JPH0313575B2 - - Google Patents
Info
- Publication number
- JPH0313575B2 JPH0313575B2 JP21890482A JP21890482A JPH0313575B2 JP H0313575 B2 JPH0313575 B2 JP H0313575B2 JP 21890482 A JP21890482 A JP 21890482A JP 21890482 A JP21890482 A JP 21890482A JP H0313575 B2 JPH0313575 B2 JP H0313575B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- silver halide
- alkyl group
- formula
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 claims description 152
- 229910052709 silver Inorganic materials 0.000 claims description 106
- 239000004332 silver Substances 0.000 claims description 106
- 239000000839 emulsion Substances 0.000 claims description 48
- 239000000463 material Substances 0.000 claims description 38
- 230000001235 sensitizing effect Effects 0.000 claims description 34
- 125000000217 alkyl group Chemical group 0.000 claims description 30
- 239000002245 particle Substances 0.000 claims description 26
- 229910052717 sulfur Inorganic materials 0.000 claims description 14
- 238000009826 distribution Methods 0.000 claims description 13
- 150000001450 anions Chemical class 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- WMUIZUWOEIQJEH-UHFFFAOYSA-N benzo[e][1,3]benzoxazole Chemical group C1=CC=C2C(N=CO3)=C3C=CC2=C1 WMUIZUWOEIQJEH-UHFFFAOYSA-N 0.000 claims description 8
- 125000005843 halogen group Chemical group 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 7
- 125000004442 acylamino group Chemical group 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 125000004466 alkoxycarbonylamino group Chemical group 0.000 claims description 6
- 125000003277 amino group Chemical group 0.000 claims description 6
- 125000004423 acyloxy group Chemical group 0.000 claims description 5
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 5
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- USYCQABRSUEURP-UHFFFAOYSA-N 1h-benzo[f]benzimidazole Chemical group C1=CC=C2C=C(NC=N3)C3=CC2=C1 USYCQABRSUEURP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000975 dye Substances 0.000 description 38
- 238000000034 method Methods 0.000 description 33
- 206010070834 Sensitisation Diseases 0.000 description 27
- 230000008313 sensitization Effects 0.000 description 27
- 230000035945 sensitivity Effects 0.000 description 21
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 18
- 229910021612 Silver iodide Inorganic materials 0.000 description 18
- 229940045105 silver iodide Drugs 0.000 description 18
- 230000003595 spectral effect Effects 0.000 description 18
- 229920000159 gelatin Polymers 0.000 description 15
- 239000008273 gelatin Substances 0.000 description 15
- 108010010803 Gelatin Proteins 0.000 description 14
- 235000019322 gelatine Nutrition 0.000 description 14
- 235000011852 gelatine desserts Nutrition 0.000 description 14
- 238000011161 development Methods 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- 239000011593 sulfur Substances 0.000 description 9
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 230000005070 ripening Effects 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000000084 colloidal system Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 5
- 229910052737 gold Inorganic materials 0.000 description 5
- 239000010931 gold Substances 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 206010034960 Photophobia Diseases 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 3
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 208000013469 light sensitivity Diseases 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 3
- 229910052711 selenium Inorganic materials 0.000 description 3
- 239000011669 selenium Substances 0.000 description 3
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 3
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- KRTDQDCPEZRVGC-UHFFFAOYSA-N 2-nitro-1h-benzimidazole Chemical class C1=CC=C2NC([N+](=O)[O-])=NC2=C1 KRTDQDCPEZRVGC-UHFFFAOYSA-N 0.000 description 2
- YYROPELSRYBVMQ-UHFFFAOYSA-N 4-toluenesulfonyl chloride Chemical compound CC1=CC=C(S(Cl)(=O)=O)C=C1 YYROPELSRYBVMQ-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003289 ascorbyl group Chemical class [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 description 2
- JEHKKBHWRAXMCH-UHFFFAOYSA-N benzenesulfinic acid Chemical compound O[S@@](=O)C1=CC=CC=C1 JEHKKBHWRAXMCH-UHFFFAOYSA-N 0.000 description 2
- GYTPOXPRHJKGHD-UHFFFAOYSA-N benzo[f][1,3]benzoxazole Chemical compound C1=CC=C2C=C(OC=N3)C3=CC2=C1 GYTPOXPRHJKGHD-UHFFFAOYSA-N 0.000 description 2
- 150000001565 benzotriazoles Chemical class 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- 125000006630 butoxycarbonylamino group Chemical group 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 2
- 150000002503 iridium Chemical class 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 2
- 229940080818 propionamide Drugs 0.000 description 2
- 125000004742 propyloxycarbonyl group Chemical group 0.000 description 2
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical class O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000003283 rhodium Chemical class 0.000 description 2
- 150000003346 selenoethers Chemical class 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000001119 stannous chloride Substances 0.000 description 2
- 235000011150 stannous chloride Nutrition 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- GVEYRUKUJCHJSR-UHFFFAOYSA-N (4-azaniumyl-3-methylphenyl)-ethyl-(2-hydroxyethyl)azanium;sulfate Chemical compound OS(O)(=O)=O.OCCN(CC)C1=CC=C(N)C(C)=C1 GVEYRUKUJCHJSR-UHFFFAOYSA-N 0.000 description 1
- OMAWWKIPXLIPDE-UHFFFAOYSA-N (ethyldiselanyl)ethane Chemical compound CC[Se][Se]CC OMAWWKIPXLIPDE-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical class C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 1
- CZQIJQFTRGDODI-UHFFFAOYSA-N 1-bromo-4-isocyanatobenzene Chemical compound BrC1=CC=C(N=C=O)C=C1 CZQIJQFTRGDODI-UHFFFAOYSA-N 0.000 description 1
- ADAKRBAJFHTIEW-UHFFFAOYSA-N 1-chloro-4-isocyanatobenzene Chemical compound ClC1=CC=C(N=C=O)C=C1 ADAKRBAJFHTIEW-UHFFFAOYSA-N 0.000 description 1
- GFNKTLQTQSALEJ-UHFFFAOYSA-N 1-isocyanato-4-nitrobenzene Chemical compound [O-][N+](=O)C1=CC=C(N=C=O)C=C1 GFNKTLQTQSALEJ-UHFFFAOYSA-N 0.000 description 1
- BDQNKCYCTYYMAA-UHFFFAOYSA-N 1-isocyanatonaphthalene Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1 BDQNKCYCTYYMAA-UHFFFAOYSA-N 0.000 description 1
- KPVMVJXYXFUVLR-UHFFFAOYSA-N 12-ethyltetradecan-1-amine Chemical compound CCC(CC)CCCCCCCCCCCN KPVMVJXYXFUVLR-UHFFFAOYSA-N 0.000 description 1
- TXJUTRJFNRYTHH-UHFFFAOYSA-N 1h-3,1-benzoxazine-2,4-dione Chemical compound C1=CC=C2C(=O)OC(=O)NC2=C1 TXJUTRJFNRYTHH-UHFFFAOYSA-N 0.000 description 1
- JHFAEUICJHBVHB-UHFFFAOYSA-N 1h-indol-2-ol Chemical compound C1=CC=C2NC(O)=CC2=C1 JHFAEUICJHBVHB-UHFFFAOYSA-N 0.000 description 1
- JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical class SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 1
- HAZJTCQWIDBCCE-UHFFFAOYSA-N 1h-triazine-6-thione Chemical class SC1=CC=NN=N1 HAZJTCQWIDBCCE-UHFFFAOYSA-N 0.000 description 1
- NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- ZLUCSIRMFOLXFF-UHFFFAOYSA-N 2-amino-5-methylbenzenesulfonyl chloride Chemical compound CC1=CC=C(N)C(S(Cl)(=O)=O)=C1 ZLUCSIRMFOLXFF-UHFFFAOYSA-N 0.000 description 1
- AYPSHJCKSDNETA-UHFFFAOYSA-N 2-chloro-1h-benzimidazole Chemical class C1=CC=C2NC(Cl)=NC2=C1 AYPSHJCKSDNETA-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- OFTKFKYVSBNYEC-UHFFFAOYSA-N 2-furoyl chloride Chemical compound ClC(=O)C1=CC=CO1 OFTKFKYVSBNYEC-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- JSIAIROWMJGMQZ-UHFFFAOYSA-N 2h-triazol-4-amine Chemical class NC1=CNN=N1 JSIAIROWMJGMQZ-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- LMRKXSDOAFUINK-UHFFFAOYSA-N 3-chlorosulfonylbenzoic acid Chemical compound OC(=O)C1=CC=CC(S(Cl)(=O)=O)=C1 LMRKXSDOAFUINK-UHFFFAOYSA-N 0.000 description 1
- OWIRCRREDNEXTA-UHFFFAOYSA-N 3-nitro-1h-indazole Chemical class C1=CC=C2C([N+](=O)[O-])=NNC2=C1 OWIRCRREDNEXTA-UHFFFAOYSA-N 0.000 description 1
- MWWNNNAOGWPTQY-UHFFFAOYSA-N 3-nitrobenzenesulfonyl chloride Chemical compound [O-][N+](=O)C1=CC=CC(S(Cl)(=O)=O)=C1 MWWNNNAOGWPTQY-UHFFFAOYSA-N 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- OCVLSHAVSIYKLI-UHFFFAOYSA-N 3h-1,3-thiazole-2-thione Chemical class SC1=NC=CS1 OCVLSHAVSIYKLI-UHFFFAOYSA-N 0.000 description 1
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 description 1
- ISULKPPMRMIAMM-UHFFFAOYSA-N 4-amino-3-nitrobenzenesulfonyl chloride Chemical compound NC1=CC=C(S(Cl)(=O)=O)C=C1[N+]([O-])=O ISULKPPMRMIAMM-UHFFFAOYSA-N 0.000 description 1
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 description 1
- KMMHZIBWCXYAAH-UHFFFAOYSA-N 4-bromobenzenesulfonyl chloride Chemical compound ClS(=O)(=O)C1=CC=C(Br)C=C1 KMMHZIBWCXYAAH-UHFFFAOYSA-N 0.000 description 1
- ZLYBFBAHAQEEQQ-UHFFFAOYSA-N 4-chlorobenzenesulfonyl chloride Chemical compound ClC1=CC=C(S(Cl)(=O)=O)C=C1 ZLYBFBAHAQEEQQ-UHFFFAOYSA-N 0.000 description 1
- DTJVECUKADWGMO-UHFFFAOYSA-N 4-methoxybenzenesulfonyl chloride Chemical compound COC1=CC=C(S(Cl)(=O)=O)C=C1 DTJVECUKADWGMO-UHFFFAOYSA-N 0.000 description 1
- SKDHHIUENRGTHK-UHFFFAOYSA-N 4-nitrobenzoyl chloride Chemical compound [O-][N+](=O)C1=CC=C(C(Cl)=O)C=C1 SKDHHIUENRGTHK-UHFFFAOYSA-N 0.000 description 1
- QIZPONOMFWAPRR-UHFFFAOYSA-N 4-phenoxybenzenesulfonyl chloride Chemical compound C1=CC(S(=O)(=O)Cl)=CC=C1OC1=CC=CC=C1 QIZPONOMFWAPRR-UHFFFAOYSA-N 0.000 description 1
- MGYGFNQQGAQEON-UHFFFAOYSA-N 4-tolyl isocyanate Chemical compound CC1=CC=C(N=C=O)C=C1 MGYGFNQQGAQEON-UHFFFAOYSA-N 0.000 description 1
- HLQPFEHFAQQWLW-UHFFFAOYSA-N 5-bromo-2-chlorosulfonylbenzoic acid Chemical compound OC(=O)C1=CC(Br)=CC=C1S(Cl)(=O)=O HLQPFEHFAQQWLW-UHFFFAOYSA-N 0.000 description 1
- GIQKIFWTIQDQMM-UHFFFAOYSA-N 5h-1,3-oxazole-2-thione Chemical compound S=C1OCC=N1 GIQKIFWTIQDQMM-UHFFFAOYSA-N 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical class NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical class OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- SJUCACGNNJFHLB-UHFFFAOYSA-N O=C1N[ClH](=O)NC2=C1NC(=O)N2 Chemical class O=C1N[ClH](=O)NC2=C1NC(=O)N2 SJUCACGNNJFHLB-UHFFFAOYSA-N 0.000 description 1
- QPFYXYFORQJZEC-FOCLMDBBSA-N Phenazopyridine Chemical compound NC1=NC(N)=CC=C1\N=N\C1=CC=CC=C1 QPFYXYFORQJZEC-FOCLMDBBSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- MNOILHPDHOHILI-UHFFFAOYSA-N Tetramethylthiourea Chemical compound CN(C)C(=S)N(C)C MNOILHPDHOHILI-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 125000000738 acetamido group Chemical group [H]C([H])([H])C(=O)N([H])[*] 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 108091005647 acylated proteins Proteins 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- HTKFORQRBXIQHD-UHFFFAOYSA-N allylthiourea Chemical compound NC(=S)NCC=C HTKFORQRBXIQHD-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 150000001448 anilines Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- XNSQZBOCSSMHSZ-UHFFFAOYSA-K azane;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(3+) Chemical compound [NH4+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XNSQZBOCSSMHSZ-UHFFFAOYSA-K 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- FYXKZNLBZKRYSS-UHFFFAOYSA-N benzene-1,2-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC=C1C(Cl)=O FYXKZNLBZKRYSS-UHFFFAOYSA-N 0.000 description 1
- CSKNSYBAZOQPLR-UHFFFAOYSA-N benzenesulfonyl chloride Chemical compound ClS(=O)(=O)C1=CC=CC=C1 CSKNSYBAZOQPLR-UHFFFAOYSA-N 0.000 description 1
- BVVBQOJNXLFIIG-UHFFFAOYSA-N benzo[g][1,3]benzoxazole Chemical compound C1=CC=CC2=C(OC=N3)C3=CC=C21 BVVBQOJNXLFIIG-UHFFFAOYSA-N 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- COPHVUDURPSYBO-UHFFFAOYSA-N butyl dioctyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCCC)OCCCCCCCC COPHVUDURPSYBO-UHFFFAOYSA-N 0.000 description 1
- 150000001661 cadmium Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical class OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000000586 desensitisation Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000009034 developmental inhibition Effects 0.000 description 1
- 229920005994 diacetyl cellulose Polymers 0.000 description 1
- KYQODXQIAJFKPH-UHFFFAOYSA-N diazanium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [NH4+].[NH4+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O KYQODXQIAJFKPH-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- RIFGWPKJUGCATF-UHFFFAOYSA-N ethyl chloroformate Chemical compound CCOC(Cl)=O RIFGWPKJUGCATF-UHFFFAOYSA-N 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- ALCDAWARCQFJBA-UHFFFAOYSA-N ethylselanylethane Chemical compound CC[Se]CC ALCDAWARCQFJBA-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical class OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002344 gold compounds Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- SSBBQNOCGGHKJQ-UHFFFAOYSA-N hydroxy-(4-methylphenyl)-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound CC1=CC=C(S(S)(=O)=O)C=C1 SSBBQNOCGGHKJQ-UHFFFAOYSA-N 0.000 description 1
- WYASEAQTEQVOJE-UHFFFAOYSA-N hydroxy-phenyl-sulfanylidene-$l^{4}-sulfane Chemical compound OS(=S)C1=CC=CC=C1 WYASEAQTEQVOJE-UHFFFAOYSA-N 0.000 description 1
- 150000005204 hydroxybenzenes Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- LOCAIGRSOJUCTB-UHFFFAOYSA-N indazol-3-one Chemical class C1=CC=C2C(=O)N=NC2=C1 LOCAIGRSOJUCTB-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- OPECTNGATDYLSS-UHFFFAOYSA-N naphthalene-2-sulfonyl chloride Chemical compound C1=CC=CC2=CC(S(=O)(=O)Cl)=CC=C21 OPECTNGATDYLSS-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- VECVSKFWRQYTAL-UHFFFAOYSA-N octyl benzoate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1 VECVSKFWRQYTAL-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 125000002971 oxazolyl group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 150000002940 palladium Chemical class 0.000 description 1
- 238000003921 particle size analysis Methods 0.000 description 1
- DGTNSSLYPYDJGL-UHFFFAOYSA-N phenyl isocyanate Chemical compound O=C=NC1=CC=CC=C1 DGTNSSLYPYDJGL-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 150000003057 platinum Chemical class 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- QUCBOTJDQJBEPB-KVVVOXFISA-M potassium (Z)-2-iodooctadec-9-enoate Chemical compound IC(C(=O)[O-])CCCCCC\C=C/CCCCCCCC.[K+] QUCBOTJDQJBEPB-KVVVOXFISA-M 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 229940070891 pyridium Drugs 0.000 description 1
- HBCQSNAFLVXVAY-UHFFFAOYSA-N pyrimidine-2-thiol Chemical class SC1=NC=CC=N1 HBCQSNAFLVXVAY-UHFFFAOYSA-N 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical compound O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- HAAYBYDROVFKPU-UHFFFAOYSA-N silver;azane;nitrate Chemical compound N.N.[Ag+].[O-][N+]([O-])=O HAAYBYDROVFKPU-UHFFFAOYSA-N 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- SDKPSXWGRWWLKR-UHFFFAOYSA-M sodium;9,10-dioxoanthracene-1-sulfonate Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)[O-] SDKPSXWGRWWLKR-UHFFFAOYSA-M 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- NASFKTWZWDYFER-UHFFFAOYSA-N sodium;hydrate Chemical compound O.[Na] NASFKTWZWDYFER-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 229950000244 sulfanilic acid Drugs 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 125000004964 sulfoalkyl group Chemical group 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 150000003475 thallium Chemical class 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- 125000005323 thioketone group Chemical group 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 150000008130 triterpenoid saponins Chemical class 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/28—Sensitivity-increasing substances together with supersensitising substances
- G03C1/29—Sensitivity-increasing substances together with supersensitising substances the supersensitising mixture being solely composed of dyes ; Combination of dyes, even if the supersensitising effect is not explicitly disclosed
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
Description
æ¬çºæã¯ãåå
å¢æããæ床ãæ¹è¯ããããã
ã²ã³åéåçæå ææã«é¢ããæŽã«è©³ããã¯ç·è²
å åã«åå å¢æããæ床ãé«ãããããã€é«ç §åºŠ
çæéé²å ç¹æ§ãæ¹è¯ãããããã²ã³åéåçæ
å ææã«é¢ããã è¿å¹Žãããã²ã³åéåçé¢å ææïŒä»¥äžåã«æ
å ææãšç§°ãïŒã«å¯ŸããèŠè«ããŸããŸãå³ããã
é«å¯åºŠãåªããç²ç¶æ§ãé«é®®éæ§ãäœãã«ããªæ¿
床ããã³ååé«ãå åŠæ¿åºŠçã®åçæ§èœã«å¯ŸããŸ
ããŸãé«æ°Žæºã®èŠæ±ããªãããŠããã ç¹ã«ã¢ãããŠã¢çšã«ã©ãŒæå ææã«ã€ããŠã¯ã
æ®åœ±æè¡ã®é²æ©ã«é¢é£ããŠãã«ã¡ã©ãå°å軜éå
ããæ®åœ±ãç°¡æã§ããããæ®åœ±ã®å€±æã®ãªããã®
ã匷ãèŠæããã€ã€ããååã«å¯Ÿå¿ããŠãäŸãã°
äœç §åºŠäžã§ã®ããããªåçæ®åœ±ãéãåãã®è¢«å
äœã®åããæ¢ããé«éã·ã€ãã¿ãŒäœ¿çšã®æ®åœ±ãå¯
èœãšãããããªæ®åœ±æ¡ä»¶ã®å€åã«å¯ŸããŠèš±å®¹åºŠã®
åºãæå ææã®éçºãäžå±€åŒ·ãåæãããŠããã åšç¥ã®åŠããããã²ã³åéèªèº«ã®åºææå æ³¢é·
åã¯çŽ«å€ç·ãŸãã¯éè²å ã®çæ³¢é·åã«éãããŠã
ãã ãã®åºææå æ³¢é·åã§ã®æ床ã¯äžè¬ã«ããã²ã³
åéä¹³å€ã«ç¡«é»å¢æå€ãéå¢æå€ãéå å¢æå€ç
ã®ååŠç©è³ªãæ·»å ããŠçæããæè¬ååŠå¢æã«ã
ã€ãŠé«ãããããæå æ³¢é·åã¯æ®ãã©å€åããª
ãã æå æ³¢é·åã®æ¡åŒµã¯ä¹³å€ã«å¢æè²çŽ ãæ·»å ãã
ããšã«ãã€ãŠãªããããã®ããšã¯åå å¢æãšããŠ
ç¥ãããŠãããæŽã«æ°çš®ã®å¢æè²çŽ ãããã¯ç¡è²
ã®ååç©ãå ããŠåå å¢æã匷åããããšã¯â匷
è²å¢æâãšåŒã°ããæ¢ã«æ°å€ãã®çµã¿åãããå ±
åãããŠãããåå å¢ææ³¢é·åã§ã®åçæ床ã¯å
å å¢æãããã¯åŒ·è²å¢æå¹æã«ãã€ãŠæ¯é ããã
ã°ããã§ãªããååŠå¢æå¹æã«ãã€ãŠãæ¯é ãã
ãããšãç¥ãããŠãããããããããã«æé©åã
ãããåå å¢ææè¡ã®äž»èŠãªèª²é¡ã§ããã å¢æè²çŽ ã®çµã¿åããã«ãã匷è²å¢æã®æè¡ã«
é¢ããŠã¯äœ¿çšããè²çŽ ãåã«åå æ床ãé«ããã®
ã¿ã§ãªããåå å¢ææ³¢é·åãé©åã§ãããçš®ã ã®
åççšæ·»å å€ãšã®éã§æªãçžäºäœçšããªããä¹³å€
å¡åžåŸãªãã³ã«æå ææãšããŠä¿åäžã§ã®åçç¹
æ§ã®çµæå€åãå°ãªããæŽã«ã¯çŸååŠçåŸã®æå
ææã«è²çŽ æ±æãæ®ããªãçã®è«žæ¡ä»¶ãæºè¶³ãã
å¿ èŠããããããç®çã«å¿ããé©åãªïŒçš®é¡ä»¥äž
ã®å¢æè²çŽ ã®çµã¿åãããèŠãåºãããšã¯å®¹æã§
ãªãããšãç¥ãããŠããã ãããŸã§ã«ã©ãŒæå ææã«ãããŠèµ€è²ãç·è²ã
ãã³éè²ã®åæ³¢é·åã®å ã«æå æ§ãæããåãã
ã²ã³åéä¹³å€å±€ã®ãã¡ãç·è²ã®æ³¢é·åã«æå 床ã
ãããããããªããã²ã³åéä¹³å€å±€ã®åå å¢ææ
è¡ã«ã€ããŠã¯ãäŸãã°ãªããµã«ã«ãã·ã¢ãã³è²çŽ
ãšãã³ãŸã€ãããŸãã«ã«ãã·ã¢ãã³è²çŽ ã®ïŒçš®ã
çµã¿åãããŠäœ¿çšããæè¡ãç¹å ¬æ43â22884å·ã
å45â4511å·ãå45â18433å·ãå45â4936å·ã
å48â25652å·ãå53â12375å·ãå50â34411å·ã
ç¹éæ52â82416å·ãå52â16223å·åå ¬å ±ããã³
ç±³åœç¹èš±ç¬¬3672898å·æ现æžçã«é瀺ãããŠããã ãããã®ç·ææ§åå å¢ææè¡ã¯é©åãªåå æ³¢é·
åãåå å¢æããããšãã§ããåççšæ·»å å€ãç¹
ã«ããŒã³ã¿ã«ãã©ãŒãšã®æªãçžäºäœçšã«ããæžæ
ããã³æ®è²æ§ã®å°ãªãå¢ææè¡ãšããŠè©äŸ¡ãããŠ
ããã ããããªããããããã®å¢ææ¹æ³ã«å¯ŸããŠã¯æŽ
ã«åå æ床ã®å¢å€§ãæåŸ ãããŠããããŸãåæã«
åè¿°ã®åŠãå¢ææ¹æ³ã«ãã€ãŠåŸãããåå æ床ã
ãã€æå ææã«é«ç §åºŠçæéé²å ãè¡ã€ãå Žåã«
ãæ床ãæ倧çºè²æ¿åºŠãã¬ã³ããŸãã¯é調æ§ã®äœ
äžãŸãã¯å£åãã¿ãããªããããªæå ææãæåŸ
ãããŠããã ããã§æ¬çºæã®ç®çã¯ãç·è²å æ³¢é·åã®å ã«å¯Ÿ
ããŠåå æ床ãããé«ããããæå ææãæäŸã
ãããšã«ããããŸãå¥ã®ç®çã¯ãç·è²å ã«å¯ŸããŠ
åå å¢æããããã€é«ç §åºŠçæéé²å ã«å¯Ÿããç¹
æ§ãæ¹è¯ãããæå ææãæäŸããããšã«ããã æ¬çºæè çããäžèšã«å¯Ÿãæ€èšãéããçµæã
æ¯æäœäžã«ãå°ãªããšãïŒå±€ã®ããã²ã³åéä¹³å€
å±€ãæããæå ææã«ãããŠãäžèšããã²ã³åé
ä¹³å€å±€ã«äžèšåŒ(A)ã§ç€ºãããç²åºŠååžãæããå®
質çã«ååæ£æ§ã®ããã²ã³åéç²åãå«æãããŠ
ããããã€è©²ããã²ã³åéç²åãäžèšäžè¬åŒ
ããã§ç€ºãããå°ãªããšãïŒçš®ã®å¢æè²çŽ ãäž
èšäžè¬åŒããã§ç€ºãããå°ãªããšãïŒçš®ã®å¢æ
è²çŽ ããã³äžèšäžè¬åŒããã§ç€ºãããå°ãªããš
ãïŒçš®ã®å¢æè²çŽ ãšãçµã¿åãããŠå¢æãããŠã
ãæå ææã«ããåèšç®çãéæãåŸãããšãèŠ
ãåºããã åŒ(A) ïŒâŠ0.20 ããã§ïŒ³ããã³ã¯ãããã²ã³åéç²åã®ç²åºŠ
ååžã«ãããŠãã¯æšæºåå·®ããã¯å¹³åç²åŸã
è¡šããã ïŒâΣïŒÎ³âγiïŒ2niïŒÎ£ni ïŒÎ£niγiïŒÎ£ni γiïŒïœçªç®ã®ç²åã®ç²åŸ niïŒïœçªç®ã®ç²åã®æ° ã§ç€ºãããã äžè¬åŒãã åŒäžãY1ãY2ãY3ããã³Y4ã¯ããããæ°ŽçŽ å
åãããã²ã³ååãããããã·ã«åºãã¢ã«ã³ãã·
åºãã¢ããåºãã¢ã·ã«ã¢ããåºãã¢ã·ã«ãªãã·
åºãã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ã«ã³ãã·ã«ã«ã
ãã«ã¢ããåºãã¢ãªãŒã«åºãã·ã¢ãåºãã¢ã«ãã«
åºãè¡šãããY1ãšY2ãŸãã¯Y3ãšY4ã®ã©ã¡ããäž
æ¹ã¯ç°ã圢æãããããªããµãŸãŒã«ç°ã圢æããŠ
ãããããŸãR1ã¯æ°ŽçŽ ååãŸãã¯ã¢ã«ãã«åºã
è¡šããR2ããã³R3ã¯ããããã¢ã«ãã«åºãè¡šã
ããX1 ã¯ã¢ããªã³ãè¡šãããïœã¯ïŒãŸãã¯ïŒ
ã®æŽæ°ãè¡šããããã ããïœãïŒãè¡šãããšã
ã¯ãR2ãŸãã¯R3ã¯ååå å¡©ã圢æãåŸãåºãè¡š
ããã äžè¬åŒãã åŒäžãY5ãšY6ããã³Y7ãšY8ã¯ããããé£çµã
ãŠç°ã圢æããããããããããªããµãŸãŒã«ç°ã
圢æããåå矀ãè¡šããããŸãR4ã¯æ°ŽçŽ ååãŸ
ãã¯ã¢ã«ãã«åºãè¡šãããR5ããã³R6ã¯ããã
ãã¢ã«ãã«åºãè¡šãããX2 ã¯ã¢ããªã³ãè¡šã
ãïœã¯ïŒãŸãã¯ïŒã®æŽæ°ãè¡šããããã ããïœã
ïŒãè¡šãããšãã¯ãR5ãŸãã¯R6ã¯ååå å¡©ã圢
æãåŸãåºãè¡šããã äžè¬åŒãã åŒäžãY9ãY10ãY11ããã³Y12ã¯ããããæ°ŽçŽ
ååãããã²ã³ååãããããã·ã«åºãã¢ã«ã³ã
ã·åºãã¢ããåºãã¢ã·ã«ã¢ããåºãã¢ã·ã«ãªãã·
åºãã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ã«ã³ãã·ã«ã«ã
ãã«ã¢ããåºãã¢ãªãŒã«åºãã·ã¢ãåºãã¢ã«ãã«
åºãè¡šãããY9ãšY10ããã³ïŒãŸãã¯Y11ãšY12ã¯
ããããé£çµããŠç°ã圢æããããããããŸãŒã«
ç°ã圢æããŠãããããŸãR7ã¯æ°ŽçŽ ååãŸãã¯
ã¢ã«ãã«åºãè¡šãããR8ãR9ãR10ããã³R11ã¯
ããããã¢ã«ãã«åºãè¡šãããX3 ã¯ã¢ããªã³
ãè¡šããïœã¯ïŒãŸãã¯ïŒã®æŽæ°ãè¡šããããã
ããïœãïŒãè¡šãããšãã¯ãR8ãR9ãR10ãŸãã¯
R11ã¯ååå å¡©ã圢æãåŸãåºãè¡šããã ããªãã¡ãæ¬çºæã®æå ææã¯ãæ¯æäœäžã«èš
ããããããã²ã³åéä¹³å€å±€ãåèšåŒ(A)ã§ç€ºãã
ãåŠãç²åºŠååžãæããå®è³ªçã«ååæ£æ§ã®ãã
ã²ã³åéç²åãå«æãããã®ã§ããããã€è©²ãã
ã²ã³åéç²åãåèšäžè¬åŒãããããããã³
ããã§ç€ºãããå¢æè²çŽ ã®ããããå°ãªããšã
ïŒçš®ã¥ã€ãçµã¿åãããŠåå å¢æããããããã
ããšãç¹åŸŽãšããæ¬çºæã®å¹æãå ·äœçã«ã¯ç·è²
å ã«å¯ŸããŠé«ãåå å¢ææ床ãæãããããé«ç §
床çæéé²å ã«å¯Ÿããç¹æ§ãæ¹è¯ãããé«æ床ã®
æå ææãåŸãããšãã§ããã ãŸããæ¬çºæè ãã¯å ã«æå57幎ïŒ12æïŒå·®ã
åºãç¹èš±é¡çºæã®å称ãããã²ã³åéåçæå æ
æãã«ãããŠãåèšæ¬çºæã«ä¿ãäžè¬åŒããã
ãã³ããã§ç€ºãããå¢æè²çŽ ãçšããæè¡ãé
瀺ããããæŽã«æ¬çºæè ããéæç 究ãéããçµ
æåèšæ¬çºæã«ä¿ãæ§æãæããæå ææã«ã
ããåè¿°ã®å¹æãæããæå ææãåŸãããšãã§
ããã®ã§ããã 以äžãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æããã å ã¥åèšäžè¬åŒããã«ãããŠãY1ãY2ãY3
ããã³Y4ããããã瀺ãããã²ã³ååãšããŠã¯ã
äŸãã°å¡©çŽ ãèçŽ ãæ²çŽ ãããçŽ ããããã¢ã«ã³
ãã·åºãšããŠã¯ãäŸãã°ã¡ããã·ããšããã·ãã
ãããã·ããããã·çã®ååºããããã¢ããåºãš
ããŠã¯ãäŸãã°ã¢ãããã¡ãã«ã¢ããããžã¡ãã«
ã¢ããããžãšãã«ã¢ããçã®ååºãæããããšã
ã§ããã¢ã·ã«ã¢ããåºãšããŠã¯ãäŸãã°ã¢ã»ãã¢
ãããããããªã³ã¢ããçã®ååºããããã¢ã«ã³
ãã·ã«ã«ããã«åºãšããŠã¯ãäŸãã°ãšããã·ã«ã«
ããã«ãããããã·ã«ã«ããã«çã®ååºãããã
ã¢ã«ã³ãã·ã«ã«ããã«ã¢ããåºãšããŠã¯ãäŸãã°
ãšããã·ã«ã«ããã«ã¢ãããããããã·ã«ã«ãã
ã«ã¢ããããããã·ã«ã«ããã«ã¢ããçã®åºãã
ããã¢ãªãŒã«åºãšããŠã¯äŸãã°ããšãã«ãããªãŒ
ã«çã®åºããããã¢ã«ãã«åºãšããŠã¯ã奜ãŸãã
ã¯äœçŽã¢ã«ãã«åºãäŸãã°ã¡ãã«ããšãã«ããã
ãã«çã®åºãæããããšãã§ããããããŠäžèš
Y1ãY2ã®å°ãªããšãïŒã€ãããã³Y3ãY4ã®å°ãª
ããšãïŒã€ãã¢ãªãŒã«åºã§ããããšã奜ãŸããã
ãŸãY1ãšY2ãŸãã¯Y3ãšY4ã®ã©ã¡ããäžæ¹ãé£çµ
ããŠç°ã圢æããŠãããããã®çµæããããªããµ
ãŸãŒã«ç°ãäŸãã°ããããïŒïŒïŒâïœããªããµãŸ
ãŒã«ãããããïŒïŒïŒâïœããªããµãŸãŒã«ããã
ããïŒïŒïŒâïœããªããµãŸãŒã«çãäžè¬åŒãã
ã§ç€ºãããååç©ã®ååå ã«åœ¢æããŠãããŸããª
ãã ããã«åèšäžè¬åŒããã«ãããŠR1ãè¡šãã
ã¢ã«ãã«åºãšããŠã¯ãäœçŽã¢ã«ãã«åºã奜ãŸã
ããäŸãã°ã¡ãã«ããšãã«ããããã«çã®åºãã
ãããŸãR2ããã³R3ãããããè¡šããã¢ã«ãã«
åºãšããŠã¯ãäŸãã°ã¡ãã«ããšãã«ãã¹ã«ããšã
ã«ãã«ã«ããã·ãããã«ãããã«ãã¹ã«ãããã«
çã®åºãæããããšãã§ãããããã¯åããã®ã§
ãã€ãŠããããäºãã«ç°ãªã€ãŠããŠãããã åèšäžè¬åŒããã«ãããŠãX1 ãè¡šããã¢
ããªã³ãšããŠã¯ãäŸãã°å¡©åç©ãèåç©ãæ²å
ç©ãããªã·ã¢ããŒãããµã«ãã¢ã¡ãŒããã¡ãã«ãµ
ã«ããšãŒãããšãã«ãµã«ããšãŒããããŒã¯ãã¬ãŒ
ããïœâãã«ãšã³ã¹ã«ãããŒãçã®ã¢ããªã³ãã
ãã åŒç¶ããŠåèšäžè¬åŒããã«ãããŠY5ãšY6ã
ãã³Y7ãšY8ãããããé£çµããŠç°ã圢æããã
ã®çµæããããªããµãŸãŒã«ç°ãäŸãã°ããã
ãïŒïŒïŒâïœããªããµãŸãŒã«ç°ãããããïŒïŒïŒ
âïœããªããµãŸãŒã«ç°ãŸãã¯ããããïŒïŒïŒâ
ïœããªããµãŸãŒã«ç°çãäžè¬åŒããã§ç€ºããã
ååç©ã®ååå ã«ãããã圢æããããšã奜ãŸã
ãã ãŸãR4ãè¡šããã¢ã«ãã«åºãšããŠã¯ãäœçŽã¢
ã«ãã«åºã奜ãŸãããäŸãã°ã¡ãã«ããšãã«ãã
ããã«çã®åºããããããã«ã¯R5ããã³R6ãè¡š
ããã¢ã«ãã«åºãšããŠã¯ãäŸãã°ã¡ãã«ããšã
ã«ãã¹ã«ããšãã«ãã«ã«ããã·ãããã«ããã
ã«ãã¹ã«ãããã«çã®åºããã€ãŠããããã¯åã
ã§ãã€ãŠãäºãã«ç°ãªã€ãŠããŠããããããã«
X2 ãè¡šããã¢ããªã³ãšããŠã¯ãäŸãã°å¡©åç©ã
èåç©ãæ²åç©ãããªã·ã¢ããŒãããµã«ãã¢ã¡ãŒ
ããã¡ãã«ãµã«ããšãŒãããšãã«ãµã«ããšãŒãã
ããŒã¯ãã¬ãŒããïœâãã«ãšã³ã¹ã«ãããŒãçã®
ã¢ããªã³ãããã 次ã«åèšäžè¬åŒããã«ãããŠãY9ãY10ã
Y11ããã³Y12ãããããè¡šããããã²ã³ååãš
ããŠã¯ãäŸãã°å¡©çŽ ãèçŽ ãæ²çŽ ãããçŽ çãã
ããã¢ã«ã³ãã·åºãšããŠã¯ãäŸãã°ã¡ããã·ããš
ããã·ãããããã·ããããã·çã®åºãæãã
ããã¢ããåºãšããŠã¯ãäŸãã°ã¢ãããã¡ãã«ã¢
ããããžã¡ãã«ã¢ããããžãšãã«ã¢ããçã®åºã
ãããã¢ã·ã«ã¢ããåºãšããŠã¯ãäŸãã°ã¢ã»ãã¢
ãããããããªã³ã¢ããçã®åºããããã¢ã·ã«ãª
ãã·åºãšããŠã¯ãäŸãã°ã¢ã»ããã·ãããããªã³
ãªãã·çã®åºããããã¢ã«ã³ãã·ã«ã«ããã«åºãš
ããŠã¯ãäŸãã°ãšããã·ã«ã«ããã«ãããããã·
ã«ã«ããã«çã®åºããããã¢ã«ã³ãã·ã«ã«ããã«
ã¢ããåºãšããŠã¯ãäŸãã°ãšããã·ã«ã«ããã«ã¢
ãããããããã·ã«ã«ããã«ã¢ããããããã·ã«
ã«ããã«ã¢ããçã®åºããããã¢ãªãŒã«åºãšããŠ
ã¯ãäŸãã°ããšãã«ãããªãŒã«çã®åºããããã¢
ã«ãã«åºãšããŠã¯ãäœçŽã¢ã«ãã«åºã奜ãŸããã
äŸãã°ã¡ãã«ããšãã«ããããã«çã®åºãããã
ãããŠäžèšY9ãY10ãY11ããã³Y12ãåæã«å¡©çŽ
ååãè¡šããããšã奜ãŸãããããã«ã¯Y9ãšY10
ã®å°ãªããšãïŒã€ããã³Y11ãšY12ã®å°ãªããšã
ïŒã€ãã·ã¢ãã§ããããšã奜ãŸããããŸãY9ãš
Y10ããã³Y11ãšY12ãããããé£çµããŠåœ¢æãã
ãããã€ãããŸãŒã«ç°ã圢æããŠãããŸããªãã
ãŸãR7ãè¡šããã¢ã«ãã«åºãšããŠã¯äœçŽã¢ã«ã
ã«åºã奜ãŸãããäŸãã°ã¡ãã«ããšãã«ãããã
ã«çã®åºããããR8ãR9ãR10ããã³R11ããã
ããè¡šããã¢ã«ãã«åºãšããŠã¯ãäŸãã°ã¡ãã«ã
ãšãã«ãã¹ã«ããšãã«ãã«ã«ããã·ãããã«ãã
ãã«ãã¹ã«ãããã«çã®åºããããããã«X3
ãè¡šããã¢ããªã³ãšããŠã¯ãäŸãã°å¡©åç©ãèå
ç©ãæ²åç©ãããªã·ã¢ããŒãããµã«ãã¢ã¡ãŒãã
ã¡ãã«ãµã«ããšãŒãããšãã«ãµã«ããšãŒããããŒ
ã¯ãã¬ãŒããïœâãã«ãšã³ã¹ã«ãããŒãçã®ã¢ã
ãªã³ãè¡šããã 以äžã«æ¬çºæã«ãããŠçšããããäžè¬åŒããã
ããããã³ããã«ãã€ãŠè¡šããããå¢æè²çŽ
ã®ä»£è¡šçãªãã®ã瀺ãããæ¬çºæããããã«éå®
ããããã®ã§ã¯ãªãã æ¬çºæã®äžè¬åŒãããããããã³ããã§è¡š
ããããå¢æžè²çŽ ã¯ãäŸãã°ç±³åœç¹èš±ç¬¬3397060
å·ãåç3506443å·çã«èšèŒãããŠãããããã«
äžèšå¢æè²çŽ ã®åææ³ã«ã€ããŠãèšè¿°ãããŠã
ãããªãäžèšç¹èš±æ现æžã«èšèŒã®ãªãå¢æè²çŽ ã
äžèšèšèŒã®åææ³ã«æºããŠåœæ¥è ã容æã«åæã
ãããšãã§ããã æ¬çºæã®æå ææã«ãããŠã¯ãæ¯æäœäžã«èšã
ãããå°ãªããšãïŒå±€ã®ããã²ã³åéä¹³å€å±€ã«å«
æãããæ¬çºæã«ä¿ãããã²ã³åéç²åãäžèšã«
ããåæãããæ¬çºæã«ä¿ãå¢æžè²çŽ ãçµã¿åã
ãå«æãå¢æãããããšã«ããåèšåå å¢æå¹æ
çãåŸãããšãã§ããããæ¬çºæã«ããã°ãäžèš
ããã²ã³åéä¹³å€å±€ã«ã¯ãåèšåŒ(A)ã§ç€ºãããç²
床ååžãæããå®è³ªçã«ååæ£æ§ã®ããã²ã³åé
ç²åãå«æããŠããããšã奜ãŸãããããªãã¡ã
æ¬çºæã«ãããäžèšããã²ã³åéç²åã®ç²åºŠååž
ã¯ãæ¬çºæã«ããäžèšåŒ(A)ã§èŠå®ãããåŠããæš
æºå差ãå¹³åç²åŸã§å²ã€ãæã®å€ã0.20ãŸã
ã¯ãã以äžã®ãã®ãèšãã åŒ(A) ïŒÎ³âŠ0.20 ïŒâΣïŒÎ³âγiïŒ2niïŒÎ£ni ããã§èšãå¹³åç²åŸãšã¯ãçç¶ã®ããã²ã³åé
ç²åã®å Žåã¯ããã®çŽåŸããŸãç«æ¹äœãçç¶ä»¥å€
ã®åœ¢ç¶ã®ç²åã®å Žåã¯ããã®æ圱åãåé¢ç©ã®å
åã«æç®ããæã®çŽåŸã®å¹³åå€ã§ãã€ãŠãåã ã®
ãã®ç²åŸãγiã§ããããã®æ°ãniã§ããæãäžèš
ã®åŒã«ãã€ãŠÎ³ãå®çŸ©ããããã®ã§ããã ïŒÎ£niγiïŒÎ£ni ãªããäžèšã®ç²ååŸã¯äžèšã®ç®çã®ããã«åœè©²
æè¡åéã«ãããŠäžè¬ã«çšããããåçš®ã®æ¹æ³ã«
ãã€ãŠããã枬å®ããããšãã§ããã代衚çãªæ¹
æ³ãšããŠã¯ãã©ãã©ã³ãã®ãç²ååŸåææ³ãA.S.
T.M.ã·ã³ããžãŠã ã»ãªã³ã»ã©ã€ãã»ãã€ã¯ãã¹
ã³ããŒã1955幎ã94ã122é ãŸãã¯ãåçããã»
ã¹ã®çè«ãããŒã¹ããã³ãžãšãŒã ãºå ±èã第ïŒ
çããã¯ãã©ã³ç€Ÿçºè¡ïŒ1966幎ïŒã®ç¬¬ïŒç« ã«èšèŒ
ãããŠããããã®ç²ååŸã¯ç²åã®æ圱é¢ç©ãçŽåŸ
è¿äŒŒå€ã䜿ã€ãŠããã枬å®ããããšãã§ãããç²
åãå®è³ªçã«åäžåœ¢ç¶ã§ããå Žåã¯ãç²åŸååžã¯
çŽåŸãæ圱é¢ç©ãšããŠãããªãæ£ç¢ºã«ãããè¡šã
ãããšãã§ããã ç²åŸååžã®é¢ä¿ã¯ãåçä¹³å€ã«ãããã»ã³ã·ã
ã¡ããªãŒååžãšç²åºŠååžãšã®éã®çµéšçé¢ä¿ãã¶
ããªãã°ã©ãã€ãã¯ãžã€ãŒãã«ãLXXIXå·»ã
ïŒ1949幎ïŒ330ã338é ã®ããªããªãšã¹ãã¹ã®è«æ
ã«èšèŒãããæ¹æ³ã§ãããã決ããããšãã§ã
ãã æ¬çºæã®æå ææã«çšããããããã²ã³åéç²
åã¯ãæ¬çºæã«ä¿ãååæ£æ§ã®ããã²ã³åéç²å
ãåäžããã²ã³åéä¹³å€å±€ã«ãããå šç²åã®70ïŒ
以äžå«æããŠããããšã奜ãŸãããç¹ã«å šç²åã
ååæ£ç²åã§ããããšã奜ãŸãããæ¬çºæã«ä¿ã
å®è³ªçã«ååæ£æ§ã®ããã²ã³åéç²åã¯ãåç¬ã§
䜿çšããŠããããå¹³åç²ååŸã®ç°ãªãïŒçš®ä»¥äžã®
ååæ£æ§ã®ããã²ã³åéç²åãä»»æã«æ··åããŠäœ¿
çšããŠãããã æ¬çºæã«ãããŠã¯ãåèšäžè¬åŒãããããã
ãã³ããã§ç€ºãããå¢æè²çŽ ïŒä»¥äžãæ¬çºæã«
ä¿ãå¢æè²çŽ ãšç§°ããïŒã«ããå¹æçã«åå å¢æ
ãããããã²ã³åéç²åã¯ãæ²åéå«æçã®ç°ãª
ãïŒå±€ä»¥äžã®å±€ããæ§æãããŠããç²åæ§é ã«ãª
ããã®ã奜ãŸããã該ïŒå±€ä»¥äžã®å±€ã®ãã¡ã®æè¡š
é¢å±€ã«ãããå¹³åæ²åéå«æçãããããããå
éšã®å±€ã®å¹³åæ²åºŠå«æçã«æ¯ã¹ãŠäœãããšã奜ãŸ
ãããæ¬çºæã«ããå¹æã¯ãäžèšã®ãããªæè¡šé¢
å±€ããå éšã«æ¯ã¹ãŠæè¡šé¢å±€ã«ãããæ²åéå«æ
çããããäœãç²åæ§é ãæããããã²ã³åéç²
åãå«æããããã²ã³åéä¹³å€ã®äœ¿çšã«ããäžå±€
é¡èã«çºæ®ãããã æ¬çºæã§ã¯ãäžèšçµæã«ãªãããã²ã³åéç²å
ã®æè¡šé¢å±€ã«ãããæ²åéå«æçã¯ãäœãã»ã©æ
ãŸãããã»ãŒïŒïŒ ã«è¿ãããšã奜ãŸããã ãã®ãããªããã²ã³åéç²åãå«æããä¹³å€ã§
ã¯ãå¢æå¹çãé«ããæã«è¡šé¢æœååä¹³å€ãåŸã
ã«é©ããŠããã äžèšã®åŠãããã²ã³åéçµæãæããããã²ã³
åéç²åã¯ãäŸãã°è©²ç²åäžã«ã³ã¢ãšã·ãšã«ãæ§
æããæè¬ã³ã¢ïŒã·ãšã«åã®ããã²ã³åéç²åãš
ããŠåœ¢æãããããšãã§ããããæŽã«è©²ç²åã®å
éšã®ã³ã¢ãæ²åéå«æçã®ç°ãªãïŒå±€ä»¥äžã®å±€ãš
ããŠåœ¢æãããŠãããããã®ãããªå Žåãæ²åé
å«æçã®é«ãå±€ãšå«æçã®äœãå±€ã®å«æçã®å·®ã¯
ã·ã€ãŒããªå¢çãæãããã®ã§ãããããŸãå¢ç
ã®å¿ ãããæçœã§ã¯ãªãé£ç¶ããŠå€åãããã®ã§
ãã€ãŠãããã äžèšã®ããã²ã³åéç²åã«ãããæ²åéã®ååž
ç¶æ ã¯ãåçš®ã®ç©çç枬å®æ³ã«ãã€ãŠæ€ç¥ããã
ãšãã§ããäŸãã°æ¥æ¬åçåŠäŒãæå56幎床幎次
倧äŒè¬æŒèŠæšéã«èšèŒãããŠãããããªäœæž©ã§ã®
ã«ãããã»ã³ã¹ã枬å®ããããšã«ãã€ãŠã調ã¹ã
ããšãã§ããã äžèšæ¬çºæã®ã³ã¢ïŒã·ãšã«åããã²ã³åéç²å
ã¯ãæ²åéãå«ãããã²ã³åéãããªãã³ã¢ãšã
該ã³ã¢ã被èŠããæ²åéã®å«æçãäžèšã³ã¢ã«ã
ããå«æçããäœãããã²ã³åéãããªãã·ãšã«
ãšãããªãããã€äžèšã·ãšã«ã®åãã0.001ã
0.1ÎŒã§ããããã²ã³åéç²åã§ããã ãããŠæ¬çºæã®å¥œãŸããããã²ã³åéç²åã®å®
æœæ æ§ãšããŠã¯ãäžèšã³ã¢ã®ããã²ã³åéçµæã
æ²åéãïŒã15ã¢ã«ïŒ ãå«ãããã²ã³åéã§ãã
ãŸãäžèšã·ãšã«éšã¯æ²åéãïŒãïŒã¢ã«ïŒ ãå«ã
ããã²ã³åéã§ããããšã§ããããŸãåèšã·ãšã«
éšãšã³ã¢éšã®æ²åéå«æçã®å·®ã¯ïŒã¢ã«ïŒ 以äžã
ãããšã奜ãŸãããæ¬çºæã«ãããããã²ã³åé
ç²åã¯ãäžèšæ²åé以å€ã®ããã²ã³åéçµæã¯äž»
ãšããŠèåéã§ããããšã奜ãŸããããæ¬çºæã®
å¹æãæããªãéãã«ãããŠå¡©åéãå«ãã§ãã
ãã æ¬çºæã«ä¿ãããã²ã³åéç²åã®å¹³åæ²åéå«
æçã¯0.5ã¢ã«ïŒ ã15ã¢ã«ïŒ ã奜ãŸãããããã«
奜ãŸããã¯ïŒã¢ã«ïŒ ã12ã¢ã«ïŒ ã®ç¯å²ã§ããã æ¬çºæã«ä¿ãããã²ã³åéç²åã®åœ¢ç¶ã¯ãäŸã
ã°å é¢äœãå «é¢äœãååé¢äœãæ¿ç¶äœãçç¶äœã®
äœãã§ãããããŸããããå皮圢ç¶ã®æ··åããã
ã®ã§ãã€ãŠãããããå «é¢äœãååé¢äœã®ç²åã
奜ãŸããã æ¬çºæã®ç¹å®ã®å±€æ§æãæããããã²ã³åéç²
åãå«æããããã²ã³åéä¹³å€ã¯ãååæ£æ§ã®ã
ãã²ã³åéç²åãã³ã¢ãšããŠãããã«ã·ãšã«ã被
èŠããããšã«ãã€ãŠè£œé ããããšãã§ããã åèšã³ã¢ã®ååæ£æ§ã®ããã²ã³åéç²åã補é
ããã«ã¯ãPAgãäžå®ã«ä¿ã¡ãªããããã«ãžãš
ããæ³ã«ããææã®å€§ããã®ç²åãåŸãããšãã§
ããããŸãé«åºŠã®ååæ£æ§ã®ããã²ã³åéä¹³å€
ã¯ãç¹éæ54â48521å·å ¬å ±ã«èšèŒãããŠããæ¹
æ³ãé©çšããããšãã§ãããäŸãã°æ²èåã«ãªãŠ
ã âãŒã©ãã³æ°Žæº¶æ¶²ãšã¢ã³ã¢ãã¢æ§ç¡é žé氎溶液
ãšãããã²ã³åéçš®ç²åãå«ããŒã©ãã³æ°Žæº¶æ¶²äž
ã«æ·»å é床ãæéã®é¢æ°ãšããŠå€åãããŠæ·»å ã
ãæ¹æ³ã«ãã€ãŠè£œé ããããã®éæ·»å é床ã®æé
é¢æ°ãpHãpAgã枩床çãé©å®ã«éžæããããš
ã«ããé«åºŠã®ååæ£æ§ã®ããã²ã³åéç²åãåŸã
ããšãã§ããã 次ã«ã³ã¢ã被èŠããã·ãšã«ã®åãã¯ã³ã¢ã®å¥œãŸ
ããçŽ è³ªãé èœãã¬åãã§ããããã€éã«ã³ã¢ã®
奜ãŸãããããçŽ è³ªãé èœããã«è¶³ãåã¿ã§ãªã
ãã°ãªããªããå³ã¡ãåã¿ã¯ãã®ãããªäžéãšäž
éãšã§éãããçãç¯å²ã«éå®ãããããã®ãã
ãªã·ãšã«ã¯å¯æº¶æ§ããã²ã³ååç©æº¶æ¶²ãšå¯æº¶æ§é
塩溶液ãããã«ãžãšããæ³ã«ãã€ãŠååæ£æ§ã®ã
ãã²ã³åéç²åã®ã³ã¢ã«æ²ç©ãããŠåœ¢æãããã
ãšãã§ããã äžèšã®ã³ã¢ïŒã·ãšã«åããã²ã³åéç²åã®è£œé
æ¹æ³ã«ã€ããŠã¯ãäŸãã°è¥¿ç¬ç¹èš±ç¬¬1169290å·ã
è±åœç¹èš±ç¬¬1027146å·åæ现æžãç¹éæ57â
154232å·ãç¹å ¬æ51â1417å·åå ¬å ±çã«ãèšèŒã
ããŠããã æ¬çºæã§ã¯ãæ¬çºæã«ä¿ãããã²ã³åéç²åã®
補é éçšã«ãããŠãäŸãã°ã«ãããŠã å¡©ãäºé
å¡©ãéå¡©ãã¿ãªãŠã å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã
ãã®é¯å¡©ãããžãŠã å¡©ãŸãã¯ãã®é¯å¡©çãå ±åã
ããŠãããã æ¬çºæã«ãããŠã¯ãæ¬çºæã«ä¿ãå¢æè²çŽ ãå
èšã«ãã補é ãããååæ£æ§ã®ããã²ã³åéç²å
ãå«æããããã²ã³åéä¹³å€ã«æ·»å ããããšã«ã
ãåå å¢æãè¡ãªããããäžèšå¢æè²çŽ ã®æ·»å æ
æãšããŠã¯ãããã²ã³åéä¹³å€ã®ååŠçæïŒç¬¬ïŒ
çæãšãåŒã°ããïŒéå§æãçæé²è¡äžãçæçµ
äºããŸãã¯ä¹³å€å¡åžã«å ç«ã€é©åãªææçäœãã®
å·¥çšã§ãå·®æ¯ããªãã ãŸãæ¬çºæã®åèšåäžè¬åŒã§ç€ºãããå¢æè²çŽ
ãäžèšåçä¹³å€ã«æ·»å ããæ¹æ³ãšããŠã¯ãåŸæ¥ã
ãææ¡ãããŠããçš®ã ã®æ¹æ³ãé©çšã§ãããäŸã
ã°ç±³åœç¹èš±ç¬¬3469987å·ã«èšèŒãããåŠãå¢æè²
çŽ ãæ®çºæ§ææ©æº¶åªã«æº¶è§£ãã該溶液ã芪氎æ§ã³
ãã€ãäžã«åæ£ãããã®åæ£ç©ãä¹³å€ã«æ·»å ãã
æ¹æ³ã«ããè¡ãªã€ãŠãããããŸãããã«æ¬çºæã®
å¢æè²çŽ ã¯ãåã ã«åäžãŸãã¯ç°ãªã溶åªã«æº¶è§£
ããä¹³å€ã«æ·»å ããåã«ããããã®æº¶æ¶²ãæ··åã
ãããå¥ã ã«æ·»å ããããšãã§ããã æ¬çºæã«ä¿ãå¢æè²çŽ ãããã²ã³åéåçä¹³å€
ã«æ·»å ãããšãã®è²çŽ ã®æº¶åªãšããŠã¯ãäŸãã°ã¡
ãã«ã¢ã«ã³ãŒã«ããšãã«ã¢ã«ã³ãŒã«ãã¢ã»ãã³ç
ã®æ°Žæ··åæ§ææ©çšåªã奜ãŸããçšããããã æ¬çºæã«ä¿ãå¢æè²çŽ ãããã²ã³åéä¹³å€ã«æ·»
å ããããå Žåã®æ·»å éã¯ãããã²ã³åéïŒã¢ã«
åœãïŒÃ10-5ã¢ã«ãªãã2.5Ã10-2ã¢ã«ã奜ãŸã
ãã¯1.0Ã10-4ã¢ã«ãªãã1.0Ã10-3ã¢ã«ã§ããã
ãããŠæ¬çºæã«ä¿ãå¢æè²çŽ ã®å¥œãŸãã䜿çšæ¯ç
ã¯ãããããåèšäžè¬åŒãããããããã³
ããã®é ã«åŸã€ãŠ0.1ãïŒïŒïŒïŒ0.1ãïŒã®ç¯å²
ã§ããã æ¬çºæã«ä¿ãå¢æè²çŽ ã¯ãæŽã«ä»ã®å¢æè²çŽ ãŸ
ãã¯åŒ·è²å¢æå€ãšäœµçšããããšãã§ããã æ¬çºæã«ããããã²ã³åéç²åã¯äžè¬çã«æœã
ããåçš®ã®ååŠå¢ææ³ãæœãããšãã§ãããããª
ãã¡æŽ»æ§ãŒã©ãã³ïŒæ°Žæº¶æ§éå¡©ã氎溶æ§çœéå¡©ã
氎溶æ§ãã©ãžãŠã å¡©ã氎溶æ§ããžãŠã å¡©ã氎溶æ§
ã€ãªãžãŠã å¡©çã®è²Žéå±å¢æå€ïŒç¡«é»å¢æå€ïŒã»
ã¬ã³å¢æå€ïŒããªã¢ãã³ãå¡©å第ïŒé«çã®éå å¢
æå€çã®ååŠå¢æå€çã«ããåç¬ã«ããããã¯äœµ
çšããŠååŠå¢æããããšãã§ããã æ¬çºæã«ãããŠãäžèšã®ç¡«é»å¢æå€ãšããŠã¯å ¬
ç¥ã®ãã®ãçšããããšãã§ãããäŸãã°ããªç¡«é ž
å¡©ãã¢ãªã«ããªã«ã«ãããããªå°¿çŽ ãã¢ãªã«ã€ãœ
ãã¢ã·ã¢ããŒããã·ã¹ãã³ãïœâãã«ãšã³ããªã¹
ã«ãã³é žå¡©ãããŒããã³ãªã©ãæããããããã®
ä»ç±³åœç¹èš±ç¬¬1574944å·ãå第2410689å·ãå第
2278947å·ãå第2728668å·ãå第3501313å·ãå
第3656955å·åæ现æžããã€ãç¹èš±ç¬¬1422869ãæ¥
æ¬ç¹èš±æ56â24937å·ãç¹éæ55â45016å·å ¬å ±ç
ã«èšèŒãããŠããç¡«é»å¢æå€ãçšããããšãã§ã
ããç¡«é»å¢æå€ã®æ·»åéã¯ãä¹³å€ã®æ床ãå¹æç
ã«å¢å€§ãããã«ååãªéã§ããããã®éã¯ããã
ãã·ã¢ã¶ã€ã³ãã³ã®æ·»å éãPHã枩床ãããã²ã³
åéç²åã®å€§ãããªã©çš®ã ã®æ¡ä»¶ã®äžã§çžåœã®ç¯
å²ã«ããã€ãŠå€åããããç®å®ãšããŠã¯ããã²ã³
åéïŒã¢ã«åœãçŽ10-7ã¢ãªãçŽ10-1ã¢ã«çšåºŠã奜
ãŸããã æ¬çºæã«ãããŠã¯ãç¡«é»å¢æã®ä»£ãã«ã»ã¬ã³å¢
æãçšããããšãã§ããããã»ã¬ã³å¢æå€ã¯ãã¢
ãªã«ã€ãœã»ã¬ãã·ã¢ããŒãã®åŠãèèªæã€ãœã»ã¬
ãã·ã¢ããŒãé¡ãã»ã¬ãå°¿çŽ é¡ãã»ã¬ãã±ãã³
é¡ãã»ã¬ãã¢ããé¡ãã»ã¬ãã«ã«ãã³é žé¡ããã³
ãšã¹ãã«é¡ãã»ã¬ãããªã¹ããšãŒãé¡ããžãšãã«
ã»ã¬ãã€ãããžãšãã«ãžã»ã¬ãã€ãçã®ã»ã¬ãã€
ãé¡ãªã©ãçšããããšãã§ãããããã®å ·äœäŸã¯
ç±³åœç¹èš±ç¬¬1574944å·ãå第1602592å·ãå第
1623499å·æ现æžã«èšèŒãããŠããã æ·»å éã¯ç¡«é»å¢æå€ãšåæ§ã«åºãç¯å²ã«ããã€
ãŠå€åããããç®å®ãšããŠã¯ããã²ã³åéïŒã¢ã«
åœãçŽ10-7ã¢ã«ãã10-3ã¢ã«çšåºŠã奜ãŸããã æ¬çºæã«ãããŠãéå¢æå€ãšããŠã¯éã®é žåæ°
ãïŒïŒäŸ¡ã§ãïŒïŒäŸ¡ã§ãããå€éã®éååç©ãçš
ããããã代衚çãªäŸãšããŠã¯å¡©åéé žå¡©ãã«ãª
ãŠã ã¯ãããªãŒã¬ãŒãããªãŒãªãã¯ããªã¯ãã©ã€
ããã«ãªãŠã ãªãŒãªãã¯ããªã·ã¢ããŒããã«ãªãŠ
ã ãšãŒããªãŒã¬ãŒããããã©ã·ã¢ããªãŒãªãã¯ã¢
ã·ããã¢ã³ã¢ããŠã ãªãŒããªãã·ã¢ããŒããããª
ãžã«ããªã¯ãããŽãŒã«ããªã©ãæããããã éå¢æå€ã®æ·»å éã¯çš®ã ã®æ¡ä»¶ã«ããç°ãªãã
ç®å®ãšããŠã¯ããã²ã³åéïŒã¢ã«åœãçŽ10-7ã¢ã«
ãã10-1ã¢ã«ãŸã§ã®ç¯å²ã奜ãŸããã æ¬çºæã«ãããããã²ã³åéç²åã®å¢ææ³ã«ã¯
ä»ã®è²Žéå±ãäŸãã°çœéããã©ãžãŠã ãã€ãªãžãŠ
ã ãããžãŠã ã®ãããªéå±ãããã¯ãããã®å¡©ã«
ããå¢ææ³ã䜵çšã§ããã æ¬çºæã«ãããŠã¯ãããã«éå å¢æã䜵çšãã
ããšãå¯èœã§ãããéå å€ãšããŠã¯ç¹ã«å¶éã¯ãª
ããå ¬ç¥ã®å¡©å第äžã¹ãºãäºé žåããªå°¿çŽ ããã
ã©ãžã³èªå°äœãã·ã©ã³ååç©ãæããããã éå å¢æãè¡ãªãææã¯ããã²ã³åéç²åã®æ
é·äžã«è¡ãªãããç¡«é»å¢æããã³éå¢æã®çµäºåŸ
ã«è¡ãªãããšã奜ãŸããã ãŸããæ¬çºæã«ãããŠã¯åèšã®æ¬çºæã«ä¿ãã
ãã²ã³åéç²åã¯ãããã²ã³åé溶å€ã®ååšäžã«
ååŠçæãè¡ãªãããšã«ãã€ãŠèããé«æ床åã
éæããããããšãã§ããã æ¬çºæã§çšããããããã²ã³åé溶å€ãšããŠã¯
ç±³åœç¹èš±ç¬¬3271157å·ãå第3531289å·ãå第
3574628å·ãç¹éæ54â1019å·ãå54â158917å·
çã«èšèŒããã(a)ææ©ããªãšãŒãã«é¡ãç¹éæ53
â82408å·ãå55â77737å·ãå55â2982å·çã«èš
èŒããã(b)ããªå°¿çŽ èªå°äœãç¹éæ53â144319å·
ã«èšèŒããã(c)é žçŽ ãŸãã¯ç¡«é»ååãšçªçŽ ååãš
ã«ã¯ããŸããããªã«ã«ããã«åºãæããããã²ã³
åé溶å€ãç¹éæ54â100717å·ã«èšèŒããã(d)ã€
ãããŸãŒã«é¡ã(e)äºç¡«é žå¡©ã(f)ããªã·ã¢ããŒãç
ãæããããã 以äžã«ãããã®å ·äœçååç©ã瀺ãã (e) K2SO3 (f) NH4SCN KSCN ç¹ã«å¥œãŸãã溶å€ãšããŠã¯ãããªã·ã¢ããŒãã
ãã³ããã©ã¡ãã«ããªå°¿çŽ ãããããŸãçšããã
ã溶å€ã®éã¯çš®é¡ã«ãã€ãŠãç°ãªãããäŸãã°ã
ãªã·ã¢ããŒãã®å Žåã奜ãŸããéã¯ããã²ã³åé
ïŒã¢ã«åœãïŒmgãïŒïœã®ç¯å²ã§ããã æ¬çºæã®ããã²ã³åéç²åã«ã¯ããã®è£œé å·¥
çšãä¿åäžãããã¯çŸååŠçäžã®ãã¶ãã®çºçã
é²æ¢ãããããã¯åçæ§èœãå®å®åãããç®çã§
ååŠçæã®çµäºæãçš®ã ã®ååç©ãå«æãããŠã
ããã äŸãã°ã¢ãŸãŒã«é¡ãäŸãã°ãã³ãŸãã¢ãŸãªãŠã
å¡©ããããã€ã³ããŸãŒã«é¡ãããããã³ãºã€ãã
ãŸãŒã«é¡ãã¯ãããã³ãºã€ãããŸãŒã«é¡ãããã¢
ãã³ãºã€ãã¿ãŸãŒã«é¡ãã¡ã«ã«ãããã¢ãŸãŒã«
é¡ãã¡ã«ã«ãããã³ãºã€ãããŸãŒã«é¡ãã¢ããã
ãªã¢ãŸãŒã«é¡ããã³ãŸããªã¢ãŸãŒã«é¡ããããã
ã³ãŸããªã¢ãŸãŒã«é¡ãã¡ã«ã«ããããã©ãŸãŒã«é¡
ïŒç¹ã«ïŒâããšãã«âïŒâã¡ã«ã«ããããã©ãŸãŒ
ã«ïŒãªã©ããŸãã¡ã«ã«ããããªããžã³é¡ãã¡ã«ã«
ããããªã¢ãžã³é¡ãäŸãã°ãªããµãŸãªã³ããªã³ã®
ãããªããªã±ãååç©ãæŽã«ã¯ãã³ãŒã³ããªã¹ã«
ãã€ã³é žããã³ãŒã³ã¹ã«ãã€ã³é žããã³ãŒã³ã¹ã«
ããªã³é žã¢ããããã€ããããã³èªå°äœãã¢ãã
ããšããŒã«èªå°äœã没é£åé žèªå°äœãã¢ã¹ã³ã«ã
ã³é žèªå°äœçã®ãããªã«ããªé²æ¢å€ãŸãã¯å®å®å€
ãšããŠç¥ãããå€ãã®ååç©ãå ããããšãã§ã
ãããããã®è¬å€ã¯ååŠçææãæãã¯å¡åžåã«
æ·»å ããã®ã奜ãŸããã æ¬çºæã®ããã²ã³åéä¹³å€ã®ãã€ã³ããŒãšããŠ
ã¯ãŒã©ãã³ãå§ããçš®ã ã®èŠªæ°Žæ§ã³ãã€ããçšã
ãããããŒã©ãã³ãšããŠã¯ãŒã©ãã³ã®ã¿ãªããèª
å°äœãŒã©ãã³ãå å«ãããèªå°äœãŒã©ãã³ãšããŠ
ã¯ããŒã©ãã³é žç¡æ°Žç©ãšã®åå¿çæç©ããŒã©ãã³
ãšã€ãœã·ã¢ããŒããšã®åå¿çæç©ãæãã¯ãŒã©ã
ã³ãšæŽ»æ§ããã²ã³ååãæããååç©ãšã®åå¿ç
æç©çãå å«ããããããã«ãŒã©ãã³ãšã®åå¿ã«
çšããããé žç¡æ°Žç©ãšããŠã¯ãäŸãã°ç¡æ°Žãã¬ã€
ã³é žãç¡æ°Žãã¿ã«é žãç¡æ°Žå®æ¯éŠé žãç¡æ°Žé ¢é žã
ç¡æ°Žã€ãµãé žãç¡æ°Žã³ãã¯é žçãå«ãŸããã€ãœã·
ã¢ããŒãååç©ãšããŠã¯ãäŸãã°ããšãã«ã€ãœã·
ã¢ããŒããïœâããã¢ããšãã«ã€ãœã·ã¢ããŒãã
ïœâã¯ããããšãã«ã€ãœã·ã¢ããŒããïœâããªã«
ã€ãœã·ã¢ããŒããïœâãããããšãã«ã€ãœã·ã¢ã
ãŒãããããã«ã€ãœã·ã¢ããŒãçãæããããšã
ã§ããã æŽã«æŽ»æ§ããã²ã³ååãæããååç©ãšããŠã¯
äŸãã°ãã³ãŒã³ã¹ã«ããã«ã¯ãã©ã€ããïœâã¡ã
ãã·ãã³ãŒã³ã¹ã«ããã«ã¯ãã©ã€ããïœâããšã
ãã·ãã³ãŒã«ã¹ã«ããã«ã¯ãã©ã€ããïœâããã¢
ãã³ãŒã³ã¹ã«ããã«ã¯ãã©ã€ããïœâãã«ãšã³ã¹
ã«ããã«ã¯ãã©ã€ããïœâããããã³ãŒã³ã¹ã«ã
ãã«ã¯ãã©ã€ããïœâã¹ã«ããã³ãŸã€ã«ãžã¯ãã©
ã€ããããã¿ã¬ã³âβâã¹ã«ããã«ã¯ãã©ã€ãã
ïœâã¯ãããã³ãŒã³ã¹ã«ããã«ã¯ãã©ã€ããïŒâ
ãããâïŒâã¢ãããã³ãŒã«ã¹ã«ããã«ã¯ãã©ã€
ããïŒâã«ã«ããã·âïŒâããã¢ãã³ãŒã³ã¹ã«ã
ãã«ã¯ãã©ã€ããïœâã«ã«ããã·ãã³ãŒã³ã¹ã«ã
ãã«ã¯ãã©ã€ããïŒâã¢ããâïŒâã¡ãã«ãã³ãŒ
ã³ã¹ã«ããã«ã¯ãã©ã€ãããã¿ãªã«ã¯ãã©ã€ãã
ïœâããããã³ãŸã€ã«ã¯ãã©ã€ãããã³ãŸã€ã«ã¯
ãã©ã€ãããšãã«ã¯ããã«ãŒãããŒããããã€ã«
ã¯ãã©ã€ãçãå å«ãããã ãŸãããã²ã³åéä¹³å€ãäœæããããã«èŠªæ°Žæ§
ã³ãã€ããšããŠãåèšã®åŠãèªå°äœãŒã©ãã³ãã
ã³éåžžã®åççšãŒã©ãã³ã®ä»ãå¿ èŠã«å¿ããŠã³ã
ã€ãç¶ã¢ã«ããã³ãå¯å€©ãã¢ã©ãã¢ãŽã ãããã¹
ãã©ã³ãã¢ã«ã®ã³é žãäŸãã°ã¢ã»ãã«å«é19ã26
ïŒ ã«ãŸã§å æ°Žå解ãããã»ã«ããŒã¹ã¢ã»ããŒãã®
åŠãã»ã«ããŒã¹èªå°äœãããªã¢ã¯ãªã«ã¢ãããã€
ããåããªã¢ã¯ãªã«ã¢ãããã«ãŒã€ã³ãäŸãã°ã
ãã«ã¢ã«ã³ãŒã«ãŒããã«ã·ã¢ãã¢ã»ããŒãã³ããª
ããŒã®åŠããŠã¬ã¿ã³ã«ã«ãã³é žåºãŸãã¯ã·ã¢ãã¢
ã»ãã«åºãå«ãããã«ã¢ã«ã³ãŒã«ããªããŒãããª
ããã«ã¢ã«ã³ãŒã«ãŒããªããã«ãããªãã³ãå æ°Ž
å解ããªããã«ã¢ã»ããŒããèçœè³ªãŸãã¯é£œåã¢
ã·ã«åèçœè³ªãšããã«åºãæããã¢ãããŒãšã®é
åã§åŸãããããªããŒãããªããã«ããªãžã³ãã
ãªããã«ã¢ãã³ãããªã¢ãããšãã«ã¡ã¿ã¯ãªã¬ãŒ
ããããªãšãã¬ã³ã€ãã³çã䜿çšããããšãã§ã
ãã æ¬çºæã®ããã²ã³åéä¹³å€ã«ã¯ãå¡åžå©å€ã垯
é»é²æ¢ãã¹ããªæ§æ¹è¯ãä¹³ååæ£ãæ¥çé²æ¢ãã
ã³åçæ§æ¹è¯ïŒäŸãã°çŸåä¿é²ã硬調åãå¢æïŒ
ãªã©çš®ã ã®ç®çã§çš®ã ã®å ¬ç¥ã®çé¢æŽ»æ§å€ãå«ã
ã§ãããã ããªãã¡ãç±³åœç¹èš±ç¬¬2240472å·ãåç2831766
å·ãå第3158484å·ãå第3210191å·ãå第
3294540å·ãå第3507660å·ãè±åœç¹èš±ç¬¬1012495
å·ãå第1022878å·ãå第1179290å·ãå第
1198450å·ãç±³åœç¹èš±ç¬¬2739891å·ãå第2823123
å·ãå第1179290å·ãå第1198450å·ãå第
2739891å·ãå第2823123å·ãå第3068101å·ãå
第3415649å·ãå第3666478å·ãå第3756828å·ã
è±åœç¹èš±ç¬¬1397218å·ãå第3113816å·ãå第
3411413å·ãå第3473174å·ãå第3345974å·ãå
第3726683å·ãå第3843368å·ããã«ã®ãŒç¹èš±ç¬¬
731126å·ãè±åœç¹èš±ç¬¬1138514å·ãå第1159825
å·ãå第1374780å·ãç±³åœç¹èš±ç¬¬2271623å·ãå第
2288226å·ãå第2944900å·ãå第3235919å·ãå
第3671247å·ãå第3772021å·ãå第3589906å·ã
å第3666478å·ãå第3754924å·ã西ç¬ç¹èš±åºé¡
OLS1961683å·åæ现æžããã³ç¹éæ50â117414
å·ãå50â59025å·ãç¹å ¬æ40â378å·ãå40â
379å·ãå43â13822å·åå ¬å ±ã«èšèŒãããŠããã
äŸãã°ãµããã³ïŒã¹ããã€ãç³»ïŒãã¢ã«ãã¬ã³ãª
ããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³ãŒ
ã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ïŒããªãããã¬ã³ã°
ãªã³ãŒã«çž®åç©ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«ã
ã«ãŸãã¯ã¢ã«ãã«ã¢ãªãŒã«ãšãŒãã«ããªãšãã¬ã³
ã°ãªã³ãŒã«ãšã¹ãã«é¡ãããªãšãã¬ã³ã°ãªã³ãŒã«
ãœã«ãã¿ã³ãšã¹ãã«é¡ãããªã¢ã«ãã¬ã³ã°ãªã³ãŒ
ã«ã¢ã«ãã«ã¢ãã³ãŸãã¯ã¢ããé¡ãã·ãªã³ãŒã³ã®
ããªãšãã¬ã³ãªããµã€ãä»å ç©é¡ïŒãã°ãªã·ããŒ
ã«èªå°äœïŒäŸãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»
ãªããã¢ã«ãã«ããšããŒã«ããªã°ãªã»ãªãïŒãå€
䟡ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«
ãšã¹ãã«é¡ãåãããŠã¬ã¿ã³é¡ãŸãã¯ãšãŒãã«é¡
ãªã©ã®éã€ãªã³æ§çé¢æŽ»æ§å€ãããªãã«ããã€ã
ç³»ãµããã³ãã¢ã«ãã«ã«ã«ãã³é žå¡©ãã¢ã«ãã«ã
ã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬ã³ã¹ã«
ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¢ã«ãã«
ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«ââã¢ã«ãã«ã¿
ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«é¡ãã¹ã«ãã¢
ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«ãšãŒ
ãã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãªã³é žãšã¹
ãã«é¡ãªã©ã®ãããªã«ã«ããã·ãã¹ã«ãåºããã¹
ãåºãç¡«é žãšã¹ãã«åºããªã³é žãšã¹ãã«åºçã®é ž
æ§åºãå«ãã¢ããªã³çé¢æŽ»æ§å€ãã¢ããé žé¡ãã¢
ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ããã¢ã«ãã«ç¡«é ž
ãŸãã¯ãªã³é žãšã¹ãã«é¡ãã¢ã«ãã«ãã¿ã€ã³é¡ã
ã¢ãã³ã€ããé¡ãã¢ãã³ãªãã·ãé¡ãªã©ã®äž¡æ§ç
é¢æŽ»æ§å€ãã¢ã«ãã«ã¢ãã³å¡©é¡ãèèªææãã¯è³
éŠæ第ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããªãžãŠã ãã€ã
ããŸãªãŠã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©é¡
ããã³èèªæãŸãã¯è€çŽ ç°ãå«ãã¹ã«ãããŠã ãŸ
ãã¯ã¹ã«ãããŠã å¡©é¡ãªã©ã®ã«ããªã³çé¢æŽ»æ§å€
ãçšããããšãã§ããã æ¬çºæã®ããã²ã³åéä¹³å€ã«ã¯ãçŸåä¿é²å€ãš
ããŠãåèšã®çé¢æŽ»æ§å€ã®ä»ã«è¥¿ç¬ç¹èš±åºé¡
ïŒOLSïŒ2002871å·ãå第2445611å·ãå第
2360878å·ãè±åœç¹èš±ç¬¬1352196å·åæ现æžãªã©ã«
èšèŒãããŠããã€ãããŸãŒã«é¡ãããªãšãŒãã«
é¡ãã»ã¬ããšãŒãã«é¡ãªã©ãå«æããŠãããã ãŸãæ¬çºæã®ããã²ã³åéä¹³å€ãã«ã©ãŒçšã®æ
å ææã«é©çšããã«ã¯ãæ¬çºæã«ä¿ãç·ææ§ã®ã
ãã²ã³åéä¹³å€ãèµ€ææ§ããã³éææ§ã«èª¿ç¯ãã
ãããã²ã³åéä¹³å€ã«ããŒã³ã¿ãã·ã¢ã³ããã³ã€
ãšããŒã«ãã©ãŒãããããçµåãããŠå«æããã
ããªã©ã«ã©ãŒçšæå ææã«äœ¿çšãããææ³ããã³
çŽ æãå åœããã°ãããã«ãã©ãŒã¯ååäžã«ãã©
ã¹ãåºãšåŒã°ããçæ°Žåºãæããéæ¡æ£æ§ã®ãã®
ãæãŸãããã«ãã©ãŒã¯éã€ãªã³ã«å¯ŸãïŒåœéæ§
ãããã¯ïŒåœéæ§ã®ã©ã¡ãã§ãããããŸãè²è£æ£
ã®å¹æããã€ã«ã©ãŒãã«ãã©ãŒãæãã¯çŸåã«ãš
ããªã€ãŠçŸåæå¶å€ãæŸåºããã«ãã©ãŒïŒããã
ãDIRã«ãã©ãŒïŒãå«ãã§ããããæŽã«ã«ãã©ãŒ
ã¯ã«ãããªã³ã°åå¿ã®çæç©ãç¡è²ã§ãããããª
ã«ãã©ãŒã§ãããã é»è²çºè²ã«ãã©ãŒãšããŠã¯å ¬ç¥ã®ééã±ãã¡ã
ã¬ã³ç³»ã«ãã©ãŒãçšããããšãã§ããããããã®
ãã¡ãã³ãŸã€ã«ã¢ã»ãã¢ããªãç³»ããã³ãããã€
ã«ã¢ã»ãã¢ããªãç³»ååç©ã¯æå©ã§ãããçšãåŸ
ãé»è²çºè²ã«ãã©ãŒã®å ·äœäŸã¯ãç±³åœç¹èš±ç¬¬
2875057å·ãå第3265506å·ãå第3408194å·ãå
第3551155å·ãå第3582322å·ãå第3725072å·ã
å第3891445å·ã西ç¬ç¹èš±ç¬¬1547868å·ã西ç¬ç¹èš±
åºé¡ïŒOLSïŒ2213461å·ãå第2219917å·ãå第
2261361å·ãå第2414006å·ãå第2263875å·ãªã©
ã«èšèŒããããã®ã§ããã ããŒã³ã¿çºè²ã«ãã©ãŒãšããŠã¯ãã©ãŸãã³ç³»å
åç©ãã€ã³ããŸãã³ç³»ååç©ãã·ã¢ãã¢ã»ãã«å
åç©ãªã©ãçšããããšãã§ããç¹ã«ãã©ãŸãã³ç³»
ååç©ã¯æå©ã§ãããçšãåŸãããŒã³ã¿çºè²ã«ã
ã©ãŒã®å ·äœäŸã¯ãç±³åœç¹èš±ç¬¬2600788å·ãå第
2983608å·ãå第3062653å·ãå第3127269å·ãå
第3311476å·ãå第3419391å·ãå第3519429å·ã
å第3558319å·ãå第3582322å·ãå第3615506å·ã
å第3834908å·ãå第3891445å·ã西ç¬ç¹èš±ç¬¬
1810464å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2408665å·ã
å第2417945å·ãå第2418959å·ãå第2424467å·ã
ç¹å ¬æ40â6031å·ãªã©ã«èšèŒã®ãã®ã§ããã ã·ã¢ã³çºè²ã«ãã©ãŒãšããŠã¯ããšããŒã«ç³»åå
ç©ãããããŒã«ç³»ååç©ãªã©ãçšããããšãã§ã
ãããã®å ·äœäŸã¯ç±³åœç¹èš±ç¬¬2369929å·ãå第
2434272å·ãå第2474293å·ãå第2521908å·ãå
第2895826å·ãå第3034892å·ãå第3311476å·ã
å第3458315å·ãå第3476563å·ãå第3583971å·ã
å第3591383å·ãå第3767411å·ã西ç¬ç¹èš±åºé¡
ïŒOLSïŒ2414830å·ãå第2454329å·ãç¹éæ48â
59838å·ã«èšèŒããããã®ã§ããã ã«ã©ãŒãã»ã«ãã©ãŒãšããŠã¯ãäŸãã°ç±³åœç¹èš±
第3476560å·ãå第2521908å·ãå第3034892å·ã
ç¹å ¬æ44â2016å·ãå38â22335å·ãå42â11304
å·ãå44â32461å·ãç¹é¡æ49â98469å·æ现æžã
å50â118029å·æ现æžã西ç¬ç¹èš±åºé¡ïŒOLSïŒ
2418959å·ã«èšèŒã®ãã®ã䜿çšã§ããã DIRã«ãã©ãŒãšããŠã¯ãäŸãã°ç±³åœç¹èš±ç¬¬
3227554å·ãå第3617291å·ãå第3701783å·ãå
第3790384å·ãå第3632345å·ã西ç¬ç¹èš±åºé¡
ïŒOLSïŒ2414006å·ãå第2454301å·ãå第
2454329å·ãè±åœç¹èš±ç¬¬953454å·ãç¹é¡æ50â
146570å·ã«èšèŒããããã®ã䜿çšã§ããã DIRã«ãã©ãŒä»¥å€ã«çŸåã«ãšããªã€ãŠçŸåæå¶
ãæŸåºããååç©ãæå ææäžã«å«ãã§ãããã
äŸãã°ç±³åœç¹èš±ç¬¬3297445å·ãå第3379529å·ã西
ç¬ç¹èš±åºé¡ïŒOLSïŒ2417914å·ã«èšèŒã®ãã®ã䜿
çšã§ããããã®ä»ç¹éæ55â85549å·ãå57â
94752å·ãå56â65134å·ãå56â135841å·ãå54
â130716å·ãå56â133734å·ãå56â135841å·ã
ç±³åœç¹èš±ç¬¬4310618å·ãè±åœç¹èš±ç¬¬2083640å·ããª
ãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒãNo.18360ïŒ1979幎ïŒ
No.14850ïŒ1980幎ïŒãNo.19033ïŒ1980幎ïŒãNo.19146
ïŒ1980幎ïŒãNo.20525ïŒ1981幎ïŒãNo.21728ïŒ1982幎ïŒ
ã«èšèŒãããã«ãã©ãŒã䜿çšããããšãã§ããã äžèšã®ã«ãã©ãŒã¯ãåäžå±€ã«äºçš®ä»¥äžå«ãããš
ãã§ããããŸãåäžã®ååç©ãç°ãªãïŒã€ä»¥äžã®
å±€ã«å«ãã§ãããã ã«ãã©ãŒãããã²ã³åéä¹³å€å±€ã«å°å ¥ããã«ã¯
å ¬ç¥ã®æ¹æ³ãäŸãã°ç±³åœç¹èš±ç¬¬2322027å·ã«èšèŒ
ã®æ¹æ³ãªã©ãçšãããããäŸãã°ãã¿ãŒã«é žã¢ã«
ãã«ãšã¹ãã«ïŒãžããã«ãã¿ã¬ãŒãããžãªã¯ãã«
ãã¿ã¬ãŒããªã©ïŒããªã³é žãšã¹ãã«ïŒãžããšãã«
ããªã¹ããšãŒããããªããšãã«ããªã¹ããšãŒãã
ããªã¯ã¬ãžã«ããªã¹ããšãŒãããžãªã¯ãã«ããã«
ããªã¹ããšãŒãïŒãã¯ãšã³é žãšã¹ãã«ïŒäŸãã°ã¢
ã»ãã«ã¯ãšã³é žããªããã«ïŒãå®æ¯éŠé žãšã¹ãã«
ïŒäŸãã°å®æ¯éŠé žãªã¯ãã«ïŒãã¢ã«ãã«ã¢ããïŒäŸ
ãã°ãžãšãã«ã©ãŠãªã«ã¢ããïŒãªã©ããŸãã¯æ²žç¹
çŽ30âä¹è³150âã®ææ©æº¶åªãäŸãã°é ¢é žãšãã«ã
é ¢é žããã«ã®åŠãäœçŽã¢ã«ãã«ã¢ã»ããŒãããã
ããªã³é žãšãã«ãïŒçŽããã«ã¢ã«ã³ãŒã«ãã¡ãã«
ã€ãœããã«ã±ãã³ãβâãšããã·ãšãã«ã¢ã»ããŒ
ããã¡ãã«ã»ããœã«ãã¢ã»ããŒãçã«æº¶è§£ããã®
ã¡ã芪氎æ§ã³ãã€ãã«åæ£ããããäžèšã®é«æ²žç¹
ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åªãšãæ··åããŠçšããŠã
ããã ã«ãã©ãŒãã«ã«ãã³é žãã¹ã«ããªã³é žã®åŠãé ž
åºãæããå Žåã«ã¯ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãšããŠèŠª
åæ§ã³ãã€ãäžã«å°å ¥ãããã ãããã®ã«ãã©ãŒã¯ãäžè¬ã«ããã²ã³åéä¹³å€
å±€äžã®éïŒã¢ã«åœãïŒÃ10-3ã¢ã«ä¹è³ïŒÃ10-1ã¢
ã«ã奜ãŸããã¯ïŒÃ10-2ã¢ã«ä¹è³ïŒÃ10-1ã¢ã«æ·»
å ãããã æ¬çºæãçšããŠäœãããæå ææã¯è²ã«ããªé²
æ¢å€ãšããŠãã€ããããã³èªå°äœãã¢ããããšã
ãŒã«èªå°äœã没é£åèªå°äœãã¢ã¹ã³ã«ãã³é žèªå°
äœãªã©ãå«æããŠãããããã®å ·äœäŸã¯ç±³åœç¹èš±
第2360290å·ãå第2336327å·ãå第2403721å·ã
å第2418613å·ãå第2675314å· å第2701197å·ã
å第2704713å· å第2728659å·ãå第2732300å·
å第2735765å·ãç¹éæ50â92988å·ãå50â
92989å·ãå50â93928å·ãå50â110337å·ãç¹å ¬
æ50â23813å·çã«èšèŒãããŠããã 垯é»é²æ¢å€ãšããŠã¯ãžã¢ã»ãã«ã»ã«ããŒã¹ãã¹
ãã¬ã³ããŒãã«ãªãã¢ã«ãã«ãªãžãŠã ãã¬ãšãŒã
å ±éåäœãã¹ãã¬ã³âç¡æ°Žãã¬ã€ã³é žå ±éåäœãš
ïœâã¢ãããã³ãŒã³ã¹ã«ãã³é žãšã®åå¿ç©ã®ã¢ã«
ã«ãªå¡©çãæå¹ã§ããããããå€ãšããŠã¯ããªã¡
ã¿ã¢ã¯ãªã«é žã¡ãã«ãããªã¹ãã¬ã³ããã³ã¢ã«ã«
ãªå¯æº¶æ§ããªããŒãªã©ãæããããããŸãæŽã«ã³
ãã€ãç¶é žåçªçŽ ã®äœ¿çšãå¯èœã§ããããŸãèç©
æ§ãåäžããããã«æ·»å ããã©ããã¯ã¹ãšããŠã¯
ã¢ã¯ãªã«é žãšã¹ãã«ãããã«ãšã¹ãã«çãšä»ã®ãš
ãã¬ã³åºãæã€åéäœãšã®å ±éåäœãæããããš
ãã§ããããŒã©ãã³å¯å¡å€ãšããŠã¯ã°ãªã»ãªã³ã
ã°ãªã³ãŒã«ç³»ååç©ãæããããšãã§ããå¢ç²å€
ãšããŠã¯ã¹ãã¬ã³âãã¬ã€ã³é žãœãŒãå ±éåäœã
ã¢ã«ãã«ããã«ãšãŒãã«ãŒãã¬ã€ã³é žå ±éåäœç
ãæããããã äžèšã®ããã«ããŠèª¿æŽãããããã²ã³åéä¹³å€
ãçšããŠäœãããæå ææã®æ¯æäœãšããŠã¯ãäŸ
ãã°ãã©ã€ã¿çŽãããªãšãã¬ã³è¢«èŠçŽãããªãã
ãã¬ã³åæçŽãã¬ã©ã¹çŽãã»ã«ããŒã¹ã¢ã»ããŒ
ããã»ã«ããŒã¹ãã€ãã¬ãŒããããªããã«ã¢ã»ã¿
ãŒã«ãããªãããã¬ã³ãäŸãã°ããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒãçã®ããªãšã¹ãã«ãã€ã«ã ãããªã¹ã
ã¬ã³çãããããããã®æ¯æäœã¯ããããã®æå
ææã®äœ¿çšç®çã«å¿ããŠé©å®éžæãããã ãããã®æ¯æäœã¯ãå¿ èŠã«å¿ããŠäžåŒå å·¥ãæœ
ãããã æ¬çºæã®ããã²ã³åéä¹³å€ãçšããŠäœãããæ
å ææã¯é²å åŸãéåžžçšããããå ¬ç¥ã®æ¹æ³ã«ã
ãçŸååŠçããããšãã§ããã é»çœçŸå液ã¯ãããããã·ãã³ãŒã³é¡ãã¢ãã
ããšããŒã«é¡ãã¢ãããã³ãŒã³é¡çã®çŸåäž»è¬ã
å«ãã¢ã«ã«ãªæº¶æ¶²ã§ããããã®ä»ã¢ã«ã«ãªéå±å¡©
ã®äºç¡«é žå¡©ãçé žå¡©ãéäºç¡«é žå¡©ãèåç©ããã³
æ²åç©çãå«ãããšãã§ããããŸã該æå ææã
ã«ã©ãŒçšã®å Žåã«ã¯éåžžçšããããçºè²çŸåæ³ã§
çºè²çŸåããããšãã§ãããå転æ³ã§ã¯ãŸãé»è²
ãã¬çŸå液ã§çŸåãã次ãã§çœè²é²å ãäžããã
æãã¯ã«ããªå€ãå«æãã济ã§åŠçããæŽã«çºè²
çŸåäž»è¬ãå«ãã¢ã«ã«ãªçŸå液ã§çºè²çŸåããã
åŠçæ¹æ³ã«ã€ããŠã¯ç¹ã«å¶éã¯ãªããããããåŠ
çæ¹æ³ãé©çšã§ããããäŸãã°ãã®ä»£è¡šçãªãã®
ãšããŠã¯ãçºè²çŸååŸãæŒçœå®çåŠçãè¡ãªãå¿
èŠã«å¿ããããã«æ°ŽæŽãå®å®åŠçãè¡ãªãæ¹åŒã
æãã¯çºè²çŸååŸãæŒçœãšå®çãåé¢ããŠè¡ãªã
å¿ èŠã«å¿ããŠãããã«æ°ŽæŽãå®å®åŠçãè¡ãªãæ¹
åŒãé©çšããããšãã§ããã åè¿°ã®ããã²ã³åéä¹³å€ã¯åçæ床ãèããé«
ãããããé«ç §åºŠçæéé²å ã«å¯Ÿããç¹æ§ãæ¹è¯
ããããã€ã«ããªãå°ãªãããå€ãã®æå ææã«
奜ãŸããé©çšãããã äŸãã°æ¬çºæã«ä¿ãæå ææã¯çœé»äžè¬çšã
ã¬ã€çšãã«ã©ãŒçšãèµ€å€çšããã€ã¯ãçšãéè²çŽ
æŒçœæ³çšãå転çšãæ¡æ£è»¢åæ³çšçã®çš®ã ã®çšé
ã®æå ææã«æå¹ã«é©çšããããšãã§ããã 次ã«ãå®æœäŸããããŠæ¬çºæãå ·äœçã«èª¬æã
ãããæ¬çºæã¯ãããã«ãã€ãŠéå®ããããã®ã§
ã¯ãªãã å®æœäŸ ïŒ ç¹éæ57â154232å·å ¬å ±ã«èšèŒãããŠããæ¹æ³
ãšåæ§ã®æ¹æ³ã«åŸã€ãŠãå¹³åç²åŸã0.56ÎŒã®åå
é¢äœçµæ¶ã®ããã²ã³åéç²åãããªãæ²èåéä¹³
å€ïŒæ²åéå«æçïŒã¢ã«ïŒ ãç²åºŠååžïŒ³ïŒïŒ
0.15ïŒã§ãã€ãŠãæ²åéãäžèšããã²ã³åéç²å
äžã«åäžã«ååžããŠããä¹³å€ïŒä¹³å€ïŒ¡ãšããïŒ
ãšãåã0.02ÎŒã®èåéã®ã·ãšã«ã«ãã€ãŠè¢«èŠã
ããŠããã³ã¢ã»ã·ãšã«åèæ²åéä¹³å€ïŒå¹³åç²åŸ
0.58ÎŒãç²åºŠååžïŒ³ïŒïŒ0.14ãæ²åéå«æçïŒ
ã¢ã«ïŒ ïŒïŒä¹³å€ïŒ¢ãšããïŒãšããããã調æŽããã ãã®ããã«ããŠèª¿æŽãããä¹³å€ïŒ¡ããã²ïŒ¢ãå
å²ãã第ïŒè¡šã«ç€ºãããã«åä¹³å€ã«å¯ŸããŠããã
ããæ¬çºæã«ä¿ãå¢æè²çŽ ïŒåèšäžè¬åŒããã
ããããã³ããã§è¡šããããå¢æè²çŽ ïŒãšã
ãªç¡«é žãããªãŠã ãå¡©åéé žãããªã·ã¢ã³é žã¢ã³
ã¢ããŠã ãæ·»å ããããããé©åãªæ¡ä»¶äžã«ååŠ
å¢æããã³åå å¢æãæœããã
ã²ã³åéåçæå ææã«é¢ããæŽã«è©³ããã¯ç·è²
å åã«åå å¢æããæ床ãé«ãããããã€é«ç §åºŠ
çæéé²å ç¹æ§ãæ¹è¯ãããããã²ã³åéåçæ
å ææã«é¢ããã è¿å¹Žãããã²ã³åéåçé¢å ææïŒä»¥äžåã«æ
å ææãšç§°ãïŒã«å¯ŸããèŠè«ããŸããŸãå³ããã
é«å¯åºŠãåªããç²ç¶æ§ãé«é®®éæ§ãäœãã«ããªæ¿
床ããã³ååé«ãå åŠæ¿åºŠçã®åçæ§èœã«å¯ŸããŸ
ããŸãé«æ°Žæºã®èŠæ±ããªãããŠããã ç¹ã«ã¢ãããŠã¢çšã«ã©ãŒæå ææã«ã€ããŠã¯ã
æ®åœ±æè¡ã®é²æ©ã«é¢é£ããŠãã«ã¡ã©ãå°å軜éå
ããæ®åœ±ãç°¡æã§ããããæ®åœ±ã®å€±æã®ãªããã®
ã匷ãèŠæããã€ã€ããååã«å¯Ÿå¿ããŠãäŸãã°
äœç §åºŠäžã§ã®ããããªåçæ®åœ±ãéãåãã®è¢«å
äœã®åããæ¢ããé«éã·ã€ãã¿ãŒäœ¿çšã®æ®åœ±ãå¯
èœãšãããããªæ®åœ±æ¡ä»¶ã®å€åã«å¯ŸããŠèš±å®¹åºŠã®
åºãæå ææã®éçºãäžå±€åŒ·ãåæãããŠããã åšç¥ã®åŠããããã²ã³åéèªèº«ã®åºææå æ³¢é·
åã¯çŽ«å€ç·ãŸãã¯éè²å ã®çæ³¢é·åã«éãããŠã
ãã ãã®åºææå æ³¢é·åã§ã®æ床ã¯äžè¬ã«ããã²ã³
åéä¹³å€ã«ç¡«é»å¢æå€ãéå¢æå€ãéå å¢æå€ç
ã®ååŠç©è³ªãæ·»å ããŠçæããæè¬ååŠå¢æã«ã
ã€ãŠé«ãããããæå æ³¢é·åã¯æ®ãã©å€åããª
ãã æå æ³¢é·åã®æ¡åŒµã¯ä¹³å€ã«å¢æè²çŽ ãæ·»å ãã
ããšã«ãã€ãŠãªããããã®ããšã¯åå å¢æãšããŠ
ç¥ãããŠãããæŽã«æ°çš®ã®å¢æè²çŽ ãããã¯ç¡è²
ã®ååç©ãå ããŠåå å¢æã匷åããããšã¯â匷
è²å¢æâãšåŒã°ããæ¢ã«æ°å€ãã®çµã¿åãããå ±
åãããŠãããåå å¢ææ³¢é·åã§ã®åçæ床ã¯å
å å¢æãããã¯åŒ·è²å¢æå¹æã«ãã€ãŠæ¯é ããã
ã°ããã§ãªããååŠå¢æå¹æã«ãã€ãŠãæ¯é ãã
ãããšãç¥ãããŠãããããããããã«æé©åã
ãããåå å¢ææè¡ã®äž»èŠãªèª²é¡ã§ããã å¢æè²çŽ ã®çµã¿åããã«ãã匷è²å¢æã®æè¡ã«
é¢ããŠã¯äœ¿çšããè²çŽ ãåã«åå æ床ãé«ããã®
ã¿ã§ãªããåå å¢ææ³¢é·åãé©åã§ãããçš®ã ã®
åççšæ·»å å€ãšã®éã§æªãçžäºäœçšããªããä¹³å€
å¡åžåŸãªãã³ã«æå ææãšããŠä¿åäžã§ã®åçç¹
æ§ã®çµæå€åãå°ãªããæŽã«ã¯çŸååŠçåŸã®æå
ææã«è²çŽ æ±æãæ®ããªãçã®è«žæ¡ä»¶ãæºè¶³ãã
å¿ èŠããããããç®çã«å¿ããé©åãªïŒçš®é¡ä»¥äž
ã®å¢æè²çŽ ã®çµã¿åãããèŠãåºãããšã¯å®¹æã§
ãªãããšãç¥ãããŠããã ãããŸã§ã«ã©ãŒæå ææã«ãããŠèµ€è²ãç·è²ã
ãã³éè²ã®åæ³¢é·åã®å ã«æå æ§ãæããåãã
ã²ã³åéä¹³å€å±€ã®ãã¡ãç·è²ã®æ³¢é·åã«æå 床ã
ãããããããªããã²ã³åéä¹³å€å±€ã®åå å¢ææ
è¡ã«ã€ããŠã¯ãäŸãã°ãªããµã«ã«ãã·ã¢ãã³è²çŽ
ãšãã³ãŸã€ãããŸãã«ã«ãã·ã¢ãã³è²çŽ ã®ïŒçš®ã
çµã¿åãããŠäœ¿çšããæè¡ãç¹å ¬æ43â22884å·ã
å45â4511å·ãå45â18433å·ãå45â4936å·ã
å48â25652å·ãå53â12375å·ãå50â34411å·ã
ç¹éæ52â82416å·ãå52â16223å·åå ¬å ±ããã³
ç±³åœç¹èš±ç¬¬3672898å·æ现æžçã«é瀺ãããŠããã ãããã®ç·ææ§åå å¢ææè¡ã¯é©åãªåå æ³¢é·
åãåå å¢æããããšãã§ããåççšæ·»å å€ãç¹
ã«ããŒã³ã¿ã«ãã©ãŒãšã®æªãçžäºäœçšã«ããæžæ
ããã³æ®è²æ§ã®å°ãªãå¢ææè¡ãšããŠè©äŸ¡ãããŠ
ããã ããããªããããããã®å¢ææ¹æ³ã«å¯ŸããŠã¯æŽ
ã«åå æ床ã®å¢å€§ãæåŸ ãããŠããããŸãåæã«
åè¿°ã®åŠãå¢ææ¹æ³ã«ãã€ãŠåŸãããåå æ床ã
ãã€æå ææã«é«ç §åºŠçæéé²å ãè¡ã€ãå Žåã«
ãæ床ãæ倧çºè²æ¿åºŠãã¬ã³ããŸãã¯é調æ§ã®äœ
äžãŸãã¯å£åãã¿ãããªããããªæå ææãæåŸ
ãããŠããã ããã§æ¬çºæã®ç®çã¯ãç·è²å æ³¢é·åã®å ã«å¯Ÿ
ããŠåå æ床ãããé«ããããæå ææãæäŸã
ãããšã«ããããŸãå¥ã®ç®çã¯ãç·è²å ã«å¯ŸããŠ
åå å¢æããããã€é«ç §åºŠçæéé²å ã«å¯Ÿããç¹
æ§ãæ¹è¯ãããæå ææãæäŸããããšã«ããã æ¬çºæè çããäžèšã«å¯Ÿãæ€èšãéããçµæã
æ¯æäœäžã«ãå°ãªããšãïŒå±€ã®ããã²ã³åéä¹³å€
å±€ãæããæå ææã«ãããŠãäžèšããã²ã³åé
ä¹³å€å±€ã«äžèšåŒ(A)ã§ç€ºãããç²åºŠååžãæããå®
質çã«ååæ£æ§ã®ããã²ã³åéç²åãå«æãããŠ
ããããã€è©²ããã²ã³åéç²åãäžèšäžè¬åŒ
ããã§ç€ºãããå°ãªããšãïŒçš®ã®å¢æè²çŽ ãäž
èšäžè¬åŒããã§ç€ºãããå°ãªããšãïŒçš®ã®å¢æ
è²çŽ ããã³äžèšäžè¬åŒããã§ç€ºãããå°ãªããš
ãïŒçš®ã®å¢æè²çŽ ãšãçµã¿åãããŠå¢æãããŠã
ãæå ææã«ããåèšç®çãéæãåŸãããšãèŠ
ãåºããã åŒ(A) ïŒâŠ0.20 ããã§ïŒ³ããã³ã¯ãããã²ã³åéç²åã®ç²åºŠ
ååžã«ãããŠãã¯æšæºåå·®ããã¯å¹³åç²åŸã
è¡šããã ïŒâΣïŒÎ³âγiïŒ2niïŒÎ£ni ïŒÎ£niγiïŒÎ£ni γiïŒïœçªç®ã®ç²åã®ç²åŸ niïŒïœçªç®ã®ç²åã®æ° ã§ç€ºãããã äžè¬åŒãã åŒäžãY1ãY2ãY3ããã³Y4ã¯ããããæ°ŽçŽ å
åãããã²ã³ååãããããã·ã«åºãã¢ã«ã³ãã·
åºãã¢ããåºãã¢ã·ã«ã¢ããåºãã¢ã·ã«ãªãã·
åºãã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ã«ã³ãã·ã«ã«ã
ãã«ã¢ããåºãã¢ãªãŒã«åºãã·ã¢ãåºãã¢ã«ãã«
åºãè¡šãããY1ãšY2ãŸãã¯Y3ãšY4ã®ã©ã¡ããäž
æ¹ã¯ç°ã圢æãããããªããµãŸãŒã«ç°ã圢æããŠ
ãããããŸãR1ã¯æ°ŽçŽ ååãŸãã¯ã¢ã«ãã«åºã
è¡šããR2ããã³R3ã¯ããããã¢ã«ãã«åºãè¡šã
ããX1 ã¯ã¢ããªã³ãè¡šãããïœã¯ïŒãŸãã¯ïŒ
ã®æŽæ°ãè¡šããããã ããïœãïŒãè¡šãããšã
ã¯ãR2ãŸãã¯R3ã¯ååå å¡©ã圢æãåŸãåºãè¡š
ããã äžè¬åŒãã åŒäžãY5ãšY6ããã³Y7ãšY8ã¯ããããé£çµã
ãŠç°ã圢æããããããããããªããµãŸãŒã«ç°ã
圢æããåå矀ãè¡šããããŸãR4ã¯æ°ŽçŽ ååãŸ
ãã¯ã¢ã«ãã«åºãè¡šãããR5ããã³R6ã¯ããã
ãã¢ã«ãã«åºãè¡šãããX2 ã¯ã¢ããªã³ãè¡šã
ãïœã¯ïŒãŸãã¯ïŒã®æŽæ°ãè¡šããããã ããïœã
ïŒãè¡šãããšãã¯ãR5ãŸãã¯R6ã¯ååå å¡©ã圢
æãåŸãåºãè¡šããã äžè¬åŒãã åŒäžãY9ãY10ãY11ããã³Y12ã¯ããããæ°ŽçŽ
ååãããã²ã³ååãããããã·ã«åºãã¢ã«ã³ã
ã·åºãã¢ããåºãã¢ã·ã«ã¢ããåºãã¢ã·ã«ãªãã·
åºãã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ã«ã³ãã·ã«ã«ã
ãã«ã¢ããåºãã¢ãªãŒã«åºãã·ã¢ãåºãã¢ã«ãã«
åºãè¡šãããY9ãšY10ããã³ïŒãŸãã¯Y11ãšY12ã¯
ããããé£çµããŠç°ã圢æããããããããŸãŒã«
ç°ã圢æããŠãããããŸãR7ã¯æ°ŽçŽ ååãŸãã¯
ã¢ã«ãã«åºãè¡šãããR8ãR9ãR10ããã³R11ã¯
ããããã¢ã«ãã«åºãè¡šãããX3 ã¯ã¢ããªã³
ãè¡šããïœã¯ïŒãŸãã¯ïŒã®æŽæ°ãè¡šããããã
ããïœãïŒãè¡šãããšãã¯ãR8ãR9ãR10ãŸãã¯
R11ã¯ååå å¡©ã圢æãåŸãåºãè¡šããã ããªãã¡ãæ¬çºæã®æå ææã¯ãæ¯æäœäžã«èš
ããããããã²ã³åéä¹³å€å±€ãåèšåŒ(A)ã§ç€ºãã
ãåŠãç²åºŠååžãæããå®è³ªçã«ååæ£æ§ã®ãã
ã²ã³åéç²åãå«æãããã®ã§ããããã€è©²ãã
ã²ã³åéç²åãåèšäžè¬åŒãããããããã³
ããã§ç€ºãããå¢æè²çŽ ã®ããããå°ãªããšã
ïŒçš®ã¥ã€ãçµã¿åãããŠåå å¢æããããããã
ããšãç¹åŸŽãšããæ¬çºæã®å¹æãå ·äœçã«ã¯ç·è²
å ã«å¯ŸããŠé«ãåå å¢ææ床ãæãããããé«ç §
床çæéé²å ã«å¯Ÿããç¹æ§ãæ¹è¯ãããé«æ床ã®
æå ææãåŸãããšãã§ããã ãŸããæ¬çºæè ãã¯å ã«æå57幎ïŒ12æïŒå·®ã
åºãç¹èš±é¡çºæã®å称ãããã²ã³åéåçæå æ
æãã«ãããŠãåèšæ¬çºæã«ä¿ãäžè¬åŒããã
ãã³ããã§ç€ºãããå¢æè²çŽ ãçšããæè¡ãé
瀺ããããæŽã«æ¬çºæè ããéæç 究ãéããçµ
æåèšæ¬çºæã«ä¿ãæ§æãæããæå ææã«ã
ããåè¿°ã®å¹æãæããæå ææãåŸãããšãã§
ããã®ã§ããã 以äžãæ¬çºæãæŽã«è©³çŽ°ã«èª¬æããã å ã¥åèšäžè¬åŒããã«ãããŠãY1ãY2ãY3
ããã³Y4ããããã瀺ãããã²ã³ååãšããŠã¯ã
äŸãã°å¡©çŽ ãèçŽ ãæ²çŽ ãããçŽ ããããã¢ã«ã³
ãã·åºãšããŠã¯ãäŸãã°ã¡ããã·ããšããã·ãã
ãããã·ããããã·çã®ååºããããã¢ããåºãš
ããŠã¯ãäŸãã°ã¢ãããã¡ãã«ã¢ããããžã¡ãã«
ã¢ããããžãšãã«ã¢ããçã®ååºãæããããšã
ã§ããã¢ã·ã«ã¢ããåºãšããŠã¯ãäŸãã°ã¢ã»ãã¢
ãããããããªã³ã¢ããçã®ååºããããã¢ã«ã³
ãã·ã«ã«ããã«åºãšããŠã¯ãäŸãã°ãšããã·ã«ã«
ããã«ãããããã·ã«ã«ããã«çã®ååºãããã
ã¢ã«ã³ãã·ã«ã«ããã«ã¢ããåºãšããŠã¯ãäŸãã°
ãšããã·ã«ã«ããã«ã¢ãããããããã·ã«ã«ãã
ã«ã¢ããããããã·ã«ã«ããã«ã¢ããçã®åºãã
ããã¢ãªãŒã«åºãšããŠã¯äŸãã°ããšãã«ãããªãŒ
ã«çã®åºããããã¢ã«ãã«åºãšããŠã¯ã奜ãŸãã
ã¯äœçŽã¢ã«ãã«åºãäŸãã°ã¡ãã«ããšãã«ããã
ãã«çã®åºãæããããšãã§ããããããŠäžèš
Y1ãY2ã®å°ãªããšãïŒã€ãããã³Y3ãY4ã®å°ãª
ããšãïŒã€ãã¢ãªãŒã«åºã§ããããšã奜ãŸããã
ãŸãY1ãšY2ãŸãã¯Y3ãšY4ã®ã©ã¡ããäžæ¹ãé£çµ
ããŠç°ã圢æããŠãããããã®çµæããããªããµ
ãŸãŒã«ç°ãäŸãã°ããããïŒïŒïŒâïœããªããµãŸ
ãŒã«ãããããïŒïŒïŒâïœããªããµãŸãŒã«ããã
ããïŒïŒïŒâïœããªããµãŸãŒã«çãäžè¬åŒãã
ã§ç€ºãããååç©ã®ååå ã«åœ¢æããŠãããŸããª
ãã ããã«åèšäžè¬åŒããã«ãããŠR1ãè¡šãã
ã¢ã«ãã«åºãšããŠã¯ãäœçŽã¢ã«ãã«åºã奜ãŸã
ããäŸãã°ã¡ãã«ããšãã«ããããã«çã®åºãã
ãããŸãR2ããã³R3ãããããè¡šããã¢ã«ãã«
åºãšããŠã¯ãäŸãã°ã¡ãã«ããšãã«ãã¹ã«ããšã
ã«ãã«ã«ããã·ãããã«ãããã«ãã¹ã«ãããã«
çã®åºãæããããšãã§ãããããã¯åããã®ã§
ãã€ãŠããããäºãã«ç°ãªã€ãŠããŠãããã åèšäžè¬åŒããã«ãããŠãX1 ãè¡šããã¢
ããªã³ãšããŠã¯ãäŸãã°å¡©åç©ãèåç©ãæ²å
ç©ãããªã·ã¢ããŒãããµã«ãã¢ã¡ãŒããã¡ãã«ãµ
ã«ããšãŒãããšãã«ãµã«ããšãŒããããŒã¯ãã¬ãŒ
ããïœâãã«ãšã³ã¹ã«ãããŒãçã®ã¢ããªã³ãã
ãã åŒç¶ããŠåèšäžè¬åŒããã«ãããŠY5ãšY6ã
ãã³Y7ãšY8ãããããé£çµããŠç°ã圢æããã
ã®çµæããããªããµãŸãŒã«ç°ãäŸãã°ããã
ãïŒïŒïŒâïœããªããµãŸãŒã«ç°ãããããïŒïŒïŒ
âïœããªããµãŸãŒã«ç°ãŸãã¯ããããïŒïŒïŒâ
ïœããªããµãŸãŒã«ç°çãäžè¬åŒããã§ç€ºããã
ååç©ã®ååå ã«ãããã圢æããããšã奜ãŸã
ãã ãŸãR4ãè¡šããã¢ã«ãã«åºãšããŠã¯ãäœçŽã¢
ã«ãã«åºã奜ãŸãããäŸãã°ã¡ãã«ããšãã«ãã
ããã«çã®åºããããããã«ã¯R5ããã³R6ãè¡š
ããã¢ã«ãã«åºãšããŠã¯ãäŸãã°ã¡ãã«ããšã
ã«ãã¹ã«ããšãã«ãã«ã«ããã·ãããã«ããã
ã«ãã¹ã«ãããã«çã®åºããã€ãŠããããã¯åã
ã§ãã€ãŠãäºãã«ç°ãªã€ãŠããŠããããããã«
X2 ãè¡šããã¢ããªã³ãšããŠã¯ãäŸãã°å¡©åç©ã
èåç©ãæ²åç©ãããªã·ã¢ããŒãããµã«ãã¢ã¡ãŒ
ããã¡ãã«ãµã«ããšãŒãããšãã«ãµã«ããšãŒãã
ããŒã¯ãã¬ãŒããïœâãã«ãšã³ã¹ã«ãããŒãçã®
ã¢ããªã³ãããã 次ã«åèšäžè¬åŒããã«ãããŠãY9ãY10ã
Y11ããã³Y12ãããããè¡šããããã²ã³ååãš
ããŠã¯ãäŸãã°å¡©çŽ ãèçŽ ãæ²çŽ ãããçŽ çãã
ããã¢ã«ã³ãã·åºãšããŠã¯ãäŸãã°ã¡ããã·ããš
ããã·ãããããã·ããããã·çã®åºãæãã
ããã¢ããåºãšããŠã¯ãäŸãã°ã¢ãããã¡ãã«ã¢
ããããžã¡ãã«ã¢ããããžãšãã«ã¢ããçã®åºã
ãããã¢ã·ã«ã¢ããåºãšããŠã¯ãäŸãã°ã¢ã»ãã¢
ãããããããªã³ã¢ããçã®åºããããã¢ã·ã«ãª
ãã·åºãšããŠã¯ãäŸãã°ã¢ã»ããã·ãããããªã³
ãªãã·çã®åºããããã¢ã«ã³ãã·ã«ã«ããã«åºãš
ããŠã¯ãäŸãã°ãšããã·ã«ã«ããã«ãããããã·
ã«ã«ããã«çã®åºããããã¢ã«ã³ãã·ã«ã«ããã«
ã¢ããåºãšããŠã¯ãäŸãã°ãšããã·ã«ã«ããã«ã¢
ãããããããã·ã«ã«ããã«ã¢ããããããã·ã«
ã«ããã«ã¢ããçã®åºããããã¢ãªãŒã«åºãšããŠ
ã¯ãäŸãã°ããšãã«ãããªãŒã«çã®åºããããã¢
ã«ãã«åºãšããŠã¯ãäœçŽã¢ã«ãã«åºã奜ãŸããã
äŸãã°ã¡ãã«ããšãã«ããããã«çã®åºãããã
ãããŠäžèšY9ãY10ãY11ããã³Y12ãåæã«å¡©çŽ
ååãè¡šããããšã奜ãŸãããããã«ã¯Y9ãšY10
ã®å°ãªããšãïŒã€ããã³Y11ãšY12ã®å°ãªããšã
ïŒã€ãã·ã¢ãã§ããããšã奜ãŸããããŸãY9ãš
Y10ããã³Y11ãšY12ãããããé£çµããŠåœ¢æãã
ãããã€ãããŸãŒã«ç°ã圢æããŠãããŸããªãã
ãŸãR7ãè¡šããã¢ã«ãã«åºãšããŠã¯äœçŽã¢ã«ã
ã«åºã奜ãŸãããäŸãã°ã¡ãã«ããšãã«ãããã
ã«çã®åºããããR8ãR9ãR10ããã³R11ããã
ããè¡šããã¢ã«ãã«åºãšããŠã¯ãäŸãã°ã¡ãã«ã
ãšãã«ãã¹ã«ããšãã«ãã«ã«ããã·ãããã«ãã
ãã«ãã¹ã«ãããã«çã®åºããããããã«X3
ãè¡šããã¢ããªã³ãšããŠã¯ãäŸãã°å¡©åç©ãèå
ç©ãæ²åç©ãããªã·ã¢ããŒãããµã«ãã¢ã¡ãŒãã
ã¡ãã«ãµã«ããšãŒãããšãã«ãµã«ããšãŒããããŒ
ã¯ãã¬ãŒããïœâãã«ãšã³ã¹ã«ãããŒãçã®ã¢ã
ãªã³ãè¡šããã 以äžã«æ¬çºæã«ãããŠçšããããäžè¬åŒããã
ããããã³ããã«ãã€ãŠè¡šããããå¢æè²çŽ
ã®ä»£è¡šçãªãã®ã瀺ãããæ¬çºæããããã«éå®
ããããã®ã§ã¯ãªãã æ¬çºæã®äžè¬åŒãããããããã³ããã§è¡š
ããããå¢æžè²çŽ ã¯ãäŸãã°ç±³åœç¹èš±ç¬¬3397060
å·ãåç3506443å·çã«èšèŒãããŠãããããã«
äžèšå¢æè²çŽ ã®åææ³ã«ã€ããŠãèšè¿°ãããŠã
ãããªãäžèšç¹èš±æ现æžã«èšèŒã®ãªãå¢æè²çŽ ã
äžèšèšèŒã®åææ³ã«æºããŠåœæ¥è ã容æã«åæã
ãããšãã§ããã æ¬çºæã®æå ææã«ãããŠã¯ãæ¯æäœäžã«èšã
ãããå°ãªããšãïŒå±€ã®ããã²ã³åéä¹³å€å±€ã«å«
æãããæ¬çºæã«ä¿ãããã²ã³åéç²åãäžèšã«
ããåæãããæ¬çºæã«ä¿ãå¢æžè²çŽ ãçµã¿åã
ãå«æãå¢æãããããšã«ããåèšåå å¢æå¹æ
çãåŸãããšãã§ããããæ¬çºæã«ããã°ãäžèš
ããã²ã³åéä¹³å€å±€ã«ã¯ãåèšåŒ(A)ã§ç€ºãããç²
床ååžãæããå®è³ªçã«ååæ£æ§ã®ããã²ã³åé
ç²åãå«æããŠããããšã奜ãŸãããããªãã¡ã
æ¬çºæã«ãããäžèšããã²ã³åéç²åã®ç²åºŠååž
ã¯ãæ¬çºæã«ããäžèšåŒ(A)ã§èŠå®ãããåŠããæš
æºå差ãå¹³åç²åŸã§å²ã€ãæã®å€ã0.20ãŸã
ã¯ãã以äžã®ãã®ãèšãã åŒ(A) ïŒÎ³âŠ0.20 ïŒâΣïŒÎ³âγiïŒ2niïŒÎ£ni ããã§èšãå¹³åç²åŸãšã¯ãçç¶ã®ããã²ã³åé
ç²åã®å Žåã¯ããã®çŽåŸããŸãç«æ¹äœãçç¶ä»¥å€
ã®åœ¢ç¶ã®ç²åã®å Žåã¯ããã®æ圱åãåé¢ç©ã®å
åã«æç®ããæã®çŽåŸã®å¹³åå€ã§ãã€ãŠãåã ã®
ãã®ç²åŸãγiã§ããããã®æ°ãniã§ããæãäžèš
ã®åŒã«ãã€ãŠÎ³ãå®çŸ©ããããã®ã§ããã ïŒÎ£niγiïŒÎ£ni ãªããäžèšã®ç²ååŸã¯äžèšã®ç®çã®ããã«åœè©²
æè¡åéã«ãããŠäžè¬ã«çšããããåçš®ã®æ¹æ³ã«
ãã€ãŠããã枬å®ããããšãã§ããã代衚çãªæ¹
æ³ãšããŠã¯ãã©ãã©ã³ãã®ãç²ååŸåææ³ãA.S.
T.M.ã·ã³ããžãŠã ã»ãªã³ã»ã©ã€ãã»ãã€ã¯ãã¹
ã³ããŒã1955幎ã94ã122é ãŸãã¯ãåçããã»
ã¹ã®çè«ãããŒã¹ããã³ãžãšãŒã ãºå ±èã第ïŒ
çããã¯ãã©ã³ç€Ÿçºè¡ïŒ1966幎ïŒã®ç¬¬ïŒç« ã«èšèŒ
ãããŠããããã®ç²ååŸã¯ç²åã®æ圱é¢ç©ãçŽåŸ
è¿äŒŒå€ã䜿ã€ãŠããã枬å®ããããšãã§ãããç²
åãå®è³ªçã«åäžåœ¢ç¶ã§ããå Žåã¯ãç²åŸååžã¯
çŽåŸãæ圱é¢ç©ãšããŠãããªãæ£ç¢ºã«ãããè¡šã
ãããšãã§ããã ç²åŸååžã®é¢ä¿ã¯ãåçä¹³å€ã«ãããã»ã³ã·ã
ã¡ããªãŒååžãšç²åºŠååžãšã®éã®çµéšçé¢ä¿ãã¶
ããªãã°ã©ãã€ãã¯ãžã€ãŒãã«ãLXXIXå·»ã
ïŒ1949幎ïŒ330ã338é ã®ããªããªãšã¹ãã¹ã®è«æ
ã«èšèŒãããæ¹æ³ã§ãããã決ããããšãã§ã
ãã æ¬çºæã®æå ææã«çšããããããã²ã³åéç²
åã¯ãæ¬çºæã«ä¿ãååæ£æ§ã®ããã²ã³åéç²å
ãåäžããã²ã³åéä¹³å€å±€ã«ãããå šç²åã®70ïŒ
以äžå«æããŠããããšã奜ãŸãããç¹ã«å šç²åã
ååæ£ç²åã§ããããšã奜ãŸãããæ¬çºæã«ä¿ã
å®è³ªçã«ååæ£æ§ã®ããã²ã³åéç²åã¯ãåç¬ã§
䜿çšããŠããããå¹³åç²ååŸã®ç°ãªãïŒçš®ä»¥äžã®
ååæ£æ§ã®ããã²ã³åéç²åãä»»æã«æ··åããŠäœ¿
çšããŠãããã æ¬çºæã«ãããŠã¯ãåèšäžè¬åŒãããããã
ãã³ããã§ç€ºãããå¢æè²çŽ ïŒä»¥äžãæ¬çºæã«
ä¿ãå¢æè²çŽ ãšç§°ããïŒã«ããå¹æçã«åå å¢æ
ãããããã²ã³åéç²åã¯ãæ²åéå«æçã®ç°ãª
ãïŒå±€ä»¥äžã®å±€ããæ§æãããŠããç²åæ§é ã«ãª
ããã®ã奜ãŸããã該ïŒå±€ä»¥äžã®å±€ã®ãã¡ã®æè¡š
é¢å±€ã«ãããå¹³åæ²åéå«æçãããããããå
éšã®å±€ã®å¹³åæ²åºŠå«æçã«æ¯ã¹ãŠäœãããšã奜ãŸ
ãããæ¬çºæã«ããå¹æã¯ãäžèšã®ãããªæè¡šé¢
å±€ããå éšã«æ¯ã¹ãŠæè¡šé¢å±€ã«ãããæ²åéå«æ
çããããäœãç²åæ§é ãæããããã²ã³åéç²
åãå«æããããã²ã³åéä¹³å€ã®äœ¿çšã«ããäžå±€
é¡èã«çºæ®ãããã æ¬çºæã§ã¯ãäžèšçµæã«ãªãããã²ã³åéç²å
ã®æè¡šé¢å±€ã«ãããæ²åéå«æçã¯ãäœãã»ã©æ
ãŸãããã»ãŒïŒïŒ ã«è¿ãããšã奜ãŸããã ãã®ãããªããã²ã³åéç²åãå«æããä¹³å€ã§
ã¯ãå¢æå¹çãé«ããæã«è¡šé¢æœååä¹³å€ãåŸã
ã«é©ããŠããã äžèšã®åŠãããã²ã³åéçµæãæããããã²ã³
åéç²åã¯ãäŸãã°è©²ç²åäžã«ã³ã¢ãšã·ãšã«ãæ§
æããæè¬ã³ã¢ïŒã·ãšã«åã®ããã²ã³åéç²åãš
ããŠåœ¢æãããããšãã§ããããæŽã«è©²ç²åã®å
éšã®ã³ã¢ãæ²åéå«æçã®ç°ãªãïŒå±€ä»¥äžã®å±€ãš
ããŠåœ¢æãããŠãããããã®ãããªå Žåãæ²åé
å«æçã®é«ãå±€ãšå«æçã®äœãå±€ã®å«æçã®å·®ã¯
ã·ã€ãŒããªå¢çãæãããã®ã§ãããããŸãå¢ç
ã®å¿ ãããæçœã§ã¯ãªãé£ç¶ããŠå€åãããã®ã§
ãã€ãŠãããã äžèšã®ããã²ã³åéç²åã«ãããæ²åéã®ååž
ç¶æ ã¯ãåçš®ã®ç©çç枬å®æ³ã«ãã€ãŠæ€ç¥ããã
ãšãã§ããäŸãã°æ¥æ¬åçåŠäŒãæå56幎床幎次
倧äŒè¬æŒèŠæšéã«èšèŒãããŠãããããªäœæž©ã§ã®
ã«ãããã»ã³ã¹ã枬å®ããããšã«ãã€ãŠã調ã¹ã
ããšãã§ããã äžèšæ¬çºæã®ã³ã¢ïŒã·ãšã«åããã²ã³åéç²å
ã¯ãæ²åéãå«ãããã²ã³åéãããªãã³ã¢ãšã
該ã³ã¢ã被èŠããæ²åéã®å«æçãäžèšã³ã¢ã«ã
ããå«æçããäœãããã²ã³åéãããªãã·ãšã«
ãšãããªãããã€äžèšã·ãšã«ã®åãã0.001ã
0.1ÎŒã§ããããã²ã³åéç²åã§ããã ãããŠæ¬çºæã®å¥œãŸããããã²ã³åéç²åã®å®
æœæ æ§ãšããŠã¯ãäžèšã³ã¢ã®ããã²ã³åéçµæã
æ²åéãïŒã15ã¢ã«ïŒ ãå«ãããã²ã³åéã§ãã
ãŸãäžèšã·ãšã«éšã¯æ²åéãïŒãïŒã¢ã«ïŒ ãå«ã
ããã²ã³åéã§ããããšã§ããããŸãåèšã·ãšã«
éšãšã³ã¢éšã®æ²åéå«æçã®å·®ã¯ïŒã¢ã«ïŒ 以äžã
ãããšã奜ãŸãããæ¬çºæã«ãããããã²ã³åé
ç²åã¯ãäžèšæ²åé以å€ã®ããã²ã³åéçµæã¯äž»
ãšããŠèåéã§ããããšã奜ãŸããããæ¬çºæã®
å¹æãæããªãéãã«ãããŠå¡©åéãå«ãã§ãã
ãã æ¬çºæã«ä¿ãããã²ã³åéç²åã®å¹³åæ²åéå«
æçã¯0.5ã¢ã«ïŒ ã15ã¢ã«ïŒ ã奜ãŸãããããã«
奜ãŸããã¯ïŒã¢ã«ïŒ ã12ã¢ã«ïŒ ã®ç¯å²ã§ããã æ¬çºæã«ä¿ãããã²ã³åéç²åã®åœ¢ç¶ã¯ãäŸã
ã°å é¢äœãå «é¢äœãååé¢äœãæ¿ç¶äœãçç¶äœã®
äœãã§ãããããŸããããå皮圢ç¶ã®æ··åããã
ã®ã§ãã€ãŠãããããå «é¢äœãååé¢äœã®ç²åã
奜ãŸããã æ¬çºæã®ç¹å®ã®å±€æ§æãæããããã²ã³åéç²
åãå«æããããã²ã³åéä¹³å€ã¯ãååæ£æ§ã®ã
ãã²ã³åéç²åãã³ã¢ãšããŠãããã«ã·ãšã«ã被
èŠããããšã«ãã€ãŠè£œé ããããšãã§ããã åèšã³ã¢ã®ååæ£æ§ã®ããã²ã³åéç²åã補é
ããã«ã¯ãPAgãäžå®ã«ä¿ã¡ãªããããã«ãžãš
ããæ³ã«ããææã®å€§ããã®ç²åãåŸãããšãã§
ããããŸãé«åºŠã®ååæ£æ§ã®ããã²ã³åéä¹³å€
ã¯ãç¹éæ54â48521å·å ¬å ±ã«èšèŒãããŠããæ¹
æ³ãé©çšããããšãã§ãããäŸãã°æ²èåã«ãªãŠ
ã âãŒã©ãã³æ°Žæº¶æ¶²ãšã¢ã³ã¢ãã¢æ§ç¡é žé氎溶液
ãšãããã²ã³åéçš®ç²åãå«ããŒã©ãã³æ°Žæº¶æ¶²äž
ã«æ·»å é床ãæéã®é¢æ°ãšããŠå€åãããŠæ·»å ã
ãæ¹æ³ã«ãã€ãŠè£œé ããããã®éæ·»å é床ã®æé
é¢æ°ãpHãpAgã枩床çãé©å®ã«éžæããããš
ã«ããé«åºŠã®ååæ£æ§ã®ããã²ã³åéç²åãåŸã
ããšãã§ããã 次ã«ã³ã¢ã被èŠããã·ãšã«ã®åãã¯ã³ã¢ã®å¥œãŸ
ããçŽ è³ªãé èœãã¬åãã§ããããã€éã«ã³ã¢ã®
奜ãŸãããããçŽ è³ªãé èœããã«è¶³ãåã¿ã§ãªã
ãã°ãªããªããå³ã¡ãåã¿ã¯ãã®ãããªäžéãšäž
éãšã§éãããçãç¯å²ã«éå®ãããããã®ãã
ãªã·ãšã«ã¯å¯æº¶æ§ããã²ã³ååç©æº¶æ¶²ãšå¯æº¶æ§é
塩溶液ãããã«ãžãšããæ³ã«ãã€ãŠååæ£æ§ã®ã
ãã²ã³åéç²åã®ã³ã¢ã«æ²ç©ãããŠåœ¢æãããã
ãšãã§ããã äžèšã®ã³ã¢ïŒã·ãšã«åããã²ã³åéç²åã®è£œé
æ¹æ³ã«ã€ããŠã¯ãäŸãã°è¥¿ç¬ç¹èš±ç¬¬1169290å·ã
è±åœç¹èš±ç¬¬1027146å·åæ现æžãç¹éæ57â
154232å·ãç¹å ¬æ51â1417å·åå ¬å ±çã«ãèšèŒã
ããŠããã æ¬çºæã§ã¯ãæ¬çºæã«ä¿ãããã²ã³åéç²åã®
補é éçšã«ãããŠãäŸãã°ã«ãããŠã å¡©ãäºé
å¡©ãéå¡©ãã¿ãªãŠã å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã
ãã®é¯å¡©ãããžãŠã å¡©ãŸãã¯ãã®é¯å¡©çãå ±åã
ããŠãããã æ¬çºæã«ãããŠã¯ãæ¬çºæã«ä¿ãå¢æè²çŽ ãå
èšã«ãã補é ãããååæ£æ§ã®ããã²ã³åéç²å
ãå«æããããã²ã³åéä¹³å€ã«æ·»å ããããšã«ã
ãåå å¢æãè¡ãªããããäžèšå¢æè²çŽ ã®æ·»å æ
æãšããŠã¯ãããã²ã³åéä¹³å€ã®ååŠçæïŒç¬¬ïŒ
çæãšãåŒã°ããïŒéå§æãçæé²è¡äžãçæçµ
äºããŸãã¯ä¹³å€å¡åžã«å ç«ã€é©åãªææçäœãã®
å·¥çšã§ãå·®æ¯ããªãã ãŸãæ¬çºæã®åèšåäžè¬åŒã§ç€ºãããå¢æè²çŽ
ãäžèšåçä¹³å€ã«æ·»å ããæ¹æ³ãšããŠã¯ãåŸæ¥ã
ãææ¡ãããŠããçš®ã ã®æ¹æ³ãé©çšã§ãããäŸã
ã°ç±³åœç¹èš±ç¬¬3469987å·ã«èšèŒãããåŠãå¢æè²
çŽ ãæ®çºæ§ææ©æº¶åªã«æº¶è§£ãã該溶液ã芪氎æ§ã³
ãã€ãäžã«åæ£ãããã®åæ£ç©ãä¹³å€ã«æ·»å ãã
æ¹æ³ã«ããè¡ãªã€ãŠãããããŸãããã«æ¬çºæã®
å¢æè²çŽ ã¯ãåã ã«åäžãŸãã¯ç°ãªã溶åªã«æº¶è§£
ããä¹³å€ã«æ·»å ããåã«ããããã®æº¶æ¶²ãæ··åã
ãããå¥ã ã«æ·»å ããããšãã§ããã æ¬çºæã«ä¿ãå¢æè²çŽ ãããã²ã³åéåçä¹³å€
ã«æ·»å ãããšãã®è²çŽ ã®æº¶åªãšããŠã¯ãäŸãã°ã¡
ãã«ã¢ã«ã³ãŒã«ããšãã«ã¢ã«ã³ãŒã«ãã¢ã»ãã³ç
ã®æ°Žæ··åæ§ææ©çšåªã奜ãŸããçšããããã æ¬çºæã«ä¿ãå¢æè²çŽ ãããã²ã³åéä¹³å€ã«æ·»
å ããããå Žåã®æ·»å éã¯ãããã²ã³åéïŒã¢ã«
åœãïŒÃ10-5ã¢ã«ãªãã2.5Ã10-2ã¢ã«ã奜ãŸã
ãã¯1.0Ã10-4ã¢ã«ãªãã1.0Ã10-3ã¢ã«ã§ããã
ãããŠæ¬çºæã«ä¿ãå¢æè²çŽ ã®å¥œãŸãã䜿çšæ¯ç
ã¯ãããããåèšäžè¬åŒãããããããã³
ããã®é ã«åŸã€ãŠ0.1ãïŒïŒïŒïŒ0.1ãïŒã®ç¯å²
ã§ããã æ¬çºæã«ä¿ãå¢æè²çŽ ã¯ãæŽã«ä»ã®å¢æè²çŽ ãŸ
ãã¯åŒ·è²å¢æå€ãšäœµçšããããšãã§ããã æ¬çºæã«ããããã²ã³åéç²åã¯äžè¬çã«æœã
ããåçš®ã®ååŠå¢ææ³ãæœãããšãã§ãããããª
ãã¡æŽ»æ§ãŒã©ãã³ïŒæ°Žæº¶æ§éå¡©ã氎溶æ§çœéå¡©ã
氎溶æ§ãã©ãžãŠã å¡©ã氎溶æ§ããžãŠã å¡©ã氎溶æ§
ã€ãªãžãŠã å¡©çã®è²Žéå±å¢æå€ïŒç¡«é»å¢æå€ïŒã»
ã¬ã³å¢æå€ïŒããªã¢ãã³ãå¡©å第ïŒé«çã®éå å¢
æå€çã®ååŠå¢æå€çã«ããåç¬ã«ããããã¯äœµ
çšããŠååŠå¢æããããšãã§ããã æ¬çºæã«ãããŠãäžèšã®ç¡«é»å¢æå€ãšããŠã¯å ¬
ç¥ã®ãã®ãçšããããšãã§ãããäŸãã°ããªç¡«é ž
å¡©ãã¢ãªã«ããªã«ã«ãããããªå°¿çŽ ãã¢ãªã«ã€ãœ
ãã¢ã·ã¢ããŒããã·ã¹ãã³ãïœâãã«ãšã³ããªã¹
ã«ãã³é žå¡©ãããŒããã³ãªã©ãæããããããã®
ä»ç±³åœç¹èš±ç¬¬1574944å·ãå第2410689å·ãå第
2278947å·ãå第2728668å·ãå第3501313å·ãå
第3656955å·åæ现æžããã€ãç¹èš±ç¬¬1422869ãæ¥
æ¬ç¹èš±æ56â24937å·ãç¹éæ55â45016å·å ¬å ±ç
ã«èšèŒãããŠããç¡«é»å¢æå€ãçšããããšãã§ã
ããç¡«é»å¢æå€ã®æ·»åéã¯ãä¹³å€ã®æ床ãå¹æç
ã«å¢å€§ãããã«ååãªéã§ããããã®éã¯ããã
ãã·ã¢ã¶ã€ã³ãã³ã®æ·»å éãPHã枩床ãããã²ã³
åéç²åã®å€§ãããªã©çš®ã ã®æ¡ä»¶ã®äžã§çžåœã®ç¯
å²ã«ããã€ãŠå€åããããç®å®ãšããŠã¯ããã²ã³
åéïŒã¢ã«åœãçŽ10-7ã¢ãªãçŽ10-1ã¢ã«çšåºŠã奜
ãŸããã æ¬çºæã«ãããŠã¯ãç¡«é»å¢æã®ä»£ãã«ã»ã¬ã³å¢
æãçšããããšãã§ããããã»ã¬ã³å¢æå€ã¯ãã¢
ãªã«ã€ãœã»ã¬ãã·ã¢ããŒãã®åŠãèèªæã€ãœã»ã¬
ãã·ã¢ããŒãé¡ãã»ã¬ãå°¿çŽ é¡ãã»ã¬ãã±ãã³
é¡ãã»ã¬ãã¢ããé¡ãã»ã¬ãã«ã«ãã³é žé¡ããã³
ãšã¹ãã«é¡ãã»ã¬ãããªã¹ããšãŒãé¡ããžãšãã«
ã»ã¬ãã€ãããžãšãã«ãžã»ã¬ãã€ãçã®ã»ã¬ãã€
ãé¡ãªã©ãçšããããšãã§ãããããã®å ·äœäŸã¯
ç±³åœç¹èš±ç¬¬1574944å·ãå第1602592å·ãå第
1623499å·æ现æžã«èšèŒãããŠããã æ·»å éã¯ç¡«é»å¢æå€ãšåæ§ã«åºãç¯å²ã«ããã€
ãŠå€åããããç®å®ãšããŠã¯ããã²ã³åéïŒã¢ã«
åœãçŽ10-7ã¢ã«ãã10-3ã¢ã«çšåºŠã奜ãŸããã æ¬çºæã«ãããŠãéå¢æå€ãšããŠã¯éã®é žåæ°
ãïŒïŒäŸ¡ã§ãïŒïŒäŸ¡ã§ãããå€éã®éååç©ãçš
ããããã代衚çãªäŸãšããŠã¯å¡©åéé žå¡©ãã«ãª
ãŠã ã¯ãããªãŒã¬ãŒãããªãŒãªãã¯ããªã¯ãã©ã€
ããã«ãªãŠã ãªãŒãªãã¯ããªã·ã¢ããŒããã«ãªãŠ
ã ãšãŒããªãŒã¬ãŒããããã©ã·ã¢ããªãŒãªãã¯ã¢
ã·ããã¢ã³ã¢ããŠã ãªãŒããªãã·ã¢ããŒããããª
ãžã«ããªã¯ãããŽãŒã«ããªã©ãæããããã éå¢æå€ã®æ·»å éã¯çš®ã ã®æ¡ä»¶ã«ããç°ãªãã
ç®å®ãšããŠã¯ããã²ã³åéïŒã¢ã«åœãçŽ10-7ã¢ã«
ãã10-1ã¢ã«ãŸã§ã®ç¯å²ã奜ãŸããã æ¬çºæã«ãããããã²ã³åéç²åã®å¢ææ³ã«ã¯
ä»ã®è²Žéå±ãäŸãã°çœéããã©ãžãŠã ãã€ãªãžãŠ
ã ãããžãŠã ã®ãããªéå±ãããã¯ãããã®å¡©ã«
ããå¢ææ³ã䜵çšã§ããã æ¬çºæã«ãããŠã¯ãããã«éå å¢æã䜵çšãã
ããšãå¯èœã§ãããéå å€ãšããŠã¯ç¹ã«å¶éã¯ãª
ããå ¬ç¥ã®å¡©å第äžã¹ãºãäºé žåããªå°¿çŽ ããã
ã©ãžã³èªå°äœãã·ã©ã³ååç©ãæããããã éå å¢æãè¡ãªãææã¯ããã²ã³åéç²åã®æ
é·äžã«è¡ãªãããç¡«é»å¢æããã³éå¢æã®çµäºåŸ
ã«è¡ãªãããšã奜ãŸããã ãŸããæ¬çºæã«ãããŠã¯åèšã®æ¬çºæã«ä¿ãã
ãã²ã³åéç²åã¯ãããã²ã³åé溶å€ã®ååšäžã«
ååŠçæãè¡ãªãããšã«ãã€ãŠèããé«æ床åã
éæããããããšãã§ããã æ¬çºæã§çšããããããã²ã³åé溶å€ãšããŠã¯
ç±³åœç¹èš±ç¬¬3271157å·ãå第3531289å·ãå第
3574628å·ãç¹éæ54â1019å·ãå54â158917å·
çã«èšèŒããã(a)ææ©ããªãšãŒãã«é¡ãç¹éæ53
â82408å·ãå55â77737å·ãå55â2982å·çã«èš
èŒããã(b)ããªå°¿çŽ èªå°äœãç¹éæ53â144319å·
ã«èšèŒããã(c)é žçŽ ãŸãã¯ç¡«é»ååãšçªçŽ ååãš
ã«ã¯ããŸããããªã«ã«ããã«åºãæããããã²ã³
åé溶å€ãç¹éæ54â100717å·ã«èšèŒããã(d)ã€
ãããŸãŒã«é¡ã(e)äºç¡«é žå¡©ã(f)ããªã·ã¢ããŒãç
ãæããããã 以äžã«ãããã®å ·äœçååç©ã瀺ãã (e) K2SO3 (f) NH4SCN KSCN ç¹ã«å¥œãŸãã溶å€ãšããŠã¯ãããªã·ã¢ããŒãã
ãã³ããã©ã¡ãã«ããªå°¿çŽ ãããããŸãçšããã
ã溶å€ã®éã¯çš®é¡ã«ãã€ãŠãç°ãªãããäŸãã°ã
ãªã·ã¢ããŒãã®å Žåã奜ãŸããéã¯ããã²ã³åé
ïŒã¢ã«åœãïŒmgãïŒïœã®ç¯å²ã§ããã æ¬çºæã®ããã²ã³åéç²åã«ã¯ããã®è£œé å·¥
çšãä¿åäžãããã¯çŸååŠçäžã®ãã¶ãã®çºçã
é²æ¢ãããããã¯åçæ§èœãå®å®åãããç®çã§
ååŠçæã®çµäºæãçš®ã ã®ååç©ãå«æãããŠã
ããã äŸãã°ã¢ãŸãŒã«é¡ãäŸãã°ãã³ãŸãã¢ãŸãªãŠã
å¡©ããããã€ã³ããŸãŒã«é¡ãããããã³ãºã€ãã
ãŸãŒã«é¡ãã¯ãããã³ãºã€ãããŸãŒã«é¡ãããã¢
ãã³ãºã€ãã¿ãŸãŒã«é¡ãã¡ã«ã«ãããã¢ãŸãŒã«
é¡ãã¡ã«ã«ãããã³ãºã€ãããŸãŒã«é¡ãã¢ããã
ãªã¢ãŸãŒã«é¡ããã³ãŸããªã¢ãŸãŒã«é¡ããããã
ã³ãŸããªã¢ãŸãŒã«é¡ãã¡ã«ã«ããããã©ãŸãŒã«é¡
ïŒç¹ã«ïŒâããšãã«âïŒâã¡ã«ã«ããããã©ãŸãŒ
ã«ïŒãªã©ããŸãã¡ã«ã«ããããªããžã³é¡ãã¡ã«ã«
ããããªã¢ãžã³é¡ãäŸãã°ãªããµãŸãªã³ããªã³ã®
ãããªããªã±ãååç©ãæŽã«ã¯ãã³ãŒã³ããªã¹ã«
ãã€ã³é žããã³ãŒã³ã¹ã«ãã€ã³é žããã³ãŒã³ã¹ã«
ããªã³é žã¢ããããã€ããããã³èªå°äœãã¢ãã
ããšããŒã«èªå°äœã没é£åé žèªå°äœãã¢ã¹ã³ã«ã
ã³é žèªå°äœçã®ãããªã«ããªé²æ¢å€ãŸãã¯å®å®å€
ãšããŠç¥ãããå€ãã®ååç©ãå ããããšãã§ã
ãããããã®è¬å€ã¯ååŠçææãæãã¯å¡åžåã«
æ·»å ããã®ã奜ãŸããã æ¬çºæã®ããã²ã³åéä¹³å€ã®ãã€ã³ããŒãšããŠ
ã¯ãŒã©ãã³ãå§ããçš®ã ã®èŠªæ°Žæ§ã³ãã€ããçšã
ãããããŒã©ãã³ãšããŠã¯ãŒã©ãã³ã®ã¿ãªããèª
å°äœãŒã©ãã³ãå å«ãããèªå°äœãŒã©ãã³ãšããŠ
ã¯ããŒã©ãã³é žç¡æ°Žç©ãšã®åå¿çæç©ããŒã©ãã³
ãšã€ãœã·ã¢ããŒããšã®åå¿çæç©ãæãã¯ãŒã©ã
ã³ãšæŽ»æ§ããã²ã³ååãæããååç©ãšã®åå¿ç
æç©çãå å«ããããããã«ãŒã©ãã³ãšã®åå¿ã«
çšããããé žç¡æ°Žç©ãšããŠã¯ãäŸãã°ç¡æ°Žãã¬ã€
ã³é žãç¡æ°Žãã¿ã«é žãç¡æ°Žå®æ¯éŠé žãç¡æ°Žé ¢é žã
ç¡æ°Žã€ãµãé žãç¡æ°Žã³ãã¯é žçãå«ãŸããã€ãœã·
ã¢ããŒãååç©ãšããŠã¯ãäŸãã°ããšãã«ã€ãœã·
ã¢ããŒããïœâããã¢ããšãã«ã€ãœã·ã¢ããŒãã
ïœâã¯ããããšãã«ã€ãœã·ã¢ããŒããïœâããªã«
ã€ãœã·ã¢ããŒããïœâãããããšãã«ã€ãœã·ã¢ã
ãŒãããããã«ã€ãœã·ã¢ããŒãçãæããããšã
ã§ããã æŽã«æŽ»æ§ããã²ã³ååãæããååç©ãšããŠã¯
äŸãã°ãã³ãŒã³ã¹ã«ããã«ã¯ãã©ã€ããïœâã¡ã
ãã·ãã³ãŒã³ã¹ã«ããã«ã¯ãã©ã€ããïœâããšã
ãã·ãã³ãŒã«ã¹ã«ããã«ã¯ãã©ã€ããïœâããã¢
ãã³ãŒã³ã¹ã«ããã«ã¯ãã©ã€ããïœâãã«ãšã³ã¹
ã«ããã«ã¯ãã©ã€ããïœâããããã³ãŒã³ã¹ã«ã
ãã«ã¯ãã©ã€ããïœâã¹ã«ããã³ãŸã€ã«ãžã¯ãã©
ã€ããããã¿ã¬ã³âβâã¹ã«ããã«ã¯ãã©ã€ãã
ïœâã¯ãããã³ãŒã³ã¹ã«ããã«ã¯ãã©ã€ããïŒâ
ãããâïŒâã¢ãããã³ãŒã«ã¹ã«ããã«ã¯ãã©ã€
ããïŒâã«ã«ããã·âïŒâããã¢ãã³ãŒã³ã¹ã«ã
ãã«ã¯ãã©ã€ããïœâã«ã«ããã·ãã³ãŒã³ã¹ã«ã
ãã«ã¯ãã©ã€ããïŒâã¢ããâïŒâã¡ãã«ãã³ãŒ
ã³ã¹ã«ããã«ã¯ãã©ã€ãããã¿ãªã«ã¯ãã©ã€ãã
ïœâããããã³ãŸã€ã«ã¯ãã©ã€ãããã³ãŸã€ã«ã¯
ãã©ã€ãããšãã«ã¯ããã«ãŒãããŒããããã€ã«
ã¯ãã©ã€ãçãå å«ãããã ãŸãããã²ã³åéä¹³å€ãäœæããããã«èŠªæ°Žæ§
ã³ãã€ããšããŠãåèšã®åŠãèªå°äœãŒã©ãã³ãã
ã³éåžžã®åççšãŒã©ãã³ã®ä»ãå¿ èŠã«å¿ããŠã³ã
ã€ãç¶ã¢ã«ããã³ãå¯å€©ãã¢ã©ãã¢ãŽã ãããã¹
ãã©ã³ãã¢ã«ã®ã³é žãäŸãã°ã¢ã»ãã«å«é19ã26
ïŒ ã«ãŸã§å æ°Žå解ãããã»ã«ããŒã¹ã¢ã»ããŒãã®
åŠãã»ã«ããŒã¹èªå°äœãããªã¢ã¯ãªã«ã¢ãããã€
ããåããªã¢ã¯ãªã«ã¢ãããã«ãŒã€ã³ãäŸãã°ã
ãã«ã¢ã«ã³ãŒã«ãŒããã«ã·ã¢ãã¢ã»ããŒãã³ããª
ããŒã®åŠããŠã¬ã¿ã³ã«ã«ãã³é žåºãŸãã¯ã·ã¢ãã¢
ã»ãã«åºãå«ãããã«ã¢ã«ã³ãŒã«ããªããŒãããª
ããã«ã¢ã«ã³ãŒã«ãŒããªããã«ãããªãã³ãå æ°Ž
å解ããªããã«ã¢ã»ããŒããèçœè³ªãŸãã¯é£œåã¢
ã·ã«åèçœè³ªãšããã«åºãæããã¢ãããŒãšã®é
åã§åŸãããããªããŒãããªããã«ããªãžã³ãã
ãªããã«ã¢ãã³ãããªã¢ãããšãã«ã¡ã¿ã¯ãªã¬ãŒ
ããããªãšãã¬ã³ã€ãã³çã䜿çšããããšãã§ã
ãã æ¬çºæã®ããã²ã³åéä¹³å€ã«ã¯ãå¡åžå©å€ã垯
é»é²æ¢ãã¹ããªæ§æ¹è¯ãä¹³ååæ£ãæ¥çé²æ¢ãã
ã³åçæ§æ¹è¯ïŒäŸãã°çŸåä¿é²ã硬調åãå¢æïŒ
ãªã©çš®ã ã®ç®çã§çš®ã ã®å ¬ç¥ã®çé¢æŽ»æ§å€ãå«ã
ã§ãããã ããªãã¡ãç±³åœç¹èš±ç¬¬2240472å·ãåç2831766
å·ãå第3158484å·ãå第3210191å·ãå第
3294540å·ãå第3507660å·ãè±åœç¹èš±ç¬¬1012495
å·ãå第1022878å·ãå第1179290å·ãå第
1198450å·ãç±³åœç¹èš±ç¬¬2739891å·ãå第2823123
å·ãå第1179290å·ãå第1198450å·ãå第
2739891å·ãå第2823123å·ãå第3068101å·ãå
第3415649å·ãå第3666478å·ãå第3756828å·ã
è±åœç¹èš±ç¬¬1397218å·ãå第3113816å·ãå第
3411413å·ãå第3473174å·ãå第3345974å·ãå
第3726683å·ãå第3843368å·ããã«ã®ãŒç¹èš±ç¬¬
731126å·ãè±åœç¹èš±ç¬¬1138514å·ãå第1159825
å·ãå第1374780å·ãç±³åœç¹èš±ç¬¬2271623å·ãå第
2288226å·ãå第2944900å·ãå第3235919å·ãå
第3671247å·ãå第3772021å·ãå第3589906å·ã
å第3666478å·ãå第3754924å·ã西ç¬ç¹èš±åºé¡
OLS1961683å·åæ现æžããã³ç¹éæ50â117414
å·ãå50â59025å·ãç¹å ¬æ40â378å·ãå40â
379å·ãå43â13822å·åå ¬å ±ã«èšèŒãããŠããã
äŸãã°ãµããã³ïŒã¹ããã€ãç³»ïŒãã¢ã«ãã¬ã³ãª
ããµã€ãèªå°äœïŒäŸãã°ããªãšãã¬ã³ã°ãªã³ãŒ
ã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ïŒããªãããã¬ã³ã°
ãªã³ãŒã«çž®åç©ãããªãšãã¬ã³ã°ãªã³ãŒã«ã¢ã«ã
ã«ãŸãã¯ã¢ã«ãã«ã¢ãªãŒã«ãšãŒãã«ããªãšãã¬ã³
ã°ãªã³ãŒã«ãšã¹ãã«é¡ãããªãšãã¬ã³ã°ãªã³ãŒã«
ãœã«ãã¿ã³ãšã¹ãã«é¡ãããªã¢ã«ãã¬ã³ã°ãªã³ãŒ
ã«ã¢ã«ãã«ã¢ãã³ãŸãã¯ã¢ããé¡ãã·ãªã³ãŒã³ã®
ããªãšãã¬ã³ãªããµã€ãä»å ç©é¡ïŒãã°ãªã·ããŒ
ã«èªå°äœïŒäŸãã°ã¢ã«ã±ãã«ã³ãã¯é žããªã°ãªã»
ãªããã¢ã«ãã«ããšããŒã«ããªã°ãªã»ãªãïŒãå€
䟡ã¢ã«ã³ãŒã«ã®èèªé žãšã¹ãã«é¡ãç³ã®ã¢ã«ãã«
ãšã¹ãã«é¡ãåãããŠã¬ã¿ã³é¡ãŸãã¯ãšãŒãã«é¡
ãªã©ã®éã€ãªã³æ§çé¢æŽ»æ§å€ãããªãã«ããã€ã
ç³»ãµããã³ãã¢ã«ãã«ã«ã«ãã³é žå¡©ãã¢ã«ãã«ã
ã³ãŒã³ã¹ã«ããªã³é žå¡©ãã¢ã«ãã«ããã¿ã¬ã³ã¹ã«
ããªã³é žå¡©ãã¢ã«ãã«ç¡«é žãšã¹ãã«é¡ãã¢ã«ãã«
ãªã³é žãšã¹ãã«é¡ãâã¢ã·ã«ââã¢ã«ãã«ã¿
ãŠãªã³é¡ãã¹ã«ãã³ãã¯é žãšã¹ãã«é¡ãã¹ã«ãã¢
ã«ãã«ããªãªãã·ãšãã¬ã³ã¢ã«ãã«ããšãã«ãšãŒ
ãã«é¡ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãªã³é žãšã¹
ãã«é¡ãªã©ã®ãããªã«ã«ããã·ãã¹ã«ãåºããã¹
ãåºãç¡«é žãšã¹ãã«åºããªã³é žãšã¹ãã«åºçã®é ž
æ§åºãå«ãã¢ããªã³çé¢æŽ»æ§å€ãã¢ããé žé¡ãã¢
ããã¢ã«ãã«ã¹ã«ãã³é žé¡ãã¢ããã¢ã«ãã«ç¡«é ž
ãŸãã¯ãªã³é žãšã¹ãã«é¡ãã¢ã«ãã«ãã¿ã€ã³é¡ã
ã¢ãã³ã€ããé¡ãã¢ãã³ãªãã·ãé¡ãªã©ã®äž¡æ§ç
é¢æŽ»æ§å€ãã¢ã«ãã«ã¢ãã³å¡©é¡ãèèªææãã¯è³
éŠæ第ïŒçŽã¢ã³ã¢ããŠã å¡©é¡ãããªãžãŠã ãã€ã
ããŸãªãŠã ãªã©ã®è€çŽ ç°ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©é¡
ããã³èèªæãŸãã¯è€çŽ ç°ãå«ãã¹ã«ãããŠã ãŸ
ãã¯ã¹ã«ãããŠã å¡©é¡ãªã©ã®ã«ããªã³çé¢æŽ»æ§å€
ãçšããããšãã§ããã æ¬çºæã®ããã²ã³åéä¹³å€ã«ã¯ãçŸåä¿é²å€ãš
ããŠãåèšã®çé¢æŽ»æ§å€ã®ä»ã«è¥¿ç¬ç¹èš±åºé¡
ïŒOLSïŒ2002871å·ãå第2445611å·ãå第
2360878å·ãè±åœç¹èš±ç¬¬1352196å·åæ现æžãªã©ã«
èšèŒãããŠããã€ãããŸãŒã«é¡ãããªãšãŒãã«
é¡ãã»ã¬ããšãŒãã«é¡ãªã©ãå«æããŠãããã ãŸãæ¬çºæã®ããã²ã³åéä¹³å€ãã«ã©ãŒçšã®æ
å ææã«é©çšããã«ã¯ãæ¬çºæã«ä¿ãç·ææ§ã®ã
ãã²ã³åéä¹³å€ãèµ€ææ§ããã³éææ§ã«èª¿ç¯ãã
ãããã²ã³åéä¹³å€ã«ããŒã³ã¿ãã·ã¢ã³ããã³ã€
ãšããŒã«ãã©ãŒãããããçµåãããŠå«æããã
ããªã©ã«ã©ãŒçšæå ææã«äœ¿çšãããææ³ããã³
çŽ æãå åœããã°ãããã«ãã©ãŒã¯ååäžã«ãã©
ã¹ãåºãšåŒã°ããçæ°Žåºãæããéæ¡æ£æ§ã®ãã®
ãæãŸãããã«ãã©ãŒã¯éã€ãªã³ã«å¯ŸãïŒåœéæ§
ãããã¯ïŒåœéæ§ã®ã©ã¡ãã§ãããããŸãè²è£æ£
ã®å¹æããã€ã«ã©ãŒãã«ãã©ãŒãæãã¯çŸåã«ãš
ããªã€ãŠçŸåæå¶å€ãæŸåºããã«ãã©ãŒïŒããã
ãDIRã«ãã©ãŒïŒãå«ãã§ããããæŽã«ã«ãã©ãŒ
ã¯ã«ãããªã³ã°åå¿ã®çæç©ãç¡è²ã§ãããããª
ã«ãã©ãŒã§ãããã é»è²çºè²ã«ãã©ãŒãšããŠã¯å ¬ç¥ã®ééã±ãã¡ã
ã¬ã³ç³»ã«ãã©ãŒãçšããããšãã§ããããããã®
ãã¡ãã³ãŸã€ã«ã¢ã»ãã¢ããªãç³»ããã³ãããã€
ã«ã¢ã»ãã¢ããªãç³»ååç©ã¯æå©ã§ãããçšãåŸ
ãé»è²çºè²ã«ãã©ãŒã®å ·äœäŸã¯ãç±³åœç¹èš±ç¬¬
2875057å·ãå第3265506å·ãå第3408194å·ãå
第3551155å·ãå第3582322å·ãå第3725072å·ã
å第3891445å·ã西ç¬ç¹èš±ç¬¬1547868å·ã西ç¬ç¹èš±
åºé¡ïŒOLSïŒ2213461å·ãå第2219917å·ãå第
2261361å·ãå第2414006å·ãå第2263875å·ãªã©
ã«èšèŒããããã®ã§ããã ããŒã³ã¿çºè²ã«ãã©ãŒãšããŠã¯ãã©ãŸãã³ç³»å
åç©ãã€ã³ããŸãã³ç³»ååç©ãã·ã¢ãã¢ã»ãã«å
åç©ãªã©ãçšããããšãã§ããç¹ã«ãã©ãŸãã³ç³»
ååç©ã¯æå©ã§ãããçšãåŸãããŒã³ã¿çºè²ã«ã
ã©ãŒã®å ·äœäŸã¯ãç±³åœç¹èš±ç¬¬2600788å·ãå第
2983608å·ãå第3062653å·ãå第3127269å·ãå
第3311476å·ãå第3419391å·ãå第3519429å·ã
å第3558319å·ãå第3582322å·ãå第3615506å·ã
å第3834908å·ãå第3891445å·ã西ç¬ç¹èš±ç¬¬
1810464å·ã西ç¬ç¹èš±åºé¡ïŒOLSïŒ2408665å·ã
å第2417945å·ãå第2418959å·ãå第2424467å·ã
ç¹å ¬æ40â6031å·ãªã©ã«èšèŒã®ãã®ã§ããã ã·ã¢ã³çºè²ã«ãã©ãŒãšããŠã¯ããšããŒã«ç³»åå
ç©ãããããŒã«ç³»ååç©ãªã©ãçšããããšãã§ã
ãããã®å ·äœäŸã¯ç±³åœç¹èš±ç¬¬2369929å·ãå第
2434272å·ãå第2474293å·ãå第2521908å·ãå
第2895826å·ãå第3034892å·ãå第3311476å·ã
å第3458315å·ãå第3476563å·ãå第3583971å·ã
å第3591383å·ãå第3767411å·ã西ç¬ç¹èš±åºé¡
ïŒOLSïŒ2414830å·ãå第2454329å·ãç¹éæ48â
59838å·ã«èšèŒããããã®ã§ããã ã«ã©ãŒãã»ã«ãã©ãŒãšããŠã¯ãäŸãã°ç±³åœç¹èš±
第3476560å·ãå第2521908å·ãå第3034892å·ã
ç¹å ¬æ44â2016å·ãå38â22335å·ãå42â11304
å·ãå44â32461å·ãç¹é¡æ49â98469å·æ现æžã
å50â118029å·æ现æžã西ç¬ç¹èš±åºé¡ïŒOLSïŒ
2418959å·ã«èšèŒã®ãã®ã䜿çšã§ããã DIRã«ãã©ãŒãšããŠã¯ãäŸãã°ç±³åœç¹èš±ç¬¬
3227554å·ãå第3617291å·ãå第3701783å·ãå
第3790384å·ãå第3632345å·ã西ç¬ç¹èš±åºé¡
ïŒOLSïŒ2414006å·ãå第2454301å·ãå第
2454329å·ãè±åœç¹èš±ç¬¬953454å·ãç¹é¡æ50â
146570å·ã«èšèŒããããã®ã䜿çšã§ããã DIRã«ãã©ãŒä»¥å€ã«çŸåã«ãšããªã€ãŠçŸåæå¶
ãæŸåºããååç©ãæå ææäžã«å«ãã§ãããã
äŸãã°ç±³åœç¹èš±ç¬¬3297445å·ãå第3379529å·ã西
ç¬ç¹èš±åºé¡ïŒOLSïŒ2417914å·ã«èšèŒã®ãã®ã䜿
çšã§ããããã®ä»ç¹éæ55â85549å·ãå57â
94752å·ãå56â65134å·ãå56â135841å·ãå54
â130716å·ãå56â133734å·ãå56â135841å·ã
ç±³åœç¹èš±ç¬¬4310618å·ãè±åœç¹èš±ç¬¬2083640å·ããª
ãµãŒãã»ãã€ã¹ã¯ããŒãžã€ãŒãNo.18360ïŒ1979幎ïŒ
No.14850ïŒ1980幎ïŒãNo.19033ïŒ1980幎ïŒãNo.19146
ïŒ1980幎ïŒãNo.20525ïŒ1981幎ïŒãNo.21728ïŒ1982幎ïŒ
ã«èšèŒãããã«ãã©ãŒã䜿çšããããšãã§ããã äžèšã®ã«ãã©ãŒã¯ãåäžå±€ã«äºçš®ä»¥äžå«ãããš
ãã§ããããŸãåäžã®ååç©ãç°ãªãïŒã€ä»¥äžã®
å±€ã«å«ãã§ãããã ã«ãã©ãŒãããã²ã³åéä¹³å€å±€ã«å°å ¥ããã«ã¯
å ¬ç¥ã®æ¹æ³ãäŸãã°ç±³åœç¹èš±ç¬¬2322027å·ã«èšèŒ
ã®æ¹æ³ãªã©ãçšãããããäŸãã°ãã¿ãŒã«é žã¢ã«
ãã«ãšã¹ãã«ïŒãžããã«ãã¿ã¬ãŒãããžãªã¯ãã«
ãã¿ã¬ãŒããªã©ïŒããªã³é žãšã¹ãã«ïŒãžããšãã«
ããªã¹ããšãŒããããªããšãã«ããªã¹ããšãŒãã
ããªã¯ã¬ãžã«ããªã¹ããšãŒãããžãªã¯ãã«ããã«
ããªã¹ããšãŒãïŒãã¯ãšã³é žãšã¹ãã«ïŒäŸãã°ã¢
ã»ãã«ã¯ãšã³é žããªããã«ïŒãå®æ¯éŠé žãšã¹ãã«
ïŒäŸãã°å®æ¯éŠé žãªã¯ãã«ïŒãã¢ã«ãã«ã¢ããïŒäŸ
ãã°ãžãšãã«ã©ãŠãªã«ã¢ããïŒãªã©ããŸãã¯æ²žç¹
çŽ30âä¹è³150âã®ææ©æº¶åªãäŸãã°é ¢é žãšãã«ã
é ¢é žããã«ã®åŠãäœçŽã¢ã«ãã«ã¢ã»ããŒãããã
ããªã³é žãšãã«ãïŒçŽããã«ã¢ã«ã³ãŒã«ãã¡ãã«
ã€ãœããã«ã±ãã³ãβâãšããã·ãšãã«ã¢ã»ããŒ
ããã¡ãã«ã»ããœã«ãã¢ã»ããŒãçã«æº¶è§£ããã®
ã¡ã芪氎æ§ã³ãã€ãã«åæ£ããããäžèšã®é«æ²žç¹
ææ©æº¶åªãšäœæ²žç¹ææ©æº¶åªãšãæ··åããŠçšããŠã
ããã ã«ãã©ãŒãã«ã«ãã³é žãã¹ã«ããªã³é žã®åŠãé ž
åºãæããå Žåã«ã¯ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãšããŠèŠª
åæ§ã³ãã€ãäžã«å°å ¥ãããã ãããã®ã«ãã©ãŒã¯ãäžè¬ã«ããã²ã³åéä¹³å€
å±€äžã®éïŒã¢ã«åœãïŒÃ10-3ã¢ã«ä¹è³ïŒÃ10-1ã¢
ã«ã奜ãŸããã¯ïŒÃ10-2ã¢ã«ä¹è³ïŒÃ10-1ã¢ã«æ·»
å ãããã æ¬çºæãçšããŠäœãããæå ææã¯è²ã«ããªé²
æ¢å€ãšããŠãã€ããããã³èªå°äœãã¢ããããšã
ãŒã«èªå°äœã没é£åèªå°äœãã¢ã¹ã³ã«ãã³é žèªå°
äœãªã©ãå«æããŠãããããã®å ·äœäŸã¯ç±³åœç¹èš±
第2360290å·ãå第2336327å·ãå第2403721å·ã
å第2418613å·ãå第2675314å· å第2701197å·ã
å第2704713å· å第2728659å·ãå第2732300å·
å第2735765å·ãç¹éæ50â92988å·ãå50â
92989å·ãå50â93928å·ãå50â110337å·ãç¹å ¬
æ50â23813å·çã«èšèŒãããŠããã 垯é»é²æ¢å€ãšããŠã¯ãžã¢ã»ãã«ã»ã«ããŒã¹ãã¹
ãã¬ã³ããŒãã«ãªãã¢ã«ãã«ãªãžãŠã ãã¬ãšãŒã
å ±éåäœãã¹ãã¬ã³âç¡æ°Žãã¬ã€ã³é žå ±éåäœãš
ïœâã¢ãããã³ãŒã³ã¹ã«ãã³é žãšã®åå¿ç©ã®ã¢ã«
ã«ãªå¡©çãæå¹ã§ããããããå€ãšããŠã¯ããªã¡
ã¿ã¢ã¯ãªã«é žã¡ãã«ãããªã¹ãã¬ã³ããã³ã¢ã«ã«
ãªå¯æº¶æ§ããªããŒãªã©ãæããããããŸãæŽã«ã³
ãã€ãç¶é žåçªçŽ ã®äœ¿çšãå¯èœã§ããããŸãèç©
æ§ãåäžããããã«æ·»å ããã©ããã¯ã¹ãšããŠã¯
ã¢ã¯ãªã«é žãšã¹ãã«ãããã«ãšã¹ãã«çãšä»ã®ãš
ãã¬ã³åºãæã€åéäœãšã®å ±éåäœãæããããš
ãã§ããããŒã©ãã³å¯å¡å€ãšããŠã¯ã°ãªã»ãªã³ã
ã°ãªã³ãŒã«ç³»ååç©ãæããããšãã§ããå¢ç²å€
ãšããŠã¯ã¹ãã¬ã³âãã¬ã€ã³é žãœãŒãå ±éåäœã
ã¢ã«ãã«ããã«ãšãŒãã«ãŒãã¬ã€ã³é žå ±éåäœç
ãæããããã äžèšã®ããã«ããŠèª¿æŽãããããã²ã³åéä¹³å€
ãçšããŠäœãããæå ææã®æ¯æäœãšããŠã¯ãäŸ
ãã°ãã©ã€ã¿çŽãããªãšãã¬ã³è¢«èŠçŽãããªãã
ãã¬ã³åæçŽãã¬ã©ã¹çŽãã»ã«ããŒã¹ã¢ã»ããŒ
ããã»ã«ããŒã¹ãã€ãã¬ãŒããããªããã«ã¢ã»ã¿
ãŒã«ãããªãããã¬ã³ãäŸãã°ããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒãçã®ããªãšã¹ãã«ãã€ã«ã ãããªã¹ã
ã¬ã³çãããããããã®æ¯æäœã¯ããããã®æå
ææã®äœ¿çšç®çã«å¿ããŠé©å®éžæãããã ãããã®æ¯æäœã¯ãå¿ èŠã«å¿ããŠäžåŒå å·¥ãæœ
ãããã æ¬çºæã®ããã²ã³åéä¹³å€ãçšããŠäœãããæ
å ææã¯é²å åŸãéåžžçšããããå ¬ç¥ã®æ¹æ³ã«ã
ãçŸååŠçããããšãã§ããã é»çœçŸå液ã¯ãããããã·ãã³ãŒã³é¡ãã¢ãã
ããšããŒã«é¡ãã¢ãããã³ãŒã³é¡çã®çŸåäž»è¬ã
å«ãã¢ã«ã«ãªæº¶æ¶²ã§ããããã®ä»ã¢ã«ã«ãªéå±å¡©
ã®äºç¡«é žå¡©ãçé žå¡©ãéäºç¡«é žå¡©ãèåç©ããã³
æ²åç©çãå«ãããšãã§ããããŸã該æå ææã
ã«ã©ãŒçšã®å Žåã«ã¯éåžžçšããããçºè²çŸåæ³ã§
çºè²çŸåããããšãã§ãããå転æ³ã§ã¯ãŸãé»è²
ãã¬çŸå液ã§çŸåãã次ãã§çœè²é²å ãäžããã
æãã¯ã«ããªå€ãå«æãã济ã§åŠçããæŽã«çºè²
çŸåäž»è¬ãå«ãã¢ã«ã«ãªçŸå液ã§çºè²çŸåããã
åŠçæ¹æ³ã«ã€ããŠã¯ç¹ã«å¶éã¯ãªããããããåŠ
çæ¹æ³ãé©çšã§ããããäŸãã°ãã®ä»£è¡šçãªãã®
ãšããŠã¯ãçºè²çŸååŸãæŒçœå®çåŠçãè¡ãªãå¿
èŠã«å¿ããããã«æ°ŽæŽãå®å®åŠçãè¡ãªãæ¹åŒã
æãã¯çºè²çŸååŸãæŒçœãšå®çãåé¢ããŠè¡ãªã
å¿ èŠã«å¿ããŠãããã«æ°ŽæŽãå®å®åŠçãè¡ãªãæ¹
åŒãé©çšããããšãã§ããã åè¿°ã®ããã²ã³åéä¹³å€ã¯åçæ床ãèããé«
ãããããé«ç §åºŠçæéé²å ã«å¯Ÿããç¹æ§ãæ¹è¯
ããããã€ã«ããªãå°ãªãããå€ãã®æå ææã«
奜ãŸããé©çšãããã äŸãã°æ¬çºæã«ä¿ãæå ææã¯çœé»äžè¬çšã
ã¬ã€çšãã«ã©ãŒçšãèµ€å€çšããã€ã¯ãçšãéè²çŽ
æŒçœæ³çšãå転çšãæ¡æ£è»¢åæ³çšçã®çš®ã ã®çšé
ã®æå ææã«æå¹ã«é©çšããããšãã§ããã 次ã«ãå®æœäŸããããŠæ¬çºæãå ·äœçã«èª¬æã
ãããæ¬çºæã¯ãããã«ãã€ãŠéå®ããããã®ã§
ã¯ãªãã å®æœäŸ ïŒ ç¹éæ57â154232å·å ¬å ±ã«èšèŒãããŠããæ¹æ³
ãšåæ§ã®æ¹æ³ã«åŸã€ãŠãå¹³åç²åŸã0.56ÎŒã®åå
é¢äœçµæ¶ã®ããã²ã³åéç²åãããªãæ²èåéä¹³
å€ïŒæ²åéå«æçïŒã¢ã«ïŒ ãç²åºŠååžïŒ³ïŒïŒ
0.15ïŒã§ãã€ãŠãæ²åéãäžèšããã²ã³åéç²å
äžã«åäžã«ååžããŠããä¹³å€ïŒä¹³å€ïŒ¡ãšããïŒ
ãšãåã0.02ÎŒã®èåéã®ã·ãšã«ã«ãã€ãŠè¢«èŠã
ããŠããã³ã¢ã»ã·ãšã«åèæ²åéä¹³å€ïŒå¹³åç²åŸ
0.58ÎŒãç²åºŠååžïŒ³ïŒïŒ0.14ãæ²åéå«æçïŒ
ã¢ã«ïŒ ïŒïŒä¹³å€ïŒ¢ãšããïŒãšããããã調æŽããã ãã®ããã«ããŠèª¿æŽãããä¹³å€ïŒ¡ããã²ïŒ¢ãå
å²ãã第ïŒè¡šã«ç€ºãããã«åä¹³å€ã«å¯ŸããŠããã
ããæ¬çºæã«ä¿ãå¢æè²çŽ ïŒåèšäžè¬åŒããã
ããããã³ããã§è¡šããããå¢æè²çŽ ïŒãšã
ãªç¡«é žãããªãŠã ãå¡©åéé žãããªã·ã¢ã³é žã¢ã³
ã¢ããŠã ãæ·»å ããããããé©åãªæ¡ä»¶äžã«ååŠ
å¢æããã³åå å¢æãæœããã
åŠçå·¥çšïŒ38âïŒ åŠçæé
çºè²çŸå âŠïŒå45ç§
æŒ çœ âŠâŠïŒå30ç§
æ°Ž æŽ âŠâŠïŒå15ç§
å® ç âŠâŠïŒå30ç§
æ°Ž æŽ âŠâŠïŒå15ç§
å®å®å âŠâŠïŒå30ç§
ååŠçå·¥çšã«ãããŠäœ¿çšããåŠç液çµæã¯ãäž
èšã®åŠãã§ããã çºè²çŸå液çµæïŒ ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âããããã·ãšãã«ïŒâã¢ããªã³ç¡«é žå¡©
4.8ïœ ç¡æ°Žäºç¡«é žãããªãŠã 0.14ïœ ããããã·ã¢ãã³ã»1/2ç¡«é žå¡© 1.98ïœ ç¡« é ž 0.74mg ç¡æ°Žçé žã«ãªãŠã 28.85ïœ ç¡æ°Žçé žæ°ŽçŽ ã«ãªãŠã 3.46ïœ ç¡æ°Žäºç¡«é žã«ãªãŠã 5.10ïœ èåã«ãªãŠã 1.16ïœ å¡©åãããªãŠã 0.14ïœ ãããªãããªé ¢é žã»ïŒãããªãŠã å¡©ïŒïŒæ°Žå¡©ïŒ
1.20ïœ æ°Žé žåã«ãªãŠã 1.48ïœ æ°Žãå ããŠïŒãšããã æŒçœæ¶²çµæïŒ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã å¡©
100.0ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã å¡©
10.0ïœ èåã¢ã³ã¢ããŠã 150.0ïœ æ°·é ¢é ž 10.0ml æ°Žãå ããŠïŒãšããŠã¢ã³ã¢ãã¢æ°ŽãçšããŠPH
6.0ã«èª¿æŽããã å®ç液çµæïŒ ããªç¡«é žã¢ã³ã¢ããŠã 175.0ïœ ç¡æ°Žäºç¡«é žãããªãŠã 8.6ïœ ã¡ã¿äºç¡«é žãããªãŠã 2.3ïœ æ°Žãå ããŠïŒãšãé ¢é žãçšããŠPH6.0ã«èª¿æŽ
ããã å®å®å液çµæïŒ ãã«ããªã³ïŒ37ïŒ æ°Žæº¶æ¶²ïŒ 1.5ml ã³ãããã¯ã¹ïŒå°è¥¿å åçå·¥æ¥æ ªåŒäŒç€Ÿè£œïŒ
7.5ml æ°Žãå ããŠïŒãšããã åŸãããè²çŽ ç»åã«ã€ããŠãããããç·è²ãã€
ã«ã¿ãŒãéããŠæ¿åºŠæž¬å®ãè¡ãªãç·è²å æ床ãã
ã³ã«ããªãæ±ãããæ床ã¯ãã«ããªïŒ0.1ãã®å
åŠæ¿åºŠãäžããã®ã«å¿ èŠãªé²å éããæ±ãããåŸ
ãããçµæã第ïŒè¡šã«ç€ºããã
èšã®åŠãã§ããã çºè²çŸå液çµæïŒ ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââ
ïŒÎ²âããããã·ãšãã«ïŒâã¢ããªã³ç¡«é žå¡©
4.8ïœ ç¡æ°Žäºç¡«é žãããªãŠã 0.14ïœ ããããã·ã¢ãã³ã»1/2ç¡«é žå¡© 1.98ïœ ç¡« é ž 0.74mg ç¡æ°Žçé žã«ãªãŠã 28.85ïœ ç¡æ°Žçé žæ°ŽçŽ ã«ãªãŠã 3.46ïœ ç¡æ°Žäºç¡«é žã«ãªãŠã 5.10ïœ èåã«ãªãŠã 1.16ïœ å¡©åãããªãŠã 0.14ïœ ãããªãããªé ¢é žã»ïŒãããªãŠã å¡©ïŒïŒæ°Žå¡©ïŒ
1.20ïœ æ°Žé žåã«ãªãŠã 1.48ïœ æ°Žãå ããŠïŒãšããã æŒçœæ¶²çµæïŒ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã å¡©
100.0ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã å¡©
10.0ïœ èåã¢ã³ã¢ããŠã 150.0ïœ æ°·é ¢é ž 10.0ml æ°Žãå ããŠïŒãšããŠã¢ã³ã¢ãã¢æ°ŽãçšããŠPH
6.0ã«èª¿æŽããã å®ç液çµæïŒ ããªç¡«é žã¢ã³ã¢ããŠã 175.0ïœ ç¡æ°Žäºç¡«é žãããªãŠã 8.6ïœ ã¡ã¿äºç¡«é žãããªãŠã 2.3ïœ æ°Žãå ããŠïŒãšãé ¢é žãçšããŠPH6.0ã«èª¿æŽ
ããã å®å®å液çµæïŒ ãã«ããªã³ïŒ37ïŒ æ°Žæº¶æ¶²ïŒ 1.5ml ã³ãããã¯ã¹ïŒå°è¥¿å åçå·¥æ¥æ ªåŒäŒç€Ÿè£œïŒ
7.5ml æ°Žãå ããŠïŒãšããã åŸãããè²çŽ ç»åã«ã€ããŠãããããç·è²ãã€
ã«ã¿ãŒãéããŠæ¿åºŠæž¬å®ãè¡ãªãç·è²å æ床ãã
ã³ã«ããªãæ±ãããæ床ã¯ãã«ããªïŒ0.1ãã®å
åŠæ¿åºŠãäžããã®ã«å¿ èŠãªé²å éããæ±ãããåŸ
ãããçµæã第ïŒè¡šã«ç€ºããã
ç¡«é
žââã¡ãã«ã¢ããããšããŒã« ïŒïœ
ç¡æ°Žäºç¡«é
žãããªãŠã 50ïœ
ãã€ããããã³ ïŒïœ
çé
žãããªãŠã 29.5ïœ
èåã«ãªãŠã ïŒïœ
æ°Žãå ã㊠ïŒã«ãã
åŸãããéç»åã«ã€ããŠæ¿åºŠæž¬å®ãè¡ãªãé»è²
å æ床ããã³ã«ããªãæ±ãããæ床衚瀺æ³ã¯å®æœ
äŸïŒãšåæ§ã§ããã åŸãããçµæãäžèšç¬¬ïŒè¡šã«ç€ºããã
å æ床ããã³ã«ããªãæ±ãããæ床衚瀺æ³ã¯å®æœ
äŸïŒãšåæ§ã§ããã åŸãããçµæãäžèšç¬¬ïŒè¡šã«ç€ºããã
ãè¡šã
ãè¡šã
ãè¡šã
äžèšè¡šãããæãããªããã«ãæ¬çºæã«ä¿ãå
åæ£æ§ã®ããã²ã³åéä¹³å€ã«æ¬çºæã«ä¿ãå¢æè²
çŽ ãçµã¿åãããŠäœ¿çšããæ¬çºæè©ŠæïŒè©Šæ15ã
18ïŒã¯ãå€åæ£æ§ã®ããã²ã³åéä¹³å€ã«å¯ŸããŠå¢
æè²çŽ ãçµã¿åããçšããæ¯èŒè©ŠæïŒè©Šæ13ãã
ã³14ïŒã«æ¯ã¹ãŠæ床ãé«ãããŸãé«ç §åºŠçæéé²
å æã§ã®æ床ã®äœäžãå°ãªãããšãç解ã§ããã
åæ£æ§ã®ããã²ã³åéä¹³å€ã«æ¬çºæã«ä¿ãå¢æè²
çŽ ãçµã¿åãããŠäœ¿çšããæ¬çºæè©ŠæïŒè©Šæ15ã
18ïŒã¯ãå€åæ£æ§ã®ããã²ã³åéä¹³å€ã«å¯ŸããŠå¢
æè²çŽ ãçµã¿åããçšããæ¯èŒè©ŠæïŒè©Šæ13ãã
ã³14ïŒã«æ¯ã¹ãŠæ床ãé«ãããŸãé«ç §åºŠçæéé²
å æã§ã®æ床ã®äœäžãå°ãªãããšãç解ã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¯æäœäžã«ãå°ãªããšãïŒå±€ã®ããã²ã³åé
ä¹³å€å±€ãæããããã²ã³åéåçæå ææã«ãã
ãŠåèšããã²ã³åéä¹³å€å±€ã¯äžèšåŒ(A)ã§ç€ºããã
ç²åºŠååžãæããå®è³ªçã«ååæ£æ§ã®ããã²ã³å
éç²åãå«æãããŠããããã€è©²ããã²ã³åéç²
åã¯äžèšäžè¬åŒããã§ç€ºãããå°ãªããšãïŒçš®
ã®å¢æè²çŽ ãäžèšäžè¬åŒããã§ç€ºãããå°ãªã
ãšãïŒçš®ã®å¢æè²çŽ ããã³äžèšäžè¬åŒããã§ç€º
ãããå°ãªããšãïŒçš®ã®å¢æè²çŽ ãšãçµã¿åãã
ãŠå¢æãããŠããããšãç¹åŸŽãšããããã²ã³åé
åçæå ææã åŒ(A) ïŒâŠ0.20 ãããã§ïŒ³ããã³ã¯ãããã²ã³åéç²åã®ç²åºŠ
ååžã«ãããŠïŒ³ã¯æšæºåå·®ããã¯å¹³åç²åŸãè¡š
ããã ïŒâΣïŒÎ³âγiïŒ2niïŒÎ£ni ïŒÎ£niγiïŒÎ£ni riïŒïœçªç®ã®ç²åã®ç²åŸ niïŒïœçªç®ã®ç²åã®æ° ã§ç€ºããããã äžè¬åŒãã ãåŒäžãY1ãY2ãY3ããã³Y4ã¯ããããæ°ŽçŽ å
åãããã²ã³ååãããããã·ã«åºãã¢ã«ã³ãã·
åºãã¢ããåºãã¢ã·ã«ã¢ããåºãã¢ã·ã«ãªãã·
åºãã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ã«ã³ãã·ã«ã«ã
ãã«ã¢ããåºãã¢ãªãŒã«åºãã·ã¢ãåºãã¢ã«ãã«
åºãè¡šãããY1ãšY2ãŸãã¯Y3ãšY4ã®ã©ã¡ããäž
æ¹ã¯é£çµããŠç°ã圢æããããããªããµãŸãŒã«ç°
ã圢æããŠãããããŸãR1ã¯æ°ŽçŽ ååãŸãã¯ã¢
ã«ãã«åºãè¡šãããR2ããã³R3ã¯ããããã¢ã«
ãã«åºãè¡šãããX1 ã¯ã¢ããªã³ãè¡šãããïœ
ã¯ïŒãŸãã¯ïŒã®æŽæ°ãè¡šããããã ããïœãïŒã
è¡šãããšãã¯ãR2ãŸãã¯R3ã¯ååå å¡©ã圢æã
åŸãåºãè¡šãããã äžè¬åŒãã ãåŒäžãY5ãšY6ããã³Y7ãšY8ã¯ããããé£çµã
ãŠç°ã圢æããããããããããªããµãŸãŒã«ç°ã
圢æããåå矀ãè¡šããããŸãR4ã¯æ°ŽçŽ ååãŸ
ãã¯ã¢ã«ãã«åºãè¡šãããR5ããã³R6ã¯ããã
ãã¢ã«ãã«åºãè¡šãããX2 ã¯ã¢ããªã³ãè¡šã
ããïœã¯ïŒãŸãã¯ïŒã®æŽæ°ãè¡šããããã ããïœ
ãïŒãè¡šãããšãã¯ãR5ãŸãã¯R6ã¯ååå å¡©ã
圢æãåŸãåºãè¡šãããã äžè¬åŒãã ãåŒäžãY9ãY10ãY11ããã³Y12ã¯ããããæ°ŽçŽ
ååãããã²ã³ååãããããã·ã«åºãã¢ã«ã³ã
ã·åºãã¢ããåºãã¢ã·ã«ã¢ããåºãã¢ã·ã«ãªãã·
åºãã¢ã«ã³ãã·ã«ã«ããã«åºãã¢ã«ã³ãã·ã«ã«ã
ãã«ã¢ããåºãã¢ãªãŒã«åºãã·ã¢ãåºãã¢ã«ãã«
åºãè¡šãããY9ãšY10ããã³ïŒãŸãã¯Y11ãšY12ã¯
ããããé£çµããŠç°ã圢æãããããã€ãããŸãŒ
ã«ç°ã圢æããŠãããããŸãR7ã¯æ°ŽçŽ ååãŸã
ã¯ã¢ã«ãã«åºãè¡šãããR8ãR9ãR10ããã³R11
ã¯ããããã¢ã«ãã«åºãè¡šãããX3 ã¯ã¢ããª
ã³ãè¡šãããïœã¯ïŒãŸãã¯ïŒã®æŽæ°ãè¡šãããã
ã ããïœãïŒãè¡šãããšãã¯ãR8ãR9ãR10ãŸã
ã¯R11ã¯ååå å¡©ã圢æãåŸãåºãè¡šãããã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21890482A JPS59116646A (ja) | 1982-12-14 | 1982-12-14 | ããã²ã³åéåçæå ææ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21890482A JPS59116646A (ja) | 1982-12-14 | 1982-12-14 | ããã²ã³åéåçæå ææ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59116646A JPS59116646A (ja) | 1984-07-05 |
| JPH0313575B2 true JPH0313575B2 (ja) | 1991-02-22 |
Family
ID=16727130
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21890482A Granted JPS59116646A (ja) | 1982-12-14 | 1982-12-14 | ããã²ã³åéåçæå ææ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59116646A (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101598460B1 (ko) * | 2015-09-02 | 2016-02-29 | (죌) ìŒìŽìíµì | ê°ìì± ì©êž°ì ëŽêžŽ ììŽì€í¬ëŠŒì ìì¶ë°©ììŒë¡ ë°°ì¶íë ììŽì€í¬ëŠŒ ë¶ë°°êž° |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4725529A (en) | 1985-04-30 | 1988-02-16 | Konishiroku Photo Industry Co., Ltd. | Developing inhibitor arrangment in light-sensitive silver halide color photographic materials |
| CA1267557A (en) | 1985-05-16 | 1990-04-10 | Shigeharu Koboshi | Method for color-developing a silver halide photographic light-sensitive material |
| AU6892687A (en) * | 1986-01-23 | 1987-08-14 | Fuji Photo Film Co., Ltd. | Process for forming colored image |
| JPH0713732B2 (ja) * | 1986-02-18 | 1995-02-15 | ã³ãã«æ ªåŒäŒç€Ÿ | ç·è²åå æ床åã³è²æ±æãæ¹è¯ãããããã²ã³åéåçæå ææ |
| JPS62194252A (ja) * | 1986-02-20 | 1987-08-26 | Fuji Photo Film Co Ltd | ã«ã©âç»å圢ææ¹æ³ |
| JPS62267739A (ja) * | 1986-05-15 | 1987-11-20 | Konika Corp | é«éåŠçå¯èœãªããã²ã³åéåçæå ææ |
| JPH0348235A (ja) * | 1989-07-17 | 1991-03-01 | Fuji Photo Film Co Ltd | ããã²ã³åéåçä¹³å€ |
| EP1246000A1 (en) * | 2001-03-29 | 2002-10-02 | Agfa-Gevaert | Radiation-sensitive emulsion, silver halide photographic film material and radiographic intensifying screen-film combination |
| US6686142B2 (en) | 2001-03-29 | 2004-02-03 | Agfa-Gevaert | Radiation-sensitive emulsion, silver halide photographic film material and radiographic intensifying screen-film combination |
-
1982
- 1982-12-14 JP JP21890482A patent/JPS59116646A/ja active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101598460B1 (ko) * | 2015-09-02 | 2016-02-29 | (죌) ìŒìŽìíµì | ê°ìì± ì©êž°ì ëŽêžŽ ììŽì€í¬ëŠŒì ìì¶ë°©ììŒë¡ ë°°ì¶íë ììŽì€í¬ëŠŒ ë¶ë°°êž° |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59116646A (ja) | 1984-07-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4775617A (en) | Silver halide color photographic material containing monodispersed tabular silver halide grains | |
| JPS62160448A (ja) | ã«ã©âåçæå ææ | |
| JPS6365132B2 (ja) | ||
| JPH0422258B2 (ja) | ||
| JPS61245151A (ja) | ããã²ã³åéåçæå ææ | |
| JPH0378613B2 (ja) | ||
| JPH0431100B2 (ja) | ||
| JPH0313575B2 (ja) | ||
| JPS6365133B2 (ja) | ||
| JPH0322611B2 (ja) | ||
| JPH0437979B2 (ja) | ||
| JPS6167845A (ja) | ããã²ã³åéåçæå ææ | |
| JPH0456299B2 (ja) | ||
| JPH0610756B2 (ja) | ããã²ã³åéã«ã©âå転åçææ | |
| JPH0466013B2 (ja) | ||
| JPH0430572B2 (ja) | ||
| JPS61246739A (ja) | ããã²ã³åéåçæå ææ | |
| JPH04181939A (ja) | ããã²ã³åéä¹³å€åã³ãããçšããåçæå ææ | |
| JP796H (ja) | ããã²ã³åéåçæå ææ | |
| JPH0617986B2 (ja) | ããã²ã³åéåçæå ææ | |
| JP2849868B2 (ja) | ããã²ã³åéåçä¹³å€ã®è£œé æ¹æ³åã³ããã²ã³åéã«ã©ãŒåçæå ææ | |
| JP2516740B2 (ja) | ããã²ã³åéåçæå ææ | |
| JP2961717B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPS62115434A (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
| JPS6012541A (ja) | ããã²ã³åéåçæå ææ |