JP6650148B2 - デュアルキュア型耐汚染性マイクロスフェア物品 - Google Patents

デュアルキュア型耐汚染性マイクロスフェア物品 Download PDF

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Publication number
JP6650148B2
JP6650148B2 JP2016550782A JP2016550782A JP6650148B2 JP 6650148 B2 JP6650148 B2 JP 6650148B2 JP 2016550782 A JP2016550782 A JP 2016550782A JP 2016550782 A JP2016550782 A JP 2016550782A JP 6650148 B2 JP6650148 B2 JP 6650148B2
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polymer
binder resin
article
mol
microspheres
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English (en)
Japanese (ja)
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JP2017512670A5 (enExample
JP2017512670A (ja
Inventor
ビー．ウォーカー，ジュニア クリストファー
ビー．ウォーカー，ジュニア クリストファー
シー．クラーク ジョン
シー．クラーク ジョン
ピー．クルン トーマス
ピー．クルン トーマス
ジェイ．マクマン スティーブン
ジェイ．マクマン スティーブン
エー．モハムド アブダラヒ
エー．モハムド アブダラヒ
ジェイ．クゲル アレクサンダー
ジェイ．クゲル アレクサンダー
クリシュナン ビベク
クリシュナン ビベク
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP2016550782A 2014-02-13 2015-02-13 デュアルキュア型耐汚染性マイクロスフェア物品 Active JP6650148B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201461939369P 2014-02-13 2014-02-13
US61/939,369 2014-02-13
US201461944782P 2014-02-26 2014-02-26
US61/944,782 2014-02-26
PCT/US2015/015923 WO2015123582A1 (en) 2014-02-13 2015-02-13 Dual cure stain resistant microsphere articles

Publications (3)

Publication Number Publication Date
JP2017512670A JP2017512670A (ja) 2017-05-25
JP2017512670A5 JP2017512670A5 (enExample) 2018-03-22
JP6650148B2 true JP6650148B2 (ja) 2020-02-19

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ID=52630490

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JP2016550782A Active JP6650148B2 (ja) 2014-02-13 2015-02-13 デュアルキュア型耐汚染性マイクロスフェア物品

Country Status (6)

Country Link
US (1) US10245812B2 (enExample)
EP (1) EP3105048B1 (enExample)
JP (1) JP6650148B2 (enExample)
KR (1) KR102300849B1 (enExample)
CN (1) CN106029363B (enExample)
WO (1) WO2015123582A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101749722B1 (ko) * 2014-06-17 2017-06-21 주식회사 엘지화학 코팅 조성물, 이를 이용하여 제조된 플라스틱 필름 및 그 제조방법
WO2016104377A1 (ja) * 2014-12-25 2016-06-30 旭硝子株式会社 硬化性樹脂組成物
WO2017106239A1 (en) * 2015-12-18 2017-06-22 3M Innovative Properties Company Decorative article featuring a microscopic periodic pattern and methods of making the same
JP6972006B2 (ja) * 2016-03-30 2021-11-24 スリーエム イノベイティブ プロパティズ カンパニー ランダムに分散された微小球の所定のパターンを主とする物品及びその製造方法
CN111511555A (zh) * 2017-12-20 2020-08-07 Ａｇｃ株式会社 装饰薄膜、装饰薄膜的制造方法、带装饰薄膜的三维成形品的制造方法及含氟聚合物组合物
WO2019240189A1 (ja) * 2018-06-13 2019-12-19 Ａｇｃ株式会社 加飾フィルム、組成物、加飾フィルムの製造方法、加飾フィルム付き３次元成形品の製造方法
WO2020225717A1 (en) 2019-05-08 2020-11-12 3M Innovative Properties Company Nanostructured article
CN113825642B (zh) 2019-05-17 2024-04-26 3M创新有限公司 微球涂覆的聚氨酯制品及其制备方法
US20210147593A1 (en) * 2019-11-20 2021-05-20 Madico, Inc. Fluoro acrylate and methods making and using the same

Family Cites Families (102)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2326634A (en) 1941-12-26 1943-08-10 Minnesota Mining & Mfg Reflex light reflector
US2567233A (en) 1946-09-19 1951-09-11 Minnesota Mining & Mfg Reflex-reflective sheet material useful for protective garments and the like
US2803656A (en) 1956-01-23 1957-08-20 Minnesota Mining & Mfg Fluorocarbonsulfonamidoalkanols and sulfates thereof
NL257502A (enExample) 1959-11-02
US3190178A (en) 1961-06-29 1965-06-22 Minnesota Mining & Mfg Reflex-reflecting sheeting
US3154872A (en) 1963-02-13 1964-11-03 Minnesota Mining & Mfg Tamper-proof markings for reflecting structures
NL168339C (nl) 1969-01-21 1982-03-16 Minnesota Mining & Mfg Reflecterend vel.
US3551025A (en) 1969-03-28 1970-12-29 Minnesota Mining & Mfg Highly flexible reflex reflecting constructions
US3764455A (en) 1970-04-01 1973-10-09 Goodyear Tire & Rubber Reflective surface and method of production
US3758192A (en) 1970-08-20 1973-09-11 Minnesota Mining & Mfg Reflex-reflective structures including fabric and transfer foils
US3700478A (en) 1970-11-09 1972-10-24 Minnesota Mining & Mfg Microspheres having an antireflection coating and their use
US3700305A (en) 1970-12-14 1972-10-24 Minnesota Mining & Mfg Retroreflective microspheres having a dielectric mirror on a portion of their surface and retroreflective constructions containing such microspheres
US3801183A (en) 1973-06-01 1974-04-02 Minnesota Mining & Mfg Retro-reflective film
US4107391A (en) 1973-12-10 1978-08-15 General Electric Company Method for making thermoformable composites and composites made thereby
GB1447585A (en) 1974-03-21 1976-08-25 Minnesota Mining & Mfg Retro-reflective fiom
US4025159A (en) 1976-02-17 1977-05-24 Minnesota Mining And Manufacturing Company Cellular retroreflective sheeting
US4102562A (en) 1976-06-14 1978-07-25 Minnesota Mining And Manufacturing Company Retroreflective transfer sheet material
US4576850A (en) 1978-07-20 1986-03-18 Minnesota Mining And Manufacturing Company Shaped plastic articles having replicated microstructure surfaces
US4198465A (en) 1978-11-01 1980-04-15 General Electric Company Photocurable acrylic coated polycarbonate articles
US4393187A (en) 1982-06-23 1983-07-12 Congoleum Corporation Stain resistant, abrasion resistant polyurethane coating composition, substrate coated therewith and production thereof
US4725494A (en) 1982-09-02 1988-02-16 Minnesota Mining And Manufacturing Co. Retroreflective sheeting
JPH0617921B2 (ja) 1984-03-15 1994-03-09 西武ポリマ化成株式会社 セル状反射シート
US4808471A (en) 1985-03-01 1989-02-28 Minnesota Mining And Manufacturing Company Flat transparent top coat for retroreflective sheeting
US4721649A (en) 1985-05-08 1988-01-26 Minnesota Mining And Manufacturing Company Retroreflective sheeting
US5064272A (en) 1985-11-18 1991-11-12 Minnesota Mining And Manufacturing Company Encapsulated-lens retroreflective sheeting and method of making
US4897136A (en) 1985-11-18 1990-01-30 Minnesota Mining And Manufacturing Company Method of making encapsulated-lens retroreflective sheeting
US4763985A (en) 1986-08-01 1988-08-16 Minnesota Mining And Manufacturing Company Retroreflective sheet with enhanced brightness
JP2546853B2 (ja) 1987-09-03 1996-10-23 オーツタイヤ株式会社 装飾性ビーズコートシートおよびその製造方法
US5008142A (en) 1988-09-02 1991-04-16 Minnesota Mining And Manufacturing Company Embedded lens retroreflective sheeting with flexible, dimensionally stable coating
EP0386297A1 (en) 1989-03-10 1990-09-12 General Electric Company Uv curable thermoformable protective coatings
JP2996476B2 (ja) 1990-01-29 1999-12-27 株式会社アイジー技術研究所 高耐候性金属リシン板
JP2794890B2 (ja) 1990-04-09 1998-09-10 三菱化学株式会社 ハードコート層を有するプロピレン系樹脂成形品の製造方法
US5117304A (en) 1990-09-21 1992-05-26 Minnesota Mining And Manufacturing Company Retroreflective article
JP3048062B2 (ja) 1991-05-08 2000-06-05 ミネソタ マイニング アンド マニュファクチャリング カンパニー 洗濯可能な再帰性反射アップリケ
US5200262A (en) 1992-04-01 1993-04-06 Minnesota Mining And Manufacturing Company Launderable retroreflective applique with improved retention of retroreflective elements
US5344705A (en) 1993-05-05 1994-09-06 Minnesota Mining And Manufacturing Company Retroreflective transfer sheet material
JP3315004B2 (ja) 1993-05-14 2002-08-19 旭硝子株式会社 表面処理された基材およびその製造方法
US5474827A (en) 1994-03-23 1995-12-12 Minnesota Mining And Manufacturing Company Retroreflective article and method of making the same
JP2740943B2 (ja) 1994-10-31 1998-04-15 大日本印刷株式会社 耐摩耗性を有する化粧材
CN1119672C (zh) 1994-11-23 2003-08-27 美国3M公司 含有聚醚聚氨酯粘合剂层的反光制品及其制造方法和用途
EP0795137B1 (en) 1994-11-29 1998-08-26 Minnesota Mining And Manufacturing Company Transparent decorative article having an etched appearing/prismatic image thereon
JP3629297B2 (ja) 1995-05-11 2005-03-16 ミネソタ マイニング アンド マニュファクチャリング カンパニー 再帰性反射シート及び再帰性反射性能を有する物品
US5645938A (en) 1995-09-15 1997-07-08 Minnesota Mining And Manufacturing Company Retroreflective article containing a polyester polyurethane binder layer
US5812317A (en) 1995-10-26 1998-09-22 Minnesota Mining And Manufacturing Company Exposed lens retroreflective article having a polymeric intermediate layer disposed between microspheric and reflective layers
US5620775A (en) 1995-11-03 1997-04-15 Minnesota Mining And Manufacturing Company Low refractive index glass microsphere coated article having a smooth surface and a method for preparing same
US5882771A (en) 1996-04-10 1999-03-16 Minnesota Mining And Manufacturing Company Conformable embossable retroreflective sheeting
MY121667A (en) 1996-04-26 2006-02-28 Nissha Printing Thermo and active energy ray curable resin composition used for protecting layer of transfer material transfer material surface protecting material and process for producing molded article excellent in abrasion resistance and chemical resistance.
DE19628966C1 (de) 1996-07-18 1997-12-18 Daimler Benz Ag Verfahren zum Applizieren einer Lackfolie auf dreidimensional gewölbte Flächen formstabiler Substrate
US5976669A (en) 1996-12-20 1999-11-02 3M Innovative Properties Company Retroreflective article having launderably durable bead-bond
US6156436A (en) 1997-04-04 2000-12-05 3M Innovative Properties Company Use of a crystalline bead bond layer in a retroreflective article
US6159537A (en) 1997-08-01 2000-12-12 3M Innovative Properties Company Method of making a retroreflective article that has a binder layer containing an epoxy resin and silicone crosslinked polymer
US5959775A (en) 1997-12-23 1999-09-28 3M Innovative Properties Company Urethane/acrylate bead bond for retroreflective articles
US6054208A (en) 1998-01-16 2000-04-25 Avery Dennison Corporation Film forming mixtures, image bearing films and image bearing retroreflective sheeting
US7727436B2 (en) 1998-03-05 2010-06-01 Omnova Solutions Inc. Coating derived from polyesters crosslinked with melamine formaldehyde
US6852399B2 (en) 1998-07-14 2005-02-08 Dai Nippon Printing Co., Ltd. Decorative material
US6527898B1 (en) 1998-10-01 2003-03-04 Nissha Printing Co., Ltd. Transfer material, surface-protective sheet, and process for producing molded article with these
DE19917965A1 (de) 1999-04-21 2000-10-26 Daimler Chrysler Ag Strahlungshärtbare Verbundschichtplatte oder -folie
DE19938759A1 (de) 1999-08-16 2001-02-22 Basf Coatings Ag Beschichtungsstoff und seine Verwendung zur Herstellung hochkratzfester mehrschichtiger Klarlackierungen
US6677028B1 (en) 1999-09-10 2004-01-13 3M Innovative Properties Company Retroreflective articles having multilayer films and methods of manufacturing same
US6342119B1 (en) 1999-11-08 2002-01-29 Ying-Chi Shih Manufacturing method of a compound substrate for light-reflective application
US6355302B1 (en) 1999-12-10 2002-03-12 3M Innovative Properties Company Continuous process for making high performance retroreflective fabric
US6416188B1 (en) 2000-04-11 2002-07-09 3M Innovative Properties Company Dielectric mirror retroreflective appliques having excellent repetitive laundering performance
DE10041634C2 (de) 2000-08-24 2002-10-17 Basf Coatings Ag Wäßrige Dispersion und ihre Verwendung zur Herstellung von thermisch und mit aktinischer Strahlung härtbaren Beschichtungsstoffen, Klebstoffen und Dichtungsmassen
US6632508B1 (en) 2000-10-27 2003-10-14 3M Innovative Properties Company Optical elements comprising a polyfluoropolyether surface treatment
GB0114738D0 (en) 2001-06-16 2001-08-08 Reflec Plc Retroreflective fabric production
ITMO20010125A1 (it) 2001-06-21 2002-12-21 Autoadesivi S R L Procedimento per la fabbricazione di un tessuto o termoadesivo rinfrangente o retroriflettente
ITMO20010126A1 (it) 2001-06-21 2002-12-21 Autoadesivi S R L Tessuto o termoadesivo rinfrangente o retroriflettente
ITMO20010157A1 (it) 2001-07-27 2003-01-27 Giorgio Corradi Metodo per la fabbricazione di un laminato retroriflettente
US6815501B2 (en) 2002-04-09 2004-11-09 E. I. Du Pont De Nemours And Company Dual cure coating compositions and process for the production of multilayer coatings
US6905754B2 (en) 2002-04-26 2005-06-14 3M Innovative Properties Company Optical elements comprising fluorochemical surface treatment
US20040023019A1 (en) 2002-08-02 2004-02-05 3M Innovative Properties Company Particulate transfer film with improved bead carrier
ATE342673T1 (de) 2003-04-17 2006-11-15 Ind Bergamasca Rifrangenti S R Verfahren zur herstellung von gedruckten reflektierenden gut sichtbaren produkten
US8030430B2 (en) 2003-10-06 2011-10-04 3M Innovative Properties Company Stain resistant polyurethane coatings
US20050197444A1 (en) 2004-03-08 2005-09-08 Kyte William J. Stain-resistant grout composition, dispenser therefor, and method of use
DE102004026906A1 (de) 2004-06-01 2005-12-22 Basf Ag Strahlungshärtbare Verbundschichtplatte oder -folie
DE102004030196A1 (de) 2004-06-22 2006-01-19 Bayer Materialscience Ag Verfahren zur Herstellung von Polyurethan-Formkörpern
US7511016B2 (en) 2004-07-07 2009-03-31 Mosamedix B.V. Annexins, derivatives thereof, and annexin-cys variants, as well as therapeutic and diagnostic uses thereof
US7985478B2 (en) 2004-11-04 2011-07-26 Basf Coatings Ag Method for producing moulded parts, in particular for use in the car industry, and a film comprising a coating which is suitable therefor
CN102544149B (zh) * 2005-11-30 2016-07-20 大金工业株式会社 太阳能电池以及太阳能电池的保护罩用层积膜
KR100788215B1 (ko) 2006-03-31 2007-12-27 주식회사 지.비라이트 수성수지를 이용한 재귀반사 제품의 제조방법
WO2008007394A1 (en) 2006-07-10 2008-01-17 Fabio Valle Process for applying refracting and reflecting spheres and/or microspheres on surfaces and product obtained therewith
US9248470B2 (en) 2006-07-31 2016-02-02 Safe Reflections, Inc. Colorized retroreflective material and method
EP2097258A2 (de) 2006-10-13 2009-09-09 Basf Se Verfahren zur folienbeschichtung von gegenständen
US8071198B2 (en) * 2006-11-17 2011-12-06 E.I. Du Pont De Nemours And Company Glass articles with adhesion and stain resistant non-stick coatings
ITBO20060882A1 (it) 2006-12-27 2008-06-28 Teuco Guzzini Spa Materiale facilmente pulibile
JP2009024145A (ja) 2007-07-24 2009-02-05 Asahi Glass Co Ltd 塗料用フッ素樹脂組成物およびこれを用いた物品
KR100969041B1 (ko) 2008-03-25 2010-07-09 현대자동차주식회사 생체질감을 갖는 무용제 폴리우레탄계 인조피혁 및 이의제조방법
US20090269504A1 (en) 2008-04-24 2009-10-29 Momentive Performance Materials Inc. Flexible hardcoats and substrates coated therewith
CN101314684B (zh) 2008-06-18 2010-09-01 深圳市广田环保涂料有限公司 一种单组分氟碳银粉烤漆及其制备方法、专用稀释剂和使用方法
US20100003523A1 (en) 2008-07-02 2010-01-07 Sabic Innovative Plastics Ip B.V. Coated Film for Insert Mold Decoration, Methods for Using the Same, and Articles Made Thereby
CN101319113B (zh) 2008-07-18 2010-06-02 深圳市广田环保涂料有限公司 中温烘烤型氟碳漆及其使用方法
EP2310468A1 (en) 2008-07-25 2011-04-20 3M Innovative Properties Company Elastic bonding films
US20100092759A1 (en) 2008-10-13 2010-04-15 Hua Fan Fluoropolymer/particulate filled protective sheet
JP2010182862A (ja) 2009-02-05 2010-08-19 Dic Corp 低誘電率絶縁体材料層の形成方法及び該方法で形成された層又はパターン
DE102009029834A1 (de) 2009-06-17 2010-12-23 Bernhard Förster Gmbh Baureihe von Brackets für die Orthodontie
EP2464515A4 (en) * 2009-08-10 2013-12-04 Saint Gobain Performance Plast FLUOROPOLYMER / PARTICLE FILLED PROTECTIVE FOIL
KR101721721B1 (ko) 2010-05-03 2017-03-30 쓰리엠 이노베이티브 프로퍼티즈 컴파니 나노구조의 제조 방법
KR20130138294A (ko) 2010-12-16 2013-12-18 쓰리엠 이노베이티브 프로퍼티즈 컴파니 상호침투 중합체 층
US20130052437A1 (en) 2011-08-24 2013-02-28 Pratt & Whitney Substrates Coated with Wear Resistant Layers and Methods of Applying Wear Resistant Layers to Same
EP2817153A4 (en) 2012-02-22 2016-07-20 3M Innovative Properties Co MICROSPHERES ARTICLES AND ARTICLES OF TRANSFER
JP6388589B2 (ja) 2012-10-04 2018-09-12 スリーエム イノベイティブ プロパティズ カンパニー 熱成形可能な微小球物品
JP6576337B2 (ja) * 2013-06-26 2019-09-18 スリーエム イノベイティブ プロパティズ カンパニー 耐汚染性マイクロスフェア物品

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US20160347042A1 (en) 2016-12-01
US10245812B2 (en) 2019-04-02
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CN106029363B (zh) 2018-01-16

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