JPH0441166B2 - - Google Patents
Info
- Publication number
- JPH0441166B2 JPH0441166B2 JP59115395A JP11539584A JPH0441166B2 JP H0441166 B2 JPH0441166 B2 JP H0441166B2 JP 59115395 A JP59115395 A JP 59115395A JP 11539584 A JP11539584 A JP 11539584A JP H0441166 B2 JPH0441166 B2 JP H0441166B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- cyclopentadienyl
- component
- aluminoxane
- mmol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 claims description 38
- 229920000098 polyolefin Polymers 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 150000003623 transition metal compounds Chemical class 0.000 claims description 9
- 150000001336 alkenes Chemical class 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000010936 titanium Substances 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 229910052735 hafnium Chemical group 0.000 claims description 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical group [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 2
- -1 cyclopentadienyl compound Chemical class 0.000 description 29
- 239000004698 Polyethylene Substances 0.000 description 13
- 239000004743 Polypropylene Substances 0.000 description 13
- 229920000573 polyethylene Polymers 0.000 description 13
- 229920001155 polypropylene Polymers 0.000 description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 10
- 230000003197 catalytic effect Effects 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 5
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- LURXHPLXDPBPNX-UHFFFAOYSA-L cyclopenta-1,3-diene;dichlorovanadium Chemical compound Cl[V]Cl.C1C=CC=C1.C1C=CC=C1 LURXHPLXDPBPNX-UHFFFAOYSA-L 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 3
- KSFCHHFBQJDGFF-UHFFFAOYSA-L cyclopenta-1,3-diene;dichlorotitanium Chemical compound Cl[Ti]Cl.C1C=CC=C1.C1C=CC=C1 KSFCHHFBQJDGFF-UHFFFAOYSA-L 0.000 description 3
- QRUYYSPCOGSZGQ-UHFFFAOYSA-L cyclopentane;dichlorozirconium Chemical compound Cl[Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 QRUYYSPCOGSZGQ-UHFFFAOYSA-L 0.000 description 3
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- IZYHZMFAUFITLK-UHFFFAOYSA-N 1-ethenyl-2,4-difluorobenzene Chemical compound FC1=CC=C(C=C)C(F)=C1 IZYHZMFAUFITLK-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910000365 copper sulfate Inorganic materials 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- QOXHZZQZTIGPEV-UHFFFAOYSA-K cyclopenta-1,3-diene;titanium(4+);trichloride Chemical compound Cl[Ti+](Cl)Cl.C=1C=C[CH-]C=1 QOXHZZQZTIGPEV-UHFFFAOYSA-K 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- YNRRZINZEMMGJB-UHFFFAOYSA-N C1(C=CC=C1)[V] Chemical class C1(C=CC=C1)[V] YNRRZINZEMMGJB-UHFFFAOYSA-N 0.000 description 1
- MXVFWIHIMKGTFU-UHFFFAOYSA-N C1=CC=CC1[Hf] Chemical compound C1=CC=CC1[Hf] MXVFWIHIMKGTFU-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- JFWBIRAGFWPMTI-UHFFFAOYSA-N [Zr].[CH]1C=CC=C1 Chemical class [Zr].[CH]1C=CC=C1 JFWBIRAGFWPMTI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229920001585 atactic polymer Polymers 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- SRKKQWSERFMTOX-UHFFFAOYSA-N cyclopentane;titanium Chemical compound [Ti].[CH]1C=CC=C1 SRKKQWSERFMTOX-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11539584A JPS60260602A (ja) | 1984-06-07 | 1984-06-07 | ポリオレフィンの製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11539584A JPS60260602A (ja) | 1984-06-07 | 1984-06-07 | ポリオレフィンの製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60260602A JPS60260602A (ja) | 1985-12-23 |
| JPH0441166B2 true JPH0441166B2 (fr) | 1992-07-07 |
Family
ID=14661492
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11539584A Granted JPS60260602A (ja) | 1984-06-07 | 1984-06-07 | ポリオレフィンの製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60260602A (fr) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5252693A (en) * | 1986-07-18 | 1993-10-12 | Idemitsu Kosan Company Limited | Syndiotactic styrene polymers |
| US5700750A (en) * | 1985-12-26 | 1997-12-23 | Mitsui Petrochemical Industries, Ltd. | Process for polymerization of alpha-olefins |
| JP2610796B2 (ja) * | 1986-09-24 | 1997-05-14 | 三井石油化学工業株式会社 | オレフィンの重合方法 |
| ATE89836T1 (de) | 1986-09-24 | 1993-06-15 | Mitsui Petrochemical Ind | Polymerisierungsverfahren fuer olefine. |
| JPH0780937B2 (ja) * | 1986-10-01 | 1995-08-30 | 三井石油化学工業株式会社 | オレフインの重合方法 |
| JP2502071B2 (ja) * | 1986-09-24 | 1996-05-29 | 三井石油化学工業株式会社 | オレフインの重合方法 |
| US5700749A (en) * | 1986-09-24 | 1997-12-23 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing olefins |
| JPH0780933B2 (ja) * | 1986-11-20 | 1995-08-30 | 三井石油化学工業株式会社 | オレフインの重合方法 |
| IL84797A (en) * | 1986-12-15 | 1993-01-14 | Montedison Spa | Production of crystalline vinyl aromatic polymers having mainly a syndiotactic structure |
| JPH0794498B2 (ja) * | 1987-04-20 | 1995-10-11 | 三井石油化学工業株式会社 | オレフインの重合方法 |
| US5122491A (en) * | 1987-04-20 | 1992-06-16 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
| JP2698085B2 (ja) * | 1988-01-19 | 1998-01-19 | 出光興産株式会社 | スチレン系重合体の製造方法とその触媒 |
| US5340786A (en) * | 1988-02-12 | 1994-08-23 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst and process for the polymerization of olefins |
| JP2501865B2 (ja) * | 1988-04-09 | 1996-05-29 | 三井石油化学工業株式会社 | アルミノオキサン化合物の炭化水素溶液 |
| US5321107A (en) * | 1989-01-31 | 1994-06-14 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst and process for the polymerization of olefins |
| US5157008A (en) * | 1991-08-01 | 1992-10-20 | Ethyl Corporation | Hydrocarbon solutions of alkylaluminoxane compounds |
| US5391660A (en) * | 1992-01-14 | 1995-02-21 | Nippon Oil Company, Limited | Process for preparing polyolefines |
| JPH0733821A (ja) * | 1993-07-22 | 1995-02-03 | Nippon Oil Co Ltd | オレフィン類重合用触媒成分 |
| CA2129794A1 (fr) * | 1993-08-10 | 1995-02-11 | Toshiyuki Tsutsui | Catalyseurs pour la polymerisation d'olefines et methodes a cette fin |
| JP2752964B2 (ja) * | 1996-08-19 | 1998-05-18 | 三井化学株式会社 | オレフィンの重合方法 |
| US6664208B1 (en) | 1999-09-07 | 2003-12-16 | Sumitomo Chemical Company, Limited | Modified aluminum oxy compound, polymerization catalyst and process for producing olefin polymer and alkenyl aromatic hydrocarbon polymer |
| JP2007182495A (ja) | 2006-01-06 | 2007-07-19 | Idemitsu Kosan Co Ltd | ポリオレフィンの製造方法およびその製造に用いる触媒成分 |
| JP2008201709A (ja) * | 2007-02-20 | 2008-09-04 | Sumitomo Chemical Co Ltd | バナジウム錯体、オレフィン重合用触媒及びオレフィン重合体の製造方法 |
| JP5611833B2 (ja) | 2008-11-11 | 2014-10-22 | 東ソー・ファインケム株式会社 | 固体状ポリメチルアルミノキサン組成物およびその製造方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3242099A (en) * | 1964-03-27 | 1966-03-22 | Union Carbide Corp | Olefin polymerization catalysts |
| JPS5819309A (ja) * | 1981-07-09 | 1983-02-04 | ヘキスト・アクチエンゲゼルシヤフト | ポリオレフインの製造法 |
| US4404344A (en) * | 1980-02-29 | 1983-09-13 | Basf Aktiengesellschaft | Preparing ethylene polymers using Ziegler catalyst comprising cyclodienyl compound of zirconium |
| JPS60245605A (ja) * | 1984-05-22 | 1985-12-05 | Idemitsu Kosan Co Ltd | ポリオレフィンの製造法 |
-
1984
- 1984-06-07 JP JP11539584A patent/JPS60260602A/ja active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3242099A (en) * | 1964-03-27 | 1966-03-22 | Union Carbide Corp | Olefin polymerization catalysts |
| US4404344A (en) * | 1980-02-29 | 1983-09-13 | Basf Aktiengesellschaft | Preparing ethylene polymers using Ziegler catalyst comprising cyclodienyl compound of zirconium |
| JPS5819309A (ja) * | 1981-07-09 | 1983-02-04 | ヘキスト・アクチエンゲゼルシヤフト | ポリオレフインの製造法 |
| JPS60245605A (ja) * | 1984-05-22 | 1985-12-05 | Idemitsu Kosan Co Ltd | ポリオレフィンの製造法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60260602A (ja) | 1985-12-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |