JP6687185B2 - フレキシブルプラスチックフィルム - Google Patents
フレキシブルプラスチックフィルム Download PDFInfo
- Publication number
- JP6687185B2 JP6687185B2 JP2018191313A JP2018191313A JP6687185B2 JP 6687185 B2 JP6687185 B2 JP 6687185B2 JP 2018191313 A JP2018191313 A JP 2018191313A JP 2018191313 A JP2018191313 A JP 2018191313A JP 6687185 B2 JP6687185 B2 JP 6687185B2
- Authority
- JP
- Japan
- Prior art keywords
- plastic film
- flexible plastic
- inorganic fine
- coating layer
- film according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002985 plastic film Substances 0.000 title claims description 56
- 229920002457 flexible plastic Polymers 0.000 title claims description 51
- 239000011247 coating layer Substances 0.000 claims description 78
- 239000010419 fine particle Substances 0.000 claims description 51
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 48
- 239000011230 binding agent Substances 0.000 claims description 44
- 239000000758 substrate Substances 0.000 claims description 40
- 239000010410 layer Substances 0.000 claims description 28
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 21
- -1 Polyethylene terephthalate Polymers 0.000 claims description 14
- 238000009826 distribution Methods 0.000 claims description 14
- 239000004642 Polyimide Substances 0.000 claims description 13
- 229920001721 polyimide Polymers 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 7
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 7
- 239000004697 Polyetherimide Substances 0.000 claims description 5
- 229920001601 polyetherimide Polymers 0.000 claims description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 4
- 230000002902 bimodal effect Effects 0.000 claims description 4
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 239000011112 polyethylene naphthalate Substances 0.000 claims description 4
- 229910000077 silane Inorganic materials 0.000 claims description 4
- 238000002834 transmittance Methods 0.000 claims description 4
- 229920002284 Cellulose triacetate Polymers 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 claims description 3
- NLSFWPFWEPGCJJ-UHFFFAOYSA-N 2-methylprop-2-enoyloxysilicon Chemical compound CC(=C)C(=O)O[Si] NLSFWPFWEPGCJJ-UHFFFAOYSA-N 0.000 claims description 2
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical compound S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 claims description 2
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims 2
- 241001307210 Pene Species 0.000 claims 1
- 229920002873 Polyethylenimine Polymers 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 239000007822 coupling agent Substances 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 150000004756 silanes Chemical class 0.000 claims 1
- YNDXUCZADRHECN-JNQJZLCISA-N triamcinolone acetonide Chemical compound C1CC2=CC(=O)C=C[C@]2(C)[C@]2(F)[C@@H]1[C@@H]1C[C@H]3OC(C)(C)O[C@@]3(C(=O)CO)[C@@]1(C)C[C@@H]2O YNDXUCZADRHECN-JNQJZLCISA-N 0.000 claims 1
- 239000010408 film Substances 0.000 description 78
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 48
- 239000008199 coating composition Substances 0.000 description 21
- 230000000704 physical effect Effects 0.000 description 18
- 238000005452 bending Methods 0.000 description 17
- 239000006185 dispersion Substances 0.000 description 16
- 239000000463 material Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- 238000005259 measurement Methods 0.000 description 7
- 239000000088 plastic resin Substances 0.000 description 7
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 6
- 239000006087 Silane Coupling Agent Substances 0.000 description 6
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical group C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 229920006255 plastic film Polymers 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 238000001723 curing Methods 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 230000001186 cumulative effect Effects 0.000 description 4
- 238000000016 photochemical curing Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- MWGMEGAYPPQWFG-UHFFFAOYSA-N [SiH4].OC(=O)C=C Chemical compound [SiH4].OC(=O)C=C MWGMEGAYPPQWFG-UHFFFAOYSA-N 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 238000013112 stability test Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 2
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 2
- FDSUVTROAWLVJA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)COCC(CO)(CO)CO FDSUVTROAWLVJA-UHFFFAOYSA-N 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- LWRBVKNFOYUCNP-UHFFFAOYSA-N 2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ylpropan-1-one Chemical compound C1=CC(SC)=CC=C1C(=O)C(C)(C)N1CCOCC1 LWRBVKNFOYUCNP-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000012963 UV stabilizer Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000005456 alcohol based solvent Substances 0.000 description 2
- 238000007611 bar coating method Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000013039 cover film Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000002050 diffraction method Methods 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 239000010954 inorganic particle Substances 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- RQAGEUFKLGHJPA-UHFFFAOYSA-N prop-2-enoylsilicon Chemical compound [Si]C(=O)C=C RQAGEUFKLGHJPA-UHFFFAOYSA-N 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- YAXWOADCWUUUNX-UHFFFAOYSA-N 1,2,2,3-tetramethylpiperidine Chemical compound CC1CCCN(C)C1(C)C YAXWOADCWUUUNX-UHFFFAOYSA-N 0.000 description 1
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 1
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- DHMBUENCUGKPAD-UHFFFAOYSA-N 2-(dimethylamino)-2-ethyl-1-(4-morpholin-4-ylphenyl)-3-phenylpropane-1,3-dione Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(N(C)C)(CC)C(=O)C1=CC=CC=C1 DHMBUENCUGKPAD-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- OADIZUFHUPTFAG-UHFFFAOYSA-N 2-[2-(2-ethylhexoxy)ethoxy]ethanol Chemical compound CCCCC(CC)COCCOCCO OADIZUFHUPTFAG-UHFFFAOYSA-N 0.000 description 1
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 229940093475 2-ethoxyethanol Drugs 0.000 description 1
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 1
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 description 1
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 1
- LDMRLRNXHLPZJN-UHFFFAOYSA-N 3-propoxypropan-1-ol Chemical compound CCCOCCCO LDMRLRNXHLPZJN-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- AHGFXGSMYLFWEC-UHFFFAOYSA-N [SiH4].CC(=C)C(O)=O Chemical compound [SiH4].CC(=C)C(O)=O AHGFXGSMYLFWEC-UHFFFAOYSA-N 0.000 description 1
- GUCYFKSBFREPBC-UHFFFAOYSA-N [phenyl-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C(=O)C1=C(C)C=C(C)C=C1C GUCYFKSBFREPBC-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- UGZICOVULPINFH-UHFFFAOYSA-N acetic acid;butanoic acid Chemical compound CC(O)=O.CCCC(O)=O UGZICOVULPINFH-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229920005822 acrylic binder Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007607 die coating method Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- GYIQEXBTYUXXHZ-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone;2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ylpropan-1-one Chemical compound C1=CC(SC)=CC=C1C(=O)C(C)(C)N1CCOCC1.CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 GYIQEXBTYUXXHZ-UHFFFAOYSA-N 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000002296 dynamic light scattering Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- YLHXLHGIAMFFBU-UHFFFAOYSA-N methyl phenylglyoxalate Chemical compound COC(=O)C(=O)C1=CC=CC=C1 YLHXLHGIAMFFBU-UHFFFAOYSA-N 0.000 description 1
- 238000010295 mobile communication Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000007764 slot die coating Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000005341 toughened glass Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Description
支持基材;および前記支持基材の少なくとも一面に形成される紫外線硬化型コーティング層を含むフィルムであって、
750gの荷重で6H以上の鉛筆硬度を示し、
前記フィルムの中間に4mmの間隔をおいてフィルムの両側を底面に対して90度に折り畳んだ状態で常温で放置した後、平らな底面に広げた時、フィルムが底面から持ち上げられた高さが0.5mm以下である、フレキシブル(flexible)プラスチックフィルムを提供する。
3官能のアクリレート系バインダーのトリメチロールプロパントリアクリレート(TMPTA)(製造会社:Cytec、Mw=296g/mol、アクリレート基当量=99g/mol)30g、9官能のウレタンアクリレート系バインダーのMU9800(製造会社:MIWON、Mw=3500g/mol、アクリレート基当量=389g/mol)40g、10官能のウレタンアクリレート系バインダーのMU9020(製造会社:MIWON、Mw=4500g/mol、アクリレート基当量=450g/mol)30g、光開始剤Irgacure184(製造会社:Ciba)1g、メチルエチルケトン(MEK)15gを混合して、アクリレート溶液を製造した。
実施例1において、S2分散溶液を83.3gとし、別途のメチルエチルケトン溶媒を含まないことを除けば、実施例1と同様の方法でコーティング層を形成した。
実施例1において、メチルエチルケトンを25gとし、S2分散溶液50gの代わりに、シリカ粒子S3(d10=108nm、d50=119nm、d90=131nmであり、アクリレートシランカップリング剤で表面改質される)がMEKに40重量%分散している溶液(以下、S3分散溶液)37.5gを混合して、コーティング組成物を製造した。
TMPTA(製造会社:Cytec、Mw=296g/mol、アクリレート基当量=99g/mol)20g、MU9800(製造会社:MIWON、Mw=3500g/mol、アクリレート基当量=389g/mol)40g、MU9020(製造会社:MIWON、Mw=4500g/mol、アクリレート基当量=450g/mol)40g、光開始剤Irgacure184(製造会社:Ciba)1g、メチルエチルケトン(MEK)12gを混合して、アクリレート溶液を製造した。
ASTM D882により測定した弾性モジュラス値が4.2GPaのポリイミド基材(大きさ:20cmx30cm、厚さ:35μm)を用いたことを除けば、残りの工程は実施例1と同様にしてコーティング層を形成した。
ASTM D882により測定した弾性モジュラス値が7.6GPaのポリイミド基材(大きさ:20cmx30cm、厚さ:35μm)を用いたことを除けば、残りの工程は実施例1と同様にしてコーティング層を形成した。
TMPTA(製造会社:Cytec、Mw=296g/mol、アクリレート基当量=99g/mol)30g、MU9020(製造会社:MIWON、Mw=4500g/mol、アクリレート基当量=450g/mol)30g、15官能のウレタンアクリレート系バインダーのSC2152(製造会社:MIWON、Mw=20,000g/mol、アクリレート基当量=1,333g/mol)40g、光開始剤Irgacure184(製造会社:Ciba)1g、メチルエチルケトン(MEK)42gを混合して、アクリレート溶液を製造した。
AZO粒子分散液CX−610M(製造会社:Nissan、固形分60%)20g、ジペンタエリスリトールペンタクリレート(DPHA)10g、光開始剤Irgacure184(製造会社:Ciba)0.5g、エタノール100gを混合して、帯電防止層組成物を製造した。
まず、実施例1と同様の過程でポリイミド基材の両面にコーティング層を形成した。
実施例1において、メチルエチルケトンを55gとし、コーティング組成物にシリカ粒子を含まないことを除けば、実施例1と同様にしてコーティング層を形成した。
実施例1において、メチルエチルケトンを12gとし、シリカ粒子S4(d10=12nm、d50=17nm、d90=21nmであり、アクリレートシランカップリング剤で表面改質される)がMEKに40重量%分散している溶液(以下、S4分散溶液)のみを112.5g用いたことを除けば、実施例1と同様にしてコーティング層を形成した。
実施例1において、メチルエチルケトンを35gとし、S1分散溶液のみを110g含むことを除けば、実施例1と同様にしてコーティング層を形成した。
実施例1において、S3分散溶液を125g、S4分散溶液を25g用い、別途のメチルエチルケトン溶媒を含まないことを除けば、実施例1と同様の方法でコーティング層を形成した。
ASTM D882により測定した弾性モジュラス値が3.1GPaのポリイミド基材(大きさ:20cmx30cm、厚さ:35μm)を用いたことを除けば、残りの工程は実施例1と同様にしてコーティング層を形成した。
ASTM D882により測定した弾性モジュラス値が4.2GPaのポリエチレンテレフタレート基材(大きさ:20cmx30cm、厚さ:250μm)を用いたことを除けば、残りの工程は実施例1と同様にしてコーティング層を形成した。
比較例3において、MU9800とMU9020を用いず、6官能のポリエステルアクリレート系バインダーのPS610(製造会社:MIWON、Mw=5,400g/mol、アクリレート基当量=900g/mol)70gを用いたことを除けば、残りの工程は比較例3と同様にしてコーティング層を形成した。
鉛筆硬度測定器を用いて、測定標準JIS K5400−5−4により750gの荷重、45度の角度で3回往復した後、キズのない最大硬度を確認した。
分光光度計(機器名:COH−400)を用いて、透過率およびヘイズを測定した。
測定標準JIS K5600−5−1の方法により各フィルムを多様な直径の円筒形マンドレルに挟んで巻いた後、長さ3mm以上のクラックが発生しない最小直径を測定した。
図1は、本発明の一実施例によるフィルムに対して、曲げ安定性テストを実施する方法を概略的に示す図である。
Claims (15)
- 支持基材;
および前記支持基材の少なくとも一面に形成される紫外線硬化型コーティング層を含むフィルムであって、
750gの荷重で6H以上の鉛筆硬度を示し、
前記フィルムの中間に4mmの間隔をおいてフィルムの両側を底面に対して90度に折り畳んだ状態で常温で放置した後、平らな底面に広げた時、フィルムが底面から持ち上げられた高さが0.5mm以下であり、
前記折り畳んだ屈曲部の形状は円筒型であって、
前記支持基材およびコーティング層の厚さ比は、1:0.05〜約1:1であり、
前記支持基材は、ASTM D882により測定した時、4〜9GPaの弾性モジュラスを有し、
前記紫外線硬化型コーティング層は、アクリレート系バインダーおよびバイモーダル(bi−modal)粒子分布を有する無機微粒子を含む、
フレキシブル(flexible)プラスチックフィルム。 - 前記紫外線硬化型コーティング層は、3〜6官能性アクリレート系バインダーと7〜20官能性ウレタンアクリレート系バインダーとの架橋共重合体を含む、
請求項1に記載のフレキシブルプラスチックフィルム。 - 前記無機微粒子は、
d 50 が20〜35nmの第1無機微粒子群および
d 50 が40〜130nmの第2無機微粒子群を含むことで
前記バイモーダル(bi−modal)粒子分布を有するものである、
請求項1に記載のフレキシブルプラスチックフィルム。 - 前記支持基材の厚さは、
20〜200μmである、
請求項1から3のいずれか一項に記載のフレキシブルプラスチックフィルム。 - 前記紫外線硬化型コーティング層の厚さは、
3〜20μmである、
請求項1から4のいずれか1項に記載のフレキシブルプラスチックフィルム。 - 前記紫外線硬化型コーティング層は、
3〜6官能性アクリレート系バインダーと7〜20官能性ウレタンアクリレート系バインダーとの架橋共重合体;
並びにd50が20〜35nmの第1無機微粒子群および
d50が40〜130nmの第2無機微粒子群を含むことで
バイモーダル(bi−modal)粒子分布を有する
無機微粒子を含む、
請求項1から5のいずれか1項に記載のフレキシブルプラスチックフィルム。 - 前記3〜6官能性アクリレート系バインダーおよび
7〜20官能性ウレタンアクリレート系バインダーの重量比は、
1:9〜4:6である、
請求項6に記載のフレキシブルプラスチックフィルム。 - 前記紫外線硬化型コーティング層100重量部に対して、
前記3〜6官能性アクリレート系バインダーを10〜50重量部、
前記7〜20官能性ウレタンアクリレート系バインダーを40〜70重量部、
前記第1無機微粒子群を5〜50重量部、
前記第2無機微粒子群を5〜50重量部含む、
請求項6または7に記載のフレキシブルプラスチックフィルム。 - 前記第1無機微粒子群および第2無機微粒子群は、
それぞれ独立に、同一または異なって、
(メタ)アクリルシラン((meth)acrylsilane)、メタクロキシシラン(methacroxysilane)、ビニルシラン(vinylsilane)、エポキシシラン(epoxysilane)、およびメルカプトシラン(mercaptosilane)からなる群より選択されるいずれか1つ以上のシランカップリング剤で表面が改質処理されたものである、
請求項6から8のいずれか1項に記載のフレキシブルプラスチックフィルム。 - 前記第1無機微粒子群のd10は、10〜19nmであり、
d90は、25〜40nmであり、
前記第2無機微粒子群のd10は、25〜110nmであり、
d90は、60〜150nmである、
請求項6から9のいずれか1項に記載のフレキシブルプラスチックフィルム。 - 前記第1無機微粒子群および第2無機微粒子群の重量比は、
9:1〜3:7である、
請求項6から10のいずれか1項に記載のフレキシブルプラスチックフィルム。 - 前記支持基材は、
ポリイミド(polyimide、PI)、ポリイミドアミド(polyimideamide)、ポリエーテルイミド(polyetherimide、PEI)、ポリエチレンテレフタレート(polyethyleneterephtalate、PET)、ポリエチレンナフタレート(polyethylenenaphthalate、PEN)、ポリエーテルエーテルケトン(polyetheretherketon、PEEK)、サイクリックオレフィン重合体(cyclic olefin polymer、COP)、ポリアクリレート(polyacrylate、PAC)、ポリメチルメタクリレート(polymethylmethacrylate、PMMA)、およびトリアセチルセルロース(triacetylcellulose、TAC)からなる群より選択される1種以上である、
請求項1から11のいずれか1項に記載のフレキシブルプラスチックフィルム。 - 前記紫外線硬化型コーティング層の上面または下面に帯電防止層または低屈折率層をさらに含む、
請求項1から12のいずれか1項に記載のフレキシブルプラスチックフィルム。 - 直径4mmのマンドレル(mandrel)に巻いた時、
クラック(crack)が発生しない、
請求項1から13のいずれか1項に記載のフレキシブルプラスチックフィルム。 - 前記フレキシブルプラスチックフィルムは、88.0%以上の光透過率および1.5%以下のヘイズを有する、請求項1に記載のフレキシブルプラスチックフィルム。
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US20230301046A1 (en) * | 2020-03-09 | 2023-09-21 | Dai Nippon Printing Co., Ltd. | Stacked body for flexible display device, stacked body for display device and flexible display device |
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---|---|---|---|---|
JP3033445B2 (ja) | 1994-07-05 | 2000-04-17 | 信越化学工業株式会社 | 樹脂用無機質充填剤及びエポキシ樹脂組成物 |
KR100199552B1 (ko) | 1996-12-26 | 1999-06-15 | 김기협 | 필름에 고내스크래치성 박막코팅을 부여하는 자외선 경화형 수지조성물 |
US6686031B2 (en) | 2000-02-23 | 2004-02-03 | Fuji Photo Film Co., Ltd. | Hard coat film and display device having same |
KR100390478B1 (ko) | 2001-02-21 | 2003-07-04 | 대한잉크화학주식회사 | 우레탄 아크릴레이트 올리고머의 제조 방법 및 이를포함하는 자외선 경화형 도막 조성물 |
EP1391493A1 (en) | 2002-08-22 | 2004-02-25 | Lintec Corporation | Surface protecting film for polycarbonate |
JP2005113033A (ja) | 2003-10-08 | 2005-04-28 | Toagosei Co Ltd | 活性エネルギー線硬化型プレコート鋼板用コーティング剤組成物 |
JP2006036835A (ja) | 2004-07-23 | 2006-02-09 | Jsr Corp | 硬化性樹脂組成物及び反射防止膜 |
CN1772820A (zh) | 2004-11-10 | 2006-05-17 | 比亚迪股份有限公司 | 一种用于塑料的紫外光固化涂料及其制造方法 |
US20060132025A1 (en) | 2004-12-22 | 2006-06-22 | Eastman Kodak Company | Flexible display designed for minimal mechanical strain |
US7264872B2 (en) | 2004-12-30 | 2007-09-04 | 3M Innovative Properties Company | Durable high index nanocomposites for AR coatings |
US7615283B2 (en) | 2006-06-13 | 2009-11-10 | 3M Innovative Properties Company | Fluoro(meth)acrylate polymer composition suitable for low index layer of antireflective film |
US8231973B2 (en) | 2006-06-13 | 2012-07-31 | 3M Innovative Properties Company | Fluoro(meth)acrylate polymer composition suitable for low index layer of antireflective film |
JP5446071B2 (ja) | 2006-09-11 | 2014-03-19 | Dic株式会社 | 保護粘着フィルム、スクリーンパネル及び携帯電子端末 |
JP2008089969A (ja) | 2006-10-02 | 2008-04-17 | Konica Minolta Opto Inc | 反射防止フィルム、偏光板、及び表示装置 |
JP2008165205A (ja) | 2006-12-05 | 2008-07-17 | Fujifilm Corp | 光学フィルム、反射防止フィルム、それを用いた偏光板およびディスプレイ装置 |
JP2008151998A (ja) | 2006-12-18 | 2008-07-03 | Nitto Denko Corp | ハードコートフィルムの製造方法、ハードコートフィルム、偏光板および画像表示装置 |
KR100884079B1 (ko) | 2006-12-28 | 2009-02-19 | 제일모직주식회사 | 하드코팅용 조성물 |
US20100087611A1 (en) | 2007-04-27 | 2010-04-08 | Showa Denko K.K. | Urethane compound, curable composition containing the same, and cured product thereof |
CN101657474A (zh) * | 2007-04-27 | 2010-02-24 | 昭和电工株式会社 | 氨基甲酸酯化合物、含有该化合物的固化性组合物及其固化物 |
WO2009005975A1 (en) | 2007-06-29 | 2009-01-08 | 3M Innovative Properties Company | Flexible hardcoat compositions, articles, and methods |
JP5217744B2 (ja) * | 2007-08-02 | 2013-06-19 | 大日本印刷株式会社 | 反射防止フィルム及び反射防止フィルムの製造方法 |
CN101790695B (zh) | 2007-08-10 | 2011-12-21 | 大日本印刷株式会社 | 硬涂膜 |
US20090075074A1 (en) | 2007-09-12 | 2009-03-19 | Dai Nippon Printing Co., Ltd. | Optical layered body, method of producing the same, polarizer, and image display device |
KR20090044089A (ko) | 2007-10-31 | 2009-05-07 | 금호석유화학 주식회사 | 하드코팅액 조성물 |
KR20090057597A (ko) | 2007-12-03 | 2009-06-08 | 제일모직주식회사 | 유연성, 고경도 및 고내열성을 가지는 하드코팅 조성물 |
EP2295481A4 (en) | 2008-05-23 | 2011-12-28 | Showa Denko Kk | CURABLE COMPOSITION COMPRISING A REACTIVE (METH) ACRYLATE POLYMER, AND HARDENED PRODUCT THEREOF |
JP5320848B2 (ja) | 2008-06-23 | 2013-10-23 | コニカミノルタ株式会社 | ハードコート層付積層体 |
US20100003523A1 (en) | 2008-07-02 | 2010-01-07 | Sabic Innovative Plastics Ip B.V. | Coated Film for Insert Mold Decoration, Methods for Using the Same, and Articles Made Thereby |
WO2010024115A1 (ja) | 2008-08-29 | 2010-03-04 | コニカミノルタオプト株式会社 | 光学フィルム、反射防止フィルム、偏光板及び液晶表示装置 |
JP5186327B2 (ja) | 2008-09-30 | 2013-04-17 | 富士フイルム株式会社 | 防眩フィルム、偏光板、および画像表示装置 |
JP5136336B2 (ja) | 2008-09-30 | 2013-02-06 | 大日本印刷株式会社 | ハードコートフィルム及びハードコートフィルムの製造方法 |
KR101098529B1 (ko) | 2008-10-15 | 2011-12-26 | 한국생산기술연구원 | 고경도 하드코팅 필름 조성물 |
JP2010174201A (ja) | 2009-02-02 | 2010-08-12 | Sony Corp | 帯電防止ハードコートフィルム、及び紫外線硬化性樹脂材料組成物 |
KR20170070278A (ko) | 2009-02-12 | 2017-06-21 | 코베스트로 도이칠란드 아게 | 반사-방지/연무-방지 코팅 |
JP4851554B2 (ja) | 2009-03-25 | 2012-01-11 | パナソニック株式会社 | プラズマディスプレイパネルの製造方法 |
JP5557274B2 (ja) | 2009-10-20 | 2014-07-23 | 日本化薬株式会社 | 紫外線硬化型ハードコート樹脂組成物、それを用いたハードコートフィルム及びハードコート成形物 |
US9067381B2 (en) | 2010-02-19 | 2015-06-30 | Fujifilm Corporation | Manufacturing method of functional film and functional film |
JP5541457B2 (ja) | 2010-03-31 | 2014-07-09 | 住友ベークライト株式会社 | ハードコートフィルム |
KR20110111768A (ko) | 2010-04-05 | 2011-10-12 | 동우 화인켐 주식회사 | 하드 코팅용 조성물, 이로 제조된 하드 코팅 필름, 상기 하드 코팅 필름을 구비하는 편광판 및 화상표시장치 |
JP5690094B2 (ja) | 2010-07-30 | 2015-03-25 | 大日本印刷株式会社 | 耐候ハードコートフィルム |
CN102129090B (zh) | 2010-11-30 | 2012-07-25 | 中国乐凯胶片集团公司 | 一种光学硬化膜 |
WO2012086551A1 (ja) * | 2010-12-24 | 2012-06-28 | 大日本印刷株式会社 | ハードコートフィルム、偏光板及び画像表示装置 |
KR101411006B1 (ko) | 2010-12-31 | 2014-06-23 | 제일모직주식회사 | 하드코팅필름 |
KR101227551B1 (ko) | 2011-02-25 | 2013-01-31 | 에스케이씨 주식회사 | 굴곡성이 향상된 하드코팅 필름 |
KR101127952B1 (ko) | 2011-03-16 | 2012-03-23 | 에스케이씨 주식회사 | 광학용 하드코팅 필름 |
JP5819952B2 (ja) | 2011-05-26 | 2015-11-24 | 株式会社ダイセル | ディスプレイ用透明積層フィルム及びその使用方法並びにタッチパネル |
JP2014529762A (ja) | 2011-08-26 | 2014-11-13 | エルジー・ケム・リミテッド | 反射防止コーティング用組成物及びこれを用いて製造された反射防止フィルム |
JP5709706B2 (ja) | 2011-09-15 | 2015-04-30 | 日揮触媒化成株式会社 | 透明被膜形成用塗料および透明被膜付基材 |
KR20130074830A (ko) | 2011-12-23 | 2013-07-05 | 금호석유화학 주식회사 | 안티블로킹 하드코팅액 조성물 및 안티블로킹용 하드코팅층 |
JP5929252B2 (ja) | 2012-02-01 | 2016-06-01 | Jnc株式会社 | 自己修復層を備えた積層体およびその製造方法 |
CN103374246A (zh) | 2012-04-13 | 2013-10-30 | Sdc科技有限公司 | 柔韧的uv可固化的涂料组合物 |
KR101472895B1 (ko) | 2012-05-18 | 2014-12-16 | 티씨씨주식회사 | 자외선 경화성 수지 조성물 및 이를 사용하여 제조된 투명필름 |
KR101418409B1 (ko) * | 2012-05-31 | 2014-07-09 | 주식회사 엘지화학 | 하드코팅 조성물 |
KR101379491B1 (ko) | 2012-05-31 | 2014-04-01 | 주식회사 엘지화학 | 하드코팅 필름 및 이의 제조방법 |
KR101501686B1 (ko) | 2012-05-31 | 2015-03-11 | 주식회사 엘지화학 | 하드코팅 필름 |
JP6203715B2 (ja) | 2012-06-22 | 2017-09-27 | ソマール株式会社 | エネルギー線硬化型樹脂組成物、硬化物及び積層体 |
JP2014030910A (ja) | 2012-08-01 | 2014-02-20 | 3M Innovative Properties Co | ハードコートを有するウィンドウフィルム |
JP6371032B2 (ja) | 2012-08-01 | 2018-08-08 | スリーエム イノベイティブ プロパティズ カンパニー | 反射防止ハードコートおよび反射防止物品 |
JP6062680B2 (ja) | 2012-08-01 | 2017-01-18 | スリーエム イノベイティブ プロパティズ カンパニー | 防汚性ハードコートおよび防汚性ハードコート前駆体 |
WO2014027761A1 (ko) | 2012-08-17 | 2014-02-20 | 제일모직 주식회사 | 표시소자용 플렉서블 기판, 그 제조방법 및 이를 이용한 디스플레이 장치 |
KR101470466B1 (ko) | 2012-08-23 | 2014-12-08 | 주식회사 엘지화학 | 적층 하드코팅 필름 |
KR101470465B1 (ko) | 2012-08-23 | 2014-12-08 | 주식회사 엘지화학 | 하드코팅 필름 |
KR101415840B1 (ko) | 2012-08-23 | 2014-07-09 | 주식회사 엘지화학 | 하드코팅 필름 |
KR101910111B1 (ko) | 2012-08-28 | 2018-10-22 | 삼성디스플레이 주식회사 | 접이식 표시 장치 |
KR101443845B1 (ko) | 2012-09-03 | 2014-09-23 | 주식회사 엘지화학 | 하드코팅 필름을 포함하는 편광판 |
JP2014079974A (ja) * | 2012-10-17 | 2014-05-08 | 3M Innovative Properties Co | 車輛用部材 |
KR20140058762A (ko) | 2012-11-06 | 2014-05-15 | 동우 화인켐 주식회사 | 하드코팅필름 및 이를 적용한 커버 윈도우 |
KR101948655B1 (ko) * | 2012-12-06 | 2019-02-15 | 동우 화인켐 주식회사 | 하드코팅필름 및 이를 이용한 플렉시블 디스플레이 |
KR101537845B1 (ko) | 2012-12-12 | 2015-07-17 | 코오롱인더스트리 주식회사 | 투명 폴리이미드 기판 및 그 제조방법 |
US8754145B1 (en) | 2012-12-20 | 2014-06-17 | Momentive Performance Materials Inc. | Radiation curable hardcoat with improved weatherability |
CN103013324B (zh) | 2012-12-21 | 2015-09-09 | 湖南松井新材料有限公司 | 自修复型紫外光固化漆 |
KR101391241B1 (ko) | 2013-02-18 | 2014-05-02 | 주식회사 효성 | 광학용 투명 하드코팅 필름의 제조방법 |
KR101482687B1 (ko) | 2013-02-20 | 2015-01-16 | 한국과학기술원 | 투명 플렉시블 하드코팅 필름, 및 이의 제조 방법 |
KR101578914B1 (ko) | 2013-03-15 | 2015-12-18 | 주식회사 엘지화학 | 플라스틱 필름 |
KR101587190B1 (ko) | 2013-03-15 | 2016-01-20 | 주식회사 엘지화학 | 플라스틱 필름 |
JP2015003516A (ja) | 2013-05-24 | 2015-01-08 | デクセリアルズ株式会社 | 保護コート層付フィルム |
KR101523747B1 (ko) | 2013-06-20 | 2015-05-28 | 주식회사 피치 | 박막형 하드코팅 필름 및 이의 제조방법 |
KR20150000729A (ko) | 2013-06-25 | 2015-01-05 | 코오롱인더스트리 주식회사 | 중공형 실리카를 포함하는 항블록킹 하드코팅 필름 |
MX2015017754A (es) | 2013-06-26 | 2016-06-21 | Momentive Performance Mat Inc | Composicion de recubrimiento fotocurable y su uso. |
WO2014208323A1 (ja) * | 2013-06-28 | 2014-12-31 | 横浜ゴム株式会社 | ハードコート層形成用樹脂組成物 |
JP5650347B1 (ja) | 2013-07-18 | 2015-01-07 | 日本合成化学工業株式会社 | 樹脂成形体、ディスプレイ用保護板及びタッチパネル基板、並びに樹脂成形体の自己修復方法 |
JP2015060963A (ja) | 2013-09-19 | 2015-03-30 | 凸版印刷株式会社 | 太陽電池モジュール保護シート及びその製造方法並びに該保護シートを用いた太陽電池モジュール |
WO2015076566A1 (ko) | 2013-11-19 | 2015-05-28 | 주식회사 엘지화학 | 플라스틱 필름 |
KR101671431B1 (ko) * | 2013-11-19 | 2016-11-01 | 주식회사 엘지화학 | 플라스틱 필름 |
KR101686644B1 (ko) | 2013-11-19 | 2016-12-14 | 주식회사 엘지화학 | 플라스틱 필름 적층체 |
JP2015112670A (ja) | 2013-12-10 | 2015-06-22 | 住友ベークライト株式会社 | 工作機用窓、およびハードコート層形成用組成物 |
KR20150072549A (ko) | 2013-12-20 | 2015-06-30 | (주)엘지하우시스 | 대전방지 코팅조성물 및 이를 포함하는 대전방지 보호필름 |
JP2015123721A (ja) * | 2013-12-27 | 2015-07-06 | 三菱レイヨン株式会社 | 樹脂積層体およびその製造方法 |
CN105899623B (zh) | 2014-01-15 | 2018-08-10 | 3M创新有限公司 | 包含烷氧基化的多(甲基)丙烯酸酯单体和经表面处理的纳米粒子的硬质涂膜 |
CN104199128B (zh) | 2014-08-21 | 2016-07-06 | 昆山乐凯锦富光电科技有限公司 | 一种光学硬化膜 |
KR20160103682A (ko) | 2015-02-25 | 2016-09-02 | 동우 화인켐 주식회사 | 폴더블 하드코팅 필름의 제조방법 |
KR102268999B1 (ko) | 2015-03-24 | 2021-06-23 | 동우 화인켐 주식회사 | 하드코팅 필름 및 이를 구비하는 화상 표시 장치 |
KR101853387B1 (ko) | 2015-03-27 | 2018-04-30 | 동우 화인켐 주식회사 | 플렉서블 디스플레이용 하드코팅 필름 |
JP5985100B1 (ja) | 2015-05-21 | 2016-09-06 | デクセリアルズ株式会社 | 透明積層体 |
KR101862252B1 (ko) * | 2015-08-03 | 2018-05-29 | 주식회사 엘지화학 | 플렉시블 플라스틱 필름 |
KR101801471B1 (ko) | 2016-06-23 | 2017-11-24 | 동우 화인켐 주식회사 | 하드코팅 필름 및 이를 이용한 화상표시장치 |
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EP3309229A1 (en) | 2018-04-18 |
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CN107849388B (zh) | 2019-06-18 |
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