JP6717650B2 - 装飾部材の凹凸面に適用するための追従性粘着フィルム及びその製造方法 - Google Patents
装飾部材の凹凸面に適用するための追従性粘着フィルム及びその製造方法 Download PDFInfo
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- JP6717650B2 JP6717650B2 JP2016087230A JP2016087230A JP6717650B2 JP 6717650 B2 JP6717650 B2 JP 6717650B2 JP 2016087230 A JP2016087230 A JP 2016087230A JP 2016087230 A JP2016087230 A JP 2016087230A JP 6717650 B2 JP6717650 B2 JP 6717650B2
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- VFXXTYGQYWRHJP-UHFFFAOYSA-N 4,4'-azobis(4-cyanopentanoic acid) Chemical compound OC(=O)CCC(C)(C#N)N=NC(C)(CCC(O)=O)C#N VFXXTYGQYWRHJP-UHFFFAOYSA-N 0.000 description 1
- SXIFAEWFOJETOA-UHFFFAOYSA-N 4-hydroxy-butyl Chemical group [CH2]CCCO SXIFAEWFOJETOA-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
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- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- PQJYXFVJBSRUPG-UHFFFAOYSA-N [3-(2-methylaziridine-1-carbonyl)phenyl]-(2-methylaziridin-1-yl)methanone Chemical compound CC1CN1C(=O)C1=CC=CC(C(=O)N2C(C2)C)=C1 PQJYXFVJBSRUPG-UHFFFAOYSA-N 0.000 description 1
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
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- 239000006230 acetylene black Substances 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 239000002998 adhesive polymer Substances 0.000 description 1
- 238000007718 adhesive strength test Methods 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- ARCGXLSVLAOJQL-UHFFFAOYSA-N anhydrous trimellitic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 1
- YUENFNPLGJCNRB-UHFFFAOYSA-N anthracen-1-amine Chemical compound C1=CC=C2C=C3C(N)=CC=CC3=CC2=C1 YUENFNPLGJCNRB-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000006231 channel black Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
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- 239000004567 concrete Substances 0.000 description 1
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- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- 125000004985 dialkyl amino alkyl group Chemical group 0.000 description 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 1
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- 150000001993 dienes Chemical class 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- ZQMHJBXHRFJKOT-UHFFFAOYSA-N methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoate Chemical compound COC(=O)C(C)(C)N=NC(C)(C)C(=O)OC ZQMHJBXHRFJKOT-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- DFFZOPXDTCDZDP-UHFFFAOYSA-N naphthalene-1,5-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1C(O)=O DFFZOPXDTCDZDP-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 229920006287 phenoxy resin Polymers 0.000 description 1
- 239000013034 phenoxy resin Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000006234 thermal black Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 239000010981 turquoise Substances 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
装置:HP−1090 Series II(Hewlett−Packard社製)
溶媒:テトラヒドロフラン
カラム:Plgel MIXED−Bx2(300mm、外径7.5mm、内径5mm)
フローレート:1.0mL/min
検出手段:屈折率
サンプル濃度:0.1wt%
キャリブレーション標準:ポリスチレン
追従性粘着フィルムの特性を以下の方法に従って評価した。
コントロールタック(商標)フィルムIJ180−10(スリーエムジャパン株式会社製)上に、インクジェットプリンター(株式会社ミマキエンジニアリング製UJV500)でLUS200 UV硬化型インク(スリーエムジャパン株式会社製)を印刷し硬化させて、UV硬化型インクによる凹凸面を有する印刷物が形成された装飾部材の試料を作製した。印刷条件は、シアン67%、マゼンタ66%、イエロー66%、ブラック100%とした。装飾部材の凹凸面をハンディサーフ E−35A(株式会社東洋精密製)で測定した。カットオフ値は2.5mm、測定長さは12.5mm、測定領域は40μmとした。3回測定し、その測定値の平均値を代表値とした。その結果、装飾部材の凹凸面の大きさは、算術平均粗さ(Ra)で3.4μm、十点平均粗さ(Rz)で24.0μmであった。50mm角に切断した追従性粘着フィルムの試験片を、23℃の環境下で装飾部材の凹凸面にローラーで貼り付けた。試験片を23℃の環境下に放置し、貼り付け5分後、1時間後、24時間後のエア噛み割合を目視で評価した。エア噛み割合が、5%未満であれば「優良」、5%以上20%未満であれば「良」、20%以上50%未満であれば「悪」、50%以上であれば「劣悪」と評価した。図2の左側がエア噛み割合50%以上(劣悪)の実施態様(比較例1)を示す写真であり、右側がエア噛み割合5%未満(優良)の実施態様(例3)を示す写真である。
エア噛み評価試験と同様の手順で凹凸面を有する装飾部材の試料を準備した。50mm角に切断した追従性粘着フィルムの試験片を、23℃の環境下で装飾部材の凹凸面にローラーで貼り付けた。試験片を23℃の環境下に放置し、貼り付け5分後、1時間後、24時間後のL*値(明度)を分光計CM−3700d(コニカミノルタ株式会社製)で測定した。
50mm角に切断した追従性粘着フィルムの試験片を、23℃の環境下でアルミ板上にローラーで貼り付けた。アルミ板を備える試験片を23℃の環境下に24時間放置した。24時間放置後の試験片にカッターで十字に切り込みを入れ、65℃のオーブンに24時間放置した。オーブンからアルミ板を備える試験片を取り出し、マイクロメーターで試験片の収縮を測定した。試験片の収縮が0.30mm以下の場合は「優良」、0.30mmを超えて0.50mm以下の場合は「良」、0.50mmを超えた場合、試験片の周囲に粘着剤を残して試験片の収縮が確認された場合は「不良」と判断した。なお、アルミ板に貼り付ける前に剥離紙上で試験片の収縮が生じた場合も「不良」と判断した。
追従性粘着フィルムの試験片を長さ150mm、幅25mmに切断した。JIS Z 0237 8.2.3.に従い、試験片をメラミン焼き付け塗装板(株式会社パルテック製)に20℃の環境下で貼り付けた。試験片を20℃環境下に5分間、及び48時間放置した。20℃の環境下でテンシロン引っ張り試験機(株式会社オリエンテック製)により180度接着力を測定した。掴み間隔は100mm、剥離速さは300mm/分とした。
<例1>
熱架橋型粘着剤ADH1及び架橋剤CL1からなる熱架橋型粘着剤溶液を準備した。熱架橋型粘着剤ADH1及び架橋剤CL1の質量比は固形分換算で100:0.12であった。得られた熱架橋型粘着剤溶液を両面ポリエチレンラミネート剥離紙のシリコーン処理面上にナイフコータで塗布して未架橋の粘着剤層を形成した。この粘着剤層を95℃で5分間加熱乾燥して31μm厚の架橋した粘着剤層を得た。50μm厚の透明なポリ塩化ビニル系フィルムに架橋した粘着剤層を貼り合わせて、追従性粘着フィルムの試験片を作製した。
CL1の添加量を0.15質量部に変更したこと、及び架橋後の粘着剤層の厚さを30μmとしたことを除き、例1と同様にして追従性粘着フィルムの試験片を作製した。
例1で得られた熱架橋型粘着剤溶液を50μm厚の透明なポリ塩化ビニル系フィルム上にナイフコータで塗布して未架橋の粘着剤層を形成した。この粘着剤層を95℃で5分間加熱乾燥して32m厚の架橋した粘着剤層を得た。両面ポリエチレンラミネート剥離紙のシリコーン処理面に架橋した粘着剤層を貼り合わせて、追従性粘着フィルムの試験片を作製した。
CL1の添加量を0.15質量部に変更したこと、及び架橋後の粘着剤層の厚さを31μmとしたことを除き、例3と同様にして追従性粘着フィルムの試験片を作製した。
例5から例16は、熱架橋型粘着剤及び架橋剤の種類、架橋剤の添加量、並びに架橋後の粘着剤層の厚さを表4に記載されるとおりにしたことを除き、例1と同様にして追従性粘着フィルムの試験片を作製した。
比較例1から比較例7は、熱架橋型粘着剤及び架橋剤の種類、架橋剤の添加量、並びに架橋後の粘着剤層の厚さを表4に記載されるとおりにしたことを除き、例1と同様にして追従性粘着フィルムの試験片を作製した。
110 装飾部材
120 凹凸面
130 粘着剤層
140 追従性基材
150 追従性粘着フィルム
本開示の実施態様の一部を以下の[項目1]−[項目10]に記載する。
[項目1]
追従性基材と、粘着剤層とを含む、装飾部材の凹凸面に適用するための追従性粘着フィルムであって、
前記粘着剤層は、30万以下の重量平均分子量(Mw)を有する熱架橋型粘着剤、並びにエポキシ系架橋剤及び又はビスアミド系架橋剤を前記熱架橋型粘着剤100質量部に対して0.5質量部以下含む組成物を架橋させた層であり、前記装飾部材の凹凸面に前記追従性粘着フィルムの粘着剤層を適用した場合に、該追従性粘着フィルムにおける1時間後のエア噛み割合が20%未満である、追従性粘着フィルム。
[項目2]
前記装飾部材の凹凸面が、十点平均粗さ(Rz)で5μm以上を有する、項目1記載の追従性粘着フィルム。
[項目3]
前記粘着剤層は、前記装飾部材の凹凸面の平均粗さ(Rz)より厚い、項目1又は2記載の追従性粘着フィルム。
[項目4]
前記粘着剤層は、10μm〜50μmの厚みを有する、項目1〜3のいずれか一項に記載の追従性粘着フィルム。
[項目5]
前記熱架橋型粘着剤のガラス転移温度が、−80℃以上、−5℃以下である、項目1〜4のいずれか一項に記載の追従性粘着フィルム。
[項目6]
前記熱架橋型粘着剤が(メタ)アクリル系ポリマーを含む、項目1〜5のいずれか一項に記載の追従性粘着フィルム。
[項目7]
前記装飾部材の凹凸面の凹凸が、紫外線硬化型インクを用いたインクジェット印刷物である、項目1〜6のいずれか一項に記載の追従性粘着フィルム。
[項目8]
前記追従性基材が、ポリ塩化ビニル樹脂、ポリウレタン樹脂、ポリオレフィン樹脂、(メタ)アクリル樹脂、ポリエステル樹脂及びフッ素樹脂からなる群より選択される少なくとも1つの樹脂を含む、項目1〜7のいずれか一項に記載の追従性粘着フィルム。
[項目9]
粘着フィルムの製造方法であって、
追従性基材を提供する工程と、
固形分50%以上の溶剤系粘着剤組成物を提供する工程であって、該溶剤系粘着剤組成物が、30万以下の重量平均分子量(Mw)を有する熱架橋型粘着剤、並びにエポキシ系架橋剤及び又はビスアミド系架橋剤を前記熱架橋型粘着剤100質量部に対して0.5質量部以下含む、工程と、
前記粘着剤組成物を架橋する工程と、
前記粘着剤組成物を架橋する前または架橋後に前記追従性基材上に適用する工程と、を有する、粘着フィルムの製造方法。
[項目10]
固形分50%以上の溶剤系粘着剤組成物であって、該溶剤系粘着剤組成物が、30万以下の重量平均分子量(Mw)を有する熱架橋型粘着剤、並びにエポキシ系架橋剤及び又はビスアミド系架橋剤を前記熱架橋型粘着剤100質量部に対して0.5質量部以下含む、溶剤系粘着剤組成物。
Claims (10)
- 追従性基材と、粘着剤層とを含む、装飾部材の凹凸面に適用するための追従性粘着フィルムであって、
前記粘着剤層は、30万未満の重量平均分子量(Mw)を有する熱架橋型粘着剤、並びにエポキシ系架橋剤及び又はビスアミド系架橋剤を前記熱架橋型粘着剤100質量部に対して0.5質量部以下含む組成物を架橋させた層である、追従性粘着フィルム。 - 前記装飾部材の凹凸面が、十点平均粗さ(Rz)で5μm以上を有する、請求項1記載の追従性粘着フィルム。
- 前記粘着剤層は、前記装飾部材の凹凸面の平均粗さ(Rz)より厚い、請求項1又は2記載の追従性粘着フィルム。
- 前記粘着剤層は、10μm〜50μmの厚みを有する、請求項1〜3のいずれか一項に記載の追従性粘着フィルム。
- 前記熱架橋型粘着剤のガラス転移温度が、−80℃以上、−5℃以下である、請求項1〜4のいずれか一項に記載の追従性粘着フィルム。
- 前記熱架橋型粘着剤が(メタ)アクリル系ポリマーを含む、請求項1〜5のいずれか一項に記載の追従性粘着フィルム。
- 前記装飾部材の凹凸面の凹凸が、紫外線硬化型インクを用いたインクジェット印刷物である、請求項1〜6のいずれか一項に記載の追従性粘着フィルム。
- 前記追従性基材が、ポリ塩化ビニル樹脂、ポリウレタン樹脂、ポリオレフィン樹脂、(メタ)アクリル樹脂、ポリエステル樹脂及びフッ素樹脂からなる群より選択される少なくとも1つの樹脂を含む、請求項1〜7のいずれか一項に記載の追従性粘着フィルム。
- 粘着フィルムの製造方法であって、
追従性基材を提供する工程と、
固形分50%以上の溶剤系粘着剤組成物を提供する工程であって、該溶剤系粘着剤組成物が、30万未満の重量平均分子量(Mw)を有する熱架橋型粘着剤、並びにエポキシ系架橋剤及び又はビスアミド系架橋剤を前記熱架橋型粘着剤100質量部に対して0.5質量部以下含む、工程と、
前記粘着剤組成物を架橋する工程と、
前記粘着剤組成物を架橋する前または架橋後に前記追従性基材上に適用する工程と、を有する、粘着フィルムの製造方法。 - 固形分50%以上の溶剤系粘着剤組成物であって、該溶剤系粘着剤組成物が、30万未満の重量平均分子量(Mw)を有する熱架橋型粘着剤、並びにエポキシ系架橋剤及び又はビスアミド系架橋剤を前記熱架橋型粘着剤100質量部に対して0.5質量部以下含む、溶剤系粘着剤組成物。
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