JP6768731B2 - シラン基含有ポリマー組成物およびそれを含むコーティング - Google Patents
シラン基含有ポリマー組成物およびそれを含むコーティング Download PDFInfo
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- JP6768731B2 JP6768731B2 JP2018072092A JP2018072092A JP6768731B2 JP 6768731 B2 JP6768731 B2 JP 6768731B2 JP 2018072092 A JP2018072092 A JP 2018072092A JP 2018072092 A JP2018072092 A JP 2018072092A JP 6768731 B2 JP6768731 B2 JP 6768731B2
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- polymer
- silane
- weight
- floor care
- composition
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- 229920000642 polymer Polymers 0.000 title claims description 250
- 239000000203 mixture Substances 0.000 title claims description 209
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title claims description 68
- 238000000576 coating method Methods 0.000 title description 27
- 229910000077 silane Inorganic materials 0.000 claims description 75
- 239000007787 solid Substances 0.000 claims description 55
- 239000000178 monomer Substances 0.000 claims description 52
- 239000002253 acid Substances 0.000 claims description 22
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 20
- 239000004014 plasticizer Substances 0.000 claims description 17
- 229920002554 vinyl polymer Polymers 0.000 claims description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 14
- 150000004291 polyenes Chemical class 0.000 claims description 8
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 5
- 238000009472 formulation Methods 0.000 claims description 5
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical group CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 claims 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims 1
- -1 polishes Substances 0.000 description 40
- 150000004756 silanes Chemical class 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 239000000654 additive Substances 0.000 description 18
- 239000004094 surface-active agent Substances 0.000 description 18
- 239000001993 wax Substances 0.000 description 17
- 239000004615 ingredient Substances 0.000 description 16
- 239000002245 particle Substances 0.000 description 13
- 239000011248 coating agent Substances 0.000 description 12
- 239000004816 latex Substances 0.000 description 12
- 229920000126 latex Polymers 0.000 description 12
- 239000003973 paint Substances 0.000 description 12
- 239000004971 Cross linker Substances 0.000 description 11
- 230000000996 additive effect Effects 0.000 description 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 10
- 239000002023 wood Substances 0.000 description 10
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- 239000003431 cross linking reagent Substances 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
- 230000002378 acidificating effect Effects 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 125000000524 functional group Chemical group 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000002609 medium Substances 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000011737 fluorine Substances 0.000 description 6
- 229910052731 fluorine Inorganic materials 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 229920000058 polyacrylate Polymers 0.000 description 5
- 229920002635 polyurethane Polymers 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 5
- 229920003048 styrene butadiene rubber Polymers 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- 239000002174 Styrene-butadiene Substances 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 4
- 229910001385 heavy metal Inorganic materials 0.000 description 4
- 239000004579 marble Substances 0.000 description 4
- 229920005749 polyurethane resin Polymers 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000011115 styrene butadiene Substances 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Chemical group 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 230000001588 bifunctional effect Effects 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 150000007942 carboxylates Chemical group 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000010438 granite Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- UDUKMRHNZZLJRB-UHFFFAOYSA-N triethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OCC)(OCC)OCC)CCC2OC21 UDUKMRHNZZLJRB-UHFFFAOYSA-N 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
- UAJRSHJHFRVGMG-UHFFFAOYSA-N 1-ethenyl-4-methoxybenzene Chemical compound COC1=CC=C(C=C)C=C1 UAJRSHJHFRVGMG-UHFFFAOYSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- KVZUCOGWKYOPID-UHFFFAOYSA-N 2,4,5-Trimethoxybenzoic acid Chemical compound COC1=CC(OC)=C(C(O)=O)C=C1OC KVZUCOGWKYOPID-UHFFFAOYSA-N 0.000 description 2
- XZRHNAFEYMSXRG-UHFFFAOYSA-N 2,5-dimethylbenzoic acid Chemical compound CC1=CC=C(C)C(C(O)=O)=C1 XZRHNAFEYMSXRG-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000009408 flooring Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920006029 tetra-polymer Polymers 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 1
- APPOKADJQUIAHP-GGWOSOGESA-N (2e,4e)-hexa-2,4-diene Chemical compound C\C=C\C=C\C APPOKADJQUIAHP-GGWOSOGESA-N 0.000 description 1
- POTYORUTRLSAGZ-UHFFFAOYSA-N (3-chloro-2-hydroxypropyl) prop-2-enoate Chemical compound ClCC(O)COC(=O)C=C POTYORUTRLSAGZ-UHFFFAOYSA-N 0.000 description 1
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 1
- 125000006832 (C1-C10) alkylene group Chemical group 0.000 description 1
- 125000006527 (C1-C5) alkyl group Chemical group 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
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- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- JKJAJSWMKTWWJS-UHFFFAOYSA-N 1-(4-methoxyphenyl)cyclohexane-1-carboxylic acid Chemical compound C1=CC(OC)=CC=C1C1(C(O)=O)CCCCC1 JKJAJSWMKTWWJS-UHFFFAOYSA-N 0.000 description 1
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical group CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
- NSOAQRMLVFRWIT-UHFFFAOYSA-N 1-ethenoxydecane Chemical compound CCCCCCCCCCOC=C NSOAQRMLVFRWIT-UHFFFAOYSA-N 0.000 description 1
- LMAUULKNZLEMGN-UHFFFAOYSA-N 1-ethyl-3,5-dimethylbenzene Chemical compound CCC1=CC(C)=CC(C)=C1 LMAUULKNZLEMGN-UHFFFAOYSA-N 0.000 description 1
- WAGRIKSHWXFXHV-UHFFFAOYSA-N 1-hydroxybutyl prop-2-enoate Chemical compound CCCC(O)OC(=O)C=C WAGRIKSHWXFXHV-UHFFFAOYSA-N 0.000 description 1
- WULAHPYSGCVQHM-UHFFFAOYSA-N 2-(2-ethenoxyethoxy)ethanol Chemical compound OCCOCCOC=C WULAHPYSGCVQHM-UHFFFAOYSA-N 0.000 description 1
- PRAMZQXXPOLCIY-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethanesulfonic acid Chemical compound CC(=C)C(=O)OCCS(O)(=O)=O PRAMZQXXPOLCIY-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- VZABAOXACKGQDM-UHFFFAOYSA-N 2-aminoacetic acid;azane;zinc Chemical compound N.[Zn].NCC(O)=O VZABAOXACKGQDM-UHFFFAOYSA-N 0.000 description 1
- OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
- GNUGVECARVKIPH-UHFFFAOYSA-N 2-ethenoxypropane Chemical compound CC(C)OC=C GNUGVECARVKIPH-UHFFFAOYSA-N 0.000 description 1
- WLJVXDMOQOGPHL-PPJXEINESA-N 2-phenylacetic acid Chemical compound O[14C](=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-PPJXEINESA-N 0.000 description 1
- RLFXJQPKMZNLMP-UHFFFAOYSA-N 2-phenylprop-2-enenitrile Chemical compound N#CC(=C)C1=CC=CC=C1 RLFXJQPKMZNLMP-UHFFFAOYSA-N 0.000 description 1
- SSBWZCVLJGUIGM-UHFFFAOYSA-N 2-sulfanylpropyl 2-methylprop-2-enoate Chemical compound CC(S)COC(=O)C(C)=C SSBWZCVLJGUIGM-UHFFFAOYSA-N 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- IGLWCQMNTGCUBB-UHFFFAOYSA-N 3-methylidenepent-1-ene Chemical compound CCC(=C)C=C IGLWCQMNTGCUBB-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- XRHGYUZYPHTUJZ-UHFFFAOYSA-N 4-chlorobenzoic acid Chemical compound OC(=O)C1=CC=C(Cl)C=C1 XRHGYUZYPHTUJZ-UHFFFAOYSA-N 0.000 description 1
- IPLKGJHGWCVSOG-UHFFFAOYSA-N 4-chlorobutanoic acid Chemical compound OC(=O)CCCCl IPLKGJHGWCVSOG-UHFFFAOYSA-N 0.000 description 1
- FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical compound OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 description 1
- DXWCXUYPHZMDFL-UHFFFAOYSA-N 6-methoxypyrido[2,3-b]pyrazine Chemical compound N1=CC=NC2=NC(OC)=CC=C21 DXWCXUYPHZMDFL-UHFFFAOYSA-N 0.000 description 1
- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- ODIUACFRPDQOPA-UHFFFAOYSA-M C(C=C/C(=O)[O-])(=O)[O-].[Zn+].[NH4+] Chemical compound C(C=C/C(=O)[O-])(=O)[O-].[Zn+].[NH4+] ODIUACFRPDQOPA-UHFFFAOYSA-M 0.000 description 1
- PNFOZEDBTQHPPH-UHFFFAOYSA-M C([O-])([O-])=O.C(CN)N.[Ca+].[NH4+] Chemical compound C([O-])([O-])=O.C(CN)N.[Ca+].[NH4+] PNFOZEDBTQHPPH-UHFFFAOYSA-M 0.000 description 1
- WRAGBEWQGHCDDU-UHFFFAOYSA-M C([O-])([O-])=O.[NH4+].[Zr+] Chemical compound C([O-])([O-])=O.[NH4+].[Zr+] WRAGBEWQGHCDDU-UHFFFAOYSA-M 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
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- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- BZUYOAAPZVNNSP-UHFFFAOYSA-N N.[Zr+4] Chemical compound N.[Zr+4] BZUYOAAPZVNNSP-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 208000004880 Polyuria Diseases 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
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Classifications
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- C08L35/06—Copolymers with vinyl aromatic monomers
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- C08L43/04—Homopolymers or copolymers of monomers containing silicon
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/28—Non-macromolecular organic substances
- C08L2666/44—Silicon-containing compounds
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Description
本国際出願は、2012年1月25日出願の米国仮出願番号61/590,545の優先権を主張しその利益を得る。この開示は本明細書中に参考として援用される。
ポリマーコーティングはペイント、木材用仕上げ剤、印刷表面、写真、床のケア製品、ワックス、ポリッシュ剤等において、方向(例えば、垂直、水平、またはそうでない方向)にかかわらず表面を被覆して保護するために使用される。
以下の説明はポリマーおよびシランを含む組成物に関連する。シランはポリマーバックボーンに結合したシラン基の形態、または異なる構成要素として存在することができる。ポリマーはラテックス、たとえば液体、特には水中のポリマーエマルションまたは懸濁液として提供することができる。組成物は、様々な仕上げ組成物(finish composition)、特に硬い高光沢表面における使用が意図される仕上げ組成物に使用されることができる。本明細書の多くの記載は、特に床ケア組成物として有用なポリマー仕上げ組成物に関し、特には硬い高光沢表面への使用のためのものに関する。ポリマーとシランを含む説明されたポリマー組成物は、他のポリマー仕上げ組成物においても有用であることが想定されるが、特にペイント、木材仕上げ剤、床以外用のワックス、ポリッシュなどの建築物用コーティングとして有用である。
「ポリマー」は1種以上のモノマーの重合生成物を意味し、ホモ−、ジ−、ター−、および、テトラ−ポリマーなどを含む。「単量体単位」または「単量体単位ユニット(mer unit)」は、単一の反応体分子から得られたポリマーの部分を意味する。例えば、エチレン単量体単位は、一般式 −CH2CH2− を有する。
「コポリマー」は、典型的には複数のモノマーである2つの反応体から得られた単量体単位ユニットを含むポリマーを意味し、ランダム、ブロック、セグメント化、グラフトなどのコポリマーを含む。
「インターポリマー」は、典型的には複数のモノマーである少なくとも2つの反応体から得られた単量体単位ユニットを含むポリマーを意味し、コポリマー、ターポリマー、テトラポリマー、および同様のものを含む。
「ポリエン」は、少なくとも2個の二重結合をその最も長い部分に有する分子を意味し、具体的にはジエン類、トリエン類、および同様のものを含む。
「水性」は構成要素として水を含むすべての液体ブレンドまたは混合物をいう。
「外部界面活性剤」は、直接組成物に加えられる表面活性剤を意味して、組成物の別の成分の構成要素の結果物としては存在しない。
先の要約で説明したように、本発明のポリマー組成物はポリマーとシランを含む。ポリマー組成物は、ポリマー仕上げ組成物を始めとするが、それには制限されない組成物を提供するのに使用される。
最大70%、一般的に約10から約50%のビニル芳香族単量体、たとえばスチレン、またはさまざまなハロゲン化スチレン系モノマー、ビニルトルエン、oまたはp−メトキシスチレン、アリルフェニルエーテル、アリルトリルエーテル、およびα−メチルスチレンから得られる単位;
約3から約50%、一般的に約5から20%の、少なくとも1つのエチレン性不飽和酸単量体、たとえばマレイン酸、フマル酸、ケイ皮酸、アコニット酸、クロトン酸、シトラコン酸、アクリルオキシプロピオン酸、(メタ)アクリル酸、イタコン酸、ポリ酸である上記のものの部分エステルから得られる単位;
約30から約97%、一般的に約35から約70%の、C1−C20、好ましくはC1−C12のアルキル(メタ)アクリレート単量体、たとえばメチル(メタ)アクリレート、エチル(メタ)アクリレート、n−ブチル(メタ)アクリレート、イソブチル(メタ)アクリレート、2−エチルヘキシルアクリレート、n−オクチルアクリレート、sec−ブチルアクリレート、シクロプロピルメタクリレート、さまざまなアセトアセトキシアルキル(メタ)アクリレート、2,3−ジ(アセトアセトキシ)プロピル(メタ)アクリレート、および同様のものなどから得られる単位;
任意に、最大40%の少なくとも1つの極性または分極可能な非イオン形成性親水性単量体、たとえば(メタ)アクリロニトリル、クロトノニトリル、α−シアノスチレン、α−クロロアクリロニトリル、エチルビニルエーテル、イソプロピルビニルエーテル、イソブチル−およびブチル−ビニルエーテル、ジエチレングリコールビニルエーテル、デシルビニルエーテル、酢酸ビニル、メタクリル酸イソボルニル、ヒドロキシアルキル(メタ)アクリレート、たとえば2−ヒドロキシエチル(メタ)アクリレート、2−または3−ヒドロキシプロピル(メタ)アクリレート、ブタンジオールアクリレート、3−クロロ−2−ヒドロキシプロピルアクリレート、並びにビニルチオール類、たとえば2−メルカプトプロピルメタクリレート、2−スルホエチルメタクリレート、メチルビニルチオールエーテル、およびプロピルビニルチオ−エーテルなどから得られる単位;および
任意に、最大10%の、酸部位がC1−C18の芳香族または脂肪族酸から得られる少なくとも1種のビニルエステル単量体、たとえばギ酸、酢酸、プロピオン酸、n−酪酸、n−吉草酸、パルミチック酸、ステリアン酸、フェニル酢酸、安息香酸、クロロ酢酸、ジクロロ酢酸、γ−クロロ酪酸、4−クロロ安息香酸、2,5−ジメチル安息香酸、o−トルイル酸、2,4,5−トリメトキシ安息香酸、シクロブタンカルボン酸、シクロヘキサンカルボン酸、1−(p−メトキシフェニル)シクロヘキサンカルボン酸、1−(p−トリル)−1−シクロペンタンカルボン酸、ヘキサン酸、ミリスチル酸、およびp−トルイル酸などから得られる単位。
単量体単位の相対量は、重合プロセス条件が実質的に完全な変換を可能にするときに、使用されるそれぞれのモノマーの量で近似できる。従って、上記の割合のすべてがモルパーセントであることが理解される。
実施例
1)なし(コントロール)
2)β−(3,4−エポキシシクロヘキシル)エチルトリエトキシシラン
3)3−(トリイソプロポキシルシリル)プロピルメタクリレート
4)ビニルトリエトキシシラン
5)ダウコーニング製の3−グリシドキシプロピルトリメトキシシラン
6)信越化学製の3−グリシドキシプロピルトリメトキシシラン
7)メチル(グリシドキシプロピル)ジエトキシシラン、および
8)3−メタクリロキシプロピルトリメトキシシラン。
ビニルトリエトキシシラン単量体単位がポリマーバックボーンに取り入れられている同じポリマーのバージョンが、追加のポリマー組成物(実施例9)を提供するのに使用された。
Claims (4)
- 以下を含む床ケア組成物:
a) 10から50モル%のビニル芳香族単量体単位、5から20モル%のメタアクリル酸から誘導されるエチレン性不飽和酸単量体単位、30から70モル%のメチル(メタ)アクリレート、ブチルアクリレートまたはそれらの組み合わせから誘導される単量体単位、0.1から1.5重量%のトリメトキシシランまたはトリエトキシシラン基のペンダントを有するシラン含有単量体単位を含むポリマーであって、
該シラン含有単量体がグリシドキシプロピルトリメトキシシランまたはビニルトリエトキシシランから誘導され、
該ポリマーは床ケア組成物の総固形分重量の70から92重量%の範囲である、
b) 床ケア組成物の総固形分重量の0.05から7重量部のワックス、
c) 床ケア組成物の総固形分重量の1から10重量部の永久的可塑剤、
d) 床ケア組成物の総固形分重量の1から10重量部の造膜助剤、
e) フルオロ界面活性剤、および
f) 水性液体、
床ケア組成物は、任意に亜鉛を含まず、配合後10日目に、ブルックフィールド LV粘度計で、1秒あたり1回転で#1スピンドルを使用して測定された動粘度が100cP未満である。 - 前記シラン含有ポリマーがさらに、ポリエン単量体単位を含む、請求項1記載の床ケア組成物。
- 永久的可塑剤の量が床ケア組成物の総固形分重量の1から5重量部である、請求項1記載の床ケア組成物。
- 前記ビニル芳香族単量体単位がスチレンに由来する単量体単位である、請求項1から3のいずれか1項記載の床ケア組成物。
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US201261590545P | 2012-01-25 | 2012-01-25 | |
US61/590,545 | 2012-01-25 |
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JP2018072092A Expired - Fee Related JP6768731B2 (ja) | 2012-01-25 | 2018-04-04 | シラン基含有ポリマー組成物およびそれを含むコーティング |
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EP (1) | EP2807223A4 (ja) |
JP (2) | JP2015506405A (ja) |
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-
2013
- 2013-01-24 EP EP13740766.4A patent/EP2807223A4/en not_active Withdrawn
- 2013-01-24 WO PCT/US2013/022888 patent/WO2013112683A2/en active Application Filing
- 2013-01-24 JP JP2014554816A patent/JP2015506405A/ja active Pending
- 2013-01-24 CN CN201380012345.2A patent/CN104144995A/zh active Pending
- 2013-01-24 CN CN201910825001.2A patent/CN110655871A/zh active Pending
- 2013-01-24 US US14/374,493 patent/US10259928B2/en active Active
-
2018
- 2018-04-04 JP JP2018072092A patent/JP6768731B2/ja not_active Expired - Fee Related
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Publication number | Publication date |
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WO2013112683A2 (en) | 2013-08-01 |
US10259928B2 (en) | 2019-04-16 |
CN104144995A (zh) | 2014-11-12 |
EP2807223A2 (en) | 2014-12-03 |
JP2018141157A (ja) | 2018-09-13 |
EP2807223A4 (en) | 2015-08-26 |
WO2013112683A3 (en) | 2013-10-03 |
CN110655871A (zh) | 2020-01-07 |
US20150018472A1 (en) | 2015-01-15 |
JP2015506405A (ja) | 2015-03-02 |
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