JP6806060B2 - 積層体の製造方法 - Google Patents
積層体の製造方法 Download PDFInfo
- Publication number
- JP6806060B2 JP6806060B2 JP2017530863A JP2017530863A JP6806060B2 JP 6806060 B2 JP6806060 B2 JP 6806060B2 JP 2017530863 A JP2017530863 A JP 2017530863A JP 2017530863 A JP2017530863 A JP 2017530863A JP 6806060 B2 JP6806060 B2 JP 6806060B2
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- Prior art keywords
- thread
- vinyl chloride
- sheet
- chloride resin
- sewing
- Prior art date
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- 238000004519 manufacturing process Methods 0.000 title claims description 31
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- 239000011347 resin Substances 0.000 claims description 68
- 238000000034 method Methods 0.000 claims description 50
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- 238000009958 sewing Methods 0.000 claims description 46
- 239000007788 liquid Substances 0.000 claims description 43
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- 239000011342 resin composition Substances 0.000 claims description 36
- 238000005470 impregnation Methods 0.000 claims description 34
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- 239000004814 polyurethane Substances 0.000 claims description 26
- 238000010030 laminating Methods 0.000 claims description 25
- 238000009835 boiling Methods 0.000 claims description 11
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- -1 allyl ethers Chemical class 0.000 description 50
- 229910052751 metal Inorganic materials 0.000 description 21
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- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 11
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- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 10
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- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 6
- JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 6
- 210000003491 skin Anatomy 0.000 description 6
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- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- KMZHZAAOEWVPSE-UHFFFAOYSA-N 2,3-dihydroxypropyl acetate Chemical compound CC(=O)OCC(O)CO KMZHZAAOEWVPSE-UHFFFAOYSA-N 0.000 description 4
- NXQMCAOPTPLPRL-UHFFFAOYSA-N 2-(2-benzoyloxyethoxy)ethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCOCCOC(=O)C1=CC=CC=C1 NXQMCAOPTPLPRL-UHFFFAOYSA-N 0.000 description 4
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
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- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 4
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 description 4
- UYXTWWCETRIEDR-UHFFFAOYSA-N Tributyrin Chemical compound CCCC(=O)OCC(OC(=O)CCC)COC(=O)CCC UYXTWWCETRIEDR-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 4
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- 239000004611 light stabiliser Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 4
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 4
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 3
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000010556 emulsion polymerization method Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
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- 238000010438 heat treatment Methods 0.000 description 3
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 3
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
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- 229920002397 thermoplastic olefin Polymers 0.000 description 3
- 235000010215 titanium dioxide Nutrition 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 3
- 239000003981 vehicle Substances 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- PHDVPEOLXYBNJY-KTKRTIGZSA-N 2-(2-hydroxyethoxy)ethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCOCCO PHDVPEOLXYBNJY-KTKRTIGZSA-N 0.000 description 2
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- VVAAYFMMXYRORI-UHFFFAOYSA-N 4-butoxy-2-methylidene-4-oxobutanoic acid Chemical compound CCCCOC(=O)CC(=C)C(O)=O VVAAYFMMXYRORI-UHFFFAOYSA-N 0.000 description 2
- OIYTYGOUZOARSH-UHFFFAOYSA-N 4-methoxy-2-methylidene-4-oxobutanoic acid Chemical compound COC(=O)CC(=C)C(O)=O OIYTYGOUZOARSH-UHFFFAOYSA-N 0.000 description 2
- GPZYYYGYCRFPBU-UHFFFAOYSA-N 6-Hydroxyflavone Chemical compound C=1C(=O)C2=CC(O)=CC=C2OC=1C1=CC=CC=C1 GPZYYYGYCRFPBU-UHFFFAOYSA-N 0.000 description 2
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
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- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 description 2
- VOWAEIGWURALJQ-UHFFFAOYSA-N Dicyclohexyl phthalate Chemical compound C=1C=CC=C(C(=O)OC2CCCCC2)C=1C(=O)OC1CCCCC1 VOWAEIGWURALJQ-UHFFFAOYSA-N 0.000 description 2
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- 239000004593 Epoxy Substances 0.000 description 2
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- 239000005977 Ethylene Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
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- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
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- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 2
- FRQDZJMEHSJOPU-UHFFFAOYSA-N Triethylene glycol bis(2-ethylhexanoate) Chemical compound CCCCC(CC)C(=O)OCCOCCOCCOC(=O)C(CC)CCCC FRQDZJMEHSJOPU-UHFFFAOYSA-N 0.000 description 2
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 description 2
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- ROPXFXOUUANXRR-BUHFOSPRSA-N bis(2-ethylhexyl) (e)-but-2-enedioate Chemical compound CCCCC(CC)COC(=O)\C=C\C(=O)OCC(CC)CCCC ROPXFXOUUANXRR-BUHFOSPRSA-N 0.000 description 2
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- IMIOEHJVRZOQBJ-UHFFFAOYSA-N bis(6-methylheptyl) benzene-1,3-dicarboxylate Chemical compound CC(C)CCCCCOC(=O)C1=CC=CC(C(=O)OCCCCCC(C)C)=C1 IMIOEHJVRZOQBJ-UHFFFAOYSA-N 0.000 description 2
- QUCSUPGVEFBICW-UHFFFAOYSA-N bis(8-methylnonyl) 7-oxabicyclo[4.1.0]heptane-3,4-dicarboxylate Chemical compound C1C(C(=O)OCCCCCCCC(C)C)C(C(=O)OCCCCCCCC(C)C)CC2OC21 QUCSUPGVEFBICW-UHFFFAOYSA-N 0.000 description 2
- OAXZVLMNNOOMGN-UHFFFAOYSA-N bis(8-methylnonyl) decanedioate Chemical compound CC(C)CCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC(C)C OAXZVLMNNOOMGN-UHFFFAOYSA-N 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- FEXXLIKDYGCVGJ-UHFFFAOYSA-N butyl 8-(3-octyloxiran-2-yl)octanoate Chemical compound CCCCCCCCC1OC1CCCCCCCC(=O)OCCCC FEXXLIKDYGCVGJ-UHFFFAOYSA-N 0.000 description 2
- ULBTUVJTXULMLP-UHFFFAOYSA-N butyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCC ULBTUVJTXULMLP-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
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Description
本発明は、糸を用いてシート状物に縫製加工を施す縫製工程と、縫製工程の前若しくは後、又は、該縫製工程中に、糸の少なくとも一部に液体を含浸させる含浸工程と、縫製工程及び含浸工程により得られるシート状成形体の少なくとも一方の面に、発泡ポリウレタン層を積層させる積層工程と、を備える積層体の製造方法である。
ここで、「貫通している部位付近」とは、糸のうち、シート状成形体の厚み方向に亘って糸がシート状物を貫通している部位、及び/又は、該部位からシート状成形体の厚み方向に平行な方向に糸の厚み分だけ突出した部位を指す。
縫製工程S1aは、糸3を用いてシート状物2に対して縫製加工を行い、シート状物2にステッチ模様を付する工程である。縫製加工を行うことで、積層体10の意匠性、及び商品性を向上することが可能となる。
防黴剤の具体例は、脂肪族エステル系防黴剤、炭化水素系防黴剤、有機窒素系防黴剤、有機窒素硫黄系防黴剤等である。
帯電防止剤の具体例は、脂肪酸塩類、高級アルコール硫酸エステル類、スルホン酸塩類等のアニオン系帯電防止剤;脂肪族アミン塩類、第四級アンモニウム塩類のカチオン系帯電防止剤;ポリオキシエチレンアルキルエーテル類、ポリオキシエチレンアルキルフェノールエーテル類等のノニオン系帯電防止剤等である。
光安定剤の具体例は、ベンゾトリアゾール系、ベンゾフェノン系、ニッケルキレート系等の紫外線吸収剤、ヒンダートアミン系光安定剤等である。
β−ジケトン類の含有量は特定の範囲に限定されない。好ましい当該含有量は、塩化ビニル樹脂(a)100質量部に対して0.1〜5質量部である。
含浸工程S1bは、糸3の少なくとも一部に液体を含浸させる工程であり、縫製工程S1aの前若しくは後、又は、該縫製工程中に行われる。糸3の少なくとも一部に液体を含浸させることにより、後述する積層工程S2において、発泡ポリウレタン層4の発泡ポリウレタンがシート状成形体1の意匠面の縫製箇所7から流出すること防止可能となる。糸3に液体を含浸させる部分については、特に制限はないが、少なくとも糸3がシート状物2を貫通している部位付近の糸の少なくとも一部に液体が含浸させることが好ましい。ここで、「貫通している部位付近」とは、糸3のうち、シート状成形体1の厚み方向に亘って糸3がシート状物1を貫通している部位(例えば、図3にAで示す部位)、及び/又は、該部位からシート状成形体の厚み方向に平行な方向に糸の厚み分だけ突出した部位(例えば、図3にBで示す部位)を指す。糸3が上糸と下糸とからなっている場合は、少なくとも下糸の少なくとも一部に液体を含浸させることが好ましい。
積層工程S2は、縫製工程S1a及び含浸工程S1bにより得られるシート状成形体1の少なくとも一方の面に、発泡ポリウレタン層4を積層する工程である。
本発明は、積層工程S2の後に、糸に含浸させた液体の少なくとも一部を除去する除去工程S3を備えていてもよい。除去工程S3を設けることで、糸に含浸させた液体の少なくとも一部が除去された積層体10を提供することができる。
後に説明するようにして、シート状物に所定の糸を用いて縫製加工が施されたシート状成形体に発泡ポリウレタン層が積層されてなる積層体を作製した。各条件のステッチ数を数え、そのうち何か所からウレタンが漏れているかを目視で確認した。ここで、「ウレタン漏れ」とは、意匠面のステッチ部からウレタンが見えることを指す。このウレタン漏れが発生するステッチ数を、総ステッチ数で割り、ウレタン漏れ発生割合を求めた。結果を表2に示す。ウレタン漏れ発生割合が15%未満であれば、ウレタン漏れが防止できているといえる。
<シート状物の作製>
表1に示す配合成分のうち可塑剤及びダスティング剤を除く成分をヘンシェルミキサーに入れて混合し、混合物の温度が80℃に上昇した時点で可塑剤を添加後、ドライアップ(可塑剤が塩化ビニル樹脂粒子に吸収されて、上記混合物がさらさらになった状態をいう。)し、その後、組成物が70℃以下に冷却された時点でダスティング剤である乳化重合塩化ビニル樹脂を添加し、粉体成形用塩化ビニル樹脂組成物を調製した。
ボビン単体の重量を測定したのち、エースクラウン 車輌用 #8をボビンに巻き取り、ボビン全体の重量を測定した。その後、ボビン側面より、可塑剤(トリメックス N−08、沸点=430℃、花王(株)製)をスポイトで滴下し、糸に可塑剤を含浸させた。糸に可塑剤を含浸させた後のボビン全体の重量を測定し、糸に対しての液体の含浸率を求めた。得られた含浸率を表2に示す。
含浸工程の直後に、シート状物に対して縫製加工を施した。使用したミシンは、JUKI社製LU−2860−7である。縫製糸は上糸としてエースクラウン 車輌用 #5を用い、下糸として上記含浸工程において液体を含浸させたエースクラウン 車輌用 #8を用いた。ステッチ間隔は3ステッチ/cmで、速度は3.3ステッチ/secで9〜10cm程度の長さを縫製した。これを同一の成形シート上に3本縫製加工し(縫製番号:1〜3)、実施例1に係るシート状成形体を作製した。
200mm×300mm×10mmの金型の下に、250mm×340mm×2mmのアルミ板を置き、得られたシート状成形体2枚を348mm×255mm×10mmの金型の蓋に、シボ付き面が蓋側になるように、それぞれ仮固定し、プロピレングリコールのPO・EOブロック付加物(水酸基価28、末端EO単位の含有量10%、内部EO単位の含有量4%)50質量部、グリセリンのPO・EOブロック付加物(水酸基価21、末端EO単位の含有量14%)50質量部、水2.5質量部、トリエチレンジアミンのエチレングリコ−ル溶液(東ソー(株)製、商品名:「TEDA−L33」)0.2質量部、トリエタノールアミン1.2質量部、トリエチルアミン0.5質量部及び整泡剤(信越化学工業(株)製、商品名:「F−122」)0.5質量部からなるポリオール混合物と、ポリメチレンポリフェニレンポリイソシアネート(ポリメリックMDI))とを、インデックスが98になる比率で混合して混合液を作製し、それを金型に注ぎ、上記シート状成形体を仮固定した蓋で、金型を密閉した。5分後、1mm厚のシート状成形体からなる表皮に、9mm厚・密度0.18g/cm3の発泡ポリウレタン、及び、上記アルミ板が、この順にて裏打ちされた試料である積層体を金型から取り出した。
積層工程により得られた積層体を風乾し、糸に含浸させた液体の少なくとも一部を除去することで、実施例1に係る積層体を得た。
実施例1で用いた糸に含浸させる液体を可塑剤から水(沸点=100℃、イオン交換水)に変更した以外は、実施例1と同様にして実施例2に係る積層体を作製した。
実施例1の含浸工程を除いた以外は、実施例1と同様にして比較例1に係る積層体を作製した。
(実施例3)
実施例1と同様にして得られたシート状成形体を、積層工程の前に40℃で2時間乾燥した以外は、実施例1と同様にして実施例3に係る積層体を作製した。
実施例2と同様にして得られたシート状成形体を、積層工程の前に40℃で2時間乾燥した以外は、実施例2と同様にして実施例4に係る積層体を作製した。
2 シート状物
3 糸
3a 上糸
3b 下糸
4 発泡ポリウレタン層
5 基材
6 凹溝
7 縫製箇所
10 積層体
Claims (11)
- 糸を用いてシート状物に縫製加工を施す縫製工程と、
前記縫製工程の前若しくは後、又は、該縫製工程中に、前記糸の少なくとも一部に沸点が150〜1000℃の液体を含浸させる含浸工程と、
前記縫製工程及び前記含浸工程により得られるシート状成形体の少なくとも一方の面に、発泡ポリウレタン層を積層させる積層工程と、を備える積層体の製造方法。 - 前記含浸工程において、
前記縫製工程及び前記含浸工程により得られる前記シート状成形体における、少なくとも前記糸が前記シート状成形体を貫通している部位付近の前記糸の少なくとも一部に前記液体を含浸させる、請求項1に記載の積層体の製造方法。 - 前記縫製工程の前に前記含浸工程を行う、請求項1又は2に記載の積層体の製造方法。
- 前記積層工程の後に、前記糸に含浸させた前記液体の少なくとも一部を除去する除去工程を備える、請求項1〜3のいずれか1項に記載の積層体の製造方法。
- 前記シート状物が、粉体成形用樹脂組成物をパウダースラッシュ成形してなるものである、請求項1〜4のいずれか1項に記載の積層体の製造方法。
- 前記粉体成形用樹脂組成物が塩化ビニル樹脂を含有する粉体成形用塩化ビニル樹脂組成物である、請求項5に記載の積層体の製造方法。
- 前記塩化ビニル樹脂の平均重合度が800〜5000である、請求項6に記載の積層体の製造方法。
- 前記粉体成形用樹脂組成物が、前記塩化ビニル樹脂100質量部に対して、可塑剤を30〜200質量部含む、請求項6又は7に記載の積層体の製造方法。
- 前記液体が可塑剤である、請求項1〜8のいずれか1項に記載の積層体の製造方法。
- 前記液体の含浸率が0.1〜50wt.%である、請求項1〜9のいずれか1項に記載の積層体の製造方法。
- 前記糸が上糸及び下糸からなり、
前記含浸工程において、前記上糸及び前記下糸のうち、少なくとも前記下糸の少なくとも一部に前記液体を含浸させることを特徴とする、請求項1〜10のいずれか1項に記載の積層体の製造方法。
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JPH05177068A (ja) * | 1991-12-28 | 1993-07-20 | Takamichi Konno | 防水性を必要とする縫製品の縫製方法 |
JP2506020B2 (ja) * | 1992-02-10 | 1996-06-12 | 東亞合成株式会社 | 粉末成形用樹脂組成物 |
JPH08208944A (ja) * | 1995-02-02 | 1996-08-13 | Showa Denko Kk | 多層積層体 |
DE60201968T2 (de) * | 2002-02-08 | 2005-12-22 | Visteon Global Technologies, Inc., Dearborn | Verfahren zur Herstellung eines dekorativen Armaturbretts und entsprechendes Armaturbrett |
WO2012020618A1 (ja) * | 2010-08-12 | 2012-02-16 | 日本ゼオン株式会社 | 粉体成形用塩化ビニル樹脂組成物、塩化ビニル樹脂成形体及び積層体 |
US20130048219A1 (en) * | 2011-08-24 | 2013-02-28 | Roxanne Ferreiro | Adhesive Thread System |
JP2013119688A (ja) * | 2011-12-08 | 2013-06-17 | Kanagawa Kk | 熱膨張性縫製糸及びその縫製方法 |
CN102977510B (zh) * | 2012-12-11 | 2014-11-12 | 苏州润佳工程塑料股份有限公司 | 仪表板蒙皮用搪塑pvc材料及其制备方法 |
JP2015136827A (ja) * | 2014-01-21 | 2015-07-30 | トヨタ自動車株式会社 | 内装部材とその製造方法 |
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2016
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EP3330073B1 (en) | 2020-03-18 |
CN107848250A (zh) | 2018-03-27 |
EP3330073A4 (en) | 2019-02-27 |
TW201710072A (zh) | 2017-03-16 |
JPWO2017018387A1 (ja) | 2018-05-17 |
WO2017018387A1 (ja) | 2017-02-02 |
EP3330073A1 (en) | 2018-06-06 |
US20180207843A1 (en) | 2018-07-26 |
MX2018000908A (es) | 2018-05-15 |
KR20180035821A (ko) | 2018-04-06 |
CA2993302A1 (en) | 2017-02-02 |
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