JP7495542B2 - 塗膜形成用組成物、塗膜及び粘着シート - Google Patents
塗膜形成用組成物、塗膜及び粘着シート Download PDFInfo
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- JP7495542B2 JP7495542B2 JP2023032747A JP2023032747A JP7495542B2 JP 7495542 B2 JP7495542 B2 JP 7495542B2 JP 2023032747 A JP2023032747 A JP 2023032747A JP 2023032747 A JP2023032747 A JP 2023032747A JP 7495542 B2 JP7495542 B2 JP 7495542B2
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- RTCOGUMHFFWOJV-UHFFFAOYSA-N nicosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(=O)N(C)C)=N1 RTCOGUMHFFWOJV-UHFFFAOYSA-N 0.000 description 1
- NVGOPFQZYCNLDU-UHFFFAOYSA-N norflurazon Chemical compound O=C1C(Cl)=C(NC)C=NN1C1=CC=CC(C(F)(F)F)=C1 NVGOPFQZYCNLDU-UHFFFAOYSA-N 0.000 description 1
- IOXAXYHXMLCCJJ-UHFFFAOYSA-N oxetan-3-yl 2-[(4,6-dimethylpyrimidin-2-yl)carbamoylsulfamoyl]benzoate Chemical compound CC1=CC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(=O)OC2COC2)=N1 IOXAXYHXMLCCJJ-UHFFFAOYSA-N 0.000 description 1
- 229960000321 oxolinic acid Drugs 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 229940070805 p-chloro-m-cresol Drugs 0.000 description 1
- FIKAKWIAUPDISJ-UHFFFAOYSA-L paraquat dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 FIKAKWIAUPDISJ-UHFFFAOYSA-L 0.000 description 1
- OGYFATSSENRIKG-UHFFFAOYSA-N pencycuron Chemical compound C1=CC(Cl)=CC=C1CN(C(=O)NC=1C=CC=CC=1)C1CCCC1 OGYFATSSENRIKG-UHFFFAOYSA-N 0.000 description 1
- CHIFOSRWCNZCFN-UHFFFAOYSA-N pendimethalin Chemical compound CCC(CC)NC1=C([N+]([O-])=O)C=C(C)C(C)=C1[N+]([O-])=O CHIFOSRWCNZCFN-UHFFFAOYSA-N 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical class [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- LKPLKUMXSAEKID-UHFFFAOYSA-N pentachloronitrobenzene Chemical compound [O-][N+](=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl LKPLKUMXSAEKID-UHFFFAOYSA-N 0.000 description 1
- JZPKLLLUDLHCEL-UHFFFAOYSA-N pentoxazone Chemical compound O=C1C(=C(C)C)OC(=O)N1C1=CC(OC2CCCC2)=C(Cl)C=C1F JZPKLLLUDLHCEL-UHFFFAOYSA-N 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- IDOWTHOLJBTAFI-UHFFFAOYSA-N phenmedipham Chemical compound COC(=O)NC1=CC=CC(OC(=O)NC=2C=C(C)C=CC=2)=C1 IDOWTHOLJBTAFI-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- NQQVFXUMIDALNH-UHFFFAOYSA-N picloram Chemical compound NC1=C(Cl)C(Cl)=NC(C(O)=O)=C1Cl NQQVFXUMIDALNH-UHFFFAOYSA-N 0.000 description 1
- CWKFPEBMTGKLKX-UHFFFAOYSA-N picolinafen Chemical compound C1=CC(F)=CC=C1NC(=O)C1=CC=CC(OC=2C=C(C=CC=2)C(F)(F)F)=N1 CWKFPEBMTGKLKX-UHFFFAOYSA-N 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- QXJKBPAVAHBARF-BETUJISGSA-N procymidone Chemical compound O=C([C@]1(C)C[C@@]1(C1=O)C)N1C1=CC(Cl)=CC(Cl)=C1 QXJKBPAVAHBARF-BETUJISGSA-N 0.000 description 1
- AAEVYOVXGOFMJO-UHFFFAOYSA-N prometryn Chemical compound CSC1=NC(NC(C)C)=NC(NC(C)C)=N1 AAEVYOVXGOFMJO-UHFFFAOYSA-N 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- MFOUDYKPLGXPGO-UHFFFAOYSA-N propachlor Chemical compound ClCC(=O)N(C(C)C)C1=CC=CC=C1 MFOUDYKPLGXPGO-UHFFFAOYSA-N 0.000 description 1
- FKLQIONHGSFYJY-UHFFFAOYSA-N propan-2-yl 5-[4-bromo-1-methyl-5-(trifluoromethyl)pyrazol-3-yl]-2-chloro-4-fluorobenzoate Chemical compound C1=C(Cl)C(C(=O)OC(C)C)=CC(C=2C(=C(N(C)N=2)C(F)(F)F)Br)=C1F FKLQIONHGSFYJY-UHFFFAOYSA-N 0.000 description 1
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 description 1
- NQLVQOSNDJXLKG-UHFFFAOYSA-N prosulfocarb Chemical compound CCCN(CCC)C(=O)SCC1=CC=CC=C1 NQLVQOSNDJXLKG-UHFFFAOYSA-N 0.000 description 1
- APTZNLHMIGJTEW-UHFFFAOYSA-N pyraflufen-ethyl Chemical group C1=C(Cl)C(OCC(=O)OCC)=CC(C=2C(=C(OC(F)F)N(C)N=2)Cl)=C1F APTZNLHMIGJTEW-UHFFFAOYSA-N 0.000 description 1
- ASRAWSBMDXVNLX-UHFFFAOYSA-N pyrazolynate Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=O)C=1C(C)=NN(C)C=1OS(=O)(=O)C1=CC=C(C)C=C1 ASRAWSBMDXVNLX-UHFFFAOYSA-N 0.000 description 1
- FKERUJTUOYLBKB-UHFFFAOYSA-N pyrazoxyfen Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=O)C=1C(C)=NN(C)C=1OCC(=O)C1=CC=CC=C1 FKERUJTUOYLBKB-UHFFFAOYSA-N 0.000 description 1
- VTRWMTJQBQJKQH-UHFFFAOYSA-N pyributicarb Chemical compound COC1=CC=CC(N(C)C(=S)OC=2C=C(C=CC=2)C(C)(C)C)=N1 VTRWMTJQBQJKQH-UHFFFAOYSA-N 0.000 description 1
- YBBJKCMMCRQZMA-UHFFFAOYSA-N pyrithione Chemical compound ON1C=CC=CC1=S YBBJKCMMCRQZMA-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- FFSSWMQPCJRCRV-UHFFFAOYSA-N quinclorac Chemical compound ClC1=CN=C2C(C(=O)O)=C(Cl)C=CC2=C1 FFSSWMQPCJRCRV-UHFFFAOYSA-N 0.000 description 1
- FBQQHUGEACOBDN-UHFFFAOYSA-N quinomethionate Chemical compound N1=C2SC(=O)SC2=NC2=CC(C)=CC=C21 FBQQHUGEACOBDN-UHFFFAOYSA-N 0.000 description 1
- OSUHJPCHFDQAIT-GFCCVEGCSA-N quizalofop-P-ethyl Chemical group C1=CC(O[C@H](C)C(=O)OCC)=CC=C1OC1=CN=C(C=C(Cl)C=C2)C2=N1 OSUHJPCHFDQAIT-GFCCVEGCSA-N 0.000 description 1
- BACHBFVBHLGWSL-JTQLQIEISA-N rac-diclofop methyl Natural products C1=CC(O[C@@H](C)C(=O)OC)=CC=C1OC1=CC=C(Cl)C=C1Cl BACHBFVBHLGWSL-JTQLQIEISA-N 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- MEFOUWRMVYJCQC-UHFFFAOYSA-N rimsulfuron Chemical compound CCS(=O)(=O)C1=CC=CN=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 MEFOUWRMVYJCQC-UHFFFAOYSA-N 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000000741 silica gel Chemical class 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- ODCWYMIRDDJXKW-UHFFFAOYSA-N simazine Chemical compound CCNC1=NC(Cl)=NC(NCC)=N1 ODCWYMIRDDJXKW-UHFFFAOYSA-N 0.000 description 1
- MGLWZSOBALDPEK-UHFFFAOYSA-N simetryn Chemical compound CCNC1=NC(NCC)=NC(SC)=N1 MGLWZSOBALDPEK-UHFFFAOYSA-N 0.000 description 1
- JRQGDDUXDKCWRF-UHFFFAOYSA-M sodium;n-(2-methoxycarbonylphenyl)sulfonyl-4-methyl-5-oxo-3-propoxy-1,2,4-triazole-1-carboximidate Chemical compound [Na+].O=C1N(C)C(OCCC)=NN1C(=O)[N-]S(=O)(=O)C1=CC=CC=C1C(=O)OC JRQGDDUXDKCWRF-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- PQTBTIFWAXVEPB-UHFFFAOYSA-N sulcotrione Chemical compound ClC1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O PQTBTIFWAXVEPB-UHFFFAOYSA-N 0.000 description 1
- OORLZFUTLGXMEF-UHFFFAOYSA-N sulfentrazone Chemical compound O=C1N(C(F)F)C(C)=NN1C1=CC(NS(C)(=O)=O)=C(Cl)C=C1Cl OORLZFUTLGXMEF-UHFFFAOYSA-N 0.000 description 1
- ZDXMLEQEMNLCQG-UHFFFAOYSA-N sulfometuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=CC(C)=N1 ZDXMLEQEMNLCQG-UHFFFAOYSA-N 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- ROZUQUDEWZIBHV-UHFFFAOYSA-N tecloftalam Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(=O)NC1=CC=CC(Cl)=C1Cl ROZUQUDEWZIBHV-UHFFFAOYSA-N 0.000 description 1
- XQTLDIFVVHJORV-UHFFFAOYSA-N tecnazene Chemical compound [O-][N+](=O)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl XQTLDIFVVHJORV-UHFFFAOYSA-N 0.000 description 1
- IUQAXCIUEPFPSF-UHFFFAOYSA-N tembotrione Chemical compound ClC1=C(COCC(F)(F)F)C(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O IUQAXCIUEPFPSF-UHFFFAOYSA-N 0.000 description 1
- IROINLKCQGIITA-UHFFFAOYSA-N terbutryn Chemical compound CCNC1=NC(NC(C)(C)C)=NC(SC)=N1 IROINLKCQGIITA-UHFFFAOYSA-N 0.000 description 1
- FZXISNSWEXTPMF-UHFFFAOYSA-N terbutylazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C)=N1 FZXISNSWEXTPMF-UHFFFAOYSA-N 0.000 description 1
- AHTPATJNIAFOLR-UHFFFAOYSA-N thifensulfuron-methyl Chemical group S1C=CC(S(=O)(=O)NC(=O)NC=2N=C(OC)N=C(C)N=2)=C1C(=O)OC AHTPATJNIAFOLR-UHFFFAOYSA-N 0.000 description 1
- WOSNCVAPUOFXEH-UHFFFAOYSA-N thifluzamide Chemical compound S1C(C)=NC(C(F)(F)F)=C1C(=O)NC1=C(Br)C=C(OC(F)(F)F)C=C1Br WOSNCVAPUOFXEH-UHFFFAOYSA-N 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- OBZIQQJJIKNWNO-UHFFFAOYSA-N tolclofos-methyl Chemical group COP(=S)(OC)OC1=C(Cl)C=C(C)C=C1Cl OBZIQQJJIKNWNO-UHFFFAOYSA-N 0.000 description 1
- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- IQGKIPDJXCAMSM-UHFFFAOYSA-N triazoxide Chemical compound N=1C2=CC=C(Cl)C=C2[N+]([O-])=NC=1N1C=CN=C1 IQGKIPDJXCAMSM-UHFFFAOYSA-N 0.000 description 1
- REEQLXCGVXDJSQ-UHFFFAOYSA-N trichlopyr Chemical compound OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl REEQLXCGVXDJSQ-UHFFFAOYSA-N 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
- IMEVJVISCHQJRM-UHFFFAOYSA-N triflusulfuron-methyl Chemical group COC(=O)C1=CC=CC(C)=C1S(=O)(=O)NC(=O)NC1=NC(OCC(F)(F)F)=NC(N(C)C)=N1 IMEVJVISCHQJRM-UHFFFAOYSA-N 0.000 description 1
- RROQIUMZODEXOR-UHFFFAOYSA-N triforine Chemical compound O=CNC(C(Cl)(Cl)Cl)N1CCN(C(NC=O)C(Cl)(Cl)Cl)CC1 RROQIUMZODEXOR-UHFFFAOYSA-N 0.000 description 1
- KVEQCVKVIFQSGC-UHFFFAOYSA-N tritosulfuron Chemical compound FC(F)(F)C1=NC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(F)(F)F)=N1 KVEQCVKVIFQSGC-UHFFFAOYSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 1
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 description 1
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 1
- 229930007845 β-thujaplicin Natural products 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/201—Adhesives in the form of films or foils characterised by their carriers characterised by the release coating composition on the carrier layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
- C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
- C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/41—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2483/00—Presence of polysiloxane
- C09J2483/006—Presence of polysiloxane in the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Adhesive Tapes (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
(1)当該塗膜に水を滴下して5分間経過した後の、当該塗膜の水接触角が80°以下である。
(2)当該塗膜をメタノールに3時間接触させた後に、水を滴下して5分間経過した後の、当該塗膜の水接触角が80°以下である。
本実施形態の塗膜形成用組成物は、塗膜を形成するための塗膜形成用組成物であり、当該塗膜形成用組成物はシリコーン樹脂及びシリコーンオイルを含有し、当該塗膜形成用組成物からなる塗膜は下記(1)及び(2)を満たすことが好ましい。
(1)当該塗膜に水を滴下して5分間経過した後の、当該塗膜の水接触角が80°以下である。
(2)当該塗膜をメタノールに3時間接触させた後に、水を滴下して5分間経過した後の、当該塗膜の水接触角が80°以下である。
水滴下後の水接触角およびメタノール3時間接触及び水滴下後の水接触角が80°以下であることにより、表面オイル層による防汚効果が良好に発揮される。
なお、これら塗膜の水接触角は、水滴下後の水接触角の値であるが、試験の期間である35日程度海水に浸漬させただけでは、ほとんど変化しない。
つまり、メタノール3時間後の水接触角が80°以下であれば、約4年に相当する期間フジツボ等の水生生物に対する防汚性があることがわかる。
塗膜形成用組成物中のシリコーン樹脂の含有割合は、防汚剤などの他の成分の含有割合によって、任意の適切な含有割合を採用し得る。塗膜形成用組成物中のシリコーン樹脂の含有割合は、好ましくは30重量%~98重量%であり、より好ましくは40重量%~97重量%であり、さらに好ましくは45重量%~96重量%であり、特に好ましくは50重量%~95重量%である。塗膜形成用組成物中のシリコーン樹脂の含有割合が上記範囲内に収まることにより、塗膜形成用組成物により形成される塗膜の防汚効果がより十分に発現できるとともに、塗膜の機械的特性がより十分に発現できる。塗膜形成用組成物中のシリコーン樹脂の含有割合が低すぎると、塗膜の機械的特性が低下するおそれがある。塗膜形成用組成物中のシリコーン樹脂の含有割合が高すぎると、塗膜の防汚効果が十分に発現できないおそれがある。
本実施形態の塗膜形成用組成物において、塗膜の安定性等の観点からは、シリコーンオイルは、非反応性のシリコーンオイルであることが好ましい。
親水性シリコーンオイルとしては、ポリエーテル変性シリコーンオイル、ポリグリセリン変性シリコーンオイル、ポリエーテルなどの親水性基とアルキルなどの疎水性基が共変性されたシリコーンオイル等が挙げられ、本実施形態の塗膜形成用組成物においては、塗膜を形成した際に上記した要件(1)及び(2)が満たされる範囲で、これらの中から適宜選択して用いることができる。なお、用いられる親水性シリコーンオイルは、1種のみであってもよいし、2種以上であってもよい。
これら親水性シリコーンオイルにおける、ポリエーテル変性シリコーンオイル、ポリグリセリン変性シリコーンオイル、ポリエーテルなどの親水基は、末端が水酸基であってもよいし、メチル基等のアルキル基でキャップされていてもよい。
親水性シリコーンオイルは、塗膜が水と接触することにより塗膜表面に引き寄せられて偏析し、オイル薄層を形成することで、良好な防汚効果を発揮する。ここで、親水性シリコーンオイルの粘度が小さいほど、塗膜が水と接触した際に塗膜表面に引き寄せられる速度がより速くなるため、水滴下後の水接触角やメタノール接触及び水滴下後の水接触角が小さくなりやすくなる。したがって、防汚効果が良好に発揮され、また、たとえ水中における物理的な要因により塗膜表面のオイル層が取り除かれてしまったときでも、水と接触することによりオイル層を再びより早期に形成し、防汚効果をより迅速に回復することができる。かかる観点から、親水性シリコーンオイルの粘度は、好ましくは10000mm2/s以下であり、より好ましくは5000mm2/s以下であり、さらに好ましくは1000mm2/s以下であり、特に好ましくは400mm2/s以下であり、最も好ましくは150mm2/s以下である。なお、親水性シリコーンオイルの粘度の下限値は特に限定されるものではないが、防汚性の持続性の観点からは、例えば10mm2/s以上である。
なお、本実施形態における親水性シリコーンオイルの粘度(動粘度)は、ASTM D
445-46T或いはJIS Z 8803によるウッベローペ粘度計より測定されるものである。
また、HLBは具体的には、例えば、下記式
HLB値=(分子中に占める親水性基(オキシエチレン単位、OH基)の質量%値の総和)/5により求めることができる。
なお、本実施形態において、疎水性シリコーンオイルとは、そのHLBが1未満のシリコーンオイルである。
疎水性シリコーンオイルの含有量と親水性シリコーンオイルの含有量の比を上記の範囲内に調整することにより、疎水性オイルによって親水性オイルが保持されるために、メタノール接触による親水性オイルの除去が抑制され、長期の防汚性能がより十分に発現できる。
また、12.0以下であることが好ましく、6.0以下であることがより好ましく4.0以下であることが更に好ましい。
疎水性シリコーンオイルの含有量と親水性シリコーンオイルの含有量の比を上記の範囲内に調整することにより、メタノール接触後も親水性オイルが残存するため、長期防汚性がより十分に発現できる。
本実施形態の塗膜は、上述した塗膜形成用組成物により形成される塗膜であり、水生生物の付着を防止するために有用である。すなわち、本実施形態の塗膜は、シリコーン樹脂及びシリコーンオイルを含有するとともに、下記(1)及び(2)を満たすものであり、水中における水流等の物理的な要因がある中でも、水生生物に対する付着阻害効果を安定に発揮することができる。なお、本明細書において、本実施形態の塗膜を、防汚層という場合がある。
(1)前記塗膜に水を滴下して5分間経過した後の、前記塗膜の水接触角が80°以下である。
(2)前記塗膜をメタノールに3時間接触させた後に、水を滴下して5分間経過した後の、前記塗膜の水接触角が80°以下である。
上記した塗膜形成用組成物は、前述のとおり、水中構造物等の被着体に直接塗布、乾燥して塗膜を形成させてもよいが、例えば、基材層及び粘着剤層を有する粘着シートの基材層表面に塗布、乾燥して塗膜を形成させることで、塗膜(防汚層)、基材層及び粘着剤層をこの順に有する粘着シートの形態とし、これを被着体に貼り付けて用いてもよい。
なお、実施例15、18、20、21はそれぞれ参考例15、18、20、21に読み替えるものとする。
シリコーン樹脂1(付加型シリコーン樹脂、商品名「KE-1935」、信越シリコーン(株)製):100重量部、親水性シリコーンオイル1(ポリエーテル変性シリコーンオイル、商品名「KF6015」、信越シリコーン(株)製、HLB:4.5、PEO鎖の鎖長:3、粘度130mm2/s):10重量部、親水性シリコーンオイル2(ポリエーテル変性シリコーンオイル、商品名「KF6016」、信越シリコーン(株)製、HLB:4.5、PEO鎖の鎖長:9、粘度150mm2/s):5重量部、疎水性シリコーンオイル1(非反応性シリコーンオイル、商品名「KF96-100」、信越シリコーン(株)製):25重量部、及び疎水性シリコーンオイル2(非反応性シリコーンオイル、商品名「KF415」、信越シリコーン(株)製):30重量部を混合して、実施例1の塗膜形成用組成物を作製した。
親水性シリコーンオイルとして、親水性シリコーンオイル1(ポリエーテル変性シリコーンオイル、商品名「KF6015」、信越シリコーン(株)製):10重量部及び親水性シリコーンオイル2(ポリエーテル変性シリコーンオイル、商品名「KF6016」、信越シリコーン(株)製):5重量部の代わりに、親水性シリコーンオイル2(ポリエーテル変性シリコーンオイル、商品名「KF6016」、信越シリコーン(株)製):15重量部を用いた以外は実施例1と同様にして、実施例2の塗膜形成用組成物を作製した。
親水性シリコーンオイルとして、親水性シリコーンオイル1(ポリエーテル変性シリコーンオイル、商品名「KF6015」、信越シリコーン(株)製):10重量部及び親水性シリコーンオイル2(ポリエーテル変性シリコーンオイル、商品名「KF6016」、信越シリコーン(株)製):5重量部の代わりに、親水性シリコーンオイル1(ポリエーテル変性シリコーンオイル、商品名「KF6015」、信越シリコーン(株)製):15重量部を用いた以外は実施例1と同様にして、実施例3の塗膜形成用組成物を作製した。
疎水性シリコーンオイルとして、疎水性シリコーンオイル1(非反応性シリコーンオイル、商品名「KF96-100」、信越シリコーン(株)製):25重量部、及び疎水性シリコーンオイル2(非反応性シリコーンオイル、商品名「KF415」、信越シリコーン(株)製):30重量部の代わりに、疎水性シリコーンオイル1(非反応性シリコーンオイル、商品名「KF96-100」、信越シリコーン(株)製):55重量部を用いた以外は実施例2と同様にして、実施例4の塗膜形成用組成物を作製した。
疎水性シリコーンオイルとして、疎水性シリコーンオイル1(非反応性シリコーンオイル、商品名「KF96-100」、信越シリコーン(株)製):25重量部、及び疎水性シリコーンオイル2(非反応性シリコーンオイル、商品名「KF415」、信越シリコーン(株)製):30重量部の代わりに、疎水性シリコーンオイル1(非反応性シリコーンオイル、商品名「KF96-100」、信越シリコーン(株)製):55重量部を用いた以外は実施例1と同様にして、実施例5の塗膜形成用組成物を作製した。
シリコーン樹脂(縮合型シリコーン樹脂、商品名「KE-17」、信越シリコーン(株)製):100重量部、親水性シリコーンオイル1(ポリエーテル変性シリコーンオイル、商品名「KF6015」、信越シリコーン(株)製、HLB:4.5、PEO鎖の鎖長:3、粘度130mm2/s):10重量部、親水性シリコーンオイル2(ポリエーテル変性シリコーンオイル、商品名「KF6016」、信越シリコーン(株)製、HLB:4.5、PEO鎖の鎖長:9、粘度150mm2/s):5重量部、疎水性シリコーンオイル1(非反応性シリコーンオイル、商品名「KF96-100」、信越シリコーン(株)製):25重量部、及び疎水性シリコーンオイル2(非反応性シリコーンオイル、商品名「KF415」、信越シリコーン(株)製):30重量部を混合して、実施例6の塗膜形成用組成物を作製した。
シリコーン樹脂、親水性シリコーンオイル、及び疎水性シリコーンオイルの種類及び使用量を表1に記載のとおりに変更した以外は実施例1と同様にして、実施例7~21の塗膜形成用組成物を作製した。
シリコーン樹脂2(付加型シリコーン樹脂、商品名「KE-1950-50」、信越シリコーン(株)製):100重量部、親水性シリコーンオイル3(ポリエーテル変性シリコーンオイル、商品名「KF6013」、信越シリコーン(株)製、HLB:10、PEO鎖の鎖長:9、粘度400mm2/s):20重量部、疎水性シリコーンオイル1(非反応性シリコーンオイル、商品名「KF96-100」、信越シリコーン(株)製):70重量部を混合して、比較例1の塗膜形成用組成物を作製した。
シリコーン樹脂2(付加型シリコーン樹脂、商品名「KE-1950-50」、信越シリコーン(株)製):100重量部、親水性シリコーンオイル4(ポリエーテル変性シリコーンオイル、商品名「KF6017」、信越シリコーン(株)製、HLB:4.5、PEO鎖の鎖長:10、粘度530mm2/s):30重量部、疎水性シリコーンオイル1(非反応性シリコーンオイル、商品名「KF96-100」、信越シリコーン(株)製):60重量部を混合して、比較例2の塗膜形成用組成物を作製した。
シリコーン樹脂1(付加型シリコーン樹脂、商品名「KE-1935」、信越シリコーン(株)製):100重量部、疎水性シリコーンオイル3(非反応性シリコーンオイル、商品名「KF50-100」、信越シリコーン(株)製):60重量部を混合して、比較例3の塗膜形成用組成物を作製した。
シリコーン樹脂、親水性シリコーンオイル、及び疎水性シリコーンオイルの種類及び使用量を表1に記載のとおりに変更した以外は比較例1と同様にして、比較例4~6、8~11の塗膜形成用組成物を作製した。
各実施例及び比較例の塗膜形成用組成物を、縦30cm×横25cm×厚み0.75cmのPETフィルム(製品名「ルミラー」、東レ(株)製)の表面にアプリケーターにて塗布し、硬化させて、厚み100μmの塗膜を形成し、測定用試料を作製した。
なお、塗膜形成用組成物の硬化条件は、実施例1~5及び比較例1~3(付加型シリコーン樹脂を使用)については、150℃で3分間の加熱である。実施例6~21及び比較例4~11(縮合型シリコーン樹脂を使用)については、室温で12時間である。
各実施例及び比較例の測定用試料について、2μlの水を塗膜表面に滴下し、5分間経過後の塗膜表面の水接触角を、JIS R 3257による静滴法により、接触角計(DropMaster、協和界面科学株式会社製)を用いて測定した。
各実施例及び比較例の測定用試料について、測定用試料を1000mlのメタノールを入れた容器に3時間浸漬した後に、測定用試料を容器から取り出して80℃で1時間乾燥させてメタノールを除去した後、2μlの水を塗膜表面に滴下し、5分間経過後の塗膜表面の水接触角を、JIS R 3257による静滴法により、接触角計(DropMaster、協和界面科学株式会社製)を用いて測定した。
各実施例及び比較例の測定用試料について、塗膜の面積が20mm×60mmの大きさになるように切り取り、引張試験機(装置名「AUTOGRAPH AGS-X」、(株)島津製作所製)を用いて塗膜の弾性率を評価した。
・KE-1935(信越シリコーン(株)製)
・KE-1950-50(信越シリコーン(株)製)
・KE-17(信越シリコーン(株)製)
・KE-108(信越シリコーン(株)製)
〔親水性シリコーンオイル〕
・SilwetL-7602(HLB:7.3,粘度100mm2/s,末端CH3)(モメンティブ(株))
・KF6015(HLB:4.5,PEO鎖長:3,粘度130mm2/s,末端OH)(信越シリコーン(株)製)
・KF6016(HLB:4.5,PEO鎖長:9,粘度150mm2/s,末端CH3)(信越シリコーン(株)製)
・SilwetL-7600(HLB:14.3,粘度110mm2/s,末端CH3)(モメンティブ(株))
・FZ-2162(HLB:14,粘度180mm2/s,末端OH)(東レ・ダウコーニング(株))
・SilwetL-7604(HLB:10.6,粘度420mm2/s,末端OH)(モメンティブ(株))
・SilwetL-7622(HLB:8,PEO鎖長:10,粘度400mm2/s,末端CH3)(モメンティブ(株))
・TSF4440(HLB:14,粘度160mm2/s)(モメンティブ(株))
・SilwetL-7657(HLB:12.9,粘度600mm2/s,末端OH)(モメンティブ(株))
・KF6013(HLB:10,PEO鎖長:9,粘度400mm2/s,末端OH)(信越シリコーン(株)製)
・KF6017(HLB:4.5,PEO鎖長:10,粘度530mm2/s,末端OH)(信越シリコーン(株)製)
・TSF4445(HLB:7,粘度800mm2/s)(モメンティブ(株))
〔疎水性シリコーンオイル〕
・KF-96-100(信越シリコーン(株)製)
・KF-96-50(信越シリコーン(株)製)
・KF415(信越シリコーン(株)製)
・KF50-100(信越シリコーン(株)製)
・KF50-300(信越シリコーン(株)製)
・KF50-1000(信越シリコーン(株)製)
・KF50-3000(信越シリコーン(株)製)
実施例1~6、8及び比較例1~3の測定用試料について、下記の手順により水中生物付着試験を行った。
PMMA板(商品名「デラグラスK」、旭化成テクノプラス株式会社製、メタクリル酸メチル重合体:96.6%以上)に、厚み100μmの塗膜を作製した。得られた塗膜を姫路市沿岸の水深1mに浸漬した。36か月間浸漬後、防汚層の表面に水生生物が付着するかどうかを下記基準で評価し、表2に示した。
○:動物系生物の付着がなく、藻類の付着もない。
△:動物系生物の付着はなく、藻類の付着がある。
×:動物系生物の付着があり、藻類の付着もある。
実施例5の測定用試料について、2μlの水を塗膜表面に滴下し、5分間経過後の塗膜表面を飛行時間型二次イオン質量分析計(TOF.SIMS5、(独)ION-TOF社製)により分析したところ、塗膜表面にオイル層が形成されていることが確認された。オイル層の厚みは約50nmであった。
なお、実施例5以外の実施例及び比較例についても、塗膜表面におけるオイル層の形成が確認された。
一方、メタノール接触及び水滴下後の水接触角が本発明規定の範囲外である比較例1及び比較例2は、水生生物付着試験の結果が付着ありと不良であった。また、水滴下後の水接触角、並びに、メタノール接触及び水滴下後の水接触角が本発明規定の範囲外である比較例3は、水生生物付着試験の結果が付着ありと不良であった。
Claims (4)
- 塗膜を形成するための塗膜形成用組成物であって、
前記塗膜形成用組成物はシリコーン樹脂及びシリコーンオイルを含有し、
前記シリコーンオイルは、親水性シリコーンオイル及び疎水性シリコーンオイルを含有し、
前記疎水性シリコーンオイルの含有量と前記親水性シリコーンオイルの含有量の比である前記疎水性シリコーンオイルの含有量/前記親水性シリコーンオイルの含有量が、0.6以上6.0以下であり、
前記シリコーン樹脂100重量部に対するシリコーンオイルの総量が、80重量部以下であり、
前記親水性シリコーンオイルは、HLBが1以上15以下であり、粘度が400mm2/s以下のポリオキシアルキレン基が側鎖に結合されたポリエーテル変性シリコーンオイルであり、
前記疎水性シリコーンオイルは、HLBが1未満であり、粘度が100mm2/s以上630mm2/s以下のジメチルシリコーンオイルであり、
前記塗膜形成用組成物を、縦30cm×横25cm×厚み0.75cmのPETフィルムの表面にアプリケーターにて塗布し、硬化させた、厚み100μmの塗膜は下記(1)及び(2)を満たす、
塗膜形成用組成物。
(1)前記塗膜に水を滴下して5分間経過した後の、前記塗膜の水接触角が80°以下である。
(2)前記塗膜を1000mlのメタノールを入れた容器に3時間浸漬した後に、容器から取り出して80℃で1時間乾燥させてメタノールを除去した後、2μlの水を前記塗膜表面に滴下し、5分間経過後の前記塗膜表面の水接触角を、JIS R 3257による静滴法により、接触角計を用いて測定した水接触角が60°以下である。 - 請求項1に記載の塗膜形成用組成物からなる塗膜。
- 弾性率が0.1MPa以上である、請求項2に記載の塗膜。
- 請求項2または3に記載の塗膜、基材及び粘着剤層をこの順に含む粘着シート。
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Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001139816A (ja) | 1999-11-17 | 2001-05-22 | Chugoku Marine Paints Ltd | 硬化性組成物、コーティング用組成物、塗料、防汚塗料、その硬化物、並びに基材の防汚方法 |
JP2001181509A (ja) | 1999-10-13 | 2001-07-03 | Chugoku Marine Paints Ltd | 硬化性組成物、コーティング用組成物、塗料、防汚塗料、その硬化物、並びに基材の防汚方法 |
JP2006045339A (ja) | 2004-08-04 | 2006-02-16 | Kansai Paint Co Ltd | 防汚塗料組成物及び該組成物を用いた塗装方法 |
JP2006274267A (ja) | 2006-04-28 | 2006-10-12 | Dainippon Toryo Co Ltd | 防汚塗料組成物 |
JP2007056052A (ja) | 2005-08-22 | 2007-03-08 | Dow Corning Toray Co Ltd | オルガノポリシロキサン組成物、塗料添加剤および防汚塗料組成物 |
US20100003211A1 (en) | 2008-07-07 | 2010-01-07 | Shin-Etsu Chemical Co., Ltd. | Antifouling coating composition and underwater structure using the same |
CN102993853A (zh) | 2012-11-28 | 2013-03-27 | 天长市开林化工有限公司 | 一种无毒料释放型防污漆及其制备方法 |
JP2015174902A (ja) | 2014-03-14 | 2015-10-05 | 日東電工株式会社 | 水生生物付着防止粘着テープ |
JP2016108416A (ja) | 2014-12-04 | 2016-06-20 | 日東電工株式会社 | 水生生物付着防止粘着テープ |
JP2016518969A (ja) | 2013-03-20 | 2016-06-30 | ヘンペル エイ/エス | 新規なポリシロキサン系汚損抑制塗装系 |
WO2016163360A1 (ja) | 2015-04-08 | 2016-10-13 | 日東電工株式会社 | 水生生物付着防止粘着テープ |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06104793B2 (ja) * | 1989-06-16 | 1994-12-21 | ナテックス株式会社 | 防汚塗料 |
JPH04142373A (ja) * | 1990-10-01 | 1992-05-15 | Hayashikane Paint Kk | 防汚塗料 |
US5298060A (en) | 1992-04-03 | 1994-03-29 | Air Products And Chemicals, Inc. | Use of silicone resins and fluids to retard marine life buildup on submerged surfaces |
JPH08231898A (ja) * | 1994-12-26 | 1996-09-10 | Shin Etsu Chem Co Ltd | 水中防汚組成物 |
JPH08302245A (ja) * | 1995-04-27 | 1996-11-19 | Tozai:Kk | 海中生物付着防止方法 |
JPH0912413A (ja) * | 1995-06-23 | 1997-01-14 | Shin Etsu Chem Co Ltd | 水中防汚剤 |
JPH10316933A (ja) * | 1997-03-14 | 1998-12-02 | Kansai Paint Co Ltd | 防汚塗料組成物 |
AU2001232295A1 (en) * | 2000-02-21 | 2001-08-27 | Daikin Industries Ltd. | Resin composition for preventing attachment of aquatic organism or physiologicalsubstance |
JP6369935B2 (ja) * | 2014-07-25 | 2018-08-08 | 日東電工株式会社 | シリコーン系樹脂組成物、防汚膜、および水生生物付着防止粘着フィルム |
JP6440665B2 (ja) | 2016-10-27 | 2018-12-19 | 株式会社半導体エネルギー研究所 | 表示装置 |
-
2018
- 2018-03-30 US US16/499,410 patent/US20200032109A1/en not_active Abandoned
- 2018-03-30 JP JP2018068722A patent/JP7287757B2/ja active Active
- 2018-03-30 CN CN201880022766.6A patent/CN110475833A/zh active Pending
- 2018-03-30 WO PCT/JP2018/013997 patent/WO2018182023A1/ja active Application Filing
- 2018-03-30 EP EP18777749.5A patent/EP3604466A4/en active Pending
-
2023
- 2023-03-03 JP JP2023032747A patent/JP7495542B2/ja active Active
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001181509A (ja) | 1999-10-13 | 2001-07-03 | Chugoku Marine Paints Ltd | 硬化性組成物、コーティング用組成物、塗料、防汚塗料、その硬化物、並びに基材の防汚方法 |
JP2001139816A (ja) | 1999-11-17 | 2001-05-22 | Chugoku Marine Paints Ltd | 硬化性組成物、コーティング用組成物、塗料、防汚塗料、その硬化物、並びに基材の防汚方法 |
JP2006045339A (ja) | 2004-08-04 | 2006-02-16 | Kansai Paint Co Ltd | 防汚塗料組成物及び該組成物を用いた塗装方法 |
JP2007056052A (ja) | 2005-08-22 | 2007-03-08 | Dow Corning Toray Co Ltd | オルガノポリシロキサン組成物、塗料添加剤および防汚塗料組成物 |
JP2006274267A (ja) | 2006-04-28 | 2006-10-12 | Dainippon Toryo Co Ltd | 防汚塗料組成物 |
US20100003211A1 (en) | 2008-07-07 | 2010-01-07 | Shin-Etsu Chemical Co., Ltd. | Antifouling coating composition and underwater structure using the same |
JP2010013591A (ja) | 2008-07-07 | 2010-01-21 | Shin-Etsu Chemical Co Ltd | 水中生物付着防止塗料組成物及びそれを用いた水中構造物 |
CN102993853A (zh) | 2012-11-28 | 2013-03-27 | 天长市开林化工有限公司 | 一种无毒料释放型防污漆及其制备方法 |
JP2016518969A (ja) | 2013-03-20 | 2016-06-30 | ヘンペル エイ/エス | 新規なポリシロキサン系汚損抑制塗装系 |
JP2015174902A (ja) | 2014-03-14 | 2015-10-05 | 日東電工株式会社 | 水生生物付着防止粘着テープ |
JP2016108416A (ja) | 2014-12-04 | 2016-06-20 | 日東電工株式会社 | 水生生物付着防止粘着テープ |
WO2016163360A1 (ja) | 2015-04-08 | 2016-10-13 | 日東電工株式会社 | 水生生物付着防止粘着テープ |
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