JPH042947B2 - - Google Patents
Info
- Publication number
- JPH042947B2 JPH042947B2 JP6972485A JP6972485A JPH042947B2 JP H042947 B2 JPH042947 B2 JP H042947B2 JP 6972485 A JP6972485 A JP 6972485A JP 6972485 A JP6972485 A JP 6972485A JP H042947 B2 JPH042947 B2 JP H042947B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- general formula
- layer
- charge
- substituent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000049 pigment Substances 0.000 claims description 40
- 108091008695 photoreceptors Proteins 0.000 claims description 38
- 125000001424 substituent group Chemical group 0.000 claims description 18
- 125000000623 heterocyclic group Chemical group 0.000 claims description 17
- 125000003118 aryl group Chemical group 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- 125000003277 amino group Chemical group 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 125000003367 polycyclic group Chemical group 0.000 claims description 4
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 3
- 125000000732 arylene group Chemical group 0.000 claims description 3
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- 230000032258 transport Effects 0.000 description 35
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 23
- -1 etc.) Chemical group 0.000 description 23
- 238000000576 coating method Methods 0.000 description 13
- 229920005989 resin Polymers 0.000 description 13
- 239000011347 resin Substances 0.000 description 13
- 239000000126 substance Substances 0.000 description 13
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 12
- 239000010408 film Substances 0.000 description 11
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 10
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- DNXIASIHZYFFRO-UHFFFAOYSA-N pyrazoline Chemical compound C1CN=NC1 DNXIASIHZYFFRO-UHFFFAOYSA-N 0.000 description 10
- 230000035945 sensitivity Effects 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 8
- 239000005018 casein Substances 0.000 description 8
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 8
- 235000021240 caseins Nutrition 0.000 description 8
- 238000001035 drying Methods 0.000 description 8
- 239000000975 dye Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000012546 transfer Methods 0.000 description 8
- 239000002800 charge carrier Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 6
- TXCDCPKCNAJMEE-UHFFFAOYSA-N dibenzofuran Chemical compound C1=CC=C2C3=CC=CC=C3OC2=C1 TXCDCPKCNAJMEE-UHFFFAOYSA-N 0.000 description 6
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 6
- 125000004076 pyridyl group Chemical group 0.000 description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000006193 diazotization reaction Methods 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 4
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 4
- 230000008878 coupling Effects 0.000 description 4
- 238000010168 coupling process Methods 0.000 description 4
- 238000005859 coupling reaction Methods 0.000 description 4
- 239000012860 organic pigment Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920002382 photo conductive polymer Polymers 0.000 description 3
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- VHQGURIJMFPBKS-UHFFFAOYSA-N 2,4,7-trinitrofluoren-9-one Chemical compound [O-][N+](=O)C1=CC([N+]([O-])=O)=C2C3=CC=C([N+](=O)[O-])C=C3C(=O)C2=C1 VHQGURIJMFPBKS-UHFFFAOYSA-N 0.000 description 2
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- MYONAGGJKCJOBT-UHFFFAOYSA-N benzimidazol-2-one Chemical compound C1=CC=CC2=NC(=O)N=C21 MYONAGGJKCJOBT-UHFFFAOYSA-N 0.000 description 2
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical compound C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 230000005525 hole transport Effects 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920001230 polyarylate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 150000003219 pyrazolines Chemical class 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 1
- 125000006569 (C5-C6) heterocyclic group Chemical group 0.000 description 1
- ZXBSSAFKXWFUMF-UHFFFAOYSA-N 1,2,3-trinitrofluoren-9-one Chemical compound C12=CC=CC=C2C(=O)C2=C1C=C([N+](=O)[O-])C([N+]([O-])=O)=C2[N+]([O-])=O ZXBSSAFKXWFUMF-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical group ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- 125000002030 1,2-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([*:2])C([H])=C1[H] 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- WQGWMEKAPOBYFV-UHFFFAOYSA-N 1,5,7-trinitrothioxanthen-9-one Chemical compound C1=CC([N+]([O-])=O)=C2C(=O)C3=CC([N+](=O)[O-])=CC([N+]([O-])=O)=C3SC2=C1 WQGWMEKAPOBYFV-UHFFFAOYSA-N 0.000 description 1
- LFKNYYQRWMMFSM-UHFFFAOYSA-N 1-ethyl-9h-carbazole;formaldehyde Chemical compound O=C.N1C2=CC=CC=C2C2=C1C(CC)=CC=C2 LFKNYYQRWMMFSM-UHFFFAOYSA-N 0.000 description 1
- MYKQKWIPLZEVOW-UHFFFAOYSA-N 11h-benzo[a]carbazole Chemical compound C1=CC2=CC=CC=C2C2=C1C1=CC=CC=C1N2 MYKQKWIPLZEVOW-UHFFFAOYSA-N 0.000 description 1
- JOERSAVCLPYNIZ-UHFFFAOYSA-N 2,4,5,7-tetranitrofluoren-9-one Chemical compound O=C1C2=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C2C2=C1C=C([N+](=O)[O-])C=C2[N+]([O-])=O JOERSAVCLPYNIZ-UHFFFAOYSA-N 0.000 description 1
- FVNMKGQIOLSWHJ-UHFFFAOYSA-N 2,4,5,7-tetranitroxanthen-9-one Chemical compound C1=C([N+]([O-])=O)C=C2C(=O)C3=CC([N+](=O)[O-])=CC([N+]([O-])=O)=C3OC2=C1[N+]([O-])=O FVNMKGQIOLSWHJ-UHFFFAOYSA-N 0.000 description 1
- NAZDVUBIEPVUKE-UHFFFAOYSA-N 2,5-dimethoxyaniline Chemical compound COC1=CC=C(OC)C(N)=C1 NAZDVUBIEPVUKE-UHFFFAOYSA-N 0.000 description 1
- WCQLACGUXBFKGM-UHFFFAOYSA-N 2-(2,4,7-trinitro-1-oxo-2h-fluoren-9-ylidene)propanedinitrile Chemical compound [O-][N+](=O)C1=CC=C2C(C(=CC(C3=O)[N+](=O)[O-])[N+]([O-])=O)=C3C(=C(C#N)C#N)C2=C1 WCQLACGUXBFKGM-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- JFGQHAHJWJBOPD-UHFFFAOYSA-N 3-hydroxy-n-phenylnaphthalene-2-carboxamide Chemical compound OC1=CC2=CC=CC=C2C=C1C(=O)NC1=CC=CC=C1 JFGQHAHJWJBOPD-UHFFFAOYSA-N 0.000 description 1
- XXWVEJFXXLLAIB-UHFFFAOYSA-N 4-[[4-(diethylamino)-2-methylphenyl]-phenylmethyl]-n,n-diethyl-3-methylaniline Chemical compound CC1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)N(CC)CC)C)C1=CC=CC=C1 XXWVEJFXXLLAIB-UHFFFAOYSA-N 0.000 description 1
- PLAZXGNBGZYJSA-UHFFFAOYSA-N 9-ethylcarbazole Chemical compound C1=CC=C2N(CC)C3=CC=CC=C3C2=C1 PLAZXGNBGZYJSA-UHFFFAOYSA-N 0.000 description 1
- LSZJZNNASZFXKN-UHFFFAOYSA-N 9-propan-2-ylcarbazole Chemical compound C1=CC=C2N(C(C)C)C3=CC=CC=C3C2=C1 LSZJZNNASZFXKN-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229920001893 acrylonitrile styrene Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 125000004653 anthracenylene group Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- MGIAHHJRDZCTHG-UHFFFAOYSA-N benzene-1,3-dicarboxylic acid;terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1.OC(=O)C1=CC=CC(C(O)=O)=C1 MGIAHHJRDZCTHG-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000009125 cardiac resynchronization therapy Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 125000006575 electron-withdrawing group Chemical group 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000002541 furyl group Chemical group 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 125000002346 iodo group Chemical group I* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000010147 laser engraving Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000007760 metering rod coating Methods 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- FTMRMQALUDDFQO-UHFFFAOYSA-N naphtho[2,3-b][1]benzofuran Chemical compound C1=CC=C2C=C3C4=CC=CC=C4OC3=CC2=C1 FTMRMQALUDDFQO-UHFFFAOYSA-N 0.000 description 1
- 125000004957 naphthylene group Chemical group 0.000 description 1
- 125000004923 naphthylmethyl group Chemical group C1(=CC=CC2=CC=CC=C12)C* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000004866 oxadiazoles Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229920006287 phenoxy resin Polymers 0.000 description 1
- 239000013034 phenoxy resin Substances 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- RCYFOPUXRMOLQM-UHFFFAOYSA-N pyrene-1-carbaldehyde Chemical compound C1=C2C(C=O)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 RCYFOPUXRMOLQM-UHFFFAOYSA-N 0.000 description 1
- 125000001725 pyrenyl group Chemical group 0.000 description 1
- 125000005493 quinolyl group Chemical group 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- NLDYACGHTUPAQU-UHFFFAOYSA-N tetracyanoethylene Chemical group N#CC(C#N)=C(C#N)C#N NLDYACGHTUPAQU-UHFFFAOYSA-N 0.000 description 1
- PCCVSPMFGIFTHU-UHFFFAOYSA-N tetracyanoquinodimethane Chemical compound N#CC(C#N)=C1C=CC(=C(C#N)C#N)C=C1 PCCVSPMFGIFTHU-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 125000004001 thioalkyl group Chemical group 0.000 description 1
- 125000004014 thioethyl group Chemical group [H]SC([H])([H])C([H])([H])* 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- 125000004055 thiomethyl group Chemical group [H]SC([H])([H])* 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 125000004035 thiopropyl group Chemical group [H]SC([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- PBIMIGNDTBRRPI-UHFFFAOYSA-N trifluoro borate Chemical class FOB(OF)OF PBIMIGNDTBRRPI-UHFFFAOYSA-N 0.000 description 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Photoreceptors In Electrophotography (AREA)
Description
ãç£æ¥äžã®å©çšåéã
æ¬çºæã¯é»ååçæå
äœã«é¢ãããšãã«ç¹å®ã®
ã¢ãŸé¡æãæå å±€ã«å«æãããé»ååçæå äœã«
é¢ããã ãåŸæ¥æè¡ã ãããŸã§ã»ã¬ã³ãç¡«åã«ãããŠã ãé žåäºéãª
ã©ã®ç¡æ©å å°é»äœãæå æåãšããŠå©çšããé»å
åçæå äœã¯å ¬ç¥ã§ããã äžæ¹ãç¹å®ã®ææ©ååç©ãå å°é»æ§ã瀺ãããš
ãçºèŠãããŠãããæ°å€ãã®ææ©å å°é»äœãéçº
ãããŠæ¥ããäŸãã°ãããªââããã«ã«ã«ããŸ
ãŒã«ãããªããã«ã¢ã³ãã©ã»ã³ãªã©ã®ææ©å å°é»
æ§ããªããŒãã«ã«ããŸãŒã«ãã¢ã³ãã©ã»ã³ããã©
ãŸãªã³é¡ããªããµãžã¢ãŸãŒã«é¡ãããã©ãŸã³é¡ã
ããªã¢ãªãŒã«ã¢ã«ã«ã³é¡ãªã©ã®äœååã®ææ©å å°
é»äœããã¿ãã·ã¢ãã³é¡æãã¢ãŸé¡æãã·ã¢ãã³
ææãå€ç°ããã³é¡æãããªã¬ã³ç³»é¡æãã€ã³ãž
ãŽææãããªã€ã³ãžãŽææãããã¯ã¹ã¯ãšã¢ãªã
ã¯é žã¡ãã³ææãªã©ã®ææ©é¡æãææãç¥ãããŠ
ãããç¹ã«å å°é»æ§ãæããææ©é¡æãææã¯ã
ç¡æ©ææã«èŒã¹ãŠåæã容æã§ããããé©åœãªæ³¢
é·åã«å å°é»æ§ã瀺ãååç©ãéžæã§ããããªãš
ãŒã·ãšã³ãæ¡å€§ãããããšãªã©ãããæ°å€ãã®å
å°é»æ§ææ©é¡æãææãææ¡ãããŠãããäŸã
ã°ãç±³åœç¹èš±ç¬¬4123270å·ãå第4247614å·ãå第
4251613å·ãå第4251614å·ãå第4256821å·ãå
第4260672å·ãå第4268596å·ãå第4278747å·ã
å第4293628å·ãªã©ã«é瀺ãããæ§ã«é»è·çºçå±€
ãšé»è·èŒžéå±€ã«æ©èœåé¢ããæå å±€ã«ãããé»è·
çºçç©è³ªãšããŠå å°é»æ§ã瀺ããžã¹ã¢ãŸé¡æãçš
ããé»ååçæå äœãªã©ãç¥ãããŠããã ãã®æ§ãªææ©å å°é»äœãçšããé»ååçæå äœ
ã¯ããã€ã³ããŒãé©åœã«éžæããããšã«ãã€ãŠå¡
å·¥æ¹æ³ã§çç£ã§ããããã極ããŠçç£æ§ãé«ãã
å®äŸ¡ãªæå äœãæäŸã§ãããããææ©é¡æã®éžæ
ã«ãã€ãŠæå æ³¢é·åãèªåšã«ã³ã³ãããŒã«ã§ãã
å©ç¹ãæããŠããåé¢ããã®æå äœã¯æ床åã³è
ä¹ æ§ã«å£ããããããŸã§å®çšåãããŠãããã®ã¯
ããå ãã§ããã ãçºæã解決ããããšããåé¡ç¹ã æ¬çºæã®ç®çã¯æ°èŠãªé»ååçæå äœãæäŸã
ãããšã«ããã æ¬çºæã®å¥ã®ç®çã¯å®çšäžããããæ床ãšèä¹
æ§ãåããé»ååçæå äœãæäŸããããšã«ã
ãã ãåé¡ç¹ã解決ããããã®æ段ã å³ã¡ãæ¬çºæã¯ã次ã®äžè¬åŒïŒ ïŒåŒäžAr1ãAr6ã¯ãããã眮æåºãæããŠãã
ãã¢ãªãŒã¬ã³åºãããã¯ïŒäŸ¡ã®è€çŽ ç°åºã瀺ãã
ïœåã³ïœã¯ããããïŒãããã¯ïŒã瀺ããã¯ã
ãšããŒã«æ§OHåºãæããã«ãã©ãŒæ®åºã瀺ãïŒ
ã§è¡šããããã¢ãŸé¡æãæå å±€ã«å«æãããããš
ãç¹åŸŽãšããé»ååçæå äœãæäŸãããã äžèšäžè¬åŒ(1)ã«ãããŠAr1ãAr6ã®å®çŸ©ãšããŠ
ã¢ãªãŒã¬ã³åºã¯äŸãã°ãããšãã¬ã³ããããšãã¬
ã³ããããã¬ã³ãã¢ã³ã¹ãªã¬ã³ãªã©ãæããã
ãããŸãè€çŽ ç°åºãšããŠã¯ããªãžã³ããããªã³ã
ããªããšã³ãã«ã«ããŸãŒã«ãªã©ã®ïŒäŸ¡ãäŸç€ºãã
ããAr1ãAr6ã¯æŽã«çœ®æåºãæããŠããããã
ãã眮æåºãšããŠã¯ããã²ã³ïŒããçŽ ãå¡©çŽ ãè
çŽ ããšãŒãïŒãã¢ã«ãã«åºïŒã¡ãã«ããšãã«ãã
ããã«ãªã©ïŒãã¢ã«ã³ãã·åºïŒã¡ããã·ããšãã
ã·ãããããã·ãªã©ïŒãããªã¢ã«ãã«åºïŒããªã¡
ãã«ãããªãšãã«ãããªãããã«ãªã©ïŒããããã
ã·ã¢ããããªãã«ãªãã¡ãã«ãªã©ãæããããã ããã«ãäžè¬åŒ(1)ã«ãããã®ããšããŒã«æ§
OHåºãæããã«ãã©ãŒæ®åºãšããŠã¯ãäŸãã°äž
èšã®äžè¬åŒ(2)ã(8)ã瀺ãããïŒ ïŒåŒäžïŒžã¯ãã³ãŒã³ç°ãšçž®åããŠå€ç°è³éŠç°ãã
ãã¯è€çŽ ç°ã圢æããæ®åºïŒR3ããã³R4ã¯æ°ŽçŽ ã
眮æåºãæããŠãããã¢ã«ãã«ãã¢ã©ã«ãã«ãã¢
ãªãŒã«ãããã¯è€çŽ ç°åºãŸãã¯äžç·ã«ãªã€ãŠçªçŽ
ååãšå ±ã«ç°ç¶ã¢ããåºã圢æããïŒR5åã³R6
ã¯ãããã眮æåºãæããŠãããã¢ã«ãã«ãã¢ã©
ã«ãã«ãã¢ãªãŒã«ã瀺ãïŒïŒ¹ã¯è³éŠæçåæ°ŽçŽ ã®
ïŒäŸ¡ã®åºãããã¯çªçŽ ååãšäžç·ã«ãªã€ãŠè€çŽ ç°
ã®ïŒäŸ¡ã®åºã圢æããïŒR7ã¯çœ®æåºãæããŠã
ããã¢ãªãŒã«ãããã¯è€çŽ ç°åºã瀺ãïŒR8åã³
R9ã¯ãããã眮æåºãæããŠãããã¢ã«ãã«ã
ã¢ã©ã«ãã«ãã¢ãªãŒã«ãããã¯è€çŽ ç°åºã瀺ãïŒã äžèšïŒžã®å€ç°è³éŠç°ãšããŠã¯äŸãã°ããã¿ã¬
ã³ãã¢ã³ãã©ã»ã³ãã«ã«ããŸãŒã«ããã³ãºã«ã«ã
ãŸãŒã«ããžãã³ãŸãã©ã³ããã³ãŸããããã©ã³ã
ãžããšãã¬ã³ãµã«ãã¢ã€ããªã©ã瀺ãããããã
ãã¯åèšã®åŠã眮æåºã§çœ®æãããŠãããããŸã
R3ãR4ã®å Žåã¢ã«ãã«ã¯äŸãã°ã¡ãã«ããšãã«ã
ãããã«ãããã«ãªã©ã瀺ãããã¢ã©ã«ãã«ã¯äŸ
ãã°ãã³ãžã«ãããšããã«ããããã«ã¡ãã«ãªã©
ã§ãããã¢ãªãŒã«ã¯äŸãã°ããšãã«ããžããšã
ã«ããããã«ãã¢ã³ã¹ãªã«ãªã©ã§ããããšãã«
R3ãæ°ŽçŽ ã§ããR4ãïœâäœã«ããã²ã³ããããã
ã·ã¢ããããªãã«ãªãã¡ãã«ãªã©ã®é»ååžåŒæ§åº
ãæããããšãã«åºã§ããæ§é ãæããååç©ã
奜ãŸããããããã¯çœ®æåºãæããŠãããã è€çŽ ç°ãšããŠã¯ã«ã«ããŸãŒã«ããžãã³ãŸãã©
ã³ããã³ãºã€ãããŸãã³ããã³ãºãã¢ãŸãŒã«ãã
ã¢ãŸãŒã«ãããªãžã³ãªã©ãäŸç€ºãããã R5åã³R6ã®å ·äœäŸã¯åèšR3ãR4ã§äŸç€ºããã
ãã®ãšåããã®ãæããããããããã¯åèšã®åŠ
ã眮æåºã§çœ®æãããŠãããã ã®å®çŸ©ã«ãããŠïŒäŸ¡ã®è³éŠæçåæ°ŽçŽ ãšããŠ
ã¯äŸãã°ïœâããšãã¬ã³ã®åŠãåç°åŒè³éŠæçå
æ°ŽçŽ åºãïœâãããã¬ã³ãããªãããã¬ã³ãïŒïŒ
ïŒâã¢ã³ã¹ãªã¬ã³ãïŒïŒ10âããšãã³ã¹ãªã¬ã³ãª
ã©ã®çž®åå€ç°åŒè³éŠæçåæ°ŽçŽ åºãæããããã ãŸãçªçŽ ååãšäžç·ã«ãªã€ãŠïŒäŸ¡ã®è€çŽ ç°ã圢
æããäŸãšããŠã¯ãïŒïŒïŒâãã©ãŸãŒã«ãžã€ã«
åºãïŒïŒïŒâããªãžã³ãžã€ã«åºãïŒïŒïŒâããªã
ãžã³ãžã€ã«åºãïŒïŒïŒâã€ã³ããŸãŒã«ãžã€ã«åºã
ïŒïŒïŒâãã³ãºã€ãããŸãŒã«ãžã€ã«åºãïŒïŒïŒâ
ãããªã³ãžã€ã«åºçã®ïŒãïŒå¡è€çŽ ç°ã®ïŒäŸ¡ã®åº
ãæããããã R7ã®ã¢ãªãŒã«åºåã¯è€çŽ ç°åºãšããŠã¯ããšã
ã«ããããã«ãã¢ã³ã¹ãªã«ããã¬ãã«ãªã©ïŒããª
ãžã«ãããšãã«ãããªã«ãã«ã«ããŸãªã«ãªã©ãäŸ
瀺ãããããããã¯åèšã®åŠã眮æåºã§çœ®æãã
ãŠãããã R8ãR9ã«ãããã¢ã«ãã«ãã¢ãªãŒã«ãã¢ã©ã«
ãã«ã®å ·äœäŸã¯åèšã®äŸç€ºãšåããã®ãæããã
ããè€çŽ ç°ãšããŠã¯ã«ã«ããŸãŒã«ããžãã³ãŸãã©
ã³ããã³ãºã€ãããŸãã³ããã³ãºãã¢ãŸãŒã«ãã
ã¢ãŸãŒã«ãããªãžã³ãªã©ãäŸç€ºãããããããã¯
åèšã®åŠã眮æåºã§çœ®æãããŠãããã æ¬çºæã«ãããŠã¯çè«ã«ææããããã®ã§ã¯ãª
ãããäžè¬åŒ(1)ã®ã¢ãŸé¡æã®éªšæ Œããªã
ã¢ãŸé¡æãæå å±€ã«å«æãããé»ååçæå äœã«
é¢ããã ãåŸæ¥æè¡ã ãããŸã§ã»ã¬ã³ãç¡«åã«ãããŠã ãé žåäºéãª
ã©ã®ç¡æ©å å°é»äœãæå æåãšããŠå©çšããé»å
åçæå äœã¯å ¬ç¥ã§ããã äžæ¹ãç¹å®ã®ææ©ååç©ãå å°é»æ§ã瀺ãããš
ãçºèŠãããŠãããæ°å€ãã®ææ©å å°é»äœãéçº
ãããŠæ¥ããäŸãã°ãããªââããã«ã«ã«ããŸ
ãŒã«ãããªããã«ã¢ã³ãã©ã»ã³ãªã©ã®ææ©å å°é»
æ§ããªããŒãã«ã«ããŸãŒã«ãã¢ã³ãã©ã»ã³ããã©
ãŸãªã³é¡ããªããµãžã¢ãŸãŒã«é¡ãããã©ãŸã³é¡ã
ããªã¢ãªãŒã«ã¢ã«ã«ã³é¡ãªã©ã®äœååã®ææ©å å°
é»äœããã¿ãã·ã¢ãã³é¡æãã¢ãŸé¡æãã·ã¢ãã³
ææãå€ç°ããã³é¡æãããªã¬ã³ç³»é¡æãã€ã³ãž
ãŽææãããªã€ã³ãžãŽææãããã¯ã¹ã¯ãšã¢ãªã
ã¯é žã¡ãã³ææãªã©ã®ææ©é¡æãææãç¥ãããŠ
ãããç¹ã«å å°é»æ§ãæããææ©é¡æãææã¯ã
ç¡æ©ææã«èŒã¹ãŠåæã容æã§ããããé©åœãªæ³¢
é·åã«å å°é»æ§ã瀺ãååç©ãéžæã§ããããªãš
ãŒã·ãšã³ãæ¡å€§ãããããšãªã©ãããæ°å€ãã®å
å°é»æ§ææ©é¡æãææãææ¡ãããŠãããäŸã
ã°ãç±³åœç¹èš±ç¬¬4123270å·ãå第4247614å·ãå第
4251613å·ãå第4251614å·ãå第4256821å·ãå
第4260672å·ãå第4268596å·ãå第4278747å·ã
å第4293628å·ãªã©ã«é瀺ãããæ§ã«é»è·çºçå±€
ãšé»è·èŒžéå±€ã«æ©èœåé¢ããæå å±€ã«ãããé»è·
çºçç©è³ªãšããŠå å°é»æ§ã瀺ããžã¹ã¢ãŸé¡æãçš
ããé»ååçæå äœãªã©ãç¥ãããŠããã ãã®æ§ãªææ©å å°é»äœãçšããé»ååçæå äœ
ã¯ããã€ã³ããŒãé©åœã«éžæããããšã«ãã€ãŠå¡
å·¥æ¹æ³ã§çç£ã§ããããã極ããŠçç£æ§ãé«ãã
å®äŸ¡ãªæå äœãæäŸã§ãããããææ©é¡æã®éžæ
ã«ãã€ãŠæå æ³¢é·åãèªåšã«ã³ã³ãããŒã«ã§ãã
å©ç¹ãæããŠããåé¢ããã®æå äœã¯æ床åã³è
ä¹ æ§ã«å£ããããããŸã§å®çšåãããŠãããã®ã¯
ããå ãã§ããã ãçºæã解決ããããšããåé¡ç¹ã æ¬çºæã®ç®çã¯æ°èŠãªé»ååçæå äœãæäŸã
ãããšã«ããã æ¬çºæã®å¥ã®ç®çã¯å®çšäžããããæ床ãšèä¹
æ§ãåããé»ååçæå äœãæäŸããããšã«ã
ãã ãåé¡ç¹ã解決ããããã®æ段ã å³ã¡ãæ¬çºæã¯ã次ã®äžè¬åŒïŒ ïŒåŒäžAr1ãAr6ã¯ãããã眮æåºãæããŠãã
ãã¢ãªãŒã¬ã³åºãããã¯ïŒäŸ¡ã®è€çŽ ç°åºã瀺ãã
ïœåã³ïœã¯ããããïŒãããã¯ïŒã瀺ããã¯ã
ãšããŒã«æ§OHåºãæããã«ãã©ãŒæ®åºã瀺ãïŒ
ã§è¡šããããã¢ãŸé¡æãæå å±€ã«å«æãããããš
ãç¹åŸŽãšããé»ååçæå äœãæäŸãããã äžèšäžè¬åŒ(1)ã«ãããŠAr1ãAr6ã®å®çŸ©ãšããŠ
ã¢ãªãŒã¬ã³åºã¯äŸãã°ãããšãã¬ã³ããããšãã¬
ã³ããããã¬ã³ãã¢ã³ã¹ãªã¬ã³ãªã©ãæããã
ãããŸãè€çŽ ç°åºãšããŠã¯ããªãžã³ããããªã³ã
ããªããšã³ãã«ã«ããŸãŒã«ãªã©ã®ïŒäŸ¡ãäŸç€ºãã
ããAr1ãAr6ã¯æŽã«çœ®æåºãæããŠããããã
ãã眮æåºãšããŠã¯ããã²ã³ïŒããçŽ ãå¡©çŽ ãè
çŽ ããšãŒãïŒãã¢ã«ãã«åºïŒã¡ãã«ããšãã«ãã
ããã«ãªã©ïŒãã¢ã«ã³ãã·åºïŒã¡ããã·ããšãã
ã·ãããããã·ãªã©ïŒãããªã¢ã«ãã«åºïŒããªã¡
ãã«ãããªãšãã«ãããªãããã«ãªã©ïŒããããã
ã·ã¢ããããªãã«ãªãã¡ãã«ãªã©ãæããããã ããã«ãäžè¬åŒ(1)ã«ãããã®ããšããŒã«æ§
OHåºãæããã«ãã©ãŒæ®åºãšããŠã¯ãäŸãã°äž
èšã®äžè¬åŒ(2)ã(8)ã瀺ãããïŒ ïŒåŒäžïŒžã¯ãã³ãŒã³ç°ãšçž®åããŠå€ç°è³éŠç°ãã
ãã¯è€çŽ ç°ã圢æããæ®åºïŒR3ããã³R4ã¯æ°ŽçŽ ã
眮æåºãæããŠãããã¢ã«ãã«ãã¢ã©ã«ãã«ãã¢
ãªãŒã«ãããã¯è€çŽ ç°åºãŸãã¯äžç·ã«ãªã€ãŠçªçŽ
ååãšå ±ã«ç°ç¶ã¢ããåºã圢æããïŒR5åã³R6
ã¯ãããã眮æåºãæããŠãããã¢ã«ãã«ãã¢ã©
ã«ãã«ãã¢ãªãŒã«ã瀺ãïŒïŒ¹ã¯è³éŠæçåæ°ŽçŽ ã®
ïŒäŸ¡ã®åºãããã¯çªçŽ ååãšäžç·ã«ãªã€ãŠè€çŽ ç°
ã®ïŒäŸ¡ã®åºã圢æããïŒR7ã¯çœ®æåºãæããŠã
ããã¢ãªãŒã«ãããã¯è€çŽ ç°åºã瀺ãïŒR8åã³
R9ã¯ãããã眮æåºãæããŠãããã¢ã«ãã«ã
ã¢ã©ã«ãã«ãã¢ãªãŒã«ãããã¯è€çŽ ç°åºã瀺ãïŒã äžèšïŒžã®å€ç°è³éŠç°ãšããŠã¯äŸãã°ããã¿ã¬
ã³ãã¢ã³ãã©ã»ã³ãã«ã«ããŸãŒã«ããã³ãºã«ã«ã
ãŸãŒã«ããžãã³ãŸãã©ã³ããã³ãŸããããã©ã³ã
ãžããšãã¬ã³ãµã«ãã¢ã€ããªã©ã瀺ãããããã
ãã¯åèšã®åŠã眮æåºã§çœ®æãããŠãããããŸã
R3ãR4ã®å Žåã¢ã«ãã«ã¯äŸãã°ã¡ãã«ããšãã«ã
ãããã«ãããã«ãªã©ã瀺ãããã¢ã©ã«ãã«ã¯äŸ
ãã°ãã³ãžã«ãããšããã«ããããã«ã¡ãã«ãªã©
ã§ãããã¢ãªãŒã«ã¯äŸãã°ããšãã«ããžããšã
ã«ããããã«ãã¢ã³ã¹ãªã«ãªã©ã§ããããšãã«
R3ãæ°ŽçŽ ã§ããR4ãïœâäœã«ããã²ã³ããããã
ã·ã¢ããããªãã«ãªãã¡ãã«ãªã©ã®é»ååžåŒæ§åº
ãæããããšãã«åºã§ããæ§é ãæããååç©ã
奜ãŸããããããã¯çœ®æåºãæããŠãããã è€çŽ ç°ãšããŠã¯ã«ã«ããŸãŒã«ããžãã³ãŸãã©
ã³ããã³ãºã€ãããŸãã³ããã³ãºãã¢ãŸãŒã«ãã
ã¢ãŸãŒã«ãããªãžã³ãªã©ãäŸç€ºãããã R5åã³R6ã®å ·äœäŸã¯åèšR3ãR4ã§äŸç€ºããã
ãã®ãšåããã®ãæããããããããã¯åèšã®åŠ
ã眮æåºã§çœ®æãããŠãããã ã®å®çŸ©ã«ãããŠïŒäŸ¡ã®è³éŠæçåæ°ŽçŽ ãšããŠ
ã¯äŸãã°ïœâããšãã¬ã³ã®åŠãåç°åŒè³éŠæçå
æ°ŽçŽ åºãïœâãããã¬ã³ãããªãããã¬ã³ãïŒïŒ
ïŒâã¢ã³ã¹ãªã¬ã³ãïŒïŒ10âããšãã³ã¹ãªã¬ã³ãª
ã©ã®çž®åå€ç°åŒè³éŠæçåæ°ŽçŽ åºãæããããã ãŸãçªçŽ ååãšäžç·ã«ãªã€ãŠïŒäŸ¡ã®è€çŽ ç°ã圢
æããäŸãšããŠã¯ãïŒïŒïŒâãã©ãŸãŒã«ãžã€ã«
åºãïŒïŒïŒâããªãžã³ãžã€ã«åºãïŒïŒïŒâããªã
ãžã³ãžã€ã«åºãïŒïŒïŒâã€ã³ããŸãŒã«ãžã€ã«åºã
ïŒïŒïŒâãã³ãºã€ãããŸãŒã«ãžã€ã«åºãïŒïŒïŒâ
ãããªã³ãžã€ã«åºçã®ïŒãïŒå¡è€çŽ ç°ã®ïŒäŸ¡ã®åº
ãæããããã R7ã®ã¢ãªãŒã«åºåã¯è€çŽ ç°åºãšããŠã¯ããšã
ã«ããããã«ãã¢ã³ã¹ãªã«ããã¬ãã«ãªã©ïŒããª
ãžã«ãããšãã«ãããªã«ãã«ã«ããŸãªã«ãªã©ãäŸ
瀺ãããããããã¯åèšã®åŠã眮æåºã§çœ®æãã
ãŠãããã R8ãR9ã«ãããã¢ã«ãã«ãã¢ãªãŒã«ãã¢ã©ã«
ãã«ã®å ·äœäŸã¯åèšã®äŸç€ºãšåããã®ãæããã
ããè€çŽ ç°ãšããŠã¯ã«ã«ããŸãŒã«ããžãã³ãŸãã©
ã³ããã³ãºã€ãããŸãã³ããã³ãºãã¢ãŸãŒã«ãã
ã¢ãŸãŒã«ãããªãžã³ãªã©ãäŸç€ºãããããããã¯
åèšã®åŠã眮æåºã§çœ®æãããŠãããã æ¬çºæã«ãããŠã¯çè«ã«ææããããã®ã§ã¯ãª
ãããäžè¬åŒ(1)ã®ã¢ãŸé¡æã®éªšæ Œããªã
ãåŒãæ§é ã®çªçŽ ååã®ããŒã³ãã¢
ã«ããé¡æååã®ã¢ãŸåºéã®å
±åœ¹ãä¿ããããã
å ã«ããçæããé»è·ãèªç±ã«ç§»åããåºããã
æã¡ãååéã§ã®é»è·ç§»åãè¯å¥œã«ãããã®ãšè
ããããã åŸã€ãŠäžè¬åŒ(1)ã®ã¢ãŸé¡æãæå å±€ã«å«æãã
ãããšã«ããããã€ãªã€ãŒçºçå¹çåã³ãã€ãªã€
ãŒèŒžéå¹çã®ãã¥ããäžæ¹åã¯åæ¹ãè¯å¥œãšãªã
ããæ床ãåäžãèä¹ äœ¿çšæã«ãããé»äœå®å®æ§
ã確ä¿ãããããšã«ãªãã æŽã«é«æ床ãéæãããã®ã§ã¬ãŒã¶ãŒããŒã ã
ãªã³ã¿ãŒãLEDããªã³ã¿ãŒã液æ¶ããªã³ã¿ãŒãª
ã©ãžã®é©çšãå¯èœãšãªããŸãæå äœã®åæŽã«ãã
ãå®å®ããé»äœã確ä¿ãããããå®å®ããçŸãã
ç»åãåŸãããã æ¬çºæã«çšããããã¢ãŸé¡æã®ä»£è¡šäŸãè¡šïŒã«
åæããã
å ã«ããçæããé»è·ãèªç±ã«ç§»åããåºããã
æã¡ãååéã§ã®é»è·ç§»åãè¯å¥œã«ãããã®ãšè
ããããã åŸã€ãŠäžè¬åŒ(1)ã®ã¢ãŸé¡æãæå å±€ã«å«æãã
ãããšã«ããããã€ãªã€ãŒçºçå¹çåã³ãã€ãªã€
ãŒèŒžéå¹çã®ãã¥ããäžæ¹åã¯åæ¹ãè¯å¥œãšãªã
ããæ床ãåäžãèä¹ äœ¿çšæã«ãããé»äœå®å®æ§
ã確ä¿ãããããšã«ãªãã æŽã«é«æ床ãéæãããã®ã§ã¬ãŒã¶ãŒããŒã ã
ãªã³ã¿ãŒãLEDããªã³ã¿ãŒã液æ¶ããªã³ã¿ãŒãª
ã©ãžã®é©çšãå¯èœãšãªããŸãæå äœã®åæŽã«ãã
ãå®å®ããé»äœã確ä¿ãããããå®å®ããçŸãã
ç»åãåŸãããã æ¬çºæã«çšããããã¢ãŸé¡æã®ä»£è¡šäŸãè¡šïŒã«
åæããã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãããã®ã¢ãŸé¡æã¯ãïŒçš®ãŸãã¯ïŒçš®ä»¥äžçµå
ããŠçšããããšãã§ããã ãŸãããããã®é¡æã¯ãäŸãã°äžéäœã®ããªã
ããååç©ãéå ãäžè¬åŒ ïŒäœãåŒäžã®Ar1ãAr6åã³ïœãïœã¯äžè¬åŒ(1)äž
ã®èšå·ãšåãæå³ã瀺ããïŒ ã§ç€ºãããããªã¢ãã³ãåžžæ³ã«ããã¢ããåºã®ã
ã¹ãŠããžã¢ãŸååå¿ã«ä»ãã次ãã§ããšããŒã«æ§
ã®OHåºãæããã«ãã©ãŒãã¢ã«ã«ãªã®ååšäžã«
ã«ãããªã³ã°ãããããŸãã¯åèšã®ããªã¢ãã³ã®
ãã¹ãŠã®ã¢ããåºããžã¢ãŸååå¿ãããŠåŸããã
ããªã¢ãŸããŠã å¡©ãããŠããåå¡©ãããã¯å¡©åäº
éè€å¡©çã®åœ¢ã§äžæŠåé¢ããåŸãé©åœãªæº¶åªäŸã
ã°ïŒ®ïŒïŒ®âãžã¡ãã«ãã«ã ã¢ããããžã¡ãã«ã¹ã«
ããã·ãçã®æº¶åªäžã§ã¢ã«ã«ãªã®ååšäžã«ã«ãã©
ãŒãšã«ãããªã³ã°ããããšã«ãã容æã«è£œé ãã
ããšãã§ããã åãå¥ã®æ¹æ³ãšããŠã¯åæã®
ããŠçšããããšãã§ããã ãŸãããããã®é¡æã¯ãäŸãã°äžéäœã®ããªã
ããååç©ãéå ãäžè¬åŒ ïŒäœãåŒäžã®Ar1ãAr6åã³ïœãïœã¯äžè¬åŒ(1)äž
ã®èšå·ãšåãæå³ã瀺ããïŒ ã§ç€ºãããããªã¢ãã³ãåžžæ³ã«ããã¢ããåºã®ã
ã¹ãŠããžã¢ãŸååå¿ã«ä»ãã次ãã§ããšããŒã«æ§
ã®OHåºãæããã«ãã©ãŒãã¢ã«ã«ãªã®ååšäžã«
ã«ãããªã³ã°ãããããŸãã¯åèšã®ããªã¢ãã³ã®
ãã¹ãŠã®ã¢ããåºããžã¢ãŸååå¿ãããŠåŸããã
ããªã¢ãŸããŠã å¡©ãããŠããåå¡©ãããã¯å¡©åäº
éè€å¡©çã®åœ¢ã§äžæŠåé¢ããåŸãé©åœãªæº¶åªäŸã
ã°ïŒ®ïŒïŒ®âãžã¡ãã«ãã«ã ã¢ããããžã¡ãã«ã¹ã«
ããã·ãçã®æº¶åªäžã§ã¢ã«ã«ãªã®ååšäžã«ã«ãã©
ãŒãšã«ãããªã³ã°ããããšã«ãã容æã«è£œé ãã
ããšãã§ããã åãå¥ã®æ¹æ³ãšããŠã¯åæã®
ãåŒããçšããžã¢ãŸååå¿
ãã察å¿ãããããµãŸããŠã å¡©ãåæããã€ãã§
ãã®ãããµãŸããŠã å¡©ïŒã¢ã«ã«å¯Ÿãçã¢ã«ã®
HArâNH2ããªããã¯ïŒåã¢ã«ã®HArâNH2ãª
ããã¯ïŒåã¢ã«ã®HArâNH2ãé žæ§ã«ãããªã³
ã°ã«ããåå¿ãããããåŸãããååç©äžã®ã¢ã
ãåºãæŽã«ãžã¢ãŸååå¿ã«ä»ããåŸåèšãšåæ§ã«
ããšããŒã«æ§OHåºãæããã«ãã©ãŒãšã«ãããª
ã³ã°åå¿ãããããšã«ããåèšäžè¬åŒ(1)ã«å¯Ÿå¿ã
ãã¢ãŸé¡æãåæããããšãã§ããã åèšHArâNHäžã®Arã¯äžè¬åŒ(1)äžã®Ar2ã
Ar4ãAr6ããéžæãããåºã瀺ãã 次ã«æ¬çºæã§çšããã¢ãŸé¡æã®ä»£è¡šçåæäŸã
説æããã åæäŸ ïŒ ïŒåèšäŸç€ºããªã¢ãŸé¡æNo.ïŒã®åæïŒ
ãã®ãããµãŸããŠã å¡©ïŒã¢ã«ã«å¯Ÿãçã¢ã«ã®
HArâNH2ããªããã¯ïŒåã¢ã«ã®HArâNH2ãª
ããã¯ïŒåã¢ã«ã®HArâNH2ãé žæ§ã«ãããªã³
ã°ã«ããåå¿ãããããåŸãããååç©äžã®ã¢ã
ãåºãæŽã«ãžã¢ãŸååå¿ã«ä»ããåŸåèšãšåæ§ã«
ããšããŒã«æ§OHåºãæããã«ãã©ãŒãšã«ãããª
ã³ã°åå¿ãããããšã«ããåèšäžè¬åŒ(1)ã«å¯Ÿå¿ã
ãã¢ãŸé¡æãåæããããšãã§ããã åèšHArâNHäžã®Arã¯äžè¬åŒ(1)äžã®Ar2ã
Ar4ãAr6ããéžæãããåºã瀺ãã 次ã«æ¬çºæã§çšããã¢ãŸé¡æã®ä»£è¡šçåæäŸã
説æããã åæäŸ ïŒ ïŒåèšäŸç€ºããªã¢ãŸé¡æNo.ïŒã®åæïŒ
ãåŒããšïŒïŒïŒâãžã¡ããã·
ã¢ããªã³ãåžžæ³ã«ããã¢ã«æ¯ïŒïŒïŒã§é
žæ§ã«ãã
ãªã³ã°ããã ãåæããã®ååç©ãæŽã«ãžã¢ãŸååå¿ã«ä»ãã
åŸNa+BF4 -ã«ããåŠçã㊠ã容æã«åŸãããã ãã®ããªãã«ãªããã¬ãŒã21.6ïœïŒ0.03ã¢ã«ïŒ
ãïŒããŒã«ãŒäžã®DMF1.8ã«æº¶è§£ãæŽã«ã«ã
ã©ãŒæåãšããŠïŒâããããã·âïŒâããããšé ž
ã¢ããªã24.5ïœïŒ0.093ã¢ã«ïŒã溶解ã液枩ãïŒ
âãŸã§å·åŽããã ãã®æº¶æ¶²ãæ¹æããªãããã®æº¶æ¶²äžãžããªãšã
ã«ã¢ãã³61.7ïœïŒ0.61ã¢ã«ïŒã30åãããŠæ¶²æž©ã
ïŒã10âã«ä¿ã¡ãªãã滎äžããã滎äžçµäºåŸæŽã«
ïŒæéæ¹æã宀枩ã§ïŒæ©æŸçœ®åŸåå¿æ¶²ãæ¿Ÿéã
ãã åŸãããé¡æãæ°ŽïŒã§æ¹æãæŽæµãæ¿ŸéãïŒ
åããè¿ããåŸDMF600mlã§ïŒåãMEK600mlã§
ïŒåããããæ¹æãæŽæµãæ¿Ÿéãé 次ããè¿ã
ãã åŸãããããŒã¹ãç¶ç©ã宀枩ã§é颚也ç¥ã31.8
ïœïŒåç83ïŒ ïŒã®é¡æãåŸãã èç¹ 250â以äžã å çŽ åæ èšç®å€ïŒ å®æž¬å€ïŒ  72.39 72.31  4.43 4.46  13.16 13.08 æ¬çºæã®å¥œãŸããå ·äœäŸã§ã¯ãæå å±€ãé»è·çº
çå±€ãšé»è·èŒžéå±€ã«æ©èœåé¢ããé»ååçæå äœ
ã«ãããé»è·çºçç©è³ªã«åèšäžè¬åŒ(1)ã«ç€ºãã¢ãŸ
é¡æãçšããããšãã§ãããé»è·çºçå±€ã¯ãåå
ãªåžå 床ãåŸãããã«ãã§ããéãå€ãã®åèšã¢
ãŸé¡æãå«æããäžã€çºçããé»è·ãã€ãªã¢ãé»
è·çºçå±€å ã§ãã©ãããããããšãé²ãããã«ã
èèå±€ãäŸãã°ïŒãã¯ãã³ä»¥äžã奜ãŸããã¯0.01
ãã¯ãã³ãïŒãã¯ãã³ã®èèããã€èèå±€ãšãã
ããšã奜ãŸããããã®ããšã¯ãå ¥å°å éã®å€§éšå
ãé»è·çºçå±€ã§åžåãããŠãå€ãã®é»è·ãã€ãªã¢
ãçæããããšãããã«çºçããé»è·ãã€ãªã¢ã
åçµåãæç²ïŒãã©ããïŒã«ãã倱掻ããããšãª
ãé»è·èŒžéå±€ã«æ³šå ¥ããå¿ èŠãããããšã«åž°å ã
ãŠããã é»è·çºçå±€ã¯ãåè¿°ã®ã¢ãŸé¡æãé©åœãªãã€ã³
ããŒã«åæ£ããããããåºäœã®äžã«å¡å·¥ããããš
ã«ãã€ãŠåœ¢æã§ãããŸãç空èžçè£ çœ®ã«ããèžç
èã圢æããããšã«ãã€ãŠåŸãããšãã§ãããé»
è·çºçå±€ãå¡å·¥ã«ãã€ãŠåœ¢æããéã«çšãããã
ã€ã³ããŒãšããŠã¯åºç¯ãªçµ¶çžæ§æš¹èããéžæã§
ãããŸãããªââããã«ã«ã«ããŸãŒã«ãããªã
ãã«ã¢ã³ãã©ã»ã³ãããªããã«ãã¬ã³ãªã©ã®ææ©
å å°é»æ§ããªããŒããéžæã§ããã奜ãŸããã¯ã
ããªããã«ããã©ãŒã«ãããªã¢ã«ã¬ãŒãïŒãã¹ã
ãšããŒã«ïŒ¡ãšãã¿ã«é žã®çž®éåäœãªã©ããªã«ãŒã
ããŒãïŒãã¹ããšããŒã«ïŒ¡ãã¿ã€ãçïŒããªãš
ã¹ãã«ãããšããã·æš¹èãããªé ¢é žããã«ãã¢ã¯
ãªã«æš¹èãããªã¢ã¯ãªã«ã¢ããæš¹èãããªã¢ã
ããããªããã«ããªãžã³ãã»ã«ããŒã¹ç³»æš¹èããŠ
ã¬ã¿ã³æš¹èããšããã·æš¹èãã«ãŒã€ã³ãããªãã
ã«ã¢ã«ã³ãŒã«ãããªããã«ãããªãã³ãªã©ã®çµ¶çž
æ§æš¹èãæããããšãã§ãããé»è·çºçå±€äžã«å«
æããæš¹èã¯ã80ééïŒ ä»¥äžã奜ãŸããã¯40éé
ïŒ ä»¥äžãé©ããŠããã ãããã®æš¹èã溶解ãã溶å€ã¯ãæš¹èã®çš®é¡ã«
ãã€ãŠç°ãªãããŸãäžè¿°ã®é»è·èŒžéå±€ãäžåŒå±€ã
溶解ããªããã®ããéžæããããšã奜ãŸãããå ·
äœçãªææ©æº¶å€ãšããŠã¯ãã¡ã¿ããŒã«ããšã¿ããŒ
ã«ãã€ãœãããããŒã«ãªã©ã®ã¢ã«ã³ãŒã«é¡ãã¢ã»
ãã³ãã¡ãã«ãšãã«ã±ãã³ãã·ã¯ããããµãã³ãª
ã©ã®ã±ãã³é¡ãïŒïŒ®âãžã¡ãã«ãã«ã ã¢ããã
ïŒïŒ®âãžã¡ãã«ã¢ã»ãã¢ãããªã©ã®ã¢ããé¡ã
ãžã¡ãã«ã¹ã«ããã·ããªã©ã®ã¹ã«ããã·ãé¡ãã
ãã©ããããã©ã³ããžãªããµã³ããšãã¬ã³ã°ãªã³
ãŒã«ã¢ãã¡ãã«ãšãŒãã«ãªã©ã®ãšãŒãã«é¡ãé ¢é ž
ã¡ãã«ãé ¢é žãšãã«ãªã©ã®ãšã¹ãã«é¡ãã¯ããã
ã«ã ãå¡©åã¡ãã¬ã³ããžã¯ãã«ãšãã¬ã³ãåå¡©å
ççŽ ãããªã¯ãã«ãšãã¬ã³ãªã©ã®èèªæããã²ã³
åçåæ°ŽçŽ é¡ãããã¯ãã³ãŒã³ããã«ãšã³ããã·
ã¬ã³ããªã°ãã€ã³ãã¢ãã¯ãã«ãã³ãŒã³ããžã¯ã
ã«ãã³ãŒã³ãªã©ã®è³éŠæé¡ãªã©ãçšããããšãã§
ããã å¡å·¥ã¯ã浞挬ã³ãŒãã€ã³ã°æ³ãã¹ãã¬ãŒã³ãŒã
ã€ã³ã°æ³ãã¹ãã³ããŒã³ãŒãã€ã³ã°æ³ãããŒãã³
ãŒãã€ã³ã°æ³ããã€ã€ãŒããŒã³ãŒãã€ã³ã°æ³ãã
ã¬ãŒãã³ãŒãã€ã³ã°æ³ãããŒã©ãŒã³ãŒãã€ã³ã°
æ³ãã«ãŒãã³ã³ãŒãã€ã³ã°æ³ãªã©ã®ã³ãŒãã€ã³ã°
æ³ãçšããŠè¡ãªãããšãã§ããã也ç¥ã¯ã宀枩ã«
ãããæ觊也ç¥åŸãå ç±ä¹Ÿç¥ããæ¹æ³ã奜ãŸã
ããå ç±ä¹Ÿç¥ã¯ã30âã200âã®æž©åºŠã§ïŒåãïŒ
æéã®ç¯å²ã®æéã§éæ¢ãŸãã¯é颚äžã§è¡ãªãã
ãšãã§ããã é»è·èŒžéå±€ã¯ãåè¿°ã®é»è·çºçå±€ãšé»æ°çã«æ¥
ç¶ãããŠãããé»çã®ååšäžã§é»è·çºçå±€ãã泚
å ¥ãããé»è·ãã€ãªã¢ãåãåããšãšãã«ããã
ãã®é»è·ãã€ãªã¢ãè¡šé¢ãŸã§èŒžéã§ããæ©èœãæ
ããŠããããã®éããã®é»è·èŒžéå±€ã¯ãé»è·çºç
å±€ã®äžã«ç©å±€ãããŠããŠããããŸããã®äžã«ç©å±€
ãããŠããŠãããã é»è·èŒžéå±€ãé»è·çºçå±€ã®äžã«åœ¢æãããå Ž
åãé»è·èŒžéå±€ã«ãããé»è·ãã€ãªã¢ã茞éãã
ç©è³ªïŒä»¥äžãåã«é»è·èŒžéç©è³ªãšããïŒã¯ãåè¿°
ã®é»è·çºçå±€ãæå¿ããé»ç£æ³¢ã®æ³¢é·åã«å®è³ªç
ã«éæå¿æ§ã§ããããšã奜ãŸãããçç±ã¯é»è·èŒž
éå±€ããã€ã«ã¿ãŒå¹æããã¡æ床äœäžããããã®
ãé²æ¢ããçºã§ãããããã§ãããé»ç£æ³¢ããšã¯
γç·ãç·ã玫å€ç·ãå¯èŠå ç·ãè¿èµ€å€ç·ãèµ€å€
ç·ãé èµ€å€ç·ãªã©ãå å«ããåºçŸ©ã®ãå ç·ãã®å®
矩ãå å«ããã é»è·èŒžéç©è³ªãšããŠã¯é»å茞éæ§ç©è³ªãšæ£å茞
éæ§ç©è³ªããããé»å茞éæ§ç©è³ªãšããŠã¯ãã¯ã
ã«ã¢ãã«ãããã¢ã¢ãã«ãããã©ã·ã¢ããšãã¬
ã³ãããã©ã·ã¢ããããžã¡ã¿ã³ãïŒïŒïŒïŒïŒâã
ãªãããâïŒâãã«ãªã¬ãã³ãïŒïŒïŒïŒïŒïŒïŒâ
ããã©ãããâïŒâãã«ãªã¬ãã³ãïŒïŒïŒïŒïŒâ
ããªãããâïŒâãžã·ã¢ãã¡ãã¬ã³ãã«ãªã¬ã
ã³ãïŒïŒïŒïŒïŒïŒïŒâããã©ãããããµã³ãã³ã
ïŒïŒïŒïŒïŒâããªãããããªããµã³ãã³çã®é»å
åžåŒæ§ç©è³ªããããé»ååžåŒç©è³ªãé«åååãã
ãã®çãããã æ£å茞éæ§ç©è³ªãšããŠã¯ããã¬ã³ãâãšãã«
ã«ã«ããŸãŒã«ãâã€ãœãããã«ã«ã«ããŸãŒã«ã
âã¡ãã«ââããšãã«ããã©ãžãâïŒâã¡ã
ãªãã³âïŒâãšãã«ã«ã«ããŸãŒã«ãïŒïŒ®âãžã
ãšãã«ããã©ãžãâïŒâã¡ããªãã³âïŒâãšãã«
ã«ã«ããŸãŒã«ãïŒïŒ®âãžããšãã«ããã©ãžãâ
ïŒâã¡ããªãã³â10âãšãã«ããšããã¢ãžã³ã
ïŒïŒ®âãžããšãã«ããã©ãžãâïŒâã¡ããªãã³
â10âãšãã«ããšãããµãžã³ãâãžãšãã«ã¢ã
ããã³ãºã¢ã«ãããâïŒïŒ®âãžããšãã«ããã©
ãŸã³ãâãžãšãã«ã¢ãããã³ãºã¢ã«ãããâ
âαâãããã«ââããšãã«ããã©ãŸã³ãâ
ãããªãžããã³ãºã¢ã«ãããâïŒïŒ®âãžããšã
ã«ããã©ãŸã³ãïŒïŒïŒïŒïŒâããªã¡ãã«ã€ã³ãã¬
ãã³âÏâã¢ã«ãããâïŒïŒ®âãžããšãã«ãã
ã©ãŸã³ãâãžãšãã«ãã³ãºã¢ã«ãããâïŒâã¡
ãã«ãã³ãºãã¢ãŸãªãã³âïŒâããã©ãŸã³çã®ã
ãã©ãŸã³é¡ãïŒïŒïŒâãã¹ïŒïŒ°âãžãšãã«ã¢ãã
ããšãã«ïŒâïŒïŒïŒïŒïŒâãªããµãžã¢ãŸãŒã«ãïŒ
âããšãã«âïŒâïŒïŒ°âãžãšãã«ã¢ããã¹ããªã«ïŒ
âïŒâïŒïŒ°âãžãšãã«ã¢ããããšãã«ïŒãã©ãŸãª
ã³ãïŒâããããªã«(2)ãâïŒâïŒïŒ°âãžãšãã«ã¢ã
ãã¹ããªã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢ããããšã
ã«ïŒãã©ãŸãªã³ãïŒâãããªãžã«(2)ãâïŒâïŒïŒ°â
ãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢
ããããšãã«ïŒãã©ãŸãªã³ãïŒâãïŒâã¡ããã·
âããªãžã«(2)ãâïŒâïŒïŒ°âãžãšãã«ã¢ããã¹ããª
ã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢ããããšãã«ïŒãã©ãŸ
ãªã³ãïŒâãããªãžã«(3)ãâïŒâïŒïŒ°âãžãšãã«ã¢
ããã¹ããªã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢ããããšã
ã«ïŒãã©ãŸãªã³ãïŒâãããªãžã«(2)ãâïŒâïŒïŒ°â
ãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢
ããããšãã«ïŒãã©ãŸãªã³ãïŒâãããªãžã«(2)ãâ
ïŒâïŒïŒ°âãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâã¡ãã«
âïŒâïŒïŒ°âãžãšãã«ã¢ããããšãã«ïŒãã©ãŸãª
ã³ãïŒâãããªãžã«(2)ãâïŒâïŒÎ±âã¡ãã«ââ
ãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢
ããããšãã«ïŒãã©ãŸãªã³ãïŒâããšãã«âïŒâ
ïŒïŒ°âãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâã¡ãã«âïŒ
âïŒïŒ°âãžãšãã«ã¢ããããšãã«ïŒãã©ãŸãªã³ã
ïŒâããšãã«âïŒâïŒÎ±âãã³ãžã«ââãžãšã
ã«ã¢ããã¹ããªã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢ããã
ãšãã«ïŒãã©ãŸãªã³ãã¹ãããã©ãŸãªã³ãªã©ã®ã
ã©ãŸãªã³é¡ãïŒâïŒïŒ°âãžãšãã«ã¢ããã¹ããªã«ïŒ
âïŒâãžãšãã«ã¢ãããã³ãºãªããµãŸãŒã«ãïŒâ
ïŒïŒ°âãžãšãã«ã¢ããããšãã«ïŒâïŒâïŒïŒ°âãžã¡
ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâã¯ããããšã
ã«ïŒãªããµãŸãŒã«çã®ãªããµãŸãŒã«ç³»ååç©ãïŒ
âïŒïŒ°âãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâãžãšãã«
ã¢ãããã³ãŸãã¢ãŸãŒã«çã®ãã¢ãŸãŒã«ç³»åå
ç©ããã¹ïŒïŒâãžãšãã«ã¢ããâïŒâã¡ãã«ããš
ãã«ïŒâããšãã«ã¡ã¿ã³çã®ããªã¢ãªãŒã«ã¡ã¿ã³
ç³»ååç©ãïŒïŒïŒâãã¹ïŒïŒâïŒïŒ®âãžãšãã«
ã¢ããâïŒâã¡ãã«ããšãã«ïŒããã¿ã³ãïŒïŒ
ïŒïŒïŒïŒïŒâããã©ãã¹ïŒïŒâïŒïŒ®âãžã¡ãã«
ã¢ããâïŒâã¡ãã«ããšãã«ïŒãšã¿ã³çã®ããªã¢
ãªãŒã«ã¢ã«ã«ã³é¡ãããªããšãã«ã¢ãã³ãã¹ãã«
ãã³èªå°äœãã¹ããªã«åºãæããè³éŠæå€ç°åå
ç©ããããç°ååç©ãããªââããã«ã«ã«ããŸ
ãŒã«ãããªããã«ãã¬ã³ãããªããã«ã¢ã³ãã©ã»
ã³ãããªããã«ã¢ã¯ãªãžã³ãããªâïŒâããã«ã
ãšãã«ã¢ã³ãã©ã»ã³ããã¬ã³âãã«ã ã¢ã«ããã
æš¹èããšãã«ã«ã«ããŸãŒã«ãã«ã ã¢ã«ãããæš¹è
çãããã ãããã®ææ©é»è·èŒžéç©è³ªã®ä»ã«ã»ã¬ã³ãã»ã¬
ã³âãã«ã«ã¢ã¢ã«ãã¢ã¹ã·ãªã³ã³ãç¡«åã«ãããŠ
ã ãªã©ã®ç¡æ©ææãçšããããšãã§ããã ãŸãããããã®é»è·èŒžéç©è³ªã¯ãïŒçš®ãŸãã¯ïŒ
皮以äžçµåããŠçšããããšãã§ããã é»è·èŒžéç©è³ªã«æèæ§ãæããŠããªãæã«ã¯ã
é©åœãªãã€ã³ããŒãéžæããããšã«ãã€ãŠè¢«è圢
æã§ããããã€ã³ããŒãšããŠäœ¿çšã§ããæš¹èã¯ã
äŸãã°ã¢ã¯ãªã«æš¹èããªã¢ãªã¬ãŒããããªãšã¹ã
ã«ãããªã«ãŒãããŒãïŒãã¹ããšããŒã«ïŒ¡ãã¿
ã€ããªã©ïŒããªã¹ãã¬ã³ãã¢ã¯ãªããããªã«âã¹
ãã¬ã³ã³ããªããŒãã¢ã¯ãªããããªã«âãã¿ãžãš
ã³ã³ããªããŒãããªããã«ããã©ãŒã«ãããªãã
ã«ãã«ããŒã«ãããªã¹ã«ãã³ãããªã¢ã¯ãªã«ã¢ã
ããããªã¢ãããå¡©çŽ åãŽã ãªã©ã®çµ¶çžæ§æš¹èã
ãããã¯ããªââããã«ã«ã«ããŸãŒã«ãããªã
ãã«ã¢ã³ãã©ã»ã³ãããªããã«ãã¬ã³ãªã©ã®ææ©
å å°é»æ§ããªããŒãæããããšãã§ããã é»è·èŒžéå±€ã¯ãé»è·ãã€ãªã¢ã茞éã§ããéç
ãããã®ã§ãå¿ èŠä»¥äžã«èåãåãããããšãã§
ããªããäžè¬çã«ã¯ãïŒãã¯ãã³ã30ãã¯ãã³ã§
ãããã奜ãŸããç¯å²ã¯ïŒãã¯ãã³ã20ãã¯ãã³
ã§ãããå¡å·¥ã«ãã€ãŠé»è·èŒžéå±€ã圢æããéã«
ã¯ãåè¿°ããæ§ãªé©åœãªã³ãŒãã€ã³ã°æ³ãçšãã
ããšãã§ããã ãã®æ§ãªé»è·çºçå±€ãšé»è·èŒžéå±€ã®ç©å±€æ§é ã
ããªãæå å±€ã¯ãå°é»å±€ãæããåºäœã®äžã«èšã
ããããå°é»å±€ãæããåºäœãšããŠã¯ãåºäœèªäœ
ãå°é»æ§ããã€ãã®ãäŸãã°ã¢ã«ãããŠã ãã¢ã«
ãããŠã åéãé ãäºéãã¹ãã³ã¬ã¹ããããžãŠ
ã ãã¢ãªããã³ãã¯ãã ããã¿ã³ãããã±ã«ãã€
ã³ãžãŠã ãéãçœéãªã©ãçšããããšãã§ããã
ã®ä»ã«ã¢ã«ãããŠã ãã¢ã«ãããŠã åéãé žåã€
ã³ãžãŠã ãé žåé«ãé žåã€ã³ãžãŠã âé žåé«åé
ãªã©ãç空èžçæ³ã«ãã€ãŠè¢«è圢æãããå±€ãæ
ãããã©ã¹ããã¯ïŒäŸãã°ãããªãšãã¬ã³ãããª
ãããã¬ã³ãããªå¡©åããã«ãããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒããã¢ã¯ãªã«æš¹èãããªããåãšãã¬ã³
ãªã©ïŒããããã¯å°é»æ§ç²åïŒäŸãã°ãã«ãŒãã³
ãã©ãã¯éç²åãªã©ïŒãé©åœãªãã€ã³ããŒãšãšã
ã«ãã©ã¹ããã¯ã®äžã«è¢«èŠããåºäœãå°é»æ§ç²å
ããã©ã¹ããã¯ãçŽã«å«æµžããåºäœãå°é»æ§ããª
ããŒãæãããã©ã¹ããã¯ãªã©ãçšããããšãã§
ããã å°é»å±€ãšæå å±€ã®äžéã«ãããªã€ãŒæ©èœãšæ¥ç
æ©èœããã€äžåŒå±€ãèšããããšãã§ãããäžåŒå±€
ã¯ãã«ãŒã€ã³ãããªããã«ã¢ã«ã³ãŒã«ããããã»
ã«ããŒã¹ããšãã¬ã³âã¢ã¯ãªã«é žã³ããªããŒãã
ãªã¢ããïŒãã€ãã³ïŒããã€ãã³66ããã€ãã³
610ãå ±éåãã€ãã³ãã¢ã«ã³ãã·ã¡ãã«åãã€
ãã³ãªã©ïŒãããªãŠã¬ã¿ã³ããŒã©ãã³ãé žåã¢ã«
ãããŠã ãªã©ã«ãã€ãŠåœ¢æã§ããã äžåŒå±€ã®èåã¯ã0.1ãã¯ãã³ãïŒãã¯ãã³ã
奜ãŸããã¯0.5ãã¯ãã³ãïŒãã¯ãã³ãé©åœã§ã
ãã å°é»å±€ãé»è·çºçå±€ãé»è·èŒžéå±€ã®é ã«ç©å±€ã
ãæå äœã䜿çšããå Žåã«ãããŠé»è·èŒžéç©è³ªã
é»å茞éæ§ç©è³ªãããªããšãã¯ãé»è·èŒžé局衚é¢
ãæ£ã«åž¯é»ããå¿ èŠãããã垯é»åŸé²å ãããšé²
å éšã§ã¯é»è·çºçå±€ã«ãããŠçæããé»åãé»è·
茞éå±€ã«æ³šå ¥ããããã®ããšè¡šé¢ã«éããŠæ£é»è·
ãäžåããè¡šé¢é»äœã®æžè¡°ãçãæªé²å éšãšã®é
ã«éé»ã³ã³ãã©ã¹ããçããããã®æ§ã«ããŠã§ã
ãéé»æœåãè² è·é»æ§ã®ãããŒã§çŸè±¡ããã°å¯èŠ
åãåŸãããããããçŽæ¥å®çãããããããã¯
ãããŒåãçŽããã©ã¹ããã¯ãã€ã«ã çã«è»¢å
åŸãçŸåãå®çããããšãã§ããã ãŸããæå äœäžã®éé»æœåã転åçŽã®çµ¶çžå±€äž
ã«è»¢ååŸçŸåããå®çããæ¹æ³ããšãããçŸåå€
ã®çš®é¡ãçŸåæ¹æ³ãå®çæ¹æ³ã¯å ¬ç¥ã®ãã®ãå ¬ç¥
ã®æ¹æ³ã®ããããæ¡çšããŠãè¯ããç¹å®ã®ãã®ã«
éå®ããããã®ã§ã¯ãªãã äžæ¹ãé»è·èŒžéç©è³ªãæ£å茞éç©è³ªããæãå Ž
åãé»è·èŒžé局衚é¢ãè² ã«åž¯é»ããå¿ èŠãããã
垯é»åŸãé²å ãããšé²å éšã§ã¯é»è·çºçå±€ã«ãã
ãŠçæããæ£åãé»è·èŒžéå±€ã«æ³šå ¥ããããã®åŸ
è¡šé¢ã«éããŠè² é»è·ãäžåããè¡šé¢é»äœã®æžè¡°ã
çãæªé²å éšãšã®éã«éé»ã³ã³ãã©ã¹ããçã
ããçŸåæã«ã¯é»å茞éç©è³ªãçšããå Žåãšã¯é
ã«æ£é»è·æ§ãããŒãçšããå¿ èŠãããã æ¬çºæã®å¥ã®å ·äœäŸãšããŠã¯ãåè¿°ã®ã¢ãŸé¡æ
ãé»è·èŒžéç©è³ªãšãšãã«åäžå±€ã«å«æãããé»å
åçæå äœãæããããšãã§ããããã®éãåè¿°
ã®é»è·èŒžéç©è³ªã®ä»ã«ããªââããã«ã«ã«ããŸ
ãŒã«ãšããªããããã«ãªã¬ãã³ãããªãé»è·ç§»å
é¯ååç©ãçšããããšãã§ããã ãã®äŸã®é»ååçæå äœã¯ãåè¿°ã®ã¢ãŸé¡æãš
é»è·ç§»åé¯ååç©ãããã©ããããã©ã³ã«æº¶è§£ã
ããããªãšã¹ãã«æº¶æ¶²äžã«åæ£ãããåŸãããå¡
工液ãçšããŠè¢«è圢æãããŠèª¿è£œã§ããã ãããã®æå äœã«ãããŠããçšããé¡æã¯äžè¬
åŒ(1)ã§ç€ºãããã¢ãŸé¡æããéžã°ããå°ãªããšã
ïŒçš®é¡ã®é¡æãå«æãããã®çµæ¶åœ¢ã¯éæ¶è³ªã§ã
ã€ãŠãçµæ¶è³ªã§ãã€ãŠãããã åå¿ èŠã«å¿ããŠå åžåã®ç°ãªãé¡æãçµåããŠ
䜿çšããŠæå äœã®æ床ãé«ãããããã³ã¯ããã
ãã¯ãªæå äœãåŸããªã©ã®ç®çã§äžè¬åŒ(1)ã§ç€ºã
ããã¢ãŸé¡æãïŒçš®é¡ä»¥äžçµåãããããŸãã¯å ¬
ç¥ã®ææãé¡æããéžã°ããé»è·çºçç©è³ªãšçµå
ããŠäœ¿çšããããšãå¯èœã§ããã æ¬çºæã®é»ååçæå äœã¯åèšåçè€åæ©ã«å©
çšããã®ã¿ãªãããã¬ãŒã¶ãŒããªã³ã¿ãŒãCRT
ããªã³ã¿ãŒãLEDããªã³ã¿ãŒã液æ¶ããªã³ã¿ãŒã
ã¬ãŒã¶ãŒè£œççã®é»ååçå¿çšåéã«ãåºãçšã
ãäºãã§ããã 以äžæ¬çºæãå®æœäŸã«ãã€ãŠèª¬æããã å®æœäŸ ïŒã44 ã¢ã«ãæ¿äžã«ã«ãŒã€ã³ã®ã¢ã³ã¢ãã¢æ°Žæº¶æ¶²ïŒã«
ãŒã€ã³11.2ïœã28ïŒ ã¢ã³ã¢ãã¢æ°ŽïŒïœãæ°Ž222mlïŒ
ããã€ã€ãŒããŒã§ã也ç¥åŸã®èåã1.0ãã¯ãã³
ãšãªãæ§ã«å¡åžãã也ç¥ããã 次ã«ãåèšäŸç€ºã®ã¢ãŸé¡æNo.ïŒã®ïŒïœãããšã¿
ããŒã«95mlã«ããã©ãŒã«æš¹èïŒããã©ãŒã«å床63
ã¢ã«ïŒ ïŒïŒïœã溶ããã液ã«å ãããµã³ããã«ã§
ïŒæéåæ£ããããã®åæ£æ¶²ãå ã«åœ¢æããã«ãŒ
ã€ã³å±€ã®äžã«ä¹Ÿç¥åŸã®èåã0.5ãã¯ãã³ãšãªã
æ§ã«ãã€ã€ãŒããŒã§å¡åžãã也ç¥ããŠé»è·çºçå±€
ã圢æããã 次ãã§ãæ§é åŒ ã®ããã©ãŸã³ååç©ïŒïœãšããªã¡ãã«ã¡ã¿ã¯ãªã¬
ãŒãæš¹èïŒæ°å¹³åååé100000ïŒïŒïœããã³ãŒã³
70mlã«æº¶è§£ãããããé»è·çºçå±€ã®äžã«ä¹Ÿç¥åŸã®
èåã12ãã¯ãã³ãšãªãæ§ã«ãã€ã€ãŒããŒã§å¡åž
ã也ç¥ããŠé»è·èŒžéå±€ã圢æããæå äœãäœæã
ããã¢ãŸé¡æNo.ïŒã®ä»£ãã«ç¬¬ïŒè¡šã«ç€ºãã¢ãŸé¡æ
ãçšãåæ§ã«ããŠå®æœäŸïŒã44ã®æå äœãäœæã
ãã ãã®æ§ã«ããŠäœæããé»ååçæå äœãå·å£é»
æ©(æ ª)補éé»è€åçŽè©Šéšè£ 眮Model SPâ428ãçš
ããŠã¹ã¿ããã¯æ¹åŒã§â5kVã§ã³ãã垯é»ãææ
ã§ïŒç§éä¿æããåŸãç §åºŠ2luxã§é²å ã垯é»ç¹æ§
ã枬å®ããã 垯é»ç¹æ§ãšããŠã¯è¡šé¢é»äœïŒV0ïŒãšïŒç§éæ
æžè¡°ãããæã®é»äœã1/2ã«æžè¡°ããã«å¿ èŠãªé²
å éE1/2ïŒluxã»secïŒã枬å®ãããçµæã第ïŒè¡š
ã«ç€ºãã
ãªã³ã°ããã ãåæããã®ååç©ãæŽã«ãžã¢ãŸååå¿ã«ä»ãã
åŸNa+BF4 -ã«ããåŠçã㊠ã容æã«åŸãããã ãã®ããªãã«ãªããã¬ãŒã21.6ïœïŒ0.03ã¢ã«ïŒ
ãïŒããŒã«ãŒäžã®DMF1.8ã«æº¶è§£ãæŽã«ã«ã
ã©ãŒæåãšããŠïŒâããããã·âïŒâããããšé ž
ã¢ããªã24.5ïœïŒ0.093ã¢ã«ïŒã溶解ã液枩ãïŒ
âãŸã§å·åŽããã ãã®æº¶æ¶²ãæ¹æããªãããã®æº¶æ¶²äžãžããªãšã
ã«ã¢ãã³61.7ïœïŒ0.61ã¢ã«ïŒã30åãããŠæ¶²æž©ã
ïŒã10âã«ä¿ã¡ãªãã滎äžããã滎äžçµäºåŸæŽã«
ïŒæéæ¹æã宀枩ã§ïŒæ©æŸçœ®åŸåå¿æ¶²ãæ¿Ÿéã
ãã åŸãããé¡æãæ°ŽïŒã§æ¹æãæŽæµãæ¿ŸéãïŒ
åããè¿ããåŸDMF600mlã§ïŒåãMEK600mlã§
ïŒåããããæ¹æãæŽæµãæ¿Ÿéãé 次ããè¿ã
ãã åŸãããããŒã¹ãç¶ç©ã宀枩ã§é颚也ç¥ã31.8
ïœïŒåç83ïŒ ïŒã®é¡æãåŸãã èç¹ 250â以äžã å çŽ åæ èšç®å€ïŒ å®æž¬å€ïŒ  72.39 72.31  4.43 4.46  13.16 13.08 æ¬çºæã®å¥œãŸããå ·äœäŸã§ã¯ãæå å±€ãé»è·çº
çå±€ãšé»è·èŒžéå±€ã«æ©èœåé¢ããé»ååçæå äœ
ã«ãããé»è·çºçç©è³ªã«åèšäžè¬åŒ(1)ã«ç€ºãã¢ãŸ
é¡æãçšããããšãã§ãããé»è·çºçå±€ã¯ãåå
ãªåžå 床ãåŸãããã«ãã§ããéãå€ãã®åèšã¢
ãŸé¡æãå«æããäžã€çºçããé»è·ãã€ãªã¢ãé»
è·çºçå±€å ã§ãã©ãããããããšãé²ãããã«ã
èèå±€ãäŸãã°ïŒãã¯ãã³ä»¥äžã奜ãŸããã¯0.01
ãã¯ãã³ãïŒãã¯ãã³ã®èèããã€èèå±€ãšãã
ããšã奜ãŸããããã®ããšã¯ãå ¥å°å éã®å€§éšå
ãé»è·çºçå±€ã§åžåãããŠãå€ãã®é»è·ãã€ãªã¢
ãçæããããšãããã«çºçããé»è·ãã€ãªã¢ã
åçµåãæç²ïŒãã©ããïŒã«ãã倱掻ããããšãª
ãé»è·èŒžéå±€ã«æ³šå ¥ããå¿ èŠãããããšã«åž°å ã
ãŠããã é»è·çºçå±€ã¯ãåè¿°ã®ã¢ãŸé¡æãé©åœãªãã€ã³
ããŒã«åæ£ããããããåºäœã®äžã«å¡å·¥ããããš
ã«ãã€ãŠåœ¢æã§ãããŸãç空èžçè£ çœ®ã«ããèžç
èã圢æããããšã«ãã€ãŠåŸãããšãã§ãããé»
è·çºçå±€ãå¡å·¥ã«ãã€ãŠåœ¢æããéã«çšãããã
ã€ã³ããŒãšããŠã¯åºç¯ãªçµ¶çžæ§æš¹èããéžæã§
ãããŸãããªââããã«ã«ã«ããŸãŒã«ãããªã
ãã«ã¢ã³ãã©ã»ã³ãããªããã«ãã¬ã³ãªã©ã®ææ©
å å°é»æ§ããªããŒããéžæã§ããã奜ãŸããã¯ã
ããªããã«ããã©ãŒã«ãããªã¢ã«ã¬ãŒãïŒãã¹ã
ãšããŒã«ïŒ¡ãšãã¿ã«é žã®çž®éåäœãªã©ããªã«ãŒã
ããŒãïŒãã¹ããšããŒã«ïŒ¡ãã¿ã€ãçïŒããªãš
ã¹ãã«ãããšããã·æš¹èãããªé ¢é žããã«ãã¢ã¯
ãªã«æš¹èãããªã¢ã¯ãªã«ã¢ããæš¹èãããªã¢ã
ããããªããã«ããªãžã³ãã»ã«ããŒã¹ç³»æš¹èããŠ
ã¬ã¿ã³æš¹èããšããã·æš¹èãã«ãŒã€ã³ãããªãã
ã«ã¢ã«ã³ãŒã«ãããªããã«ãããªãã³ãªã©ã®çµ¶çž
æ§æš¹èãæããããšãã§ãããé»è·çºçå±€äžã«å«
æããæš¹èã¯ã80ééïŒ ä»¥äžã奜ãŸããã¯40éé
ïŒ ä»¥äžãé©ããŠããã ãããã®æš¹èã溶解ãã溶å€ã¯ãæš¹èã®çš®é¡ã«
ãã€ãŠç°ãªãããŸãäžè¿°ã®é»è·èŒžéå±€ãäžåŒå±€ã
溶解ããªããã®ããéžæããããšã奜ãŸãããå ·
äœçãªææ©æº¶å€ãšããŠã¯ãã¡ã¿ããŒã«ããšã¿ããŒ
ã«ãã€ãœãããããŒã«ãªã©ã®ã¢ã«ã³ãŒã«é¡ãã¢ã»
ãã³ãã¡ãã«ãšãã«ã±ãã³ãã·ã¯ããããµãã³ãª
ã©ã®ã±ãã³é¡ãïŒïŒ®âãžã¡ãã«ãã«ã ã¢ããã
ïŒïŒ®âãžã¡ãã«ã¢ã»ãã¢ãããªã©ã®ã¢ããé¡ã
ãžã¡ãã«ã¹ã«ããã·ããªã©ã®ã¹ã«ããã·ãé¡ãã
ãã©ããããã©ã³ããžãªããµã³ããšãã¬ã³ã°ãªã³
ãŒã«ã¢ãã¡ãã«ãšãŒãã«ãªã©ã®ãšãŒãã«é¡ãé ¢é ž
ã¡ãã«ãé ¢é žãšãã«ãªã©ã®ãšã¹ãã«é¡ãã¯ããã
ã«ã ãå¡©åã¡ãã¬ã³ããžã¯ãã«ãšãã¬ã³ãåå¡©å
ççŽ ãããªã¯ãã«ãšãã¬ã³ãªã©ã®èèªæããã²ã³
åçåæ°ŽçŽ é¡ãããã¯ãã³ãŒã³ããã«ãšã³ããã·
ã¬ã³ããªã°ãã€ã³ãã¢ãã¯ãã«ãã³ãŒã³ããžã¯ã
ã«ãã³ãŒã³ãªã©ã®è³éŠæé¡ãªã©ãçšããããšãã§
ããã å¡å·¥ã¯ã浞挬ã³ãŒãã€ã³ã°æ³ãã¹ãã¬ãŒã³ãŒã
ã€ã³ã°æ³ãã¹ãã³ããŒã³ãŒãã€ã³ã°æ³ãããŒãã³
ãŒãã€ã³ã°æ³ããã€ã€ãŒããŒã³ãŒãã€ã³ã°æ³ãã
ã¬ãŒãã³ãŒãã€ã³ã°æ³ãããŒã©ãŒã³ãŒãã€ã³ã°
æ³ãã«ãŒãã³ã³ãŒãã€ã³ã°æ³ãªã©ã®ã³ãŒãã€ã³ã°
æ³ãçšããŠè¡ãªãããšãã§ããã也ç¥ã¯ã宀枩ã«
ãããæ觊也ç¥åŸãå ç±ä¹Ÿç¥ããæ¹æ³ã奜ãŸã
ããå ç±ä¹Ÿç¥ã¯ã30âã200âã®æž©åºŠã§ïŒåãïŒ
æéã®ç¯å²ã®æéã§éæ¢ãŸãã¯é颚äžã§è¡ãªãã
ãšãã§ããã é»è·èŒžéå±€ã¯ãåè¿°ã®é»è·çºçå±€ãšé»æ°çã«æ¥
ç¶ãããŠãããé»çã®ååšäžã§é»è·çºçå±€ãã泚
å ¥ãããé»è·ãã€ãªã¢ãåãåããšãšãã«ããã
ãã®é»è·ãã€ãªã¢ãè¡šé¢ãŸã§èŒžéã§ããæ©èœãæ
ããŠããããã®éããã®é»è·èŒžéå±€ã¯ãé»è·çºç
å±€ã®äžã«ç©å±€ãããŠããŠããããŸããã®äžã«ç©å±€
ãããŠããŠãããã é»è·èŒžéå±€ãé»è·çºçå±€ã®äžã«åœ¢æãããå Ž
åãé»è·èŒžéå±€ã«ãããé»è·ãã€ãªã¢ã茞éãã
ç©è³ªïŒä»¥äžãåã«é»è·èŒžéç©è³ªãšããïŒã¯ãåè¿°
ã®é»è·çºçå±€ãæå¿ããé»ç£æ³¢ã®æ³¢é·åã«å®è³ªç
ã«éæå¿æ§ã§ããããšã奜ãŸãããçç±ã¯é»è·èŒž
éå±€ããã€ã«ã¿ãŒå¹æããã¡æ床äœäžããããã®
ãé²æ¢ããçºã§ãããããã§ãããé»ç£æ³¢ããšã¯
γç·ãç·ã玫å€ç·ãå¯èŠå ç·ãè¿èµ€å€ç·ãèµ€å€
ç·ãé èµ€å€ç·ãªã©ãå å«ããåºçŸ©ã®ãå ç·ãã®å®
矩ãå å«ããã é»è·èŒžéç©è³ªãšããŠã¯é»å茞éæ§ç©è³ªãšæ£å茞
éæ§ç©è³ªããããé»å茞éæ§ç©è³ªãšããŠã¯ãã¯ã
ã«ã¢ãã«ãããã¢ã¢ãã«ãããã©ã·ã¢ããšãã¬
ã³ãããã©ã·ã¢ããããžã¡ã¿ã³ãïŒïŒïŒïŒïŒâã
ãªãããâïŒâãã«ãªã¬ãã³ãïŒïŒïŒïŒïŒïŒïŒâ
ããã©ãããâïŒâãã«ãªã¬ãã³ãïŒïŒïŒïŒïŒâ
ããªãããâïŒâãžã·ã¢ãã¡ãã¬ã³ãã«ãªã¬ã
ã³ãïŒïŒïŒïŒïŒïŒïŒâããã©ãããããµã³ãã³ã
ïŒïŒïŒïŒïŒâããªãããããªããµã³ãã³çã®é»å
åžåŒæ§ç©è³ªããããé»ååžåŒç©è³ªãé«åååãã
ãã®çãããã æ£å茞éæ§ç©è³ªãšããŠã¯ããã¬ã³ãâãšãã«
ã«ã«ããŸãŒã«ãâã€ãœãããã«ã«ã«ããŸãŒã«ã
âã¡ãã«ââããšãã«ããã©ãžãâïŒâã¡ã
ãªãã³âïŒâãšãã«ã«ã«ããŸãŒã«ãïŒïŒ®âãžã
ãšãã«ããã©ãžãâïŒâã¡ããªãã³âïŒâãšãã«
ã«ã«ããŸãŒã«ãïŒïŒ®âãžããšãã«ããã©ãžãâ
ïŒâã¡ããªãã³â10âãšãã«ããšããã¢ãžã³ã
ïŒïŒ®âãžããšãã«ããã©ãžãâïŒâã¡ããªãã³
â10âãšãã«ããšãããµãžã³ãâãžãšãã«ã¢ã
ããã³ãºã¢ã«ãããâïŒïŒ®âãžããšãã«ããã©
ãŸã³ãâãžãšãã«ã¢ãããã³ãºã¢ã«ãããâ
âαâãããã«ââããšãã«ããã©ãŸã³ãâ
ãããªãžããã³ãºã¢ã«ãããâïŒïŒ®âãžããšã
ã«ããã©ãŸã³ãïŒïŒïŒïŒïŒâããªã¡ãã«ã€ã³ãã¬
ãã³âÏâã¢ã«ãããâïŒïŒ®âãžããšãã«ãã
ã©ãŸã³ãâãžãšãã«ãã³ãºã¢ã«ãããâïŒâã¡
ãã«ãã³ãºãã¢ãŸãªãã³âïŒâããã©ãŸã³çã®ã
ãã©ãŸã³é¡ãïŒïŒïŒâãã¹ïŒïŒ°âãžãšãã«ã¢ãã
ããšãã«ïŒâïŒïŒïŒïŒïŒâãªããµãžã¢ãŸãŒã«ãïŒ
âããšãã«âïŒâïŒïŒ°âãžãšãã«ã¢ããã¹ããªã«ïŒ
âïŒâïŒïŒ°âãžãšãã«ã¢ããããšãã«ïŒãã©ãŸãª
ã³ãïŒâããããªã«(2)ãâïŒâïŒïŒ°âãžãšãã«ã¢ã
ãã¹ããªã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢ããããšã
ã«ïŒãã©ãŸãªã³ãïŒâãããªãžã«(2)ãâïŒâïŒïŒ°â
ãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢
ããããšãã«ïŒãã©ãŸãªã³ãïŒâãïŒâã¡ããã·
âããªãžã«(2)ãâïŒâïŒïŒ°âãžãšãã«ã¢ããã¹ããª
ã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢ããããšãã«ïŒãã©ãŸ
ãªã³ãïŒâãããªãžã«(3)ãâïŒâïŒïŒ°âãžãšãã«ã¢
ããã¹ããªã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢ããããšã
ã«ïŒãã©ãŸãªã³ãïŒâãããªãžã«(2)ãâïŒâïŒïŒ°â
ãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢
ããããšãã«ïŒãã©ãŸãªã³ãïŒâãããªãžã«(2)ãâ
ïŒâïŒïŒ°âãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâã¡ãã«
âïŒâïŒïŒ°âãžãšãã«ã¢ããããšãã«ïŒãã©ãŸãª
ã³ãïŒâãããªãžã«(2)ãâïŒâïŒÎ±âã¡ãã«ââ
ãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢
ããããšãã«ïŒãã©ãŸãªã³ãïŒâããšãã«âïŒâ
ïŒïŒ°âãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâã¡ãã«âïŒ
âïŒïŒ°âãžãšãã«ã¢ããããšãã«ïŒãã©ãŸãªã³ã
ïŒâããšãã«âïŒâïŒÎ±âãã³ãžã«ââãžãšã
ã«ã¢ããã¹ããªã«ïŒâïŒâïŒïŒ°âãžãšãã«ã¢ããã
ãšãã«ïŒãã©ãŸãªã³ãã¹ãããã©ãŸãªã³ãªã©ã®ã
ã©ãŸãªã³é¡ãïŒâïŒïŒ°âãžãšãã«ã¢ããã¹ããªã«ïŒ
âïŒâãžãšãã«ã¢ãããã³ãºãªããµãŸãŒã«ãïŒâ
ïŒïŒ°âãžãšãã«ã¢ããããšãã«ïŒâïŒâïŒïŒ°âãžã¡
ãã«ã¢ããããšãã«ïŒâïŒâïŒïŒâã¯ããããšã
ã«ïŒãªããµãŸãŒã«çã®ãªããµãŸãŒã«ç³»ååç©ãïŒ
âïŒïŒ°âãžãšãã«ã¢ããã¹ããªã«ïŒâïŒâãžãšãã«
ã¢ãããã³ãŸãã¢ãŸãŒã«çã®ãã¢ãŸãŒã«ç³»åå
ç©ããã¹ïŒïŒâãžãšãã«ã¢ããâïŒâã¡ãã«ããš
ãã«ïŒâããšãã«ã¡ã¿ã³çã®ããªã¢ãªãŒã«ã¡ã¿ã³
ç³»ååç©ãïŒïŒïŒâãã¹ïŒïŒâïŒïŒ®âãžãšãã«
ã¢ããâïŒâã¡ãã«ããšãã«ïŒããã¿ã³ãïŒïŒ
ïŒïŒïŒïŒïŒâããã©ãã¹ïŒïŒâïŒïŒ®âãžã¡ãã«
ã¢ããâïŒâã¡ãã«ããšãã«ïŒãšã¿ã³çã®ããªã¢
ãªãŒã«ã¢ã«ã«ã³é¡ãããªããšãã«ã¢ãã³ãã¹ãã«
ãã³èªå°äœãã¹ããªã«åºãæããè³éŠæå€ç°åå
ç©ããããç°ååç©ãããªââããã«ã«ã«ããŸ
ãŒã«ãããªããã«ãã¬ã³ãããªããã«ã¢ã³ãã©ã»
ã³ãããªããã«ã¢ã¯ãªãžã³ãããªâïŒâããã«ã
ãšãã«ã¢ã³ãã©ã»ã³ããã¬ã³âãã«ã ã¢ã«ããã
æš¹èããšãã«ã«ã«ããŸãŒã«ãã«ã ã¢ã«ãããæš¹è
çãããã ãããã®ææ©é»è·èŒžéç©è³ªã®ä»ã«ã»ã¬ã³ãã»ã¬
ã³âãã«ã«ã¢ã¢ã«ãã¢ã¹ã·ãªã³ã³ãç¡«åã«ãããŠ
ã ãªã©ã®ç¡æ©ææãçšããããšãã§ããã ãŸãããããã®é»è·èŒžéç©è³ªã¯ãïŒçš®ãŸãã¯ïŒ
皮以äžçµåããŠçšããããšãã§ããã é»è·èŒžéç©è³ªã«æèæ§ãæããŠããªãæã«ã¯ã
é©åœãªãã€ã³ããŒãéžæããããšã«ãã€ãŠè¢«è圢
æã§ããããã€ã³ããŒãšããŠäœ¿çšã§ããæš¹èã¯ã
äŸãã°ã¢ã¯ãªã«æš¹èããªã¢ãªã¬ãŒããããªãšã¹ã
ã«ãããªã«ãŒãããŒãïŒãã¹ããšããŒã«ïŒ¡ãã¿
ã€ããªã©ïŒããªã¹ãã¬ã³ãã¢ã¯ãªããããªã«âã¹
ãã¬ã³ã³ããªããŒãã¢ã¯ãªããããªã«âãã¿ãžãš
ã³ã³ããªããŒãããªããã«ããã©ãŒã«ãããªãã
ã«ãã«ããŒã«ãããªã¹ã«ãã³ãããªã¢ã¯ãªã«ã¢ã
ããããªã¢ãããå¡©çŽ åãŽã ãªã©ã®çµ¶çžæ§æš¹èã
ãããã¯ããªââããã«ã«ã«ããŸãŒã«ãããªã
ãã«ã¢ã³ãã©ã»ã³ãããªããã«ãã¬ã³ãªã©ã®ææ©
å å°é»æ§ããªããŒãæããããšãã§ããã é»è·èŒžéå±€ã¯ãé»è·ãã€ãªã¢ã茞éã§ããéç
ãããã®ã§ãå¿ èŠä»¥äžã«èåãåãããããšãã§
ããªããäžè¬çã«ã¯ãïŒãã¯ãã³ã30ãã¯ãã³ã§
ãããã奜ãŸããç¯å²ã¯ïŒãã¯ãã³ã20ãã¯ãã³
ã§ãããå¡å·¥ã«ãã€ãŠé»è·èŒžéå±€ã圢æããéã«
ã¯ãåè¿°ããæ§ãªé©åœãªã³ãŒãã€ã³ã°æ³ãçšãã
ããšãã§ããã ãã®æ§ãªé»è·çºçå±€ãšé»è·èŒžéå±€ã®ç©å±€æ§é ã
ããªãæå å±€ã¯ãå°é»å±€ãæããåºäœã®äžã«èšã
ããããå°é»å±€ãæããåºäœãšããŠã¯ãåºäœèªäœ
ãå°é»æ§ããã€ãã®ãäŸãã°ã¢ã«ãããŠã ãã¢ã«
ãããŠã åéãé ãäºéãã¹ãã³ã¬ã¹ããããžãŠ
ã ãã¢ãªããã³ãã¯ãã ããã¿ã³ãããã±ã«ãã€
ã³ãžãŠã ãéãçœéãªã©ãçšããããšãã§ããã
ã®ä»ã«ã¢ã«ãããŠã ãã¢ã«ãããŠã åéãé žåã€
ã³ãžãŠã ãé žåé«ãé žåã€ã³ãžãŠã âé žåé«åé
ãªã©ãç空èžçæ³ã«ãã€ãŠè¢«è圢æãããå±€ãæ
ãããã©ã¹ããã¯ïŒäŸãã°ãããªãšãã¬ã³ãããª
ãããã¬ã³ãããªå¡©åããã«ãããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒããã¢ã¯ãªã«æš¹èãããªããåãšãã¬ã³
ãªã©ïŒããããã¯å°é»æ§ç²åïŒäŸãã°ãã«ãŒãã³
ãã©ãã¯éç²åãªã©ïŒãé©åœãªãã€ã³ããŒãšãšã
ã«ãã©ã¹ããã¯ã®äžã«è¢«èŠããåºäœãå°é»æ§ç²å
ããã©ã¹ããã¯ãçŽã«å«æµžããåºäœãå°é»æ§ããª
ããŒãæãããã©ã¹ããã¯ãªã©ãçšããããšãã§
ããã å°é»å±€ãšæå å±€ã®äžéã«ãããªã€ãŒæ©èœãšæ¥ç
æ©èœããã€äžåŒå±€ãèšããããšãã§ãããäžåŒå±€
ã¯ãã«ãŒã€ã³ãããªããã«ã¢ã«ã³ãŒã«ããããã»
ã«ããŒã¹ããšãã¬ã³âã¢ã¯ãªã«é žã³ããªããŒãã
ãªã¢ããïŒãã€ãã³ïŒããã€ãã³66ããã€ãã³
610ãå ±éåãã€ãã³ãã¢ã«ã³ãã·ã¡ãã«åãã€
ãã³ãªã©ïŒãããªãŠã¬ã¿ã³ããŒã©ãã³ãé žåã¢ã«
ãããŠã ãªã©ã«ãã€ãŠåœ¢æã§ããã äžåŒå±€ã®èåã¯ã0.1ãã¯ãã³ãïŒãã¯ãã³ã
奜ãŸããã¯0.5ãã¯ãã³ãïŒãã¯ãã³ãé©åœã§ã
ãã å°é»å±€ãé»è·çºçå±€ãé»è·èŒžéå±€ã®é ã«ç©å±€ã
ãæå äœã䜿çšããå Žåã«ãããŠé»è·èŒžéç©è³ªã
é»å茞éæ§ç©è³ªãããªããšãã¯ãé»è·èŒžé局衚é¢
ãæ£ã«åž¯é»ããå¿ èŠãããã垯é»åŸé²å ãããšé²
å éšã§ã¯é»è·çºçå±€ã«ãããŠçæããé»åãé»è·
茞éå±€ã«æ³šå ¥ããããã®ããšè¡šé¢ã«éããŠæ£é»è·
ãäžåããè¡šé¢é»äœã®æžè¡°ãçãæªé²å éšãšã®é
ã«éé»ã³ã³ãã©ã¹ããçããããã®æ§ã«ããŠã§ã
ãéé»æœåãè² è·é»æ§ã®ãããŒã§çŸè±¡ããã°å¯èŠ
åãåŸãããããããçŽæ¥å®çãããããããã¯
ãããŒåãçŽããã©ã¹ããã¯ãã€ã«ã çã«è»¢å
åŸãçŸåãå®çããããšãã§ããã ãŸããæå äœäžã®éé»æœåã転åçŽã®çµ¶çžå±€äž
ã«è»¢ååŸçŸåããå®çããæ¹æ³ããšãããçŸåå€
ã®çš®é¡ãçŸåæ¹æ³ãå®çæ¹æ³ã¯å ¬ç¥ã®ãã®ãå ¬ç¥
ã®æ¹æ³ã®ããããæ¡çšããŠãè¯ããç¹å®ã®ãã®ã«
éå®ããããã®ã§ã¯ãªãã äžæ¹ãé»è·èŒžéç©è³ªãæ£å茞éç©è³ªããæãå Ž
åãé»è·èŒžé局衚é¢ãè² ã«åž¯é»ããå¿ èŠãããã
垯é»åŸãé²å ãããšé²å éšã§ã¯é»è·çºçå±€ã«ãã
ãŠçæããæ£åãé»è·èŒžéå±€ã«æ³šå ¥ããããã®åŸ
è¡šé¢ã«éããŠè² é»è·ãäžåããè¡šé¢é»äœã®æžè¡°ã
çãæªé²å éšãšã®éã«éé»ã³ã³ãã©ã¹ããçã
ããçŸåæã«ã¯é»å茞éç©è³ªãçšããå Žåãšã¯é
ã«æ£é»è·æ§ãããŒãçšããå¿ èŠãããã æ¬çºæã®å¥ã®å ·äœäŸãšããŠã¯ãåè¿°ã®ã¢ãŸé¡æ
ãé»è·èŒžéç©è³ªãšãšãã«åäžå±€ã«å«æãããé»å
åçæå äœãæããããšãã§ããããã®éãåè¿°
ã®é»è·èŒžéç©è³ªã®ä»ã«ããªââããã«ã«ã«ããŸ
ãŒã«ãšããªããããã«ãªã¬ãã³ãããªãé»è·ç§»å
é¯ååç©ãçšããããšãã§ããã ãã®äŸã®é»ååçæå äœã¯ãåè¿°ã®ã¢ãŸé¡æãš
é»è·ç§»åé¯ååç©ãããã©ããããã©ã³ã«æº¶è§£ã
ããããªãšã¹ãã«æº¶æ¶²äžã«åæ£ãããåŸãããå¡
工液ãçšããŠè¢«è圢æãããŠèª¿è£œã§ããã ãããã®æå äœã«ãããŠããçšããé¡æã¯äžè¬
åŒ(1)ã§ç€ºãããã¢ãŸé¡æããéžã°ããå°ãªããšã
ïŒçš®é¡ã®é¡æãå«æãããã®çµæ¶åœ¢ã¯éæ¶è³ªã§ã
ã€ãŠãçµæ¶è³ªã§ãã€ãŠãããã åå¿ èŠã«å¿ããŠå åžåã®ç°ãªãé¡æãçµåããŠ
䜿çšããŠæå äœã®æ床ãé«ãããããã³ã¯ããã
ãã¯ãªæå äœãåŸããªã©ã®ç®çã§äžè¬åŒ(1)ã§ç€ºã
ããã¢ãŸé¡æãïŒçš®é¡ä»¥äžçµåãããããŸãã¯å ¬
ç¥ã®ææãé¡æããéžã°ããé»è·çºçç©è³ªãšçµå
ããŠäœ¿çšããããšãå¯èœã§ããã æ¬çºæã®é»ååçæå äœã¯åèšåçè€åæ©ã«å©
çšããã®ã¿ãªãããã¬ãŒã¶ãŒããªã³ã¿ãŒãCRT
ããªã³ã¿ãŒãLEDããªã³ã¿ãŒã液æ¶ããªã³ã¿ãŒã
ã¬ãŒã¶ãŒè£œççã®é»ååçå¿çšåéã«ãåºãçšã
ãäºãã§ããã 以äžæ¬çºæãå®æœäŸã«ãã€ãŠèª¬æããã å®æœäŸ ïŒã44 ã¢ã«ãæ¿äžã«ã«ãŒã€ã³ã®ã¢ã³ã¢ãã¢æ°Žæº¶æ¶²ïŒã«
ãŒã€ã³11.2ïœã28ïŒ ã¢ã³ã¢ãã¢æ°ŽïŒïœãæ°Ž222mlïŒ
ããã€ã€ãŒããŒã§ã也ç¥åŸã®èåã1.0ãã¯ãã³
ãšãªãæ§ã«å¡åžãã也ç¥ããã 次ã«ãåèšäŸç€ºã®ã¢ãŸé¡æNo.ïŒã®ïŒïœãããšã¿
ããŒã«95mlã«ããã©ãŒã«æš¹èïŒããã©ãŒã«å床63
ã¢ã«ïŒ ïŒïŒïœã溶ããã液ã«å ãããµã³ããã«ã§
ïŒæéåæ£ããããã®åæ£æ¶²ãå ã«åœ¢æããã«ãŒ
ã€ã³å±€ã®äžã«ä¹Ÿç¥åŸã®èåã0.5ãã¯ãã³ãšãªã
æ§ã«ãã€ã€ãŒããŒã§å¡åžãã也ç¥ããŠé»è·çºçå±€
ã圢æããã 次ãã§ãæ§é åŒ ã®ããã©ãŸã³ååç©ïŒïœãšããªã¡ãã«ã¡ã¿ã¯ãªã¬
ãŒãæš¹èïŒæ°å¹³åååé100000ïŒïŒïœããã³ãŒã³
70mlã«æº¶è§£ãããããé»è·çºçå±€ã®äžã«ä¹Ÿç¥åŸã®
èåã12ãã¯ãã³ãšãªãæ§ã«ãã€ã€ãŒããŒã§å¡åž
ã也ç¥ããŠé»è·èŒžéå±€ã圢æããæå äœãäœæã
ããã¢ãŸé¡æNo.ïŒã®ä»£ãã«ç¬¬ïŒè¡šã«ç€ºãã¢ãŸé¡æ
ãçšãåæ§ã«ããŠå®æœäŸïŒã44ã®æå äœãäœæã
ãã ãã®æ§ã«ããŠäœæããé»ååçæå äœãå·å£é»
æ©(æ ª)補éé»è€åçŽè©Šéšè£ 眮Model SPâ428ãçš
ããŠã¹ã¿ããã¯æ¹åŒã§â5kVã§ã³ãã垯é»ãææ
ã§ïŒç§éä¿æããåŸãç §åºŠ2luxã§é²å ã垯é»ç¹æ§
ã枬å®ããã 垯é»ç¹æ§ãšããŠã¯è¡šé¢é»äœïŒV0ïŒãšïŒç§éæ
æžè¡°ãããæã®é»äœã1/2ã«æžè¡°ããã«å¿ èŠãªé²
å éE1/2ïŒluxã»secïŒã枬å®ãããçµæã第ïŒè¡š
ã«ç€ºãã
ãè¡šã
ãè¡šã
ãè¡šã
æ¯èŒäŸ ïŒãïŒ
äŸç€ºã¢ãŸé¡æNo.ïŒã23ã31ã57ã«å¯Ÿå¿ããæ¯èŒ
ããªã¹ã¢ãŸé¡æïŒãïŒ ãçšãå®æœäŸïŒã®é¡æã«ä»£ãæå äœãå®æœäŸïŒãš
å šãåæ§ã«ããŠäœæã垯é»æž¬å®ãè¡ã€ãã 第ïŒè¡šã«æ¬çºæã«å¯Ÿæ¯ãããæ¯èŒäŸã®ç¹æ§ã瀺
ãã
ããªã¹ã¢ãŸé¡æïŒãïŒ ãçšãå®æœäŸïŒã®é¡æã«ä»£ãæå äœãå®æœäŸïŒãš
å šãåæ§ã«ããŠäœæã垯é»æž¬å®ãè¡ã€ãã 第ïŒè¡šã«æ¬çºæã«å¯Ÿæ¯ãããæ¯èŒäŸã®ç¹æ§ã瀺
ãã
ãè¡šã
ïŒ ç¬¬ïŒè¡šã®ããŒã¿ããæç²
第ïŒè¡šã®çµæããæãããªæ§ã«æ¬çºæã®æå äœ
ã¯é¡æã®Ïé»åã®åºãããç¹éæ53â132347ã«é
瀺ãããŠããæ§ãªããªã¹ã¢ãŸé¡æãããæŽã«åºã
ãçºã«é»ååçæ床ãèããè¯å¥œã«ãªãããšã確
èªãããã å®æœäŸ45ã48åã³æ¯èŒäŸïŒãïŒ å®æœäŸïŒã19ã25ã37ã«çšããæå äœãšæ¯èŒäŸ
ïŒãïŒã«çšããæå äœãçšãç¹°è¿ã䜿çšæã®æéš
é»äœãšæéšé»äœã®å€åã枬å®ãããæ¹æ³ãšããŠã¯
â5.6kVã®ã³ãã垯é»åšãé²å å åŠç³»ãçŸååšã
転å垯é»åšãé€é»é²å å åŠç³»ããã³ã¯ãªãŒããŒã
åããé»ååçè€åæ©ã®ã·ãªã³ããŒã«æå äœã貌
ãä»ããããã®è€åæ©ã¯ãã·ãªã³ããŒã®é§åã«äŒŽ
ãã転åçŽäžã«ç»åãåŸãããæ§æã«ãªã€ãŠã
ãããã®è€åæ©ãçšããŠåæã®æéšé»äœïŒVLïŒ
ãšæéšé»äœïŒVDïŒãããããâ100Våã³â600V
ä»è¿ã«èšå®ã5000å䜿çšããåŸã®æéšé»äœ
ïŒVLïŒãæéšé»äœïŒVDïŒã枬å®ããããã®çµæã
第ïŒè¡šã«ç€ºãã
第ïŒè¡šã®çµæããæãããªæ§ã«æ¬çºæã®æå äœ
ã¯é¡æã®Ïé»åã®åºãããç¹éæ53â132347ã«é
瀺ãããŠããæ§ãªããªã¹ã¢ãŸé¡æãããæŽã«åºã
ãçºã«é»ååçæ床ãèããè¯å¥œã«ãªãããšã確
èªãããã å®æœäŸ45ã48åã³æ¯èŒäŸïŒãïŒ å®æœäŸïŒã19ã25ã37ã«çšããæå äœãšæ¯èŒäŸ
ïŒãïŒã«çšããæå äœãçšãç¹°è¿ã䜿çšæã®æéš
é»äœãšæéšé»äœã®å€åã枬å®ãããæ¹æ³ãšããŠã¯
â5.6kVã®ã³ãã垯é»åšãé²å å åŠç³»ãçŸååšã
転å垯é»åšãé€é»é²å å åŠç³»ããã³ã¯ãªãŒããŒã
åããé»ååçè€åæ©ã®ã·ãªã³ããŒã«æå äœã貌
ãä»ããããã®è€åæ©ã¯ãã·ãªã³ããŒã®é§åã«äŒŽ
ãã転åçŽäžã«ç»åãåŸãããæ§æã«ãªã€ãŠã
ãããã®è€åæ©ãçšããŠåæã®æéšé»äœïŒVLïŒ
ãšæéšé»äœïŒVDïŒãããããâ100Våã³â600V
ä»è¿ã«èšå®ã5000å䜿çšããåŸã®æéšé»äœ
ïŒVLïŒãæéšé»äœïŒVDïŒã枬å®ããããã®çµæã
第ïŒè¡šã«ç€ºãã
ãè¡šã
æ¬çºæã®æå
äœã¯ç¹°è¿ã䜿çšæãVDãVLã®å®
å®æ§ã極ããŠè¯å¥œã§ãã€ãã å®æœäŸ 49 å®æœäŸïŒã§äœæããé»è·çºçå±€ã®äžã«ãïŒïŒ
ïŒïŒïŒâããªãããâïŒâãã«ãªã¬ãã³ïŒïœãšã
ãªâïŒïŒ4â²âãžãªãã·ãžããšãã«âïŒïŒ2â²âãã
ãã³ã«ãŒãããŒãïŒååé300000ïŒïŒïœãããã©
ããããã©ã³70mlã«æº¶è§£ããŠäœæããå¡åžæ¶²ã也
ç¥åŸã®å¡å·¥éã10ïœïŒm2ãšãªãæ§ã«å¡åžãã也ç¥
ããã ããããŠäœæããé»ååçæå äœãå®æœäŸïŒãš
åæ§ã®æ¹æ³ã§åž¯é»æž¬å®ãè¡ãªã€ãããã®æã垯é»
極æ§ã¯ãšããããã®çµæã第ïŒè¡šã«ç€ºãã 第ïŒè¡š V0ïŒ570ãã«ã E1/2ïŒ5.7luxã»sec å®æœäŸ 50 ã¢ã«ãèžçããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«
ã ã®ã¢ã«ãé¢äžã«èå0.5ãã¯ãã³ã®ããªããã«
ã¢ã«ã³ãŒã«ã®è¢«èã圢æããã 次ã«ãå®æœäŸïŒã§çšããã¢ãŸé¡æã®åæ£æ¶²ãå
ã«åœ¢æããããªãã«ã¢ã«ã³ãŒã«å±€ã®äžã«ã也ç¥åŸ
ã®èåã0.5ãã¯ãã³ãšãªãæ§ã«ãã€ã€ãŒããŒã§
å¡åžãã也ç¥ããŠé»è·çºçå±€ã圢æããã 次ãã§ãæ§é åŒ ã§ç€ºãããã¹ãã«ãã³èªå°äœ2.5ïœãšæ§é åŒ ã®ãã©ãŸãªã³ååç©2.5ïœãšããªã¢ãªã¬ãŒãæš¹è
ïŒãã¹ããšããŒã«ïŒ¡ãšãã¬ãã¿ã«é žâã€ãœãã¿ã«
é žã®çž®éåäœïŒïŒïœãããã©ããããã©ã³70mlã«
溶ããã液ãé»è·çºçå±€ã®äžã«ä¹Ÿç¥åŸã®èåã10
ãã¯ãã³ãšãªãæ§ã«å¡åžãã也ç¥ããŠé»è·èŒžéå±€
ã圢æããã ããããŠèª¿è£œããæå äœã®åž¯é»ç¹æ§ããã³èä¹
ç¹æ§ãå®æœäŸïŒåã³å®æœäŸ45ãšåæ§ã®æ¹æ³ã«ãã€
ãŠæž¬å®ããããã®çµæã第ïŒè¡šã«ç€ºãã 第ïŒè¡š V0ïŒ590V E1/2ïŒ3.4luxã»sec èä¹ ç¹æ§ å æ 5000æèä¹ åŸ VD VL VD VL â600V â100V â630V â120 第ïŒè¡šã®çµæããæ¬çºæã®æå äœã¯æ床ãè¯ã
èä¹ äœ¿çšæã®é»äœå®å®æ§ãè¯å¥œã§ããã å®æœäŸ 51 åã100ãã¯ãã³åã®ã¢ã«ãæ¿äžã«ã«ãŒã€ã³ã®
ã¢ã³ã¢ãã¢æ°Žæº¶æ¶²ãå¡åžãã也ç¥ããŠèå0.5ã
ã¯ãã³ã®äžåŒå±€ã圢æããã 次ã«ãïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãªã¬
ãã³ïŒïœãšããªââããã«ã«ã«ããŸãŒã«ïŒæ°å¹³
åååé300000ïŒïŒïœãããã©ããããã©ã³70ml
ã«æº¶ãããŠé»è·ç§»åé¯ååç©ã圢æããããã®é»
è·ç§»åé¯ååç©ãšåèšäŸç€ºã®ã¢ãŸé¡æNo.ïŒ26ïŒïŒ
ïœããããªãšã¹ãã«æš¹èïŒãã€ãã³æ±æŽçŽ¡è£œïŒïŒ
ïœãããã©ããããã©ã³70mlã«æº¶ããã液ã«å
ããåæ£ããããã®åæ£æ¶²ãäžåŒå±€ã®äžã«ä¹Ÿç¥åŸ
ã®èåã12ãã¯ãã³ãšãªãæ§ã«å¡åžãã也ç¥ã
ãã ãããã調補ããæå äœã®åž¯é»ç¹æ§ãšèä¹ ç¹æ§
ãå®æœäŸïŒåã³å®æœäŸ45ãšåæ§ã®æ¹æ³ã«ãã€ãŠæž¬
å®ããããã®çµæã第ïŒè¡šã«ç€ºããäœãã垯é»æ¥µ
æ§ã¯ãšããã 第ïŒè¡š V0ïŒ570V E1/2ïŒ5.8luxã»sec èä¹ ç¹æ§ å æ 5000æèä¹ åŸ VD VL VD VL ïŒ595 ïŒ100 ïŒ615 ïŒ115 å®æœäŸ 52 å®æœäŸïŒã§çšããã«ãŒã€ã³å±€ãæœããã¢ã«ãã
ãŠã åºæ¿ã®ã«ãŒã€ã³å±€äžã«å®æœäŸïŒã®é»è·èŒžéå±€
ãšé»è·çºçå±€ãšãé 次ç©å±€ãå±€æ§æé åºãç°ã«ã
ã以å€ã¯å®æœäŸïŒãšå šãåæ§ã«ããŠæå äœãäœæ
ãå®æœäŸïŒãšåæ§ã«åž¯é»æž¬å®ããããäœã垯é»æ¥µ
æ§ããšããã垯é»ç¹æ§ã第ïŒè¡šã«ç€ºãã 第ïŒè¡š V0ïŒ610V E1/2ïŒ4.0luxã»sec
å®æ§ã極ããŠè¯å¥œã§ãã€ãã å®æœäŸ 49 å®æœäŸïŒã§äœæããé»è·çºçå±€ã®äžã«ãïŒïŒ
ïŒïŒïŒâããªãããâïŒâãã«ãªã¬ãã³ïŒïœãšã
ãªâïŒïŒ4â²âãžãªãã·ãžããšãã«âïŒïŒ2â²âãã
ãã³ã«ãŒãããŒãïŒååé300000ïŒïŒïœãããã©
ããããã©ã³70mlã«æº¶è§£ããŠäœæããå¡åžæ¶²ã也
ç¥åŸã®å¡å·¥éã10ïœïŒm2ãšãªãæ§ã«å¡åžãã也ç¥
ããã ããããŠäœæããé»ååçæå äœãå®æœäŸïŒãš
åæ§ã®æ¹æ³ã§åž¯é»æž¬å®ãè¡ãªã€ãããã®æã垯é»
極æ§ã¯ãšããããã®çµæã第ïŒè¡šã«ç€ºãã 第ïŒè¡š V0ïŒ570ãã«ã E1/2ïŒ5.7luxã»sec å®æœäŸ 50 ã¢ã«ãèžçããªãšãã¬ã³ãã¬ãã¿ã¬ãŒããã€ã«
ã ã®ã¢ã«ãé¢äžã«èå0.5ãã¯ãã³ã®ããªããã«
ã¢ã«ã³ãŒã«ã®è¢«èã圢æããã 次ã«ãå®æœäŸïŒã§çšããã¢ãŸé¡æã®åæ£æ¶²ãå
ã«åœ¢æããããªãã«ã¢ã«ã³ãŒã«å±€ã®äžã«ã也ç¥åŸ
ã®èåã0.5ãã¯ãã³ãšãªãæ§ã«ãã€ã€ãŒããŒã§
å¡åžãã也ç¥ããŠé»è·çºçå±€ã圢æããã 次ãã§ãæ§é åŒ ã§ç€ºãããã¹ãã«ãã³èªå°äœ2.5ïœãšæ§é åŒ ã®ãã©ãŸãªã³ååç©2.5ïœãšããªã¢ãªã¬ãŒãæš¹è
ïŒãã¹ããšããŒã«ïŒ¡ãšãã¬ãã¿ã«é žâã€ãœãã¿ã«
é žã®çž®éåäœïŒïŒïœãããã©ããããã©ã³70mlã«
溶ããã液ãé»è·çºçå±€ã®äžã«ä¹Ÿç¥åŸã®èåã10
ãã¯ãã³ãšãªãæ§ã«å¡åžãã也ç¥ããŠé»è·èŒžéå±€
ã圢æããã ããããŠèª¿è£œããæå äœã®åž¯é»ç¹æ§ããã³èä¹
ç¹æ§ãå®æœäŸïŒåã³å®æœäŸ45ãšåæ§ã®æ¹æ³ã«ãã€
ãŠæž¬å®ããããã®çµæã第ïŒè¡šã«ç€ºãã 第ïŒè¡š V0ïŒ590V E1/2ïŒ3.4luxã»sec èä¹ ç¹æ§ å æ 5000æèä¹ åŸ VD VL VD VL â600V â100V â630V â120 第ïŒè¡šã®çµæããæ¬çºæã®æå äœã¯æ床ãè¯ã
èä¹ äœ¿çšæã®é»äœå®å®æ§ãè¯å¥œã§ããã å®æœäŸ 51 åã100ãã¯ãã³åã®ã¢ã«ãæ¿äžã«ã«ãŒã€ã³ã®
ã¢ã³ã¢ãã¢æ°Žæº¶æ¶²ãå¡åžãã也ç¥ããŠèå0.5ã
ã¯ãã³ã®äžåŒå±€ã圢æããã 次ã«ãïŒïŒïŒïŒïŒâããªãããâïŒâãã«ãªã¬
ãã³ïŒïœãšããªââããã«ã«ã«ããŸãŒã«ïŒæ°å¹³
åååé300000ïŒïŒïœãããã©ããããã©ã³70ml
ã«æº¶ãããŠé»è·ç§»åé¯ååç©ã圢æããããã®é»
è·ç§»åé¯ååç©ãšåèšäŸç€ºã®ã¢ãŸé¡æNo.ïŒ26ïŒïŒ
ïœããããªãšã¹ãã«æš¹èïŒãã€ãã³æ±æŽçŽ¡è£œïŒïŒ
ïœãããã©ããããã©ã³70mlã«æº¶ããã液ã«å
ããåæ£ããããã®åæ£æ¶²ãäžåŒå±€ã®äžã«ä¹Ÿç¥åŸ
ã®èåã12ãã¯ãã³ãšãªãæ§ã«å¡åžãã也ç¥ã
ãã ãããã調補ããæå äœã®åž¯é»ç¹æ§ãšèä¹ ç¹æ§
ãå®æœäŸïŒåã³å®æœäŸ45ãšåæ§ã®æ¹æ³ã«ãã€ãŠæž¬
å®ããããã®çµæã第ïŒè¡šã«ç€ºããäœãã垯é»æ¥µ
æ§ã¯ãšããã 第ïŒè¡š V0ïŒ570V E1/2ïŒ5.8luxã»sec èä¹ ç¹æ§ å æ 5000æèä¹ åŸ VD VL VD VL ïŒ595 ïŒ100 ïŒ615 ïŒ115 å®æœäŸ 52 å®æœäŸïŒã§çšããã«ãŒã€ã³å±€ãæœããã¢ã«ãã
ãŠã åºæ¿ã®ã«ãŒã€ã³å±€äžã«å®æœäŸïŒã®é»è·èŒžéå±€
ãšé»è·çºçå±€ãšãé 次ç©å±€ãå±€æ§æé åºãç°ã«ã
ã以å€ã¯å®æœäŸïŒãšå šãåæ§ã«ããŠæå äœãäœæ
ãå®æœäŸïŒãšåæ§ã«åž¯é»æž¬å®ããããäœã垯é»æ¥µ
æ§ããšããã垯é»ç¹æ§ã第ïŒè¡šã«ç€ºãã 第ïŒè¡š V0ïŒ610V E1/2ïŒ4.0luxã»sec
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¬¡ã®äžè¬åŒïŒã ïŒåŒäžAr1ãAr6ã¯ãããã眮æåºãæããŠãã
ãã¢ãªãŒã¬ã³åºãããã¯ïŒäŸ¡ã®è€çŽ ç°åºã瀺ãã
ïœåã³ïœã¯ããããïŒãããã¯ïŒã瀺ããã¯ã
ãšããŒã«æ§OHåºãæããã«ãã©ãŒæ®åºã瀺ãïŒ
ã§è¡šããããã¢ãŸé¡æãæå å±€ã«å«æãããããš
ãç¹åŸŽãšããé»ååçæå äœã ïŒ äžèšäžè¬åŒïŒã«ããããäžèšäžè¬åŒïŒãïŒ
ã§ç€ºãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã®é»ååçæå
äœïŒ ïŒåŒäžïŒžã¯ãã³ãŒã³ç°ãšçž®åããŠå€ç°è³éŠç°ãã
ãã¯è€çŽ ç°ã圢æããæ®åºïŒR3ããã³R4ã¯æ°ŽçŽ ã
眮æåºãæããŠãè¯ãã¢ã«ãã«ãã¢ã©ã«ãã«ãã¢
ãªãŒã«ãããã¯è€çŽ ç°åºãŸãã¯äžç·ã«ãªã€ãŠçªçŽ
ååãšå ±ã«ç°ç¶ã¢ããåºã圢æããåºïŒR5åã³
R6ã¯ãããã眮æåºãæããŠãããã¢ã«ãã«ã
ã¢ã©ã«ãã«ãã¢ãªãŒã«ã瀺ãïŒïŒ¹ã¯è³éŠæçåæ°Ž
çŽ ã®ïŒäŸ¡ã®åºãããã¯çªçŽ ååãšäžç·ã«ãªã€ãŠè€
çŽ ç°ã®ïŒäŸ¡ã®åºã圢æããïŒR7ã¯çœ®æåºãæã
ãŠãããã¢ãªãŒã«ãããã¯è€çŽ ç°åºã瀺ãïŒR8
åã³R9ã¯ãããã眮æåºãæããŠãããã¢ã«ã
ã«ãã¢ã©ã«ãã«ãã¢ãªãŒã«ãããã¯è€çŽ ç°åºã瀺
ãïŒã ïŒ äžèšæå å±€ãé»è·çºçå±€ãšé»è·èŒžéå±€ãšãã
ãªãæ©èœåé¢åã§ãã該é»è·çºçå±€ãäžèšäžè¬åŒ
(1)ã§ç€ºãããã¢ãŸé¡æãå«æãããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé ã®é»ååçæå äœã ïŒ äžèšäžè¬åŒ(2)ã«ãããR3ãæ°ŽçŽ ã§ãããR4
ã次ã®äžè¬åŒ ïŒåŒäžR10ã¯ããã²ã³ãããããã·ã¢ããããªã
ã«ãªãã¡ãã«ããéžã°ãã眮æåºïŒã§è¡šãããã
眮æããšãã«ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã®é»å
åçæå äœã
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6972485A JPS61251863A (ja) | 1985-04-02 | 1985-04-02 | é»ååçæå äœ |
| US06/846,900 US4735882A (en) | 1985-04-02 | 1986-04-01 | Trisazo photsensitive member for electrophotography |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6972485A JPS61251863A (ja) | 1985-04-02 | 1985-04-02 | é»ååçæå äœ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61251863A JPS61251863A (ja) | 1986-11-08 |
| JPH042947B2 true JPH042947B2 (ja) | 1992-01-21 |
Family
ID=13411069
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6972485A Granted JPS61251863A (ja) | 1985-04-02 | 1985-04-02 | é»ååçæå äœ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61251863A (ja) |
-
1985
- 1985-04-02 JP JP6972485A patent/JPS61251863A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61251863A (ja) | 1986-11-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH042944B2 (ja) | ||
| JPH0441342B2 (ja) | ||
| JPS61129653A (ja) | é»ååçæå äœ | |
| JP2592271B2 (ja) | é»ååçæå äœ | |
| JPH039462B2 (ja) | ||
| JPH0454228B2 (ja) | ||
| JPH042946B2 (ja) | ||
| JPH0727235B2 (ja) | é»ååçæå äœ | |
| JPH0516586B2 (ja) | ||
| JPH042948B2 (ja) | ||
| JP2652389B2 (ja) | é»ååçæå äœ | |
| JP2535203B2 (ja) | é»ååçæå äœ | |
| JPH0513502B2 (ja) | ||
| JP2608310B2 (ja) | é»ååçæå äœ | |
| JPH0435751B2 (ja) | ||
| JP2572771B2 (ja) | é»ååçæå äœ | |
| JPH042947B2 (ja) | ||
| JP2566431B2 (ja) | é»ååçæå äœ | |
| JP2515999B2 (ja) | é»ååçæå äœ | |
| JPH0473578B2 (ja) | ||
| JP2538266B2 (ja) | é»ååçæå äœ | |
| JPH0370221B2 (ja) | ||
| JPH07117759B2 (ja) | é»ååçæå äœ | |
| JPH07120056B2 (ja) | é»ååçæå äœ | |
| JPH0370218B2 (ja) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |