JPH041787B2 - - Google Patents
Info
- Publication number
- JPH041787B2 JPH041787B2 JP61037718A JP3771886A JPH041787B2 JP H041787 B2 JPH041787 B2 JP H041787B2 JP 61037718 A JP61037718 A JP 61037718A JP 3771886 A JP3771886 A JP 3771886A JP H041787 B2 JPH041787 B2 JP H041787B2
- Authority
- JP
- Japan
- Prior art keywords
- polyester
- modifier
- synthetic resin
- liquid rubber
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001400 block copolymer Polymers 0.000 claims description 33
- 229920001971 elastomer Polymers 0.000 claims description 33
- 229920000728 polyester Polymers 0.000 claims description 32
- 239000005060 rubber Substances 0.000 claims description 32
- 229920003002 synthetic resin Polymers 0.000 claims description 29
- 239000000057 synthetic resin Substances 0.000 claims description 29
- 239000007788 liquid Substances 0.000 claims description 28
- 150000001875 compounds Chemical group 0.000 claims description 25
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 22
- 239000003607 modifier Substances 0.000 claims description 21
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 18
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 7
- 229920002857 polybutadiene Polymers 0.000 claims description 7
- 239000005062 Polybutadiene Substances 0.000 claims description 6
- 150000008064 anhydrides Chemical class 0.000 claims description 6
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 claims description 4
- LNPQMDSMIGLHSR-UHFFFAOYSA-N 2-oxaspiro[3.5]non-5-ene-1,3-dione Chemical compound O=C1OC(=O)C11C=CCCC1 LNPQMDSMIGLHSR-UHFFFAOYSA-N 0.000 claims description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- 229940014800 succinic anhydride Drugs 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical group CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- HHCHLHOEAKKCAB-UHFFFAOYSA-N 2-oxaspiro[3.5]nonane-1,3-dione Chemical compound O=C1OC(=O)C11CCCCC1 HHCHLHOEAKKCAB-UHFFFAOYSA-N 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 125000003700 epoxy group Chemical group 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 1
- 125000003277 amino group Chemical group 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 21
- 229920005989 resin Polymers 0.000 description 17
- 239000011347 resin Substances 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 15
- 239000011159 matrix material Substances 0.000 description 15
- -1 polyethylene terephthalate Polymers 0.000 description 15
- 229920001187 thermosetting polymer Polymers 0.000 description 12
- 239000000126 substance Substances 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 229920006337 unsaturated polyester resin Polymers 0.000 description 8
- 229920001169 thermoplastic Polymers 0.000 description 7
- 239000004416 thermosoftening plastic Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 150000002118 epoxides Chemical class 0.000 description 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920005992 thermoplastic resin Polymers 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000012744 reinforcing agent Substances 0.000 description 3
- 238000011191 terminal modification Methods 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002990 reinforced plastic Substances 0.000 description 2
- 238000007142 ring opening reaction Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- OMIHGPLIXGGMJB-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]hepta-1,3,5-triene Chemical compound C1=CC=C2OC2=C1 OMIHGPLIXGGMJB-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920013646 Hycar Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GRSMWKLPSNHDHA-UHFFFAOYSA-N Naphthalic anhydride Chemical compound C1=CC(C(=O)OC2=O)=C3C2=CC=CC3=C1 GRSMWKLPSNHDHA-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- ZWAJLVLEBYIOTI-UHFFFAOYSA-N cyclohexene oxide Chemical compound C1CCCC2OC21 ZWAJLVLEBYIOTI-UHFFFAOYSA-N 0.000 description 1
- FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohexene oxide Natural products O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- DDFYFBUWEBINLX-UHFFFAOYSA-M tetramethylammonium bromide Chemical compound [Br-].C[N+](C)(C)C DDFYFBUWEBINLX-UHFFFAOYSA-M 0.000 description 1
- FBEVECUEMUUFKM-UHFFFAOYSA-M tetrapropylazanium;chloride Chemical compound [Cl-].CCC[N+](CCC)(CCC)CCC FBEVECUEMUUFKM-UHFFFAOYSA-M 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- DHAWHVVWUNNONG-UHFFFAOYSA-M tributyl(methyl)azanium;bromide Chemical compound [Br-].CCCC[N+](C)(CCCC)CCCC DHAWHVVWUNNONG-UHFFFAOYSA-M 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/40—Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds, other than from esters thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
ïŒç£æ¥äžã®å©çšåéïŒ
æ¬çºæã¯åææš¹èææçšæ¹è³ªå€ãç¹ã«æ¶²ç¶ãŽã
ç³»âããªãšã¹ãã«ç³»ãããã¯å ±éåäœïŒä»¥äžã
PDâPESãããã¯å ±éåäœãšããïŒããæãç±
硬åæ§åã¯ç±å¯å¡æ§åææš¹èææçšæ¹è³ªå€ã«é¢ã
ãã å€ãã®ç±ç¡¬åæ§åææš¹èåã³ç±å¯å¡æ§åææš¹è
ãã济槜ãæµå槜å ã®äœå® æ©æãæ©æ¢°ãé»æ°è£œå
çã®å·¥æ¥éšæãèªåè»ãééè»èŒçã®èŒžéæ©åš
æãæŽã«ã¯è²¯èµçšã¿ã³ã¯ã容åšçã«åºãå©çšãã
ãŠãããããããã®åææš¹èã䜿çšããŠå å·¥ãã
å Žé¢ã§ã¯äžè¬ã«ããã®æ©æ¢°ç匷床çç©æ§ãæ¹åã
ãããã«ããã®ä»ã®åçš®ã®åææš¹èé¡ãå å¡«å€ã
ç¹ç¶è£åŒ·å€çãæ·»å ããããç¹ã«ãã®æ圢ç©ãæ§
é ææãšããŠäœ¿çšãããå Žåã«ã¯ãè¡æ匷床ãå
äžãããããšãå¿ é ã§ããããã®ãããåçš®ã®è£
匷å€ã«å ãããŽã ç³»ç©è³ªãä»ã®ããªããŒãç®çã«
å¿ããŠãã¬ã³ããããããšã¯ããç¥ãããŠããã
ãŸããç±ç¡¬åæ§åææš¹èã®äžã€ã§ããäžé£œåããª
ãšã¹ãã«æš¹èã¯ç¡¬ååå¿ã«ãšããªãïŒã10ïŒ ã®äœ
ç©åçž®ãçããæ圢ç©ã®å€èŠ³ã寞æ³ç²ŸåºŠãäœäžã
ãããã®ããããŽã ç³»ç©è³ªãä»ã®ç±å¯å¡æ§åææš¹
èããã¬ã³ããããããšãããç¥ãããŠãããã
ããŠäžèšã®ãããªè¡æ匷床ã®æ¹åãäœç©åçž®ã®äœ
äžãå³ãããã«äœ¿çšããããŽã ç³»ç©è³ªãšããŠãã
ãªãã¿ãžãšã³ããã¿ãžãšã³âã¹ãã¬ã³å ±éåäœã
ãã¿ãžãšã³âã¢ã¯ãªããããªã«å ±éåäœããã¿ãž
ãšã³âã¹ãã¬ã³âã¢ã¯ãªããããªã«äžå å ±éå
äœãåã³å€æ§ããªãã¿ãžãšã³çãããããšããŸã
ããç¥ãããŠããã èè¡ææ§ãæ¹è¯ãã匷åãã©ã¹ããã¯ã¹ã®äž»æ
åææš¹èã§ããæè¬ãããªãã¯ã¹æš¹èãšããŠãç±
硬åæ§äžé£œåããªãšã¹ãã«æš¹è䞊ã³ã«ãããªãšã
ã¬ã³ãã¬ãã¿ã¬ãŒããããªããã«ãã¬ãã¿ã¬ãŒ
ããããªã«ãŒãããŒããããªã¢ããçã®ç±å¯å¡æ§
åææš¹èããã®åéã«åºãå©çšãããŠããããã
ãã®åææš¹èã«ããŽã ç³»ç©è³ªãè£åŒ·æãé¡æãå
å¡«å€çãé åããåçš®ã®æ圢æ¹æ³ãçµãŠåŒ·åãã©
ã¹ããã¯ã¹ã補é ãããã®ã§ããã ãšãããããããªãã¯ã¹æš¹èãšãŽã ç³»ç©è³ªãš
ã¯ããã®ç©æ§ãäŸãã°æ¥µæ§ã溶解ãã©ã¡ãŒã¿ãŒç
ã倧ããç°ãªããããåæ¹ãåäžã«æ··åãæãã¯
å®å®ã«åæ£ãããããšã極ããŠå°é£ã§ãããäžå®
å®ãªæ··åç¶æ ã®ç±ç¡¬åæ§åææš¹èçµæç©ããåŸã
ããæ圢ç©ã®è¡šé¢ç¶æ ã¯äžè¯ã§ãå¹åžããŽã ç³»ç©
質ã®æµ®ãåºãçãèªããããç®çãšããæ©æ¢°ç匷
床ãåçž®äœæžçã極ããŠäžå åãªãã®ãšãªãããŸ
ãäžå®å®ãªåæ£ç¶æ ã®ç±å¯å¡æ§åææš¹èçµæç©ã
çšãããšãæ圢æã«äžæ¹ã®æåãåéããããã
æ圢æ§ã®äžè¯ãæ圢ç©ã®ç©æ§ã®ãã©ããã倧ãã
ãªãçã®äžå ·åãçããã ããã§ãç±ç¡¬åæ§æãã¯ç±å¯å¡æ§ã®ãããªãã¯
ã¹æš¹èã«å¯ŸããŠåäžæ··åæãã¯å®å®åæ£ããæ圢
äœæ¥æ§ããããåªããè¡šé¢ã®æ圢ç©ãåŸããã該
æ圢ç©ã®æ©æ¢°ç匷床ãåçž®äœæžçãæ Œæ®µã«æ¹è¯ã
ãããšãã§ããæ¹è³ªå€ã®åºçŸã匷ãèŠè«ãããã æ¬çºæã¯ãããèŠè«ã«å¿ããåææš¹èææçšæ¹
質å€ã«é¢ãããã®ã§ããã ïŒåŸæ¥ã®æè¡ããã®åé¡ç¹ïŒ åŸæ¥ãç±ç¡¬åæ§æãã¯ç±å¯å¡æ§åææš¹èãšã®çž
溶ä¹è³ã¯åæ£æ§æ¹åãç®çãšããåçš®ã®ææ¡ããª
ãããŠãããæ·»å ãããŽã ç³»ç©è³ªã®æ¹è³ªã«é¢ãã
ææ¡ã§ã¯ããŽã ç³»ç©è³ªã«ä»ã®åéäœãäŸãã°ã¹ã
ã¬ã³ããã¬ã€ã³é žãã¡ã¿ã¯ãªã«é žãšã¹ãã«ãã¢ã¯
ãªã«é žãšã¹ãã«çãã°ã©ããéåããããã®ãã
ãïŒç¹éæ54â18862ãç¹éæ54â40846çïŒãã
ããã®ãã®ã¯ãäžè¬ã«ã°ã©ããå¹çãæªããæªã
å åãªçžæº¶æ§ä¹è³ã¯åæ£æ§ã瀺ãã«è³ããªããšã
ãåé¡ç¹ãããããŸããç±ç¡¬åæ§åææš¹èã«å¯Ÿã
ãçžæº¶æ§ãæ¹åããææ¡ãšããŠãã¹ãã¬ã³ç³»ããª
ããŒã®ãããã¯å ±éåäœãããïŒç¹éæ53â
74592ãç¹éæ60â99158ïŒããã®ãã®ã¯ãçžæº¶æ§
ã¯ããçšåºŠæ¹åãããŠãããã®ã®ãæ¬è³ªçã«éæ§
ã®ä¹ããã¹ãã¬ã³ç³»ããªããŒãçšãããã®ã§ãã
ãããäœåçž®æ§äžŠã³ã«ãšãããèè¡ææ§ã®ç¹ã§è
ãããå£ããšããåé¡ç¹ããããäžé£œåããªãšã¹
ãã«æš¹èããŽã å€æ§ããææ¡ã§ã¯ãαïŒÎ²âäžé£œ
åãžã«ã«ãã³é žãå«ãäžé£œåããªãšã¹ãã«ã®äºé
åçµåã«å¯ŸããŠãå ±åœ¹ãžãšã³ç³»ååç©ãäŸãã°ãž
ã·ã¯ããã³ã¿ãžãšã³ããã€ãŒã«ã¹ã¢ã«ããŒä»å ã
ããã®ãããïŒç¹éæ58â2315ïŒããã®ãã®ã¯ã
å ±åœ¹ãžãšã³ç³»ååç©ã®ä»å éãå°ãªãããã«ãäž
飜åããªãšã¹ãã«æš¹èãšã®çžæº¶æ§ã¯æåŸ ã§ããå
é¢ãäœåçž®æ§åã³èè¡ææ§ã®ç¹ã§å¹æãåŸãããª
ããšããåé¡ç¹ãããã ïŒçºæã解決ããããšããåé¡ç¹ããã®è§£æ±ºæ段
ïŒ æ¬çºæã¯ãåäžã®åŠãåŸæ¥ã®åé¡ç¹ã解決ãã
åè¿°ããèŠè«ã«å¿ããåææš¹èææ溶é質å€ãæ
äŸãããã®ã§ããã ããããŠæ¬çºæè ãã¯ãäžèšèŠ³ç¹ã§éæç 究ã
ãçµæã液ç¶ãŽã ç³»ååç©éšåãšããªãšã¹ãã«éš
åãšãã»ã°ã¡ã³ããšããŠæããPDâPESããã
ã¯å ±éåäœãæ£ãã奜é©ã§ããããšãèŠåºããæ¬
çºæãå®æããã«å°ã€ãã ããªãã¡æ¬çºæã¯ããããæ§æããã»ã°ã¡ã³ã
ãšããŠãšãã«ãããã¯ç¶ã®æ¶²ç¶ãŽã ç³»ååç©éšå
ãšããªãšã¹ãã«éšåãšãå°ãªããšãåãã液ç¶ãŽ
ã ç³»ååç©éšåïŒåã«å¯ŸããŠãšã¹ãã«çµåãä»ã
ãŠããªãšã¹ãã«éšåãïŒååã¯ïŒå以äžé£çµãã
ãŠãã液ç¶ãŽã ç³»âããªãšã¹ãã«ç³»ãããã¯å ±é
åäœã§ãã€ãŠã該ããªãšã¹ãã«éšåã液ç¶ãŽã å
åç©ååäžã®ã«ã«ããã·ã«åºåã¯æ°Žé žåºãåºçºåº
質ãšããŠããã«ææ©ãžã«ã«ãã³é žç¡æ°Žç©ãšïŒïŒïŒ
âãšããã·ããšã觊åªååšäžã«äº€äºã«çž®å圢æã
ããããªãšã¹ãã«éã§ãã液ç¶ãŽã ç³»âããªãšã¹
ãã«ç³»ãããã¯å ±éåäœããæãããšãç¹åŸŽãšã
ãåææš¹èææçšæ¹è³ªå€ã«ä¿ãã æ¬çºæã®PDâPESãããã¯å ±éåäœã¯ãåå
å ã«ãæ°Žé žåºåã¯ã«ã«ããã·ã«åºçã®æŽ»æ§æ°ŽçŽ ã
æã€åå¿æ§åºãæãã液ç¶ãŽã ç³»ååç©ãåºçºç©
質ãšãã觊åªååšäžã«ãææ©ãžã«ã«ãã³é žç¡æ°Žç©
ãšïŒïŒïŒâãšããã·ããšãåå¿ããã液ç¶ãŽã ç³»
ååç©ã®åå¿æ§åºãä»ããŠããªãšã¹ãã«éãå°å ¥
ããããšã«ãããå·¥æ¥äžæå©ã«å®å®ããŠåŸãããš
ãã§ããããã®åå¿ã«ãããããªãšã¹ãã«éã®åœ¢
æéçšã¯ã掻æ§æ°ŽçŽ ãæããåå¿æ§åºãšããŠã®äŸ
ãã°æ°Žé žåºãšææ©ãžã«ã«ãã³é žç¡æ°Žç©ãšã®åå¿ã«
ãã€ãŠåœ¢æãããã«ã«ããã·ã«åºã«ïŒïŒïŒâãšã
ãã·ããéç°ä»å ããŠæ°Žé žåºã圢æãããããã«
ãŸãææ©ãžã«ã«ãã³é žç¡æ°Žç©ãä»å ãããšããã
æ°Žé žåºãšææ©ãžã«ã«ãã³é žç¡æ°Žç©ãšã®ãšã¹ãã«å
åå¿ãšãã«ã«ããã·ã«åºãšïŒïŒïŒâãšããã·ããš
ã®éç°ä»å åå¿ãšããé 次亀äºã«èµ·ãããããªãš
ã¹ãã«éã圢æããŠãããã®ã§ããã äžèšåå¿ã«ãããŠæ¶²ç¶ãŽã ç³»ååç©ã¯ãåèšã
ããããªãæ°Žé žåºåã¯ã«ã«ããã·ã«åºã®æŽ»æ§æ°ŽçŽ
åºãæããããžãšã³ç³»ãã¢ããªããŒåã¯ãããã«
éšåçã«ãããŠå¥œãŸããã¯ã§ããã ãå°éã§ãã
ã«ç³»ååç©ãå«ãŸããããªããŒã§ããããã®ãã
ãªæŽ»æ§æ°Žé žåºã¯ãããªãžãšã³éã®éäžåã¯æ«ç«¯ã«
ïŒååã¯ïŒå以äžååšãããã®ã§ããã°ããã掻
æ§æ°Žé žåºã®ããªãžãšã³éãžã®å°å ¥äœçœ®ã«ã€ããŠç¹
ã«å¶éãããã®ã§ã¯ãªãããŸãã液ç¶ãŽã ç³»åå
ç©ã®éåæ¹åŒãäŸãã°ã©ãžã«ã«éåãã¢ããªã³é
åãã¢ããªã³ãã³ã°éåçã®éãã«ãããã®éå
äœã®ç«äœç°æ§äœãæ§é ç°æ§äœã«ã€ããŠãç¹ã«å¶é
ãããã®ã§ã¯ãªãã äžèšã®ãããªæ¶²ç¶ãŽã ç³»ååç©ãæ§æããåé
äœãžãšã³ååç©ã¯ããã¿ãžãšã³ãã€ãœãã¬ã³ãã¯
ãããã¬ã³ãïŒïŒïŒâãã³ã¿ãžãšã³ãã·ã¯ããã³
ã¿ãžãšã³çã§ããã åèšåå¿ã§ãæå©ã«äœ¿çšã§ãã液ç¶ãŽã ç³»åå
ç©ãäŸç€ºãããšãαïŒÏâïŒïŒïŒâããªãã¿ãžãš
ã³ã°ãªã³ãŒã«ïŒNisso PBâã·ãªãŒãºïŒãαïŒ
ÏâïŒïŒïŒâããªãã¿ãžãšã³ã«ã«ãã³é žïŒNisso
PBâã·ãªãŒãºïŒãαïŒÏâïŒïŒïŒâããªãã¿ãž
ãšã³æ«ç«¯ãã¬ã€ã³é žåãšã¹ãã«ïŒNisso PBâ
GMã·ãªãŒãºã以äžïŒç¹ã¯æ¥æ¬æ¹ç€Ÿè£œïŒãæ«ç«¯ã«
ã«ããã·ã«å€æ§ïŒïŒïŒâããªãã¿ãžãšã³ïŒHycar
CTBã·ãªãŒãºãå®éšèç£ç€Ÿè£œåã¯B.F.ã°ãããª
ãã瀟補ïŒãæ«ç«¯æ°Žé žåºå€æ§ïŒïŒïŒâããªãã¿ãž
ãšã³ïŒPolyâbd â45Måã¯ïŒ²â45HTãåºå
ç³æ²¹ååŠç€Ÿè£œåã¯ã¢ãŒã³ã±ãã«ã«ç€Ÿè£œïŒçãæã
ãããã 掻æ§æ°Žé žåºãæãã液ç¶ãŽã ç³»ååç©ãšããŠ
ã¯ãäžèšãããããªæ¶²ç¶ãŽã ç³»ååç©ã®äž»éåã¯
åŽéã®ççŽ âççŽ äºéçµåãéšåçã«åã¯å®å šã«
æ°ŽçŽ æ·»å ãããã®ãå©çšã§ãããããã«ã¯äŸã
ã°ãæ°ŽçŽ æ·»å αïŒÏâïŒïŒïŒâããªãã¿ãžãšã³ã°
ãªã³ãŒã«ïŒNisso PBâGIã·ãªãŒãºãæ¥æ¬æ¹é瀟
補ïŒãæ°ŽçŽ æ·»å αïŒÏâïŒïŒïŒâããªãã¿ãžãšã³
ãžã«ã«ãã³é žïŒNisso PBâCIã·ãªãŒãºãæ¥æ¬æ¹
é瀟補ïŒçãããã ãŸãåèšåå¿ã«ãããŠææ©ãžã«ã«ãã³é žç¡æ°Žç©
ãšããŠã¯ãã³ãã¯é žç¡æ°Žç©ããã¬ã€ã³é žç¡æ°Žç©ã
ã¢ã«ã±ãã«ã³ãã¯é žç¡æ°Žç©çã®èèªæãžã«ã«ãã³
é žç¡æ°Žç©ããã¿ã«é žç¡æ°Žç©ãããã¿ã¬ã³ãžã«ã«ã
ã³é žç¡æ°Žç©çã®è³éŠæãžã«ã«ãã³é žç¡æ°Žç©ãã·ã¯
ããããµã³ãžã«ã«ãã³é žç¡æ°Žç©ãã·ã¯ãããã»ã³
ãžã«ã«ãã³é žç¡æ°Žç©ããšã³ãã¡ãã¬ã³ã·ã¯ããã
ã»ã³ãžã«ã«ãã³é žç¡æ°Žç©çã®èç°æãžã«ã«ãã³é ž
ç¡æ°Žé žç©çãæããããã æŽã«åèšåå¿ã«ãããŠïŒïŒïŒâãšããã·ããšã
ãŠã¯ããšãã¬ã³ãªããµã€ãããããã¬ã³ãªããµã€
ããïŒïŒïŒâããã¬ã³ãªããµã€ããççŽ æ°ïŒã12
ã®ã¢ã«ãã«åã¯ã¢ã«ãã±ã«ã°ãªã·ãžã«ãšãŒãã«ç
ã®èèªæãšããã·ãé¡ãããšãã¬ã³ãªããµã€ãã
ã·ã¯ãããã»ã³ãªããµã€ãçã®è³éŠæãšããã·ã
åã¯èç°æãšããã·ãé¡ãã¹ãã¬ã³ãªããµã€ãã
ããšãã«ã°ãªã·ãžã«ãšãŒãã«çã®è³éŠæåºãæã
ããšããã·ãé¡ãã°ãªã·ãžã«ã¡ã¿ã¯ãªã¬ãŒããã°
ãªã·ãžã«ã¢ã¯ãªã¬ãŒãçã®Î±ïŒÎ²âäžé£œåçåæ°Ž
çŽ åºãæãããšããã·ãé¡çãæããããã ãããŠåèšåå¿ã«ãããŠè§ŠåªãšããŠã¯ãå¡©åãª
ããŠã ãèåãªããŠã çã®ããã²ã³åãªããŠã ã
ããã©ã¡ãã«ã¢ã³ã¢ããŠã ãããã€ããããªãã
ã«ã¡ãã«ã¢ã³ã¢ããŠã ãããã€ããããã©ããã
ã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãçã®ããã©ã¢ã«ãã«ç¬¬
åçŽã¢ã³ã¢ããŠã å¡©ãæããããã ãããŸã§ããªãã以äžäŸç€ºãããããã«ã€ããŠ
ããæ¬çºæããããã«éå®ããããšãããã®ã§ã¯
ãªãã 次ã«ãæ¬çºæã®PDâPESãããã¯å ±éåäœã®
æå©ãªè£œé æ¹æ³ã®äžäŸãããå ·äœçã«æãããäž
掻æ§æº¶åªã®ååšäžåã¯éååšäžã«ãæ°Žé žåºåã¯ã«
ã«ããã·ã«åºãæãã液ç¶ãŽã ç³»ååç©ïŒã¢ã«ã«
察ãæå®ã¢ã«éã®ææ©ãžã«ã«ãã³é žç¡æ°Žç©åã³è§Š
åªãåå¿å®¹åšã«ä»èŸŒã¿ãåžžå§åã¯å å§äžã«æå®ã¢
ã«éã®ïŒïŒïŒâãšããã·ããå°å ¥ãã50ã200âã
奜ãŸããã¯120ã150âã®å ç±äžã«åå¿ãããŠã
PDâPESãããã¯å ±éåäœãåŸãã ããããŠåŸãããæ¬çºæã®ãããã¯å ±éåäœäž
ã®ããªãšã¹ãã«éã®æ«ç«¯åºã¯ãéåžžãæ°Žé žåºåã¯
ã«ã«ããã·ã«åºæãã¯ãããã®æ··åãšãªãããæ«
端åºãšããŠã®æ°Žé žåºãšã«ã«ããã·ã«åºãšã®æ¯çã¯
åå¿ã«é¢äžããææ©ãžã«ã«ãã³é žç¡æ°Žç©ãšïŒïŒïŒ
âãšããã·ããšã®ã¢ã«æ¯ã«ãã€ãŠå·Šå³ããããã
ãæ ãæ«ç«¯åºãšããŠã®æ°Žé žåºãšã«ã«ããã·ã«åºãš
ã®æ¯çã¯äžèšäž¡è ã®åå¿ã¢ã«æ¯ãéžæããããšã«
ãã€ãŠå€åãããããšãã§ããã äžèšã®ãããªæ«ç«¯åºãšããŠã®æ°Žé žåºåã³ïŒåã¯
ã«ã«ããã·ã«åºã¯ã該æ«ç«¯åºãšåå¿æ§ã®ããç©è³ª
ãšãåå¿ããããšãŒãã«çµåããšã¹ãã«çµåçã®
é£çµåºãä»ããŠåçš®ã®åå¿æ§åºãäŸãã°ããã«
åºããšããã·åºãã€ãœã·ã¢ããŒãåºçãä»å ãã
æ«ç«¯å€æ§ãè¡ãªãããšãã§ãããŸãæ«ç«¯ã®æ°Žé žåº
ã«å¯Ÿãããžã«ã«ãã³é žãäºäŸ¡ä»¥äžã®å€å¡©åºé žåã¯
ãããã®é žç¡æ°Žç©ãåå¿ãããŠæ«ç«¯ã«ã«ããã·ã«
å€æ§ãããããšãã§ãããæŽã«ãæ«ç«¯åºãšããŠã®
æ°Žé žåºåã¯ã«ã«ããã·ã«åºãããšãŒãã«çµåããš
ã¹ãã«çµååã¯ã¢ããçµåçãä»ããŠå°éããé
åå¿æ§ã®æ«ç«¯å€æ§ãè¡ãªãããšãã§ããæ«ç«¯ã®ã«
ã«ããã·ã«åºã®åå¿æ§ãäžæŽ»æ§åããç®çã§ã該
ã«ã«ããã·ã«åºãã¢ã«ã«ãªéå±å¡©ãã¢ã«ã«ãªåé¡
éå±å¡©çã®å¡©ã«å€åœ¢ããããšãã§ããã æ¬çºæã®PDâPESãããã¯å ±éåäœã®æ«ç«¯åº
ã«ã€ããŠãSMCïŒæ¿ç¶æ圢ææïŒãBMCïŒå¡ç¶æ
圢ææïŒã®è£œé ã§ã¯å¢ç²å€ãšããŠé žåãã°ãã·ãŠ
ã åã¯ã€ãœã·ã¢ããŒãé¡ã䜿çšãããããé žåã
ã°ãã·ãŠã ã䜿çšããå Žåã¯æ«ç«¯åºãšããŠã«ã«ã
ãã·ã«åºã®æ¯çãããŸãã€ãœã·ã¢ããŒãé¡ã䜿çš
ããå Žåã¯æ«ç«¯åºãšããŠæ°Žé žåºã®æ¯çããããã
é«ãããã®ããæ圢ææã§ããäžé£œåããªãšã¹ã
ã«æš¹èçµæç©ã®å®å®æ§ãåŸãããæ圢ç©ã®ç©æ§æ¹
åã«æ¥µããŠæå¹ã§ããããããŠãåè¿°ã®åŠãåå¿
æ§ã®æ«ç«¯å€æ§ãè¡ãªã€ããã®ã¯ããã®ãã®ãšãã
ãªãã¯ã¹æš¹èåã¯åçš®ã®å å¡«å€ãæ¶æ©å€ãšã®éã«
ååŠççµåã圢æããããããæ圢ç©ã®ç©æ§æ¹è¯
ã«ã¯æ¥µããŠæå¹ãªå Žåãå€ãããŸãåè¿°ã®åŠãé
åå¿æ§ã®æ«ç«¯å€æ§ãè¡ãªã€ããã®ã¯ããããªãã¯
ã¹æš¹èãšã®çžæº¶æ§æãã¯ååŠçå®å®æ§ãåäžãã
å Žåãå€ãã æ¬çºæã®PDâPESãããã¯å ±éåäœã¯ãç±ç¡¬
åæ§æš¹èåã³åçš®ã®ç±å¯å¡æ§æš¹èããããªãã¯ã¹
æš¹èãšããæ圢ç©ã®èè¡ææ§åäžåã³ïŒåã¯ç¡¬å
åçž®äœäžãç®çãšããæ¹è³ªå€ãšããŠç¹ã«åªããæ§
質ãæããããã®çç±ã¯ãPDâPESãããã¯å ±
éåäœããåŸæ¥ããåæ§ã®ç®çã§äœ¿çšããããŽã
ç³»ç©è³ªãç±å¯å¡æ§æš¹èã«æ¯èŒããŠããããªãã¯ã¹
æš¹èã«å¯Ÿããåäžäžã€å®å®ãªçžæº¶æ§ä¹è³åæ£æ§ã
çºæ®ããããã§ãããPDâPESãããã¯å ±éå
äœã¯ã液ç¶ãŽã ç³»ååç©éšåãšããªãšã¹ãã«éšå
ãšã®ãåæ¹ã®ååéãæ§é ãçµæ䞊ã³ã«ååéæ¯
ççã«ãã€ãŠææã®æ§è³ªã®ãã®ãåŸãããããã
ãªãã¯ã¹æš¹èãšã®çžæº¶æ§ä¹è³åæ£æ§ãåäžããã
ã«ã¯ãããªãšã¹ãã«éšåã®ååéæ¯çãé«ããã
ãšã«ãã€ãŠå¯èœã§ãããããå ·äœçã«ã¯ããããª
ãã¯ã¹æš¹èã®çš®é¡ã«å¿ããŠãããªãšã¹ãã«éšåã
æ§æããææ©ãžã«ã«ãã³é žç¡æ°Žç©åã³ïŒïŒïŒâãš
ããã·ãã®çš®é¡äžŠã³ã«ãããã®äœ¿çšæ¯çãé©å®ã«
å€ããããšãããããããã®ç®çãšããæ§è³ªãæ
ãããã®ãåŸãããããŸããããªãšã¹ãã«éšåã®
æ¯çãçžå¯Ÿçã«å€§ãããããšããããªãã¯ã¹æš¹è
ãšã®çžæº¶æ§ã¯æ¥µããŠè¯å¥œãšãªãåé¢ãæ圢ç©ã®è¡š
é¢ç¹æ§çã¯å¿ ãããæ¹åãããªããªãããããã€
ãŠããããªãã¯ã¹æš¹èãšã®çžæº¶æ§ä¹è³åæ£æ§ãšæ
圢ç©ã®è¡šé¢ç¹æ§çãšã®åæ¹ãæºè¶³ããã«ã¯ã液ç¶
ãŽã ç³»ååç©éšåãšããªãšã¹ãã«éšåãšã®æ¯çã
åé¡ã«ãªãããããã¯åéšåã®æ§é ãé©çšããã
ããªãã¯ã¹æš¹èã®çš®é¡ã«ãã€ãŠã圱é¿ãããã äžèšã®ãããªçç±ãããæ¬çºæã®PDâPESã
ããã¯å ±éåäœãèè¡ææ§åäžã硬ååçž®æ§äœæž
çãç®çãšããæ¹è³ªå€ãšããŠçšããå Žåã液ç¶ãŽ
ã ç³»ååç©éšåã®æ¯çã¯10ã95ééïŒ ãšããã®ã
奜ãŸãããç±ç¡¬åæ§åææš¹èã察象ãšããå Žåã«
ã¯40ã90ééïŒ ãšããã®ãç¹ã«å¥œãŸãããããªãš
ã¹ãã«éšåãïŒééïŒ æªæºã®ãã®ã¯ãããªãã¯ã¹
æš¹èãšã®åæ£æ§ãå£ãããã«ãªãã 以äžãæ¬çºæã®PDâPESãããã¯å ±éåäœã®
äž»ãªæ§èœã説æãããã該ãããã¯å ±éåäœã¯ã
ãããªãã¯ã¹æš¹èäžã«ãããšéçžæº¶æ§ã®ä»ã®ç±å¯
å¡æ§æš¹èãå®å®åæ£ãããããã®åæ£å€ãšããŠã
極ããŠæå¹ã§ããã æ¬çºæã«ä¿ãæ¹è³ªå€ã¯ãPDâPESãããã¯å ±
éåäœã«ãç±ç¡¬åæ§åææš¹èåæã§ãããšã©ã¹ã
ããŒããã¬ããªããŒãç±å¯å¡æ§æš¹èãããã«éå
æ§åéäœãææ©æº¶å€ãå¯å¡å€ãææ©åã¯ç¡æ©æ§å¢
éå€ãç¹ç¶ç¶åŒ·åå€çãé©å®ã«æ·»å å«æãããã
ã®ãšããããšãã§ãããç¹ã«ãPDâPESããã
ã¯å ±éåäœãç±ç¡¬åæ§äžé£œåããªãšã¹ãã«æš¹èãž
çšããå Žåãè©²å ±éåäœããã¹ãã¬ã³ãã¡ãã«ã¹
ãã¬ã³ãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãçã®ããã«éåæ§
åéäœãžé©å®ã®æ¿åºŠã§åžéããçµæç©ã䜿çšäžæ¥µ
ããŠå¥œéœåã§ããã 以äžãæ¬çºæãããæ確ã«ããããPDâPES
ãããã¯å ±éåäœã®è£œé åèäŸåã³å®æœäŸäžŠã³ã«
ãã®è©äŸ¡ãå ·äœçã«æããã ïŒå®æœäŸçïŒ ã»è£œé åèäŸ ïŒ ïŒåŸèšç¬¬ïŒè¡šäžã§ïŒ¢ã«çžåœãããã®ïŒ ç¡æ°Žãã¿ã«é ž52.3ïœïŒ0.35ã¢ã«ïŒãç¡æ°Žã³ãã¯
é ž82.5ïœïŒ0.825ã¢ã«ïŒã觊åªãšããŠå¡©åãªããŠã
0.7ïœåã³Î±ïŒÏâ1.2âããªãã¿ãžãšã³ã°ãªã³ãŒ
ã«ïŒNisso PBâG1000ãå¹³åååé1430ãæ¥æ¬
æ¹é瀟補ïŒ715ïŒ0.5ã¢ã«ïŒããªãŒãã¯ã¬ãŒãã«ä»
蟌ã¿ãåå¿ç³»ãçªçŽ ã¬ã¹çœ®æããåŸãæ¹æããªã
ã130âã«ãŸã§å ç±ããã次ãã§ããããã¬ã³ãª
ããµã€ã42.7ïœïŒ0.74ã¢ã«ïŒãïŒæéãããŠå§å ¥
ããã130âã§ïŒæéçæãè¡ãªããåå¿ãå®çµ
ãããæ·¡é»è²éæç²æ¶²ç¶ã®çæç©890ïœãåŸãã
ããã§åŸãããããªãã¿ãžãšã³âããªãšã¹ãã«ã
ããã¯å ±éåäœã®ååéã¯1786ïŒèšç®å€ã以äžå
åéã¯èšç®å€ïŒãããªãžãšã³ç³»ã»ã°ã¡ã³ãã®æ¯ç
ã¯80.0ééïŒ ïŒä»¥äžïŒ ã¯ééïŒ ïŒãé žäŸ¡27ãæ°Žé ž
åºäŸ¡38ã§ãã€ãã ããã§åŸããããããã¯å ±éåäœ800ïœã«ãã¹
ãã¬ã³ã¢ãããŒ200ïœåã³ãã€ããããã³0.1ïœã
å ããŠæº¶è§£ãããããã¯å ±éåäœ80ïŒ ãå«ãæ·¡é»
è²éæã®ã¹ãã¬ã³æº¶æ¶²ãåŸãã ã»è£œé åèäŸ ïŒ ïŒåŸèšç¬¬ïŒè¡šäžã§ïŒªã«çžåœãããã®ïŒ 補é åèäŸïŒã§åŸããããããã¯å ±éåäœ800
ïœïŒ0.448ã¢ã«ïŒåã³ç¡æ°Žã³ãã¯é ž54.2ïœïŒ0.54ã¢
ã«ïŒããã©ã¹ã³ã«ä»èŸŒã¿ã120ã125âã®æž©åºŠäžã
çªçŽ æ°æµäžã«ãŠãïŒæéåå¿ããããå 容ç©ã50
âã«å·åŽåŸãã¹ãã¬ã³ã¢ãããŒ200ïœãå ããŠæº¶
解ããããããã¯å ±éåäœãå«ãã¹ãã¬ã³æº¶æ¶²ã®
é žäŸ¡50.7ãæ°Žé žåºäŸ¡1.9ã§ãããããªãšã¹ãã«é
ã®æ«ç«¯ãã«ã«ããã·ã«å€æ§ãããããªãã¿ãžãšã³
âããªãšã¹ãã«ãããã¯å ±éåäœãåŸãããã ã»å®æœäŸ ïŒ ïŒPDâPESãããã¯å ±éåäœã®äŸïŒ 補é åèäŸïŒãšåæ§ã«ããŠã第ïŒè¡šèšèŒã®PD
âPESãããã¯å ±éåäœãåŸãã
ç³»âããªãšã¹ãã«ç³»ãããã¯å ±éåäœïŒä»¥äžã
PDâPESãããã¯å ±éåäœãšããïŒããæãç±
硬åæ§åã¯ç±å¯å¡æ§åææš¹èææçšæ¹è³ªå€ã«é¢ã
ãã å€ãã®ç±ç¡¬åæ§åææš¹èåã³ç±å¯å¡æ§åææš¹è
ãã济槜ãæµå槜å ã®äœå® æ©æãæ©æ¢°ãé»æ°è£œå
çã®å·¥æ¥éšæãèªåè»ãééè»èŒçã®èŒžéæ©åš
æãæŽã«ã¯è²¯èµçšã¿ã³ã¯ã容åšçã«åºãå©çšãã
ãŠãããããããã®åææš¹èã䜿çšããŠå å·¥ãã
å Žé¢ã§ã¯äžè¬ã«ããã®æ©æ¢°ç匷床çç©æ§ãæ¹åã
ãããã«ããã®ä»ã®åçš®ã®åææš¹èé¡ãå å¡«å€ã
ç¹ç¶è£åŒ·å€çãæ·»å ããããç¹ã«ãã®æ圢ç©ãæ§
é ææãšããŠäœ¿çšãããå Žåã«ã¯ãè¡æ匷床ãå
äžãããããšãå¿ é ã§ããããã®ãããåçš®ã®è£
匷å€ã«å ãããŽã ç³»ç©è³ªãä»ã®ããªããŒãç®çã«
å¿ããŠãã¬ã³ããããããšã¯ããç¥ãããŠããã
ãŸããç±ç¡¬åæ§åææš¹èã®äžã€ã§ããäžé£œåããª
ãšã¹ãã«æš¹èã¯ç¡¬ååå¿ã«ãšããªãïŒã10ïŒ ã®äœ
ç©åçž®ãçããæ圢ç©ã®å€èŠ³ã寞æ³ç²ŸåºŠãäœäžã
ãããã®ããããŽã ç³»ç©è³ªãä»ã®ç±å¯å¡æ§åææš¹
èããã¬ã³ããããããšãããç¥ãããŠãããã
ããŠäžèšã®ãããªè¡æ匷床ã®æ¹åãäœç©åçž®ã®äœ
äžãå³ãããã«äœ¿çšããããŽã ç³»ç©è³ªãšããŠãã
ãªãã¿ãžãšã³ããã¿ãžãšã³âã¹ãã¬ã³å ±éåäœã
ãã¿ãžãšã³âã¢ã¯ãªããããªã«å ±éåäœããã¿ãž
ãšã³âã¹ãã¬ã³âã¢ã¯ãªããããªã«äžå å ±éå
äœãåã³å€æ§ããªãã¿ãžãšã³çãããããšããŸã
ããç¥ãããŠããã èè¡ææ§ãæ¹è¯ãã匷åãã©ã¹ããã¯ã¹ã®äž»æ
åææš¹èã§ããæè¬ãããªãã¯ã¹æš¹èãšããŠãç±
硬åæ§äžé£œåããªãšã¹ãã«æš¹è䞊ã³ã«ãããªãšã
ã¬ã³ãã¬ãã¿ã¬ãŒããããªããã«ãã¬ãã¿ã¬ãŒ
ããããªã«ãŒãããŒããããªã¢ããçã®ç±å¯å¡æ§
åææš¹èããã®åéã«åºãå©çšãããŠããããã
ãã®åææš¹èã«ããŽã ç³»ç©è³ªãè£åŒ·æãé¡æãå
å¡«å€çãé åããåçš®ã®æ圢æ¹æ³ãçµãŠåŒ·åãã©
ã¹ããã¯ã¹ã補é ãããã®ã§ããã ãšãããããããªãã¯ã¹æš¹èãšãŽã ç³»ç©è³ªãš
ã¯ããã®ç©æ§ãäŸãã°æ¥µæ§ã溶解ãã©ã¡ãŒã¿ãŒç
ã倧ããç°ãªããããåæ¹ãåäžã«æ··åãæãã¯
å®å®ã«åæ£ãããããšã極ããŠå°é£ã§ãããäžå®
å®ãªæ··åç¶æ ã®ç±ç¡¬åæ§åææš¹èçµæç©ããåŸã
ããæ圢ç©ã®è¡šé¢ç¶æ ã¯äžè¯ã§ãå¹åžããŽã ç³»ç©
質ã®æµ®ãåºãçãèªããããç®çãšããæ©æ¢°ç匷
床ãåçž®äœæžçã極ããŠäžå åãªãã®ãšãªãããŸ
ãäžå®å®ãªåæ£ç¶æ ã®ç±å¯å¡æ§åææš¹èçµæç©ã
çšãããšãæ圢æã«äžæ¹ã®æåãåéããããã
æ圢æ§ã®äžè¯ãæ圢ç©ã®ç©æ§ã®ãã©ããã倧ãã
ãªãçã®äžå ·åãçããã ããã§ãç±ç¡¬åæ§æãã¯ç±å¯å¡æ§ã®ãããªãã¯
ã¹æš¹èã«å¯ŸããŠåäžæ··åæãã¯å®å®åæ£ããæ圢
äœæ¥æ§ããããåªããè¡šé¢ã®æ圢ç©ãåŸããã該
æ圢ç©ã®æ©æ¢°ç匷床ãåçž®äœæžçãæ Œæ®µã«æ¹è¯ã
ãããšãã§ããæ¹è³ªå€ã®åºçŸã匷ãèŠè«ãããã æ¬çºæã¯ãããèŠè«ã«å¿ããåææš¹èææçšæ¹
質å€ã«é¢ãããã®ã§ããã ïŒåŸæ¥ã®æè¡ããã®åé¡ç¹ïŒ åŸæ¥ãç±ç¡¬åæ§æãã¯ç±å¯å¡æ§åææš¹èãšã®çž
溶ä¹è³ã¯åæ£æ§æ¹åãç®çãšããåçš®ã®ææ¡ããª
ãããŠãããæ·»å ãããŽã ç³»ç©è³ªã®æ¹è³ªã«é¢ãã
ææ¡ã§ã¯ããŽã ç³»ç©è³ªã«ä»ã®åéäœãäŸãã°ã¹ã
ã¬ã³ããã¬ã€ã³é žãã¡ã¿ã¯ãªã«é žãšã¹ãã«ãã¢ã¯
ãªã«é žãšã¹ãã«çãã°ã©ããéåããããã®ãã
ãïŒç¹éæ54â18862ãç¹éæ54â40846çïŒãã
ããã®ãã®ã¯ãäžè¬ã«ã°ã©ããå¹çãæªããæªã
å åãªçžæº¶æ§ä¹è³ã¯åæ£æ§ã瀺ãã«è³ããªããšã
ãåé¡ç¹ãããããŸããç±ç¡¬åæ§åææš¹èã«å¯Ÿã
ãçžæº¶æ§ãæ¹åããææ¡ãšããŠãã¹ãã¬ã³ç³»ããª
ããŒã®ãããã¯å ±éåäœãããïŒç¹éæ53â
74592ãç¹éæ60â99158ïŒããã®ãã®ã¯ãçžæº¶æ§
ã¯ããçšåºŠæ¹åãããŠãããã®ã®ãæ¬è³ªçã«éæ§
ã®ä¹ããã¹ãã¬ã³ç³»ããªããŒãçšãããã®ã§ãã
ãããäœåçž®æ§äžŠã³ã«ãšãããèè¡ææ§ã®ç¹ã§è
ãããå£ããšããåé¡ç¹ããããäžé£œåããªãšã¹
ãã«æš¹èããŽã å€æ§ããææ¡ã§ã¯ãαïŒÎ²âäžé£œ
åãžã«ã«ãã³é žãå«ãäžé£œåããªãšã¹ãã«ã®äºé
åçµåã«å¯ŸããŠãå ±åœ¹ãžãšã³ç³»ååç©ãäŸãã°ãž
ã·ã¯ããã³ã¿ãžãšã³ããã€ãŒã«ã¹ã¢ã«ããŒä»å ã
ããã®ãããïŒç¹éæ58â2315ïŒããã®ãã®ã¯ã
å ±åœ¹ãžãšã³ç³»ååç©ã®ä»å éãå°ãªãããã«ãäž
飜åããªãšã¹ãã«æš¹èãšã®çžæº¶æ§ã¯æåŸ ã§ããå
é¢ãäœåçž®æ§åã³èè¡ææ§ã®ç¹ã§å¹æãåŸãããª
ããšããåé¡ç¹ãããã ïŒçºæã解決ããããšããåé¡ç¹ããã®è§£æ±ºæ段
ïŒ æ¬çºæã¯ãåäžã®åŠãåŸæ¥ã®åé¡ç¹ã解決ãã
åè¿°ããèŠè«ã«å¿ããåææš¹èææ溶é質å€ãæ
äŸãããã®ã§ããã ããããŠæ¬çºæè ãã¯ãäžèšèŠ³ç¹ã§éæç 究ã
ãçµæã液ç¶ãŽã ç³»ååç©éšåãšããªãšã¹ãã«éš
åãšãã»ã°ã¡ã³ããšããŠæããPDâPESããã
ã¯å ±éåäœãæ£ãã奜é©ã§ããããšãèŠåºããæ¬
çºæãå®æããã«å°ã€ãã ããªãã¡æ¬çºæã¯ããããæ§æããã»ã°ã¡ã³ã
ãšããŠãšãã«ãããã¯ç¶ã®æ¶²ç¶ãŽã ç³»ååç©éšå
ãšããªãšã¹ãã«éšåãšãå°ãªããšãåãã液ç¶ãŽ
ã ç³»ååç©éšåïŒåã«å¯ŸããŠãšã¹ãã«çµåãä»ã
ãŠããªãšã¹ãã«éšåãïŒååã¯ïŒå以äžé£çµãã
ãŠãã液ç¶ãŽã ç³»âããªãšã¹ãã«ç³»ãããã¯å ±é
åäœã§ãã€ãŠã該ããªãšã¹ãã«éšåã液ç¶ãŽã å
åç©ååäžã®ã«ã«ããã·ã«åºåã¯æ°Žé žåºãåºçºåº
質ãšããŠããã«ææ©ãžã«ã«ãã³é žç¡æ°Žç©ãšïŒïŒïŒ
âãšããã·ããšã觊åªååšäžã«äº€äºã«çž®å圢æã
ããããªãšã¹ãã«éã§ãã液ç¶ãŽã ç³»âããªãšã¹
ãã«ç³»ãããã¯å ±éåäœããæãããšãç¹åŸŽãšã
ãåææš¹èææçšæ¹è³ªå€ã«ä¿ãã æ¬çºæã®PDâPESãããã¯å ±éåäœã¯ãåå
å ã«ãæ°Žé žåºåã¯ã«ã«ããã·ã«åºçã®æŽ»æ§æ°ŽçŽ ã
æã€åå¿æ§åºãæãã液ç¶ãŽã ç³»ååç©ãåºçºç©
質ãšãã觊åªååšäžã«ãææ©ãžã«ã«ãã³é žç¡æ°Žç©
ãšïŒïŒïŒâãšããã·ããšãåå¿ããã液ç¶ãŽã ç³»
ååç©ã®åå¿æ§åºãä»ããŠããªãšã¹ãã«éãå°å ¥
ããããšã«ãããå·¥æ¥äžæå©ã«å®å®ããŠåŸãããš
ãã§ããããã®åå¿ã«ãããããªãšã¹ãã«éã®åœ¢
æéçšã¯ã掻æ§æ°ŽçŽ ãæããåå¿æ§åºãšããŠã®äŸ
ãã°æ°Žé žåºãšææ©ãžã«ã«ãã³é žç¡æ°Žç©ãšã®åå¿ã«
ãã€ãŠåœ¢æãããã«ã«ããã·ã«åºã«ïŒïŒïŒâãšã
ãã·ããéç°ä»å ããŠæ°Žé žåºã圢æãããããã«
ãŸãææ©ãžã«ã«ãã³é žç¡æ°Žç©ãä»å ãããšããã
æ°Žé žåºãšææ©ãžã«ã«ãã³é žç¡æ°Žç©ãšã®ãšã¹ãã«å
åå¿ãšãã«ã«ããã·ã«åºãšïŒïŒïŒâãšããã·ããš
ã®éç°ä»å åå¿ãšããé 次亀äºã«èµ·ãããããªãš
ã¹ãã«éã圢æããŠãããã®ã§ããã äžèšåå¿ã«ãããŠæ¶²ç¶ãŽã ç³»ååç©ã¯ãåèšã
ããããªãæ°Žé žåºåã¯ã«ã«ããã·ã«åºã®æŽ»æ§æ°ŽçŽ
åºãæããããžãšã³ç³»ãã¢ããªããŒåã¯ãããã«
éšåçã«ãããŠå¥œãŸããã¯ã§ããã ãå°éã§ãã
ã«ç³»ååç©ãå«ãŸããããªããŒã§ããããã®ãã
ãªæŽ»æ§æ°Žé žåºã¯ãããªãžãšã³éã®éäžåã¯æ«ç«¯ã«
ïŒååã¯ïŒå以äžååšãããã®ã§ããã°ããã掻
æ§æ°Žé žåºã®ããªãžãšã³éãžã®å°å ¥äœçœ®ã«ã€ããŠç¹
ã«å¶éãããã®ã§ã¯ãªãããŸãã液ç¶ãŽã ç³»åå
ç©ã®éåæ¹åŒãäŸãã°ã©ãžã«ã«éåãã¢ããªã³é
åãã¢ããªã³ãã³ã°éåçã®éãã«ãããã®éå
äœã®ç«äœç°æ§äœãæ§é ç°æ§äœã«ã€ããŠãç¹ã«å¶é
ãããã®ã§ã¯ãªãã äžèšã®ãããªæ¶²ç¶ãŽã ç³»ååç©ãæ§æããåé
äœãžãšã³ååç©ã¯ããã¿ãžãšã³ãã€ãœãã¬ã³ãã¯
ãããã¬ã³ãïŒïŒïŒâãã³ã¿ãžãšã³ãã·ã¯ããã³
ã¿ãžãšã³çã§ããã åèšåå¿ã§ãæå©ã«äœ¿çšã§ãã液ç¶ãŽã ç³»åå
ç©ãäŸç€ºãããšãαïŒÏâïŒïŒïŒâããªãã¿ãžãš
ã³ã°ãªã³ãŒã«ïŒNisso PBâã·ãªãŒãºïŒãαïŒ
ÏâïŒïŒïŒâããªãã¿ãžãšã³ã«ã«ãã³é žïŒNisso
PBâã·ãªãŒãºïŒãαïŒÏâïŒïŒïŒâããªãã¿ãž
ãšã³æ«ç«¯ãã¬ã€ã³é žåãšã¹ãã«ïŒNisso PBâ
GMã·ãªãŒãºã以äžïŒç¹ã¯æ¥æ¬æ¹ç€Ÿè£œïŒãæ«ç«¯ã«
ã«ããã·ã«å€æ§ïŒïŒïŒâããªãã¿ãžãšã³ïŒHycar
CTBã·ãªãŒãºãå®éšèç£ç€Ÿè£œåã¯B.F.ã°ãããª
ãã瀟補ïŒãæ«ç«¯æ°Žé žåºå€æ§ïŒïŒïŒâããªãã¿ãž
ãšã³ïŒPolyâbd â45Måã¯ïŒ²â45HTãåºå
ç³æ²¹ååŠç€Ÿè£œåã¯ã¢ãŒã³ã±ãã«ã«ç€Ÿè£œïŒçãæã
ãããã 掻æ§æ°Žé žåºãæãã液ç¶ãŽã ç³»ååç©ãšããŠ
ã¯ãäžèšãããããªæ¶²ç¶ãŽã ç³»ååç©ã®äž»éåã¯
åŽéã®ççŽ âççŽ äºéçµåãéšåçã«åã¯å®å šã«
æ°ŽçŽ æ·»å ãããã®ãå©çšã§ãããããã«ã¯äŸã
ã°ãæ°ŽçŽ æ·»å αïŒÏâïŒïŒïŒâããªãã¿ãžãšã³ã°
ãªã³ãŒã«ïŒNisso PBâGIã·ãªãŒãºãæ¥æ¬æ¹é瀟
補ïŒãæ°ŽçŽ æ·»å αïŒÏâïŒïŒïŒâããªãã¿ãžãšã³
ãžã«ã«ãã³é žïŒNisso PBâCIã·ãªãŒãºãæ¥æ¬æ¹
é瀟補ïŒçãããã ãŸãåèšåå¿ã«ãããŠææ©ãžã«ã«ãã³é žç¡æ°Žç©
ãšããŠã¯ãã³ãã¯é žç¡æ°Žç©ããã¬ã€ã³é žç¡æ°Žç©ã
ã¢ã«ã±ãã«ã³ãã¯é žç¡æ°Žç©çã®èèªæãžã«ã«ãã³
é žç¡æ°Žç©ããã¿ã«é žç¡æ°Žç©ãããã¿ã¬ã³ãžã«ã«ã
ã³é žç¡æ°Žç©çã®è³éŠæãžã«ã«ãã³é žç¡æ°Žç©ãã·ã¯
ããããµã³ãžã«ã«ãã³é žç¡æ°Žç©ãã·ã¯ãããã»ã³
ãžã«ã«ãã³é žç¡æ°Žç©ããšã³ãã¡ãã¬ã³ã·ã¯ããã
ã»ã³ãžã«ã«ãã³é žç¡æ°Žç©çã®èç°æãžã«ã«ãã³é ž
ç¡æ°Žé žç©çãæããããã æŽã«åèšåå¿ã«ãããŠïŒïŒïŒâãšããã·ããšã
ãŠã¯ããšãã¬ã³ãªããµã€ãããããã¬ã³ãªããµã€
ããïŒïŒïŒâããã¬ã³ãªããµã€ããççŽ æ°ïŒã12
ã®ã¢ã«ãã«åã¯ã¢ã«ãã±ã«ã°ãªã·ãžã«ãšãŒãã«ç
ã®èèªæãšããã·ãé¡ãããšãã¬ã³ãªããµã€ãã
ã·ã¯ãããã»ã³ãªããµã€ãçã®è³éŠæãšããã·ã
åã¯èç°æãšããã·ãé¡ãã¹ãã¬ã³ãªããµã€ãã
ããšãã«ã°ãªã·ãžã«ãšãŒãã«çã®è³éŠæåºãæã
ããšããã·ãé¡ãã°ãªã·ãžã«ã¡ã¿ã¯ãªã¬ãŒããã°
ãªã·ãžã«ã¢ã¯ãªã¬ãŒãçã®Î±ïŒÎ²âäžé£œåçåæ°Ž
çŽ åºãæãããšããã·ãé¡çãæããããã ãããŠåèšåå¿ã«ãããŠè§ŠåªãšããŠã¯ãå¡©åãª
ããŠã ãèåãªããŠã çã®ããã²ã³åãªããŠã ã
ããã©ã¡ãã«ã¢ã³ã¢ããŠã ãããã€ããããªãã
ã«ã¡ãã«ã¢ã³ã¢ããŠã ãããã€ããããã©ããã
ã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãçã®ããã©ã¢ã«ãã«ç¬¬
åçŽã¢ã³ã¢ããŠã å¡©ãæããããã ãããŸã§ããªãã以äžäŸç€ºãããããã«ã€ããŠ
ããæ¬çºæããããã«éå®ããããšãããã®ã§ã¯
ãªãã 次ã«ãæ¬çºæã®PDâPESãããã¯å ±éåäœã®
æå©ãªè£œé æ¹æ³ã®äžäŸãããå ·äœçã«æãããäž
掻æ§æº¶åªã®ååšäžåã¯éååšäžã«ãæ°Žé žåºåã¯ã«
ã«ããã·ã«åºãæãã液ç¶ãŽã ç³»ååç©ïŒã¢ã«ã«
察ãæå®ã¢ã«éã®ææ©ãžã«ã«ãã³é žç¡æ°Žç©åã³è§Š
åªãåå¿å®¹åšã«ä»èŸŒã¿ãåžžå§åã¯å å§äžã«æå®ã¢
ã«éã®ïŒïŒïŒâãšããã·ããå°å ¥ãã50ã200âã
奜ãŸããã¯120ã150âã®å ç±äžã«åå¿ãããŠã
PDâPESãããã¯å ±éåäœãåŸãã ããããŠåŸãããæ¬çºæã®ãããã¯å ±éåäœäž
ã®ããªãšã¹ãã«éã®æ«ç«¯åºã¯ãéåžžãæ°Žé žåºåã¯
ã«ã«ããã·ã«åºæãã¯ãããã®æ··åãšãªãããæ«
端åºãšããŠã®æ°Žé žåºãšã«ã«ããã·ã«åºãšã®æ¯çã¯
åå¿ã«é¢äžããææ©ãžã«ã«ãã³é žç¡æ°Žç©ãšïŒïŒïŒ
âãšããã·ããšã®ã¢ã«æ¯ã«ãã€ãŠå·Šå³ããããã
ãæ ãæ«ç«¯åºãšããŠã®æ°Žé žåºãšã«ã«ããã·ã«åºãš
ã®æ¯çã¯äžèšäž¡è ã®åå¿ã¢ã«æ¯ãéžæããããšã«
ãã€ãŠå€åãããããšãã§ããã äžèšã®ãããªæ«ç«¯åºãšããŠã®æ°Žé žåºåã³ïŒåã¯
ã«ã«ããã·ã«åºã¯ã該æ«ç«¯åºãšåå¿æ§ã®ããç©è³ª
ãšãåå¿ããããšãŒãã«çµåããšã¹ãã«çµåçã®
é£çµåºãä»ããŠåçš®ã®åå¿æ§åºãäŸãã°ããã«
åºããšããã·åºãã€ãœã·ã¢ããŒãåºçãä»å ãã
æ«ç«¯å€æ§ãè¡ãªãããšãã§ãããŸãæ«ç«¯ã®æ°Žé žåº
ã«å¯Ÿãããžã«ã«ãã³é žãäºäŸ¡ä»¥äžã®å€å¡©åºé žåã¯
ãããã®é žç¡æ°Žç©ãåå¿ãããŠæ«ç«¯ã«ã«ããã·ã«
å€æ§ãããããšãã§ãããæŽã«ãæ«ç«¯åºãšããŠã®
æ°Žé žåºåã¯ã«ã«ããã·ã«åºãããšãŒãã«çµåããš
ã¹ãã«çµååã¯ã¢ããçµåçãä»ããŠå°éããé
åå¿æ§ã®æ«ç«¯å€æ§ãè¡ãªãããšãã§ããæ«ç«¯ã®ã«
ã«ããã·ã«åºã®åå¿æ§ãäžæŽ»æ§åããç®çã§ã該
ã«ã«ããã·ã«åºãã¢ã«ã«ãªéå±å¡©ãã¢ã«ã«ãªåé¡
éå±å¡©çã®å¡©ã«å€åœ¢ããããšãã§ããã æ¬çºæã®PDâPESãããã¯å ±éåäœã®æ«ç«¯åº
ã«ã€ããŠãSMCïŒæ¿ç¶æ圢ææïŒãBMCïŒå¡ç¶æ
圢ææïŒã®è£œé ã§ã¯å¢ç²å€ãšããŠé žåãã°ãã·ãŠ
ã åã¯ã€ãœã·ã¢ããŒãé¡ã䜿çšãããããé žåã
ã°ãã·ãŠã ã䜿çšããå Žåã¯æ«ç«¯åºãšããŠã«ã«ã
ãã·ã«åºã®æ¯çãããŸãã€ãœã·ã¢ããŒãé¡ã䜿çš
ããå Žåã¯æ«ç«¯åºãšããŠæ°Žé žåºã®æ¯çããããã
é«ãããã®ããæ圢ææã§ããäžé£œåããªãšã¹ã
ã«æš¹èçµæç©ã®å®å®æ§ãåŸãããæ圢ç©ã®ç©æ§æ¹
åã«æ¥µããŠæå¹ã§ããããããŠãåè¿°ã®åŠãåå¿
æ§ã®æ«ç«¯å€æ§ãè¡ãªã€ããã®ã¯ããã®ãã®ãšãã
ãªãã¯ã¹æš¹èåã¯åçš®ã®å å¡«å€ãæ¶æ©å€ãšã®éã«
ååŠççµåã圢æããããããæ圢ç©ã®ç©æ§æ¹è¯
ã«ã¯æ¥µããŠæå¹ãªå Žåãå€ãããŸãåè¿°ã®åŠãé
åå¿æ§ã®æ«ç«¯å€æ§ãè¡ãªã€ããã®ã¯ããããªãã¯
ã¹æš¹èãšã®çžæº¶æ§æãã¯ååŠçå®å®æ§ãåäžãã
å Žåãå€ãã æ¬çºæã®PDâPESãããã¯å ±éåäœã¯ãç±ç¡¬
åæ§æš¹èåã³åçš®ã®ç±å¯å¡æ§æš¹èããããªãã¯ã¹
æš¹èãšããæ圢ç©ã®èè¡ææ§åäžåã³ïŒåã¯ç¡¬å
åçž®äœäžãç®çãšããæ¹è³ªå€ãšããŠç¹ã«åªããæ§
質ãæããããã®çç±ã¯ãPDâPESãããã¯å ±
éåäœããåŸæ¥ããåæ§ã®ç®çã§äœ¿çšããããŽã
ç³»ç©è³ªãç±å¯å¡æ§æš¹èã«æ¯èŒããŠããããªãã¯ã¹
æš¹èã«å¯Ÿããåäžäžã€å®å®ãªçžæº¶æ§ä¹è³åæ£æ§ã
çºæ®ããããã§ãããPDâPESãããã¯å ±éå
äœã¯ã液ç¶ãŽã ç³»ååç©éšåãšããªãšã¹ãã«éšå
ãšã®ãåæ¹ã®ååéãæ§é ãçµæ䞊ã³ã«ååéæ¯
ççã«ãã€ãŠææã®æ§è³ªã®ãã®ãåŸãããããã
ãªãã¯ã¹æš¹èãšã®çžæº¶æ§ä¹è³åæ£æ§ãåäžããã
ã«ã¯ãããªãšã¹ãã«éšåã®ååéæ¯çãé«ããã
ãšã«ãã€ãŠå¯èœã§ãããããå ·äœçã«ã¯ããããª
ãã¯ã¹æš¹èã®çš®é¡ã«å¿ããŠãããªãšã¹ãã«éšåã
æ§æããææ©ãžã«ã«ãã³é žç¡æ°Žç©åã³ïŒïŒïŒâãš
ããã·ãã®çš®é¡äžŠã³ã«ãããã®äœ¿çšæ¯çãé©å®ã«
å€ããããšãããããããã®ç®çãšããæ§è³ªãæ
ãããã®ãåŸãããããŸããããªãšã¹ãã«éšåã®
æ¯çãçžå¯Ÿçã«å€§ãããããšããããªãã¯ã¹æš¹è
ãšã®çžæº¶æ§ã¯æ¥µããŠè¯å¥œãšãªãåé¢ãæ圢ç©ã®è¡š
é¢ç¹æ§çã¯å¿ ãããæ¹åãããªããªãããããã€
ãŠããããªãã¯ã¹æš¹èãšã®çžæº¶æ§ä¹è³åæ£æ§ãšæ
圢ç©ã®è¡šé¢ç¹æ§çãšã®åæ¹ãæºè¶³ããã«ã¯ã液ç¶
ãŽã ç³»ååç©éšåãšããªãšã¹ãã«éšåãšã®æ¯çã
åé¡ã«ãªãããããã¯åéšåã®æ§é ãé©çšããã
ããªãã¯ã¹æš¹èã®çš®é¡ã«ãã€ãŠã圱é¿ãããã äžèšã®ãããªçç±ãããæ¬çºæã®PDâPESã
ããã¯å ±éåäœãèè¡ææ§åäžã硬ååçž®æ§äœæž
çãç®çãšããæ¹è³ªå€ãšããŠçšããå Žåã液ç¶ãŽ
ã ç³»ååç©éšåã®æ¯çã¯10ã95ééïŒ ãšããã®ã
奜ãŸãããç±ç¡¬åæ§åææš¹èã察象ãšããå Žåã«
ã¯40ã90ééïŒ ãšããã®ãç¹ã«å¥œãŸãããããªãš
ã¹ãã«éšåãïŒééïŒ æªæºã®ãã®ã¯ãããªãã¯ã¹
æš¹èãšã®åæ£æ§ãå£ãããã«ãªãã 以äžãæ¬çºæã®PDâPESãããã¯å ±éåäœã®
äž»ãªæ§èœã説æãããã該ãããã¯å ±éåäœã¯ã
ãããªãã¯ã¹æš¹èäžã«ãããšéçžæº¶æ§ã®ä»ã®ç±å¯
å¡æ§æš¹èãå®å®åæ£ãããããã®åæ£å€ãšããŠã
極ããŠæå¹ã§ããã æ¬çºæã«ä¿ãæ¹è³ªå€ã¯ãPDâPESãããã¯å ±
éåäœã«ãç±ç¡¬åæ§åææš¹èåæã§ãããšã©ã¹ã
ããŒããã¬ããªããŒãç±å¯å¡æ§æš¹èãããã«éå
æ§åéäœãææ©æº¶å€ãå¯å¡å€ãææ©åã¯ç¡æ©æ§å¢
éå€ãç¹ç¶ç¶åŒ·åå€çãé©å®ã«æ·»å å«æãããã
ã®ãšããããšãã§ãããç¹ã«ãPDâPESããã
ã¯å ±éåäœãç±ç¡¬åæ§äžé£œåããªãšã¹ãã«æš¹èãž
çšããå Žåãè©²å ±éåäœããã¹ãã¬ã³ãã¡ãã«ã¹
ãã¬ã³ãã¡ãã«ã¡ã¿ã¯ãªã¬ãŒãçã®ããã«éåæ§
åéäœãžé©å®ã®æ¿åºŠã§åžéããçµæç©ã䜿çšäžæ¥µ
ããŠå¥œéœåã§ããã 以äžãæ¬çºæãããæ確ã«ããããPDâPES
ãããã¯å ±éåäœã®è£œé åèäŸåã³å®æœäŸäžŠã³ã«
ãã®è©äŸ¡ãå ·äœçã«æããã ïŒå®æœäŸçïŒ ã»è£œé åèäŸ ïŒ ïŒåŸèšç¬¬ïŒè¡šäžã§ïŒ¢ã«çžåœãããã®ïŒ ç¡æ°Žãã¿ã«é ž52.3ïœïŒ0.35ã¢ã«ïŒãç¡æ°Žã³ãã¯
é ž82.5ïœïŒ0.825ã¢ã«ïŒã觊åªãšããŠå¡©åãªããŠã
0.7ïœåã³Î±ïŒÏâ1.2âããªãã¿ãžãšã³ã°ãªã³ãŒ
ã«ïŒNisso PBâG1000ãå¹³åååé1430ãæ¥æ¬
æ¹é瀟補ïŒ715ïŒ0.5ã¢ã«ïŒããªãŒãã¯ã¬ãŒãã«ä»
蟌ã¿ãåå¿ç³»ãçªçŽ ã¬ã¹çœ®æããåŸãæ¹æããªã
ã130âã«ãŸã§å ç±ããã次ãã§ããããã¬ã³ãª
ããµã€ã42.7ïœïŒ0.74ã¢ã«ïŒãïŒæéãããŠå§å ¥
ããã130âã§ïŒæéçæãè¡ãªããåå¿ãå®çµ
ãããæ·¡é»è²éæç²æ¶²ç¶ã®çæç©890ïœãåŸãã
ããã§åŸãããããªãã¿ãžãšã³âããªãšã¹ãã«ã
ããã¯å ±éåäœã®ååéã¯1786ïŒèšç®å€ã以äžå
åéã¯èšç®å€ïŒãããªãžãšã³ç³»ã»ã°ã¡ã³ãã®æ¯ç
ã¯80.0ééïŒ ïŒä»¥äžïŒ ã¯ééïŒ ïŒãé žäŸ¡27ãæ°Žé ž
åºäŸ¡38ã§ãã€ãã ããã§åŸããããããã¯å ±éåäœ800ïœã«ãã¹
ãã¬ã³ã¢ãããŒ200ïœåã³ãã€ããããã³0.1ïœã
å ããŠæº¶è§£ãããããã¯å ±éåäœ80ïŒ ãå«ãæ·¡é»
è²éæã®ã¹ãã¬ã³æº¶æ¶²ãåŸãã ã»è£œé åèäŸ ïŒ ïŒåŸèšç¬¬ïŒè¡šäžã§ïŒªã«çžåœãããã®ïŒ 補é åèäŸïŒã§åŸããããããã¯å ±éåäœ800
ïœïŒ0.448ã¢ã«ïŒåã³ç¡æ°Žã³ãã¯é ž54.2ïœïŒ0.54ã¢
ã«ïŒããã©ã¹ã³ã«ä»èŸŒã¿ã120ã125âã®æž©åºŠäžã
çªçŽ æ°æµäžã«ãŠãïŒæéåå¿ããããå 容ç©ã50
âã«å·åŽåŸãã¹ãã¬ã³ã¢ãããŒ200ïœãå ããŠæº¶
解ããããããã¯å ±éåäœãå«ãã¹ãã¬ã³æº¶æ¶²ã®
é žäŸ¡50.7ãæ°Žé žåºäŸ¡1.9ã§ãããããªãšã¹ãã«é
ã®æ«ç«¯ãã«ã«ããã·ã«å€æ§ãããããªãã¿ãžãšã³
âããªãšã¹ãã«ãããã¯å ±éåäœãåŸãããã ã»å®æœäŸ ïŒ ïŒPDâPESãããã¯å ±éåäœã®äŸïŒ 補é åèäŸïŒãšåæ§ã«ããŠã第ïŒè¡šèšèŒã®PD
âPESãããã¯å ±éåäœãåŸãã
ãè¡šã
ã»å®æœäŸ ïŒ
ïŒæ«ç«¯å€æ§ãè¡ãªã€ãPDâPESãããã¯å
±é
åäœã®äŸïŒ 第ïŒè¡šèšèŒã®ïŒ¢ã察象ã«ããŠã第ïŒè¡šèšèŒã®æ«
端å€æ§ãè¡ãªã€ãPDâPESãããã¯å ±éåäœã
åŸãïŒäœãã第ïŒè¡šäžã®ïŒ«ã¯ç¬¬ïŒè¡šèšèŒã®ïŒŠã察
象ã«ããïŒã
åäœã®äŸïŒ 第ïŒè¡šèšèŒã®ïŒ¢ã察象ã«ããŠã第ïŒè¡šèšèŒã®æ«
端å€æ§ãè¡ãªã€ãPDâPESãããã¯å ±éåäœã
åŸãïŒäœãã第ïŒè¡šäžã®ïŒ«ã¯ç¬¬ïŒè¡šèšèŒã®ïŒŠã察
象ã«ããïŒã
ãè¡šã
ãè¡šã
ãè¡šã
ã»è©äŸ¡ïŒ
åºåœ¢å60ïŒ
ãå«æããäžé£œåããªãšã¹ãã«æš¹è
ã®ã¹ãã¬ã³æº¶æ¶²ïŒããªã»ãã9107ãæ¥ç«åæ瀟
補ããã¿ã«é žãšã¹ãã«ç³»ïŒ60éééšãã¹ãã¬ã³ã¢
ãããŒ27éééšã第ïŒè¡šèšèŒã®æ¹è³ªå€13éééšã
ããŒã«ãŒã«ãšãããããã©æ¹ææ©ã«ãŠïŒåéåäž
ã«æ··åæ¹æãã100mlã¡ã¹ã·ãªã³ããŒã«ç§»ããŠå®€
æž©é眮ããç¶æ ã§ãçµæçã«çžåé¢éïŒäœç©ïŒ ïŒ
ã枬å®ããçµæã第ïŒè¡šã«ç€ºããã
ã®ã¹ãã¬ã³æº¶æ¶²ïŒããªã»ãã9107ãæ¥ç«åæ瀟
補ããã¿ã«é žãšã¹ãã«ç³»ïŒ60éééšãã¹ãã¬ã³ã¢
ãããŒ27éééšã第ïŒè¡šèšèŒã®æ¹è³ªå€13éééšã
ããŒã«ãŒã«ãšãããããã©æ¹ææ©ã«ãŠïŒåéåäž
ã«æ··åæ¹æãã100mlã¡ã¹ã·ãªã³ããŒã«ç§»ããŠå®€
æž©é眮ããç¶æ ã§ãçµæçã«çžåé¢éïŒäœç©ïŒ ïŒ
ã枬å®ããçµæã第ïŒè¡šã«ç€ºããã
ãè¡šã
ãè¡šã
ã»è©äŸ¡ïŒ
第ïŒè¡šã«èšèŒããã®33ïŒ
ã¹ãã¬ã³æº¶æ¶²40éé
éšãäžé£œåããªãšã¹ãã«æš¹èïŒãŠãã«7507ãæ¥æ¬
ãŠãã«ç€Ÿè£œïŒ60éééšãã¿ãŒã·ã€ãªãŒããã«ããŒ
ãã³ãŸãšãŒã1.5éééšãã¹ãã¢ãªã³é žäºé3.0é
ééšããã³ããªãŒãããµãŒäžã«ä»èŸŒã¿ãããã«
200éééšã®çé žã«ã«ã·ãŠã ç²æ«ãå ããããå
äžã«ããåŸãç¹ç¶é·1/2ã€ã³ãã®ã¬ã©ã¹ç¹ç¶ã60
éééšæ·»å ããŠïŒååŸã«ãã³ããªãŒãããµãŒãå
æ¢ããåŸããããã¬ããã¯ã¹ã145âã§æ圢ããã
æ圢æ¿ã¯åäžãªè¡šé¢å æ²¢ãåããæ圢åçž®çã¯
0.005ïŒ ã§ãã€ãã ã«ä»£ããŠç¬¬ïŒè¡šã«èšèŒããPBGãçšããã
ã¬ããã¯ã¹ã¯å ¬ç¥ã®ãã®ã§ãããããã®æ圢æ¿ã®
è¡šé¢ã¯å æ²¢ã ã©ãèããã€ãã ã»è©äŸ¡ïŒ 第ïŒè¡šã«èšèŒããæ¹è³ªå€ã®33ïŒ ã¹ãã¬ã³æº¶æ¶²40
éééšãäžé£œåããªãšã¹ãã«æš¹èïŒããªã»ãã
9120ãæ¥ç«åæ瀟補ïŒ60éééšãã¹ãã¢ãªã³é žäº
éïŒéééšãã¿ãŒã·ã€ãªãŒããã«ããŒãã³ãŸãšãŒ
ã1.5éééšãçé žã«ã«ã·ãŠã ç²æ«140éééšãã
ã©ãã³ãŸããã³0.3éééšãæ··åããã次ãã§é ž
åãã°ãã·ãŠã ïŒéééšãå ããçŽã¡ã«ç¹ç¶é·ïŒ
ã€ã³ãã®ã¬ã©ã¹ç¹ç¶10ïŒ ãå«ãçµæç©ãäœã€ãã
ãããéåã«æµã蟌ã¿ãéå枩床140âã«ãŠå ç±
æ圢ããSMCãåŸããåŸãããSMCã«ã€ããŠã
ãã®è¡šé¢å æ²¢ãèçŒèŠ³å¯ãããã®æ圢åçž®çãæ±
ãããçµæã第ïŒè¡šã«ç€ºããã
éšãäžé£œåããªãšã¹ãã«æš¹èïŒãŠãã«7507ãæ¥æ¬
ãŠãã«ç€Ÿè£œïŒ60éééšãã¿ãŒã·ã€ãªãŒããã«ããŒ
ãã³ãŸãšãŒã1.5éééšãã¹ãã¢ãªã³é žäºé3.0é
ééšããã³ããªãŒãããµãŒäžã«ä»èŸŒã¿ãããã«
200éééšã®çé žã«ã«ã·ãŠã ç²æ«ãå ããããå
äžã«ããåŸãç¹ç¶é·1/2ã€ã³ãã®ã¬ã©ã¹ç¹ç¶ã60
éééšæ·»å ããŠïŒååŸã«ãã³ããªãŒãããµãŒãå
æ¢ããåŸããããã¬ããã¯ã¹ã145âã§æ圢ããã
æ圢æ¿ã¯åäžãªè¡šé¢å æ²¢ãåããæ圢åçž®çã¯
0.005ïŒ ã§ãã€ãã ã«ä»£ããŠç¬¬ïŒè¡šã«èšèŒããPBGãçšããã
ã¬ããã¯ã¹ã¯å ¬ç¥ã®ãã®ã§ãããããã®æ圢æ¿ã®
è¡šé¢ã¯å æ²¢ã ã©ãèããã€ãã ã»è©äŸ¡ïŒ 第ïŒè¡šã«èšèŒããæ¹è³ªå€ã®33ïŒ ã¹ãã¬ã³æº¶æ¶²40
éééšãäžé£œåããªãšã¹ãã«æš¹èïŒããªã»ãã
9120ãæ¥ç«åæ瀟補ïŒ60éééšãã¹ãã¢ãªã³é žäº
éïŒéééšãã¿ãŒã·ã€ãªãŒããã«ããŒãã³ãŸãšãŒ
ã1.5éééšãçé žã«ã«ã·ãŠã ç²æ«140éééšãã
ã©ãã³ãŸããã³0.3éééšãæ··åããã次ãã§é ž
åãã°ãã·ãŠã ïŒéééšãå ããçŽã¡ã«ç¹ç¶é·ïŒ
ã€ã³ãã®ã¬ã©ã¹ç¹ç¶10ïŒ ãå«ãçµæç©ãäœã€ãã
ãããéåã«æµã蟌ã¿ãéå枩床140âã«ãŠå ç±
æ圢ããSMCãåŸããåŸãããSMCã«ã€ããŠã
ãã®è¡šé¢å æ²¢ãèçŒèŠ³å¯ãããã®æ圢åçž®çãæ±
ãããçµæã第ïŒè¡šã«ç€ºããã
ãè¡šã
ãè¡šã
ã»è©äŸ¡ïŒ
ããªããã¬ã³ãã¬ãã¿ã¬ãŒãæš¹èïŒ0.5ïŒ
ãªã«
ã³ã¯ãã«ããšããŒã«æº¶æ¶²ã®25âã«ãããçžå¯Ÿç²åºŠ
1.70ïŒãšç¬¬ïŒè¡šã«èšèŒããæ¹è³ªå€ãšã90ïŒ10éé
æ¯ã§æ··åãã40mmå£åŸã®ãã³ãä»æŒåºæ©ã§æº¶èæ··
ç·ŽããŠãã¬ããåãããåŸããããã¬ãããç空
也ç¥ããåŸãå°åºæ圢ããŠæ圢åãåŸãããã®æ
圢åã«ã€ããŠã¢ã€ãŸããè¡æ匷床ïŒãããä»ãïŒ
ã枬å®ãïŒASTMâD256â56ïŒã䜵ããŠãããª
ãã¯ã¹æš¹èäžã«ãããæ¹è³ªå€ã®åæ£ç¶æ ãé»åé¡
埮é¡ã§èŠ³å¯ãããçµæã第ïŒè¡šã«ç€ºããã å°ã第ïŒè¡šäžã®PBAãçšããå Žåã¯ããã¬ã
ãåå·¥çšã«ãããŠãæŒåºæ©ã®ã¹ã¯ãªãŠãŒã®æ··ç·Žäž
è¯ã«åå ãã空å転çŸè±¡ãšãã³ãå£ããå°éã®å
éããPBAã®æµžåºãèªããããã
ã³ã¯ãã«ããšããŒã«æº¶æ¶²ã®25âã«ãããçžå¯Ÿç²åºŠ
1.70ïŒãšç¬¬ïŒè¡šã«èšèŒããæ¹è³ªå€ãšã90ïŒ10éé
æ¯ã§æ··åãã40mmå£åŸã®ãã³ãä»æŒåºæ©ã§æº¶èæ··
ç·ŽããŠãã¬ããåãããåŸããããã¬ãããç空
也ç¥ããåŸãå°åºæ圢ããŠæ圢åãåŸãããã®æ
圢åã«ã€ããŠã¢ã€ãŸããè¡æ匷床ïŒãããä»ãïŒ
ã枬å®ãïŒASTMâD256â56ïŒã䜵ããŠãããª
ãã¯ã¹æš¹èäžã«ãããæ¹è³ªå€ã®åæ£ç¶æ ãé»åé¡
埮é¡ã§èŠ³å¯ãããçµæã第ïŒè¡šã«ç€ºããã å°ã第ïŒè¡šäžã®PBAãçšããå Žåã¯ããã¬ã
ãåå·¥çšã«ãããŠãæŒåºæ©ã®ã¹ã¯ãªãŠãŒã®æ··ç·Žäž
è¯ã«åå ãã空å転çŸè±¡ãšãã³ãå£ããå°éã®å
éããPBAã®æµžåºãèªããããã
ãè¡šã
ãè¡šã
ã»è©äŸ¡ïŒ
第ïŒè¡šèšèŒã®ïŒ¢ãšå¯Ÿæ¯ãã€ã€ã第ïŒè¡šèšèŒã®
PDâPESãããã¯å ±éåäœã«ã€ããè©äŸ¡ïŒãšå
æ§ã«ããŠæž¬å®åã³èŠ³å¯ããããçµæã第ïŒè¡šã«ç€º
ãããå°ãæ¹è³ªå€ã®æ·»å éã¯12.5ïŒ ã§ããã
PDâPESãããã¯å ±éåäœã«ã€ããè©äŸ¡ïŒãšå
æ§ã«ããŠæž¬å®åã³èŠ³å¯ããããçµæã第ïŒè¡šã«ç€º
ãããå°ãæ¹è³ªå€ã®æ·»å éã¯12.5ïŒ ã§ããã
ãè¡šã
ïŒçºæã®å¹æïŒ
åå®æœäŸåã³åè©äŸ¡ãããæãããªããã«ã以
äžèª¬æããæ¬çºæã«ã¯ã液ç¶ãŽã ç³»ååç©åã³ã
ãªãšã¹ãã«ç³»ããªããŒã®åæ¹ã®ç¹æ§ã䜵ãæãæ
ãã¯ãŸãåæ¹ã«èŠªåæ§ãæãããåŸæ¥ææ¡ããã
ããšã®ãªãã€ã液ç¶ãŽã ç³»âããªãšã¹ãã«ç³»ãã
ãã¯å ±éåäœãå«æããæ¹è³ªå€ãšããããšã«ã
ããæ圢äœæ¥æ§ããããåªããè¡šé¢ã®æ圢ç©ãåŸ
ããã該æ圢ç©ã®æ©æ¢°ç匷床ãåçž®äœæžçãæ Œæ®µ
ã«æ¹è¯ããããšãã§ãããšããå¹æãããã
äžèª¬æããæ¬çºæã«ã¯ã液ç¶ãŽã ç³»ååç©åã³ã
ãªãšã¹ãã«ç³»ããªããŒã®åæ¹ã®ç¹æ§ã䜵ãæãæ
ãã¯ãŸãåæ¹ã«èŠªåæ§ãæãããåŸæ¥ææ¡ããã
ããšã®ãªãã€ã液ç¶ãŽã ç³»âããªãšã¹ãã«ç³»ãã
ãã¯å ±éåäœãå«æããæ¹è³ªå€ãšããããšã«ã
ããæ圢äœæ¥æ§ããããåªããè¡šé¢ã®æ圢ç©ãåŸ
ããã該æ圢ç©ã®æ©æ¢°ç匷床ãåçž®äœæžçãæ Œæ®µ
ã«æ¹è¯ããããšãã§ãããšããå¹æãããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ãããæ§æããã»ã°ã¡ã³ããšããŠãšãã«ãã
ãã¯ç¶ã®æ¶²ç¶ãŽã ç³»ååç©éšåãšããªãšã¹ã«éšå
ãšãå°ãªããšãåãã液ç¶ãŽã ç³»ååç©éšåïŒå
ã«å¯ŸããŠãšã¹ãã«çµåãä»ããŠããªãšã¹ãã«éšå
ãïŒååã¯ïŒå以äžé£çµãããŠãã液ç¶ãŽã ç³»â
ããªãšã¹ãã«ç³»ãããã¯å ±éåäœã§ãã€ãŠã該ã
ãªãšã¹ãã«éšåã液ç¶ãŽã ååç©ååäžã®ã«ã«ã
ãã·ã«åºåã¯æ°Žé žåºãåºçºåºè³ªãšããŠããã«ææ©
ãžã«ã«ãã³é žç¡æ°Žç©ãšïŒïŒïŒâãšããã·ããšã觊
åªååšäžã«äº€äºã«çž®å圢æãããããªãšã¹ãã«é
ã§ãã液ç¶ãŽã ç³»âããªãšã¹ãã«ç³»ãããã¯å ±é
åäœããæãããšãç¹åŸŽãšããåææš¹èææçšæ¹
質å€ã ïŒ ææ©ãžã«ã«ãã³é žç¡æ°Žç©ããç¡æ°Žãã¿ã«é žã
ç¡æ°Žã³ãã¯é žãç¡æ°Žãã¬ã€ã³é žãã·ã¯ããããµã³
ãžã«ã«ãã³é žç¡æ°Žç©ãã·ã¯ãããã»ã³ãžã«ã«ãã³
é žç¡æ°Žç©åã¯ãšã³ãã¡ãã¬ã³ã·ã¯ãããã»ã³ãžã«
ã«ãã³é žç¡æ°Žç©ããéžã°ããïŒçš®åã¯ïŒçš®ä»¥äžã§
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®åææš¹èææçš
æ¹è³ªå€ã ïŒ ïŒïŒïŒâãšããã·ããããšãã¬ã³ãªããµã€
ãããããã¬ã³ãªããµã€ãåã¯ããã¬ã³ãªããµã€
ãããéžã°ããïŒçš®åã¯ïŒçš®ä»¥äžã§ããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒé èšèŒã®åææš¹èææçšæ¹
質å€ã ïŒ ããªãšã¹ãã«éšåã®æ«ç«¯ããããã«åºããšã
ãã·åºãã€ãœã·ã¢ããŒãåºåã¯ã¢ããåºã®åŠãå
å¿æ§åºã§å€æ§ãããŠããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã
第ïŒé ã®ããããäžã€ã®é èšèŒã®åææš¹èææçš
æ¹è³ªå€ã ïŒ ããªãšã¹ãã«éšåã®æ«ç«¯ãããšã¹ãã«çµåã
ãšãŒãã«çµåãã¢ããçµååã¯ãŠã¬ã¿ã³çµåãä»
ããŠéåå¿æ§åºã§å€æ§ãããŠããç¹èš±è«æ±ã®ç¯å²
第ïŒé ã第ïŒé ã®ããããäžã€ã®é èšèŒã®åææš¹
èææçšæ¹è³ªå€ã ïŒ ããªãšã¹ãã«éšåã®æ«ç«¯åºã®25ïŒ ä»¥äžãã«ã«
ããã·ã«åºåã¯æ°Žé žåºã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é ã第ïŒé ã®ããããäžã€ã®é èšèŒã®åææš¹èæ
æçšæ¹è³ªå€ã ïŒ æ¶²ç¶ãŽã ç³»ååç©ãããªãã¿ãžãšã³ç³»ååç©
ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ã®ãããã
äžã€ã®é èšèŒã®åææš¹èææçšæ¹è³ªå€ã ïŒ ããªãã¿ãžãšã³ç³»ååç©ããã¿ãžãšã³ã®åç¬
éåäœã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®åææš¹
èææçšæ¹è³ªå€ã ïŒ æ¶²ç¶ãŽã ç³»âããªãšã¹ãã«ç³»ãããã¯å ±éå
äœäžã®10ã95ééïŒ ããŽã ç³»ååç©éšåã§ããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ã®ããããäžã€ã®é
èšèŒã®åææš¹èææçšæ¹è³ªå€ã
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61037718A JPS62195047A (ja) | 1986-02-21 | 1986-02-21 | åææš¹èææçšæ¹è³ªå€ |
| CA000529036A CA1268279A (en) | 1986-02-21 | 1987-02-05 | Additives for synthetic resins |
| AU68777/87A AU6877787A (en) | 1986-02-21 | 1987-02-13 | Additives for synthetic resins |
| EP19870301324 EP0242027B1 (en) | 1986-02-15 | 1987-02-16 | Block copolymers comprising rubber and polyester segments, method of preparation |
| DE19873750557 DE3750557T2 (de) | 1986-02-15 | 1987-02-16 | Blockkopolymere, die Kautschuk- und Polyesterblocks enthalten, Verfahren zur Herstellung. |
| US07/376,142 US4898964A (en) | 1986-02-21 | 1989-07-06 | Additives for synthetic resins |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61037718A JPS62195047A (ja) | 1986-02-21 | 1986-02-21 | åææš¹èææçšæ¹è³ªå€ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62195047A JPS62195047A (ja) | 1987-08-27 |
| JPH041787B2 true JPH041787B2 (ja) | 1992-01-14 |
Family
ID=12505291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61037718A Granted JPS62195047A (ja) | 1986-02-15 | 1986-02-21 | åææš¹èææçšæ¹è³ªå€ |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4898964A (ja) |
| JP (1) | JPS62195047A (ja) |
| AU (1) | AU6877787A (ja) |
| CA (1) | CA1268279A (ja) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002356608A (ja) * | 2001-05-30 | 2002-12-13 | Bridgestone Sports Co Ltd | ãŽã«ãããŒã«çšæš¹èçµæç©åã³ãŽã«ãããŒã« |
| CN110358071B (zh) * | 2019-07-15 | 2022-08-19 | 䜳åååŠç§æåå±ïŒäžæµ·ïŒæéå ¬åž | äžç§åµæ®µå ±èç©ãå纀油ååå ¶å¶å€æ¹æ³ååºçš |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS517096A (ja) * | 1974-07-09 | 1976-01-21 | Asahi Chemical Ind | Kyojugohoriesuteruno seizohoho |
| JPS55108451A (en) * | 1979-01-08 | 1980-08-20 | Gen Electric | Polyester composition |
| JPS57125214A (en) * | 1980-12-19 | 1982-08-04 | Bayer Ag | Thermoplastic block copolyester, manufacture and use for molding manufacture |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4069384A (en) * | 1971-12-22 | 1978-01-17 | The Goodyear Tire & Rubber Company | Carboxyl terminated polydienes |
-
1986
- 1986-02-21 JP JP61037718A patent/JPS62195047A/ja active Granted
-
1987
- 1987-02-05 CA CA000529036A patent/CA1268279A/en not_active Expired - Fee Related
- 1987-02-13 AU AU68777/87A patent/AU6877787A/en not_active Abandoned
-
1989
- 1989-07-06 US US07/376,142 patent/US4898964A/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS517096A (ja) * | 1974-07-09 | 1976-01-21 | Asahi Chemical Ind | Kyojugohoriesuteruno seizohoho |
| JPS55108451A (en) * | 1979-01-08 | 1980-08-20 | Gen Electric | Polyester composition |
| JPS57125214A (en) * | 1980-12-19 | 1982-08-04 | Bayer Ag | Thermoplastic block copolyester, manufacture and use for molding manufacture |
Also Published As
| Publication number | Publication date |
|---|---|
| US4898964A (en) | 1990-02-06 |
| AU6877787A (en) | 1987-08-27 |
| JPS62195047A (ja) | 1987-08-27 |
| CA1268279A (en) | 1990-04-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0585571B2 (ja) | ||
| JPH0627188B2 (ja) | åææš¹èææçšæ¹è³ªå€ | |
| US5122553A (en) | Hardenable unsaturated polyester resin compositions | |
| GB2246356A (en) | Resin compositions | |
| EP0242027B1 (en) | Block copolymers comprising rubber and polyester segments, method of preparation | |
| JP3162919B2 (ja) | ããªãšãŒãã«ãšã¹ãã«ã¢ããããã³æš¹èçµæç© | |
| JPH041787B2 (ja) | ||
| JPS63120718A (ja) | åææš¹èææçšæ¹è³ªå€ | |
| US5446092A (en) | Thermoplastic polymer composition | |
| JP2727674B2 (ja) | äœåçž®æ§äžé£œåããªãšã¹ãã«æš¹èçµæç© | |
| KR910000747B1 (ko) | í©ì±ìì§ì¬ë£ì© ê°ì§ì | |
| JPH0157139B2 (ja) | ||
| US5773517A (en) | Process for the production of thermoplastic resin composition | |
| JPS62195041A (ja) | äžé£œåããªãšã¹ãã«ç¡¬åæ§æš¹èçµæç© | |
| JP2542147B2 (ja) | èè¡ææ§ã«åªããããªã¢ããæš¹èçµæç© | |
| KR900000570B1 (ko) | ëžë¡ ê³µì€í©ì²Žì ì ì¡°ë°©ë² | |
| KR900000163B1 (ko) | ëžë¡ ê³µì€í©ì²Žì ì ì¡°ë°©ë² | |
| JPS636048A (ja) | äžé£œåããªãšã¹ãã«ç¡¬åæ§æš¹èçµæç© | |
| JPS59215351A (ja) | ç±å¯å¡æ§æš¹èçµæç© | |
| JPS633056A (ja) | äžé£œåããªãšã¹ãã«ç¡¬åæ§æš¹èçµæç© | |
| JPS63117027A (ja) | ãããã¯å ±éåäœã®è£œé æ¹æ³ | |
| JPH049170B2 (ja) | ||
| JPS6252780B2 (ja) | ||
| JPH06184425A (ja) | ããªã«ãŒãããŒãæš¹èçµæç© | |
| JPS6333464A (ja) | ç±å¯å¡æ§éåäœã®çµæç© |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |