JP6702974B2 - 光学活性カルボニル化合物を合成する方法 - Google Patents
光学活性カルボニル化合物を合成する方法 Download PDFInfo
- Publication number
- JP6702974B2 JP6702974B2 JP2017532651A JP2017532651A JP6702974B2 JP 6702974 B2 JP6702974 B2 JP 6702974B2 JP 2017532651 A JP2017532651 A JP 2017532651A JP 2017532651 A JP2017532651 A JP 2017532651A JP 6702974 B2 JP6702974 B2 JP 6702974B2
- Authority
- JP
- Japan
- Prior art keywords
- formula
- group
- alkyl
- compound
- cycloalkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
- C07C29/172—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with the obtention of a fully saturated alcohol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/56—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by isomerisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14199410 | 2014-12-19 | ||
| EP14199410.3 | 2014-12-19 | ||
| PCT/EP2015/080392 WO2016097242A1 (de) | 2014-12-19 | 2015-12-18 | Verfahren zur herstellung optisch aktiver carbonylverbindungen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2017537965A JP2017537965A (ja) | 2017-12-21 |
| JP2017537965A5 JP2017537965A5 (enExample) | 2019-02-07 |
| JP6702974B2 true JP6702974B2 (ja) | 2020-06-03 |
Family
ID=52231936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017532651A Active JP6702974B2 (ja) | 2014-12-19 | 2015-12-18 | 光学活性カルボニル化合物を合成する方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (3) | US9975837B2 (enExample) |
| EP (2) | EP3233778B1 (enExample) |
| JP (1) | JP6702974B2 (enExample) |
| CN (1) | CN107250091B (enExample) |
| ES (2) | ES2883557T3 (enExample) |
| MX (1) | MX375969B (enExample) |
| WO (1) | WO2016097242A1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016177814A1 (en) | 2015-05-04 | 2016-11-10 | Basf Se | Process for the preparation of melonal |
| JP2018533564A (ja) | 2015-10-12 | 2018-11-15 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 1,6−二置換ヘキサン誘導体を製造するためのヒドロホルミル化法 |
| PL3386919T3 (pl) | 2015-12-08 | 2022-02-21 | Basf Se | Zawierający cynę materiał zeolitowy o strukturze szkieletowej bea |
| ES2844182T3 (es) | 2016-06-07 | 2021-07-21 | Basf Se | Procedimiento para la preparación de alcoholes con insaturación en posición 2,3 |
| JP7039498B2 (ja) | 2016-06-29 | 2022-03-22 | ビーエーエスエフ ソシエタス・ヨーロピア | 液相の存在下でのアルコールの酸化によるアルファ,ベータ不飽和アルデヒドの製造方法 |
| EP3523267B1 (de) | 2016-10-06 | 2020-12-09 | Basf Se | Verfahren zur anreicherung von enantiomeren aus einem enantiomerengemisch |
| JP2021506870A (ja) * | 2017-12-21 | 2021-02-22 | ビーエイエスエフ・ソシエタス・エウロパエアBasf Se | 液相の存在下でのアルコールの酸化によるα,β不飽和アルデヒドの製造方法 |
| MY205693A (en) * | 2018-09-05 | 2024-11-07 | Basf Se | Reactor for carrying out a gas-liquid two-phase high-pressure reaction with a foaming medium |
| EP3846927B1 (de) | 2018-09-05 | 2022-11-23 | Basf Se | Reaktor zur durchführung einer reaktion zwischen zwei nicht mischbaren fluiden unterschiedlicher dichte |
| MX2021002670A (es) * | 2018-09-05 | 2021-05-12 | Basf Se | Preparacion continua de un compuesto de carbonilo opticamente activo mediante hidrogenacion asimetrica. |
| CN112770834B (zh) * | 2018-09-05 | 2023-07-21 | 巴斯夫欧洲公司 | 进行气/液两相高压反应的方法 |
| WO2020239721A1 (en) * | 2019-05-27 | 2020-12-03 | Dsm Ip Assets B.V. | Selective hydrogenation of alkynes to alkenes in the presence of a phosphorus compound and an organic sulphur compound |
| CN111056932A (zh) * | 2019-12-09 | 2020-04-24 | 万华化学集团股份有限公司 | 一种制备光学活性香茅醛的方法 |
| US12202792B2 (en) | 2019-12-09 | 2025-01-21 | Wanhua Chemical Group Co., Ltd. | Preparation method for optically active citronellal |
| CN110872217A (zh) * | 2019-12-09 | 2020-03-10 | 万华化学集团股份有限公司 | 一种光学活性的香茅醛的制备方法 |
| CN111004102B (zh) * | 2019-12-23 | 2022-11-04 | 万华化学集团股份有限公司 | 一种制备光学活性香茅醛的方法及用于该方法的催化剂 |
| CN111056933B (zh) * | 2019-12-24 | 2022-11-08 | 万华化学集团股份有限公司 | 一种制备光学活性香茅醛的方法及用于该方法的催化剂体系 |
| CN111792986B (zh) * | 2020-07-22 | 2022-09-20 | 万华化学集团股份有限公司 | 一种制备r-香茅醛的方法 |
| CN112142583B (zh) * | 2020-10-26 | 2022-07-26 | 万华化学集团股份有限公司 | 一种香叶醛制备橙花醛的方法 |
| CN113527367B (zh) * | 2021-07-14 | 2022-08-02 | 南开沧州渤海新区绿色化工研究有限公司 | 一种含四(3,5-二三氟甲基苯基)硼阴离子的手性双膦配体铑络合物和制备方法及应用 |
| WO2025011972A1 (en) | 2023-07-07 | 2025-01-16 | Basf Se | Photoisomerization of geranial and neral |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4115417A (en) * | 1975-10-16 | 1978-09-19 | Hoffmann-La Roche Inc. | Asymmetric hydrogenation catalyzed by rhodium complexes of chiral tertiary phosphines |
| JPS5278812A (en) | 1975-12-26 | 1977-07-02 | Nikki Chem Co Ltd | Selective production method of saturated aldehyde |
| FR2396735A1 (fr) * | 1977-07-04 | 1979-02-02 | Rhone Poulenc Ind | Procede de preparation de citronellal optiquement actif |
| DE19854637A1 (de) | 1998-11-26 | 2000-05-31 | Basf Ag | Reaktor zur kontinuierlichen Durchführung von Gas-Flüssig-, Flüssig-Flüssig- oder Gas-Flüssig-Fest-Reaktionen |
| JP4676617B2 (ja) | 2001-01-18 | 2011-04-27 | 高砂香料工業株式会社 | イソプレゴールの製造方法 |
| DE102004049631A1 (de) | 2004-10-11 | 2006-04-20 | Basf Ag | Verfahren zur Herstellung optisch aktiver Carbonylverbindungen |
| DE102004057277A1 (de) | 2004-11-26 | 2006-06-01 | Basf Ag | Verfahren zur Herstellung von Menthol |
| US7973198B2 (en) | 2007-04-25 | 2011-07-05 | Basf Se | Method for synthesizing optically active carbonyl compounds |
| PE20091364A1 (es) * | 2008-01-17 | 2009-10-13 | Novartis Ag | Proceso para la preparacion de inhibidores de nep |
| JP5711209B2 (ja) * | 2010-03-04 | 2015-04-30 | 高砂香料工業株式会社 | 均一系不斉水素化触媒 |
-
2015
- 2015-12-18 US US15/536,524 patent/US9975837B2/en active Active
- 2015-12-18 CN CN201580076501.0A patent/CN107250091B/zh active Active
- 2015-12-18 ES ES18206833T patent/ES2883557T3/es active Active
- 2015-12-18 EP EP15817247.8A patent/EP3233778B1/de active Active
- 2015-12-18 EP EP18206833.8A patent/EP3489213B1/de active Active
- 2015-12-18 JP JP2017532651A patent/JP6702974B2/ja active Active
- 2015-12-18 ES ES15817247T patent/ES2727384T3/es active Active
- 2015-12-18 MX MX2017008170A patent/MX375969B/es active IP Right Grant
- 2015-12-18 WO PCT/EP2015/080392 patent/WO2016097242A1/de not_active Ceased
-
2018
- 2018-04-27 US US15/964,400 patent/US10301244B2/en not_active Ceased
-
2019
- 2019-07-25 US US16/521,935 patent/USRE49036E1/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2017537965A (ja) | 2017-12-21 |
| CN107250091A (zh) | 2017-10-13 |
| MX2017008170A (es) | 2017-09-18 |
| US9975837B2 (en) | 2018-05-22 |
| EP3233778A1 (de) | 2017-10-25 |
| US20180057437A1 (en) | 2018-03-01 |
| MX375969B (es) | 2025-03-06 |
| EP3489213B1 (de) | 2021-04-28 |
| USRE49036E1 (en) | 2022-04-19 |
| EP3489213A1 (de) | 2019-05-29 |
| WO2016097242A1 (de) | 2016-06-23 |
| ES2883557T3 (es) | 2021-12-09 |
| ES2727384T3 (es) | 2019-10-15 |
| CN107250091B (zh) | 2021-05-04 |
| EP3233778B1 (de) | 2019-02-20 |
| US10301244B2 (en) | 2019-05-28 |
| US20180244598A1 (en) | 2018-08-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6702974B2 (ja) | 光学活性カルボニル化合物を合成する方法 | |
| Steinlandt et al. | Metal stereogenicity in asymmetric transition metal catalysis | |
| JP5128282B2 (ja) | 光学活性カルボニル化合物の製造方法 | |
| Brunner | Enantioselective synthesis of organic compounds with optically active transition metal catalysts in substoichiometric quantities | |
| US7973198B2 (en) | Method for synthesizing optically active carbonyl compounds | |
| Breit | Recent advances in alkene hydroformylation | |
| CN119212972A (zh) | 用于二烯酮的选择性催化氢化的方法 | |
| Nindakova et al. | Enantioselective Hydrogenation over Chiral Cobalt Complexes with (+)-(1 S, 2 S, 5 R)-Neomenthyldiphenylphosphine and (-)-(R, R)-2, 2-Dimethyl-4, 5-bis (diphenylphosphinomethyl)-1, 3-dioxolane | |
| WO2025191084A1 (en) | Rhodium-carbonyl compounds for use as selective hydrogenation catalysts | |
| WO2022072182A1 (en) | Processes of preparing ferrocene ligand mixtures suitable for propylene hydroformylation | |
| CN120187735A (zh) | 具有手性双齿双膦配体的铁羰基络合物 | |
| Nindakova et al. | New C 2-symmetric optically active salen ligands and their cobalt (II) complexes. Hydridoborate reduction of prochiral C= O and C= C bonds | |
| JP7439055B2 (ja) | 不斉水素化による光学活性カルボニル化合物の連続的調製 | |
| Calow et al. | Rhodium (I)‐Catalyzed Reductive Carbon–Carbon Bond Formation | |
| CN118660869A (zh) | 醇的制造方法 | |
| Parker | Organometallic chemistry. Part (i) The transition elements | |
| Beltrani | Oxidative Carbonylation of Unsaturated Substrates Promoted by Aryl [Alfa]-Diimine Pd (II) Complexes |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20181218 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20181218 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20190912 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20191008 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20200107 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20200128 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20200305 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20200407 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20200507 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6702974 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |