JPH0228588B2 - Nnarukiruechirenjiaminruinoseizohoho - Google Patents
NnarukiruechirenjiaminruinoseizohohoInfo
- Publication number
- JPH0228588B2 JPH0228588B2 JP7916380A JP7916380A JPH0228588B2 JP H0228588 B2 JPH0228588 B2 JP H0228588B2 JP 7916380 A JP7916380 A JP 7916380A JP 7916380 A JP7916380 A JP 7916380A JP H0228588 B2 JPH0228588 B2 JP H0228588B2
- Authority
- JP
- Japan
- Prior art keywords
- heptane
- reaction mixture
- eda
- hydrocarbon solvent
- ethylenediamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 163
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 91
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 51
- 229930195733 hydrocarbon Natural products 0.000 claims description 49
- 150000002430 hydrocarbons Chemical class 0.000 claims description 49
- 239000011541 reaction mixture Substances 0.000 claims description 48
- 239000002904 solvent Substances 0.000 claims description 48
- 239000004215 Carbon black (E152) Substances 0.000 claims description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 29
- 150000001350 alkyl halides Chemical class 0.000 claims description 26
- 238000004821 distillation Methods 0.000 claims description 25
- 239000010410 layer Substances 0.000 claims description 23
- SCZVXVGZMZRGRU-UHFFFAOYSA-N n'-ethylethane-1,2-diamine Chemical compound CCNCCN SCZVXVGZMZRGRU-UHFFFAOYSA-N 0.000 claims description 22
- 239000012044 organic layer Substances 0.000 claims description 17
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 17
- 230000003113 alkalizing effect Effects 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 238000004508 fractional distillation Methods 0.000 claims description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 12
- 239000003513 alkali Substances 0.000 claims description 11
- 150000004820 halides Chemical class 0.000 claims description 11
- 239000002002 slurry Substances 0.000 claims description 10
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 9
- 239000012452 mother liquor Substances 0.000 claims description 9
- 239000000047 product Substances 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 9
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 claims description 8
- 238000004064 recycling Methods 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- -1 ethyl halide Chemical class 0.000 claims description 7
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 6
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 claims description 6
- 238000005804 alkylation reaction Methods 0.000 claims description 6
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 claims description 4
- 150000001348 alkyl chlorides Chemical class 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 230000003472 neutralizing effect Effects 0.000 claims description 3
- 238000009835 boiling Methods 0.000 description 22
- 239000007788 liquid Substances 0.000 description 14
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 11
- 229960003750 ethyl chloride Drugs 0.000 description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000012074 organic phase Substances 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000008346 aqueous phase Substances 0.000 description 6
- 238000010533 azeotropic distillation Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 3
- ULYZAYCEDJDHCC-UHFFFAOYSA-N isopropyl chloride Chemical compound CC(C)Cl ULYZAYCEDJDHCC-UHFFFAOYSA-N 0.000 description 3
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- MLRVZFYXUZQSRU-UHFFFAOYSA-N 1-chlorohexane Chemical compound CCCCCCCl MLRVZFYXUZQSRU-UHFFFAOYSA-N 0.000 description 1
- SQCZQTSHSZLZIQ-UHFFFAOYSA-N 1-chloropentane Chemical compound CCCCCCl SQCZQTSHSZLZIQ-UHFFFAOYSA-N 0.000 description 1
- KDRUIMNNZBMLJR-UHFFFAOYSA-N 2-isopropylaminoethylamine Chemical compound CC(C)NCCN KDRUIMNNZBMLJR-UHFFFAOYSA-N 0.000 description 1
- BXSMMAVTEURRGG-UHFFFAOYSA-N 3-chlorohexane Chemical compound CCCC(Cl)CC BXSMMAVTEURRGG-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 239000012455 biphasic mixture Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000002171 ethylene diamines Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229910001502 inorganic halide Inorganic materials 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- DFPGBRPWDZFIPP-UHFFFAOYSA-N n'-butylethane-1,2-diamine Chemical compound CCCCNCCN DFPGBRPWDZFIPP-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
- C07C209/06—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms
- C07C209/08—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/048,337 US4217308A (en) | 1978-01-30 | 1979-06-14 | Process for preparing N-alkylethylenediamines |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5645442A JPS5645442A (en) | 1981-04-25 |
| JPH0228588B2 true JPH0228588B2 (ja) | 1990-06-25 |
Family
ID=21954028
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7916380A Expired - Lifetime JPH0228588B2 (ja) | 1979-06-14 | 1980-06-13 | Nnarukiruechirenjiaminruinoseizohoho |
Country Status (10)
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5001267A (en) * | 1987-12-21 | 1991-03-19 | Texaco Chemical Company | Secondary alkyl amine derivatives of ethylenediamine |
| RU2146244C1 (ru) * | 1998-07-07 | 2000-03-10 | Открытое акционерное общество "Синтез" | Способ получения ингибитора солевой коррозии |
| JP4532083B2 (ja) * | 2003-07-28 | 2010-08-25 | 東ソー株式会社 | Ｎ−モノアルキル置換アルキレンアミンの製造方法 |
| JP4731915B2 (ja) * | 2004-01-07 | 2011-07-27 | 大日本住友製薬株式会社 | メチルウレア化合物の製造方法 |
| WO2010042168A2 (en) * | 2008-10-06 | 2010-04-15 | Dow Global Technologies Inc. | Methods for making ethanolamine(s) and ethyleneamine(s) from ethylene oxide and ammonia, and related methods |
| CN116102429B (zh) * | 2022-12-27 | 2025-01-28 | 沈阳化工研究院有限公司 | 一种连续化合成n-乙基乙二胺的工艺方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1129160B (de) * | 1959-06-04 | 1962-05-10 | Basf Ag | Verfahren zur Trennung von AEthylendiamin und Wasser |
| DE1130814B (de) * | 1959-12-03 | 1962-06-07 | Basf Ag | Verfahren zur kontinuierlichen Entwaesserung von AEthylendiaminen |
| DE2113208C3 (de) * | 1971-03-18 | 1974-04-25 | Th. Goldschmidt Ag, 4300 Essen | Octylaminderivate, deren Herstellung und Verwendung als Bioeide |
| SE381867B (sv) * | 1973-03-07 | 1975-12-22 | Mo Och Domsjoe Ab | Sett att avlegsna vatten fran en blandning av etylendiamin och vatten |
| DE2455678C3 (de) * | 1974-11-25 | 1979-05-10 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Tetramethyläthylendiamin |
| IL56176A (en) * | 1978-01-30 | 1982-03-31 | American Cyanamid Co | Process for preparing n-ethylethylenediamine |
-
1979
- 1979-07-23 DE DE19792929841 patent/DE2929841A1/de active Granted
- 1979-07-25 FR FR7919187A patent/FR2459224A1/fr active Granted
- 1979-07-27 CA CA332,700A patent/CA1128070A/en not_active Expired
- 1979-07-27 NL NL7905836A patent/NL189039C/xx not_active IP Right Cessation
- 1979-07-27 CH CH699179A patent/CH649075A5/de not_active IP Right Cessation
- 1979-07-27 BE BE0/196503A patent/BE877951A/fr not_active IP Right Cessation
- 1979-07-27 GB GB7926360A patent/GB2051040B/en not_active Expired
- 1979-07-27 BR BR7904851A patent/BR7904851A/pt not_active IP Right Cessation
- 1979-08-08 IE IE145179A patent/IE48914B1/en not_active IP Right Cessation
-
1980
- 1980-06-13 JP JP7916380A patent/JPH0228588B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| NL189039B (nl) | 1992-07-16 |
| GB2051040B (en) | 1983-10-12 |
| NL7905836A (nl) | 1980-12-16 |
| IE791451L (en) | 1980-12-14 |
| IE48914B1 (en) | 1985-06-12 |
| BE877951A (fr) | 1980-01-28 |
| DE2929841C2 (enrdf_load_stackoverflow) | 1989-11-09 |
| BR7904851A (pt) | 1981-01-27 |
| JPS5645442A (en) | 1981-04-25 |
| CH649075A5 (de) | 1985-04-30 |
| FR2459224A1 (fr) | 1981-01-09 |
| CA1128070A (en) | 1982-07-20 |
| GB2051040A (en) | 1981-01-14 |
| FR2459224B1 (enrdf_load_stackoverflow) | 1984-06-15 |
| NL189039C (nl) | 1992-12-16 |
| DE2929841A1 (de) | 1980-12-18 |
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