JP6255882B2 - 化粧シート - Google Patents
化粧シート Download PDFInfo
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- JP6255882B2 JP6255882B2 JP2013215306A JP2013215306A JP6255882B2 JP 6255882 B2 JP6255882 B2 JP 6255882B2 JP 2013215306 A JP2013215306 A JP 2013215306A JP 2013215306 A JP2013215306 A JP 2013215306A JP 6255882 B2 JP6255882 B2 JP 6255882B2
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- 239000002245 particle Substances 0.000 claims description 36
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- 229920003002 synthetic resin Polymers 0.000 claims description 17
- 239000000057 synthetic resin Substances 0.000 claims description 17
- 239000004606 Fillers/Extenders Substances 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 8
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- 239000011347 resin Substances 0.000 description 19
- -1 polyethylene Polymers 0.000 description 16
- 239000000463 material Substances 0.000 description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
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- 101001117010 Homo sapiens Pericentrin Proteins 0.000 description 2
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- 102100024315 Pericentrin Human genes 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
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- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
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- 239000002023 wood Substances 0.000 description 2
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 1
- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
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- 229920001800 Shellac Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003831 antifriction material Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920005673 polypropylene based resin Polymers 0.000 description 1
- 229920005633 polypropylene homopolymer resin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000874 polytetramethylene terephthalate Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000012508 resin bead Substances 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Description
その後、この絵柄模様層3の上に表面保護層5としてアクリル系樹脂「G125HV」(DICグラフィックス(株)製)を用い、これに無機粒子あるいは合成樹脂粒子6として平均粒径40μのアクリルビーズ「AR650MX」(東洋紡績(株)製)を用いて、化粧シート表面の面積比率で10%表出するように表面保護層5の厚みを30μとしてグラビア方法により塗布し、化粧シートを得た。
無機粒子あるいは合成樹脂粒子6として平均粒径40μのアクリルビーズ「AR650MX」(東洋紡績(株)製)の代わりに平均粒径30μのアクリルビーズ「AR650」を用いた以外は実施例2と同様にして化粧シートを得た。表面保護層5の反射光は5%となった。
無機粒子あるいは合成樹脂粒子6として平均粒径40μのアクリルビーズ「AR650MX」(東洋紡績(株)製)の代わりに平均粒径100μのアクリルビーズ「AR650
L」を用いた以外は実施例2と同様にして化粧シートを得た。表面保護層5の反射光は5%となった。
以上の実施例1〜4、比較例1、比較例2に対し、以下に示す性能評価を行なった。
被験者10名に表面を指で触らせ、表面のざらつき具合を評価した。板ガラスのような平滑な表面を×、木の板の表面に近く感じるものを◎として、×、△、○、◎の4段階で評価し最も多かった評価し、平均をとった。
被験者10名に目視のみで表面が立体的に見えるかどうかを評価した。板ガラスのような平滑な表面を×、木の板の表面に近く感じるものを◎として、×、△、○、◎の4段階で評価し最も多かった評価し、平均をとった。
グラビア印刷機にて表面保護層5を塗工する際、表面の状態を目視にて評価した。被験者10名に目視のみで版の形状どおりに均質に塗れているものを◎、版の形状になるスジ、ムラなどが発生しているものを×として評価し、平均をとった。
以上の結果を表1に示す。
2…着色層
3…絵柄模様層
4…艶消し層
5…表面保護層
6…無機粒子あるいは合成樹脂粒子
Claims (2)
- 基材上に着色層およびまたは絵柄模様層を有し、最表面に表面保護層を有する化粧シートにおいて、前記表面保護層に、平均粒径40μm〜80μmの無機粒子あるいは合成樹脂粒子を含有し、前記無機粒子あるいは合成樹脂粒子が、化粧シート表面の面積比率で10〜20%表出し、前記化粧シート表面の静摩擦係数が0.11〜0.15であることを特徴とする化粧シート。
- 前記表面保護層の60°反射光が5〜10%であり、前記表面保護層と絵柄模様層との間に、艶消し剤として、5〜20μmの粗粒の体質顔料を含有する、60°反射光が1〜4%である艶消し層を追加して設けてなること特徴とする請求項1に記載の化粧シート。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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JP2013215306A JP6255882B2 (ja) | 2013-10-16 | 2013-10-16 | 化粧シート |
Applications Claiming Priority (1)
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JP2013215306A JP6255882B2 (ja) | 2013-10-16 | 2013-10-16 | 化粧シート |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015077709A JP2015077709A (ja) | 2015-04-23 |
JP6255882B2 true JP6255882B2 (ja) | 2018-01-10 |
Family
ID=53009603
Family Applications (1)
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JP2013215306A Active JP6255882B2 (ja) | 2013-10-16 | 2013-10-16 | 化粧シート |
Country Status (1)
Country | Link |
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JP (1) | JP6255882B2 (ja) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10213982B2 (en) * | 2015-07-24 | 2019-02-26 | Toppan Printing Co., Ltd. | Decorative sheet and decorative panel |
JP6763149B2 (ja) * | 2016-02-04 | 2020-09-30 | 凸版印刷株式会社 | 化粧シート、及び化粧板 |
JP6763150B2 (ja) * | 2016-02-04 | 2020-09-30 | 凸版印刷株式会社 | 化粧シート、及び化粧板 |
JP6565419B2 (ja) * | 2015-07-24 | 2019-08-28 | 凸版印刷株式会社 | 化粧シート、及び化粧板 |
JP2017065261A (ja) * | 2015-09-28 | 2017-04-06 | 大日本印刷株式会社 | 化粧シート、化粧板及び加飾樹脂成形品 |
JP2017154388A (ja) * | 2016-03-02 | 2017-09-07 | 凸版印刷株式会社 | 化粧シート、化粧板 |
JP2017159507A (ja) * | 2016-03-08 | 2017-09-14 | 凸版印刷株式会社 | 化粧シート及び化粧板 |
JP6972535B2 (ja) * | 2016-11-01 | 2021-11-24 | 凸版印刷株式会社 | 化粧シート及び化粧板 |
JP6838377B2 (ja) * | 2016-12-13 | 2021-03-03 | 凸版印刷株式会社 | 化粧シート及び化粧板 |
JP2021130260A (ja) * | 2020-02-20 | 2021-09-09 | 凸版印刷株式会社 | 化粧シート及び化粧板 |
JP2021181174A (ja) * | 2020-05-18 | 2021-11-25 | 凸版印刷株式会社 | 化粧シート及び化粧板 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004262105A (ja) * | 2003-03-03 | 2004-09-24 | Toppan Printing Co Ltd | ピーチスキン調化粧シート |
JP4694944B2 (ja) * | 2005-10-19 | 2011-06-08 | サカエグラビヤ印刷株式会社 | 化粧シート |
JP5003086B2 (ja) * | 2006-09-29 | 2012-08-15 | 大日本印刷株式会社 | 化粧シート |
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2013
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