JPH0518426B2 - - Google Patents
Info
- Publication number
- JPH0518426B2 JPH0518426B2 JP61299205A JP29920586A JPH0518426B2 JP H0518426 B2 JPH0518426 B2 JP H0518426B2 JP 61299205 A JP61299205 A JP 61299205A JP 29920586 A JP29920586 A JP 29920586A JP H0518426 B2 JPH0518426 B2 JP H0518426B2
- Authority
- JP
- Japan
- Prior art keywords
- degrees
- carrier
- layer
- group
- photoreceptor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 108091008695 photoreceptors Proteins 0.000 claims description 74
- 239000000126 substance Substances 0.000 claims description 74
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 61
- 239000011230 binding agent Substances 0.000 claims description 28
- 239000013078 crystal Substances 0.000 claims description 14
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- 238000002441 X-ray diffraction Methods 0.000 claims description 11
- 238000001228 spectrum Methods 0.000 claims description 11
- 238000010521 absorption reaction Methods 0.000 claims description 10
- 238000000862 absorption spectrum Methods 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 4
- 125000000623 heterocyclic group Chemical group 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 115
- 239000000463 material Substances 0.000 description 41
- -1 bisazo compound Chemical class 0.000 description 31
- 230000035945 sensitivity Effects 0.000 description 27
- 239000004065 semiconductor Substances 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 239000000049 pigment Substances 0.000 description 11
- 230000007423 decrease Effects 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 239000000969 carrier Substances 0.000 description 8
- 238000000227 grinding Methods 0.000 description 8
- 206010034972 Photosensitivity reaction Diseases 0.000 description 7
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 7
- 230000036211 photosensitivity Effects 0.000 description 7
- 229910052711 selenium Inorganic materials 0.000 description 7
- 239000011669 selenium Substances 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 4
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 4
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 3
- 229940126062 Compound A Drugs 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 239000002612 dispersion medium Substances 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 235000002639 sodium chloride Nutrition 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 2
- 125000002837 carbocyclic group Chemical group 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 231100000315 carcinogenic Toxicity 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 125000006575 electron-withdrawing group Chemical group 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
- 235000019325 ethyl cellulose Nutrition 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229920006158 high molecular weight polymer Polymers 0.000 description 2
- 230000005525 hole transport Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000005453 ketone based solvent Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229960005265 selenium sulfide Drugs 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- SJHPCNCNNSSLPL-CSKARUKUSA-N (4e)-4-(ethoxymethylidene)-2-phenyl-1,3-oxazol-5-one Chemical class O1C(=O)C(=C/OCC)\N=C1C1=CC=CC=C1 SJHPCNCNNSSLPL-CSKARUKUSA-N 0.000 description 1
- NMNSBFYYVHREEE-UHFFFAOYSA-N 1,2-dinitroanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C([N+]([O-])=O)C([N+](=O)[O-])=CC=C3C(=O)C2=C1 NMNSBFYYVHREEE-UHFFFAOYSA-N 0.000 description 1
- IZUKQUVSCNEFMJ-UHFFFAOYSA-N 1,2-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1[N+]([O-])=O IZUKQUVSCNEFMJ-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- HJRJRUMKQCMYDL-UHFFFAOYSA-N 1-chloro-2,4,6-trinitrobenzene Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=C(Cl)C([N+]([O-])=O)=C1 HJRJRUMKQCMYDL-UHFFFAOYSA-N 0.000 description 1
- UVHXEHGUEKARKZ-UHFFFAOYSA-N 1-ethenylanthracene Chemical compound C1=CC=C2C=C3C(C=C)=CC=CC3=CC2=C1 UVHXEHGUEKARKZ-UHFFFAOYSA-N 0.000 description 1
- WPMHMYHJGDAHKX-UHFFFAOYSA-N 1-ethenylpyrene Chemical compound C1=C2C(C=C)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 WPMHMYHJGDAHKX-UHFFFAOYSA-N 0.000 description 1
- FKNIDKXOANSRCS-UHFFFAOYSA-N 2,3,4-trinitrofluoren-1-one Chemical compound C1=CC=C2C3=C([N+](=O)[O-])C([N+]([O-])=O)=C([N+]([O-])=O)C(=O)C3=CC2=C1 FKNIDKXOANSRCS-UHFFFAOYSA-N 0.000 description 1
- HZNVUJQVZSTENZ-UHFFFAOYSA-N 2,3-dichloro-5,6-dicyano-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(C#N)=C(C#N)C1=O HZNVUJQVZSTENZ-UHFFFAOYSA-N 0.000 description 1
- VHQGURIJMFPBKS-UHFFFAOYSA-N 2,4,7-trinitrofluoren-9-one Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=C2C3=CC=C([N+](=O)[O-])C=C3C(=O)C2=C1 VHQGURIJMFPBKS-UHFFFAOYSA-N 0.000 description 1
- BIEFDNUEROKZRA-UHFFFAOYSA-N 2-(2-phenylethenyl)aniline Chemical class NC1=CC=CC=C1C=CC1=CC=CC=C1 BIEFDNUEROKZRA-UHFFFAOYSA-N 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- 125000001340 2-chloroethyl group Chemical group [H]C([H])(Cl)C([H])([H])* 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- SLAMLWHELXOEJZ-UHFFFAOYSA-N 2-nitrobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1[N+]([O-])=O SLAMLWHELXOEJZ-UHFFFAOYSA-N 0.000 description 1
- GZJIQNJINXQYTG-UHFFFAOYSA-N 2-nitrooxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1O[N+]([O-])=O GZJIQNJINXQYTG-UHFFFAOYSA-N 0.000 description 1
- UKYNESNNFCHAEV-UHFFFAOYSA-N 3,4-dibromooxolane-2,5-dione Chemical compound BrC1C(Br)C(=O)OC1=O UKYNESNNFCHAEV-UHFFFAOYSA-N 0.000 description 1
- VYWYYJYRVSBHJQ-UHFFFAOYSA-N 3,5-dinitrobenzoic acid Chemical compound OC(=O)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1 VYWYYJYRVSBHJQ-UHFFFAOYSA-N 0.000 description 1
- LWFUFLREGJMOIZ-UHFFFAOYSA-N 3,5-dinitrosalicylic acid Chemical compound OC(=O)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O LWFUFLREGJMOIZ-UHFFFAOYSA-N 0.000 description 1
- ITUYMTWJWYTELW-UHFFFAOYSA-N 4-chloroiminocyclohexa-2,5-dien-1-one Chemical compound ClN=C1C=CC(=O)C=C1 ITUYMTWJWYTELW-UHFFFAOYSA-N 0.000 description 1
- ROFZMKDROVBLNY-UHFFFAOYSA-N 4-nitro-2-benzofuran-1,3-dione Chemical compound [O-][N+](=O)C1=CC=CC2=C1C(=O)OC2=O ROFZMKDROVBLNY-UHFFFAOYSA-N 0.000 description 1
- OTLNPYWUJOZPPA-UHFFFAOYSA-N 4-nitrobenzoic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-N 0.000 description 1
- NKJIFDNZPGLLSH-UHFFFAOYSA-N 4-nitrobenzonitrile Chemical compound [O-][N+](=O)C1=CC=C(C#N)C=C1 NKJIFDNZPGLLSH-UHFFFAOYSA-N 0.000 description 1
- MMVIDXVHQANYAE-UHFFFAOYSA-N 5-nitro-2-benzofuran-1,3-dione Chemical compound [O-][N+](=O)C1=CC=C2C(=O)OC(=O)C2=C1 MMVIDXVHQANYAE-UHFFFAOYSA-N 0.000 description 1
- MEXUTNIFSHFQRG-UHFFFAOYSA-N 6,7,12,13-tetrahydro-5h-indolo[2,3-a]pyrrolo[3,4-c]carbazol-5-one Chemical compound C12=C3C=CC=C[C]3NC2=C2NC3=CC=C[CH]C3=C2C2=C1C(=O)NC2 MEXUTNIFSHFQRG-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- WZELXJBMMZFDDU-UHFFFAOYSA-N Imidazol-2-one Chemical class O=C1N=CC=N1 WZELXJBMMZFDDU-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004419 Panlite Substances 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 241000519995 Stachys sylvatica Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QHWKHLYUUZGSCW-UHFFFAOYSA-N Tetrabromophthalic anhydride Chemical compound BrC1=C(Br)C(Br)=C2C(=O)OC(=O)C2=C1Br QHWKHLYUUZGSCW-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- UATJOMSPNYCXIX-UHFFFAOYSA-N Trinitrobenzene Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1 UATJOMSPNYCXIX-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- GRADPEKRVZZVPT-UHFFFAOYSA-N [N+](=O)([O-])C1=CC(=CC=C1)[N+](=O)[O-].[N+](=O)([O-])C1=CC=CC=C1 Chemical compound [N+](=O)([O-])C1=CC(=CC=C1)[N+](=O)[O-].[N+](=O)([O-])C1=CC=CC=C1 GRADPEKRVZZVPT-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 125000000641 acridinyl group Chemical class C1(=CC=CC2=NC3=CC=CC=C3C=C12)* 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 229940058303 antinematodal benzimidazole derivative Drugs 0.000 description 1
- 229940027998 antiseptic and disinfectant acridine derivative Drugs 0.000 description 1
- 125000006615 aromatic heterocyclic group Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 125000003785 benzimidazolyl group Chemical class N1=C(NC2=C1C=CC=C2)* 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 150000001716 carbazoles Chemical class 0.000 description 1
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 150000001907 coumarones Chemical class 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000005294 ferromagnetic effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 150000002461 imidazolidines Chemical class 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- NNYHMCFMPHPHOQ-UHFFFAOYSA-N mellitic anhydride Chemical compound O=C1OC(=O)C2=C1C(C(OC1=O)=O)=C1C1=C2C(=O)OC1=O NNYHMCFMPHPHOQ-UHFFFAOYSA-N 0.000 description 1
- 239000000113 methacrylic resin Substances 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 150000004866 oxadiazoles Chemical class 0.000 description 1
- 150000007978 oxazole derivatives Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 125000001791 phenazinyl group Chemical class C1(=CC=CC2=NC3=CC=CC=C3N=C12)* 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 208000017983 photosensitivity disease Diseases 0.000 description 1
- 231100000434 photosensitization Toxicity 0.000 description 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 125000002294 quinazolinyl group Chemical class N1=C(N=CC2=CC=CC=C12)* 0.000 description 1
- 238000001226 reprecipitation Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 150000003463 sulfur Chemical class 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229940042055 systemic antimycotics triazole derivative Drugs 0.000 description 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- AUHHYELHRWCWEZ-UHFFFAOYSA-N tetrachlorophthalic anhydride Chemical compound ClC1=C(Cl)C(Cl)=C2C(=O)OC(=O)C2=C1Cl AUHHYELHRWCWEZ-UHFFFAOYSA-N 0.000 description 1
- NLDYACGHTUPAQU-UHFFFAOYSA-N tetracyanoethylene Chemical group N#CC(C#N)=C(C#N)C#N NLDYACGHTUPAQU-UHFFFAOYSA-N 0.000 description 1
- PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical compound N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 description 1
- 150000004867 thiadiazoles Chemical class 0.000 description 1
- 150000007979 thiazole derivatives Chemical class 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 125000005259 triarylamine group Chemical group 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/043—Photoconductive layers characterised by having two or more layers or characterised by their composite structure
- G03G5/047—Photoconductive layers characterised by having two or more layers or characterised by their composite structure characterised by the charge-generation layers or charge transport layers
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/06—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
- G03G5/0664—Dyes
- G03G5/0696—Phthalocyanines
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
Description
〠ç£æ¥äžã®å©çšåé
æ¬çºæã¯æå
äœãäŸãã°é»ååçæå
äœã«é¢ã
ããã®ã§ããã ã åŸæ¥æè¡ åŸæ¥ãå¯èŠå ã«å æ床ãæããé»ååççšã®æ
å äœã¯è€åæ©ãããªã³ã¿ãŒçã«åºã䜿çšãããŠã
ãã ãã®ãããªé»ååçæå äœãšããŠã¯ãã»ã¬ã³ã
é žåäºéãç¡«åã«ãããŠã çã®ç¡æ©å å°é»æ§ç©è³ª
ãäž»æåãšããæå å±€ãèšããç¡æ©æå äœãåºã
䜿çšãããŠãããããããªããããã®ãããªç¡æ©
æå äœã¯è€åæ©çã®é»ååçæå äœãšããŠèŠæ±ã
ããå æ床ãç±å®å®æ§ãè湿æ§ãèä¹ æ§çã®ç¹æ§
ã«ãããŠå¿ ãããæºè¶³ã§ãããã®ã§ã¯ãªããäŸã
ã°ãã»ã¬ã³ã¯ç±ãæã§è§Šã€ããšãã®æçŽã®æ±ãç
ã«ããçµæ¶åãããããé»ååçæå äœãšããŠã®
äžèšç¹æ§ãå£åãæãããŸããç¡«åã«ãããŠã ã
çšããé»ååçæå äœã¯è湿床æ§ãèä¹ æ§ã«å£ã
é žåäºéãçšããé»ååçæå äœã¯èä¹ æ§ã«åé¡
ãããããŸããã»ã¬ã³ãç¡«åã«ãããŠã ã®é»åå
çæå äœã¯å ±ã«æ¯æ§ãæãã補é äžãåæ±ãäžã®
å¶çŽã倧ãããšããæ¬ ç¹ãããã ãã®ãããªç¡æ©å å°é»æ§ç©è³ªã®åé¡ç¹ãå æã
ãããã«ãçš®ã ã®ææ©ã®å å°é»æ§ç©è³ªãé»ååç
æå äœã®æå å±€ã«äœ¿çšããããšãè©Šã¿ãããè¿å¹Ž
掻çºã«ç 究ãéçºãè¡ãããŠãããäŸãã°ãç¹å ¬
æ50â10496å·å ¬å ±ã«ã¯ãããªââããã«ã«ã«
ããŸãŒã«ãšïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãª
ã¬ãã³ãšã®CTé¯äœïŒé»è·ç§»åé¯äœïŒãå«æãã
æå å±€ãæããææ©æå äœãèšèŒãããŠãããã
ããããã®æå äœãæ床åã³èä¹ æ§ã«ãããŠåå
ã§ãªãããã®ãããªæ¬ ç¹ãæ¹åããããã«ãæå
å±€ã«ãããŠããã€ãªã¢çºçæ©èœãšãã€ãªã¢èŒžéæ©
èœãšãç°ãªãç©è³ªã«åå¥ã«åæ ãããããšã«ã
ããæ床ãé«ããŠèä¹ æ§ã®å€§ããææ©æå äœãé
çºããè©Šã¿ããªãããŠããããã®ãããªããã°æ©
èœåé¢åã®é»ååçæå äœã«ãããŠã¯ãåæ©èœã
çºæ®ããç©è³ªãåºãç¯å²ã®ãã®ããéžæããããš
ãã§ããã®ã§ãä»»æã®ç¹æ§ãæããé»ååçæå
äœãæ¯èŒç容æã«åŸãããããã®ãããæ床ãé«
ããèä¹ æ§ã®å€§ããææ©æå äœãåŸãããããšã
æåŸ ãããŠããã ãã®ãããªæ©èœåé¢åã®é»ååçæå äœã®ãã€
ãªã¢çºçå±€ã«æå¹ãªãã€ãªã¢çºçç©è³ªãšããŠã¯ã
åŸæ¥æ°å€ãã®ç©è³ªãææ¡ãããŠãããç¡æ©ç©è³ªã
çšããäŸãšããŠã¯ãäŸãã°ç¹å ¬æ43â16198å·å ¬
å ±ã«èšèŒãããŠããããã«ç¡å®åœ¢ã»ã¬ã³ãæãã
ããããã®ç¡å®åœ¢ã»ã¬ã³ãå«æãããã€ãªã¢çºç
å±€ã¯ææ©ãã€ãªã¢èŒžéç©è³ªãå«æãããã€ãªã¢èŒž
éå±€ãšçµã¿åããããŠäœ¿çšãããããããããã®
ç¡å®åœ¢ã»ã¬ã³ãããªããã€ãªã¢çºçå±€ã¯ãäžèšã
ããããªç±çã«ããçµæ¶åããŠãã®ç¹æ§ãå£åã
ããšããåé¡ç¹ãããã ãŸããææ©ç©è³ªãäžèšã®ãã€ãªã¢çºçç©è³ªãšã
ãŠçšããäŸãšããŠã¯ãææ©ææãææ©é¡æãæã
ããããäŸãã°ããã¹ã¢ãŸååç©ãå«æããæå
å±€ãæãããã®ãšããŠã¯ãç¹éæ47â37543å·å ¬
å ±ãç¹éæ55â22834å·å ¬å ±ãç¹éæ54â79632å·
å ¬å ±ãç¹éæ56â116040å·å ¬å ±çã«ãããã§ã«ç¥
ãããŠãããããããªããããããã®å ¬ç¥ã®ãã¹
ã¢ãŸååç©ãçæ³¢é·è¥ããã¯äžæ³¢é·åã§ã¯æ¯èŒç
è¯å¥œãªæ床ã瀺ãããé·æ³¢é·åã§ã®æ床ãäœãã
é«ä¿¡é Œæ§ã®æåŸ ãããåå°äœã¬ãŒã¶ãŒå æºãçšã
ãã¬ãŒã¶ãŒããªã³ã¿ã«çšããããšã¯å°é£ã§ãã€
ãã çŸåšãåå°äœã¬ãŒã¶ãŒãšããŠåºç¯ã«çšããããŠ
ããã¬ãªãŠã âã¢ã«ãããŠã âãçŽ ïŒGaâAlâ
AsïŒç³»çºå çŽ åã¯ãçºæ¯æ³¢é·ã750nmçšåºŠä»¥äž
ã§ããããã®ãããªé·æ³¢é·å ã«é«æ床ã®é»ååç
æå äœãåŸãããã«ãåŸæ¥æ°å€ãã®æ€èšããªãã
ãŠãããäŸãã°ãå¯èŠå é åã«é«æ床ãæããã»
ã¬ã³ãç¡«åã«ãããŠã çã®æå ææã«ãæ°ãã«é·
æ³¢é·åããããã®å¢æå€ãæ·»å ããæ¹æ³ãèãã
ããããã»ã¬ã³ãç¡«åã«ãããŠã ã¯äžèšãããã
ã«æž©åºŠã湿床çã«å¯Ÿããèç°å¢æ§ãååã§ãªãã
æ¯æ§ããã€ãŠå®çšåã«ã¯åé¡ãããããŸããå€æ°
ç¥ãããŠããææ©ç³»å å°é»ææããäžèšãããã
ã«ãã®æ床ãéåžž700nm以äžã®å¯èŠå é åã«éå®
ãããããããé·æ³¢é·åã«ååãªæ床ãæããæ
æã¯å°ãªãã ãããã®ãã¡ã§ãææ©ç³»å å°é»ææã®äžã€ã§ã
ããã¿ãã·ã¢ãã³ç³»ååç©ã¯ãä»ã®ãã®ã«æ¯ã¹æ
å åãé·æ³¢é·åã«æ¡å€§ããŠããããšãç¥ãããŠã
ãããããŠãαåã®ãã¿ãã·ã¢ãã³ãçµæ¶åœ¢ã®å®
å®ãªÎ²åã®ãã¿ãã·ã¢ãã³ã«å€ããéçšã§åçš®çµ
æ¶åœ¢ã®ãã¿ãã·ã¢ãã³ãèŠåºãããŠãããããã
ã®å å°é»æ§ã瀺ããã¿ãã·ã¢ãã³ç³»ååç©ãšããŠ
ã¯ãäŸãã°ç¹å ¬æ49â4338å·å ¬å ±ã«èšèŒãããŠã
ãåç¡éå±ãã¿ãã·ã¢ãã³ã¯ãé·æ³¢é·åã«æ床
ãæãããã€ä»ã®çµæ¶åœ¢ã®ç¡éå±ãã¿ãã·ã¢ãã³
ãšæ¯ã¹ãŠãåªããç¹æ§ãæãããããŸã äžååã§
ããã ãŸãããã¿ãã·ã¢ãã³ç³»ååç©ãšããŠã¯ãäŸã
ã°ç¹éæ58â182639å·å ¬å ±ã«èšèŒãããŠããÏå
ç¡éå±ãã¿ãã·ã¢ãã³ãç¥ãããŠããããã®Ïå
ç¡éå±ãã¿ãã·ã¢ãã³ã¯ã第ïŒïŒå³ã«ç€ºããã
ã«ãCu Kαç¹æ§ïŒžç·ïŒæ³¢é·1.541â«ïŒïŒä»¥äžããã®
ç·ãCu KαïŒ1.541â«ïŒãšèšããïŒã«å¯Ÿãããã©
ãã¯è§åºŠ2Ξã¯7.6床ïŒ9.2床ïŒ16.8床ïŒ17.4床ïŒ20.4
床ïŒ20.9床ã«ããããããŒã¯ãæããããŸããèµ€
å€ç·åžåã¹ãã¯ãã«ã§ã¯ã700ã760cm-1ã®éã«
752±ïŒcm-1ãæã匷ãïŒæ¬ã®åžå垯ã1320ã
1340cm-1ã®éã«ïŒæ¬ã®ã»ãŒåã匷ãã®åžå垯ã
3288±ïŒcm-1ã«ç¹åŸŽçãªåžå垯ãããããããã
ãã®Ïåç¡éå±ãã¿ãã·ã¢ãã³ã¯ãαåç¡éå±ã
ã¿ãã·ã¢ãã³ãé£å¡©çã®ç£šç å©å€ããšãã¬ã³ã°ãª
ã³ãŒã«çã®äžæŽ»æ§ææ©æº¶å€ãšãšãã«50ã180âã
奜ãŸããã¯60ã130âã§ïŒã20æé湿åŒæ··ç·ŽããŠ
補é ããã®ã§ããã®è£œé æ¹æ³ãè€éã§é£ãããã
ã®ãããÏåãã¿ãã·ã¢ãã³ã§ãã€ãŠãã€äžå®ã®
çµæ¶åœ¢ãæãããã®ãåžžã«åŸãããšã¯ã§ãããã
ãããã€ãªã¢çºçç©è³ªãšããŠçšãããšãã®é»åå
çæå äœã®ç¹æ§ã¯å®å®æ§ãäžååã§ããããã®ã
ããã®Ïåç¡éå±ãã¿ãã·ã¢ãã³ã¯åèšïŒžåç¡é
å±ãã¿ãã·ã¢ãã³ã«æ¯ã¹ããšã補é ã®å®¹ææ§ãçµ
æ¶å®å®æ§åã³é»ååçæå äœã®ãã€ãªã¢çºçç©è³ª
ãšããŠçšãããããšãã®ç¹°ãè¿ã䜿çšã«å¯Ÿããé»
äœå®å®æ§ã«å£ãã ãšããã§ãææ©å å°é»æ§ç©è³ªãçšããå ¬ç¥ã®æ
å äœã¯éåžžãè² åž¯é»çšãšããŠäœ¿çšãããŠãããã
ã®çç±ã¯ãè² åž¯é»äœ¿çšã®å Žåã«ã¯ããã€ãªã¢ã®ã
ã¡ããŒã«ã®ç§»å床ã倧ããããšãããããŒã«èŒžé
æ§ã®ææã䜿çšã§ããå æ床çã®ç¹ã§æå©ã§ãã
ã®ã«å¯Ÿããé»å茞éæ§ã®ææã«ã¯åªããç¹æ§ãã
ã€ãã®ãã»ãšãã©ç¡ãããããã¯çºããæ§ãæã
ãã®ã§äœ¿çšã§ããªãããã§ããã ããããªããããã®ãããªè² 垯é»äœ¿çšã§ã¯ã次
ã®åŠãåé¡ãããããšãå€æããŠããã (1) è² ã®ã³ããæŸé»æã垯é»åšã«ããè² åž¯é»æ
ã«ãé°å²æ°äžã®ãªãŸã³çºçéãå€ããç°å¢æ¡ä»¶
ãæªåããããã®ãããæå äœè¡šé¢ã®æ質ã®å£
åãã垯é»ã«ããçããã€ãªã³æ§ç©è³ªã®æå äœ
è¡šé¢ãžã®ä»çãçããç¹°ãè¿ã䜿çšæã«é»äœäœ
äžãããããããç»åäžè¯ãç»åãã±ã®åå ãš
ãªããæå äœã®å¯¿åœã«ã圱é¿ããããŸããã³ã
ãæŸé»åšã®æŸé»ã¯ã€ã€ã®æ±ãçã«ãããæŸé»ã
ã©ãçºçãããããããç»åã ã©ãçããããš
ãããã (2) è² åž¯é»çšæå äœã®çŸåã«ã¯æ£æ¥µæ§ã®ãããŒã
å¿ èŠãšãªãããæ£æ¥µæ§ã®ãããŒã¯åŒ·ç£æ§äœãã€
ãªã¢ç²åã«å¯Ÿããæ©æŠåž¯é»ç³»åããã¿ãŠè£œé ã
å°é£ã§ããã ããã§ãææ©å å°é»æ§ç©è³ªãçšããæå äœãæ£
垯é»ã§äœ¿çšããããšãææ¡ãããŠãããäŸãã°ã
ã€ãªã¢çºçå±€äžã«ãã€ãªã¢èŒžéå±€ãç©å±€ãããã€
ãªã¢èŒžéå±€ãé»å茞éèœã®å€§ããç©è³ªã§åœ¢æãã
æå äœã¯ãæ£åž¯é»çšãšããŠäœ¿çšã§ããããããå
è¿°ããããã«ãé»å茞éæ§ã®ææã«ã¯åªããç¹æ§
ãæãããã®ãã»ãšãã©ç¡ãããããã¯ç°å¢çé
æ ®ãã䜿çšã§ããªãã®ã§ãäžè¿°ã®æ£åž¯é»çšæå äœ
ã¯å®çšçã§ãªããäŸãã°ããã€ãªã¢èŒžéå±€ã«é»å
茞éèœããããããããããªããããã«ãªã¬ãã³
ãå«æãããããšãè¡ãããŠãããããã®ç©è³ªã«
ã¯çºããæ§ãããããäžé©åœã§ãããä»æ¹ãããŒ
ã«èŒžéèœã®å€§ãããã€ãªã¢èŒžéå±€äžã«ãã€ãªã¢çº
çå±€ãç©å±€ããæ£åž¯é»çšæå äœãèãããããã
ããã§ã¯è¡šé¢åŽã«éåžžã«èããã€ãªã¢çºçå±€ãå
åšããããã«èå·æ§ã»èä¹ æ§ãç¹°ãè¿ã䜿çšæã®
æ床å®å®æ§çãæªããªããå®çšçãªå±€æ§æã§ã¯ãª
ãã ãŸããæ£åž¯é»çšæå äœãšããŠãç±³åœç¹èš±ç¬¬
3615414å·æ现æžã«ã¯ããã¢ããªãªãŠã å¡©ïŒãã€
ãªã¢çºçç©è³ªïŒãããªã«ãŒãããŒãïŒãã€ã³ããŒ
æš¹èïŒãšå ±æ¶é¯äœã圢æããããã«å«æãããã
ã®ã瀺ãããŠãããããããã®å ¬ç¥ã®æå äœã§
ã¯ãã¡ã¢ãªãŒçŸè±¡ã倧ããããŽãŒã¹ããçºçãæ
ããšããæ¬ ç¹ããããç±³åœç¹èš±ç¬¬3357989å·æ现
æžã«ãããã¿ãã·ã¢ãã³ãå«æããããæå äœã
瀺ãããŠãããããã¿ãã·ã¢ãã³ã¯çµæ¶åã«ãã€
ãŠç¹æ§ãå€åããŠããŸãäžã«ãçµæ¶åãå³å¯ã«å¶
埡ããå¿ èŠããããæŽã«çæ³¢é·æ床ãäžè¶³ããã€
ã¡ã¢ãªãŒçŸè±¡ã倧ãããå¯èŠå æ³¢é·åã®å æºãçš
ããè€åæ©ã«ã¯äžé©åœã§ããã äžèšã®å®æ ããåŸæ¥ã¯ãææ©å å°é»æ§ç©è³ªãçš
ããæå äœãæ£åž¯é»äœ¿çšããããšã¯å®çŸæ§ã«ä¹ã
ãããã®ããã«ãã€ã±ãè² åž¯é»çšãšããŠäœ¿çšãã
ãŠããã®ã§ããã ã çºæã®ç®ç æ¬çºæã®ç®çã¯ãåå°äœã¬ãŒã¶ãŒå çã®æ¯èŒç
é·æ³¢é·ã®å ã«ååãªæ床ãæãããã€æ£åž¯é»ã§å
äœå¯èœã§ãããç¹ã«ãªãŸã³çºçéçãå°ãªããŠç°
å¢æ¡ä»¶ãè¯å¥œã«ä¿ã€ããšãã§ããèå·æ§ãé»äœå®
å®æ§ãã¡ã¢ãªãŒç¹æ§ãæ®çé»äœç¹æ§ã«åªããæå
äœãæäŸããããšã«ããã ã çºæã®æ§æåã³ãã®äœçšå¹æ æ¬çºæã¯ããã€ãªã¢èŒžéç©è³ªåã³ãã€ã³ããŒç©
質ãå«æãããã€ãªã¢èŒžéå±€ãšããã€ãªã¢çºçç©
質åã³ãã€ã³ããŒç©è³ªãå«æãããã€ãªã¢çºçå±€
ãšããã®é ã«ç©å±€ãããŠããæå äœã«ãããŠã Cu Kα 1.541â«ã®ïŒžç·ã«å¯Ÿãããã©ãã¯è§åºŠ2Ξ
ïŒäœãã誀差ã¯2Ξ±0.2床ïŒã7.7床ïŒ9.3床ïŒ16.9
床ïŒ17.5床ïŒ22.4床ïŒ28.8床ã«äž»èŠãªããŒã¯ãæ
ããç·çµæ¶åæã¹ãã¯ãã«ãæãããã®ïŒžç·å
æã¹ãã¯ãã«ã®äžèšãã©ãã¯è§åºŠ9.3床ã®ããŒã¯
ã«å¯Ÿãããã©ãã¯è§åºŠ16.9床ã®ããŒã¯ã®åŒ·åºŠæ¯ã
0.8ã1.0ã§ããããã€ãäžèšãã©ãã¯è§åºŠ9.3床ã®
ããŒã¯ã«å¯Ÿãããã©ãã¯è§åºŠ22.4床åã³28.8床ã®
ããããã®ããŒã¯ã®åŒ·åºŠã0.4以äžã§ããããã€ã
700ã760cm-1ïŒ1320±ïŒcm-1åã³3288±ïŒcm-1ã«
ããŒã¯ãæããèµ€å€ç·åžåã¹ãã¯ãã«ãæãã
700ã760cm-1ã®åžå垯ã«ã¯ïŒæ¬ã®ããŒã¯ãããã
ãã®ãã¡752±ïŒcm-1ãæã匷ãç¡éå±ãã¿ãã·
ã¢ãã³ãåèšãã€ãªã¢çºçå±€ã«å«æãããæŽã«è©²
ãã€ãªã¢çºçå±€ã«ãäžèšäžè¬åŒããã§è¡šããã
ååç©ãšäžèšäžè¬åŒããã§è¡šããããååç©ãš
ã®å°ãªããšãäžæ¹ãå«æãããŠããããšãç¹åŸŽãš
ããæå äœã«ä¿ãã äžè¬åŒããïŒ ïŒäœãããã®äžè¬åŒäžã R1ïŒçœ®æè¥ããã¯æªçœ®æã®ã¢ãªãŒã«åºåã¯
眮æè¥ããã¯æªçœ®æã®è€çŽ ç°åºã R2ïŒæ°ŽçŽ ååã眮æè¥ããã¯æªçœ®æã®ã¢ã«
ãã«åºãåã¯çœ®æè¥ããã¯æªçœ®æã®ã¢ãªãŒ
ã«åºã  ïŒæ°ŽçŽ ååãããã²ã³ååãã¢ã«ãã«
åºã眮æã¢ããåºãã¢ã«ã³ãã·åºåã¯ã·ã¢
ãåºã ïœ ïŒïŒåã¯ïŒã®æŽæ°ãè¡šãããïŒ äžè¬åŒããïŒ ïŒäœãããã®äžè¬åŒäžãR1ïŒR2ïŒïŒžïŒïœã¯å
èšãããã®ãšåãã§ãããïŒ æ¬çºæã®æå äœã¯ããã€ãªã¢èŒžéå±€äžã«ãã€ãª
ã¢çºçå±€ãç©å±€ããããŠæ§æããç©å±€æ§é ã®ãã®
ã§ãããå°ãäžèšãå±€ãã¯ãåŸè¿°ããããã«ãã€
ãªã¢çºçç©è³ªïŒäžèšç¡éå±ãã¿ãã·ã¢ãã³ïŒåã³
ãã€ãªã¢èŒžéç©è³ªïŒäžè¬åŒããïŒããã§è¡šãã
ããååç©ïŒã䜵æããŠãããæå äœãç©å±€æ§é
ã®å Žåã¯äžèšãå±€ãããã€ãªã¢çºçå±€ã«è©²åœã
ãã æ¬çºæã®æå äœã®æå å±€ã¯ãäžè¿°ã®ãããªæ§æ
ãæããŠããã®ã§ãç¹ã«æ£åž¯é»ã§äœ¿çšããã®ã«å¥œ
é©ã§ããã ããããäžè¿°ã®æå äœã¯ãäžèšãå±€ãäžã«ãã€
ãªã¢çºçç©è³ªãšããŠäžèšã®ãã©ãã¯è§ã®äž»èŠããŒ
ã¯ãæããç¡éå±ãã¿ãã·ã¢ãã³ã䜿çšããŠãã
ã®ã§ãæå äœã®ç¹°ãè¿ã䜿çšæã®é»äœå®å®æ§ãè¯
ããªããã¡ã¢ãªãŒçŸè±¡ãå°ãªããæ®çé»äœãå°ãª
ããã€å®å®ãšãªãããã€ãã¿ãã·ã¢ãã³èªäœã®çµ
æ¶ãå®å®ã§ããããã®è£œé ã容æã§ãããããã«
å ãããã®ç¡éå±ãã¿ãã·ã¢ãã³ãé·æ³¢é·åã«é«
æ床ã瀺ãããšãããæ¬çºæã®æå äœã¯åå°äœã¬
ãŒã¶ãŒçã«å¥œé©ã§ããã ãŸããæ¬çºæã®æå äœã«ããã°ããã€ãªã¢çºç
ç©è³ªãšãã€ãªã¢èŒžéç©è³ªãšããã€ã³ããŒç©è³ªã§çµ
çããŠãªããå±€ãã䜿çšããŠãããããã®ãå±€ã
ãåãã«èšããããšã«ãããçš®ã ã®å©ç¹ãããã å³ã¡ãåèšãå±€ãå³ã¡ãã€ãªã¢çºçå±€ãäžå±€ã«
èšããããã«æ£åž¯é»çšãšããŠã®æ§æãšãªã€ãŠãã
ããããã§ã¯ãã€ãªã¢çºçå±€ãåãã«èšããããš
ã«ãã€ãŠæ¢è¿°ããåé¡ç¹ã§ããèå·æ§ãååæºè¶³
ããããšãã§ãããäŸãã°ãéåžžèããããåã
ïŒè² 垯é»äœ¿çšã§ã¯0.2ÎŒmçšåºŠïŒããããã€ãšåã
0.6ã10ÎŒmïŒå¥œãŸããã¯ïŒã8ÎŒmïŒã®åãã«ãã€
ãªã¢çºçå±€ãèšãããšãè¯å¥œãªèå·æ§ãèä¹ æ§å
ã³ç¹°ãè¿ã䜿çšæã®æ床å®å®æ§ãåŸãããšãã§ã
ãã ãŸããæ¬çºæã®æå äœã«ãããŠãåèšãå±€ãã®
ãã€ã³ããŒç©è³ªã®å«æéãé«ããã°ãæå äœè¡šé¢
ã®è匷床ãåäžããã¯ãªãŒãã³ã°çã®å·¥çšã«ãã
ãŠæå äœè¡šé¢ã®åããé²æ¢ã§ããèæ©èæ§ãèå·
æ§åã³ç¹°ãè¿ã䜿çšæã®æ床å®å®æ§ãåäžããã
ããšãå¯èœãšãªãã ããããªããããã®ãããªäžèšãå±€ããçšãã
æå äœã«ãããŠããå±€ããåãã«èšãããšããã€
ãªã¢çºçç©è³ªã®ã¿ãå«æãããå Žåã¯ããå±€ãã®
èåã倧ãããªãã«åŸãããå±€ãäžã®ãã€ãªã¢çº
çç©è³ªã®æ¿åºŠã¯çžå¯Ÿçã«äœäžãããã€æ£è² ã®ãã€
ãªã¢ã®ãã€ãªã¢çºçäœçœ®ããã®èŒžéè·é¢ã倧ãã
ãªãããšãããçµæãšããŠãã€ãªã¢ã®èŒžéèœãè
ãããäœäžããããŸãããå±€ãäžã®ãã€ã³ããŒç©
質ã®éãå¢ãããšããã€ãªã¢çºçç©è³ªã®æ¿åºŠã¯äœ
äžãããã€ãªã¢ã®èŒžéèœã¯äœäžããããã®ããã
æå å±€ã®æ床äœäžãæ®çé»äœã®äžæãã¡ã¢ãªãŒçŸ
象ã®å¢å€§ãç¹°ãè¿ã䜿çšæã®æ床äœäžåã³åž¯é»é»
äœã®äœäžãæãããšãšãªãã ããã«å¯Ÿããæ¬çºæã®æå äœã§ã¯ãåèšãå±€ã
äžã«ç¹å®ã®ãã€ãªã¢èŒžéç©è³ªãå ããŠããã®ã§ã
äžè¿°ã®åé¡ã®æè¡ç解決ãå¯èœãšãªããããã§ã
ç¹å®ã®ãã€ãªã¢èŒžéç©è³ªãšã¯ãåèšããäžè¬åŒ
ããã§è¡šããããååç©ïŒããã©ãŸã³ååç©ïŒ
ãšäžè¬åŒããã§è¡šããããååç©ïŒããã©ãŸã³
ååç©ïŒãšã®å°ãªããšãäžæ¹ã§ããã ãã®ããã«ç¹å®ã®ãã€ãªã¢èŒžéç©è³ªãéžæãã
ã®ã¯ãåèšãå±€ãå éšã«ãããŠããã€ãªã¢çºçç©
質ã§ããåèšã®ç¡éå±ãã¿ãã·ã¢ãã³ããåäžå±€
å ã®ãã€ãªã¢èŒžéç©è³ªãžã®ãã€ãªã¢æ³šå ¥ã«éžææ§
ããããšèããããããã§ããã å³ã¡ãæ¬çºæã®ãã€ãªã¢èŒžéç©è³ªãéžæãã
ã°ãã€ãªã³åããã³ã·ã€ã«ãæ¬çºæã®ç¡éå±ãã¿
ãã·ã¢ãã³ãšé©åããŠããçã®çç±ã§ãäžèšã®ã
ã€ãªã¢æ³šå ¥ãå¹ççã«è¡ãããã®ã§ããå±€ãã®è
åã倧ãããããŸããã€ã³ããŒç©è³ªã®æ¿åºŠãé«ã
ãŠãããå±€ãå ã§çºçãããã€ãªã¢ã®èŒžéèœã¯äœ
äžããããšãªããããåäžããåŸã€ãŠåžžã«è¯å¥œ
ãªãæ床ç¹æ§ãæ®çé»äœç¹æ§ãã¡ã¢ãªãŒç¹æ§ãç¹°
ãè¿ã䜿çšæã®æ床ç¹æ§åã³åž¯é»é»äœç¹æ§ã享å
ããããšãã§ããã ãŸããæ¬çºæã®ãã€ãªã¢èŒžéç©è³ªã¯ãããŒã«èŒž
éèœã«åªããŠããããããåèšãå±€ãäžã«å«æã
ããããšã«ãããæ£åž¯é»äœ¿çšã«å¥œé©ãªæå äœãåŸ
ãããšãã§ããã æ¬çºæã®æå äœãæ§æããåèšãå±€ãã«ãããŠ
ã¯ãç²ç¶ã®ãã€ãªã¢çºçç©è³ªãšãã€ãªã¢èŒžéç©è³ª
ãšããã€ã³ããŒç©è³ªã§çµçãããŠããïŒå³ã¡ãå±€
äžã«é¡æã®åœ¢ã§åæ£ãããŠããïŒã®ãããããã®
å Žåããå±€ãã®èå·æ§ãèä¹ æ§çãè¯å¥œãšãªãã
ã¡ã¢ãªãŒçŸè±¡ãå°ãªããæ®çé»äœãå®å®ãšãªãã äžèšãããå±€ãã®æ§é ããããã€ãªã¢èŒžéç©è³ª
ãšãã€ã³ããŒç©è³ªãšã®çžæº¶æ§ã¯æå å±€ã®ç¹æ§ã«åœ±
é¿ããããã®ç¹ãæ¬çºæã®ãã€ãªã¢èŒžéç©è³ªã¯äž
èšã®çžæº¶æ§ã«åªããŠããã ãŸããæ£åž¯é»äœ¿çšã®éã«ã¯ãè² åž¯é»äœ¿çšã®å Žå
ãšç°ãªãããªãŸã³çºçéãäœãæããããšãã§ã
ãããããã§ãå°éã®ãªãŸã³çºçã¯é¿ããããª
ããããããæ¬çºæã®é»è·èŒžéç©è³ªã«ã¯ããªãŸã³
åžçã«ããå£åãçãã«ãããåŸã€ãŠç»åãã±ã
ç»åæ¬ é¥ã¯çºçãé£ãã æŽã«ãæ¬çºæã®é»è·èŒžéç©è³ªã¯ãå®å šã§ç°å¢ç
ã«å¥œãŸãããååŠçã«ãå®å®ã§ããã 以äžè¿°ã¹ãŠããããã«ãæ¬çºæã«ãã€ãŠãæ£åž¯
é»äœ¿çšã«å¥œé©ãªæå äœã®æäŸãå¯èœãšãªãããã
ã«ããæ£åž¯é»äœ¿çšã®ç¹æã®ç¹åŸŽãçºæ®ã§ããåŸæ¥
æè¡ã®é ã§è¿°ã¹ãè² åž¯é»äœ¿çšã«äŒŽãåé¡ã解決ã
ãããšãã§ãããå³ã¡ããªãŸã³çºçéãäœãæ
ããç°å¢æ¡ä»¶ãè¯å¥œãªãã®ãšããããšãã§ããã
ãã«äŒŽãæŸé»é»æ¥µã®æ±ãã«ããæŸé»ã ã©ççš®ã ã®
åé¡ãåé¿ã§ãããŸãã補é 容æãªè² 極æ§ãããŒ
ã䜿çšã§ãããæŽã«ãæ©èœåé¢åã§ããããšã
ããé«æ床ãé«èä¹ æ§ã§ãã€ãŠãæ§æææã®éžæ
ã容æãšãªãã æ¬çºæã«äœ¿ãããç¡éå±ãã¿ãã·ã¢ãã³ã¯ãåŸ
æ¥ã®ç¡éå±ãã¿ãã·ã¢ãã³ïŒäŸãã°ã第ïŒïŒå³ã«
瀺ããÏåç¡éå±ãã¿ãã·ã¢ãã³ïŒã«ç¡ãç¹åŸŽç
ãªïŒžç·åæã¹ãã¯ãã«ãæãããå³ã¡ããã©ãã¯
è§åºŠ28.8床ã«ç¹åŸŽçãªããŒã¯ãæããããšã§ã
ããäŸãã°ãæ¬çºæã«äœ¿ãããç¡éå±ãã¿ãã·ã¢
ãã³ã瀺ãç·åæã¹ãã¯ãã«ã®äŸãšããŠã第ïŒ
å³ã«ç€ºããããªãã®ãæããããã ãŸããæ¬çºæã«äœ¿ãããç¡éå±ãã¿ãã·ã¢ãã³
ã¯ã第ïŒå³ã«ç€ºãããã«ã700ã760cm-1ã«ããŒã¯
ãæããèµ€å€ç·åžåã¹ãã¯ãã«ãæãã700ã760
cm-1ã®åžå垯ã«ã¯ïŒæ¬ã®ããŒã¯ãããããã®ãã¡
720±ïŒcm-1ãæã匷ãããšãç¹åŸŽã§ããã ãŸãã第ïŒå³ã®ç¡éå±ãã¿ãã·ã¢ãã³ã®å¯èŠã
è¿èµ€å€ç·åžåã¹ãã¯ãã«ã¯ç¬¬ïŒå³ã«å®ç·ã§ç€ºãã
ãã«ã770nm以äž790nmæªæºã«åžå極倧ãããã
ãšãæãŸãããç Žç·ã§ç€ºãÏåç¡éå±ãã¿ãã·ã¢
ãã³ã790ã820nmã«åžå極倧ãæã¡ãå€ãã¯çŽ
810nmã«åžå極倧ãæã€ãã®ãšç°ãªãã æ¬çºæã«ãããäžèšç¡éå±ãã¿ãã·ã¢ãã³ã補
é ããã«ã¯ãαåç¡éå±ãã¿ãã·ã¢ãã³ãçµæ¶è»¢
移ããã«ååãªæéæ¹æãããããããã¯æ©æ¢°ç
æªåïŒäŸãã°æ··ç·ŽïŒããã€ãŠããªã³ã°ããããšã«
ãã第ïŒå³ã®ç¡éå±ãã¿ãã·ã¢ãã³ãåŸãã€ãã§
ãã®ç¡éå±ãã¿ãã·ã¢ãã³ãããã©ãã€ãããã©
ã³çã®é極æ§æº¶å€ã«ããåæ£åŠççã®æº¶å€åŠçã
ããããšã«ãã第ïŒå³ã®ç¡éå±ãã¿ãã·ã¢ãã³ã
åŸããããæ¹æããããã¯æ··ç·Žããã€ãŠããªã³ã°
ããã«ã¯ãéåžžé¡æã®åæ£ãä¹³åãæ··åçã«çšã
ãããŠããåæ£ã¡ãã€ã¢ãäŸãã°ã¬ã©ã¹ããŒãºã
ã¹ããŒã«ããŒãºãã¢ã«ããããŒã«ãããªã³ãç³ç
ãçšãããããããããåæ£ã¡ãã€ã¢ã¯å¿ ããã
å¿ èŠãšãããã®ã§ãªãã磚ç å©å€ãçšããããã
ã®ç£šç å©å€ãšããŠã¯éåžžé¡æçšã«äœ¿çšãããŠãã
ãã®ãçšããããŠããããäŸãã°é£å¡©ãéçé žãœ
ãŒãããŒãç¡çãæããããããããããã®ç£šç
å©å€ãå¿ ãããå¿ èŠãšããªãã 第ïŒå³ã«ç€ºãç¡éå±ãã¿ãã·ã¢ãã³ã¯ãCu
KαïŒ1.541â«ïŒã®ïŒžç·ã«å¯Ÿãããã©ãã¯è§åºŠïŒäœ
ãã誀差ã¯2Ξ±0.2床ïŒ7.5床ïŒ9.1床ïŒ16.7床ïŒ
17.3床ïŒ22.3床ã«ããŒã¯ãæãããŸãããã®èµ€å€
ç·åæã¹ãã¯ãã«ã¯ã第ïŒå³ã®ããã«746cm-1ïŒ
700ã750cm-1ã®éã«ïŒã€ã®ããŒã¯ã1318cm-1ïŒ
1330cm-1ã®åŒ·åºŠã®çããããŒã¯ãããã æ¹æãæ··ç·Žã磚ç æã«æº¶åªãå¿ èŠãšããå Žåã«
ã¯ããããè¡ãããŠãããšãã®æž©åºŠã«ãããŠæ¶²ç¶
ã®ãã®ãããããã®ãããªãã®ã«ã¯ãäŸãã°ã¢ã«
ã³ãŒã«ç³»æº¶åªãå³ã¡ã°ãªã»ãªã³ããšãã¬ã³ã°ãªã³
ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«è¥ããã¯ããªãšãã¬
ã³ã°ãªã³ãŒã«ç³»æº¶å€ããšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡
ãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãš
ãŒãã«çã®ã»ããœã«ã系溶å€ãã±ãã³ç³»æº¶å€ããš
ã¹ãã«ã±ãã³ç³»æº¶å€çã®çŸ€ããéžã°ããïŒçš®é¡ä»¥
äžã®æº¶å€ãéžæããããšã奜ãŸããã äžèšçµæ¶è»¢ç§»å·¥çšã«ãããŠäœ¿çšãããè£ çœ®ãšã
ãŠä»£è¡šçãªãã®ãæãããšãäžè¬çãªæ¹æè£ çœ®ã
äŸãã°ãã¢ãããµãŒããã€ã¹ããŒã¶ãŒãã¢ãžã¿
ãŒãã¹ã¿ãŒã©ãŒããããã¯ããŒãããã³ããªãŒã
ããµãŒãããŒã«ãã«ããµã³ããã«ãã¢ãã©ã€ã¿ãŒ
çãããã äžèšã®ããã«ããŠè£œé ãããæ¬çºæã®ç¡éå±ã
ã¿ãã·ã¢ãã³ã®æ§è³ªã®åªããç¹ã¯ããã®è£œé æ³ã
å¿ ããã磚ç å©å€ãå¿ èŠãšããããã®ãããã®é€
å»ãå¿ èŠããªãããã«ã§ãããŸã枩床ã³ã³ãããŒ
ã«ãå³å¯ãªãã®ã§ãªããŠããããäŸãã°å®€æž©ã§ã
ããç容æã§ããããšã§ããããã®ç¹ã¯Ïåãã¿
ãã·ã¢ãã³ã®è£œé æ³ã磚ç å©å€ãå¿ èŠãšããå³å¯
ãªæž©åºŠã³ã³ãããŒã«ãå¿ èŠãšãããã®ãšã¯ç°ãª
ãããŸããæ¬çºæã®ç¡éå±ãã¿ãã·ã¢ãã³ã¯æ¥µã
ãŠçµæ¶åœ¢ãå®å®ã§ãããã¢ã»ãã³ãããã©ããã
ãã©ã³ããã«ãšã³ãé ¢é žãšãã«ãïŒïŒïŒâãžã¯ã
ããšã¿ã³çã®ææ©æº¶å€ã«æµžæŒ¬ããããäŸãã°200
âã®é°å²æ°äžã«50æé以äžæŸçœ®ããçã®èç±è©Šéš
ãè¡ã€ããããŸãããªã³ã°çã®æ©æ¢°çæªåãå ã
ãŠãä»ã®çµæ¶åœ¢ãžã®è»¢ç§»ãèµ·ããé£ããããã¯åŸ
æ¥ã®Ïåããã¯å¿è«åªããŠããïŒãã®ç¹ã¯ç¬¬ïŒå³
ã®ãã¿ãã·ã¢ãã³ãç¹ã«è¯å¥œã§ããïŒããã®ããš
ã¯ãæ¬çºæã®ç¡éå±ãã¿ãã·ã¢ãã³ã®è£œé ããã®
å質ã®ã¶ããå°ãªãããŠè¡ããããšãå¯èœã«ãã
äžèšã®ããšãšãšãã«æŽã«ãã®è£œé ã容æã«ãããš
ãšãã«ãé»ååçæå äœã«çšãããšãã®ç¹°ãè¿ã
䜿çšã®ãšãã®é»äœå®å®æ§çã®ç¹æ§ãåäžã§ããã æ¬çºæã«çšããäžèšç¡éå±ãã¿ãã·ã¢ãã³ã¯æ¬¡
ã®æ§é åŒãããªã€ãŠããããã®ç±ååŠçç¶æ ã§äž»
ãšããŠç¬¬ïŒå³ã®ãã®ãšç¬¬ïŒå³ã®ãã®ãšã«åããã
ãã 次ã«ãæ¬çºæã«ãããŠãã€ãªã¢èŒžéç©è³ªãšããŠ
䜿çšããåèšäžè¬åŒããã®ããã©ãŸã³ååç©ã
äŸç€ºãããšã次ã®æ§é åŒãæãããã®ãæããã
ãšãã§ããããããããããã«éå®ããããã®ã§
ã¯ãªããäœããããã©ãŸã³ååç©ã¯æ¬¡ã®äžè¬åŒã«
代ããŠç€ºããŠããã
ããã®ã§ããã ã åŸæ¥æè¡ åŸæ¥ãå¯èŠå ã«å æ床ãæããé»ååççšã®æ
å äœã¯è€åæ©ãããªã³ã¿ãŒçã«åºã䜿çšãããŠã
ãã ãã®ãããªé»ååçæå äœãšããŠã¯ãã»ã¬ã³ã
é žåäºéãç¡«åã«ãããŠã çã®ç¡æ©å å°é»æ§ç©è³ª
ãäž»æåãšããæå å±€ãèšããç¡æ©æå äœãåºã
䜿çšãããŠãããããããªããããã®ãããªç¡æ©
æå äœã¯è€åæ©çã®é»ååçæå äœãšããŠèŠæ±ã
ããå æ床ãç±å®å®æ§ãè湿æ§ãèä¹ æ§çã®ç¹æ§
ã«ãããŠå¿ ãããæºè¶³ã§ãããã®ã§ã¯ãªããäŸã
ã°ãã»ã¬ã³ã¯ç±ãæã§è§Šã€ããšãã®æçŽã®æ±ãç
ã«ããçµæ¶åãããããé»ååçæå äœãšããŠã®
äžèšç¹æ§ãå£åãæãããŸããç¡«åã«ãããŠã ã
çšããé»ååçæå äœã¯è湿床æ§ãèä¹ æ§ã«å£ã
é žåäºéãçšããé»ååçæå äœã¯èä¹ æ§ã«åé¡
ãããããŸããã»ã¬ã³ãç¡«åã«ãããŠã ã®é»åå
çæå äœã¯å ±ã«æ¯æ§ãæãã補é äžãåæ±ãäžã®
å¶çŽã倧ãããšããæ¬ ç¹ãããã ãã®ãããªç¡æ©å å°é»æ§ç©è³ªã®åé¡ç¹ãå æã
ãããã«ãçš®ã ã®ææ©ã®å å°é»æ§ç©è³ªãé»ååç
æå äœã®æå å±€ã«äœ¿çšããããšãè©Šã¿ãããè¿å¹Ž
掻çºã«ç 究ãéçºãè¡ãããŠãããäŸãã°ãç¹å ¬
æ50â10496å·å ¬å ±ã«ã¯ãããªââããã«ã«ã«
ããŸãŒã«ãšïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãª
ã¬ãã³ãšã®CTé¯äœïŒé»è·ç§»åé¯äœïŒãå«æãã
æå å±€ãæããææ©æå äœãèšèŒãããŠãããã
ããããã®æå äœãæ床åã³èä¹ æ§ã«ãããŠåå
ã§ãªãããã®ãããªæ¬ ç¹ãæ¹åããããã«ãæå
å±€ã«ãããŠããã€ãªã¢çºçæ©èœãšãã€ãªã¢èŒžéæ©
èœãšãç°ãªãç©è³ªã«åå¥ã«åæ ãããããšã«ã
ããæ床ãé«ããŠèä¹ æ§ã®å€§ããææ©æå äœãé
çºããè©Šã¿ããªãããŠããããã®ãããªããã°æ©
èœåé¢åã®é»ååçæå äœã«ãããŠã¯ãåæ©èœã
çºæ®ããç©è³ªãåºãç¯å²ã®ãã®ããéžæããããš
ãã§ããã®ã§ãä»»æã®ç¹æ§ãæããé»ååçæå
äœãæ¯èŒç容æã«åŸãããããã®ãããæ床ãé«
ããèä¹ æ§ã®å€§ããææ©æå äœãåŸãããããšã
æåŸ ãããŠããã ãã®ãããªæ©èœåé¢åã®é»ååçæå äœã®ãã€
ãªã¢çºçå±€ã«æå¹ãªãã€ãªã¢çºçç©è³ªãšããŠã¯ã
åŸæ¥æ°å€ãã®ç©è³ªãææ¡ãããŠãããç¡æ©ç©è³ªã
çšããäŸãšããŠã¯ãäŸãã°ç¹å ¬æ43â16198å·å ¬
å ±ã«èšèŒãããŠããããã«ç¡å®åœ¢ã»ã¬ã³ãæãã
ããããã®ç¡å®åœ¢ã»ã¬ã³ãå«æãããã€ãªã¢çºç
å±€ã¯ææ©ãã€ãªã¢èŒžéç©è³ªãå«æãããã€ãªã¢èŒž
éå±€ãšçµã¿åããããŠäœ¿çšãããããããããã®
ç¡å®åœ¢ã»ã¬ã³ãããªããã€ãªã¢çºçå±€ã¯ãäžèšã
ããããªç±çã«ããçµæ¶åããŠãã®ç¹æ§ãå£åã
ããšããåé¡ç¹ãããã ãŸããææ©ç©è³ªãäžèšã®ãã€ãªã¢çºçç©è³ªãšã
ãŠçšããäŸãšããŠã¯ãææ©ææãææ©é¡æãæã
ããããäŸãã°ããã¹ã¢ãŸååç©ãå«æããæå
å±€ãæãããã®ãšããŠã¯ãç¹éæ47â37543å·å ¬
å ±ãç¹éæ55â22834å·å ¬å ±ãç¹éæ54â79632å·
å ¬å ±ãç¹éæ56â116040å·å ¬å ±çã«ãããã§ã«ç¥
ãããŠãããããããªããããããã®å ¬ç¥ã®ãã¹
ã¢ãŸååç©ãçæ³¢é·è¥ããã¯äžæ³¢é·åã§ã¯æ¯èŒç
è¯å¥œãªæ床ã瀺ãããé·æ³¢é·åã§ã®æ床ãäœãã
é«ä¿¡é Œæ§ã®æåŸ ãããåå°äœã¬ãŒã¶ãŒå æºãçšã
ãã¬ãŒã¶ãŒããªã³ã¿ã«çšããããšã¯å°é£ã§ãã€
ãã çŸåšãåå°äœã¬ãŒã¶ãŒãšããŠåºç¯ã«çšããããŠ
ããã¬ãªãŠã âã¢ã«ãããŠã âãçŽ ïŒGaâAlâ
AsïŒç³»çºå çŽ åã¯ãçºæ¯æ³¢é·ã750nmçšåºŠä»¥äž
ã§ããããã®ãããªé·æ³¢é·å ã«é«æ床ã®é»ååç
æå äœãåŸãããã«ãåŸæ¥æ°å€ãã®æ€èšããªãã
ãŠãããäŸãã°ãå¯èŠå é åã«é«æ床ãæããã»
ã¬ã³ãç¡«åã«ãããŠã çã®æå ææã«ãæ°ãã«é·
æ³¢é·åããããã®å¢æå€ãæ·»å ããæ¹æ³ãèãã
ããããã»ã¬ã³ãç¡«åã«ãããŠã ã¯äžèšãããã
ã«æž©åºŠã湿床çã«å¯Ÿããèç°å¢æ§ãååã§ãªãã
æ¯æ§ããã€ãŠå®çšåã«ã¯åé¡ãããããŸããå€æ°
ç¥ãããŠããææ©ç³»å å°é»ææããäžèšãããã
ã«ãã®æ床ãéåžž700nm以äžã®å¯èŠå é åã«éå®
ãããããããé·æ³¢é·åã«ååãªæ床ãæããæ
æã¯å°ãªãã ãããã®ãã¡ã§ãææ©ç³»å å°é»ææã®äžã€ã§ã
ããã¿ãã·ã¢ãã³ç³»ååç©ã¯ãä»ã®ãã®ã«æ¯ã¹æ
å åãé·æ³¢é·åã«æ¡å€§ããŠããããšãç¥ãããŠã
ãããããŠãαåã®ãã¿ãã·ã¢ãã³ãçµæ¶åœ¢ã®å®
å®ãªÎ²åã®ãã¿ãã·ã¢ãã³ã«å€ããéçšã§åçš®çµ
æ¶åœ¢ã®ãã¿ãã·ã¢ãã³ãèŠåºãããŠãããããã
ã®å å°é»æ§ã瀺ããã¿ãã·ã¢ãã³ç³»ååç©ãšããŠ
ã¯ãäŸãã°ç¹å ¬æ49â4338å·å ¬å ±ã«èšèŒãããŠã
ãåç¡éå±ãã¿ãã·ã¢ãã³ã¯ãé·æ³¢é·åã«æ床
ãæãããã€ä»ã®çµæ¶åœ¢ã®ç¡éå±ãã¿ãã·ã¢ãã³
ãšæ¯ã¹ãŠãåªããç¹æ§ãæãããããŸã äžååã§
ããã ãŸãããã¿ãã·ã¢ãã³ç³»ååç©ãšããŠã¯ãäŸã
ã°ç¹éæ58â182639å·å ¬å ±ã«èšèŒãããŠããÏå
ç¡éå±ãã¿ãã·ã¢ãã³ãç¥ãããŠããããã®Ïå
ç¡éå±ãã¿ãã·ã¢ãã³ã¯ã第ïŒïŒå³ã«ç€ºããã
ã«ãCu Kαç¹æ§ïŒžç·ïŒæ³¢é·1.541â«ïŒïŒä»¥äžããã®
ç·ãCu KαïŒ1.541â«ïŒãšèšããïŒã«å¯Ÿãããã©
ãã¯è§åºŠ2Ξã¯7.6床ïŒ9.2床ïŒ16.8床ïŒ17.4床ïŒ20.4
床ïŒ20.9床ã«ããããããŒã¯ãæããããŸããèµ€
å€ç·åžåã¹ãã¯ãã«ã§ã¯ã700ã760cm-1ã®éã«
752±ïŒcm-1ãæã匷ãïŒæ¬ã®åžå垯ã1320ã
1340cm-1ã®éã«ïŒæ¬ã®ã»ãŒåã匷ãã®åžå垯ã
3288±ïŒcm-1ã«ç¹åŸŽçãªåžå垯ãããããããã
ãã®Ïåç¡éå±ãã¿ãã·ã¢ãã³ã¯ãαåç¡éå±ã
ã¿ãã·ã¢ãã³ãé£å¡©çã®ç£šç å©å€ããšãã¬ã³ã°ãª
ã³ãŒã«çã®äžæŽ»æ§ææ©æº¶å€ãšãšãã«50ã180âã
奜ãŸããã¯60ã130âã§ïŒã20æé湿åŒæ··ç·ŽããŠ
補é ããã®ã§ããã®è£œé æ¹æ³ãè€éã§é£ãããã
ã®ãããÏåãã¿ãã·ã¢ãã³ã§ãã€ãŠãã€äžå®ã®
çµæ¶åœ¢ãæãããã®ãåžžã«åŸãããšã¯ã§ãããã
ãããã€ãªã¢çºçç©è³ªãšããŠçšãããšãã®é»åå
çæå äœã®ç¹æ§ã¯å®å®æ§ãäžååã§ããããã®ã
ããã®Ïåç¡éå±ãã¿ãã·ã¢ãã³ã¯åèšïŒžåç¡é
å±ãã¿ãã·ã¢ãã³ã«æ¯ã¹ããšã補é ã®å®¹ææ§ãçµ
æ¶å®å®æ§åã³é»ååçæå äœã®ãã€ãªã¢çºçç©è³ª
ãšããŠçšãããããšãã®ç¹°ãè¿ã䜿çšã«å¯Ÿããé»
äœå®å®æ§ã«å£ãã ãšããã§ãææ©å å°é»æ§ç©è³ªãçšããå ¬ç¥ã®æ
å äœã¯éåžžãè² åž¯é»çšãšããŠäœ¿çšãããŠãããã
ã®çç±ã¯ãè² åž¯é»äœ¿çšã®å Žåã«ã¯ããã€ãªã¢ã®ã
ã¡ããŒã«ã®ç§»å床ã倧ããããšãããããŒã«èŒžé
æ§ã®ææã䜿çšã§ããå æ床çã®ç¹ã§æå©ã§ãã
ã®ã«å¯Ÿããé»å茞éæ§ã®ææã«ã¯åªããç¹æ§ãã
ã€ãã®ãã»ãšãã©ç¡ãããããã¯çºããæ§ãæã
ãã®ã§äœ¿çšã§ããªãããã§ããã ããããªããããã®ãããªè² 垯é»äœ¿çšã§ã¯ã次
ã®åŠãåé¡ãããããšãå€æããŠããã (1) è² ã®ã³ããæŸé»æã垯é»åšã«ããè² åž¯é»æ
ã«ãé°å²æ°äžã®ãªãŸã³çºçéãå€ããç°å¢æ¡ä»¶
ãæªåããããã®ãããæå äœè¡šé¢ã®æ質ã®å£
åãã垯é»ã«ããçããã€ãªã³æ§ç©è³ªã®æå äœ
è¡šé¢ãžã®ä»çãçããç¹°ãè¿ã䜿çšæã«é»äœäœ
äžãããããããç»åäžè¯ãç»åãã±ã®åå ãš
ãªããæå äœã®å¯¿åœã«ã圱é¿ããããŸããã³ã
ãæŸé»åšã®æŸé»ã¯ã€ã€ã®æ±ãçã«ãããæŸé»ã
ã©ãçºçãããããããç»åã ã©ãçããããš
ãããã (2) è² åž¯é»çšæå äœã®çŸåã«ã¯æ£æ¥µæ§ã®ãããŒã
å¿ èŠãšãªãããæ£æ¥µæ§ã®ãããŒã¯åŒ·ç£æ§äœãã€
ãªã¢ç²åã«å¯Ÿããæ©æŠåž¯é»ç³»åããã¿ãŠè£œé ã
å°é£ã§ããã ããã§ãææ©å å°é»æ§ç©è³ªãçšããæå äœãæ£
垯é»ã§äœ¿çšããããšãææ¡ãããŠãããäŸãã°ã
ã€ãªã¢çºçå±€äžã«ãã€ãªã¢èŒžéå±€ãç©å±€ãããã€
ãªã¢èŒžéå±€ãé»å茞éèœã®å€§ããç©è³ªã§åœ¢æãã
æå äœã¯ãæ£åž¯é»çšãšããŠäœ¿çšã§ããããããå
è¿°ããããã«ãé»å茞éæ§ã®ææã«ã¯åªããç¹æ§
ãæãããã®ãã»ãšãã©ç¡ãããããã¯ç°å¢çé
æ ®ãã䜿çšã§ããªãã®ã§ãäžè¿°ã®æ£åž¯é»çšæå äœ
ã¯å®çšçã§ãªããäŸãã°ããã€ãªã¢èŒžéå±€ã«é»å
茞éèœããããããããããªããããã«ãªã¬ãã³
ãå«æãããããšãè¡ãããŠãããããã®ç©è³ªã«
ã¯çºããæ§ãããããäžé©åœã§ãããä»æ¹ãããŒ
ã«èŒžéèœã®å€§ãããã€ãªã¢èŒžéå±€äžã«ãã€ãªã¢çº
çå±€ãç©å±€ããæ£åž¯é»çšæå äœãèãããããã
ããã§ã¯è¡šé¢åŽã«éåžžã«èããã€ãªã¢çºçå±€ãå
åšããããã«èå·æ§ã»èä¹ æ§ãç¹°ãè¿ã䜿çšæã®
æ床å®å®æ§çãæªããªããå®çšçãªå±€æ§æã§ã¯ãª
ãã ãŸããæ£åž¯é»çšæå äœãšããŠãç±³åœç¹èš±ç¬¬
3615414å·æ现æžã«ã¯ããã¢ããªãªãŠã å¡©ïŒãã€
ãªã¢çºçç©è³ªïŒãããªã«ãŒãããŒãïŒãã€ã³ããŒ
æš¹èïŒãšå ±æ¶é¯äœã圢æããããã«å«æãããã
ã®ã瀺ãããŠãããããããã®å ¬ç¥ã®æå äœã§
ã¯ãã¡ã¢ãªãŒçŸè±¡ã倧ããããŽãŒã¹ããçºçãæ
ããšããæ¬ ç¹ããããç±³åœç¹èš±ç¬¬3357989å·æ现
æžã«ãããã¿ãã·ã¢ãã³ãå«æããããæå äœã
瀺ãããŠãããããã¿ãã·ã¢ãã³ã¯çµæ¶åã«ãã€
ãŠç¹æ§ãå€åããŠããŸãäžã«ãçµæ¶åãå³å¯ã«å¶
埡ããå¿ èŠããããæŽã«çæ³¢é·æ床ãäžè¶³ããã€
ã¡ã¢ãªãŒçŸè±¡ã倧ãããå¯èŠå æ³¢é·åã®å æºãçš
ããè€åæ©ã«ã¯äžé©åœã§ããã äžèšã®å®æ ããåŸæ¥ã¯ãææ©å å°é»æ§ç©è³ªãçš
ããæå äœãæ£åž¯é»äœ¿çšããããšã¯å®çŸæ§ã«ä¹ã
ãããã®ããã«ãã€ã±ãè² åž¯é»çšãšããŠäœ¿çšãã
ãŠããã®ã§ããã ã çºæã®ç®ç æ¬çºæã®ç®çã¯ãåå°äœã¬ãŒã¶ãŒå çã®æ¯èŒç
é·æ³¢é·ã®å ã«ååãªæ床ãæãããã€æ£åž¯é»ã§å
äœå¯èœã§ãããç¹ã«ãªãŸã³çºçéçãå°ãªããŠç°
å¢æ¡ä»¶ãè¯å¥œã«ä¿ã€ããšãã§ããèå·æ§ãé»äœå®
å®æ§ãã¡ã¢ãªãŒç¹æ§ãæ®çé»äœç¹æ§ã«åªããæå
äœãæäŸããããšã«ããã ã çºæã®æ§æåã³ãã®äœçšå¹æ æ¬çºæã¯ããã€ãªã¢èŒžéç©è³ªåã³ãã€ã³ããŒç©
質ãå«æãããã€ãªã¢èŒžéå±€ãšããã€ãªã¢çºçç©
質åã³ãã€ã³ããŒç©è³ªãå«æãããã€ãªã¢çºçå±€
ãšããã®é ã«ç©å±€ãããŠããæå äœã«ãããŠã Cu Kα 1.541â«ã®ïŒžç·ã«å¯Ÿãããã©ãã¯è§åºŠ2Ξ
ïŒäœãã誀差ã¯2Ξ±0.2床ïŒã7.7床ïŒ9.3床ïŒ16.9
床ïŒ17.5床ïŒ22.4床ïŒ28.8床ã«äž»èŠãªããŒã¯ãæ
ããç·çµæ¶åæã¹ãã¯ãã«ãæãããã®ïŒžç·å
æã¹ãã¯ãã«ã®äžèšãã©ãã¯è§åºŠ9.3床ã®ããŒã¯
ã«å¯Ÿãããã©ãã¯è§åºŠ16.9床ã®ããŒã¯ã®åŒ·åºŠæ¯ã
0.8ã1.0ã§ããããã€ãäžèšãã©ãã¯è§åºŠ9.3床ã®
ããŒã¯ã«å¯Ÿãããã©ãã¯è§åºŠ22.4床åã³28.8床ã®
ããããã®ããŒã¯ã®åŒ·åºŠã0.4以äžã§ããããã€ã
700ã760cm-1ïŒ1320±ïŒcm-1åã³3288±ïŒcm-1ã«
ããŒã¯ãæããèµ€å€ç·åžåã¹ãã¯ãã«ãæãã
700ã760cm-1ã®åžå垯ã«ã¯ïŒæ¬ã®ããŒã¯ãããã
ãã®ãã¡752±ïŒcm-1ãæã匷ãç¡éå±ãã¿ãã·
ã¢ãã³ãåèšãã€ãªã¢çºçå±€ã«å«æãããæŽã«è©²
ãã€ãªã¢çºçå±€ã«ãäžèšäžè¬åŒããã§è¡šããã
ååç©ãšäžèšäžè¬åŒããã§è¡šããããååç©ãš
ã®å°ãªããšãäžæ¹ãå«æãããŠããããšãç¹åŸŽãš
ããæå äœã«ä¿ãã äžè¬åŒããïŒ ïŒäœãããã®äžè¬åŒäžã R1ïŒçœ®æè¥ããã¯æªçœ®æã®ã¢ãªãŒã«åºåã¯
眮æè¥ããã¯æªçœ®æã®è€çŽ ç°åºã R2ïŒæ°ŽçŽ ååã眮æè¥ããã¯æªçœ®æã®ã¢ã«
ãã«åºãåã¯çœ®æè¥ããã¯æªçœ®æã®ã¢ãªãŒ
ã«åºã  ïŒæ°ŽçŽ ååãããã²ã³ååãã¢ã«ãã«
åºã眮æã¢ããåºãã¢ã«ã³ãã·åºåã¯ã·ã¢
ãåºã ïœ ïŒïŒåã¯ïŒã®æŽæ°ãè¡šãããïŒ äžè¬åŒããïŒ ïŒäœãããã®äžè¬åŒäžãR1ïŒR2ïŒïŒžïŒïœã¯å
èšãããã®ãšåãã§ãããïŒ æ¬çºæã®æå äœã¯ããã€ãªã¢èŒžéå±€äžã«ãã€ãª
ã¢çºçå±€ãç©å±€ããããŠæ§æããç©å±€æ§é ã®ãã®
ã§ãããå°ãäžèšãå±€ãã¯ãåŸè¿°ããããã«ãã€
ãªã¢çºçç©è³ªïŒäžèšç¡éå±ãã¿ãã·ã¢ãã³ïŒåã³
ãã€ãªã¢èŒžéç©è³ªïŒäžè¬åŒããïŒããã§è¡šãã
ããååç©ïŒã䜵æããŠãããæå äœãç©å±€æ§é
ã®å Žåã¯äžèšãå±€ãããã€ãªã¢çºçå±€ã«è©²åœã
ãã æ¬çºæã®æå äœã®æå å±€ã¯ãäžè¿°ã®ãããªæ§æ
ãæããŠããã®ã§ãç¹ã«æ£åž¯é»ã§äœ¿çšããã®ã«å¥œ
é©ã§ããã ããããäžè¿°ã®æå äœã¯ãäžèšãå±€ãäžã«ãã€
ãªã¢çºçç©è³ªãšããŠäžèšã®ãã©ãã¯è§ã®äž»èŠããŒ
ã¯ãæããç¡éå±ãã¿ãã·ã¢ãã³ã䜿çšããŠãã
ã®ã§ãæå äœã®ç¹°ãè¿ã䜿çšæã®é»äœå®å®æ§ãè¯
ããªããã¡ã¢ãªãŒçŸè±¡ãå°ãªããæ®çé»äœãå°ãª
ããã€å®å®ãšãªãããã€ãã¿ãã·ã¢ãã³èªäœã®çµ
æ¶ãå®å®ã§ããããã®è£œé ã容æã§ãããããã«
å ãããã®ç¡éå±ãã¿ãã·ã¢ãã³ãé·æ³¢é·åã«é«
æ床ã瀺ãããšãããæ¬çºæã®æå äœã¯åå°äœã¬
ãŒã¶ãŒçã«å¥œé©ã§ããã ãŸããæ¬çºæã®æå äœã«ããã°ããã€ãªã¢çºç
ç©è³ªãšãã€ãªã¢èŒžéç©è³ªãšããã€ã³ããŒç©è³ªã§çµ
çããŠãªããå±€ãã䜿çšããŠãããããã®ãå±€ã
ãåãã«èšããããšã«ãããçš®ã ã®å©ç¹ãããã å³ã¡ãåèšãå±€ãå³ã¡ãã€ãªã¢çºçå±€ãäžå±€ã«
èšããããã«æ£åž¯é»çšãšããŠã®æ§æãšãªã€ãŠãã
ããããã§ã¯ãã€ãªã¢çºçå±€ãåãã«èšããããš
ã«ãã€ãŠæ¢è¿°ããåé¡ç¹ã§ããèå·æ§ãååæºè¶³
ããããšãã§ãããäŸãã°ãéåžžèããããåã
ïŒè² 垯é»äœ¿çšã§ã¯0.2ÎŒmçšåºŠïŒããããã€ãšåã
0.6ã10ÎŒmïŒå¥œãŸããã¯ïŒã8ÎŒmïŒã®åãã«ãã€
ãªã¢çºçå±€ãèšãããšãè¯å¥œãªèå·æ§ãèä¹ æ§å
ã³ç¹°ãè¿ã䜿çšæã®æ床å®å®æ§ãåŸãããšãã§ã
ãã ãŸããæ¬çºæã®æå äœã«ãããŠãåèšãå±€ãã®
ãã€ã³ããŒç©è³ªã®å«æéãé«ããã°ãæå äœè¡šé¢
ã®è匷床ãåäžããã¯ãªãŒãã³ã°çã®å·¥çšã«ãã
ãŠæå äœè¡šé¢ã®åããé²æ¢ã§ããèæ©èæ§ãèå·
æ§åã³ç¹°ãè¿ã䜿çšæã®æ床å®å®æ§ãåäžããã
ããšãå¯èœãšãªãã ããããªããããã®ãããªäžèšãå±€ããçšãã
æå äœã«ãããŠããå±€ããåãã«èšãããšããã€
ãªã¢çºçç©è³ªã®ã¿ãå«æãããå Žåã¯ããå±€ãã®
èåã倧ãããªãã«åŸãããå±€ãäžã®ãã€ãªã¢çº
çç©è³ªã®æ¿åºŠã¯çžå¯Ÿçã«äœäžãããã€æ£è² ã®ãã€
ãªã¢ã®ãã€ãªã¢çºçäœçœ®ããã®èŒžéè·é¢ã倧ãã
ãªãããšãããçµæãšããŠãã€ãªã¢ã®èŒžéèœãè
ãããäœäžããããŸãããå±€ãäžã®ãã€ã³ããŒç©
質ã®éãå¢ãããšããã€ãªã¢çºçç©è³ªã®æ¿åºŠã¯äœ
äžãããã€ãªã¢ã®èŒžéèœã¯äœäžããããã®ããã
æå å±€ã®æ床äœäžãæ®çé»äœã®äžæãã¡ã¢ãªãŒçŸ
象ã®å¢å€§ãç¹°ãè¿ã䜿çšæã®æ床äœäžåã³åž¯é»é»
äœã®äœäžãæãããšãšãªãã ããã«å¯Ÿããæ¬çºæã®æå äœã§ã¯ãåèšãå±€ã
äžã«ç¹å®ã®ãã€ãªã¢èŒžéç©è³ªãå ããŠããã®ã§ã
äžè¿°ã®åé¡ã®æè¡ç解決ãå¯èœãšãªããããã§ã
ç¹å®ã®ãã€ãªã¢èŒžéç©è³ªãšã¯ãåèšããäžè¬åŒ
ããã§è¡šããããååç©ïŒããã©ãŸã³ååç©ïŒ
ãšäžè¬åŒããã§è¡šããããååç©ïŒããã©ãŸã³
ååç©ïŒãšã®å°ãªããšãäžæ¹ã§ããã ãã®ããã«ç¹å®ã®ãã€ãªã¢èŒžéç©è³ªãéžæãã
ã®ã¯ãåèšãå±€ãå éšã«ãããŠããã€ãªã¢çºçç©
質ã§ããåèšã®ç¡éå±ãã¿ãã·ã¢ãã³ããåäžå±€
å ã®ãã€ãªã¢èŒžéç©è³ªãžã®ãã€ãªã¢æ³šå ¥ã«éžææ§
ããããšèããããããã§ããã å³ã¡ãæ¬çºæã®ãã€ãªã¢èŒžéç©è³ªãéžæãã
ã°ãã€ãªã³åããã³ã·ã€ã«ãæ¬çºæã®ç¡éå±ãã¿
ãã·ã¢ãã³ãšé©åããŠããçã®çç±ã§ãäžèšã®ã
ã€ãªã¢æ³šå ¥ãå¹ççã«è¡ãããã®ã§ããå±€ãã®è
åã倧ãããããŸããã€ã³ããŒç©è³ªã®æ¿åºŠãé«ã
ãŠãããå±€ãå ã§çºçãããã€ãªã¢ã®èŒžéèœã¯äœ
äžããããšãªããããåäžããåŸã€ãŠåžžã«è¯å¥œ
ãªãæ床ç¹æ§ãæ®çé»äœç¹æ§ãã¡ã¢ãªãŒç¹æ§ãç¹°
ãè¿ã䜿çšæã®æ床ç¹æ§åã³åž¯é»é»äœç¹æ§ã享å
ããããšãã§ããã ãŸããæ¬çºæã®ãã€ãªã¢èŒžéç©è³ªã¯ãããŒã«èŒž
éèœã«åªããŠããããããåèšãå±€ãäžã«å«æã
ããããšã«ãããæ£åž¯é»äœ¿çšã«å¥œé©ãªæå äœãåŸ
ãããšãã§ããã æ¬çºæã®æå äœãæ§æããåèšãå±€ãã«ãããŠ
ã¯ãç²ç¶ã®ãã€ãªã¢çºçç©è³ªãšãã€ãªã¢èŒžéç©è³ª
ãšããã€ã³ããŒç©è³ªã§çµçãããŠããïŒå³ã¡ãå±€
äžã«é¡æã®åœ¢ã§åæ£ãããŠããïŒã®ãããããã®
å Žåããå±€ãã®èå·æ§ãèä¹ æ§çãè¯å¥œãšãªãã
ã¡ã¢ãªãŒçŸè±¡ãå°ãªããæ®çé»äœãå®å®ãšãªãã äžèšãããå±€ãã®æ§é ããããã€ãªã¢èŒžéç©è³ª
ãšãã€ã³ããŒç©è³ªãšã®çžæº¶æ§ã¯æå å±€ã®ç¹æ§ã«åœ±
é¿ããããã®ç¹ãæ¬çºæã®ãã€ãªã¢èŒžéç©è³ªã¯äž
èšã®çžæº¶æ§ã«åªããŠããã ãŸããæ£åž¯é»äœ¿çšã®éã«ã¯ãè² åž¯é»äœ¿çšã®å Žå
ãšç°ãªãããªãŸã³çºçéãäœãæããããšãã§ã
ãããããã§ãå°éã®ãªãŸã³çºçã¯é¿ããããª
ããããããæ¬çºæã®é»è·èŒžéç©è³ªã«ã¯ããªãŸã³
åžçã«ããå£åãçãã«ãããåŸã€ãŠç»åãã±ã
ç»åæ¬ é¥ã¯çºçãé£ãã æŽã«ãæ¬çºæã®é»è·èŒžéç©è³ªã¯ãå®å šã§ç°å¢ç
ã«å¥œãŸãããååŠçã«ãå®å®ã§ããã 以äžè¿°ã¹ãŠããããã«ãæ¬çºæã«ãã€ãŠãæ£åž¯
é»äœ¿çšã«å¥œé©ãªæå äœã®æäŸãå¯èœãšãªãããã
ã«ããæ£åž¯é»äœ¿çšã®ç¹æã®ç¹åŸŽãçºæ®ã§ããåŸæ¥
æè¡ã®é ã§è¿°ã¹ãè² åž¯é»äœ¿çšã«äŒŽãåé¡ã解決ã
ãããšãã§ãããå³ã¡ããªãŸã³çºçéãäœãæ
ããç°å¢æ¡ä»¶ãè¯å¥œãªãã®ãšããããšãã§ããã
ãã«äŒŽãæŸé»é»æ¥µã®æ±ãã«ããæŸé»ã ã©ççš®ã ã®
åé¡ãåé¿ã§ãããŸãã補é 容æãªè² 極æ§ãããŒ
ã䜿çšã§ãããæŽã«ãæ©èœåé¢åã§ããããšã
ããé«æ床ãé«èä¹ æ§ã§ãã€ãŠãæ§æææã®éžæ
ã容æãšãªãã æ¬çºæã«äœ¿ãããç¡éå±ãã¿ãã·ã¢ãã³ã¯ãåŸ
æ¥ã®ç¡éå±ãã¿ãã·ã¢ãã³ïŒäŸãã°ã第ïŒïŒå³ã«
瀺ããÏåç¡éå±ãã¿ãã·ã¢ãã³ïŒã«ç¡ãç¹åŸŽç
ãªïŒžç·åæã¹ãã¯ãã«ãæãããå³ã¡ããã©ãã¯
è§åºŠ28.8床ã«ç¹åŸŽçãªããŒã¯ãæããããšã§ã
ããäŸãã°ãæ¬çºæã«äœ¿ãããç¡éå±ãã¿ãã·ã¢
ãã³ã瀺ãç·åæã¹ãã¯ãã«ã®äŸãšããŠã第ïŒ
å³ã«ç€ºããããªãã®ãæããããã ãŸããæ¬çºæã«äœ¿ãããç¡éå±ãã¿ãã·ã¢ãã³
ã¯ã第ïŒå³ã«ç€ºãããã«ã700ã760cm-1ã«ããŒã¯
ãæããèµ€å€ç·åžåã¹ãã¯ãã«ãæãã700ã760
cm-1ã®åžå垯ã«ã¯ïŒæ¬ã®ããŒã¯ãããããã®ãã¡
720±ïŒcm-1ãæã匷ãããšãç¹åŸŽã§ããã ãŸãã第ïŒå³ã®ç¡éå±ãã¿ãã·ã¢ãã³ã®å¯èŠã
è¿èµ€å€ç·åžåã¹ãã¯ãã«ã¯ç¬¬ïŒå³ã«å®ç·ã§ç€ºãã
ãã«ã770nm以äž790nmæªæºã«åžå極倧ãããã
ãšãæãŸãããç Žç·ã§ç€ºãÏåç¡éå±ãã¿ãã·ã¢
ãã³ã790ã820nmã«åžå極倧ãæã¡ãå€ãã¯çŽ
810nmã«åžå極倧ãæã€ãã®ãšç°ãªãã æ¬çºæã«ãããäžèšç¡éå±ãã¿ãã·ã¢ãã³ã補
é ããã«ã¯ãαåç¡éå±ãã¿ãã·ã¢ãã³ãçµæ¶è»¢
移ããã«ååãªæéæ¹æãããããããã¯æ©æ¢°ç
æªåïŒäŸãã°æ··ç·ŽïŒããã€ãŠããªã³ã°ããããšã«
ãã第ïŒå³ã®ç¡éå±ãã¿ãã·ã¢ãã³ãåŸãã€ãã§
ãã®ç¡éå±ãã¿ãã·ã¢ãã³ãããã©ãã€ãããã©
ã³çã®é極æ§æº¶å€ã«ããåæ£åŠççã®æº¶å€åŠçã
ããããšã«ãã第ïŒå³ã®ç¡éå±ãã¿ãã·ã¢ãã³ã
åŸããããæ¹æããããã¯æ··ç·Žããã€ãŠããªã³ã°
ããã«ã¯ãéåžžé¡æã®åæ£ãä¹³åãæ··åçã«çšã
ãããŠããåæ£ã¡ãã€ã¢ãäŸãã°ã¬ã©ã¹ããŒãºã
ã¹ããŒã«ããŒãºãã¢ã«ããããŒã«ãããªã³ãç³ç
ãçšãããããããããåæ£ã¡ãã€ã¢ã¯å¿ ããã
å¿ èŠãšãããã®ã§ãªãã磚ç å©å€ãçšããããã
ã®ç£šç å©å€ãšããŠã¯éåžžé¡æçšã«äœ¿çšãããŠãã
ãã®ãçšããããŠããããäŸãã°é£å¡©ãéçé žãœ
ãŒãããŒãç¡çãæããããããããããã®ç£šç
å©å€ãå¿ ãããå¿ èŠãšããªãã 第ïŒå³ã«ç€ºãç¡éå±ãã¿ãã·ã¢ãã³ã¯ãCu
KαïŒ1.541â«ïŒã®ïŒžç·ã«å¯Ÿãããã©ãã¯è§åºŠïŒäœ
ãã誀差ã¯2Ξ±0.2床ïŒ7.5床ïŒ9.1床ïŒ16.7床ïŒ
17.3床ïŒ22.3床ã«ããŒã¯ãæãããŸãããã®èµ€å€
ç·åæã¹ãã¯ãã«ã¯ã第ïŒå³ã®ããã«746cm-1ïŒ
700ã750cm-1ã®éã«ïŒã€ã®ããŒã¯ã1318cm-1ïŒ
1330cm-1ã®åŒ·åºŠã®çããããŒã¯ãããã æ¹æãæ··ç·Žã磚ç æã«æº¶åªãå¿ èŠãšããå Žåã«
ã¯ããããè¡ãããŠãããšãã®æž©åºŠã«ãããŠæ¶²ç¶
ã®ãã®ãããããã®ãããªãã®ã«ã¯ãäŸãã°ã¢ã«
ã³ãŒã«ç³»æº¶åªãå³ã¡ã°ãªã»ãªã³ããšãã¬ã³ã°ãªã³
ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«è¥ããã¯ããªãšãã¬
ã³ã°ãªã³ãŒã«ç³»æº¶å€ããšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡
ãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãš
ãŒãã«çã®ã»ããœã«ã系溶å€ãã±ãã³ç³»æº¶å€ããš
ã¹ãã«ã±ãã³ç³»æº¶å€çã®çŸ€ããéžã°ããïŒçš®é¡ä»¥
äžã®æº¶å€ãéžæããããšã奜ãŸããã äžèšçµæ¶è»¢ç§»å·¥çšã«ãããŠäœ¿çšãããè£ çœ®ãšã
ãŠä»£è¡šçãªãã®ãæãããšãäžè¬çãªæ¹æè£ çœ®ã
äŸãã°ãã¢ãããµãŒããã€ã¹ããŒã¶ãŒãã¢ãžã¿
ãŒãã¹ã¿ãŒã©ãŒããããã¯ããŒãããã³ããªãŒã
ããµãŒãããŒã«ãã«ããµã³ããã«ãã¢ãã©ã€ã¿ãŒ
çãããã äžèšã®ããã«ããŠè£œé ãããæ¬çºæã®ç¡éå±ã
ã¿ãã·ã¢ãã³ã®æ§è³ªã®åªããç¹ã¯ããã®è£œé æ³ã
å¿ ããã磚ç å©å€ãå¿ èŠãšããããã®ãããã®é€
å»ãå¿ èŠããªãããã«ã§ãããŸã枩床ã³ã³ãããŒ
ã«ãå³å¯ãªãã®ã§ãªããŠããããäŸãã°å®€æž©ã§ã
ããç容æã§ããããšã§ããããã®ç¹ã¯Ïåãã¿
ãã·ã¢ãã³ã®è£œé æ³ã磚ç å©å€ãå¿ èŠãšããå³å¯
ãªæž©åºŠã³ã³ãããŒã«ãå¿ èŠãšãããã®ãšã¯ç°ãª
ãããŸããæ¬çºæã®ç¡éå±ãã¿ãã·ã¢ãã³ã¯æ¥µã
ãŠçµæ¶åœ¢ãå®å®ã§ãããã¢ã»ãã³ãããã©ããã
ãã©ã³ããã«ãšã³ãé ¢é žãšãã«ãïŒïŒïŒâãžã¯ã
ããšã¿ã³çã®ææ©æº¶å€ã«æµžæŒ¬ããããäŸãã°200
âã®é°å²æ°äžã«50æé以äžæŸçœ®ããçã®èç±è©Šéš
ãè¡ã€ããããŸãããªã³ã°çã®æ©æ¢°çæªåãå ã
ãŠãä»ã®çµæ¶åœ¢ãžã®è»¢ç§»ãèµ·ããé£ããããã¯åŸ
æ¥ã®Ïåããã¯å¿è«åªããŠããïŒãã®ç¹ã¯ç¬¬ïŒå³
ã®ãã¿ãã·ã¢ãã³ãç¹ã«è¯å¥œã§ããïŒããã®ããš
ã¯ãæ¬çºæã®ç¡éå±ãã¿ãã·ã¢ãã³ã®è£œé ããã®
å質ã®ã¶ããå°ãªãããŠè¡ããããšãå¯èœã«ãã
äžèšã®ããšãšãšãã«æŽã«ãã®è£œé ã容æã«ãããš
ãšãã«ãé»ååçæå äœã«çšãããšãã®ç¹°ãè¿ã
䜿çšã®ãšãã®é»äœå®å®æ§çã®ç¹æ§ãåäžã§ããã æ¬çºæã«çšããäžèšç¡éå±ãã¿ãã·ã¢ãã³ã¯æ¬¡
ã®æ§é åŒãããªã€ãŠããããã®ç±ååŠçç¶æ ã§äž»
ãšããŠç¬¬ïŒå³ã®ãã®ãšç¬¬ïŒå³ã®ãã®ãšã«åããã
ãã 次ã«ãæ¬çºæã«ãããŠãã€ãªã¢èŒžéç©è³ªãšããŠ
䜿çšããåèšäžè¬åŒããã®ããã©ãŸã³ååç©ã
äŸç€ºãããšã次ã®æ§é åŒãæãããã®ãæããã
ãšãã§ããããããããããã«éå®ããããã®ã§
ã¯ãªããäœããããã©ãŸã³ååç©ã¯æ¬¡ã®äžè¬åŒã«
代ããŠç€ºããŠããã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãŸããåèšäžè¬åŒããã®ããã©ãŸã³ååç©ã
äŸç€ºãããšã次ã®æ§é åŒã§ç€ºããããã®ãæãã
ããããããããããã«éå®ããããã®ã§ã¯ãª
ãã
äŸç€ºãããšã次ã®æ§é åŒã§ç€ºããããã®ãæãã
ããããããããããã«éå®ããããã®ã§ã¯ãª
ãã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
æ¬çºæã«ãããŠãåè¿°ããç¡éå±ãã¿ãã·ã¢ã
ã³ãšå ±ã«ãä»ã®ãã€ãªã¢çºçç©è³ªã®äžçš®åã¯äºçš®
以äžã䜵çšããŠãå·®ãæ¯ããªãã䜵çšã§ãããã€
ãªã¢çºçç©è³ªãšããŠã¯ãäŸãã°Î±åãβåãγ
åãÏåãÏâ²åãηåãηâ²åã®ç¡éå±ãã¿ãã·ã¢
ãã³ãæããããããŸããäžèšä»¥å€ã®ãã¿ãã·ã¢
ãã³é¡æãã¢ãŸé¡æãã¢ã³ãã©ããã³é¡æãããª
ã¬ã³é¡æãå€ç°ããã³é¡æãã¹ã¯ã¢ãªãã¯é žã¡ã
ã³é¡æçãæããããã ã¢ãŸé¡æãšããŠã¯ãäŸãã°ä»¥äžã®ãã®ãæãã
ããã ïŒâïŒïŒ âïŒïŒ®âAr1âCHïŒCHâAr2âïŒïŒ®â ïŒâïŒïŒ âïŒïŒ®âAr1âCHïŒCHâAr2âCHïŒCHâ
Ar3âïŒïŒ®â ïŒâïŒïŒ âïŒïŒ®âAr1âïŒïŒ®âAr2âïŒïŒ®â ïŒâïŒïŒ âïŒïŒ®âAr1âïŒïŒ®âAr2âïŒïŒ®âAr3â
ïŒïŒ®â ãäœããäžèšåäžè¬åŒäžã Ar1ïŒAr2åã³Ar3ïŒããããã眮æè¥ããã¯æª
眮æã®ççŽ ç°åŒè³éŠæç°åºã R3ïŒR4ïŒR5åã³R6ïŒãããããé»ååžåŒæ§åº
åã¯æ°ŽçŽ ååã§ãã€ãŠãR3ãR6ã®å°ãªããš
ãïŒã€ã¯ã·ã¢ãåºçã®é»ååžåŒæ§åºã ïŒ
ã³ãšå ±ã«ãä»ã®ãã€ãªã¢çºçç©è³ªã®äžçš®åã¯äºçš®
以äžã䜵çšããŠãå·®ãæ¯ããªãã䜵çšã§ãããã€
ãªã¢çºçç©è³ªãšããŠã¯ãäŸãã°Î±åãβåãγ
åãÏåãÏâ²åãηåãηâ²åã®ç¡éå±ãã¿ãã·ã¢
ãã³ãæããããããŸããäžèšä»¥å€ã®ãã¿ãã·ã¢
ãã³é¡æãã¢ãŸé¡æãã¢ã³ãã©ããã³é¡æãããª
ã¬ã³é¡æãå€ç°ããã³é¡æãã¹ã¯ã¢ãªãã¯é žã¡ã
ã³é¡æçãæããããã ã¢ãŸé¡æãšããŠã¯ãäŸãã°ä»¥äžã®ãã®ãæãã
ããã ïŒâïŒïŒ âïŒïŒ®âAr1âCHïŒCHâAr2âïŒïŒ®â ïŒâïŒïŒ âïŒïŒ®âAr1âCHïŒCHâAr2âCHïŒCHâ
Ar3âïŒïŒ®â ïŒâïŒïŒ âïŒïŒ®âAr1âïŒïŒ®âAr2âïŒïŒ®â ïŒâïŒïŒ âïŒïŒ®âAr1âïŒïŒ®âAr2âïŒïŒ®âAr3â
ïŒïŒ®â ãäœããäžèšåäžè¬åŒäžã Ar1ïŒAr2åã³Ar3ïŒããããã眮æè¥ããã¯æª
眮æã®ççŽ ç°åŒè³éŠæç°åºã R3ïŒR4ïŒR5åã³R6ïŒãããããé»ååžåŒæ§åº
åã¯æ°ŽçŽ ååã§ãã€ãŠãR3ãR6ã®å°ãªããš
ãïŒã€ã¯ã·ã¢ãåºçã®é»ååžåŒæ§åºã ïŒ
ãåŒã
ãåŒã
ãåŒããŸãã¯
ãåŒã
ïŒïŒžã¯ãããããã·åºã
ãåŒãåã¯â
NHSO2âR10
ãäœããR8åã³R9ã¯ãããããæ°ŽçŽ åååã¯
眮æè¥ããã¯æªçœ®æã®ã¢ã«ãã«åºãR10ã¯çœ®æè¥
ããã¯æªçœ®æã®ã¢ã«ãã«åºåã¯çœ®æè¥ããã¯æªçœ®
æã®ã¢ãªãŒã«åºãã ã¯ãæ°ŽçŽ ååãããã²ã³ååã眮æè¥ããã¯
æªçœ®æã®ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã«ã«ããã·
ã«åºãã¹ã«ãåºã眮æè¥ããã¯æªçœ®æã®ã«ã«ãã¢
ã€ã«åºåã¯çœ®æè¥ããã¯æªçœ®æã®ã¹ã«ãã¢ã¢ã€ã«
åºïŒäœããïœãïŒä»¥äžã®ãšãã¯ãäºãã«ç°ãªãåº
ã§ãã€ãŠããããïŒã ã¯ã眮æè¥ããã¯æªçœ®æã®ççŽ ç°åŒè³éŠæç°
åã¯çœ®æè¥ããã¯æªçœ®æã®è€çŽ ç°åŒè³éŠæç°ãæ§
æããã«å¿ èŠãªåå矀ã R7ã¯ãæ°ŽçŽ ååã眮æè¥ããã¯æªçœ®æã®ã¢ã
ãåºã眮æè¥ããã¯æªçœ®æã®ã«ã«ãã¢ã€ã«åºãã«
ã«ããã·ã«åºåã¯ãã®ãšã¹ãã«åºã Ar4ã¯ã眮æè¥ããã¯æªçœ®æã®ã¢ãªãŒã«åºã ïœã¯ãïŒåã¯ïŒã®æŽæ°ã ïœã¯ãïŒãïŒã®æŽæ°ã§ãããïŒã ãŸãã次ã®äžè¬åŒãã矀ã®å€ç°ããã³é¡æã
ãã€ãªã¢çºçç©è³ªãšããŠäœ¿çšã§ããã äžè¬åŒããïŒ ïŒäœãããã®äžè¬åŒäžãXâ²ã¯ããã²ã³ååã
ãããåºãã·ã¢ãåºãã¢ã·ã«åºåã¯ã«ã«ããã·ã«
åºãè¡šãããïœã¯ïŒãïŒã®æŽæ°ãïœã¯ïŒãïŒã®æŽ
æ°ãè¡šãããïŒ æ¬çºæã«ãããŠã¯ãåèšãå±€ãäžã«ãããŠãå
èšããããã©ãŸã³ååç©ãšå ±ã«ã次ã®äžè¬åŒ
ããã®ãã©ãŸãªã³ååç©ã䜿çšå¯èœã§ããã äžè¬åŒããïŒ ãäœãããã®äžè¬åŒäžã ïœ ïŒïŒåã¯ïŒã R11ïŒR12åã³R13ïŒçœ®æè¥ããã¯æªçœ®æã®ã¢ãª
ãŒã«åºã R14åã³R15ïŒæ°ŽçŽ ååãççŽ ååæ°ïŒãïŒã®
ã¢ã«ãã«åºãåã¯çœ®æè¥ããã¯æªçœ®æã®ã¢ãª
ãŒã«åºè¥ããã¯ã¢ã©ã«ãã«åºïŒäœããR14å
ã³R15ã¯å ±ã«æ°ŽçŽ ååã§ããããšã¯ãªããïŒ
ãïŒã®ãšãã¯R14ã¯æ°ŽçŽ ååã§ã¯ãªããïŒã ãŸãããã€ãªã¢èŒžéç©è³ªãšããŠãäžèšäžè¬åŒ
ããïŒããã®ããã©ãŸã³ååç©ã䜵çšå¯èœã§ã
ãã äžè¬åŒããïŒ ãäœãããã®äžè¬åŒäžã R16ïŒã¡ãã«åºããšãã«åºãïŒâããããã·ãš
ãã«åºåã¯ïŒâã¯ãã«ãšãã«åºã R17ïŒã¡ãã«åºããšãã«åºããã³ãžã«åºåã¯ã
ãšãã«åºã R18ïŒã¡ãã«åºããšãã«åºããã³ãžã«åºåã¯ã
ãšãã«åºã瀺ããã äžè¬åŒããïŒ ãäœãããã®äžè¬åŒäžã R19ã¯çœ®æè¥ããã¯é眮æã®ãããã«åºïŒR20
ã¯çœ®æè¥ããã¯é眮æã®ã¢ã«ãã«åºãã¢ã©ã«ãã«
åºåã¯ã¢ãªãŒã«åºïŒR21ã¯æ°ŽçŽ ååãã¢ã«ãã«åº
åã¯ã¢ã«ã³ãã·åºïŒR22åã³R23ã¯çœ®æè¥ããã¯
é眮æã®ã¢ã«ãã«åºãã¢ã©ã«ãã«åºåã¯ã¢ãªãŒã«
åºãããªãäºãã«åäžã®è¥ããã¯ç°ãªãåºã瀺
ããã ãªããæ¬çºæã«ãããŠããã€ãªã¢èŒžéç©è³ªãšã
ãŠãåèšã®ããã©ãŸã³ååç©ãšå ±ã«ãåŽéã«çž®å
è³éŠç°åã¯è€çŽ ç°ãæããé«ååææ©åå°äœã䜿
çšããã°ããã®é«ååææ©åå°äœã玫å€ç·åžåã«
ãã€ãŠå ãã€ãªã¢ãçæããæ§è³ªãæããŠããŠã
å å¢æã«å¹æçã«å¯äžããããã®ãããæŸé»æ²ç·
ã®è£Ÿåãããããªããç¹ã«äœé»çé åã§ã®æ床ã
åäžããããã®çµæãå°é»æ§åã¯çµ¶çžæ§äžæåçŸ
åããã»ã¹ã«ãããŠãçŸå段éã§ãã€ã¢ã¹é»å§ã
å°å ããªããŠãã«ããªã®ãªãè¯å¥œãªã³ããŒç»åã
åŸãããšãã§ãããäžæåçŸåããã»ã¹ã«ãã
ãŠããã€ã¢ã¹é»å§ãå°å ãããšãããããããªã³
ãžçŸåã«ãã€ãŠç»å端éšã®é®®æ床ãäœäžãã滲ã¿
ãçããããäžèšé«ååææ©åå°äœã«ãã€ãŠãã
ããåé¡ã¯å°ãªããªãããŸããäžèšé«ååææ©å
å°äœã¯çŽ«å€ç·é åã®åžå 床ãé«ããŠå€§éšåã®çŽ«å€
å ãåžåãã玫å€å ã«å¯ŸããŠäžçš®ã®ãã€ã«ã¿ãŒå¹
æãæããã®ã§ãåèšããã©ãŸã³ååç©ã®å£åã
é²æ¢ããäœçšããããæå å±€ã®çŽ«å€å å®å®æ§ãè
ä¹ æ§ãåäžãããããšãã§ããã äžèšã®ãããªé«ååææ©åå°äœãšããŠã¯ãäŸã
ã°æ¬¡ã«äŸç€ºãããã®ãæããããšãã§ããããã
ãããããã«éå®ããããã®ã§ã¯ãªãã äžèšããé«ååææ©åå°äœã®ãã¡ããªââã
ãã«ã«ã«ããŸãŒã«åã¯ãã®èªå°äœãå¹æã倧ã§ã
ãã奜ãŸããçšããããããããããªââãã
ã«ã«ã«ããŸãŒã«èªå°äœãšã¯ããã®ç¹°ãè¿ãåäœã«
ãããå šéšåã¯äžéšã®ã«ã«ããŸãŒã«ç°ãçš®ã ã®çœ®
æåºãäŸãã°ã¢ã«ãã«åºããããåºãã¢ããåºã
ããããã·åºåã¯ããã²ã³ååã«ãã€ãŠçœ®æãã
ããã®ã§ããã ãŸããç©å±€æ§é ãæããæå äœã«ãããŠããã€
ãªã¢èŒžéå±€ã«çšãããã€ãªã¢èŒžéç©è³ªã¯ãåè¿°ã®
ããã©ãŸã³ååç©ã§ãã€ãŠãããããã€ãªã¢çºç
å±€ãšç°ãªããå¿ ããããããäž»æåãšãããã®ã§
ãªããŠããã å³ã¡ããªããµãŸãŒã«èªå°äœããªããµãžã¢ãŸãŒã«
èªå°äœããã¢ãŸãŒã«èªå°äœããã¢ãžã¢ãŸãŒã«èªå°
äœãããªã¢ãŸãŒã«èªå°äœãã€ãããŸãŒã«èªå°äœã
ã€ãããŸãã³èªå°äœãã€ãããŸãªãžã³èªå°äœãã
ã¹ã€ãããŸãªãžã³èªå°äœãã¹ããªã«ååç©ããã
ã©ãŸã³ååç©ããã©ãŸãªã³èªå°äœããªããµãŸãã³
èªå°äœããã³ãŸãã¢ãŸãŒã«èªå°äœããã³ãºã€ãã
ãŸãŒã«èªå°äœããããŸãªã³èªå°äœããã³ãŸãã©ã³
èªå°äœãã¢ã¯ãªãžã³èªå°äœãããšããžã³èªå°äœã
ã¢ããã¹ãã«ãã³èªå°äœãããªââããã«ã«ã«
ããŸãŒã«ãããªâïŒâããã«ãã¬ã³ãããªâïŒâ
ããã«ã¢ã³ãã©ã»ã³ãããªã¢ãªãŒã«ã¢ãã³èªå°
äœãããšãã¬ã³ãžã¢ãã³èªå°äœãã¹ãã«ãã³èªå°
äœãã«ã«ããŸãŒã«èªå°äœçããéžã°ããäžçš®åã¯
äºçš®ä»¥äžã§ãã€ãŠããã æ¬çºæã«åºã¥ãæå äœãäŸãã°é»ååçæå äœ
ã®æ§æã¯ãçš®ã ã®åœ¢æ ããšãåŸãã 第ïŒå³ã第ïŒå³ã«äžè¬çãªæ§æãäŸç€ºããã第
ïŒå³ã®æå äœã¯ãç©å±€æ§é ã®ãã®ã§ãã€ãŠãå°é»
æ§æ¯æäœïŒäžã«ããã€ãªã¢èŒžéç©è³ªããã€ã³ããŒ
ç©è³ªäžã«åæ£ããããã€ãªã¢èŒžéå±€ïŒãèšããã
ã®å±€ïŒã®äžã«ãåè¿°ã®ç¡éå±ãã¿ãã·ã¢ãã³ãšå
è¿°ã®ããã©ãŸã³ååç©ãšããã€ã³ããŒç©è³ªäžã«äž»
æåãšããŠå«æãããã€ãªã¢çºçå±€ïŒã圢æã
ãŠãæå å±€ïŒãæ§æããŠããã第ïŒå³ã®æå äœã¯
åçžæ§é ã®ãã®ã§ãã€ãŠãå°é»æ§æ¯æäœïŒäžã«ã
äžèšã®ç¡éå±ãã¿ãã·ã¢ãã³ãšãäžèšã®ããã©ãŸ
ã³ååç©ãšããã€ã³ããŒç©è³ªäžã«äž»æåãšããŠå«
æããå±€ïŒã圢æããŠãåå±€åã®æå å±€ïŒãšãã
ãã®ã§ããã 第ïŒå³ïŒç¬¬ïŒå³ã®æå äœã¯ããããã第ïŒå³ïŒ
第ïŒå³ã®å±€æ§æã«ãããŠãæå å±€ïŒãšå°é»æ§æ¯æ
äœïŒãšã®éã«äžéå±€ïŒãèšããå°é»æ§æ¯æäœïŒã®
ããªãŒãšã¬ã¯ããã³ã®æ³šå ¥ãå¹æçã«é²æ¢ããã
ãã«ãããã®ã§ãããäžéå±€ïŒãšããŠã¯ãäžèšã®
ãã€ã³ããŒæš¹èãšããŠèª¬æãããããªé«ååéå
äœãããªããã«ã¢ã«ã³ãŒã«ããšãã«ã»ã«ããŒã¹ã
ã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹çã®ææ©é«ååç©è³ª
åã¯é žåã¢ã«ãããŠã çããæããã®ãçšããã
ãã 第ïŒå³ã第ïŒå³ã«ãããŠãèå·æ§åäžçã®ãã
ã«æŽã«è¡šé¢ã«ä¿è·å±€ïŒèïŒã圢æããŠãããäŸã
ã°åææš¹è被èãã³ãŒãã€ã³ã°ããŠããã äžèšæ§æã®æå å±€ã圢æããå Žåã«ããããã€
ãªã¢çºçå±€ïŒåã¯å±€ïŒã¯ã次ã®åŠãæ¹æ³ã«ãã€ãŠ
èšããããšãã§ããã (ã€) ãã€ãªã¢çºçç©è³ªãé©åœãªæº¶å€ã«æº¶è§£ãã溶
液ãããã¯ããã«ãã€ã³ããŒãå ããŠæ··å溶解
ãã溶液ãå¡åžããæ¹æ³ã (ã) ãã€ãªã¢çºçç©è³ªãããŒã«ãã«ããã¢ãããµ
ãŒçã«ãã€ãŠåæ£åªäžã§åŸ®çŽ°ç²åãšããå¿ èŠã«
å¿ããŠãã€ã³ããŒãå ããŠæ··ååæ£ããŠåŸãã
ãåæ£æ¶²ãå¡åžããæ¹æ³ã ãããã®æ¹æ³ã«ãããŠè¶ é³æ³¢ã®äœçšäžã«ç²åã
åæ£ããããšãåäžåæ£ãå¯èœã«ãªãã ãã€ãªã¢çºçå±€ã®åœ¢æã«äœ¿çšããã溶å€ããã
ã¯åæ£åªãšããŠã¯ãïœâããã«ã¢ãã³ããžãšãã«
ã¢ãã³ããšãã¬ã³ãžã¢ãã³ãã€ãœãããããŒã«ã¢
ãã³ãããªãšã¿ããŒã«ã¢ãã³ãããªãšãã¬ã³ãžã¢
ãã³ãïŒïŒ®âãžã¡ãã«ãã«ã ã¢ãããã¢ã»ã
ã³ãã¡ãã«ãšãã«ã±ãã³ãã·ã¯ããããµãã³ãã
ã³ãŒã³ããã«ãšã³ããã·ã¬ã³ãã¯ãããã«ã ã
ïŒïŒïŒâãžã¯ãããšã¿ã³ããžã¯ããã¡ã¿ã³ããã
ã©ããããã©ã³ããžãªããµã³ãã¡ã¿ããŒã«ããšã¿
ããŒã«ãã€ãœãããããŒã«ãé ¢é žãšãã«ãé ¢é žã
ãã«ããžã¡ãã«ã¹ã«ããã·ãçãæããããšãã§
ãããæå å±€ã®åœ¢æã«ãã€ã³ããŒãçšããå Žå
ã«ããã®ãã€ã³ããŒãšããŠã¯ä»»æã®ãã®ãçšãã
ããšãã§ããããç¹ã«çæ°Žæ§ã§ãã€èªå°çãé«ã
é»æ°çµ¶çžæ§ã®ãã€ã«ã 圢æèœãæããé«ååéå
äœã奜ãŸãããããããéåäœãšããŠã¯ãäŸãã°
次ã®ãã®ãæããããšãã§ããããå¿è«ãããã«
éå®ããããã®ã§ã¯ãªãã ïœ ããªã«ãŒãããŒã ïœ ããªãšã¹ãã« ïœ ã¡ã¿ã¯ãªã«æš¹è ïœ ã¢ã¯ãªã«æš¹è ïœ ããªå¡©åããã« ïœ ããªå¡©åãããªãã³ ïœ ããªã¹ãã¬ã³ ïœ ããªããã«ã¢ã»ããŒã ïœ ã¹ãã¬ã³âãã¿ãžãšã³å ±éåäœ ïœ å¡©åããã«âé ¢é žããã«å ±éåäœ ïœ å¡©åããã«âé ¢é žããã«âç¡æ°Žãã¬ã€ã³é žå ±
éåäœ ïœ ã·ãªã³ã³æš¹è ïœ ã·ãªã³ã³âã¢ã«ãããæš¹è ïœ ããšããŒã«âãã«ã ã¢ã«ãããæš¹è ïœ ã¹ãã¬ã³âã¢ã«ãããæš¹è ïœ ããªââããã«ã«ã«ããŸãŒã« ïœ ããªããã«ããã©ãŒã« ãããã®ãã€ã³ããŒã¯ãåç¬ãããã¯ïŒçš®ä»¥äž
ã®æ··åç©ãšããŠçšããããšãã§ããã æ¬çºæã«åºã¥ãæå äœãæ§æãããå±€ãïŒç¬¬ïŒ
å³ïŒç¬¬ïŒå³ã®ãã€ãªã¢çºçå±€ïŒåã³ç¬¬ïŒå³ïŒç¬¬ïŒ
å³ã®åçžæ§é ã®æå å±€ïŒã®ãããããå«ãïŒã«ã
ããŠã¯ããã€ãªã¢çºçç©è³ªããã€ã³ããŒç©è³ªã«å¯Ÿ
ãããã€ãªã¢çºçç©è³ªïŒãã€ã³ããŒç©è³ªïŒïŒã
150ïŒ ïŒå³ã¡ããã€ã³ããŒç©è³ª100éééšã«å¯ŸãïŒ
ã150éééšãæãŸããã¯10ã100éééšïŒãšç¹å®
ã®ç¯å²ã§å«æããããã°ãæ®çé»äœåã³å容é»äœ
äœäžã®å°ãªãæ£åž¯é»çšæå äœãæäŸã§ãããäžèš
ç¯å²ãå€ããŠããã€ãªã¢çºçç©è³ªãå°ãªããšå æ
床ãæªããŠæ®çé»äœãå¢ãããŸãå€ããšå容é»äœ
ã®äœäžãå€ããªããã¡ã¢ãªãŒãå¢ãæãããŸãã
äžèšãå±€ãäžã®ãã€ãªã¢èŒžéç©è³ªã®å«æéãéèŠ
ã§ããããã€ãªã¢èŒžéç©è³ªïŒãã€ã³ããŒç©è³ªïŒ20
ã200ïŒ ïŒå³ã¡ããã€ã³ããŒç©è³ª100éééšã«å¯Ÿã
20ã200éééšãæãŸããã¯50ã120éééšïŒãšã
ãã®ãããããã®ç¯å²ã«ãã€ãŠæ®çé»äœãå°ãªã
ãã€å æ床ãè¯å¥œãšãªãããã€ãªã¢èŒžéç©è³ªã®æº¶
åªæº¶è§£æ§ãè¯å¥œã«ä¿æãããããã®ç¯å²ãå€ã
ãŠããã€ãªã¢èŒžéç©è³ªãå°ãªããšæ®çé»äœãå æ
床ãå£åãæããç»åäžè¯ãçœæç¹ããã±çãç
ãæãããŸãå€ããšæº¶åªæº¶è§£æ§ãæªããªãæãã
è匷床ãå°ãšãªãåŸåãããããã®ãã€ãªã¢èŒžé
ç©è³ªã®å«æéç¯å²ã¯ã第ïŒå³ïŒç¬¬ïŒå³ã®ãã€ãªã¢
茞éå±€ïŒã§ãåæ§ã§ãã€ãŠããã ãŸããäžèšãå±€ãã«ãããäžèšãã€ãªã¢çºçç©
質ãšäžèšãã€ãªã¢èŒžéç©è³ªãšã®å²åã¯ãäž¡ç©è³ªã®
ããããã®æ©èœãæå¹ã«çºæ®ãããäžã§ããã€ãª
ã¢çºçç©è³ªïŒãã€ãªã¢èŒžéç©è³ªã¯ééæ¯ã§ïŒïŒïŒ
0.2ïŒãïŒïŒïŒ10ïŒãšããã®ãæãŸãããïŒïŒïŒ
0.5ïŒãïŒïŒïŒïŒïŒãæŽã«ããããã®ç¯å²ããã
ã€ãªã¢çºçç©è³ªã®å²åãå°ãããšå æ床äžè¶³ãšãª
ãããŸããã®å²åã倧ãããšãã€ãªã¢èŒžéèœãäœ
äžãããããã¯ãæ床äžè¶³ãšãªãã äžèšãå±€ãããã€ãªã¢çºçå±€ã§ããå Žåããã€
ãªã¢çºçå±€ïŒã®åãã¯0.6ã10ÎŒmã§ããããšã奜
ãŸãããïŒã8ÎŒmã§ããã°æŽã«å¥œãŸããããã®å
ãã0.6ÎŒmæªæºã®å Žåã«ã¯ãç¹°ãè¿ã䜿çšæã«ã
ã€ãªã¢çºç局衚é¢ãçŸè±¡åã³ã¯ãªãŒãã³ã°çã®äœ¿
çšæ æ§ã«ããæ©æ¢°çãã¡ãŒãžãåããå±€ã®äžéšã
åããããç»åäžã«ã¯é»ã¹ãžãšãªã€ãŠè¡šãããŠã
ãŸãããšãããããŸãã0.6ÎŒmæªæºã§ã¯åŽã€ãŠæ
床äžè¶³ãšãªãæããäœãããã€ãªã¢çºçå±€ã®èå
ã10ÎŒmãè¶ ãããšãç±å±èµ·ãã€ãªã¢ã®çºçæ°ã
å¢å ããç°å¢æž©åºŠã®äžæã«äŒŽãªãå容é»äœãäœäž
ããã¡ã¢ãªãŒçŸè±¡ãå¢ããç»åäžã®æ¿åºŠäœäžãç
ãæããæŽã«ããã€ãªã¢çºçç©è³ªã®åžå端ããé·
æ³¢é·ã®å ãç §å°ããå Žåã«ã¯ãå ãã€ãªã¢ã¯é»è·
çºçå±€äžã®æäžéšè¿ãã§ãçºçããããã®å Žåã«
ã¯ãé»åã¯å±€äžãè¡šé¢ãŸã§ç§»åããªããã°ãªã
ããäžè¬ã«ååãªèŒžéèœãåŸããããªãåŸåãã
ããåŸã€ãŠãç¹°ãè¿ã䜿çšæã«ã¯æ®çé»äœã®äžæ
ãèµ·ããæããªãã ãŸããäžèšãå±€ããåå±€æ§é ã®æå å±€ã§ããå Ž
åãæå å±€ã®åãã¯10ã50ÎŒmã§ããããšã奜ãŸ
ããã15ã30ÎŒmã§ããã°æŽã«å¥œãŸããããã®è
åã15ÎŒmæªæºã®å Žåã¯ãèãããã«åž¯é»é»äœã
å°ãããªããèå·æ§ã«ãå£ãããŸããæå å±€ïŒã®
åãã50ÎŒmãè¶ãããšãããã€ãŠæ®çé»äœã¯äž
æããäžã«ãäžèšãããã€ãªã¢çºçå±€ãåããã
å Žåãšåæ§ã®çŸè±¡ãçºçããŠãååãªèŒžéèœãåŸ
ããããªãåŸåãçŸããããã®ããç¹°ãè¿ã䜿çš
æã«ã¯æ®çé»äœã®äžæãèµ·ãæããªãã ãŸãã第ïŒå³ïŒç¬¬ïŒå³ã®ãã€ãªã¢èŒžéå±€ïŒã®å
ã¿ã¯ïŒã50ÎŒmã奜ãŸããã¯ïŒã30ÎŒmã§ããã®ã
ããããã®åãã5ÎŒmæªæºã§ã¯èãããã«åž¯é»é»
äœãå°ãšãªãããŸã50ÎŒmãè¶ãããšåŽã€ãŠæ®ç
é»äœã倧ãããªãæãã ãŸãããã€ãªã¢çºçå±€ãšãã€ãªã¢èŒžéå±€ã®èå
æ¯ã¯ãïŒïŒïŒïŒã30ïŒã§ããã®ãæãŸããã äžèšãã€ãªã¢çºçç©è³ªãåæ£ããããŠæå å±€ã
圢æããå Žåã«ãããŠã¯ãåœè©²ãã€ãªã¢çºçç©è³ª
ã¯5ÎŒm以äžã0.1ÎŒm以äžã奜ãŸããã¯2ÎŒm以äžã
0.2ÎŒm以äžã®å¹³åç²åŸã®ç²ç²äœãšãããã®ã奜ãŸ
ãããããªãã¡ãç²åŸãäœã倧ãããšå±€äžãžã®å
æ£ãæªããªããšãšãã«ãç²åãè¡šé¢ã«äžéšçªåºã
ãŠè¡šé¢ã®å¹³æ»æ§ãæªããªããå Žåã«ãã€ãŠã¯ç²å
ã®çªåºéšåã§æŸé»ãçãããããããã¯ãããã«
ãããŒç²åãä»çããŠãããŒãã€ã«ãã³ã°çŸè±¡ã
çãæãããã€ãªã¢çºçç©è³ªãšããŠé·æ³¢é·å ïŒã
700nmïŒã«å¯ŸããŠæ床ãæãããã®ã¯ããã€ãªã¢
çºçç©è³ªã®äžã§ã®ç±å±èµ·ãã€ãªã¢ã®çºçã«ããè¡š
é¢é»è·ãäžåããããã€ãªã¢çºçç©è³ªã®ç²åŸã倧
ãããšãã®äžåå¹æã倧ãããšæããããåŸã€
ãŠãç²åŸã埮å°åããããšã«ãã€ãŠã¯ãããŠé«æµ
æåãé«æ床åãéæã§ããã äœããäžèšç²åŸãããŸãå°ãããšåŽã€ãŠåéã
æãå±€ã®æµæãäžæããããçµæ¶æ¬ é¥ãå¢ããŠæ
床åã³ç¹°ãè¿ãç¹æ§ãäœäžãããã垯é»èœãå°ã
ããªãããŸãã埮现åããäžã§éçãããããã
å¹³åç²åŸã®äžéã0.01ÎŒmãšããã®ãæãŸããã æŽã«ãäžèšæå äœå±€ã«ã¯æ床ã®åäžãæ®çé»äœ
ä¹è³å埩䜿çšæã®ç²åŽäœæžçãç®çãšããŠãäžçš®
åã¯äºçš®ä»¥äžã®é»åå容æ§ç©è³ªãå«æããããã
ãšãã§ãããããã«çšããããšã®ã§ããé»åå容
æ§ç©è³ªãšããŠã¯ãäŸãã°ç¡æ°Žã³ãã¯é žãç¡æ°Žãã¬
ã€ã³é žããžããã ç¡æ°Žã³ãã¯é žãç¡æ°Žãã¿ã«é žã
ããã©ã¯ãã«ç¡æ°Žãã¿ã«é žãããã©ããã ç¡æ°Žã
ã¿ã«é žãïŒâãããç¡æ°Žãã¿ã«é žãïŒâãããç¡
æ°Žãã¿ã«é žãç¡æ°Žããã¡ãªããé žãç¡æ°Žã¡ãªãã
é žãããã©ã·ã¢ããšãã¬ã³ãããã©ã·ã¢ããããž
ã¡ã¿ã³ãïœâãžããããã³ãŒã³ãïœâãžãããã
ã³ãŒã³ãïŒïŒïŒïŒïŒâããªããããã³ãŒã³ããã©
ããããã³ãŸãããªã«ããã¯ãªã«ã¯ãã©ã€ããã
ãã³ã¯ãã«ã€ãããã¯ãã©ãã«ããã«ããã«ããž
ã¯ãããžã·ã¢ããã©ãã³ãŸããã³ãã¢ã³ãã©ãã
ã³ããžãããã¢ã³ãã©ããã³ãïŒâãã«ãªã¬ããª
ãã³âããžã·ã¢ãã¡ãã¬ã³ããããžãããªã«ããã
ãªãããâïŒâãã«ãªã¬ããªãã³âããžã·ã¢ãã¡
ãã¬ã³ããããžãããªã«ãããã¯ãªã³é žãïœâã
ããå®æ¯éŠé žãïœâãããå®æ¯éŠé žãïŒïŒïŒâãž
ãããå®æ¯éŠé žããã³ã¿ãã«ãªãå®æ¯éŠé žãïŒâ
ããããµãªãã«é žãïŒïŒïŒâãžããããµãªãã«
é žããã¿ã«é žãã¡ãªããé žããã®ä»ã®é»å芪åå
ã®å€§ããååç©ãæããããšãã§ããããŸããé»
åå容æ§ç©è³ªã®æ·»å å²åã¯ãééæ¯ã§ãã€ãªã¢çº
çç©è³ªïŒé»åå容æ§ç©è³ªïŒ100ïŒ0.01ã200ã奜ãŸ
ããã¯100ïŒ0.1ã100ã§ããã ãªããäžè¿°ããæå å±€ãèšããã¹ãæ¯æäœïŒã¯
éå±æ¿ãéå±ãã©ã åã¯å°é»æ§ããªããŒãé žåã€
ã³ãžãŠã çã®å°é»æ§ååç©è¥ããã¯ã¢ã«ãããŠ
ã ããã©ãžãŠã ãéçã®éå±ããæãå°é»æ§èå±€
ããå¡åžãèžçãã©ãããŒãçã®æ段ã«ããã
çŽããã©ã¹ããã¯ãã€ã«ã çã®åºäœã«èšããŠæã
ãã®ãçšãããããæ¥çå±€æãã¯ããªã€ãŒå±€çãš
ããŠæ©èœããäžéå±€ãšããŠã¯ãäžèšã®ãã€ã³ããŒ
æš¹èãšããŠèª¬æãããããªé«ååéåäœãããªã
ãã«ã¢ã«ã³ãŒã«ããšãã«ã»ã«ããŒã¹ãã«ã«ããã·
ã¡ãã«ã»ã«ããŒã¹çã®ææ©é«ååç©è³ªåã¯é žåã¢
ã«ãããŠã çããæããã®ãçšããããã æ¬çºæã®æå äœã®å€§ããªç¹é·ã¯ãæ¬çºæã«ãã
ãŠçšããç¡éå±ãã¿ãã·ã¢ãã³ã®æå æ³¢é·åã®æ¥µ
倧å€ã770nm以äžã790nmæªæºã«ååšãããšãå
å°äœã¬ãŒã¶ãŒçšæå äœãšããŠæé©ã§ããããšãã
ã®ç¡éå±ãã¿ãã·ã¢ãã³ã¯äžèšããããã«æ¥µããŠ
çµæ¶åœ¢ãå®å®ã§ãããä»ã®çµæ¶åœ¢ãžã®è»¢ç§»ã¯èµ·ã
é£ãããšã§ããããã®ããšã¯åèšããæ¬çºæã«äœ¿
çšããç¡éå±ãã¿ãã·ã¢ãã³èªäœã®è£œé ãæ§è³ªã®
ã¿ãªãããé»ååçæå äœã補é ãããšãããã
ã®äœ¿çšæã«ã倧ããªé·æãšãªããã®ã§ããã æ¬çºæã®ä»ã®å€§ããªç¹é·ã¯ãäžèšç¡éå±ãã¿ã
ã·ã¢ãã³ãå«æããå±€äžã«ãäžèšç¡éå±ãã¿ãã·
ã¢ãã³ãšé©åæ§ã®ããç¹å®ã®é»è·èŒžéç©è³ªãšããŠ
ããã©ãŸã³ååç©ãå«æãããããšã§ããããã
ã«ããç¹ã«æ£åž¯é»äœ¿çšã«å¥œé©ãªæå äœã®æäŸãå¯
èœãšãªã€ãã®ã§ããã ã å®æœäŸ 以äžãæ¬çºæãå ·äœçãªå®æœäŸã«ã€ããŠãæ¯èŒ
äŸãåç §ããªãã詳现ã«èª¬æããã ãŸãã第ïŒå³ã第ïŒå³ã«ç€ºãç¹æ§ããã€ç¡éå±
ãã¿ãã·ã¢ãã³ååç©ïŒ¡ã第ïŒå³ã第ïŒå³ã«ç€ºã
ç¹æ§ããã€ç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒ¢ã®åæ
äŸåã³Ïåç¡éå±ãã¿ãã·ã¢ãã³ååç©ã®åæäŸ
ã瀺ãã ãåæäŸ ïŒã ãªããŠã ãã¿ãã·ã¢ãã³50ïœãïŒâã«ãããŠå
åæ¹æãã600mlã®æ¿ç¡«é žã«å ããã次ãã§ãã
ã®æ··åç©ã¯ãã®æž©åºŠã«ãããŠïŒæéæ¹æãããã
次ãã§ãã§ãã溶液ã¯ç²ãçŒçµãããã¬ã©ã¹æŒæ
ãéããŠæ¿ŸéãããŠãïŒãªããã«ã®æ°·ãšæ°Žã®äžãž
æ¹æããªããåŸã ã«æ³šå ¥ããããæ°æéæŸçœ®ãã
åŸã«ããã®æ··åç©ã¯æ¿ŸéãããåŸãããå¡ãã¯äž
æ§ã«ãªããŸã§æ°Žã§æŽæµãããã次ãã§ããã®å¡ã¯
æçµçã«ã¡ã¿ããŒã«ã§æ°åæŽæµããããã€ç©ºæ°äž
ã§ä¹Ÿç¥ãããããããã®ä¹Ÿç¥ãããç²æ«ã¯24æé
é£ç¶æœåºè£ 眮äžã§ã¢ã»ãã³ã«ãã€ãŠæœåºãããã
ã€ç©ºæ°äžã§ä¹Ÿç¥ãããããŠéãç²æ«ãšãªã€ãã äžèšã«ãããŠããªããŠã ã«å¯ŸããŠå¡©ã®æ®æž£ãä¿
蚌ããããã«æåºã¯å埩ãããããã®ããã«ããŠ
30.5ïœã®éãç²æ«ãåŸãããããã®åŸããããã®
ã¯ããã®ïŒžç·åæå³åœ¢ãããã§ã«åºçãããŠãã
è³æã«èšèŒãããŠããαåãã¿ãã·ã¢ãã³ååç©
ã®ïŒžç·åæå³åœ¢ãšäžèŽããŠããã ãã®ããã«ããŠåŸããããéå±ãå«ãŸãªãαå
ãã¿ãã·ã¢ãã³ååç©30ïœããçŽåŸ13ïŒ16ã€ã³ã
ã®ããŒã«ã§ååæºããããå 容ç©900mlã®ç£è£œã
ãŒã«ãã«äžã«ä»èŸŒã¿ãçŽ80rpmã§164æéããªã³
ã°ããŠç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒ¡ãåŸããã
ã®ååç©ã¯ç¬¬ïŒå³ã«ç€ºãç·åæã¹ãã¯ãã«ã瀺
ããã ãåæäŸ ïŒã åæäŸïŒã®ç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒ¡ãšã
ãã©ããããã©ã³ãïŒïŒïŒâãžã¯ãããšã¿ã³çã®
ææ©æº¶å€200mlãããŒã«ãã«äžã«å ãã24æéå
床ããªã³ã°ããããã®ããªã³ã°ããåŸã®åæ£æ¶²ã«
ã€ããŠææ©æº¶å€ã®é€å»åã³ä¹Ÿç¥ãè¡ããç¡éå±ã
ã¿ãã·ã¢ãã³ååç©B28.2ïœãåŸãããã®ååç©
ã¯ç¬¬ïŒå³ã«ç€ºãç·åæã¹ãã¯ãã«ã瀺ããã ãåæäŸ ïŒã αåç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒICI補ã¢ã
ã©ã€ããã¢ãŒã¹ããã«GSïŒããå ç±ãããžã¡ã
ã«ãã«ã ã¢ã«ãããã«ããïŒåæœåºããŠç²Ÿè£œã
ãããã®æäœã«ãã粟補ç©ã¯Î²åã«è»¢ç§»ããã次
ã«ããã®Î²åç¡éå±ãã¿ãã·ã¢ãã³ååç©ã®äžéš
åãæ¿ç¡«é žã«æº¶è§£ãããã®æº¶æ¶²ãæ°·æ°Žäžã«æ³šãã§
åæ²æŸ±ãããããšã«ãããαåã«è»¢ç§»ããããã
ã®åæ²æŸ±ç©ãã¢ã³ã¢ãã¢æ°Žãã¡ã¿ããŒã«çã§æŽæµ
åŸ10âã§ä¹Ÿç¥ããã次ã«ãäžèšã«ãã粟補ããα
åç¡éå±ãã¿ãã·ã¢ãã³ååç©ã磚ç å©å€åã³å
æ£å€ãšãšãã«ãµã³ããã«ã«å ¥ãã枩床100±20â
ã§15ã25æéæ··ç·Žããããã®æäœã«ããçµæ¶åœ¢ã
Ïåã«è»¢ç§»ããã®ã確èªåŸã容åšããåãåºãã
æ°Žåã³ã¡ã¿ããŒã«çã§ç£šç å©å€åã³åæ£å€ãåå
é€å»ããåŸã也ç¥ããŠãé®®æãªéå³ã垯ã³ãÏå
ç¡éå±ãã¿ãã·ã¢ãã³ã®éè²çµæ¶ãåŸãããã®ã
ã¿ãã·ã¢ãã³ã¯ã第ïŒïŒå³ã®ïŒžç·åæã¹ãã¯ãã«
ã瀺ããã å®æœäŸ ïŒãïŒ ã¢ã«ãããŠã ç®ãã©ãããŒãããããªãšã¹ãã«
ãã€ã«ã ããæãå°é»æ§æ¯æäœäžã«ãå¡©åããã«
âé ¢é žããã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœããšã¹ã¬
ãã¯MFâ10ãïŒç©æ°ŽååŠç€Ÿè£œïŒããæãåã
0.05ÎŒmã®äžéå±€ã圢æããã次ãã§ã第ïŒïŒå³
ã«ç€ºãããã€ãªã¢èŒžéç©è³ªãšãã€ã³ããŒæš¹èïŒã
ãªã«ãŒãããŒãïŒãã³ã©ã€ãâ1250ïŒãšãïŒïŒ
ïŒâãžã¯ãããšã¿ã³67mlã«æº¶ããã溶液ãåèšäž
éå±€äžã«å¡åžããŠãã€ãªã¢èŒžéå±€ã圢æããã次
ãã§ã第ïŒïŒå³ã«ç€ºããå¹³åç²åŸ1ÎŒmã®åãã€ãª
ã¢çºçç©è³ªåã³åãã€ãªã¢èŒžéç©è³ªãšãã€ã³ããŒ
æš¹èãšãïŒïŒïŒâãžã¯ãããšã¿ã³67mlã«å ããŠã
ãŒã«ãã«ã§12æéåæ£ããããŠåŸãããåæ£æ¶²ã
åèšãã€ãªã¢èŒžéå±€äžã«å¡åžä¹Ÿç¥ããŠãã€ãªã¢çº
çå±€ã圢æããåé»ååçæå äœãäœè£œããã ããããŠåŸãããé»ååçæå äœãéé»è©Šéšæ©
ãEPAâ8100åãïŒå·å£é»æ©è£œäœæ補ïŒã«è£ çãã
以äžã®ç¹æ§è©Šéšãè¡ã€ããå³ã¡ã垯é»åšã«ïŒ6kV
ã®é»å§ãå°å ããŠïŒç§éã³ããæŸé»ã«ããæå å±€
ã垯é»ããããåŸïŒç§éã®éæŸçœ®ãã次ãã§æå
局衚é¢ã«åå åšã«ããåå ããã780nmã®å ãç §
å°ããŠãæå å±€ã®è¡šé¢é»äœã1/2ã«æžè¡°ãããã
ã®ã«å¿ èŠãªé²å éãå³ã¡åæžé²å é1/2ãæ±ã
ãããŸããäžèšã³ããæŸé»ã«ãã垯é»æã®å容é»
äœVAåã³10uxã»secé²å åŸã®æ®çé»äœVRã«ã€
ããŠã®å€ã枬å®ããã ãŸããå®æœäŸã«ç€ºãããã®ãšåæ§ã®æå äœå±€ã
Alãã©ã äžã«åœ¢æããã¬ãŒã¶ãŒããŒã ããªã³ã¿
ãŒLPâ3010ïŒå°è¥¿å åçå·¥æ¥(æ ª)補ïŒæ¹é æ©ïŒåå°
äœã¬ãŒã¶ãŒå æºäœ¿çšïŒã«æèŒããç»åè©äŸ¡ãå®æœ
ããïŒäœããCDã¯ç»åæ¿åºŠãã¯è§£å床ã§ã
ããïŒ âïŒæ¿åºŠãååã«é«ãã解ååãéåžžã«è¯å¥œ ïŒCDâ§1.2ïŒïŒ²â§6.0ïŒ âïŒæ¿åºŠã解ååå ±è¯å¥œ ïŒ1.2ïŒCDâ§0.7ïŒ6.0ïŒïŒ²â§4.0ïŒ ÃïŒæ¿åºŠãäœãã解ååãååã§ãªãããã€ãŸ
ããã«ããªãçœåã¯é»æç¹ãè¡šãããã ãªããCDã¯ãµã¯ã©æ¿åºŠèšïŒModel PDAâ
65ïŒå°è¥¿å åçå·¥æ¥è£œïŒã«ãŠæž¬å®ããã¯ãµã¯ã©
æ¿åºŠèšïŒModel PDAâïŒïŒå°è¥¿å åçå·¥æ¥è£œïŒ
ã«ãŠæž¬å®ãããCDåã³ïŒ²å ±ãçœçŽã®æ¿åºŠã0.0ãš
ããåå°æ¿åºŠã枬å®ããŠè©äŸ¡ãè¡ã€ãã äœããã«ã€ããŠã®æž¬å®æ³ã¯å ·äœçã«ã¯æ¬¡ã®é
ãã§ãã€ããå³ã¡ãã¹ãªãã500ÎŒÃ20ÎŒã®ãã€ã¯
ããã³ã·ãã¡ãŒã¿ãŒã§è§£ååãã€ãŒãã枬å®ã
ãã解ååãã€ãŒãã®å€å®åºæºã¯ãäžèšã®åŒã30
ïŒ ä»¥äžã®ã¬ã¹ãã³ã¹ãæãã解ååãã€ãŒããã
å€å®ãããã³ããŒç»åã®ç»åéšæ¿åºŠãDcopy naxãé
ç»åéšã®æ¿åºŠãDcopy nioããªãªãžãã«åçš¿ã®ç»åéš
æ¿åºŠãDorig naxãéç»åéšã®æ¿åºŠãDorig nioãšãããšã ïŒDcopyïŒnaxâDcopyïŒnioïŒDcopyïŒnaxïŒDcopyïŒnioïŒ
ïŒïŒDorigïŒnaxâDorigïŒnioïŒDorigïŒnaxïŒDorigïŒnio
ïŒâ§30ïŒïŒ ïŒ ãã®çµæã«ããã°ãæ¬çºæã«åºãå®æœäŸïŒãïŒ
ã®è©Šæã¯ãããããè¯å¥œãªé»ååçç¹æ§ã瀺ãã
ãšãåãã ç¹ã«ãCGMãšããŠãæ¬çºæã®ç¡éå±ãã¿ãã·
ã¢ãã³ïŒ¢ã䜿çšããããšãåã³ãã€ãªã¢çºçå±€ã«
CTMãšããŠããã©ãŸã³ååç©ãããæ·»å ãã
ããšã¯ãããããæå äœã®ç¹æ§ã倧ããå·Šå³ãã
é«åž¯é»é»äœåã³ãã®å®å®æ§ãããããå æ床ã倧
ããåäžãããçã®æ£åž¯é»çšæå äœãšããŠã®é¡è
ãªçµæãåŸãããšãã§ããããŸããåå°äœã¬ãŒã¶
ãŒäœ¿çšã®ãã¹ãã§ããé«æ¿åºŠãé«è§£ååãåŸã
ããé·æ³¢é·æ床ãåäžããããšãæãããšãªã€
ãã å®æœäŸ ïŒãïŒ å®æœäŸïŒã«ãããŠããããã䜿çšããããã©ãŸ
ã³ååç©ãããã第ïŒïŒå³ã«ç€ºãããã©ãŸã³å
åç©ããã«å€ãããŸãã䜿çšãããã€ãªã¢çºç
ç©è³ªãç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒ¢ã«å€ãã以
å€ã¯åè¿°ãããšåæ§ã«ããŠãåé»ååçæå äœã
äœè£œããåæ§ã®è©Šéšãè¡ã€ããšããã第ïŒïŒå³ã«
瀺ãçµæãåŸãããã ãã®çµæãããæ¬çºæã«åºãå®æœäŸïŒãïŒã®è©Š
æã¯ããããè¯å¥œãªçµæã瀺ãã
眮æè¥ããã¯æªçœ®æã®ã¢ã«ãã«åºãR10ã¯çœ®æè¥
ããã¯æªçœ®æã®ã¢ã«ãã«åºåã¯çœ®æè¥ããã¯æªçœ®
æã®ã¢ãªãŒã«åºãã ã¯ãæ°ŽçŽ ååãããã²ã³ååã眮æè¥ããã¯
æªçœ®æã®ã¢ã«ãã«åºãã¢ã«ã³ãã·åºãã«ã«ããã·
ã«åºãã¹ã«ãåºã眮æè¥ããã¯æªçœ®æã®ã«ã«ãã¢
ã€ã«åºåã¯çœ®æè¥ããã¯æªçœ®æã®ã¹ã«ãã¢ã¢ã€ã«
åºïŒäœããïœãïŒä»¥äžã®ãšãã¯ãäºãã«ç°ãªãåº
ã§ãã€ãŠããããïŒã ã¯ã眮æè¥ããã¯æªçœ®æã®ççŽ ç°åŒè³éŠæç°
åã¯çœ®æè¥ããã¯æªçœ®æã®è€çŽ ç°åŒè³éŠæç°ãæ§
æããã«å¿ èŠãªåå矀ã R7ã¯ãæ°ŽçŽ ååã眮æè¥ããã¯æªçœ®æã®ã¢ã
ãåºã眮æè¥ããã¯æªçœ®æã®ã«ã«ãã¢ã€ã«åºãã«
ã«ããã·ã«åºåã¯ãã®ãšã¹ãã«åºã Ar4ã¯ã眮æè¥ããã¯æªçœ®æã®ã¢ãªãŒã«åºã ïœã¯ãïŒåã¯ïŒã®æŽæ°ã ïœã¯ãïŒãïŒã®æŽæ°ã§ãããïŒã ãŸãã次ã®äžè¬åŒãã矀ã®å€ç°ããã³é¡æã
ãã€ãªã¢çºçç©è³ªãšããŠäœ¿çšã§ããã äžè¬åŒããïŒ ïŒäœãããã®äžè¬åŒäžãXâ²ã¯ããã²ã³ååã
ãããåºãã·ã¢ãåºãã¢ã·ã«åºåã¯ã«ã«ããã·ã«
åºãè¡šãããïœã¯ïŒãïŒã®æŽæ°ãïœã¯ïŒãïŒã®æŽ
æ°ãè¡šãããïŒ æ¬çºæã«ãããŠã¯ãåèšãå±€ãäžã«ãããŠãå
èšããããã©ãŸã³ååç©ãšå ±ã«ã次ã®äžè¬åŒ
ããã®ãã©ãŸãªã³ååç©ã䜿çšå¯èœã§ããã äžè¬åŒããïŒ ãäœãããã®äžè¬åŒäžã ïœ ïŒïŒåã¯ïŒã R11ïŒR12åã³R13ïŒçœ®æè¥ããã¯æªçœ®æã®ã¢ãª
ãŒã«åºã R14åã³R15ïŒæ°ŽçŽ ååãççŽ ååæ°ïŒãïŒã®
ã¢ã«ãã«åºãåã¯çœ®æè¥ããã¯æªçœ®æã®ã¢ãª
ãŒã«åºè¥ããã¯ã¢ã©ã«ãã«åºïŒäœããR14å
ã³R15ã¯å ±ã«æ°ŽçŽ ååã§ããããšã¯ãªããïŒ
ãïŒã®ãšãã¯R14ã¯æ°ŽçŽ ååã§ã¯ãªããïŒã ãŸãããã€ãªã¢èŒžéç©è³ªãšããŠãäžèšäžè¬åŒ
ããïŒããã®ããã©ãŸã³ååç©ã䜵çšå¯èœã§ã
ãã äžè¬åŒããïŒ ãäœãããã®äžè¬åŒäžã R16ïŒã¡ãã«åºããšãã«åºãïŒâããããã·ãš
ãã«åºåã¯ïŒâã¯ãã«ãšãã«åºã R17ïŒã¡ãã«åºããšãã«åºããã³ãžã«åºåã¯ã
ãšãã«åºã R18ïŒã¡ãã«åºããšãã«åºããã³ãžã«åºåã¯ã
ãšãã«åºã瀺ããã äžè¬åŒããïŒ ãäœãããã®äžè¬åŒäžã R19ã¯çœ®æè¥ããã¯é眮æã®ãããã«åºïŒR20
ã¯çœ®æè¥ããã¯é眮æã®ã¢ã«ãã«åºãã¢ã©ã«ãã«
åºåã¯ã¢ãªãŒã«åºïŒR21ã¯æ°ŽçŽ ååãã¢ã«ãã«åº
åã¯ã¢ã«ã³ãã·åºïŒR22åã³R23ã¯çœ®æè¥ããã¯
é眮æã®ã¢ã«ãã«åºãã¢ã©ã«ãã«åºåã¯ã¢ãªãŒã«
åºãããªãäºãã«åäžã®è¥ããã¯ç°ãªãåºã瀺
ããã ãªããæ¬çºæã«ãããŠããã€ãªã¢èŒžéç©è³ªãšã
ãŠãåèšã®ããã©ãŸã³ååç©ãšå ±ã«ãåŽéã«çž®å
è³éŠç°åã¯è€çŽ ç°ãæããé«ååææ©åå°äœã䜿
çšããã°ããã®é«ååææ©åå°äœã玫å€ç·åžåã«
ãã€ãŠå ãã€ãªã¢ãçæããæ§è³ªãæããŠããŠã
å å¢æã«å¹æçã«å¯äžããããã®ãããæŸé»æ²ç·
ã®è£Ÿåãããããªããç¹ã«äœé»çé åã§ã®æ床ã
åäžããããã®çµæãå°é»æ§åã¯çµ¶çžæ§äžæåçŸ
åããã»ã¹ã«ãããŠãçŸå段éã§ãã€ã¢ã¹é»å§ã
å°å ããªããŠãã«ããªã®ãªãè¯å¥œãªã³ããŒç»åã
åŸãããšãã§ãããäžæåçŸåããã»ã¹ã«ãã
ãŠããã€ã¢ã¹é»å§ãå°å ãããšãããããããªã³
ãžçŸåã«ãã€ãŠç»å端éšã®é®®æ床ãäœäžãã滲ã¿
ãçããããäžèšé«ååææ©åå°äœã«ãã€ãŠãã
ããåé¡ã¯å°ãªããªãããŸããäžèšé«ååææ©å
å°äœã¯çŽ«å€ç·é åã®åžå 床ãé«ããŠå€§éšåã®çŽ«å€
å ãåžåãã玫å€å ã«å¯ŸããŠäžçš®ã®ãã€ã«ã¿ãŒå¹
æãæããã®ã§ãåèšããã©ãŸã³ååç©ã®å£åã
é²æ¢ããäœçšããããæå å±€ã®çŽ«å€å å®å®æ§ãè
ä¹ æ§ãåäžãããããšãã§ããã äžèšã®ãããªé«ååææ©åå°äœãšããŠã¯ãäŸã
ã°æ¬¡ã«äŸç€ºãããã®ãæããããšãã§ããããã
ãããããã«éå®ããããã®ã§ã¯ãªãã äžèšããé«ååææ©åå°äœã®ãã¡ããªââã
ãã«ã«ã«ããŸãŒã«åã¯ãã®èªå°äœãå¹æã倧ã§ã
ãã奜ãŸããçšããããããããããªââãã
ã«ã«ã«ããŸãŒã«èªå°äœãšã¯ããã®ç¹°ãè¿ãåäœã«
ãããå šéšåã¯äžéšã®ã«ã«ããŸãŒã«ç°ãçš®ã ã®çœ®
æåºãäŸãã°ã¢ã«ãã«åºããããåºãã¢ããåºã
ããããã·åºåã¯ããã²ã³ååã«ãã€ãŠçœ®æãã
ããã®ã§ããã ãŸããç©å±€æ§é ãæããæå äœã«ãããŠããã€
ãªã¢èŒžéå±€ã«çšãããã€ãªã¢èŒžéç©è³ªã¯ãåè¿°ã®
ããã©ãŸã³ååç©ã§ãã€ãŠãããããã€ãªã¢çºç
å±€ãšç°ãªããå¿ ããããããäž»æåãšãããã®ã§
ãªããŠããã å³ã¡ããªããµãŸãŒã«èªå°äœããªããµãžã¢ãŸãŒã«
èªå°äœããã¢ãŸãŒã«èªå°äœããã¢ãžã¢ãŸãŒã«èªå°
äœãããªã¢ãŸãŒã«èªå°äœãã€ãããŸãŒã«èªå°äœã
ã€ãããŸãã³èªå°äœãã€ãããŸãªãžã³èªå°äœãã
ã¹ã€ãããŸãªãžã³èªå°äœãã¹ããªã«ååç©ããã
ã©ãŸã³ååç©ããã©ãŸãªã³èªå°äœããªããµãŸãã³
èªå°äœããã³ãŸãã¢ãŸãŒã«èªå°äœããã³ãºã€ãã
ãŸãŒã«èªå°äœããããŸãªã³èªå°äœããã³ãŸãã©ã³
èªå°äœãã¢ã¯ãªãžã³èªå°äœãããšããžã³èªå°äœã
ã¢ããã¹ãã«ãã³èªå°äœãããªââããã«ã«ã«
ããŸãŒã«ãããªâïŒâããã«ãã¬ã³ãããªâïŒâ
ããã«ã¢ã³ãã©ã»ã³ãããªã¢ãªãŒã«ã¢ãã³èªå°
äœãããšãã¬ã³ãžã¢ãã³èªå°äœãã¹ãã«ãã³èªå°
äœãã«ã«ããŸãŒã«èªå°äœçããéžã°ããäžçš®åã¯
äºçš®ä»¥äžã§ãã€ãŠããã æ¬çºæã«åºã¥ãæå äœãäŸãã°é»ååçæå äœ
ã®æ§æã¯ãçš®ã ã®åœ¢æ ããšãåŸãã 第ïŒå³ã第ïŒå³ã«äžè¬çãªæ§æãäŸç€ºããã第
ïŒå³ã®æå äœã¯ãç©å±€æ§é ã®ãã®ã§ãã€ãŠãå°é»
æ§æ¯æäœïŒäžã«ããã€ãªã¢èŒžéç©è³ªããã€ã³ããŒ
ç©è³ªäžã«åæ£ããããã€ãªã¢èŒžéå±€ïŒãèšããã
ã®å±€ïŒã®äžã«ãåè¿°ã®ç¡éå±ãã¿ãã·ã¢ãã³ãšå
è¿°ã®ããã©ãŸã³ååç©ãšããã€ã³ããŒç©è³ªäžã«äž»
æåãšããŠå«æãããã€ãªã¢çºçå±€ïŒã圢æã
ãŠãæå å±€ïŒãæ§æããŠããã第ïŒå³ã®æå äœã¯
åçžæ§é ã®ãã®ã§ãã€ãŠãå°é»æ§æ¯æäœïŒäžã«ã
äžèšã®ç¡éå±ãã¿ãã·ã¢ãã³ãšãäžèšã®ããã©ãŸ
ã³ååç©ãšããã€ã³ããŒç©è³ªäžã«äž»æåãšããŠå«
æããå±€ïŒã圢æããŠãåå±€åã®æå å±€ïŒãšãã
ãã®ã§ããã 第ïŒå³ïŒç¬¬ïŒå³ã®æå äœã¯ããããã第ïŒå³ïŒ
第ïŒå³ã®å±€æ§æã«ãããŠãæå å±€ïŒãšå°é»æ§æ¯æ
äœïŒãšã®éã«äžéå±€ïŒãèšããå°é»æ§æ¯æäœïŒã®
ããªãŒãšã¬ã¯ããã³ã®æ³šå ¥ãå¹æçã«é²æ¢ããã
ãã«ãããã®ã§ãããäžéå±€ïŒãšããŠã¯ãäžèšã®
ãã€ã³ããŒæš¹èãšããŠèª¬æãããããªé«ååéå
äœãããªããã«ã¢ã«ã³ãŒã«ããšãã«ã»ã«ããŒã¹ã
ã«ã«ããã·ã¡ãã«ã»ã«ããŒã¹çã®ææ©é«ååç©è³ª
åã¯é žåã¢ã«ãããŠã çããæããã®ãçšããã
ãã 第ïŒå³ã第ïŒå³ã«ãããŠãèå·æ§åäžçã®ãã
ã«æŽã«è¡šé¢ã«ä¿è·å±€ïŒèïŒã圢æããŠãããäŸã
ã°åææš¹è被èãã³ãŒãã€ã³ã°ããŠããã äžèšæ§æã®æå å±€ã圢æããå Žåã«ããããã€
ãªã¢çºçå±€ïŒåã¯å±€ïŒã¯ã次ã®åŠãæ¹æ³ã«ãã€ãŠ
èšããããšãã§ããã (ã€) ãã€ãªã¢çºçç©è³ªãé©åœãªæº¶å€ã«æº¶è§£ãã溶
液ãããã¯ããã«ãã€ã³ããŒãå ããŠæ··å溶解
ãã溶液ãå¡åžããæ¹æ³ã (ã) ãã€ãªã¢çºçç©è³ªãããŒã«ãã«ããã¢ãããµ
ãŒçã«ãã€ãŠåæ£åªäžã§åŸ®çŽ°ç²åãšããå¿ èŠã«
å¿ããŠãã€ã³ããŒãå ããŠæ··ååæ£ããŠåŸãã
ãåæ£æ¶²ãå¡åžããæ¹æ³ã ãããã®æ¹æ³ã«ãããŠè¶ é³æ³¢ã®äœçšäžã«ç²åã
åæ£ããããšãåäžåæ£ãå¯èœã«ãªãã ãã€ãªã¢çºçå±€ã®åœ¢æã«äœ¿çšããã溶å€ããã
ã¯åæ£åªãšããŠã¯ãïœâããã«ã¢ãã³ããžãšãã«
ã¢ãã³ããšãã¬ã³ãžã¢ãã³ãã€ãœãããããŒã«ã¢
ãã³ãããªãšã¿ããŒã«ã¢ãã³ãããªãšãã¬ã³ãžã¢
ãã³ãïŒïŒ®âãžã¡ãã«ãã«ã ã¢ãããã¢ã»ã
ã³ãã¡ãã«ãšãã«ã±ãã³ãã·ã¯ããããµãã³ãã
ã³ãŒã³ããã«ãšã³ããã·ã¬ã³ãã¯ãããã«ã ã
ïŒïŒïŒâãžã¯ãããšã¿ã³ããžã¯ããã¡ã¿ã³ããã
ã©ããããã©ã³ããžãªããµã³ãã¡ã¿ããŒã«ããšã¿
ããŒã«ãã€ãœãããããŒã«ãé ¢é žãšãã«ãé ¢é žã
ãã«ããžã¡ãã«ã¹ã«ããã·ãçãæããããšãã§
ãããæå å±€ã®åœ¢æã«ãã€ã³ããŒãçšããå Žå
ã«ããã®ãã€ã³ããŒãšããŠã¯ä»»æã®ãã®ãçšãã
ããšãã§ããããç¹ã«çæ°Žæ§ã§ãã€èªå°çãé«ã
é»æ°çµ¶çžæ§ã®ãã€ã«ã 圢æèœãæããé«ååéå
äœã奜ãŸãããããããéåäœãšããŠã¯ãäŸãã°
次ã®ãã®ãæããããšãã§ããããå¿è«ãããã«
éå®ããããã®ã§ã¯ãªãã ïœ ããªã«ãŒãããŒã ïœ ããªãšã¹ãã« ïœ ã¡ã¿ã¯ãªã«æš¹è ïœ ã¢ã¯ãªã«æš¹è ïœ ããªå¡©åããã« ïœ ããªå¡©åãããªãã³ ïœ ããªã¹ãã¬ã³ ïœ ããªããã«ã¢ã»ããŒã ïœ ã¹ãã¬ã³âãã¿ãžãšã³å ±éåäœ ïœ å¡©åããã«âé ¢é žããã«å ±éåäœ ïœ å¡©åããã«âé ¢é žããã«âç¡æ°Žãã¬ã€ã³é žå ±
éåäœ ïœ ã·ãªã³ã³æš¹è ïœ ã·ãªã³ã³âã¢ã«ãããæš¹è ïœ ããšããŒã«âãã«ã ã¢ã«ãããæš¹è ïœ ã¹ãã¬ã³âã¢ã«ãããæš¹è ïœ ããªââããã«ã«ã«ããŸãŒã« ïœ ããªããã«ããã©ãŒã« ãããã®ãã€ã³ããŒã¯ãåç¬ãããã¯ïŒçš®ä»¥äž
ã®æ··åç©ãšããŠçšããããšãã§ããã æ¬çºæã«åºã¥ãæå äœãæ§æãããå±€ãïŒç¬¬ïŒ
å³ïŒç¬¬ïŒå³ã®ãã€ãªã¢çºçå±€ïŒåã³ç¬¬ïŒå³ïŒç¬¬ïŒ
å³ã®åçžæ§é ã®æå å±€ïŒã®ãããããå«ãïŒã«ã
ããŠã¯ããã€ãªã¢çºçç©è³ªããã€ã³ããŒç©è³ªã«å¯Ÿ
ãããã€ãªã¢çºçç©è³ªïŒãã€ã³ããŒç©è³ªïŒïŒã
150ïŒ ïŒå³ã¡ããã€ã³ããŒç©è³ª100éééšã«å¯ŸãïŒ
ã150éééšãæãŸããã¯10ã100éééšïŒãšç¹å®
ã®ç¯å²ã§å«æããããã°ãæ®çé»äœåã³å容é»äœ
äœäžã®å°ãªãæ£åž¯é»çšæå äœãæäŸã§ãããäžèš
ç¯å²ãå€ããŠããã€ãªã¢çºçç©è³ªãå°ãªããšå æ
床ãæªããŠæ®çé»äœãå¢ãããŸãå€ããšå容é»äœ
ã®äœäžãå€ããªããã¡ã¢ãªãŒãå¢ãæãããŸãã
äžèšãå±€ãäžã®ãã€ãªã¢èŒžéç©è³ªã®å«æéãéèŠ
ã§ããããã€ãªã¢èŒžéç©è³ªïŒãã€ã³ããŒç©è³ªïŒ20
ã200ïŒ ïŒå³ã¡ããã€ã³ããŒç©è³ª100éééšã«å¯Ÿã
20ã200éééšãæãŸããã¯50ã120éééšïŒãšã
ãã®ãããããã®ç¯å²ã«ãã€ãŠæ®çé»äœãå°ãªã
ãã€å æ床ãè¯å¥œãšãªãããã€ãªã¢èŒžéç©è³ªã®æº¶
åªæº¶è§£æ§ãè¯å¥œã«ä¿æãããããã®ç¯å²ãå€ã
ãŠããã€ãªã¢èŒžéç©è³ªãå°ãªããšæ®çé»äœãå æ
床ãå£åãæããç»åäžè¯ãçœæç¹ããã±çãç
ãæãããŸãå€ããšæº¶åªæº¶è§£æ§ãæªããªãæãã
è匷床ãå°ãšãªãåŸåãããããã®ãã€ãªã¢èŒžé
ç©è³ªã®å«æéç¯å²ã¯ã第ïŒå³ïŒç¬¬ïŒå³ã®ãã€ãªã¢
茞éå±€ïŒã§ãåæ§ã§ãã€ãŠããã ãŸããäžèšãå±€ãã«ãããäžèšãã€ãªã¢çºçç©
質ãšäžèšãã€ãªã¢èŒžéç©è³ªãšã®å²åã¯ãäž¡ç©è³ªã®
ããããã®æ©èœãæå¹ã«çºæ®ãããäžã§ããã€ãª
ã¢çºçç©è³ªïŒãã€ãªã¢èŒžéç©è³ªã¯ééæ¯ã§ïŒïŒïŒ
0.2ïŒãïŒïŒïŒ10ïŒãšããã®ãæãŸãããïŒïŒïŒ
0.5ïŒãïŒïŒïŒïŒïŒãæŽã«ããããã®ç¯å²ããã
ã€ãªã¢çºçç©è³ªã®å²åãå°ãããšå æ床äžè¶³ãšãª
ãããŸããã®å²åã倧ãããšãã€ãªã¢èŒžéèœãäœ
äžãããããã¯ãæ床äžè¶³ãšãªãã äžèšãå±€ãããã€ãªã¢çºçå±€ã§ããå Žåããã€
ãªã¢çºçå±€ïŒã®åãã¯0.6ã10ÎŒmã§ããããšã奜
ãŸãããïŒã8ÎŒmã§ããã°æŽã«å¥œãŸããããã®å
ãã0.6ÎŒmæªæºã®å Žåã«ã¯ãç¹°ãè¿ã䜿çšæã«ã
ã€ãªã¢çºç局衚é¢ãçŸè±¡åã³ã¯ãªãŒãã³ã°çã®äœ¿
çšæ æ§ã«ããæ©æ¢°çãã¡ãŒãžãåããå±€ã®äžéšã
åããããç»åäžã«ã¯é»ã¹ãžãšãªã€ãŠè¡šãããŠã
ãŸãããšãããããŸãã0.6ÎŒmæªæºã§ã¯åŽã€ãŠæ
床äžè¶³ãšãªãæããäœãããã€ãªã¢çºçå±€ã®èå
ã10ÎŒmãè¶ ãããšãç±å±èµ·ãã€ãªã¢ã®çºçæ°ã
å¢å ããç°å¢æž©åºŠã®äžæã«äŒŽãªãå容é»äœãäœäž
ããã¡ã¢ãªãŒçŸè±¡ãå¢ããç»åäžã®æ¿åºŠäœäžãç
ãæããæŽã«ããã€ãªã¢çºçç©è³ªã®åžå端ããé·
æ³¢é·ã®å ãç §å°ããå Žåã«ã¯ãå ãã€ãªã¢ã¯é»è·
çºçå±€äžã®æäžéšè¿ãã§ãçºçããããã®å Žåã«
ã¯ãé»åã¯å±€äžãè¡šé¢ãŸã§ç§»åããªããã°ãªã
ããäžè¬ã«ååãªèŒžéèœãåŸããããªãåŸåãã
ããåŸã€ãŠãç¹°ãè¿ã䜿çšæã«ã¯æ®çé»äœã®äžæ
ãèµ·ããæããªãã ãŸããäžèšãå±€ããåå±€æ§é ã®æå å±€ã§ããå Ž
åãæå å±€ã®åãã¯10ã50ÎŒmã§ããããšã奜ãŸ
ããã15ã30ÎŒmã§ããã°æŽã«å¥œãŸããããã®è
åã15ÎŒmæªæºã®å Žåã¯ãèãããã«åž¯é»é»äœã
å°ãããªããèå·æ§ã«ãå£ãããŸããæå å±€ïŒã®
åãã50ÎŒmãè¶ãããšãããã€ãŠæ®çé»äœã¯äž
æããäžã«ãäžèšãããã€ãªã¢çºçå±€ãåããã
å Žåãšåæ§ã®çŸè±¡ãçºçããŠãååãªèŒžéèœãåŸ
ããããªãåŸåãçŸããããã®ããç¹°ãè¿ã䜿çš
æã«ã¯æ®çé»äœã®äžæãèµ·ãæããªãã ãŸãã第ïŒå³ïŒç¬¬ïŒå³ã®ãã€ãªã¢èŒžéå±€ïŒã®å
ã¿ã¯ïŒã50ÎŒmã奜ãŸããã¯ïŒã30ÎŒmã§ããã®ã
ããããã®åãã5ÎŒmæªæºã§ã¯èãããã«åž¯é»é»
äœãå°ãšãªãããŸã50ÎŒmãè¶ãããšåŽã€ãŠæ®ç
é»äœã倧ãããªãæãã ãŸãããã€ãªã¢çºçå±€ãšãã€ãªã¢èŒžéå±€ã®èå
æ¯ã¯ãïŒïŒïŒïŒã30ïŒã§ããã®ãæãŸããã äžèšãã€ãªã¢çºçç©è³ªãåæ£ããããŠæå å±€ã
圢æããå Žåã«ãããŠã¯ãåœè©²ãã€ãªã¢çºçç©è³ª
ã¯5ÎŒm以äžã0.1ÎŒm以äžã奜ãŸããã¯2ÎŒm以äžã
0.2ÎŒm以äžã®å¹³åç²åŸã®ç²ç²äœãšãããã®ã奜ãŸ
ãããããªãã¡ãç²åŸãäœã倧ãããšå±€äžãžã®å
æ£ãæªããªããšãšãã«ãç²åãè¡šé¢ã«äžéšçªåºã
ãŠè¡šé¢ã®å¹³æ»æ§ãæªããªããå Žåã«ãã€ãŠã¯ç²å
ã®çªåºéšåã§æŸé»ãçãããããããã¯ãããã«
ãããŒç²åãä»çããŠãããŒãã€ã«ãã³ã°çŸè±¡ã
çãæãããã€ãªã¢çºçç©è³ªãšããŠé·æ³¢é·å ïŒã
700nmïŒã«å¯ŸããŠæ床ãæãããã®ã¯ããã€ãªã¢
çºçç©è³ªã®äžã§ã®ç±å±èµ·ãã€ãªã¢ã®çºçã«ããè¡š
é¢é»è·ãäžåããããã€ãªã¢çºçç©è³ªã®ç²åŸã倧
ãããšãã®äžåå¹æã倧ãããšæããããåŸã€
ãŠãç²åŸã埮å°åããããšã«ãã€ãŠã¯ãããŠé«æµ
æåãé«æ床åãéæã§ããã äœããäžèšç²åŸãããŸãå°ãããšåŽã€ãŠåéã
æãå±€ã®æµæãäžæããããçµæ¶æ¬ é¥ãå¢ããŠæ
床åã³ç¹°ãè¿ãç¹æ§ãäœäžãããã垯é»èœãå°ã
ããªãããŸãã埮现åããäžã§éçãããããã
å¹³åç²åŸã®äžéã0.01ÎŒmãšããã®ãæãŸããã æŽã«ãäžèšæå äœå±€ã«ã¯æ床ã®åäžãæ®çé»äœ
ä¹è³å埩䜿çšæã®ç²åŽäœæžçãç®çãšããŠãäžçš®
åã¯äºçš®ä»¥äžã®é»åå容æ§ç©è³ªãå«æããããã
ãšãã§ãããããã«çšããããšã®ã§ããé»åå容
æ§ç©è³ªãšããŠã¯ãäŸãã°ç¡æ°Žã³ãã¯é žãç¡æ°Žãã¬
ã€ã³é žããžããã ç¡æ°Žã³ãã¯é žãç¡æ°Žãã¿ã«é žã
ããã©ã¯ãã«ç¡æ°Žãã¿ã«é žãããã©ããã ç¡æ°Žã
ã¿ã«é žãïŒâãããç¡æ°Žãã¿ã«é žãïŒâãããç¡
æ°Žãã¿ã«é žãç¡æ°Žããã¡ãªããé žãç¡æ°Žã¡ãªãã
é žãããã©ã·ã¢ããšãã¬ã³ãããã©ã·ã¢ããããž
ã¡ã¿ã³ãïœâãžããããã³ãŒã³ãïœâãžãããã
ã³ãŒã³ãïŒïŒïŒïŒïŒâããªããããã³ãŒã³ããã©
ããããã³ãŸãããªã«ããã¯ãªã«ã¯ãã©ã€ããã
ãã³ã¯ãã«ã€ãããã¯ãã©ãã«ããã«ããã«ããž
ã¯ãããžã·ã¢ããã©ãã³ãŸããã³ãã¢ã³ãã©ãã
ã³ããžãããã¢ã³ãã©ããã³ãïŒâãã«ãªã¬ããª
ãã³âããžã·ã¢ãã¡ãã¬ã³ããããžãããªã«ããã
ãªãããâïŒâãã«ãªã¬ããªãã³âããžã·ã¢ãã¡
ãã¬ã³ããããžãããªã«ãããã¯ãªã³é žãïœâã
ããå®æ¯éŠé žãïœâãããå®æ¯éŠé žãïŒïŒïŒâãž
ãããå®æ¯éŠé žããã³ã¿ãã«ãªãå®æ¯éŠé žãïŒâ
ããããµãªãã«é žãïŒïŒïŒâãžããããµãªãã«
é žããã¿ã«é žãã¡ãªããé žããã®ä»ã®é»å芪åå
ã®å€§ããååç©ãæããããšãã§ããããŸããé»
åå容æ§ç©è³ªã®æ·»å å²åã¯ãééæ¯ã§ãã€ãªã¢çº
çç©è³ªïŒé»åå容æ§ç©è³ªïŒ100ïŒ0.01ã200ã奜ãŸ
ããã¯100ïŒ0.1ã100ã§ããã ãªããäžè¿°ããæå å±€ãèšããã¹ãæ¯æäœïŒã¯
éå±æ¿ãéå±ãã©ã åã¯å°é»æ§ããªããŒãé žåã€
ã³ãžãŠã çã®å°é»æ§ååç©è¥ããã¯ã¢ã«ãããŠ
ã ããã©ãžãŠã ãéçã®éå±ããæãå°é»æ§èå±€
ããå¡åžãèžçãã©ãããŒãçã®æ段ã«ããã
çŽããã©ã¹ããã¯ãã€ã«ã çã®åºäœã«èšããŠæã
ãã®ãçšãããããæ¥çå±€æãã¯ããªã€ãŒå±€çãš
ããŠæ©èœããäžéå±€ãšããŠã¯ãäžèšã®ãã€ã³ããŒ
æš¹èãšããŠèª¬æãããããªé«ååéåäœãããªã
ãã«ã¢ã«ã³ãŒã«ããšãã«ã»ã«ããŒã¹ãã«ã«ããã·
ã¡ãã«ã»ã«ããŒã¹çã®ææ©é«ååç©è³ªåã¯é žåã¢
ã«ãããŠã çããæããã®ãçšããããã æ¬çºæã®æå äœã®å€§ããªç¹é·ã¯ãæ¬çºæã«ãã
ãŠçšããç¡éå±ãã¿ãã·ã¢ãã³ã®æå æ³¢é·åã®æ¥µ
倧å€ã770nm以äžã790nmæªæºã«ååšãããšãå
å°äœã¬ãŒã¶ãŒçšæå äœãšããŠæé©ã§ããããšãã
ã®ç¡éå±ãã¿ãã·ã¢ãã³ã¯äžèšããããã«æ¥µããŠ
çµæ¶åœ¢ãå®å®ã§ãããä»ã®çµæ¶åœ¢ãžã®è»¢ç§»ã¯èµ·ã
é£ãããšã§ããããã®ããšã¯åèšããæ¬çºæã«äœ¿
çšããç¡éå±ãã¿ãã·ã¢ãã³èªäœã®è£œé ãæ§è³ªã®
ã¿ãªãããé»ååçæå äœã補é ãããšãããã
ã®äœ¿çšæã«ã倧ããªé·æãšãªããã®ã§ããã æ¬çºæã®ä»ã®å€§ããªç¹é·ã¯ãäžèšç¡éå±ãã¿ã
ã·ã¢ãã³ãå«æããå±€äžã«ãäžèšç¡éå±ãã¿ãã·
ã¢ãã³ãšé©åæ§ã®ããç¹å®ã®é»è·èŒžéç©è³ªãšããŠ
ããã©ãŸã³ååç©ãå«æãããããšã§ããããã
ã«ããç¹ã«æ£åž¯é»äœ¿çšã«å¥œé©ãªæå äœã®æäŸãå¯
èœãšãªã€ãã®ã§ããã ã å®æœäŸ 以äžãæ¬çºæãå ·äœçãªå®æœäŸã«ã€ããŠãæ¯èŒ
äŸãåç §ããªãã詳现ã«èª¬æããã ãŸãã第ïŒå³ã第ïŒå³ã«ç€ºãç¹æ§ããã€ç¡éå±
ãã¿ãã·ã¢ãã³ååç©ïŒ¡ã第ïŒå³ã第ïŒå³ã«ç€ºã
ç¹æ§ããã€ç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒ¢ã®åæ
äŸåã³Ïåç¡éå±ãã¿ãã·ã¢ãã³ååç©ã®åæäŸ
ã瀺ãã ãåæäŸ ïŒã ãªããŠã ãã¿ãã·ã¢ãã³50ïœãïŒâã«ãããŠå
åæ¹æãã600mlã®æ¿ç¡«é žã«å ããã次ãã§ãã
ã®æ··åç©ã¯ãã®æž©åºŠã«ãããŠïŒæéæ¹æãããã
次ãã§ãã§ãã溶液ã¯ç²ãçŒçµãããã¬ã©ã¹æŒæ
ãéããŠæ¿ŸéãããŠãïŒãªããã«ã®æ°·ãšæ°Žã®äžãž
æ¹æããªããåŸã ã«æ³šå ¥ããããæ°æéæŸçœ®ãã
åŸã«ããã®æ··åç©ã¯æ¿ŸéãããåŸãããå¡ãã¯äž
æ§ã«ãªããŸã§æ°Žã§æŽæµãããã次ãã§ããã®å¡ã¯
æçµçã«ã¡ã¿ããŒã«ã§æ°åæŽæµããããã€ç©ºæ°äž
ã§ä¹Ÿç¥ãããããããã®ä¹Ÿç¥ãããç²æ«ã¯24æé
é£ç¶æœåºè£ 眮äžã§ã¢ã»ãã³ã«ãã€ãŠæœåºãããã
ã€ç©ºæ°äžã§ä¹Ÿç¥ãããããŠéãç²æ«ãšãªã€ãã äžèšã«ãããŠããªããŠã ã«å¯ŸããŠå¡©ã®æ®æž£ãä¿
蚌ããããã«æåºã¯å埩ãããããã®ããã«ããŠ
30.5ïœã®éãç²æ«ãåŸãããããã®åŸããããã®
ã¯ããã®ïŒžç·åæå³åœ¢ãããã§ã«åºçãããŠãã
è³æã«èšèŒãããŠããαåãã¿ãã·ã¢ãã³ååç©
ã®ïŒžç·åæå³åœ¢ãšäžèŽããŠããã ãã®ããã«ããŠåŸããããéå±ãå«ãŸãªãαå
ãã¿ãã·ã¢ãã³ååç©30ïœããçŽåŸ13ïŒ16ã€ã³ã
ã®ããŒã«ã§ååæºããããå 容ç©900mlã®ç£è£œã
ãŒã«ãã«äžã«ä»èŸŒã¿ãçŽ80rpmã§164æéããªã³
ã°ããŠç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒ¡ãåŸããã
ã®ååç©ã¯ç¬¬ïŒå³ã«ç€ºãç·åæã¹ãã¯ãã«ã瀺
ããã ãåæäŸ ïŒã åæäŸïŒã®ç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒ¡ãšã
ãã©ããããã©ã³ãïŒïŒïŒâãžã¯ãããšã¿ã³çã®
ææ©æº¶å€200mlãããŒã«ãã«äžã«å ãã24æéå
床ããªã³ã°ããããã®ããªã³ã°ããåŸã®åæ£æ¶²ã«
ã€ããŠææ©æº¶å€ã®é€å»åã³ä¹Ÿç¥ãè¡ããç¡éå±ã
ã¿ãã·ã¢ãã³ååç©B28.2ïœãåŸãããã®ååç©
ã¯ç¬¬ïŒå³ã«ç€ºãç·åæã¹ãã¯ãã«ã瀺ããã ãåæäŸ ïŒã αåç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒICI補ã¢ã
ã©ã€ããã¢ãŒã¹ããã«GSïŒããå ç±ãããžã¡ã
ã«ãã«ã ã¢ã«ãããã«ããïŒåæœåºããŠç²Ÿè£œã
ãããã®æäœã«ãã粟補ç©ã¯Î²åã«è»¢ç§»ããã次
ã«ããã®Î²åç¡éå±ãã¿ãã·ã¢ãã³ååç©ã®äžéš
åãæ¿ç¡«é žã«æº¶è§£ãããã®æº¶æ¶²ãæ°·æ°Žäžã«æ³šãã§
åæ²æŸ±ãããããšã«ãããαåã«è»¢ç§»ããããã
ã®åæ²æŸ±ç©ãã¢ã³ã¢ãã¢æ°Žãã¡ã¿ããŒã«çã§æŽæµ
åŸ10âã§ä¹Ÿç¥ããã次ã«ãäžèšã«ãã粟補ããα
åç¡éå±ãã¿ãã·ã¢ãã³ååç©ã磚ç å©å€åã³å
æ£å€ãšãšãã«ãµã³ããã«ã«å ¥ãã枩床100±20â
ã§15ã25æéæ··ç·Žããããã®æäœã«ããçµæ¶åœ¢ã
Ïåã«è»¢ç§»ããã®ã確èªåŸã容åšããåãåºãã
æ°Žåã³ã¡ã¿ããŒã«çã§ç£šç å©å€åã³åæ£å€ãåå
é€å»ããåŸã也ç¥ããŠãé®®æãªéå³ã垯ã³ãÏå
ç¡éå±ãã¿ãã·ã¢ãã³ã®éè²çµæ¶ãåŸãããã®ã
ã¿ãã·ã¢ãã³ã¯ã第ïŒïŒå³ã®ïŒžç·åæã¹ãã¯ãã«
ã瀺ããã å®æœäŸ ïŒãïŒ ã¢ã«ãããŠã ç®ãã©ãããŒãããããªãšã¹ãã«
ãã€ã«ã ããæãå°é»æ§æ¯æäœäžã«ãå¡©åããã«
âé ¢é žããã«âç¡æ°Žãã¬ã€ã³é žå ±éåäœããšã¹ã¬
ãã¯MFâ10ãïŒç©æ°ŽååŠç€Ÿè£œïŒããæãåã
0.05ÎŒmã®äžéå±€ã圢æããã次ãã§ã第ïŒïŒå³
ã«ç€ºãããã€ãªã¢èŒžéç©è³ªãšãã€ã³ããŒæš¹èïŒã
ãªã«ãŒãããŒãïŒãã³ã©ã€ãâ1250ïŒãšãïŒïŒ
ïŒâãžã¯ãããšã¿ã³67mlã«æº¶ããã溶液ãåèšäž
éå±€äžã«å¡åžããŠãã€ãªã¢èŒžéå±€ã圢æããã次
ãã§ã第ïŒïŒå³ã«ç€ºããå¹³åç²åŸ1ÎŒmã®åãã€ãª
ã¢çºçç©è³ªåã³åãã€ãªã¢èŒžéç©è³ªãšãã€ã³ããŒ
æš¹èãšãïŒïŒïŒâãžã¯ãããšã¿ã³67mlã«å ããŠã
ãŒã«ãã«ã§12æéåæ£ããããŠåŸãããåæ£æ¶²ã
åèšãã€ãªã¢èŒžéå±€äžã«å¡åžä¹Ÿç¥ããŠãã€ãªã¢çº
çå±€ã圢æããåé»ååçæå äœãäœè£œããã ããããŠåŸãããé»ååçæå äœãéé»è©Šéšæ©
ãEPAâ8100åãïŒå·å£é»æ©è£œäœæ補ïŒã«è£ çãã
以äžã®ç¹æ§è©Šéšãè¡ã€ããå³ã¡ã垯é»åšã«ïŒ6kV
ã®é»å§ãå°å ããŠïŒç§éã³ããæŸé»ã«ããæå å±€
ã垯é»ããããåŸïŒç§éã®éæŸçœ®ãã次ãã§æå
局衚é¢ã«åå åšã«ããåå ããã780nmã®å ãç §
å°ããŠãæå å±€ã®è¡šé¢é»äœã1/2ã«æžè¡°ãããã
ã®ã«å¿ èŠãªé²å éãå³ã¡åæžé²å é1/2ãæ±ã
ãããŸããäžèšã³ããæŸé»ã«ãã垯é»æã®å容é»
äœVAåã³10uxã»secé²å åŸã®æ®çé»äœVRã«ã€
ããŠã®å€ã枬å®ããã ãŸããå®æœäŸã«ç€ºãããã®ãšåæ§ã®æå äœå±€ã
Alãã©ã äžã«åœ¢æããã¬ãŒã¶ãŒããŒã ããªã³ã¿
ãŒLPâ3010ïŒå°è¥¿å åçå·¥æ¥(æ ª)補ïŒæ¹é æ©ïŒåå°
äœã¬ãŒã¶ãŒå æºäœ¿çšïŒã«æèŒããç»åè©äŸ¡ãå®æœ
ããïŒäœããCDã¯ç»åæ¿åºŠãã¯è§£å床ã§ã
ããïŒ âïŒæ¿åºŠãååã«é«ãã解ååãéåžžã«è¯å¥œ ïŒCDâ§1.2ïŒïŒ²â§6.0ïŒ âïŒæ¿åºŠã解ååå ±è¯å¥œ ïŒ1.2ïŒCDâ§0.7ïŒ6.0ïŒïŒ²â§4.0ïŒ ÃïŒæ¿åºŠãäœãã解ååãååã§ãªãããã€ãŸ
ããã«ããªãçœåã¯é»æç¹ãè¡šãããã ãªããCDã¯ãµã¯ã©æ¿åºŠèšïŒModel PDAâ
65ïŒå°è¥¿å åçå·¥æ¥è£œïŒã«ãŠæž¬å®ããã¯ãµã¯ã©
æ¿åºŠèšïŒModel PDAâïŒïŒå°è¥¿å åçå·¥æ¥è£œïŒ
ã«ãŠæž¬å®ãããCDåã³ïŒ²å ±ãçœçŽã®æ¿åºŠã0.0ãš
ããåå°æ¿åºŠã枬å®ããŠè©äŸ¡ãè¡ã€ãã äœããã«ã€ããŠã®æž¬å®æ³ã¯å ·äœçã«ã¯æ¬¡ã®é
ãã§ãã€ããå³ã¡ãã¹ãªãã500ÎŒÃ20ÎŒã®ãã€ã¯
ããã³ã·ãã¡ãŒã¿ãŒã§è§£ååãã€ãŒãã枬å®ã
ãã解ååãã€ãŒãã®å€å®åºæºã¯ãäžèšã®åŒã30
ïŒ ä»¥äžã®ã¬ã¹ãã³ã¹ãæãã解ååãã€ãŒããã
å€å®ãããã³ããŒç»åã®ç»åéšæ¿åºŠãDcopy naxãé
ç»åéšã®æ¿åºŠãDcopy nioããªãªãžãã«åçš¿ã®ç»åéš
æ¿åºŠãDorig naxãéç»åéšã®æ¿åºŠãDorig nioãšãããšã ïŒDcopyïŒnaxâDcopyïŒnioïŒDcopyïŒnaxïŒDcopyïŒnioïŒ
ïŒïŒDorigïŒnaxâDorigïŒnioïŒDorigïŒnaxïŒDorigïŒnio
ïŒâ§30ïŒïŒ ïŒ ãã®çµæã«ããã°ãæ¬çºæã«åºãå®æœäŸïŒãïŒ
ã®è©Šæã¯ãããããè¯å¥œãªé»ååçç¹æ§ã瀺ãã
ãšãåãã ç¹ã«ãCGMãšããŠãæ¬çºæã®ç¡éå±ãã¿ãã·
ã¢ãã³ïŒ¢ã䜿çšããããšãåã³ãã€ãªã¢çºçå±€ã«
CTMãšããŠããã©ãŸã³ååç©ãããæ·»å ãã
ããšã¯ãããããæå äœã®ç¹æ§ã倧ããå·Šå³ãã
é«åž¯é»é»äœåã³ãã®å®å®æ§ãããããå æ床ã倧
ããåäžãããçã®æ£åž¯é»çšæå äœãšããŠã®é¡è
ãªçµæãåŸãããšãã§ããããŸããåå°äœã¬ãŒã¶
ãŒäœ¿çšã®ãã¹ãã§ããé«æ¿åºŠãé«è§£ååãåŸã
ããé·æ³¢é·æ床ãåäžããããšãæãããšãªã€
ãã å®æœäŸ ïŒãïŒ å®æœäŸïŒã«ãããŠããããã䜿çšããããã©ãŸ
ã³ååç©ãããã第ïŒïŒå³ã«ç€ºãããã©ãŸã³å
åç©ããã«å€ãããŸãã䜿çšãããã€ãªã¢çºç
ç©è³ªãç¡éå±ãã¿ãã·ã¢ãã³ååç©ïŒ¢ã«å€ãã以
å€ã¯åè¿°ãããšåæ§ã«ããŠãåé»ååçæå äœã
äœè£œããåæ§ã®è©Šéšãè¡ã€ããšããã第ïŒïŒå³ã«
瀺ãçµæãåŸãããã ãã®çµæãããæ¬çºæã«åºãå®æœäŸïŒãïŒã®è©Š
æã¯ããããè¯å¥œãªçµæã瀺ãã
第ïŒå³ã第ïŒïŒå³ã¯æ¬çºæã説æãããã®ã§ã
ã€ãŠã第ïŒå³åã³ç¬¬ïŒå³ã¯ç¡éå±ãã¿ãã·ã¢ãã³
ã®äºäŸã®åç·åæã¹ãã¯ãã«å³ã第ïŒå³åã³ç¬¬
ïŒå³ã¯ç¡éå±ãã¿ãã·ã¢ãã³ã®äºäŸã®åèµ€å€ç·åž
åã¹ãã¯ãã«å³ã第ïŒå³ã¯ç¡éå±ãã¿ãã·ã¢ãã³
ã®è¿èµ€å€ã¹ãã¯ãã«å³ã第ïŒå³ïŒç¬¬ïŒå³ã¯ããã
ãå±€åé¢åã®æå äœã®éšåæé¢å³ã第ïŒå³ïŒç¬¬ïŒ
å³ã¯ããããåå±€æ§é ã®æå äœã®éšåæé¢å³ã第
ïŒïŒå³åã³ã第ïŒïŒå³ã¯åé»ååçæå äœã®ç¹æ§
å€åã瀺ãå³ã§ããã第ïŒïŒå³ã¯åŸæ¥ã®Ïåç¡é
å±ãã¿ãã·ã¢ãã³ã®ïŒžç·åæã¹ãã¯ãã«å³ã§ã
ãã ãªããå³é¢ã«ç€ºã笊å·ã«ãããŠãïŒâŠâŠå°é»æ§
æ¯æäœãïŒâŠâŠãã€ãªã¢çºçå±€ãïŒâŠâŠãã€ãªã¢
茞éå±€ãïŒâŠâŠæå å±€ãïŒâŠâŠäžéå±€ãïŒâŠâŠå±€
ã§ããã
ã€ãŠã第ïŒå³åã³ç¬¬ïŒå³ã¯ç¡éå±ãã¿ãã·ã¢ãã³
ã®äºäŸã®åç·åæã¹ãã¯ãã«å³ã第ïŒå³åã³ç¬¬
ïŒå³ã¯ç¡éå±ãã¿ãã·ã¢ãã³ã®äºäŸã®åèµ€å€ç·åž
åã¹ãã¯ãã«å³ã第ïŒå³ã¯ç¡éå±ãã¿ãã·ã¢ãã³
ã®è¿èµ€å€ã¹ãã¯ãã«å³ã第ïŒå³ïŒç¬¬ïŒå³ã¯ããã
ãå±€åé¢åã®æå äœã®éšåæé¢å³ã第ïŒå³ïŒç¬¬ïŒ
å³ã¯ããããåå±€æ§é ã®æå äœã®éšåæé¢å³ã第
ïŒïŒå³åã³ã第ïŒïŒå³ã¯åé»ååçæå äœã®ç¹æ§
å€åã瀺ãå³ã§ããã第ïŒïŒå³ã¯åŸæ¥ã®Ïåç¡é
å±ãã¿ãã·ã¢ãã³ã®ïŒžç·åæã¹ãã¯ãã«å³ã§ã
ãã ãªããå³é¢ã«ç€ºã笊å·ã«ãããŠãïŒâŠâŠå°é»æ§
æ¯æäœãïŒâŠâŠãã€ãªã¢çºçå±€ãïŒâŠâŠãã€ãªã¢
茞éå±€ãïŒâŠâŠæå å±€ãïŒâŠâŠäžéå±€ãïŒâŠâŠå±€
ã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ãã€ãªã¢èŒžéç©è³ªåã³ãã€ã³ããŒç©è³ªãå«æ
ãããã€ãªã¢èŒžéå±€ãšããã€ãªã¢çºçç©è³ªåã³ã
ã€ã³ããŒç©è³ªãå«æãããã€ãªã¢çºçå±€ãšããã®
é ã«ç©å±€ãããŠããæå äœã«ãããŠã Cu Kα 1.541â«ã®ïŒžç·ã«å¯Ÿãããã©ãã¯è§åºŠ2Ξ
ïŒäœãã誀差ã¯2Ξ±0.2床ïŒã7.7床ïŒ9.3床ïŒ16.9
床ïŒ17.5床ïŒ22.4床ïŒ28.8床ã«äž»èŠãªããŒã¯ãæ
ããç·çµæ¶åæã¹ãã¯ãã«ãæãããã®ïŒžç·å
æã¹ãã¯ãã«ã®äžèšãã©ãã¯è§åºŠ9.3床ã®ããŒã¯
ã«å¯Ÿãããã©ãã¯è§åºŠ16.9床ã®ããŒã¯ã®åŒ·åºŠæ¯ã
0.8ã1.0ã§ããããã€ãäžèšãã©ãã¯è§åºŠ9.3床ã®
ããŒã¯ã«å¯Ÿãããã©ãã¯è§åºŠ22.4床åã³28.8床ã®
ããããã®ããŒã¯ã®åŒ·åºŠã0.4以äžã§ããããã€ã
700ã760cm-1ïŒ1320±ïŒcm-1åã³3288±ïŒcm-1ã«
ããŒã¯ãæããèµ€å€ç·åžåã¹ãã¯ãã«ãæãã
700ã760cm-1ã®åžå垯ã«ã¯ïŒæ¬ã®ããŒã¯ãããã
ãã®ãã¡752±ïŒcm-1ãæã匷ãç¡éå±ãã¿ãã·
ã¢ãã³ãåèšãã€ãªã¢çºçå±€ã«å«æãããæŽã«è©²
ãã€ãªã¢çºçå±€ã«ãäžèšäžè¬åŒããã§è¡šããã
ãååç©ãšäžèšäžè¬åŒããã§è¡šããããååç©
ãšã®å°ãªããšãäžæ¹ãå«æãããŠããããšãç¹åŸŽ
ãšããæå äœã äžè¬åŒããïŒ ïŒäœãããã®äžè¬åŒäžã R1ïŒçœ®æè¥ããã¯æªçœ®æã®ã¢ãªãŒã«åºåã¯
眮æè¥ããã¯æªçœ®æã®è€çŽ ç°åºã R2ïŒæ°ŽçŽ ååã眮æè¥ããã¯æªçœ®æã®ã¢ã«
ãã«åºãåã¯çœ®æè¥ããã¯æªçœ®æã®ã¢ãªãŒ
ã«åºã  ïŒæ°ŽçŽ ååãããã²ã³ååãã¢ã«ãã«
åºã眮æã¢ããåºãã¢ã«ã³ãã·åºåã¯ã·ã¢
ãåºã ïœ ïŒïŒåã¯ïŒã®æŽæ°ãè¡šãããïŒ äžè¬åŒããïŒ ïŒäœãããã®äžè¬åŒäžãR1ïŒR2ïŒïŒžïŒïœã¯å
èšãããã®ãšåãã§ãããïŒ
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP29920586A JPS63149654A (ja) | 1986-12-15 | 1986-12-15 | æå äœ |
GB8814374A GB2205659B (en) | 1986-10-20 | 1987-10-20 | Photoreceptor |
PCT/JP1987/000803 WO1988002880A1 (en) | 1986-10-20 | 1987-10-20 | Photosensitive member |
US07/216,906 US4975350A (en) | 1986-10-20 | 1987-10-20 | Photoreceptor having a metal-free phthalocyanine charge generating layer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP29920586A JPS63149654A (ja) | 1986-12-15 | 1986-12-15 | æå äœ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63149654A JPS63149654A (ja) | 1988-06-22 |
JPH0518426B2 true JPH0518426B2 (ja) | 1993-03-11 |
Family
ID=17869506
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP29920586A Granted JPS63149654A (ja) | 1986-10-20 | 1986-12-15 | æå äœ |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63149654A (ja) |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58134642A (ja) * | 1982-02-05 | 1983-08-10 | Konishiroku Photo Ind Co Ltd | é»ååçæå äœ |
JPS58166354A (ja) * | 1982-03-27 | 1983-10-01 | Konishiroku Photo Ind Co Ltd | é»ååçæå äœ |
JPS58182639A (ja) * | 1982-04-20 | 1983-10-25 | Hitachi Ltd | é»ååççšæå äœ |
JPS5962861A (ja) * | 1982-07-08 | 1984-04-10 | Dainippon Ink & Chem Inc | é»ååççšæå äœ |
JPS59113445A (ja) * | 1982-12-21 | 1984-06-30 | Dainippon Ink & Chem Inc | é»ååççšæå äœ |
JPS6019153A (ja) * | 1983-07-13 | 1985-01-31 | Hitachi Ltd | é»ååççšæå äœ |
JPS6019152A (ja) * | 1983-07-13 | 1985-01-31 | Hitachi Ltd | é»ååççšæå äœ |
JPS6086552A (ja) * | 1983-10-19 | 1985-05-16 | Toyo Ink Mfg Co Ltd | å å°é»æ§ææ |
JPS6086551A (ja) * | 1983-10-19 | 1985-05-16 | Toyo Ink Mfg Co Ltd | é»ååçæå äœ |
JPS60143352A (ja) * | 1983-12-29 | 1985-07-29 | Konishiroku Photo Ind Co Ltd | æå äœ |
-
1986
- 1986-12-15 JP JP29920586A patent/JPS63149654A/ja active Granted
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58134642A (ja) * | 1982-02-05 | 1983-08-10 | Konishiroku Photo Ind Co Ltd | é»ååçæå äœ |
JPS58166354A (ja) * | 1982-03-27 | 1983-10-01 | Konishiroku Photo Ind Co Ltd | é»ååçæå äœ |
JPS58182639A (ja) * | 1982-04-20 | 1983-10-25 | Hitachi Ltd | é»ååççšæå äœ |
JPS5962861A (ja) * | 1982-07-08 | 1984-04-10 | Dainippon Ink & Chem Inc | é»ååççšæå äœ |
JPS59113445A (ja) * | 1982-12-21 | 1984-06-30 | Dainippon Ink & Chem Inc | é»ååççšæå äœ |
JPS6019153A (ja) * | 1983-07-13 | 1985-01-31 | Hitachi Ltd | é»ååççšæå äœ |
JPS6019152A (ja) * | 1983-07-13 | 1985-01-31 | Hitachi Ltd | é»ååççšæå äœ |
JPS6086552A (ja) * | 1983-10-19 | 1985-05-16 | Toyo Ink Mfg Co Ltd | å å°é»æ§ææ |
JPS6086551A (ja) * | 1983-10-19 | 1985-05-16 | Toyo Ink Mfg Co Ltd | é»ååçæå äœ |
JPS60143352A (ja) * | 1983-12-29 | 1985-07-29 | Konishiroku Photo Ind Co Ltd | æå äœ |
Also Published As
Publication number | Publication date |
---|---|
JPS63149654A (ja) | 1988-06-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPH0797221B2 (ja) | ç»å圢ææ¹æ³ | |
JPH0598181A (ja) | ã¯ããã¬ãªãŠã ãã¿ãã·ã¢ãã³ã®æ°èŠãªçµæ¶ããã®æ°èŠãªçµæ¶ãããªãå å°é»ææåã³ãããçšããé»ååçæå äœ | |
JP2657836B2 (ja) | é»ååçæå äœ | |
JPH10237347A (ja) | çµæ¶åãªããœãã¿ãã«ãã¿ãã·ã¢ãã³åã³ãããçšããé»ååçæå äœäžŠã³ã«ç»å圢ææ¹æ³ | |
JP2813812B2 (ja) | é»ååçæå äœããã³ãã®è£œé æ¹æ³ | |
JPS62103650A (ja) | é»ååçæå äœ | |
JP2700859B2 (ja) | æå äœ | |
JPH0530263B2 (ja) | ||
JP2813813B2 (ja) | é»ååçæå äœ | |
JP2867045B2 (ja) | é»ååçæå äœ | |
JPH0518424B2 (ja) | ||
JPH0786692B2 (ja) | æå äœ | |
JPH0789230B2 (ja) | æå äœ | |
JP2981994B2 (ja) | ç»å圢ææ¹æ³ | |
JP2813810B2 (ja) | é»ååçæå äœ | |
JPH0518426B2 (ja) | ||
JP2813811B2 (ja) | é»ååçæå äœ | |
JPH0518425B2 (ja) | ||
JP2004045991A (ja) | æå å±€å¡åžæ¶²äœè£œæ¹æ³ããã³åå±€åé»ååçæå äœ | |
JP2563810B2 (ja) | æå äœ | |
JPS63148269A (ja) | æå äœ | |
JPS63210943A (ja) | æå äœ | |
JPH0823705B2 (ja) | æå äœ | |
JPS62121460A (ja) | é»ååçæå äœ | |
JP2704373B2 (ja) | å転çŸåæ¹æ³ |