JPH028603B2 - - Google Patents
Info
- Publication number
- JPH028603B2 JPH028603B2 JP59129390A JP12939084A JPH028603B2 JP H028603 B2 JPH028603 B2 JP H028603B2 JP 59129390 A JP59129390 A JP 59129390A JP 12939084 A JP12939084 A JP 12939084A JP H028603 B2 JPH028603 B2 JP H028603B2
- Authority
- JP
- Japan
- Prior art keywords
- particles
- dispersion
- inorganic filler
- polymer
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002245 particle Substances 0.000 claims description 203
- 239000000203 mixture Substances 0.000 claims description 199
- 239000006185 dispersion Substances 0.000 claims description 180
- 239000002270 dispersing agent Substances 0.000 claims description 156
- 229920000642 polymer Polymers 0.000 claims description 140
- 239000007788 liquid Substances 0.000 claims description 125
- 239000011256 inorganic filler Substances 0.000 claims description 106
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 106
- 238000000465 moulding Methods 0.000 claims description 100
- 238000006116 polymerization reaction Methods 0.000 claims description 51
- 239000007787 solid Substances 0.000 claims description 44
- 239000010419 fine particle Substances 0.000 claims description 33
- 239000012530 fluid Substances 0.000 claims description 18
- 229920000620 organic polymer Polymers 0.000 claims description 10
- 230000000379 polymerizing effect Effects 0.000 claims description 7
- 238000010907 mechanical stirring Methods 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 222
- 239000000178 monomer Substances 0.000 description 102
- 239000000945 filler Substances 0.000 description 90
- 239000000377 silicon dioxide Substances 0.000 description 88
- 238000000034 method Methods 0.000 description 86
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 84
- 239000002131 composite material Substances 0.000 description 65
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 56
- 239000010954 inorganic particle Substances 0.000 description 49
- 239000000047 product Substances 0.000 description 48
- 239000011159 matrix material Substances 0.000 description 42
- 229920001577 copolymer Polymers 0.000 description 41
- 239000011230 binding agent Substances 0.000 description 35
- -1 i.e. Substances 0.000 description 34
- 230000000052 comparative effect Effects 0.000 description 31
- 239000000243 solution Substances 0.000 description 30
- 239000000835 fiber Substances 0.000 description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 21
- 239000000463 material Substances 0.000 description 21
- 239000000126 substance Substances 0.000 description 21
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 20
- 229920002554 vinyl polymer Polymers 0.000 description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 19
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 18
- 239000002253 acid Substances 0.000 description 16
- 238000003801 milling Methods 0.000 description 16
- 229920000728 polyester Polymers 0.000 description 16
- 239000004576 sand Substances 0.000 description 16
- 238000009826 distribution Methods 0.000 description 15
- 239000003999 initiator Substances 0.000 description 15
- 229920000647 polyepoxide Polymers 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 14
- 230000000694 effects Effects 0.000 description 14
- 238000007792 addition Methods 0.000 description 13
- 229910052906 cristobalite Inorganic materials 0.000 description 13
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 12
- 230000008901 benefit Effects 0.000 description 12
- 238000005266 casting Methods 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 12
- 230000008569 process Effects 0.000 description 12
- 150000004756 silanes Chemical class 0.000 description 12
- 239000002002 slurry Substances 0.000 description 12
- 239000011362 coarse particle Substances 0.000 description 11
- 239000003822 epoxy resin Substances 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 238000005452 bending Methods 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 10
- 239000000049 pigment Substances 0.000 description 10
- 239000006188 syrup Substances 0.000 description 10
- 235000020357 syrup Nutrition 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000004873 anchoring Methods 0.000 description 9
- 238000009835 boiling Methods 0.000 description 8
- 239000011162 core material Substances 0.000 description 8
- 230000009969 flowable effect Effects 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000000227 grinding Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 229920005604 random copolymer Polymers 0.000 description 7
- 230000002829 reductive effect Effects 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 239000005062 Polybutadiene Substances 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000012644 addition polymerization Methods 0.000 description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 239000003365 glass fiber Substances 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229920002857 polybutadiene Polymers 0.000 description 6
- 229920001228 polyisocyanate Polymers 0.000 description 6
- 239000005056 polyisocyanate Substances 0.000 description 6
- 239000004926 polymethyl methacrylate Substances 0.000 description 6
- 238000010992 reflux Methods 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 5
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 5
- 235000012211 aluminium silicate Nutrition 0.000 description 5
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 5
- 229920001400 block copolymer Polymers 0.000 description 5
- 125000002843 carboxylic acid group Chemical group 0.000 description 5
- 125000003700 epoxy group Chemical group 0.000 description 5
- 238000005227 gel permeation chromatography Methods 0.000 description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000006082 mold release agent Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- 239000004800 polyvinyl chloride Substances 0.000 description 5
- 229920000915 polyvinyl chloride Polymers 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- 230000009974 thixotropic effect Effects 0.000 description 5
- 239000011800 void material Substances 0.000 description 5
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 4
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- 229920005862 polyol Polymers 0.000 description 4
- 150000003077 polyols Chemical class 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- FPZQYYXSOJSITC-UHFFFAOYSA-N 1-(4-chlorophenyl)pyrrole-2,5-dione Chemical compound C1=CC(Cl)=CC=C1N1C(=O)C=CC1=O FPZQYYXSOJSITC-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- OTLNPYWUJOZPPA-UHFFFAOYSA-N 4-nitrobenzoic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000004342 Benzoyl peroxide Substances 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 3
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229960004050 aminobenzoic acid Drugs 0.000 description 3
- 150000008064 anhydrides Chemical class 0.000 description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 229940072282 cardura Drugs 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229960002887 deanol Drugs 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000012674 dispersion polymerization Methods 0.000 description 3
- RUZYUOTYCVRMRZ-UHFFFAOYSA-N doxazosin Chemical compound C1OC2=CC=CC=C2OC1C(=O)N(CC1)CCN1C1=NC(N)=C(C=C(C(OC)=C2)OC)C2=N1 RUZYUOTYCVRMRZ-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 150000002118 epoxides Chemical class 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000011152 fibreglass Substances 0.000 description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000013618 particulate matter Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 229920000768 polyamine Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 230000008707 rearrangement Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 229910021494 β-cristobalite Inorganic materials 0.000 description 3
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- 241001446467 Mama Species 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229920006243 acrylic copolymer Polymers 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 229920006125 amorphous polymer Polymers 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000012975 dibutyltin dilaurate Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000007496 glass forming Methods 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate group Chemical group C(C(=C)C)(=O)[O-] CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000010434 nepheline Substances 0.000 description 2
- 229910052664 nepheline Inorganic materials 0.000 description 2
- 229920003986 novolac Polymers 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 2
- 229920001195 polyisoprene Polymers 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
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- 239000000155 melt Substances 0.000 description 1
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- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052914 metal silicate Inorganic materials 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- YLOWTPHXXDJBAH-UHFFFAOYSA-N methyl 2-methylprop-2-enoate Chemical compound COC(=O)C(C)=C.COC(=O)C(C)=C YLOWTPHXXDJBAH-UHFFFAOYSA-N 0.000 description 1
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
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- 150000002762 monocarboxylic acid derivatives Chemical group 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
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- 238000010137 moulding (plastic) Methods 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 239000010450 olivine Substances 0.000 description 1
- 229910052609 olivine Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- CZYFDZPOVORIRJ-UHFFFAOYSA-N oxiran-2-amine Chemical compound NC1CO1 CZYFDZPOVORIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- IVDFJHOHABJVEH-UHFFFAOYSA-N pinacol Chemical compound CC(C)(O)C(C)(C)O IVDFJHOHABJVEH-UHFFFAOYSA-N 0.000 description 1
- LTEKQAPRXFBRNN-UHFFFAOYSA-N piperidin-4-ylmethanamine Chemical compound NCC1CCNCC1 LTEKQAPRXFBRNN-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000013001 point bending Methods 0.000 description 1
- 229920002863 poly(1,4-phenylene oxide) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005651 polypropylene glycol dimethacrylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000011417 postcuring Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- RLJWTAURUFQFJP-UHFFFAOYSA-N propan-2-ol;titanium Chemical compound [Ti].CC(C)O.CC(C)O.CC(C)O.CC(C)O RLJWTAURUFQFJP-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QGOKIEUFWNCGFO-UHFFFAOYSA-N propanoic acid;pyrrole-2,5-dione Chemical compound CCC(O)=O.O=C1NC(=O)C=C1 QGOKIEUFWNCGFO-UHFFFAOYSA-N 0.000 description 1
- XANRGTLFBAJYDA-UHFFFAOYSA-N propanoic acid;pyrrolidine-2,5-dione Chemical compound CCC(O)=O.O=C1CCC(=O)N1 XANRGTLFBAJYDA-UHFFFAOYSA-N 0.000 description 1
- 229960000380 propiolactone Drugs 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229920013730 reactive polymer Polymers 0.000 description 1
- 238000006462 rearrangement reaction Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052851 sillimanite Inorganic materials 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 239000010435 syenite Substances 0.000 description 1
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N tetraisopropyl titanate Substances CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
- C08G2/10—Polymerisation of cyclic oligomers of formaldehyde
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/10—Epoxy resins modified by unsaturated compounds
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB23751 | 1974-05-29 | ||
GB23751/74A GB1493393A (en) | 1974-05-29 | 1974-05-29 | Fluid curable compositions containing particulate fillers and composite polymeric materials obtained therefrom |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6084364A JPS6084364A (ja) | 1985-05-13 |
JPH028603B2 true JPH028603B2 (fr) | 1990-02-26 |
Family
ID=10200723
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP50063574A Expired JPS604202B2 (ja) | 1974-05-29 | 1975-05-29 | 無機充填剤を含む分散安定性及び流動性のよい成形用の有機単量体組成物及びその製造法 |
JP59129390A Granted JPS6084364A (ja) | 1974-05-29 | 1984-06-25 | 無機充填剤を含む有機重合体成形物品 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP50063574A Expired JPS604202B2 (ja) | 1974-05-29 | 1975-05-29 | 無機充填剤を含む分散安定性及び流動性のよい成形用の有機単量体組成物及びその製造法 |
Country Status (20)
Country | Link |
---|---|
JP (2) | JPS604202B2 (fr) |
AR (1) | AR212158A1 (fr) |
AT (1) | AT344987B (fr) |
BE (1) | BE829427A (fr) |
CA (1) | CA1065532A (fr) |
CH (1) | CH615692A5 (fr) |
DE (1) | DE2449656C2 (fr) |
DK (1) | DK152215C (fr) |
ES (1) | ES438078A1 (fr) |
FR (1) | FR2273040B1 (fr) |
GB (1) | GB1493393A (fr) |
HK (1) | HK29178A (fr) |
IE (1) | IE41339B1 (fr) |
IT (1) | IT1038488B (fr) |
LU (1) | LU72589A1 (fr) |
MY (1) | MY7800261A (fr) |
NL (1) | NL7506347A (fr) |
NO (1) | NO147033C (fr) |
SE (1) | SE411766B (fr) |
ZA (1) | ZA753140B (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04119705U (ja) * | 1991-04-11 | 1992-10-27 | オカモト株式会社 | タイヤ滑止め具の外側締付け具 |
Families Citing this family (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL83091C (fr) * | 1976-02-19 | 1900-01-01 | ||
DE2963907D1 (en) * | 1979-01-05 | 1982-11-25 | Ici Plc | Dispersions of siliceous solids in liquid organic media |
DE3172366D1 (en) | 1980-12-03 | 1985-10-24 | Ici Plc | Dental compositions |
EP0066951B1 (fr) * | 1981-05-15 | 1985-08-28 | Imperial Chemical Industries Plc | Procédé de moulage de composés thermodurcissables renforcés |
JPH0681798B2 (ja) * | 1982-10-05 | 1994-10-19 | デイナミート・ノーベル・アクチエンゲゼルシヤフト | 流動性で硬化可能な、液状のアクリル酸エステル及びメタクリル酸エステルのポリマー及び微細粒状無機填料を基礎とする注型樹脂 |
DE3331371A1 (de) * | 1982-10-05 | 1984-04-05 | Dynamit Nobel Ag, 5210 Troisdorf | Giessharze auf basis von acrylsaeureestern |
US5202075A (en) * | 1985-08-30 | 1993-04-13 | Imperial Chemical Industries Plc | Process for moulding articles from curable compositions |
GB8521652D0 (en) * | 1985-08-30 | 1985-10-02 | Ici Plc | Moulding articles & composition |
DE3531914A1 (de) * | 1985-09-07 | 1987-03-19 | Roehm Gmbh | Verfahren zur herstellung haertbarer giessharze |
DE3531913A1 (de) * | 1985-09-07 | 1987-03-19 | Roehm Gmbh | Haertbare giessharze |
DE3624142C1 (de) * | 1986-07-17 | 1988-02-25 | Dynamit Nobel Ag | Aluminiumhydroxid-gefuellte Giessharze auf Basis von Methacrylsaeureestern und ihre Verwendung |
GB8621796D0 (en) * | 1986-09-10 | 1986-10-15 | Ici Plc | Moulded article |
DE3817182A1 (de) * | 1988-05-20 | 1989-11-30 | Schock & Co Gmbh | Verfahren zur herstellung einer sandwichplatte |
DE3817224A1 (de) * | 1988-05-20 | 1989-11-30 | Schock & Co Gmbh | Sandwichplatte |
GB8907211D0 (en) * | 1989-03-30 | 1989-05-10 | Ici Plc | Composite materials |
US5164282A (en) * | 1989-04-17 | 1992-11-17 | Xerox Corporation | Processes for the preparation of toners |
JPH0380139A (ja) * | 1989-08-21 | 1991-04-04 | Inax Corp | 筒状人工大埋石の製造方法 |
DE4040602A1 (de) * | 1990-12-19 | 1992-07-02 | Schock & Co Gmbh | Gegossene kunststofformteile |
GB9119612D0 (en) * | 1991-09-13 | 1991-10-23 | Ici Plc | Fibre reinforced polymer composites |
EP0612333B1 (fr) * | 1991-11-15 | 2001-01-10 | Imperial Chemical Industries Plc | Compositions polymerisables |
US5519081A (en) * | 1991-11-15 | 1996-05-21 | Imperial Chemical Industries Plc | Polymerisable compositions |
DE4304494A1 (de) * | 1993-02-15 | 1994-08-18 | Blanco Gmbh & Co Kg | Aushärtbare Gießmassen |
DE4328545A1 (de) * | 1993-08-25 | 1995-03-02 | Roehm Gmbh | Hochgefüllte Kunststoff-Formkörper mit Graniteffekt |
GB9322810D0 (en) * | 1993-11-05 | 1993-12-22 | Ici Plc | Moulded composites |
DE4407321A1 (de) * | 1994-03-04 | 1995-09-07 | Blanco Gmbh & Co Kg | Kunststofformteile mit einer mit anorganischen Füllstoffen gefüllten Kunststoffmatrix |
DE4410526A1 (de) * | 1994-03-26 | 1995-09-28 | Blanco Gmbh & Co Kg | Gießbare, aushärtbare Masse, zur Herstellung von Kunststofformteilen |
IT1271177B (it) | 1994-06-01 | 1997-05-27 | Autohaas C V | Processo per preparare contrasti di colore su articoli ottenuti per stampaggio da composizioni polimerizzabili |
DE19503713A1 (de) * | 1995-02-04 | 1996-08-08 | Huels Chemische Werke Ag | Gießharze auf Basis von olefinisch ungesättigten Silanen und Metallsäureestern |
DE19513171A1 (de) * | 1995-04-07 | 1996-10-31 | Roehm Gmbh | Polymeres Verbundsystem |
WO1997000295A1 (fr) * | 1995-06-14 | 1997-01-03 | Nippon Shokubai Co., Ltd. | Polymere greffe a base de noir de carbone, son procede de production et son utilisation |
IT1277004B1 (it) | 1995-11-30 | 1997-11-04 | Atohaas Holding Cv | Processo per preparare contrasti di colore su articoli ottenuti per stampaggio da composizioni polimerizzabili |
IT1277005B1 (it) | 1995-11-30 | 1997-11-04 | Atohaas Holding Cv | Processo per preparare contrasti di colore su articoli ottenuti per stampaggio da composizioni polimerizzabili |
DE19812122A1 (de) | 1998-03-19 | 1999-09-30 | Blanco Gmbh & Co Kg | Gießmasse für die Herstellung von Sanitärformteilen |
GB9807180D0 (en) | 1998-04-04 | 1998-06-03 | Ecc Int Ltd | Pigment products |
JP3701480B2 (ja) | 1998-10-22 | 2005-09-28 | 株式会社ドペル | 高硬度軟質複合材 |
BR0009522A (pt) | 1999-04-01 | 2002-01-15 | Imerys Pigments Inc | Produto, composição de revestimento, e, métodos para revestir uma folha de papel e calandrar o papel para formar sobre ele um revestimento de lustro, e para produzir um produto de pigmento |
BR0009458A (pt) | 1999-04-01 | 2002-01-08 | Imerys Pigments Inc | Produto de pigmento para uma composição de revestimento de papel, processos para fabricar um produto de pigmento para uma composição de revestimento de papel, e para produzir um produto de pigmento, composição de revestimento para o uso na produção de revestimentos de brilho sobre papel e outros substratos, e, processo para revestir uma folha de papel e calandrar o papel para formar nele um revestimento de brilho |
US6554892B1 (en) | 1999-07-02 | 2003-04-29 | Imerys Kaolin, Inc. | Compositions and methods for making a coarse platey, high brightness kaolin product |
IT1316160B1 (it) * | 2000-01-07 | 2003-04-03 | Telma Guzzini S R L | Articoli stampati ad alto contenuto di filler e relativo processo dipreparazione |
GB0020182D0 (en) | 2000-08-17 | 2000-10-04 | Imerys Minerals Ltd | Particulate kaolin |
GB0020180D0 (en) | 2000-08-17 | 2000-10-04 | Imerys Minerals Ltd | Kaolin products and their production |
US6808559B2 (en) | 2002-02-26 | 2004-10-26 | Imerys Pigments, Inc. | Kaolin clay pigments suited to rotogravure printing applications and method for preparing the same |
US7589147B2 (en) | 2003-05-19 | 2009-09-15 | Nippon Shokubai Co., Ltd. | Resin composition for thermal conductive material and thermal conductive material |
WO2005071000A1 (fr) | 2004-01-23 | 2005-08-04 | Blanco Gmbh + Co Kg | Masse de coulee, en particulier pour la fabrication d'eviers de cuisine, d'elements sanitaires moules, de plans de travail de cuisine ou analogues |
US7247667B2 (en) * | 2004-03-23 | 2007-07-24 | E. I. Du Pont De Nemours And Company | Particle containing solid surface material |
IT1398823B1 (it) | 2010-03-17 | 2013-03-21 | Teuco Guzzini Spa | Procedimento per la realizzazione di materiale composito e materiale composito cosi' ottenibile |
ITBO20110179A1 (it) | 2011-04-06 | 2012-10-07 | Teuco Guzzini Spa | Procedimento per la realizzazione di un materiale composito |
AT516594B1 (de) * | 2014-11-26 | 2017-07-15 | Lenzing Akiengesellschaft | Verwendung von cellulosischen Fasern zur Herstellung von Kunststoffartikeln mittels Rotationsformen |
GB2568050A (en) * | 2017-11-01 | 2019-05-08 | Caesarstone Ltd | Compositions comprising an acrylic polymer and processes of preparing the same |
JP2021172775A (ja) * | 2020-04-28 | 2021-11-01 | タカラスタンダード株式会社 | 強化アクリル系人造大理石およびその製造法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4868683A (fr) * | 1971-12-22 | 1973-09-19 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3084068A (en) * | 1960-11-08 | 1963-04-02 | Du Pont | Process for acrylic polymerizations |
GB1156653A (en) * | 1965-06-10 | 1969-07-02 | Ici Ltd | Coated Particles |
US3488246A (en) * | 1966-08-31 | 1970-01-06 | Du Pont | Cast plastic simulated marble building product |
ZA705366B (en) * | 1969-08-15 | 1971-04-28 | Commw Scient Ind Res Org | Polymeric dispersants for minerals |
DE2312258C2 (de) * | 1972-03-21 | 1986-04-24 | Dentsply International Inc., York, Pa. | Dentalwerkstoffe für prothetische Zwecke |
-
1974
- 1974-05-29 GB GB23751/74A patent/GB1493393A/en not_active Expired
- 1974-10-18 DE DE2449656A patent/DE2449656C2/de not_active Expired - Lifetime
-
1975
- 1975-05-13 IE IE1071/75A patent/IE41339B1/xx unknown
- 1975-05-15 NO NO751728A patent/NO147033C/no unknown
- 1975-05-15 ZA ZA00753140A patent/ZA753140B/xx unknown
- 1975-05-23 BE BE156655A patent/BE829427A/fr not_active IP Right Cessation
- 1975-05-27 CA CA227,873A patent/CA1065532A/fr not_active Expired
- 1975-05-27 LU LU72589A patent/LU72589A1/xx unknown
- 1975-05-28 IT IT23833/75A patent/IT1038488B/it active
- 1975-05-28 AT AT408475A patent/AT344987B/de not_active IP Right Cessation
- 1975-05-28 FR FR7516650A patent/FR2273040B1/fr not_active Expired
- 1975-05-28 SE SE7506097A patent/SE411766B/xx not_active IP Right Cessation
- 1975-05-28 DK DK238975A patent/DK152215C/da not_active IP Right Cessation
- 1975-05-29 JP JP50063574A patent/JPS604202B2/ja not_active Expired
- 1975-05-29 CH CH692475A patent/CH615692A5/de not_active IP Right Cessation
- 1975-05-29 NL NL7506347A patent/NL7506347A/xx not_active Application Discontinuation
- 1975-05-30 ES ES438078A patent/ES438078A1/es not_active Expired
- 1975-05-30 AR AR259029A patent/AR212158A1/es active
-
1978
- 1978-06-08 HK HK291/78A patent/HK29178A/xx unknown
- 1978-12-31 MY MY1978261A patent/MY7800261A/xx unknown
-
1984
- 1984-06-25 JP JP59129390A patent/JPS6084364A/ja active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4868683A (fr) * | 1971-12-22 | 1973-09-19 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04119705U (ja) * | 1991-04-11 | 1992-10-27 | オカモト株式会社 | タイヤ滑止め具の外側締付け具 |
Also Published As
Publication number | Publication date |
---|---|
AT344987B (de) | 1978-08-25 |
DE2449656A1 (de) | 1975-12-04 |
DK152215B (da) | 1988-02-08 |
CA1065532A (fr) | 1979-10-30 |
CH615692A5 (en) | 1980-02-15 |
IE41339B1 (en) | 1979-12-05 |
JPS604202B2 (ja) | 1985-02-02 |
AR212158A1 (es) | 1978-05-31 |
SE411766B (sv) | 1980-02-04 |
BE829427A (fr) | 1975-11-24 |
NO751728L (fr) | 1975-12-02 |
DE2449656C2 (de) | 1992-10-22 |
NL7506347A (nl) | 1975-12-02 |
DK152215C (da) | 1988-08-08 |
ZA753140B (en) | 1976-04-28 |
JPS6084364A (ja) | 1985-05-13 |
MY7800261A (en) | 1978-12-31 |
GB1493393A (en) | 1977-11-30 |
NO147033C (no) | 1983-01-19 |
ES438078A1 (es) | 1977-02-01 |
JPS515383A (fr) | 1976-01-17 |
IE41339L (en) | 1975-11-29 |
DK238975A (da) | 1975-11-30 |
FR2273040B1 (fr) | 1981-03-20 |
LU72589A1 (fr) | 1976-11-11 |
HK29178A (en) | 1978-06-16 |
ATA408475A (de) | 1977-12-15 |
SE7506097L (sv) | 1975-11-30 |
NO147033B (no) | 1982-10-11 |
AU8146075A (en) | 1976-11-25 |
IT1038488B (it) | 1979-11-20 |
FR2273040A1 (fr) | 1975-12-26 |
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