JP6420236B2 - 高電界を用いたナノポアの作製 - Google Patents
高電界を用いたナノポアの作製 Download PDFInfo
- Publication number
- JP6420236B2 JP6420236B2 JP2015510885A JP2015510885A JP6420236B2 JP 6420236 B2 JP6420236 B2 JP 6420236B2 JP 2015510885 A JP2015510885 A JP 2015510885A JP 2015510885 A JP2015510885 A JP 2015510885A JP 6420236 B2 JP6420236 B2 JP 6420236B2
- Authority
- JP
- Japan
- Prior art keywords
- membrane
- potential
- reservoirs
- film
- electric field
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F3/00—Electrolytic etching or polishing
- C25F3/02—Etching
- C25F3/14—Etching locally
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
- B01D65/02—Membrane cleaning or sterilisation ; Membrane regeneration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/009—After-treatment of organic or inorganic membranes with wave-energy, particle-radiation or plasma
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C1/00—Manufacture or treatment of devices or systems in or on a substrate
- B81C1/00015—Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
- B81C1/00023—Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems without movable or flexible elements
- B81C1/00087—Holes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F7/00—Constructional parts, or assemblies thereof, of cells for electrolytic removal of material from objects; Servicing or operating
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01B—MEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
- G01B7/00—Measuring arrangements characterised by the use of electric or magnetic techniques
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0095—Semiconductive materials
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/48—Biological material, e.g. blood, urine; Haemocytometers
- G01N33/483—Physical analysis of biological material
- G01N33/487—Physical analysis of biological material of liquid biological material
- G01N33/48707—Physical analysis of biological material of liquid biological material by electrical means
- G01N33/48721—Investigating individual macromolecules, e.g. by translocation through nanopores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
- B01D2321/22—Electrical effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/42—Details of membrane preparation apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/0282—Dynamic pores-stimuli responsive membranes, e.g. thermoresponsive or pH-responsive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B2203/00—Basic microelectromechanical structures
- B81B2203/03—Static structures
- B81B2203/0353—Holes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y15/00—Nanotechnology for interacting, sensing or actuating, e.g. quantum dots as markers in protein assays or molecular motors
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Immunology (AREA)
- Biomedical Technology (AREA)
- Manufacturing & Machinery (AREA)
- Electrochemistry (AREA)
- Medicinal Chemistry (AREA)
- Food Science & Technology (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Hematology (AREA)
- Molecular Biology (AREA)
- Urology & Nephrology (AREA)
- Plasma & Fusion (AREA)
- Nanotechnology (AREA)
- Biophysics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Testing Of Short-Circuits, Discontinuities, Leakage, Or Incorrect Line Connections (AREA)
- Steroid Compounds (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261643651P | 2012-05-07 | 2012-05-07 | |
| US61/643,651 | 2012-05-07 | ||
| US201361781081P | 2013-03-14 | 2013-03-14 | |
| US61/781,081 | 2013-03-14 | ||
| PCT/IB2013/000891 WO2013167955A1 (en) | 2012-05-07 | 2013-05-07 | Fabrication of nanopores using high electric fields |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018108930A Division JP2018187626A (ja) | 2012-05-07 | 2018-06-06 | 高電界を用いたナノポアの作製 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015525114A JP2015525114A (ja) | 2015-09-03 |
| JP2015525114A5 JP2015525114A5 (enExample) | 2017-12-28 |
| JP6420236B2 true JP6420236B2 (ja) | 2018-11-07 |
Family
ID=49550214
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015510884A Active JP6298450B2 (ja) | 2012-05-07 | 2013-05-07 | 固体ナノポアの大きさを制御するための方法 |
| JP2015510885A Active JP6420236B2 (ja) | 2012-05-07 | 2013-05-07 | 高電界を用いたナノポアの作製 |
| JP2018108930A Pending JP2018187626A (ja) | 2012-05-07 | 2018-06-06 | 高電界を用いたナノポアの作製 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015510884A Active JP6298450B2 (ja) | 2012-05-07 | 2013-05-07 | 固体ナノポアの大きさを制御するための方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018108930A Pending JP2018187626A (ja) | 2012-05-07 | 2018-06-06 | 高電界を用いたナノポアの作製 |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US9777389B2 (enExample) |
| EP (2) | EP2846901B1 (enExample) |
| JP (3) | JP6298450B2 (enExample) |
| KR (2) | KR102065745B1 (enExample) |
| CN (2) | CN104411386B (enExample) |
| AU (2) | AU2013257756B2 (enExample) |
| BR (2) | BR112014027829B1 (enExample) |
| CA (2) | CA2872600C (enExample) |
| ES (2) | ES2629952T3 (enExample) |
| MX (2) | MX353370B (enExample) |
| SG (3) | SG11201407249XA (enExample) |
| WO (2) | WO2013167952A1 (enExample) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2014228529B8 (en) * | 2013-03-15 | 2018-06-14 | President And Fellows Of Harvard College | Fabrication of nanopores in atomically-thin membranes by ultra-short electrical pulsing |
| WO2015097765A1 (ja) | 2013-12-25 | 2015-07-02 | 株式会社日立製作所 | 穴形成方法、測定装置及びチップセット |
| JP6209122B2 (ja) * | 2014-04-02 | 2017-10-04 | 株式会社日立ハイテクノロジーズ | 孔形成方法及び測定装置 |
| DE102014111984B3 (de) * | 2014-08-21 | 2016-01-21 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Fluidische Gigaohm-Dichtung für Transmembranproteinmessungen |
| US11009498B2 (en) | 2014-12-01 | 2021-05-18 | Cornell University | Nanopore-containing substrates with aligned nanoscale electronic elements and methods of making and using same |
| CA2970627C (en) | 2014-12-19 | 2022-08-09 | The University Of Ottawa | Integrating nanopore sensors within microfluidic channel arrays using controlled breakdown |
| SG11201706587TA (en) * | 2015-02-24 | 2017-09-28 | Univ Ottawa | Localizing nanopore fabrication on a membrane by laser illumination during controlled breakdown |
| CN104694649A (zh) * | 2015-03-10 | 2015-06-10 | 北京大学 | 一种核酸分子低穿孔速度的纳米孔测序方法及其专用的纳米孔器件 |
| EP3067693A1 (en) | 2015-03-12 | 2016-09-14 | Ecole Polytechnique Federale de Lausanne (EPFL) | Nanopore forming method and uses thereof |
| EP3268736B1 (en) | 2015-03-12 | 2021-08-18 | Ecole Polytechnique Fédérale de Lausanne (EPFL) | Nanopore forming method and uses thereof |
| RU2712610C2 (ru) | 2015-04-03 | 2020-01-29 | Эбботт Лэборетриз | Устройства и способы для анализа образца |
| CN107690582B (zh) | 2015-04-03 | 2023-10-20 | 雅培制药有限公司 | 用于样品分析的装置和方法 |
| GB201508669D0 (en) * | 2015-05-20 | 2015-07-01 | Oxford Nanopore Tech Ltd | Methods and apparatus for forming apertures in a solid state membrane using dielectric breakdown |
| WO2017004463A1 (en) | 2015-07-01 | 2017-01-05 | Abbott Laboratories | Devices and methods for sample analysis |
| CN109863391B (zh) | 2016-10-05 | 2021-11-05 | 雅培实验室 | 用于样品分析的装置和方法 |
| US12319960B2 (en) | 2016-10-12 | 2025-06-03 | Roche Sequencing Solutions, Inc. | Nanopore voltage methods |
| GB2570849B (en) * | 2016-12-09 | 2022-03-16 | Hitachi High Tech Corp | Nanopore-forming method, nanopore-forming device and biomolecule measurement device |
| GB2573433B (en) * | 2017-01-10 | 2022-05-25 | Hitachi High Tech Corp | Current measurement device and current measurement method using nanopore |
| EP3369474A1 (en) * | 2017-03-01 | 2018-09-05 | Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung GmbH | Isoporous block copolymer membranes in flat sheet geometry |
| NO20170513A1 (en) * | 2017-03-29 | 2018-06-04 | Condalign As | A method for forming av body comprising at least one through-going passage |
| WO2018201038A1 (en) | 2017-04-28 | 2018-11-01 | The University Of Ottawa | Controlling translocating molecules through a nanopore |
| US11224842B2 (en) | 2017-05-17 | 2022-01-18 | The Royal Institution For The Advancement Of Learning / Mcgill University | Method and apparatus for making a nanopore in a membrane using an electric field applied via a conductive tip |
| US10752496B2 (en) | 2017-09-22 | 2020-08-25 | Applied Materials, Inc. | Pore formation in a substrate |
| US10830756B2 (en) | 2017-09-22 | 2020-11-10 | Applied Materials, Inc. | Method to create a free-standing membrane for biological applications |
| US10618805B2 (en) | 2017-09-22 | 2020-04-14 | Applied Materials, Inc. | Method to reduce pore diameter using atomic layer deposition and etching |
| JP6975609B2 (ja) * | 2017-10-19 | 2021-12-01 | 株式会社日立製作所 | 親水性保持基材、計測装置、デバイスおよび親水性保持方法 |
| JP6959121B2 (ja) * | 2017-12-05 | 2021-11-02 | 株式会社日立ハイテク | 孔形成方法及び孔形成装置 |
| WO2019109253A1 (zh) * | 2017-12-05 | 2019-06-13 | 清华大学 | 调控固态纳米孔系统中固态纳米孔有效尺寸的方法 |
| CN108279312B (zh) * | 2018-03-08 | 2021-06-01 | 冯建东 | 一种基于纳米孔的蛋白质组学分析装置及血清检测方法及应用 |
| US11454624B2 (en) | 2018-09-28 | 2022-09-27 | Ofer Wilner | Nanopore technologies |
| CN113260449B (zh) * | 2018-12-11 | 2023-09-29 | 豪夫迈·罗氏有限公司 | 用于膜中自限性蛋白质孔插入的系统和方法 |
| JP7174614B2 (ja) * | 2018-12-12 | 2022-11-17 | 株式会社日立製作所 | ナノポア形成方法及び分析方法 |
| US11981557B2 (en) | 2020-04-17 | 2024-05-14 | Southern Methodist University | Ohmic nanopore fabrication and real-time cleaning |
| WO2021260587A1 (en) * | 2020-06-23 | 2021-12-30 | The University Of Ottawa | Improved techniques for nanopore enlargement and formation |
| US12429449B2 (en) * | 2020-07-31 | 2025-09-30 | Hitachi High-Tech Corporation | Biomolecule analysis method, biomolecule analyzing reagent, and biomolecule analysis device |
| JP7440375B2 (ja) * | 2020-08-19 | 2024-02-28 | 株式会社日立製作所 | 孔形成方法及び孔形成装置 |
| JP7543174B2 (ja) * | 2021-03-03 | 2024-09-02 | 株式会社日立製作所 | ポア形成方法、およびポア形成装置 |
| CN116536745B (zh) * | 2022-05-20 | 2025-02-07 | 武汉铢寸科技有限公司 | 在膜中制造纳米孔的方法、装置及叠加电场的生成装置 |
| WO2024238505A1 (en) * | 2023-05-12 | 2024-11-21 | Massachusetts Institute Of Technology | Systems and methods for cascaded compression of the size distribution of zero-dimensional nanostructures |
| WO2025111147A1 (en) | 2023-11-21 | 2025-05-30 | Abbott Laboratories | Two-dimensional matrix droplet array |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02173278A (ja) * | 1988-12-26 | 1990-07-04 | Hitachi Ltd | 微細加工方法及びその装置 |
| JPH09316692A (ja) * | 1996-05-30 | 1997-12-09 | Fine Ceramics Center | 微細孔を有するアルミナ膜及びその製造法 |
| JP3902883B2 (ja) * | 1998-03-27 | 2007-04-11 | キヤノン株式会社 | ナノ構造体及びその製造方法 |
| US7258838B2 (en) * | 1999-06-22 | 2007-08-21 | President And Fellows Of Harvard College | Solid state molecular probe device |
| DE10044565B4 (de) | 2000-09-08 | 2005-06-30 | Gesellschaft für Schwerionenforschung mbH | Elektrolytische Zelle, deren Verwendung und Verfahren zum Ätzen einer in der Zelle eingespannten Membran sowie Verfahren zum Schalten einer geätzten, in der Zelle eingespannten Membran von Durchgang auf Sperrung und umgekehrt |
| JP2003001462A (ja) | 2000-09-13 | 2003-01-08 | Hamamatsu Photonics Kk | レーザ加工装置 |
| US6592742B2 (en) * | 2001-07-13 | 2003-07-15 | Applied Materials Inc. | Electrochemically assisted chemical polish |
| US6706203B2 (en) * | 2001-10-30 | 2004-03-16 | Agilent Technologies, Inc. | Adjustable nanopore, nanotome, and nanotweezer |
| EP1592641B1 (en) * | 2003-02-03 | 2018-03-07 | President and Fellows of Harvard College | Controlled fabrication of gaps in electrically conducting structures |
| AU2004311842C1 (en) * | 2003-12-24 | 2011-01-06 | The Regents Of The University Of California | Tissue ablation with irreversible electroporation |
| EP1721657A1 (en) * | 2005-05-13 | 2006-11-15 | SONY DEUTSCHLAND GmbH | A method of fabricating a polymeric membrane having at least one pore |
| JP4925670B2 (ja) * | 2006-01-16 | 2012-05-09 | 埼玉県 | チタン系金属製品の製造方法 |
| US7777505B2 (en) | 2006-05-05 | 2010-08-17 | University Of Utah Research Foundation | Nanopore platforms for ion channel recordings and single molecule detection and analysis |
| US7849581B2 (en) | 2006-05-05 | 2010-12-14 | University Of Utah Research Foundation | Nanopore electrode, nanopore membrane, methods of preparation and surface modification, and use thereof |
| DE102006035072B4 (de) | 2006-07-28 | 2009-03-12 | Westfälische Wilhelms-Universität Münster | Vorrichtung und Verfahren zum Erfassen von Partikeln mit Pipette und Nanopore |
| KR101521990B1 (ko) * | 2007-04-04 | 2015-05-20 | 더 리젠츠 오브 더 유니버시티 오브 캘리포니아 | 나노포어 사용을 위한 조성물, 장치, 시스템 및 방법 |
| FR2927169B1 (fr) * | 2008-02-05 | 2013-01-11 | Commissariat Energie Atomique | Procede de fonctionnalisation de la surface d'un pore |
| US20100122907A1 (en) | 2008-05-06 | 2010-05-20 | Government of the United States of America, | Single molecule mass or size spectrometry in solution using a solitary nanopore |
| ATE535800T1 (de) * | 2009-04-03 | 2011-12-15 | Nxp Bv | Sensorvorrichtung und verfahren zu dessen herstellung |
| EP3196645B1 (en) | 2009-09-18 | 2019-06-19 | President and Fellows of Harvard College | Bare single-layer graphene membrane having a nanopore enabling high-sensitivity molecular detection and analysis |
| EP2504082A4 (en) | 2009-11-25 | 2016-11-09 | Univ Sydney | MEMBRANE AND MEMBRANE SEPARATION SYSTEM |
| DE102010025968B4 (de) * | 2010-07-02 | 2016-06-02 | Schott Ag | Erzeugung von Mikrolöchern |
| US9422154B2 (en) * | 2010-11-02 | 2016-08-23 | International Business Machines Corporation | Feedback control of dimensions in nanopore and nanofluidic devices |
| KR20120133653A (ko) * | 2011-05-31 | 2012-12-11 | 삼성전자주식회사 | 나노 센서, 이의 제조 방법 및 이를 사용하여 표적 분자를 검출하는 방법 |
| AU2014228529B8 (en) | 2013-03-15 | 2018-06-14 | President And Fellows Of Harvard College | Fabrication of nanopores in atomically-thin membranes by ultra-short electrical pulsing |
-
2013
- 2013-05-07 WO PCT/IB2013/000884 patent/WO2013167952A1/en not_active Ceased
- 2013-05-07 AU AU2013257756A patent/AU2013257756B2/en not_active Ceased
- 2013-05-07 EP EP13787360.0A patent/EP2846901B1/en active Active
- 2013-05-07 CA CA2872600A patent/CA2872600C/en active Active
- 2013-05-07 KR KR1020147033950A patent/KR102065745B1/ko active Active
- 2013-05-07 SG SG11201407249XA patent/SG11201407249XA/en unknown
- 2013-05-07 AU AU2013257759A patent/AU2013257759B2/en not_active Ceased
- 2013-05-07 CN CN201380036310.2A patent/CN104411386B/zh active Active
- 2013-05-07 WO PCT/IB2013/000891 patent/WO2013167955A1/en not_active Ceased
- 2013-05-07 CN CN201380036177.0A patent/CN104662209B/zh active Active
- 2013-05-07 US US14/399,071 patent/US9777389B2/en active Active
- 2013-05-07 ES ES13787360.0T patent/ES2629952T3/es active Active
- 2013-05-07 KR KR1020147033949A patent/KR102065754B1/ko active Active
- 2013-05-07 BR BR112014027829-6A patent/BR112014027829B1/pt not_active IP Right Cessation
- 2013-05-07 BR BR112014027873A patent/BR112014027873B8/pt not_active IP Right Cessation
- 2013-05-07 JP JP2015510884A patent/JP6298450B2/ja active Active
- 2013-05-07 SG SG11201407252UA patent/SG11201407252UA/en unknown
- 2013-05-07 ES ES13787530.8T patent/ES2630064T3/es active Active
- 2013-05-07 MX MX2014013410A patent/MX353370B/es active IP Right Grant
- 2013-05-07 US US14/399,091 patent/US9777390B2/en active Active
- 2013-05-07 MX MX2014013412A patent/MX357200B/es active IP Right Grant
- 2013-05-07 JP JP2015510885A patent/JP6420236B2/ja active Active
- 2013-05-07 SG SG10201606334XA patent/SG10201606334XA/en unknown
- 2013-05-07 CA CA2872602A patent/CA2872602C/en active Active
- 2013-05-07 EP EP13787530.8A patent/EP2847367B1/en active Active
-
2018
- 2018-06-06 JP JP2018108930A patent/JP2018187626A/ja active Pending
Also Published As
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