JP6551626B2 - 高マンガン鋼の溶製方法 - Google Patents
高マンガン鋼の溶製方法 Download PDFInfo
- Publication number
- JP6551626B2 JP6551626B2 JP2019506740A JP2019506740A JP6551626B2 JP 6551626 B2 JP6551626 B2 JP 6551626B2 JP 2019506740 A JP2019506740 A JP 2019506740A JP 2019506740 A JP2019506740 A JP 2019506740A JP 6551626 B2 JP6551626 B2 JP 6551626B2
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- JP
- Japan
- Prior art keywords
- manganese
- molten metal
- steel
- source
- concentration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000034 method Methods 0.000 title claims description 52
- 229910000617 Mangalloy Inorganic materials 0.000 title claims description 32
- 230000008018 melting Effects 0.000 title claims description 20
- 238000002844 melting Methods 0.000 title claims description 20
- 229910052751 metal Inorganic materials 0.000 claims description 140
- 239000002184 metal Substances 0.000 claims description 140
- 239000011572 manganese Substances 0.000 claims description 133
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 117
- 229910052748 manganese Inorganic materials 0.000 claims description 117
- 229910000831 Steel Inorganic materials 0.000 claims description 65
- 239000010959 steel Substances 0.000 claims description 65
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 59
- 229910052710 silicon Inorganic materials 0.000 claims description 59
- 239000010703 silicon Substances 0.000 claims description 59
- 238000003756 stirring Methods 0.000 claims description 51
- 238000007872 degassing Methods 0.000 claims description 49
- 238000007664 blowing Methods 0.000 claims description 42
- 229910052799 carbon Inorganic materials 0.000 claims description 40
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 39
- 238000009849 vacuum degassing Methods 0.000 claims description 36
- 238000005261 decarburization Methods 0.000 claims description 31
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 description 43
- 238000006722 reduction reaction Methods 0.000 description 26
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 24
- 239000002893 slag Substances 0.000 description 17
- 239000000463 material Substances 0.000 description 15
- 230000001590 oxidative effect Effects 0.000 description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 13
- 239000001301 oxygen Substances 0.000 description 13
- 229910052760 oxygen Inorganic materials 0.000 description 13
- 238000011946 reduction process Methods 0.000 description 13
- 229910000616 Ferromanganese Inorganic materials 0.000 description 12
- 229910052742 iron Inorganic materials 0.000 description 12
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 12
- 238000007670 refining Methods 0.000 description 11
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 9
- 235000011941 Tilia x europaea Nutrition 0.000 description 9
- 239000004571 lime Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 238000006477 desulfuration reaction Methods 0.000 description 7
- 230000023556 desulfurization Effects 0.000 description 7
- 229910052698 phosphorus Inorganic materials 0.000 description 7
- 239000011574 phosphorus Substances 0.000 description 7
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000006356 dehydrogenation reaction Methods 0.000 description 6
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000010079 rubber tapping Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 238000003723 Smelting Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910000720 Silicomanganese Inorganic materials 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 238000009628 steelmaking Methods 0.000 description 3
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910000967 As alloy Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0068—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 by introducing material into a current of streaming metal
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/06—Deoxidising, e.g. killing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/064—Dephosphorising; Desulfurising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/068—Decarburising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/10—Handling in a vacuum
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Multimedia (AREA)
- Manufacturing & Machinery (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017103666 | 2017-05-25 | ||
JP2017103666 | 2017-05-25 | ||
PCT/JP2018/019526 WO2018216660A1 (ja) | 2017-05-25 | 2018-05-21 | 高マンガン鋼の溶製方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPWO2018216660A1 JPWO2018216660A1 (ja) | 2019-06-27 |
JP6551626B2 true JP6551626B2 (ja) | 2019-07-31 |
Family
ID=64396816
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2019506740A Active JP6551626B2 (ja) | 2017-05-25 | 2018-05-21 | 高マンガン鋼の溶製方法 |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP3633051B1 (ko) |
JP (1) | JP6551626B2 (ko) |
KR (1) | KR102315999B1 (ko) |
CN (1) | CN110621793A (ko) |
TW (1) | TWI685577B (ko) |
WO (1) | WO2018216660A1 (ko) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111621621B (zh) * | 2020-05-12 | 2022-03-22 | 首钢集团有限公司 | 一种RH真空处理过程钢液中Mn的控制方法 |
CN115478222B (zh) * | 2022-09-26 | 2023-08-18 | 河南中原特钢装备制造有限公司 | 一种纯净度及耐蚀性高的无磁不锈钢及其冶炼方法 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01225715A (ja) * | 1988-03-03 | 1989-09-08 | Nkk Corp | 高マンガン鋼の製造方法 |
JPH01301815A (ja) * | 1988-05-30 | 1989-12-06 | Sumitomo Metal Ind Ltd | 低炭素鋼の溶製方法 |
JP2722899B2 (ja) | 1991-11-01 | 1998-03-09 | 住友金属工業株式会社 | 高Mn鋼の脱炭精錬方法 |
WO1995001458A1 (fr) * | 1993-06-30 | 1995-01-12 | Nippon Steel Corporation | Procede de production et d'acier au moyen d'un convertisseur |
JP4534734B2 (ja) | 2004-11-29 | 2010-09-01 | Jfeスチール株式会社 | 低炭素高マンガン鋼の溶製方法 |
UA82962C2 (en) * | 2005-12-02 | 2008-05-26 | Sms Demag Ag | Method and smelting unit for obtaining steel with high manganese and low carbon content |
CN100434556C (zh) * | 2006-09-26 | 2008-11-19 | 山西太钢不锈钢股份有限公司 | 高锰含量不锈钢在冶炼中的加锰方法 |
JP4911298B2 (ja) * | 2006-10-17 | 2012-04-04 | 大同特殊鋼株式会社 | 高Mn鋼の製造方法 |
TW200920859A (en) * | 2007-11-02 | 2009-05-16 | Walsin Lihwa Corp | Steelmaking method of separately refining manganese and chromium for high manganese stainless steel |
JP5509876B2 (ja) * | 2010-01-26 | 2014-06-04 | Jfeスチール株式会社 | 低炭素高マンガン鋼の溶製方法 |
CN102168160B (zh) * | 2011-03-08 | 2013-04-17 | 武汉钢铁(集团)公司 | 使锰矿直接还原合金化的转炉炼钢工艺 |
JP5861825B2 (ja) | 2011-11-29 | 2016-02-16 | Jfeスチール株式会社 | 低炭素高マンガン鋼の溶製方法 |
JP5408369B2 (ja) * | 2012-01-19 | 2014-02-05 | Jfeスチール株式会社 | 溶銑の予備処理方法 |
CN102965584B (zh) * | 2012-12-17 | 2014-11-05 | 山西太钢不锈钢股份有限公司 | 一种高氮高锰不锈钢及其冶炼方法 |
KR101439763B1 (ko) * | 2013-04-11 | 2014-09-11 | 주식회사 포스코 | 망간 함유 용강 제조방법, 보온로, 및 보온로를 활용한 망간 함유 용강 제조설비 |
CN104109736B (zh) * | 2014-06-20 | 2018-05-04 | 宝钢不锈钢有限公司 | 一种aod转炉冶炼304不锈钢的方法 |
JP6269550B2 (ja) * | 2015-03-30 | 2018-01-31 | Jfeスチール株式会社 | 高マンガン鋼の溶製方法 |
CN105483314B (zh) * | 2016-01-04 | 2018-04-24 | 首钢总公司 | 一种提高转炉终点残锰含量的控制方法 |
-
2018
- 2018-05-21 JP JP2019506740A patent/JP6551626B2/ja active Active
- 2018-05-21 WO PCT/JP2018/019526 patent/WO2018216660A1/ja active Application Filing
- 2018-05-21 KR KR1020197033815A patent/KR102315999B1/ko active IP Right Grant
- 2018-05-21 CN CN201880032038.3A patent/CN110621793A/zh active Pending
- 2018-05-21 EP EP18806216.0A patent/EP3633051B1/en active Active
- 2018-05-24 TW TW107117640A patent/TWI685577B/zh active
Also Published As
Publication number | Publication date |
---|---|
EP3633051A1 (en) | 2020-04-08 |
TW201900897A (zh) | 2019-01-01 |
KR102315999B1 (ko) | 2021-10-21 |
TWI685577B (zh) | 2020-02-21 |
JPWO2018216660A1 (ja) | 2019-06-27 |
WO2018216660A1 (ja) | 2018-11-29 |
EP3633051B1 (en) | 2021-11-17 |
CN110621793A (zh) | 2019-12-27 |
KR20190142355A (ko) | 2019-12-26 |
EP3633051A4 (en) | 2020-04-08 |
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