€ãªã¢ã®ç·è¡šé¢ç©ãšã®æ¯
ã0.5ãïŒãšãªãã®ã奜ãŸããã 以äžã®ãããªæ¡ä»¶ã«èšå®ããã°ãèå±€äžã®ãã
ãŒãå¹çããçŸåããããšãã§ããçŸåæ§ã¯å®å®
ããŠãããè¯å¥œãªç»è³ªãåŸãããšãã§ããã åèšèå±€ã®çŸåå€å±€ã圢æããæ段ãšããŠã¯ã
çŸåå€äžã«å«ãŸãã塵åãç¹ç¶ãçŽç²åã¯ãããŒ
åã¯ãã€ãªã¢ã®åéäœçã®äžçŽç©ãæé€ããäž
ã§ãã¹ãªãŒãã«å¯ŸããŠåŒŸæ§çã«è»œåºŠã«å§æ¥ããã
å§æ¥æ¿ããæãè局圢æéšæã奜ãŸããçšããã
ãã ãã®è局圢æéšæã¯ãã¹ãªãŒãã«å¯Ÿããå 端ã
ã¹ãªãŒãå転ã®äžæµãåãããã«æŒå§ããã匟æ§
æ¿ã§ãçŸåå€ãã¹ãªãŒããšåŒŸæ§æ¿ã®éãããæã
ãããããšã«ããèå±€ã圢æããã ããã§ãè局圢æéšæïŒåŒŸæ§æ¿ïŒã®å 端ãçŸå
å€æ¬éæ äœã®å転æ¹åã®äžæµåŽãåãããã«æ§æ
ãããŠãããšã匟æ§æ¿ã®å 端ãšçŸåå€æ¬éæ äœãš
ã®éããè¶ããé«ãã®çŸåå€ã¯éãå Žããªãã匟
æ§æ¿äžã«çŸåå€ãã©ãã©ãéã蟌ãŸããé床ã«å§
çž®ãããªããèŠå¶ãããå¯åºŠã®é«ãçŸåå€å±€ãšãª
ã€ãŠããŸãããããŠããã®ããšããããããŒãã
ã€ãªã¢è¡šé¢ã«ãã€ã«ãã³ã°ããã°ããããå€æ°æ
è€åãç¹°ãè¿ãããŠãããšããã€ãªã¢ç²åå士ã
ãã€ã«ãã³ã°ãããããŒãä»ããŠçŸåå€èªäœãå
éããç»åã ã©ãç»åæããšãã€ãç»åäžè¯ãèµ·
ããŠããŸãã ããã«å¯ŸããŠãæ¬çºæã«ãã€ãŠã¯ãè局圢æéš
æïŒåŒŸæ§æ¿ïŒã¯ã匟æ§æ¿ã®å 端ãçŸåå€æ¬éæ äœ
ã®å転æ¹åã®äžæµåŽãåãããã«æ§æãããŠãã
ããã匟æ§æ¿ã®å 端ãšçŸåå€æ¬éæ äœãšã®éãã«
çžåœããçŸåå€ã ããééã§ããåèšéããè¶ã
ãé«ãã®çŸåå€ã¯åŒŸæ§æ¿ã®äžåŽã«éãããçŸåå€
ã¯å§çž®ãããã®ã軜æžããããåŸã€ãŠã匟æ§æ¿ã®
å 端ãçŸåå€æ¬éæ äœã®å転æ¹åã®äžæµåŽãåã
ããã«æ§æãããå Žåã«èµ·ããäžèšã®æ¬ é¥ãé²æ¢
ããããã®ãšãªãã ãããããã®æ¹å床ã¯ã 匟æ§æ¿ã®å 端ãçŸåå€æ¬éæ äœã®å転æ¹åã®
äžæµåŽãåãããã«æ§æãããããšã ãããŒããšãŒãã«åãã¹ããšããŒã«åéäœã
ãžã«ã«ãã³é žåéäœãé žæåå šäœã«å¯ŸããŠïŒã
30ã¢ã«ïŒ ã®ïŒäŸ¡ä»¥äžã®å€äŸ¡ã«ã«ãã³é žåéäœã
åã³åéäœæåå šäœã«å¯ŸããŠ10ã30ã¢ã«ïŒ ã®åŽ
éã«ççŽ æ°ïŒã12ã®èèªæçåæ°ŽçŽ åäœãæã
ãã³ãã¯é žãšãå«ãåéäœæåã®éåã«ãã€ãŠ
åŸãããéç·ç¶ããªãšã¹ãã«æš¹èãããªããã€
ã³ããŒæš¹èãšåèšãã€ã³ããŒæš¹è100éééšã«
察ããŠïŒã10éééšã®ããªãªã¬ãã€ã³ãå«æã
ããããŒã§ããããšã ãã€ãªã¢ç²åãã¹ãã¬ã³ç³»åéäœãšã¢ã¯ãªã«
é žãšã¹ãã«åéäœåã³ïŒåã¯ã¡ã¿ã¯ãªã«é žãšã¹
ãã«åéäœãå«ãåéäœæåãéåããŠåŸãã
ãå ±éåäœïŒStïŒAEåã³ïŒåã¯MAEïŒïŒïŒïŒ
ãïŒïŒïŒã®ééçµææ¯ïŒãããªãæš¹èãå¹³åè
åã0.3ã4ÎŒïœãšãªãããã«ããšã©ã€ãã«è¢«èŠ
ããçç¶ã®æš¹è被èŠãã€ãªã¢ã§ããã®å¹³åç²åŸ
ãïŒã50ÎŒïœãç£åã20ã50emuïŒïœãåºææµ
æã1013Ωã»cm以äžã§ããããš ãšãã€ãæ§æèŠä»¶ãææ©çã«çµåããŠããããšã«
ãã€ãŠäžå±€å¹æçã«éæããããã®ãšãªãã å³ã¡ãé«æž©å€æ¹¿ãšãã€ããããªç°å¢äžã«ãã€ãŠ
ã¯ãåèšç»åã ã©ãç»åæããšãã€ãç»åäžè¯ã
ããäžå±€èµ·ãæãã®ã§ããããäžèšã®ãããªæ§æ
èŠä»¶ãææ©çã«çµåãããããšã«ãã€ãŠãç»åã
ã©ãç»åæããšãã€ãç»åäžè¯ãããäžå±€èµ·ãé£
ããªã€ãã®ã§ããã 第ïŒå³ã¯åŒŸæ§æ¿ã®å 端ãšã¹ãªãŒããšã®ééïŒïŒ
éå£é¢ç©ïŒãšã¹ãªãŒãäžã«ä»çããŠããçŸåå€é
ãšã®é¢ä¿ã§ããããã®å³ãããééãäžå®å€ä»¥äž
ã«ãªã€ããšããã¹ãªãŒãäžã®çŸåå€éã¯ãããã®
å€åã«å¯Ÿãå®å®ããããšããããããã®å®å®ç¶æ
ã«ãããŠã¯ãå ã«è¿°ã¹ãçŸåã«å¿ èŠãªãããŒã¯å
åã«æ¬éã§ãããä»ã®å®éšãããå±€ã®åããã»ãš
ãã©å€åããªãããšãä»ã®ãã©ã¡ãŒã¿ããã®å®å®
ç¶æ ã®åºçŸã«ã»ãšãã©åœ±é¿ããªãããšãæããã«
ãªã€ãã ãããã€ãŠãå 端ã®ééã0.08mm以äžãšãã
ãšãåä»ã粟床ãæ©æ¢°ç粟床ã®ãã©ã€ãã«å¯Ÿãå®
å®ã«äžå®éã®ãããŒãæ¬éããããšãã§ãããã
ãã«ãå 端ã®ééã0.1mm以äžãšããã°ãå®å®åºŠ
ãå¢ã ãã¡ãããåèšå 端ã®ééãåŸãã«å€§ãããšã
ããšã¯æãŸããããšã§ã¯ãªããééãïŒmm以äžã«
ãããšãå±€ã®åäžæ§ã厩ããã®ã芳å¯ãããã 第ïŒå³ã«ã¯ãæ¬çºæã®çŸåæ¹æ³ãè¡ãäžã§å¥œé©
ãªçŸåè£ çœ®ã®æé¢å³ã瀺ããããå³äžïŒïŒã¯å圢
æäœãïŒã¯ããŠãžã³ã°ãïŒã¯ã¹ãªãŒããïŒã¯ïŒ®ã
S8極ãæããç£æ°ããŒã«ãïŒã¯è局圢æéšæã
ïŒã¯è©²éšæã®åºå®éšæãïŒã¯ç¬¬ïŒæ¹æéšæãïŒã¯
第ïŒæ¹æéšæã§ãããïŒåã³ïŒïŒã¯åèšæ¹æéšæ
ïŒåã³ïŒã®å転軞ãïŒïŒã¯è£çµŠãããŒå®¹åšãïŒïŒ
ã¯ãããŒè£çµŠããŒã©ãïŒïŒã¯çŸåå€æºããïŒïŒã¯
çŸåãã€ã¢ã¹é»æºãïŒïŒã¯çŸåé åãã¯ãã
ãŒãã¯çŸåå€ãè¡šãããããçŸåè£ çœ®ã«ãã
ãŠãçŸåå€æºãïŒïŒå ã®çŸåå€ïŒ€ã¯ç¢å°æ¹åã«å
転ãã第ïŒæ¹æéšæïŒãšããããšå察æ¹åã§äºã
ã«éè€ããããã«å転ãã第ïŒæ¹æéšæïŒãšã«ã
ãå åæ¹ææ··åãããç¢å°æ¹åã«å転ããã¹ãªãŒ
ãïŒãšãããšå察æ¹åã«å転ããç£æ°ããŒã«ïŒã®
æ¬éåã«ãããåèšã¹ãªãŒãïŒã®è¡šé¢ã«ä»çæ¬é
ããããåèšã¹ãªãŒãïŒè¡šé¢ã«ã¯ããŠãžã³ã°ïŒã
ã延ã³ãåºå®éšæïŒã«ããä¿æãããè局圢æéš
æïŒã端éšã«è¿ãé¢ã®éšåã§å§æ¥ãããŠããŠãå
è¿°ã®ããã«ããŠæ¬éãããçŸåå€ïŒ€ã®å±€åãèŠå¶
ããããã®çŸåå€å±€ã¯çŸåé åïŒïŒã«ãããŠç¢å°
æ¹åã«å転ããå圢æäœïŒïŒäžã®æœåãééããž
ã ãŠãŠéæ¥è§Šã§çŸåãããããŒåã圢æãããçŸ
åæã«ã¯é»æºïŒïŒãã亀æµæåãå«ãçŸåãã€ã¢
ã¹ãåèšã¹ãªãŒãïŒã«å°å ããããã®çµæã¹ãŒã
ïŒäžã®çŸåå€äžã®ãããŒã®ã¿ãéžæçã«åèšæœå
ã®é¢ã«ç§»è¡ããŠä»çãããããªããçŸåå€ã®å±€å
ã¯äŸãã°ä»¥äžã®ããã«ããã°æž¬å®ã§ãããããã
ã¡ãæ¥æ¬å åŠ(æ ª)補ãã³ã³ãããã€ãŒã«ãããžãšã¯
ã¿ãŒãçšããã¹ãªãŒãã®ã¹ã¯ãªãŒã³ã®æ圱åãšã
ã¹ãªãŒãã«èå±€ã圢æããç¶æ ã®æ圱åãšã®äœçœ®
ãšã®æ¯èŒã«ããå±€åãæ±ããããã åèšè局圢æéšæïŒã¯ãåºå®éšæïŒã«ããäžç«¯
ãåºå®ãããŠåŒŸæ§ãä»äžããããäŸãã°ç£æ§åã¯
éç£æ§ã®éå±ãéå±ååç©ããã©ã¹ããã¯ããŽã
çããæã極ããŠåäžã«æ圢ãããèæ¿ã§ããã
ãã®åãã¯50ã500ÎŒïœãšãããã åèšã®ããã«äžç«¯ãåºå®ãããè局圢æéšæã®
ä»ç«¯ã«è¿ãé¢ã®éšåã§ã¹ãªãŒãïŒã«åŒŸæ§çã«æŒå§
ããã¹ãªãŒãïŒãšèæ¿ã®æ¥è§Šäœçœ®ã«ãããŠãã€ãª
ã¢ãïŒåãã€ééãããããã«ããŠæ¬ééãèŠå¶
ãããçŸåå€ïŒ€äžã®äžçŽç©ããã€ãªã¢åã¯ãããŒ
ã®åéç©ãªã©ã¯èŠå¶äœçœ®ãééã§ããªããåŸã€
ãŠãçŸåé åïŒïŒã«å°ãçŸåå€å±€ãåžžã«èå±€ã«ã
ãŠåäžãã€å®å®ãããã®ãåŸãããã æ¬çºæã®çŸåæ¹æ³ã®åŠããç¹å®ã®æš¹è被èŠãã€
ãªã¢ãçšããå Žåãå°ç²åŸãã€ãªã¢ã§ãã€ãŠãæµ
åæ§ãè¯å¥œã§ãããããè局圢æéšæã«ããå±€å
ãèŠå¶ãããŠãçŸåå€æ¬éæ äœäžã«åäžãªçŸåå€
å±€ã圢æã§ãããŸããé¢åæ§ãè¯å¥œã§ãã€ãŠåŒ·ã
å§åãåããŠããããŒã®ãã€ãªã¢ãžã®ãã€ã«ãã³
ã°ãçºçããªãã ãªããçŸåé åïŒïŒã«å°ãçŸåå€ã®æ¬ééã¯ã
åèšè局圢æéšæïŒã®ã¹ãªãŒãïŒã«å¯ŸããæŒæ¥å
ãæ¥è§Šè§ãå€ããããšã«ããå¶åŸ¡ãããã çŸåå€ãæ§æãããã€ãªã¢åã³ãããŒãå°ç²åŸ
ã®æ¹ãç»è³ªã®è§£åååã³é調åçŸæ§ã®ç¹ããæå©
ãšããããäŸãã°ãçŸåå€å±€ã®ãããŒç²åŸã5ÎŒ
ïœä»¥äžããã€ãªã¢ã®ç²åŸã50ÎŒïœä»¥äžãããã«ã¯
30ÎŒïœä»¥äžã®å°ç²åŸãšããå Žåã§ãåèšããèå±€
圢æéšæïŒã®ãããªæ段ãçšããããšã«ããçŸå
å€äžã®äžçŽç©ãç²å¡çãèªåçã«æé€ããŠåäžãª
èå±€ã圢æããããšãã§ãããããã«ãåèšãã€
ãªã¢ããããŒãšåçšåºŠã®å°ç²åŸãšãããå Žåã§ã
åæ§äžçŽç©ã®æ··å ¥ãæé€ãããŠåäžãªè局圢æã
å¯èœãšãããã éã«ãå圢æäœã®ãã€ãªã¢ä»çãé²æ¢ãããã
ã«ã¯ããã€ãªã¢ç²åŸã倧ããæ¹ã匷ãç£åãåã
ãããšãã奜ãŸãããäŸãã°ããã€ãªã¢ç²åŸã50
ã100ÎŒïœçšåºŠã«ãªã€ãŠãåèšã®æ¹æ³ã«ããã°å
äžãªèå±€ã圢æã§ããããªãããã€ãªã¢ç²åŸã倧
ãããªããšãèå±€äžã®ãã€ãªã¢ã®ç©é«ã倧ãããª
ããšãšãã«å±€ãç²ããªããçŸåæ§ã¯æªããªããã
ã®ç¹ãããã€ãªã¢ã¯å°ç²åŸã§ç£åãäŸãã°10ã
200ã奜ãŸããã¯20ã100ãæŽã«å¥œãŸããã¯20ã
50emuïŒïœãæãŸãããç£åã10emuïŒïœæªæºã§
ãããšæå®ã®ç£æ°ãã©ã·ã圢æã§ããããŸã
200emuïŒïœãè¶ ãããšç£åã倧ããããŠæ¯åé»
çäžã§çŸåãè¯å¥œã«è¡ãªããããè¯å¥œãªç»åãåŸ
ãããªããªãã åèšçŸåè£ çœ®ã«çµã¿èŸŒãŸããæ¹æéšæïŒåã³ïŒ
ã®å ·äœçæ§é ã瀺ãæèŠå³åã³æ£é¢å³ãã第ïŒå³
ã€åã³ãã«ç€ºããããå³äžïŒïœïŒïŒïœïŒïŒïœã¯ç¬¬
ïŒæ¹æéšæã®æ¹æçŸœæ ¹ãïŒïœïŒïŒïœïŒïŒïœãã¯ç¬¬
ïŒæ¹æéšæã®æ¹æçŸœæ ¹ã§ãè§æ¿çŸœæ ¹ãåæ¿çŸœæ ¹ã
æ¥åæ¿çŸœæ ¹çåçš®ã®æ æ§ããããããããå転軞
ïŒåã³ïŒïŒã«äºãã«ç°ãªãè§åºŠåã³ïŒåã¯äœçœ®ã§
åºå®ãããŠãããåèšïŒã€ã®æ¹æéšæïŒåã³ïŒ
ã¯ãæ¹æçŸœæ ¹ãäºãè¡çªããããšãªãæ¹æé åã
ãªãŒãã©ããããããã«æ§æãããŠãããããå·Š
å³æ¹åïŒç¬¬ïŒå³ïŒã®æ¹æãååã«è¡ãªããããšå ±
ã«ãæ¹ææ¿ã®åŸæïŒç¬¬ïŒå³ïŒã®ããååŸæ¹åïŒç¬¬
ïŒå³ïŒã®æ¹æãååã«è¡ãªãããã åãè£çµŠããŒã©ïŒïŒãä»ããŠãããïŒïŒããè£
絊ããããããŒïŒŽãçæéã§çŸåå€ïŒ€äžã«åäžæ··
åãããã 以äžã®ããã«ååã«æ¹æããæãŸããæ©æŠåž¯é»
ãä»äžãããçŸåå€ïŒ€ã¯ãã¹ãªãŒãïŒäžã«ä»çæ¬
éãããéçšã§åèšè局圢æéšæïŒã«ãããèŠå¶
ãã極ããŠèããã€åäžãªçŸåå€å±€ã圢æãã
ãããã®çŸåå€å±€ã¯ã¹ãªãŒãïŒã®å転ã«ããäžæ¹
åã«æ¬éããããšå ±ã«ãç£æ°ããŒã«ïŒã®å察æ¹å
ãžã®å転ã«ããæ¯åæåããã€ç£æ°çãã€ã¢ã¹ã
åããåèšã¹ãªãŒãïŒäžã§äŸãã°ããŒãªã³ã°çã®
è€éãªéåãããã®ã§ãçŸåé åïŒïŒã«éããŠå
圢æäœïŒã®æœåãéæ¥è§Šã§çŸåãããšã該æœåé¢
ã«åããŠãããŒãå¹æçã«äŸçµŠããããã«ãªãã
åèšçŸåå€å±€ã¯åèšããããã«500ÎŒïœã10ÎŒïœãš
極ããŠèå±€ãªããšããããšãã§ããã®ã§ãå圢æ
äœïŒãšã¹ãªãŒãïŒãšã®ã®ã€ãããå³ã¡çŸåã®ã€ã
ããäŸãã°500ÎŒïœãŸã§çãããŠãéæ¥è§ŠçŸåã
ååã«å¯èœãšãªãããã®ããã«çŸåã®ã€ãããç
ããããšçŸåé åïŒïŒã®é»çã倧ãããªãã®ã§ã
ã¹ãªãŒãïŒã«å°å ããçŸåãã€ã¢ã¹ãå°ãããŠã
ååãªçŸåãéæãããçŸåãã€ã¢ã¹ã®ãªãŒã¯æŸ
é»çã軜æžãããå©ç¹ããããããã«ã¯æœåã®ã³
ã³ãã©ã¹ãã倧ãããªããããçŸåããŠåŸããã
ç»åã®è§£ååãã®ä»ç»è³ªãå šè¬çã«åäžããã åãæ¬çºæã®æ æ§ã®å¹æãšããŠã¯ãçŸåæ¹æ³ã
éæ¥è§ŠçŸåãšããããããŒã®ã¿ãæœåé¢ã«åãã€
ãŠéžæçã«é£ç¿ããŠçŸåãããã®ã§ãæœåé¢ãžã®
ãã€ãªã¢ä»çãé²æ¢ããããåãæœåé¢ãæºæŠã
ãªãã®ã§å圢æäœè¡šé¢ãæå·ããããå·ãç®ã圢
æãããããããšããªãã解åååã³é調åçŸæ§
ãè¯å¥œã§ãããååãªéã®ãããŒãæœåé¢ã«ä»ç
ãããããšãã§ãããããã«åããããŒåã圢æ
ãããå圢æäœäžã«éããŠçŸåããããšãã§ãã
ã®ã§å€è²çŸåã«å¥œé©ã§ããã ãªããæ¬çºæã®çŸåæ¹æ³ã«ãããå®å®ããçŸå
æ¡ä»¶ãšããŠã¯ãçŸåå€å±€ã10ã500ÎŒïœçŸåã®ã€
ããã200ÎŒïœã2000ÎŒïœãšãããã¹ãªãŒãïŒã®å
転é床ãå圢æïŒã®å転é床ãã¹ãªãŒãäžã®ãã
ãŒä»çéã®é¢ä¿ã¯åè¿°ã®ãããªåŒãæºãããã®ã§
ããããšã奜ãŸããã 次ã«ãæ¬çºæã®çŸåæ¹æ³ã«é©çšãããçŸåå€ã®
æ§æã¯ä»¥äžã®ããã§ããã æ¬çºæã®ãããŒã¯ããšãŒãã«åãã¹ããšããŒã«
ãšãžã«ã«ãã³é žãšã®ãšã¹ãã«æ§é ãåºæ¬éªšæ Œã«æ
ããéç·ç¶ããªãšã¹ãã«ã§ãã€ãŠãåŽéã«ççŽ æ°
ïŒã12ã®é£œåãããã¯äžé£œåã®é·éèèªæçåæ°Ž
çŽ åäœãæããããªãšã¹ãã«æš¹èããã€ã³ããŒæš¹
èãšããŠå«æãããã®ãããŒäžã«çè²å€ããã®ä»
å¿ èŠã«å¿ããŠæ·»å ãããæåãããªãã æ¬çºæã«ãããŠãã€ã³ããŒãæ§æããããªãšã¹
ãã«æš¹èïŒéç·ç¶å ±éåäœïŒã®åæã«çšãããã
åéäœæåã¯ã (ã€) å ±éåäœã®åºæ¬éªšæ Œãæ§æããæåãšããŠ
ã®ããšãŒãã«åãã¹ããšããŒã«ãäž»äœãšããïŒ
䟡ã®ã¢ã«ã³ãŒã«åéäœããã³ïŒäŸ¡ã®ã«ã«ãã³é ž
åéäœã (ã) å ±éåäœã®éç·ç¶åãããªãã¡ãã©ã³ãåãª
ããã¯ç¶²ç¶åã«é¢äžããïŒäŸ¡ä»¥äžã®å€äŸ¡ã«ã«ã
ã³é žåéäœã (ã) å ±éåäœã®åŽéã«ççŽ æ°ïŒã12ã®é£œåããã
ã¯äžé£œåã®é·éèèªæçåæ°ŽçŽ åäœãå°å ¥ãã
ããã®ãåœè©²çåæ°ŽçŽ åäœãæããã³ãã¯é žã
ãæ§æãããå¿ èŠã«å¿ãä»ã®åéäœãå«ãããš
ãã§ããã äžèš(ã€)ã®ãšãŒãã«åãã¹ããšããŒã«ãšããŠã¯ã
ããªãªãã·ãããã¬ã³ïŒïŒïŒïŒïŒâïŒïŒïŒâãã¹
ïŒïŒâããããã·ããšãã«ïŒãããã³ãããªãªã
ã·ãšãã¬ã³(2)âïŒïŒïŒâãã¹ïŒïŒâããããã·ã
ãšãã«ïŒãããã³ãããªãªãã·ãããã¬ã³(6)â
ïŒïŒïŒâãã¹ïŒïŒâããããã·ããšãã«ïŒããã
ã³ãããªãªãã·ãããã¬ã³ïŒïŒïŒïŒïŒâïŒïŒïŒâ
ãã¹ïŒïŒâããããã·ããšãã«ïŒãããã³ãçã
äŸç€ºããããšãã§ããããã®ä»ã®ïŒäŸ¡ã®ã¢ã«ã³ãŒ
ã«åéäœãšããŠã¯ããšãã¬ã³ã°ãªã³ãŒã«ããžãšã
ã¬ã³ã°ãªã³ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ãïŒïŒ
ïŒâãããã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâãããã¬ã³
ã°ãªã³ãŒã«ãïŒïŒïŒâãã¿ã³ãžãªãŒã«ãããªãã³
ãã«ã°ãªã³ãŒã«ãïŒïŒïŒâããã³ãžãªãŒã«çã®ãž
ãªãŒã«é¡ãïŒïŒïŒâãã¹ïŒããããã·ã¡ãã«ïŒã·
ã¯ããããµã³ãåã³ãã¹ããšããŒã«ïŒ¡ãæ°ŽçŽ æ·»å
ãã¹ããšããŒã«ïŒ¡çãäŸç€ºããããšãã§ããã ãŸããïŒäŸ¡ã®ã«ã«ãã³é žåéäœãšããŠã¯ããã¬
ã€ã³é žããããŒã«é žãã¡ãµã³ã³é žãã·ãã©ã³ã³
é žãã€ã¿ã³ã³é žãã°ã«ã¿ã³ã³é žããã¿ã«é žãã€ãœ
ãã¿ã«é žããã¬ãã¿ã«é žãã·ã¯ããããµã³ãžã«ã«
ãã³é žãã³ãã¯é žãã¢ãžãã³é žãã»ããã³é žãã
ãã³é žããããã®é žã®ç¡æ°Žç©çãäŸç€ºããããšã
ã§ããããããïŒäŸ¡ã®ã«ã«ãã³é žåéäœã®äœ¿çšé
ã¯ãé žæåå šäœã«å¯Ÿã10ã90ã¢ã«ïŒ ã奜ãŸããã¯
20ã60ã¢ã«ïŒ å«æãããã åèš(ã)ã«ãããïŒäŸ¡ä»¥äžã®å€äŸ¡ã«ã«ãã³é žåé
äœãšããŠã¯ãäŸãã°ãïŒïŒïŒïŒïŒâãã³ãŒã³ããª
ã«ã«ãã³é žãïŒïŒïŒïŒïŒâãã³ãŒã³ããªã«ã«ãã³
é žãïŒïŒïŒïŒïŒâã·ã¯ããããµã³ããªã«ã«ãã³
é žãïŒïŒïŒïŒïŒâããã¿ã¬ã³ããªã«ã«ãã³é žã
ïŒïŒïŒïŒïŒâããã¿ã¬ã³ããªã«ã«ãã³é žãïŒïŒ
ïŒïŒïŒâãã¿ã³ããªã«ã«ãã³é žãïŒïŒïŒïŒïŒâã
ããµã³ããªã«ã«ãã³é žãïŒïŒïŒâãžã«ã«ããã·ã«
âïŒâã¡ãã«âïŒâã¡ãã¬ã³ã«ã«ããã·ã«ããã
ã³ãããã©ïŒã¡ãã¬ã³ã«ã«ããã·ã«ïŒã¡ã¿ã³ã
ïŒïŒïŒïŒïŒïŒïŒâãªã¯ã¿ã³ããã©ã«ã«ãã³é žããš
ã³ããŒã«äžéäœé žããããã®é žã®ç¡æ°Žç©ãªã©ãæ
ããããšãã§ãããïŒäŸ¡ä»¥äžã®å€äŸ¡ã«ã«ãã³é žå
éäœã®äœ¿çšå²åã¯ãé žæåå šäœã«å¯ŸãïŒã30ã¢ã«
ïŒ ã§ããã äžèš(ã)ã®ççŽ æ°ïŒã12ã®é£œåãããã¯äžé£œåã®
é·éèèªæçåæ°ŽçŽ åäœãåŽéã«æããã³ãã¯é ž
ãšããŠã¯ïœâããã»ãã«ãã¯ãé žãã€ãœããã»ã
ã«ãã¯ãé žãïœâããã·ã«ãã¯ãé žãã€ãœâãã
ã·ã«ãã¯ãé žãã€ãœâãªã¯ãã«ãã¯ãé žãïœâãª
ã¯ãã«ã³ãã¯é žïœâããã«ãã¯ãé žçã奜é©ãªã
ã®ãšããŠäŸç€ºããããšãã§ãã䜿çšéã¯åéäœæ
åå šäœã«å¯Ÿã10ã30ã¢ã«ïŒ ã§ããã æ¬çºæã®ãããŒã¯ã以äžã®ãããªãã€ã³ããŒäž
ã«çè²å€åã³å¿ èŠã«å¿ããŠæ·»å ãããç¹æ§æ¹è¯å€
ãå«æããŠæããã®ã§ããã çè²å€ãšããŠã¯ãã«ãŒãã³ãã©ãã¯ããã°ãã·
ã³ææïŒC.I.No.50415BïŒãã¢ããªã³ãã«ãŒïŒC.I.No.
50405ïŒãã«ã«ã³ãªã€ã«ãã«ãŒïŒC.I.No.azoec
Bleu3ïŒãã¯ãã ã€ãšããŒïŒC.I.No.14090ïŒããŠã«ã
ã©ããªã³ãã«ãŒïŒC.I.No.77103ïŒãããŠãã³ãªã€ã«
ã¬ããïŒC.I.No.26105ïŒããããªã³ã€ãšããŒïŒC.I.
No.47005ïŒãã¡ãã¬ã³ãã«ãŒã¯ãã©ã€ãïŒC.I.No.
52015ïŒããã¿ãã·ã¢ãã³ãã«ãŒïŒC.I.No.74160ïŒã
ãã©ã«ã€ãã°ãªãŒã³ãªã¯ãµã¬ãŒãïŒC.I.No.
42000ïŒãã©ã³ããã©ãã¯ïŒC.I.No.77266ïŒããŒãº
ãã³ã¬ã«ïŒC.I.No.45435ïŒããããã®æ··åç©ããã®
ä»ãæããããšãã§ããããããçè²å€ã¯ãåå
ãªæ¿åºŠã®å¯èŠåã圢æãããã«ååãªå²åã§å«æ
ãããããšãå¿ èŠã§ãããéåžžãã€ã³ããŒ100é
ééšã«å¯ŸããŠïŒã20éééšçšåºŠã§ããã ãŸãããã€ãªã¢ãžã®ä»çãæŽã«é²æ¢ããããã«
䜿çšããããšãã§ããã åèšããªãªã¬ãã€ã³ãšããŠã¯ãäŸãã°ããªãã
ãã¬ã³ãããªãšãã¬ã³ãããªããã³çã®æš¹èã§ã
ã€ãŠJIS  2531â1960ã«èŠå®ãããç°çæ³ã§æž¬
å®ãããšãã®è»åç¹ã80ã180âã奜ãŸããã¯100
ã160âã®ãã®ã§ããã ããªãªã¬ãã€ã³ã®äœ¿çšéã¯ãåèšãã€ã³ããŒæš¹
è100éééšã«å¯ŸããŠïŒã10éééšã§ããã æ¬çºæã«ãããŠäœ¿çšãããæš¹è被èŠãã€ãªã¢ã®
æš¹èãšããŠã¯ãã¹ãã¬ã³ç³»åéäœãšã¢ã¯ãªã«é žå
ã¯ãã®ãšã¹ãã«åéäœããã³ïŒãŸãã¯ã¡ã¿ã¯ãªã«
é žåã¯ãã®ãšã¹ãã«åéäœãå«ãåéäœæåãé
åããŠåŸãããå ±éåäœãå«æããæš¹èã§ããã
åèšã¹ãã¬ã³ç³»åéäœãšããŠã¯ãã¹ãã¬ã³ãïœâ
ã¡ãã«ã¹ãã¬ã³ãïœâã¡ãã«ã¹ãã¬ã³ãïœâã¡ã
ã«ã¹ãã¬ã³ãαâã¡ãã«ã¹ãã¬ã³ãïœâãšãã«ã¹
ãã¬ã³ãïŒïŒïŒâãžã¡ãã«ã¹ãã¬ã³ãïœâïœâã
ãã«ã¹ãã¬ã³ãïœâtertâããã«ã¹ãã¬ã³ãïœâ
ïœâããã·ã«ã¹ãã¬ã³ãïœâïœâãªã¯ãã«ã¹ãã¬
ã³ãïœâïœâããã«ã¹ãã¬ã³ãïœâïœâãã·ã«ã¹
ãã¬ã³ãïœâïœâããã·ã«ã¹ãã¬ã³ãïœâã¡ãã
ã·ã¹ãã¬ã³ãïœâããšãã«ã¹ãã¬ã³ãïœâã¯ãã«
ã¹ãã¬ã³ãïŒïŒïŒâãžã¯ãã«ã¹ãã¬ã³ãªã©ãæã
ãããšãã§ãããããã®ãã¡ã¹ãã¬ã³ãæã奜ãŸ
ããã åèšã¹ãã¬ã³ç³»ã¢ãããŒãšå ±éåãããã¢ã¯ãª
ã«é žãšã¹ãã«ããã³ã¡ã¿ã¯ãªã«é žãšã¹ãã«ãšããŠ
ã¯ãã¡ãã«ã¢ã¯ãªã¬ãŒãããšãã«ã¢ã¯ãªã¬ãŒãã
ïœâãããã«ã¢ã¯ãªã¬ãŒããisoâãããã«ã¢ã¯
ãªã¬ãŒããïœâããã«ã¢ã¯ãªã¬ãŒããisoâãã
ã«ã¢ã¯ãªã¬ãŒããtertâããã«ã¢ã¯ãªã¬ãŒããïŒ
âãšãã«ããã·ã«ã¢ã¯ãªã¬ãŒããã·ã¯ãããã·ã«
ã¢ã¯ãªã¬ãŒããïœâãªã¯ãã«ã¢ã¯ãªã¬ãŒããiso
âãªã¯ãã«ã¢ã¯ãªã¬ãŒããïœâããã·ã«ã¢ã¯ãªã¬
ãŒããïŒâããããã·ãšãã«ã¢ã¯ãªã¬ãŒããïŒâ
ã¡ããã·ãšãã«ã¢ã¯ãªã¬ãŒããïŒâã¯ãã«ãšãã«
ã¢ã¯ãªã¬ãŒãããã³ãžã«ã¢ã¯ãªã¬ãŒããïœâã¡ã
ã«ã¢ãããšãã«ã¢ã¯ãªã¬ãŒãããžã¡ãã«ã¢ãããš
ãã«ã¢ã¯ãªã¬ãŒãçã®ã¢ã¯ãªã«é žãšã¹ãã«ããã
ã³ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãããšãã«ã¡ã¿ã¯ãªã¬ãŒ
ããïœâãããã«ã¡ã¿ã¯ãªã¬ãŒããisoâããã
ã«ã¡ã¿ã¯ãªã¬ãŒããïœâããã«ã¡ã¿ã¯ãªã¬ãŒãã
isoâããã«ã¡ã¿ã¯ãªã¬ãŒããtertâããã«ã¡ã¿
ã¯ãªã¬ãŒããïŒâãšãã«ããã·ã«ã¡ã¿ã¯ãªã¬ãŒ
ããã·ã¯ãããã·ã«ã¡ã¿ã¯ãªã¬ãŒããïœâãªã¯ã
ã«ã¡ã¿ã¯ãªã¬ãŒããisoâãªã¯ãã«ã¡ã¿ã¯ãªã¬ãŒ
ããïœâããã·ã«ã¡ã¿ã¯ãªã¬ãŒããïŒâãããã
ã·ã¡ã¿ã¯ãªã¬ãŒãããã³ãžã«ã¡ã¿ã¯ãªã¬ãŒããïœ
âã¡ãã«ã¢ãããšãã«ã¡ã¿ã¯ãªã¬ãŒãããžã¡ãã«
ã¢ãããšãã«ã¡ã¿ã¯ãªã¬ãŒãçã®ã¡ã¿ã¯ãªã«é žãš
ã¹ãã«ãæããããšãã§ãããããã®ãã¡ãã¡ã
ã«ã¡ã¿ã¯ãªã¬ãŒããæã奜ãŸããã äžèšå ±éåäœã¯éåžžçšãããããä¹³åéåãå¡
ç¶éåãæžæ¿éåããããã¯æº¶æ¶²éåãªã©ã«ãã€
ãŠè£œé ããããšãã§ããã ãŸããåèšå ±éåäœã®ååéã¯ãééå¹³ååå
éïŒMwïŒãïŒäžä»¥äžãæ°å¹³åååéïŒMnïŒã
2000以äžãMwïŒMnã2.0以äžã奜ãŸããééå¹³
åååéïŒäžæªæºãæ°å¹³åååé2000æªæºã
MwïŒMn2.0æªæºã®å Žåãèãããã«è¢«èŠæš¹èã
ã¯ããæããèä¹ æ§ãäžè¯ãšãªãæããæŽã«ãå
èšå ±éåäœã®ã¬ã©ã¹è»¢ç§»æž©åºŠïŒTgïŒã¯60â以äž
ã§ããããšã奜ãŸããã60âæªæºã§ãããšç²çæ§
ãæããããšãšãªããããŒãä»çããŠãã€ã«ãã³
ã°ãçºçãæããªãã ãŸãã被èŠããæš¹èã®å¹³åèåã¯0.3ã4ÎŒã奜
ãŸããã¯0.3ã2.0ÎŒã§ããã0.3ÎŒæªæºã®å Žåã¯çµ¶çž
æ§ãæªãè¯å¥œãªçŸåæ§ãåŸããé£ãããŸãã4ÎŒ
ãè¶ ãããšãã€ãªã¢ã®ç£åãå°ãããªãéããŠã
ã€ãªã¢ä»çãçºçãæãã æ¬çºæã«ãããŠäœ¿çšãããæš¹è被èŠãã€ãªã¢ã®
æš¹èã¯ãã¹ãã¬ã³ç³»ã¢ãããŒïŒStïŒãšã¢ã¯ãªã«é ž
ãšã¹ãã«ïŒAEïŒããã³ïŒãŸãã¯ã¡ã¿ã¯ãªã«é žãš
ã¹ãã«ïŒMAEïŒãæ§ææåãšããå ±éåäœã§ã
ããã¹ãã¬ã³ç³»æåã¯ãæš¹èã硬ããå¹çããæ©
æŠåž¯é»ããå¹æãæããã¢ã¯ãªã«é žãšã¹ãã«ãã
ã³ã¡ã¿ã¯ãªã«é žãšã¹ãã«æåã¯æš¹èã匷ããã«ã
ãå¹æãæããäž¡è ã®çžä¹å¹æã«ãã硬ããŠåŒ·ã
ããªæš¹èãšãªãèä¹ æ§ã®è¯å¥œãªãã€ãªã¢ãšããã
ãšãã§ããããã®ããã«ãå ±éåäœã®ééçµææ¯
ã¯StïŒAEããã³ïŒãŸãã¯MAEïŒïŒïŒïŒãïŒïŒïŒ
ã§ãããå¹æãšããŠãæåæ¯ãå€åãããããšã«
ããä»»æã®åž¯é»éã®èª¿æŽã容æãšãªãã æ¬çºæã«ãããæš¹è被èŠãã€ãªã¢ã®ç£æ§äœææ
ãšããŠã¯ãç£å Žã«ãã€ãŠãã®æ¹åã«åŒ·ãç£åãã
ããšã©ã€ãã䜿çšãããããšã©ã€ããšã¯ãããã§
ã¯éãå«æããç£æ§é žåç©ãç·ç§°ããŠããã
MOã»Fe2O3ïŒïŒã¯ïŒäŸ¡ã®éå±ïŒã®ååŠåŒã§ç€ºãã
ãã¹ããã«åããšã©ã€ãã«éå®ããªããããšã©ã€
ãã¯å«æéå±æåã®çµæãå€ããããšã«ããçš®ã
ã®ç£æ°ç¹æ§ãåŸãããããã«ãæ¬çºæã®ç®çã«å
ã€ããã€ãªã¢ãåŸãããšãã§ããã ãŸããããšã©ã€ãã¯é žåç©ã§ããããããã®æ¯
éãéç²ãããã±ã«ç²çã®éå±ç²ããå°ãããŠè»œ
éã§ããããããããŒãšã®æ··åãæ¹æã容æã«ãª
ããåäžãªãããŒæ¿åºŠã垯é»éãå®çŸããäžã§å¥œ
é©ã§ãããããããããšã©ã€ãã¯ãéç²ãããã±
ã«ç²ãã³ãã«ãç²çã«æ¯ã¹ãŠé»æ°æµæã倧ããã
ãïŒ108ã1012ΩâcmïŒãè¡šé¢ã®æš¹è絶çžå±€ã®èå
ã0.5ÎŒïœçšåºŠã®èèãšããŠããçŸåã®ã€ããã«é«
ããã€ã¢ã¹é»çãå°å ãããçŸåæ¹æ³ã«åå䜿çš
å¯èœãªçµ¶çžæ§ãã€ãªã¢ãå®çŸã§ãããšããé·æã
æããã ããšã©ã€ãåç¬ã§ã¯ãã®é»æ°æµæã¯æãé«ãã
ã®ã§ãé«ã 1012ΩâcmçšåºŠã§ããããã亀çªé»ç
äžã§ã¯ããã€ãªã¢ã®æå 端ãŸã§é»è·ãèªèµ·ããã
æããããããã®çºãé«çµ¶çžæ§ïŒ1014Ωâcm以
äžïŒãšããããšã奜ãŸãããããšã©ã€ãè¡šé¢ã«æš¹
è被èŠããããšãå®å®ãªçŸåãè¡ãªãããã«ã¯å¿
èŠã§ããã åèšããšã©ã€ãã¯ãå€éšç£å Ž1000Oeäžã«ãã
ã飜åç£åã10ã40emuïŒïœãä¿ç£åã0.1ã
100Oeã§ããããšã奜ãŸããããŸãæµæçãïŒÃ
106ãïŒÃ1011Ωâcmãæ¯éã4.0ã5.5ã空éçã
1.0ã10ïŒ ã奜ãŸããã æ¬çºæã«äœ¿çšãããæš¹è被èŠãã€ãªã¢ã®è£œé æ¹
æ³ã¯ã被èŠæš¹èããã³å¿ èŠã«å¿ããŠå ããããä»
ã®æš¹èæåãææ©æº¶å€ã«æº¶è§£ããŠè¢«èŠæ¶²ã調æŽ
ããäŸãã°ã¹ãã¬ãŒãã©ã€æ³ã«ãããã€ãªã¢è¡šé¢
ã«è¢«èŠå±€ã圢æããããšãã§ããããããã¯ãäŸ
ãã°æµååãããè£ çœ®ã«ãããŠãäžæããå å§ã¬
ã¹æµã«ãããã€ãªã¢ã®ç£æ§äœç²åã平衡ã®é«ããŸ
ã§äžæãããã次ã«åèšç£æ§äœç²åãåã³èœäžã
ãæãŸã§ã«åèšè¢«èŠæ¶²ãã¹ãã¬ãŒå¡åžããããã®
å¡åžãããè¿ãè¡ãªãã被èŠå±€ã圢æããããšã
ã§ããã æ¬çºæã«ãããŠãããã«å¥œãŸããç»åãåŸãã
ãã«ããããŒç²åŸïŒééå¹³åïŒã¯20ÎŒïœæªæºãç¹
ã«15ã1ÎŒïœã®ç¯å²ã§ããããšãæãŸããã 15ÎŒïœãè¶ ããå Žåé«è§£ååã§ããããé調å
çŸæ§ãåŸããã«ãããç¹ã«20ÎŒïœä»¥äžã§çŽ°åã®è§£
ååãäœäžãããå1ÎŒïœæªæºã§ã¯ããã¶ããã
ãŒã®é£æ£ãçºçããŠé®®æãªç»åãåŸãããªãã æ¬çºæã«ãããæš¹è被èŠãã€ãªã¢ã¯è§£ååãé
調åçŸæ§ãåäžããããããçç¶ã§ãããééå¹³
åç²åŸãïŒã50ÎŒïœã®ãã®ã奜é©ã§ãããããã§
ãã€ãªã¢ç²ååŸã50ÎŒïœãè¶ ãããšçŸåå€å±€ã®è
å±€åãé»å®³ããçŸåæ§ãæªããªããç»è³ªãäœäžã
ããå5ÎŒïœæªæºã ãšçŸåå€ã®çŸåæ§ãæ©æŠåž¯é»
æ§ãæµåæ§çãæªããªãããã€ãã€ãªã¢é£æ£ãç
ãæããªãã ãŸãããã€ã¢ã¹é»å§ã«ãã€ãŠé»è·ãæ³šå ¥ãããŠ
æå äœé¢ã«ãã€ãªã¢ãä»çããããæœåã圢æã
ãé»è·ãæ¶å€±ãããããã®ãé²ãããããã€ãªã¢
ã®æµæçã¯1013Ωcm以äžã奜ãŸããã¯1014Ωcm以
äžã®çµ¶çžæ§ã®ãã®ãããã ãªããæ¬çºæã§ãããããŒåã³ãã€ãªã¢ã®ç²
åŸãåã¯å¹³åç²åŸã¯ééå¹³åç²åŸãæå³ãã該é
éå¹³åç²åŸã¯ã³ãŒã«ã¿ãŒã«ãŠã³ã¿ïŒã³ãŒã«ã¿ç€Ÿ
補ïŒã§æž¬å®ãããå€ã§ããããŸãç²åã®åºææµæ
ïŒæµæçïŒã¯ãç²åã0.50cm2ã®æé¢ç©ãæãã容
åšã«å ¥ããŠã¿ããã³ã°ããåŸãè©°ããããç²åäž
ã«ïŒKgïŒcm2ã®è·éããããŠåããïŒmmçšåºŠãšãã
è·éãšåºé¢é»æ¥µãšã®éã«102ã105VïŒcmã®é»çã
çºçãããŠãã®ãšãæµããé»æµå€ããæ±ããã
ãã äžè¿°ã®ãããŒãšãã€ãªã¢ããåè¡šé¢ç©ã®ç·åã
çãããªãçšåºŠã®æ¯ã§æ··åããããšã奜ãŸããã
äŸãã°ãããŒã®å¹³åç²åŸã10ÎŒïœããã€ãªã¢ã®å¹³
åç²åŸã20ÎŒïœã§ãããšãããããŒæ¿åºŠïŒçŸåå€
ã«å ãããããŒã®ééæ¯ïŒãïŒã40wlïŒ ã奜ãŸ
ããã¯ïŒã25wlïŒ ã«èšå®ããã®ãé©åœã§ããã å³ã¡æ¬çºæã®çŸåå€ã«ãããŠã¯ãåŸæ¥ã®å€§ç²åŸ
ãã€ãªã¢ã®å€åšã«å€æ°ã®å°ç²åŸãããŒãä»çããŠ
æãçŸåå€ãšã¯ç°ãªãããã€ãªã¢ã®ç²åŸãå°ãã
ãããŒã®ç²åŸã«è¿ããã®ãšãããŠãããããäž¡è
ã®è¡šé¢ç©ã®ç·åãã»ãŒçãããªãçšåºŠã®æ··åæ¯ã
奜ãŸãããã®ãšãããã æ¬æ现æžã«ãããŠãè»åç¹ãšã¯ãé«ååŒãããŒ
ãã¹ã¿ãŒãCFTâ500åãïŒå³¶æŽ¥è£œäœæ補ïŒãçš
ããŠã枬å®æ¡ä»¶ãè·é20KgïŒcm2ãããºã«ã®çŽåŸïŒ
mmãããºã«ã®é·ãïŒmmãäºåå ç±80âã§10åéã
ææž©é床ïŒâïŒåãšãããµã³ãã«éïŒcm3ïŒçæ§æ¯
éÃïŒcm3ã§è¡šããããééïŒãšããŠæž¬å®èšé²ãã
ãšãããããŒãã¹ã¿ãŒã®ãã©ã³ãžã€ãŒéäžéâæž©
床æ²ç·ïŒè»åæµåæ²ç·ïŒã«ãããåæ²ç·ã®é«ã
ãïœãšãããšããïœïŒïŒã®ãšãã®æž©åºŠãããã ãŸãã¬ã©ã¹è»¢ç§»ç¹ãšã¯ã瀺差走æ»ç±éèšãäœæž©
DSCãïŒçåŠé»æ°ç€Ÿè£œïŒãçšããææž©é床10âïŒ
åã§æž¬å®ããéã«ãã¬ã©ã¹è»¢ç§»é åã«ããã
DSCãµãŒã¢ã°ã©ã ã®ã¬ã©ã¹è»¢ç§»ç¹ä»¥äžã®ããŒã¹
ã©ã€ã³ã®å»¶é·ç·ãšããŒã¯ã®ç«äžããéšåããããŒ
ã¯ã®é ç¹ãŸã§ã®éã§ã®æ倧åŸæã瀺ãæ¥ç·ãšã®äº€
ç¹ã®æž©åºŠãã¬ã©ã¹è»¢ç§»ç¹ãšå®ãããšãã®å€ãã
ãã éåäœã«ãããæ°å¹³åååéMnåã³ééå¹³å
ååéMwã®å€ã¯çš®ã ã®æ¹æ³ã«ãã€ãŠæž¬å®ããã
ãšãã§ãã枬å®æ¹æ³ã«ãã€ãŠè¥å¹²ã®å€åãããã
æ¬æ现æžã«ãããŠã¯ãMnåã³Mwããäžèšã®æž¬
å®æ³ã«ãã€ãŠåŸãããå€ãšå®çŸ©ããã å³ã¡ããããã®åå€ã¯ãäœããã²ã«ã»ããŒããš
ãŒã·ãšã³ã»ã¯ãããã°ã©ãã€ãŒïŒGPCïŒã«ãã€
ãŠä»¥äžã«èšãæ¡ä»¶ã§æž¬å®ãããå€ãšããã枩床40
âã«ãããŠã溶åªïŒããã©ããããã©ã³ïŒãæ¯å
1.2mlã®æµéã§æµããæ¿åºŠ15mlïŒïŒmlã®ããã©ã
ãããã©ã³è©Šæ溶液ãè©Šæééæç®ã§ïŒmgæ³šå ¥ã
ãŠæž¬å®ãè¡ãªããè©Šæã®ååé枬å®ã«éããŠã¯ã
該詊æã®æããååéããæ°çš®ã®ååæ£ããªã¹ã
ã¬ã³æšæºè©Šæã«ããäœæãããæ€éç·ã®ååéã®
察æ°ãšã«ãŠã³ãæ°ãçŽç·ãšãªãç¯å²å ã«å å«ãã
ã枬å®æ¡ä»¶ãéžæããã ãªããæ¬æž¬å®ã«åœããä¿¡é Œæ§ããäžè¿°ã®æž¬å®æ¡
件ã§è¡ãªã€ãNBS706ããªã¹ãã¬ã³æšæºè©Šæã
ãMnïŒ13.7Ã104ãMwïŒ28.8Ã104ããšãªãããš
ã«ãã確èªããã ã å®æœäŸ 以äžãå®æœäŸã«ã€ããŠæ¬çºæãå ·äœçã«èª¬æã
ãã 第ïŒå³ã¯äœ¿çšããå圢æè£ çœ®ã®æ§é ã瀺ãæé¢
å³ã§ãåçš¿å°ã移åããããšã«ãããç §æå æºïŒ
ïŒã§ç §å°ãããåçš¿åããã©ãŒïŒïŒãã¬ã³ãºïŒïŒ
ãä»ããŠå圢æäœïŒïŒäžã«ç §å°ãããããã®ãã
ã«ããŠéé»æœåã圢æãããããã®éé»æœåã¯çŸ
åè£ çœ®ïŒ¡ã«ããçŸåãããã ãã®ããã«ããŠåŸããããããŒåã¯ãé²å ã©ã³
ãïŒïŒã«ããé€é»ãããŠè»¢åããæããããåŸã
転å極ïŒïŒã«ããèšé²çŽïŒ°ã«è»¢åããããèšé²çŽ
ã¯åé¢æ¥µïŒïŒã«ããå圢æäœïŒïŒããåé¢ã
ããå®çåšïŒïŒã§å®çããããäžæ¹ãå圢æäœïŒ
ïŒã¯é€é»æ¥µïŒïŒãšã¯ãªãŒãã³ã°è£ 眮ïŒïŒã«ããæž
æãããã ã¯ãªãŒãã³ã°è£ 眮ïŒïŒã¯ã¯ãªãŒãã³ã°ãã¬ãŒã
ïŒïŒãæãããïŒïŒã¯ãã¬ãŒãïŒïŒã§æ»ãåãã
ããããŒãæéããããŒã©ã§ããã 第ïŒå³ã®è€åè£ çœ®ã«ããåèšå圢æããã»ã¹ã«
ãããŠã¯ãäžèšåŠæ¹ã®çŸåå€ãçšããŠçŸåããã
第ïŒè¡šã®äœåæ¡ä»¶ã«ããå圢æãè¡ãªãããã ããã€ã³ããŒã®è£œé ã ïŒåŽéã«ççŽ æ°ïŒã12ã®é·éçåæ°ŽçŽ é£éãæã
ãããªãšã¹ãã«ïŒ (1) ãã€ã³ããŒïŒ¡ ããªãªãã·ãããã¬ã³ïŒïŒïŒïŒïŒâïŒïŒïŒâã
ã¹ïŒïŒâããããã·ããšãã«ïŒãããã³ 700ïœ ããã«é ž 150ïœ ïœâããã»ãã«ç¡æ°Žãã¯ãé ž 55.4ïœ ãã€ããããã³ 0.1ïœ ä»¥äžã®ç©è³ªãã枩床èšãã¹ãã³ã¬ã¹ã¹ããŒã«
補æ¹æåšãã¬ã©ã¹è£œçªçŽ ã¬ã¹å°å ¥ç®¡ãåã³æ»Žäž
åŒã³ã³ãã³ãµãåãã容éïŒã®äžžåºãã©ã¹ã³
å ã«å ¥ãããã®ãã©ã¹ã³ããã³ãã«ããŒã¿ãŒã«
ã»ããããçªçŽ ã¬ã¹å°å ¥ç®¡ããçªçŽ ã¬ã¹ãå°å ¥
ããŠãã©ã¹ã³å ãäžæŽ»æ§é°å²æ°ã«ä¿ã€ãç¶æ ã§
枩床230âã«ææž©ãããæ¹æäžã«ãããŠåå¿ã
è¡ã€ããããã«ãïŒïŒïŒïŒïŒâãã³ãŒã³ããªã«
ã«ãã³é žã®ç¡æ°Žç©65.4ïœãå ããŠçŽïŒæéã«ã
ãã€ãŠåå¿ãããé žäŸ¡ã20ã«ãªã€ãæç¹ã§åå¿
ãçµäºãããããã®ããã«ããŠåŸããããããª
ãšã¹ãã«æš¹èã®è»åç¹ã¯120âã§ãã€ãã (2) ãã€ã³ããŒïŒ¢ ããªãªãã·ãšãã¬ã³(2)âïŒïŒïŒâãã¹ïŒïŒâã
ãããã·ããšãã«ïŒãããã³ 650ïœ ããã«é ž 120ïœ ã€ãœããã»ãã«ç¡æ°Žãã¯ãé ž 55.4ïœ ä»¥äžã®ç©è³ªããæš¹èã®å Žåãšåæ§ã®è£ 眮ã
çšããŠæž©åºŠ220âã«ãããŠåå¿ãããããåå¿
ã«ããçæããæ°Žãæµåºããªããªã€ãæç¹ã§é ž
䟡ã枬å®ãããš1.5ã§ãã€ãã ããã«ãïŒïŒïŒïŒïŒâãã³ãŒã³ããªã«ã«ãã³
é žã®ç¡æ°Žç©79ïœãå ãã枩床200âã«ãããŠå
å¿ãããè»åç¹ã120âã«éããæç¹ã§åå¿ã
çµäºãããã (3) ãã€ã³ããŒïŒ£ïŒæ¯èŒçšïŒ ããªãªãã·ãããã¬ã³ïŒïŒïŒïŒïŒâïŒïŒïŒâã
ã¹ïŒïŒâããããã·ããšãã«ïŒãããã³ 211ïœ ãã¬ãã¿ã«é ž 299ïœ ãã³ã¿ãšãªã¹ãªããŒã« 82ïœ ä»¥äžã®ç©è³ªããæš¹èã®å Žåãšåæ§ã®è£ 眮ã
çšããŠææž©ããããã«ãžããã«é«ãªãã·ã0.05
ïœãå ããŠæž©åºŠ200âã«ãããŠåå¿ããããè»
åç¹ã131âã«éããæç¹ã§åå¿ãçµäºãããã ããããŒã®è£œé ã åèšãã€ã³ããŒïŒ¡ãC100éééšãã«ãŒãã³ã
ã©ãã¯ïŒã¢ãŒã¬ã«ïŒ¬ïŒãã€ããã瀟補ïŒ10éé
éšãããªãããã¬ã³ïŒãã¹ã³ãŒã«660PïŒäžæŽå
補瀟補ïŒïŒéééšããã³ã·ãšã«ãããµãŒã§äºåæ··
åããåŸããšã¯ã¹ãã«ãŒããŒã§æº¶èæ··ç·Žããå·åŽ
åŸããžãšãããã«ã«ãŠåŸ®ç²ç ããŠåçŽããå¹³åç²
åŸ12ÎŒïœã®ãããŒïŒ¡ãã補é ããã ããã€ãªã¢ã®è£œé ã ãã€ãªã¢ïŒ¡ïŒ ã¹ãã¬ã³ãšã¡ãã«ã¡ã¿ã¯ãªã¬ãŒããšã®åéäœçµ
ææ¯ã30ïŒ70ã®ã¹ãã¬ã³âã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã
å ±éåäœ15ïœãã¡ãã«ãšãã«ã±ãã³300mlã«æº¶è§£
ããŠè¢«èŠæ¶²ã調補ãããã®è¢«èŠæ¶²ã«ããçç¶ã®ã
ãšã©ã€ããã¹ãã©ã³ãŒã¿ãŒïŒå²¡ç°ç²Ÿå·¥ç€Ÿè£œïŒãçš
ããŠè¢«èŠããå¹³åèå1.0ÎŒïœã®è¢«èŠå±€ãæããã
ã€ãªã¢ã補é ããããããããã€ãªã¢ïŒ¡ããšã
ãããã®ãã€ãªã¢ïŒ¡ã®ééå¹³åç²åŸã¯30ÎŒïœãç£
åã¯25emuïŒïœãåºææµæã¯1014Ωâcmãæ¯é5.2
ïœïŒcm3ã§ãã€ãã ãã€ãªã¢ïŒ¢ïŒ ãã€ãªã¢ïŒ¡ã«ããã被èŠæ¶²ã調補ããããã«çš
ããå ±éåäœã®ãããã«ãã¹ãã¬ã³ãšã¡ãã«ã¡ã¿
ã¯ãªã¬ãŒããšã®åéäœçµææ¯ã60ïŒ40ã®ã¹ãã¬ã³
âã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãå ±éåäœåã³å¥ã®çç¶ã®
ããšã©ã€ããçšããã»ãã¯ããã€ãªã¢ïŒ¡ãšåæ§ã«
ããŠè¢«èŠå±€ã®å¹³åèå1.5ÎŒïœã®ãã€ãªã¢ã補é ã
ãããããããã€ãªã¢ïŒ¢ããšããããã®ãã€ãªã¢
ã®ééå¹³åç²åŸã¯35ÎŒïœãç£åã¯20emuïŒïœã
åºææµæã¯1014Ωâcmãæ¯é5.4ïœïŒcm3ã§ãã€ãã ïŒçŸåå€ã®äœè£œïŒ ãã€ãªã¢ïŒ¡ãåã³ãããŒïŒ¡ãããããŒæ¿åºŠ
12ééïŒ ã§æ··åããŠæ¬çºæã®çŸåå€ã調補ããã
ãã®çŸåå€ãçšããŠã第ïŒè¡šã«ç€ºãæ¡ä»¶ã§çŸåã
è¡ãªããæŽã«ïŒäžæã®è€åãè¡ãªããè©äŸ¡ããã
çµæãè¡šâïŒãè¡šâïŒã«ç€ºããã第ïŒè¡š çŸåæ¡ä»¶ïŒæ£èŠçŸåïŒ å圢æäœ Seæå äœïŒ100Ïãã©ã ïŒ ç·é床 100mmïŒïœ è¡šé¢é»äœ ïŒ800VïŒæéšïŒã0VïŒæéšïŒ ã¹ãªãŒãåŸ 25mm ã¹ãªãŒãç·é床 250mmïŒïœïŒé æ¹åïŒ ç£æ°ããŒã«æ¥µæ° ïŒæ¥µ ç£æ°ããŒã«å転é床 1200r.p.m. çŸåã®ã€ãã 500ÎŒïœ çŸåå€å±€å 400ÎŒïœïŒæ倧å€ïŒ çŸåå€ãããŒæ¿åºŠ 12wtïŒ ã¹ãªãŒãäžã®çŸåå€äžã®ãããŒå«æé0.3mgïŒcm2 DCãã€ã¢ã¹ ïŒãïŒ100V ACãã€ã¢ã¹ 0.5ã2kVp-pïŒ2kHzïŒ
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
以äžã®çµæããããããããã«ãæ¬çºæã®çŸå
å€ïŒãïŒã«ãããŠã¯ãè¯å¥œãªåž¯é»éã瀺ãããã¶
ãããã€ãªã¢ä»çãçºçããããŸãåäžãªèå±€ã
圢æãããŠããŠãç»åã¬ããç»åã ã©ã®ãªãã解
åååã³é調åçŸæ§ã®è¯å¥œãªé®®æãªç»åãåŸã
ããæŽã«ïŒäžæè€ååŸåã³é«æž©é«æ¹¿äžã«ãããŠã
垯é»éå€åãå°ãªããåæ§ã«é®®æãªç»åãåŸã
ãããã®æã®æ©å ã§ã®ãããŒããã€ãªã¢ã«ããæ±
æã¯æ¥µããŠãããã§ãã€ãããŸããçŸåãã€ã¢ã¹
ã¯ç¬¬ïŒè¡šã«ç€ºããç¯å²å ã§ã¯ããããè¯å¥œãªçµæ
ãåŸãããã ããã«å¯Ÿããæ¯èŒçšçŸåå€ïŒã¯ãåæã«ãããŠ
ã¯ãã¶ãããã€ãªã¢ä»çã¯è¥å¹²æãçšåºŠã§ãã
ããïŒäžæè€ååŸåã³é«æž©é«æ¹¿äžã§ã¯åž¯é»éãäœ
äžããåäžãªèå±€ã圢æã§ããããã¶ãããã€ãª
ã¢ä»çã®å€ãäžè¯ãªç»åã§ãã€ãããŸããåæã
ã垯é»éãäœãããã¶ãã®å€ãäžè¯ãªç»åã§ã
ãããŸãïŒäžæè€ååŸåã³é«æž©é«æ¹¿äžã«ãããŠã¯
ããã«åž¯é»éãäœäžããäžè¯ãªç»åã§ãã€ãã
å€ïŒãïŒã«ãããŠã¯ãè¯å¥œãªåž¯é»éã瀺ãããã¶
ãããã€ãªã¢ä»çãçºçããããŸãåäžãªèå±€ã
圢æãããŠããŠãç»åã¬ããç»åã ã©ã®ãªãã解
åååã³é調åçŸæ§ã®è¯å¥œãªé®®æãªç»åãåŸã
ããæŽã«ïŒäžæè€ååŸåã³é«æž©é«æ¹¿äžã«ãããŠã
垯é»éå€åãå°ãªããåæ§ã«é®®æãªç»åãåŸã
ãããã®æã®æ©å ã§ã®ãããŒããã€ãªã¢ã«ããæ±
æã¯æ¥µããŠãããã§ãã€ãããŸããçŸåãã€ã¢ã¹
ã¯ç¬¬ïŒè¡šã«ç€ºããç¯å²å ã§ã¯ããããè¯å¥œãªçµæ
ãåŸãããã ããã«å¯Ÿããæ¯èŒçšçŸåå€ïŒã¯ãåæã«ãããŠ
ã¯ãã¶ãããã€ãªã¢ä»çã¯è¥å¹²æãçšåºŠã§ãã
ããïŒäžæè€ååŸåã³é«æž©é«æ¹¿äžã§ã¯åž¯é»éãäœ
äžããåäžãªèå±€ã圢æã§ããããã¶ãããã€ãª
ã¢ä»çã®å€ãäžè¯ãªç»åã§ãã€ãããŸããåæã
ã垯é»éãäœãããã¶ãã®å€ãäžè¯ãªç»åã§ã
ãããŸãïŒäžæè€ååŸåã³é«æž©é«æ¹¿äžã«ãããŠã¯
ããã«åž¯é»éãäœäžããäžè¯ãªç»åã§ãã€ãã
å³é¢ã¯æ¬çºæã®å®æœäŸã瀺ããã®ã§ãã€ãŠã第
ïŒå³ã¯çŸåè£ çœ®ã®æé¢å³ã第ïŒå³ã€ã¯æ¹æéšæã®
æèŠå³ã第ïŒå³ãã¯ãã®æ£é¢å³ã第ïŒå³ã¯åè²å
圢æè£ çœ®ã®æŠç¥å³ã第ïŒå³ã¯çŸåå€è局圢æéšæ
ãšçŸåå€æ¬éæ äœïŒã¹ãªãŒãïŒãšã®ééãšãçŸå
å€æ¬ééãšã®é¢ä¿ã瀺ãã°ã©ããã§ããã ãªããå³é¢ã«ç€ºã笊å·ã«ãããŠãïŒâŠâŠçŸåå€
æ¬éæ äœïŒã¹ãªãŒãïŒãïŒâŠâŠç£æ°ããŒã«ãïŒâŠ
âŠçŸåå€è局圢æéšæãïŒïŒïŒâŠâŠæ¹æéšæãïŒ
ïŒâŠâŠãã€ã¢ã¹é»æºãïŒïŒâŠâŠçŸåé åãïŒïŒâŠ
âŠåæ æäœãïŒïŒâŠâŠåž¯é»åšãïŒïŒ¢ïŒïŒ£ïŒïŒ€âŠ
âŠçŸåè£ çœ®ãâŠâŠçŸåå€ãïŒT1ïŒT2âŠâŠã
ããŒã§ããã
ïŒå³ã¯çŸåè£ çœ®ã®æé¢å³ã第ïŒå³ã€ã¯æ¹æéšæã®
æèŠå³ã第ïŒå³ãã¯ãã®æ£é¢å³ã第ïŒå³ã¯åè²å
圢æè£ çœ®ã®æŠç¥å³ã第ïŒå³ã¯çŸåå€è局圢æéšæ
ãšçŸåå€æ¬éæ äœïŒã¹ãªãŒãïŒãšã®ééãšãçŸå
å€æ¬ééãšã®é¢ä¿ã瀺ãã°ã©ããã§ããã ãªããå³é¢ã«ç€ºã笊å·ã«ãããŠãïŒâŠâŠçŸåå€
æ¬éæ äœïŒã¹ãªãŒãïŒãïŒâŠâŠç£æ°ããŒã«ãïŒâŠ
âŠçŸåå€è局圢æéšæãïŒïŒïŒâŠâŠæ¹æéšæãïŒ
ïŒâŠâŠãã€ã¢ã¹é»æºãïŒïŒâŠâŠçŸåé åãïŒïŒâŠ
âŠåæ æäœãïŒïŒâŠâŠåž¯é»åšãïŒïŒ¢ïŒïŒ£ïŒïŒ€âŠ
âŠçŸåè£ çœ®ãâŠâŠçŸåå€ãïŒT1ïŒT2âŠâŠã
ããŒã§ããã
Claims (1)
- ïŒ çŸåå€æ¬éæ äœãžäº€æµãã€ã¢ã¹ãå°å ããŠçŸ
åé åã«æ¯åé»çãçããããåæ æäœäžã«åœ¢æ
ãããæœåãçŸåå€æ¬éæ äœäžã®ãã€ãªã¢åã³ã
ããŒå«æçŸåå€å±€ã§çŸåããã«éããŠãåèšçŸå
å€å±€ãè局圢æéšæã«ããèŠå¶ããŠåæ æäœãšé
æ¥è§Šãšãªãããã«çŸåå€æ¬éæ äœäžã«10ã500ÎŒ
ïœã®èå±€ã圢æããåèšè局圢æéšæã¯äžç«¯ãåº
å®ããã匟æ§æ¿ã§ãããåœè©²åŒŸæ§æ¿ã®å 端ãçŸå
å€æ¬éæ äœã®å転æ¹åã®äžæµåŽãåããåœè©²åŒŸæ§
æ¿ã®å 端ãšçŸåå€æ¬éæ äœãšã®éãã0.1mm以äžã
ïŒmmæªæºãšããããã«çŸåå€æ¬éæ äœã«å¯ŸãæŒå§
ããŠåœè©²åŒŸæ§æ¿ã®ç«¯éšã«è¿ãé¢ã®éšåã§å§æ¥ã
ãŠãçŸåå€æ¬éæ äœãšåŒŸæ§æ¿ã®æ¥è§Šäœçœ®ã«ãããŠ
ãã€ãªã¢ãïŒåãã€ééãããããã«æ¬ééãèŠ
å¶ããåèšãããŒããšãŒãã«åãã¹ããšããŒã«å
éäœããžã«ã«ãã³é žåéäœãé žæåå šäœã«å¯ŸããŠ
ïŒã30ã¢ã«ïŒ ã®ïŒäŸ¡ä»¥äžã®å€äŸ¡ã«ã«ãã³é žåé
äœãåã³åéäœæåå šäœã«å¯ŸããŠ10ã30ã¢ã«ïŒ ã®
åŽéã«ççŽ æ°ïŒã12ã®èèªæçåæ°ŽçŽ åäœãæã
ãã³ãã¯é žãšãå«ãåéäœæåã®éåã«ãã€ãŠåŸ
ãããéç·ç¶ããªãšã¹ãã«æš¹èãããªããã€ã³ã
ãŒæš¹èãšåèšãã€ã³ããŒæš¹è100éééšã«å¯ŸããŠ
ïŒã10éééšã®ããªãªã¬ãã€ã³ãå«æãããããŒ
ã§ãããåèšãã€ãªã¢ç²åãã¹ãã¬ã³ç³»åéäœãš
ã¢ã¯ãªã«é žãšã¹ãã«åéäœåã³ïŒåã¯ã¡ã¿ã¯ãªã«
é žãšã¹ãã«åéäœãå«ãåéäœæåãéåããŠåŸ
ãããå ±éåäœïŒStïŒAEåã³ïŒåã¯MAEïŒïŒïŒ
ïŒãïŒïŒïŒã®ééçµææ¯ïŒãããªãæš¹èãå¹³åè
åã0.3ã4ÎŒïœãšãªãããã«ããšã©ã€ãã«è¢«èŠã
ãçç¶ã®æš¹è被èŠãã€ãªã¢ã§ããã®å¹³åç²åŸãïŒ
ã50ÎŒïœãç£åã20ã50emuïŒïœãåºææµæã
1013Ωã»cm以äžã§ããããšãç¹åŸŽãšããéé»æœå
ã®çŸåæ¹æ³ã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61021020A JPS62178278A (ja) | 1986-01-31 | 1986-01-31 | éé»æœåã®çŸåæ¹æ³ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61021020A JPS62178278A (ja) | 1986-01-31 | 1986-01-31 | éé»æœåã®çŸåæ¹æ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62178278A JPS62178278A (ja) | 1987-08-05 |
| JPH0582943B2 true JPH0582943B2 (ja) | 1993-11-24 |
Family
ID=12043352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61021020A Granted JPS62178278A (ja) | 1986-01-31 | 1986-01-31 | éé»æœåã®çŸåæ¹æ³ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62178278A (ja) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2714803B2 (ja) * | 1988-03-29 | 1998-02-16 | ã³ãã«æ ªåŒäŒç€Ÿ | ç»å圢ææ¹æ³ |
| JP2805309B2 (ja) * | 1988-03-29 | 1998-09-30 | ã³ãã«æ ªåŒäŒç€Ÿ | ç»å圢ææ¹æ³ |
| US5691096A (en) * | 1989-04-04 | 1997-11-25 | Lexmark International, Inc. | Flash fusible toner resins |
| US5688622A (en) * | 1994-09-09 | 1997-11-18 | Minolta Co., Ltd. | Developing method |
| JP3384914B2 (ja) * | 1994-10-04 | 2003-03-10 | æ ªåŒäŒç€Ÿãªã³ãŒ | çŸåè£ çœ® |
| EP1887430B1 (en) | 2005-05-27 | 2013-08-07 | Sanyo Chemical Industries, Ltd. | Resin for toner and toner composition |
| EP1887432B1 (en) | 2005-05-31 | 2012-07-18 | Sanyo Chemical Industries, Ltd. | Toner and toner binder |
| AU2006309691B2 (en) | 2005-11-02 | 2010-03-04 | Ricoh Company, Ltd. | Toner for developing electrostatic images, toner kits, and image formation equipment |
| CN101401042B (zh) | 2006-03-16 | 2011-08-31 | äžæŽåæå·¥äžæ ªåŒäŒç€Ÿ | è°è²åç²åååè°è²å |
| KR101492828B1 (ko) | 2011-10-21 | 2015-02-12 | ë칎칎ê°ì¿ ê°ë¶ìí€ê°ìŽì€ | ë¹ê²°ì ì± íŽëŠ¬ìì€í 륎 ìì§ ë° í ëì© ê²°ì°© ìì§ ë° ê²°ì°© ìì§ ë¶ì°ë¬Œ |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58129437A (ja) * | 1982-01-29 | 1983-08-02 | Konishiroku Photo Ind Co Ltd | éé»è·åçŸåå€ |
| JPS5990861A (ja) * | 1982-11-16 | 1984-05-25 | Konishiroku Photo Ind Co Ltd | äºæåç³»çŸåå€ |
| JPS60131553A (ja) * | 1983-12-20 | 1985-07-13 | Konishiroku Photo Ind Co Ltd | çŸåæ¹æ³ |
| JPS60254154A (ja) * | 1984-05-31 | 1985-12-14 | Konishiroku Photo Ind Co Ltd | éé»è·åçŸåçšããâ |
| JPS60254148A (ja) * | 1984-05-31 | 1985-12-14 | Konishiroku Photo Ind Co Ltd | éé»è·åçŸåçšããâ |
| JPS60254149A (ja) * | 1984-05-31 | 1985-12-14 | Konishiroku Photo Ind Co Ltd | éé»è·åçŸåçšããâ |
| JPS6115158A (ja) * | 1984-06-30 | 1986-01-23 | Konishiroku Photo Ind Co Ltd | ç»å圢ææ¹æ³ |
-
1986
- 1986-01-31 JP JP61021020A patent/JPS62178278A/ja active Granted
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58129437A (ja) * | 1982-01-29 | 1983-08-02 | Konishiroku Photo Ind Co Ltd | éé»è·åçŸåå€ |
| JPS5990861A (ja) * | 1982-11-16 | 1984-05-25 | Konishiroku Photo Ind Co Ltd | äºæåç³»çŸåå€ |
| JPS60131553A (ja) * | 1983-12-20 | 1985-07-13 | Konishiroku Photo Ind Co Ltd | çŸåæ¹æ³ |
| JPS60254154A (ja) * | 1984-05-31 | 1985-12-14 | Konishiroku Photo Ind Co Ltd | éé»è·åçŸåçšããâ |
| JPS60254148A (ja) * | 1984-05-31 | 1985-12-14 | Konishiroku Photo Ind Co Ltd | éé»è·åçŸåçšããâ |
| JPS60254149A (ja) * | 1984-05-31 | 1985-12-14 | Konishiroku Photo Ind Co Ltd | éé»è·åçŸåçšããâ |
| JPS6115158A (ja) * | 1984-06-30 | 1986-01-23 | Konishiroku Photo Ind Co Ltd | ç»å圢ææ¹æ³ |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62178278A (ja) | 1987-08-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6706457B2 (en) | Non-magnetic single-component toner and developing method using the same | |
| US6589703B2 (en) | Electrographic methods using hard magnetic carrier particles | |
| JPH0582943B2 (ja) | ||
| US5876893A (en) | Ferrite carrier, two-component developer and electrostatic imaging method using the developer | |
| JPH06194866A (ja) | éé»æœåçŸåå€ | |
| JPS63289559A (ja) | éé»åçŸåçšããâ | |
| JP3104883B2 (ja) | éé»è·åçŸåçšãã㌠| |
| JPS63235955A (ja) | ç±å®çåéé»åçŸåçšãããŒã®è£œé æ¹æ³ | |
| JP2000010349A (ja) | éé»çŸåå€ | |
| JPS62178279A (ja) | éé»æœåã®çŸåæ¹æ³ | |
| JPS62178277A (ja) | éé»æœåã®çŸåæ¹æ³ | |
| JP2856494B2 (ja) | ãããŒããã³ç»å圢ææ¹æ³ | |
| JP3680557B2 (ja) | ãã€ã³ããŒãã£ãªã¢ã該ãã£ãªã¢ãå«ãçŸåå€ããã³è©²çŸåå€ãçšããç»å圢ææ¹æ³ | |
| JP2836149B2 (ja) | äºæåçŸåå€ | |
| JP2853193B2 (ja) | éé»è·çŸåçšãã㌠| |
| JPS6341863A (ja) | éé»æœåã®çŸåæ¹æ³ | |
| JPH0827555B2 (ja) | çŸåæ¹æ³ | |
| JPS6341864A (ja) | éé»æœåã®çŸåæ¹æ³ | |
| JP2781198B2 (ja) | çŸåæ¹æ³ | |
| JPS63208861A (ja) | éé»åçŸåå€ããã³éé»åçŸåæ¹æ³ | |
| JP3407533B2 (ja) | çŸåæ¹æ³ | |
| JPH01113767A (ja) | ç»å圢ææ¹æ³ | |
| JPS63212944A (ja) | çŸåå€ | |
| JPS6341862A (ja) | éé»æœåã®çŸåæ¹æ³ | |
| JP2825223B2 (ja) | éç£æ§äžæåãããŒããã³çŸåæ¹æ³ |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |