JP6887988B2 - 低光沢コーティング用放射線硬化性組成物 - Google Patents
低光沢コーティング用放射線硬化性組成物 Download PDFInfo
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- JP6887988B2 JP6887988B2 JP2018510055A JP2018510055A JP6887988B2 JP 6887988 B2 JP6887988 B2 JP 6887988B2 JP 2018510055 A JP2018510055 A JP 2018510055A JP 2018510055 A JP2018510055 A JP 2018510055A JP 6887988 B2 JP6887988 B2 JP 6887988B2
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- acrylate
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- matte
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- 150000002738 metalloids Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- OTLDLKLSNZMTTA-UHFFFAOYSA-N octahydro-1h-4,7-methanoindene-1,5-diyldimethanol Chemical compound C1C2C3C(CO)CCC3C1C(CO)C2 OTLDLKLSNZMTTA-UHFFFAOYSA-N 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- FSDNTQSJGHSJBG-UHFFFAOYSA-N piperidine-4-carbonitrile Chemical compound N#CC1CCNCC1 FSDNTQSJGHSJBG-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000004671 saturated fatty acids Chemical group 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 235000011888 snacks Nutrition 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- 229940012185 zinc palmitate Drugs 0.000 description 1
- GJAPSKMAVXDBIU-UHFFFAOYSA-L zinc;hexadecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O GJAPSKMAVXDBIU-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/42—Gloss-reducing agents
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
この背景技術に対して、我々はここに、
20〜95wt%(重量%)の1種以上の(メタ)アクリル化化合物(a)、
5〜80wt%の1種以上のC10〜C22脂肪酸の金属塩(b)、及び
任意に、0〜10wt%の(a)及び(b)とは異なる化合物(c)
から本質的になる放射線硬化性組成物(I)を提供する。
・塗布粘度への影響が小さい、
・柔軟性、硬度、耐汚染性、引っ掻き耐性、及び/又は研磨可能性(sandability)のような他の望ましい性質への影響が最小限である、
・温度安定性である、
・サテン、艶消し又はデッドマット効果でさえ、それらを達成するのに高い投入量を要しない、
・少なくとも3か月の保存後実質的に同じ光沢レベルを有する安定な配合物を得ることができる、
・100%UV適用で一般的に用いられるポリマー及び艶消し剤と相溶性があり、理想的なブレンド相手となる、
・組成物を非光沢にすることが容易であり、エンドユーザーに使用の一定の柔軟性を与える、
・実質的にVOCがないので規制的にフレンドリーである、
・黄化がないか、ほとんどない、及び/又は
・UV反応性が良好のままである。
・一般に低粘度である、
・標準的な艶消し剤と組み合わせると良好な安定性(沈降しない)を提供する、
・60°の角度で光沢レベルが10未満、5未満でさえ得ることができる、
・60°の角度で1〜2のデッドマットレベルを得ることすらできる、
・広範囲のコーティング厚みにわたり安定した光沢を得ることができる、
・良好なUV硬化活性、良好な耐汚染性及び良好な引っ掻き耐性と、低光沢を一般に組み合わせている、
・溶媒又は単官能性モノマー等の追加が絶対に必要という訳ではないので、最も厳しい規制要求にも応えられる、
・UV光源及び/又は電子ビームを用いて硬化することが容易である、及び/又は
・UV−LED硬化でさえ可能である。
20〜95wt%(重量%)の1種以上の(メタ)アクリル化化合物(a)、
5〜80wt%の1種以上のC10〜C22脂肪族酸の金属塩(b)、及び
任意に、0〜10wt%の(a)及び(b)とは異なる化合物(c)
から本質的になる放射線硬化性組成物(I)が提供される。
M+n(RCOO−)n
によって特徴づけられる。
(i)本発明の組成物(I)から調製されたコーティング組成物を物品又は基材の少なくとも1つの表面に塗布するステップ、
(ii)続いてコーティングを放射線硬化させるステップ、
を含み、60°の角度で最大で50、85°の角度で最大で80の光沢レベルを有する艶消しコーティングを得、ここで該コーティングは12μmの硬化フィルム厚さを有する、上記方法に関する。一般に、乾燥厚さ(硬化後の厚さ)12μmのコーティングでは60°の角度での光沢レベルは最大15であり、85°の角度での光沢レベルが最大50である。有利に達することができるより多くの光沢レベルについては、上記を参照のこと。本発明の利点は、これらの光沢レベルが広範囲のコーティング厚さにわたって得られることである。一般に、これらはシリカ及び/又はワックスのような(さらなる)艶消し剤を添加する必要がまったくなく、6〜120μmの乾燥厚さを有するコーティングで得ることができる。
(i)上記(上記のいずれか)の「艶消し増量剤」(I)又はその成分を提供するステップ、
(ii)それぞれの量で艶消し剤(d)を添加するステップ、
(iii)任意に、さらなる(メタ)アクリル化化合物をそれぞれの量で添加するステップ、及び
(iv)任意に、添加剤及び/又は溶媒をそれぞれの量で添加するステップ、
ここで、ステップ(i)、(ii)、(iii)及び(iv)は任意の順序であり得る。基材上に塗布する前に、1種以上の光開始剤を添加してもよい(v)。
(via)DPGDA、HDDA、ODA等のような反応性希釈剤を添加する、及び/又は
(vib)艶消し組成物(II)の温度を少なくとも25℃、好ましくは少なくとも30℃、おそらくは少なくとも50℃、典型的には60℃以下の温度に上昇させる、これは硬化に先立つ
というステップ(vi)をさらに含むことができる。
(i)本発明の放射線硬化性組成物を物品又は基材の少なくとも1つの表面に塗布するステップ、
(ii)その後にコーティングを放射線硬化させるステップ
を含み、硬化フィルム厚が12μmで60°の角度で最大15、85°の角度で最大50の光沢レベルを有する艶消しコーティングを得る、上記方法である。本発明の組成物を使用する利点は、この光沢レベルが得られること、又は6〜120μmの乾燥厚さ(硬化膜厚)を有するコーティングが得られることである。したがって、艶消し効果は、広範囲のコーティング厚にわたって得られ得る。
UV硬化:
硬化は以下の方法で行った:6−120μmの厚さのコーティング層を、バーコーターによりレネタ(Leneta)紙不透明カード上に塗布した。次いで、40、80又は120ワット/cm2のHgランプを用いて、5m/分の硬化速度でUV光下でコーティングを硬化させた。
本発明を通して、及び本明細書では、DIN−67530に従ってBYK Gardner microTRI−gloss20−60−85光沢計を用いて光沢測定を行った。
試験条件:
白いLeneta紙上にバーコータにより80μ乾燥のコーティングを施す。次いで、コーティングを、80ワット/cm2のHgランプを用いて5m/分の硬化速度でUV光下で硬化させた。照射後、試料は、少なくとも1時間、制御された部屋(20℃、50%RH)中で安定化される。
耐汚染性は記載のように測定される。ある製品(Z)を一定時間(Y)、コーティング上に置き、空気乾燥を防ぐためにガラスキャッピングで覆う。時間(Y)の経過後、製品(Z)を溶媒(S)又は水/石鹸溶液に漬けた薄い織物(tissue)で除去する。以下の製品を試験した(表1)。
5・・・目に見える汚れがない
4・・・非常に薄い汚れ
3・・・中程度の汚れ
2・・・強い汚れ
1・・・非常に強い汚れ
この方法は、ドライフィルムが特定の溶媒に対して耐性であるかどうかを決定する。
白いLeneta紙上にバーコーターにより80μ乾燥のコーティングを施す。次いで、コーティングを、80ワット/cm2のHgランプを用いて5m/分の硬化速度でUV光下で硬化させた。照射後、試料は、少なくとも1時間、制御された部屋(20℃、50%RH)中で安定化される。
コーティング(X)を一定時間(Y)、溶媒(Z)と接触させておく。試験した異なる製品は、10%NH3、10%NaOH、50%エタノール(水で希釈)、水、イソプロピルアルコール及びアセトンである。その後、外観を評価する。外観はまた、損傷なし、可溶、光沢変化、接着不良などとして、視覚的に採点される。
5・・・目に見える汚れがない
4・・・非常に薄い汚れ
3・・・中程度の汚れ
2・・・強い汚れ
1・・・非常に強い汚れ
必要な場合、試験を開始する前に試料を均一にする。次いで、30mlの瓶に試料を充填し、首のみを満たさずに残す。次に、試料を適切な温度および時間でオーブンに入れる。毎日ゲル形成のチェックを行なう:一度試料を逆さまにして試料がゲル化しているかどうかを確認する。所定の試験時間の後、試料をオーブンから取り出し、ゲルをチェックする。試料にゲルが含まれている場合、試験は中止される。通常60℃(140°F)で10日間、80°C(176°F)で10日間の2つのエージング試験が実行される。試料がゲル化するまでの日数に留意する。
本発明の艶消し増量剤(I)は、艶消し剤(d)を添加しなくても光沢を低下させる。
**PEA/ステアリン酸亜鉛/添加剤(85/14/1)。PEAは EX1−Rの一つと同じである
HDDA:ヘキサンジオールジアクリレート、DPGDA:ジプロピレングリコールジアクリレート
全範囲の無機シリカ艶消し剤(d)を、本発明の「艶消し増量剤」との相溶性に関して試験した。10−20−40−80μmの乾燥厚さをそれぞれ有するコーティングを、黒色のレネタ(Leneta)紙上にバーコーターにより塗布した。次いで、コーティングを、120ワット/cm2のHgランプを用いて5m/分の硬化速度でUV光下で硬化させた。コーティングの組成を表3に示し、結果を表4に要約する。
表4のデータは、60℃で10未満の光沢レベルが標準シリカで達成できることを示している。5未満の光沢レベルですら容易に達成できる。
20μmの乾燥厚さを有するコーティングを、黒色のレネタ(Leneta)紙上でバーコーターによって塗布した。次いで、コーティングを、120ワット/cm2のHgランプを用いて5m/分の硬化速度でUV光下で硬化させた。60°の角度での光沢及び23℃での円錐平板粘度を測定した。コーティングの組成を表5に示し、結果を表6に要約する。
厚さ10−20−40−80μm厚の乾燥厚を有するコーティングを、黒色のレネタ(Leneta)紙上にバーコーターにより塗布した。次いで、コーティングを、120ワット/cm2のHgランプを用いて5m/分の硬化速度でUV光下で硬化させた。60°の角度での光沢及び85°の角度での光沢を測定した。コーティングの組成を表7に示し、結果を表8に要約する。
80μm厚の乾燥厚を有するコーティングを、黒色のレネタ(Leneta)紙上にバーコーターによって塗布した。次に、2×80ワット/cm2のHgランプを用いて7m/分の硬化速度でUV光下でコーティングを硬化させた。60°測定での光沢を2週間の貯蔵寿命の後に繰り返した。トップコート組成を表9に示す。結果を表10に要約する。最初は全てのZn触媒はあるレベルの艶消し増長を有したが、本発明の艶消し増長剤を使用しないと、この効果は混合物の12日間の貯蔵後に消失した(例えば比較例17R及び18R参照)。その場合、艶消し効果は維持され、コーティングの硬度は良好なままであった。最良の特性のバランスは、本発明の艶消し増量剤(I)で得られる(例えば実施例19参照)。比較例17−Rは、脂肪酸の長さが役割を果たすことを示す。
密閉した木材(EBECRYL(登録商標)8332)にDCコーティングを施した。トップコートを8〜15g/m2の量で適用した。次に、80ワット/cm2のHgランプを用いて2X7m/分の硬化速度でUV光下でコーティングを硬化させた。硬化速度及び機械的特性を調べた(表11)。本発明の艶消し剤は、ODA(オクチルデシルアクリレート)のような当該技術分野で使用される他の薬剤よりも明らかな利益を有する(表12)。表13では、本発明による異なる艶消し増量剤を比較する(EX26−35)。
Claims (18)
- 20〜95wt%の1種以上の(メタ)アクリル化化合物(a)、
5〜80wt%の1種以上のC10〜C22脂肪酸の金属塩(b)、及び
0〜10wt%の(a)及び(b)とは異なる1種以上の化合物(c)
から本質的になる放射線硬化性コーティング組成物(I)であって、
化合物(a)〜(c)のwt%は合計100%である上記組成物。 - 化合物(a)が、ポリエステル(メタ)アクリレート、エポキシ(メタ)アクリレート、ポリエーテル(メタ)アクリレート、アミン変性ポリエーテル(メタ)アクリレート、アクリルメタアクリレート、及び/又はウレタン(メタ)アクリレートからなる群から選ばれる、請求項1に記載の組成物。
- 前記金属が二価の金属である、請求項1又は2に記載の組成物。
- 前記金属がカルシウム、亜鉛、及び/又はジルコニウムからなる群から選ばれる、請求項3に記載の組成物。
- 前記脂肪酸がC16〜C18脂肪酸から選ばれる、請求項1〜4のいずれかに記載の組成物。
- 化合物(b)が(メタ)アクリロイル基を含まない、請求項1〜5のいずれかに記載の組成物。
- 化合物(b)がステアリン酸亜鉛及び/又はステアリン酸カルシウムから選ばれる、請求項1〜6のいずれかに記載の組成物。
- 5wt%未満の溶媒を含む、請求項1〜7のいずれかに記載の組成物。
- 2〜40wt%の請求項1〜8のいずれかに記載の組成物(I)、及び
任意に、0〜20wt%の1種以上の、化合物(b)と異なる艶消し剤(d)
を含む放射線硬化性艶消し組成物(II)であって、
放射線による硬化の後、艶消しコーティングが12μmの硬化フィルム厚で60°の角度で最大15、85°の角度で最大50の光沢レベルで得られる、上記組成物。 - 組成物中の化合物(b)の量が組成物の総重量に対し、0.1〜20wt%である、請求項9に記載の艶消し組成物。
- 艶消し組成物中の艶消し剤(d)の量が組成物の総重量に対し、0.5〜15wt%である、請求項9〜10のいずれかに記載の艶消し組成物。
- 艶消し剤(d)がシリカ及び/又はワックスから選ばれる、請求項9〜11のいずれかに記載の艶消し組成物。
- 組成物中の単官能性アルキル(メタ)アクリレートの量が10wt%のレベル未満である、請求項9〜12のいずれかに記載の艶消し組成物。
- 請求項9〜13のいずれかに記載の放射線硬化性艶消し組成物(II)の製造方法であって、
(i)請求項1〜8のいずれかに記載の放射線硬化性組成物を提供するステップ、
(ii)望むなら艶消し剤(d)を添加するステップ、
(iii)任意に、さらに(メタ)アクリル化化合物、及び
(iv)任意に、添加剤及び/又は溶媒を添加するステップ
を含み、ステップ(i)、(ii)、(iii)及び(iv)がいずれの順序であってもよい、上記方法。 - (i)請求項1〜13のいずれかに記載の放射線硬化性組成物を物品又は基材の少なくとも一つの表面に塗布するステップ、
(ii)その後、コーティングを放射線硬化するステップを含み、
12μmの硬化フィルム厚で60°の角度で最大15、85°の角度で最大50の光沢測定値を有する艶消しコーティングを得る、物品又は基材のコーティング方法。 - 前記基材が木材、プラスチック、フィルム、及び/又はホイルからなる群から選ばれる、請求項15に記載の方法により得られる基材。
- 請求項1〜13のいずれかに記載の放射線硬化性組成物から調製されるコーティング、インク、刷り重ねワニス、又は接着剤。
- 6〜120μmの乾燥厚を有するコーティングについて光沢レベルを60°の角度で最大50、85°の角度で最大80に低減するための、請求項1〜13のいずれかに記載の組成物の使用。
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