JP6882133B2 - ポリマー官能基化カーボンの存在下で有機酸を用いた硫黄粒子の形成 - Google Patents

ポリマー官能基化カーボンの存在下で有機酸を用いた硫黄粒子の形成 Download PDF

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JP6882133B2
JP6882133B2 JP2017194403A JP2017194403A JP6882133B2 JP 6882133 B2 JP6882133 B2 JP 6882133B2 JP 2017194403 A JP2017194403 A JP 2017194403A JP 2017194403 A JP2017194403 A JP 2017194403A JP 6882133 B2 JP6882133 B2 JP 6882133B2
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sulfur
bpei
conductive carbon
particles
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JP2018073813A5 (https=
JP2018073813A (ja
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ジョン・マルドゥーン
クラウディウ・ビィ・ブカー
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トヨタ モーター エンジニアリング アンド マニュファクチャリング ノース アメリカ，インコーポレイティド
トヨタ モーター エンジニアリング アンド マニュファクチャリング ノース アメリカ，インコーポレイティド
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/604—Polymers containing aliphatic main chain polymers
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/06—Making microcapsules or microballoons by phase separation
    • H—ELECTRICITY
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    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
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    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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    • H01M4/139—Processes of manufacture
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    • H—ELECTRICITY
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    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H01M4/382—Lithium
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    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
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    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
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    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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  • Chemical & Material Sciences (AREA)
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  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
JP2017194403A 2016-10-31 2017-10-04 ポリマー官能基化カーボンの存在下で有機酸を用いた硫黄粒子の形成 Active JP6882133B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/339,224 US10312517B2 (en) 2016-10-31 2016-10-31 In situ formation of sulfur particles using organic acids in the presence of polymer functionalized carbon
US15/339,224 2016-10-31

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JP2018073813A JP2018073813A (ja) 2018-05-10
JP2018073813A5 JP2018073813A5 (https=) 2019-11-07
JP6882133B2 true JP6882133B2 (ja) 2021-06-02

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Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10559817B2 (en) * 2017-02-01 2020-02-11 Toyota Motor Engineering & Manufacturing North America, Inc. Sulfur particles coated with inorganic-organic hybrid membranes as cathode active material and batteries containing the particles
US11515519B2 (en) * 2017-10-17 2022-11-29 VoltaXplore Inc Graphene-polymer porous scaffold for stable lithium-sulfur batteries
CN110707297B (zh) * 2018-07-10 2021-05-14 比亚迪股份有限公司 正极材料及其制备方法、锂离子电池和车辆
EP3948989A4 (en) * 2019-03-26 2023-05-10 Conamix Inc. NANOPARTICLES WITH POLYTHIONATE CORE
CN110518201A (zh) * 2019-08-05 2019-11-29 中南大学 一种纳米级碳硫复合材料及其制备方法
US12500227B2 (en) * 2019-10-30 2025-12-16 Salient Energy Inc. Encapsulated electroactive materials for use in rechargeable aqueous zinc cells and batteries and methods of preparing encapsulated electroactive materials
JP2025537000A (ja) * 2023-05-03 2025-11-12 エルジー エナジー ソリューション リミテッド 長寿命を有するリチウム二次電池

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100416098B1 (ko) 2001-12-18 2004-01-24 삼성에스디아이 주식회사 캐소드 전극, 이의 제조방법 및 이를 채용한 리튬 설퍼 전지
KR100477987B1 (ko) * 2002-09-11 2005-03-23 삼성에스디아이 주식회사 리튬-황 전지용 양극 및 이를 포함하는 리튬-황 전지
CN102142554A (zh) * 2011-02-16 2011-08-03 中国人民解放军63971部队 一种具有网络结构的纳米碳硫复合材料及其制备方法
EP2691338A4 (en) * 2011-03-31 2014-10-15 Basf Se PARTICULAR POROUS CARBON MATERIAL AND ITS USE IN LITHIUM CELLS
US9099744B2 (en) * 2011-03-31 2015-08-04 Basf Se Particulate porous carbon material and use thereof in lithium cells
US20130164625A1 (en) 2011-12-22 2013-06-27 Arumugam Manthiram Sulfur-carbon composite cathodes for rechargeable lithium-sulfur batteries and methods of making the same
CN104221203B (zh) * 2012-03-19 2017-04-12 国立大学法人横浜国立大学 碱金属‑硫系二次电池
US20140255770A1 (en) 2013-03-11 2014-09-11 Jong-Jan Lee Carbon-Sulfur Composite Cathode Passivation and Method for Making Same
CN103474633A (zh) * 2012-06-07 2013-12-25 中国人民解放军63971部队 一种具有网络双核壳结构的碳-硫-外壳物复合材料及其制备方法
US8980471B2 (en) * 2013-02-21 2015-03-17 Toyota Motor Engineering & Manufacturing North America, Inc. Carbon-sulfur composites encapsulated with polyelectrolyte multilayer membranes
CN104112857B (zh) * 2013-04-17 2017-06-13 中国科学院苏州纳米技术与纳米仿生研究所 一种锂硫电池正极材料的制备方法
US9806326B2 (en) 2013-12-05 2017-10-31 GM Global Technology Operations LLC One-step method for preparing a lithiated silicon electrode
US20150236343A1 (en) 2014-02-18 2015-08-20 GM Global Technology Operations LLC Coated electrodes for lithium batteries
FR3018516B1 (fr) * 2014-03-13 2019-08-23 Blue Solutions Batterie lithium-soufre
KR101601415B1 (ko) 2014-05-08 2016-03-09 현대자동차주식회사 코어-쉘 구조의 황 입자를 포함하는 이차전지
KR101683963B1 (ko) 2014-05-26 2016-12-07 현대자동차주식회사 이중 건식 복합화를 통한 황-탄소 복합체 제조 방법
US9819015B2 (en) 2014-09-18 2017-11-14 Toyota Motor Engineering & Manufacturing North America, Inc. Encapsulated sulfur sub-micron particles as electrode active material
JP6796254B2 (ja) * 2014-11-13 2020-12-09 株式会社Ｇｓユアサ 硫黄−カーボン複合体、硫黄―カーボン複合体を含む電極を備えた非水電解質電池、及び硫黄−カーボン複合体の製造方法

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US20180123133A1 (en) 2018-05-03
CN108011081B (zh) 2021-05-25
CN108011081A (zh) 2018-05-08
JP2018073813A (ja) 2018-05-10
US10312517B2 (en) 2019-06-04

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