JP6189325B2 - エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 - Google Patents
エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 Download PDFInfo
- Publication number
- JP6189325B2 JP6189325B2 JP2014548874A JP2014548874A JP6189325B2 JP 6189325 B2 JP6189325 B2 JP 6189325B2 JP 2014548874 A JP2014548874 A JP 2014548874A JP 2014548874 A JP2014548874 A JP 2014548874A JP 6189325 B2 JP6189325 B2 JP 6189325B2
- Authority
- JP
- Japan
- Prior art keywords
- independently
- atom
- hydrocarbyl
- heterohydrocarbyl
- unsubstituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161577720P | 2011-12-20 | 2011-12-20 | |
| US61/577,720 | 2011-12-20 | ||
| US201261731891P | 2012-11-30 | 2012-11-30 | |
| US61/731,891 | 2012-11-30 | ||
| PCT/US2012/070859 WO2013096573A1 (en) | 2011-12-20 | 2012-12-20 | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2015500920A JP2015500920A (ja) | 2015-01-08 |
| JP6189325B2 true JP6189325B2 (ja) | 2017-08-30 |
Family
ID=47559697
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014548874A Active JP6189325B2 (ja) | 2011-12-20 | 2012-12-20 | エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9422383B2 (cg-RX-API-DMAC10.html) |
| EP (1) | EP2794693B1 (cg-RX-API-DMAC10.html) |
| JP (1) | JP6189325B2 (cg-RX-API-DMAC10.html) |
| KR (1) | KR101989206B1 (cg-RX-API-DMAC10.html) |
| CN (1) | CN104169313B (cg-RX-API-DMAC10.html) |
| BR (1) | BR112014014855B1 (cg-RX-API-DMAC10.html) |
| ES (1) | ES2835807T3 (cg-RX-API-DMAC10.html) |
| IN (1) | IN2014CN04444A (cg-RX-API-DMAC10.html) |
| WO (1) | WO2013096573A1 (cg-RX-API-DMAC10.html) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013096573A1 (en) | 2011-12-20 | 2013-06-27 | Dow Global Technologies Llc | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
| JP5946331B2 (ja) * | 2012-06-01 | 2016-07-06 | 三井化学株式会社 | エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット |
| US10160819B2 (en) * | 2012-11-30 | 2018-12-25 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene based compositions |
| JP6393693B2 (ja) * | 2012-12-27 | 2018-09-19 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合のための触媒系 |
| US9534070B2 (en) | 2013-01-18 | 2017-01-03 | Dow Global Technologies Llc | Polymerization processes for high molecular weight polymers |
| BR112016027987B1 (pt) * | 2014-05-31 | 2022-04-19 | Bridgestone Corporation | Catalisador complexo metálico, métodos de polimerização utilizando os mesmos e seus produtos de polímero |
| MY184826A (en) | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| EP3227304B1 (en) * | 2014-12-04 | 2020-01-29 | Dow Global Technologies LLC | Five-coordinate bis-phenylphenoxy catalysts for the preparation of ethylene-based polymers |
| CN107108991B (zh) * | 2014-12-29 | 2020-04-14 | 陶氏环球技术有限责任公司 | 形成乙烯/α-烯烃互聚物的方法 |
| WO2016109265A1 (en) | 2014-12-29 | 2016-07-07 | Dow Global Technologies Llc | Process to form oil containing ethylene-based polymers |
| BR112017020525B1 (pt) * | 2015-03-31 | 2022-07-19 | Dow Global Technologies Llc | Processo para formar uma composição de polímero |
| JP6815333B2 (ja) * | 2015-05-28 | 2021-01-20 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/アルファ−オレフィンインターポリマーを形成する方法 |
| CA2996616C (en) | 2015-09-02 | 2023-09-26 | Dow Global Technologies Llc | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| EP3344694B1 (en) | 2015-09-02 | 2022-05-18 | Dow Global Technologies LLC | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| CA3003170C (en) * | 2015-10-29 | 2023-09-12 | Dow Global Technologies Llc | Crosslinkable polymeric compositions for flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| WO2017206008A1 (en) * | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymer |
| WO2017206009A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymers compositions |
| CN109563326A (zh) | 2016-06-30 | 2019-04-02 | 陶氏环球技术有限责任公司 | 基于乙烯/α-烯烃/多烯的组合物 |
| WO2018005922A1 (en) | 2016-06-30 | 2018-01-04 | Dow Global Technologies Llc | Ethylene/alpha-olefin/polyene interpolymers and compositions containing the same |
| CN109641989B (zh) | 2016-07-13 | 2022-05-03 | 埃克森美孚化学专利公司 | 双金属茂催化剂共聚物组合物 |
| WO2018013284A2 (en) | 2016-07-13 | 2018-01-18 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| US10822440B2 (en) | 2016-07-14 | 2020-11-03 | Exxonmobil Chemical Patents Inc. | Dual metallocene-catalyzed bimodal copolymer compositions |
| US10221260B2 (en) | 2016-07-29 | 2019-03-05 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| JP6957596B2 (ja) * | 2016-07-29 | 2021-11-02 | ダウ グローバル テクノロジーズ エルエルシー | 多峰性エラストマー生成用混合触媒系 |
| WO2018022279A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| WO2018119570A1 (en) * | 2016-12-26 | 2018-07-05 | Dow Global Technologies Llc | Ethylene/a-olefin/nonconjugated polyene interpolymer compositions and articles prepared from the same |
| BR112019020417B1 (pt) * | 2017-03-31 | 2023-04-04 | Dow Global Technologies Llc | Sistema catalisador e processo de polimerização para produzir um polímero à base de etileno |
| US11390704B2 (en) | 2017-06-14 | 2022-07-19 | Exxonmobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
| EP3672811A1 (en) | 2017-08-24 | 2020-07-01 | Dow Global Technologies LLC | Ethylene/c5-c10 alpha-olefin/ polyene interpolymers |
| EP3752560B1 (en) * | 2018-02-14 | 2024-09-25 | Dow Global Technologies LLC | Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance |
| WO2020046597A1 (en) | 2018-08-29 | 2020-03-05 | Exxonmobil Chemical Patents Inc. | Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes |
| KR102538844B1 (ko) * | 2018-12-21 | 2023-06-01 | 주식회사 엘지화학 | 방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법 |
| WO2020184421A1 (ja) | 2019-03-12 | 2020-09-17 | 三井化学株式会社 | オレフィン系樹脂、その架橋物およびそれらの製造方法 |
| WO2020198918A1 (en) * | 2019-03-29 | 2020-10-08 | Dow Global Technologies Llc | Oil-extended pellet form ethylene alpha-olefin diene interpolymers for thermoplastic vulcanizates |
| CN113874439B (zh) * | 2019-04-30 | 2024-03-29 | 陶氏环球技术有限责任公司 | 乙烯/丙烯/非共轭二烯互聚物组合物 |
| WO2021061580A1 (en) | 2019-09-24 | 2021-04-01 | Dow Global Technologies Llc | Polymer compositions for extruded profiles |
| CN114466891B (zh) | 2019-09-24 | 2024-06-18 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃/多烯互聚物组合物 |
| KR20220066152A (ko) | 2019-09-24 | 2022-05-23 | 다우 글로벌 테크놀로지스 엘엘씨 | 우수한 전기적 특성 및 기계적 특성을 갖는 중합체 조성물 |
| JP2023508667A (ja) * | 2019-12-27 | 2023-03-03 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/ブテンマルチブロックコポリマー及びその製造のためのプロセス |
| JP2021147420A (ja) * | 2020-03-16 | 2021-09-27 | 三井化学株式会社 | オレフィン・環状オレフィン共重合体の製造方法 |
| JP7762663B2 (ja) * | 2020-03-27 | 2025-10-30 | ダウ グローバル テクノロジーズ エルエルシー | 長鎖分岐エチレン系ポリマーを生成するためのプロセス |
| WO2021202091A1 (en) | 2020-03-30 | 2021-10-07 | Exxonmobil Chemical Patents Inc. | Comb-block copolymers and methods thereof |
| CN116261572A (zh) * | 2020-12-28 | 2023-06-13 | 沙特基础工业爱思开Nexlene私人有限公司 | 金属-配体配合物、包含其的用于制备基于乙烯的聚合物的催化剂组合物、以及使用其的基于乙烯的聚合物的制备方法 |
| KR20240074467A (ko) * | 2022-11-21 | 2024-05-28 | 롯데케미칼 주식회사 | 에틸렌-알파-올레핀 공중합체 제조방법 |
| WO2025117273A1 (en) | 2023-12-01 | 2025-06-05 | ExxonMobil Technology and Engineering Company | Support-bound activators, supported catalyst systems, and processes for use thereof |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
| US6680361B1 (en) * | 1998-11-02 | 2004-01-20 | Dupont Dow Elastomers Llc | Shear thinning ethylene/α-olefin interpolymers and their preparation |
| CA2483192A1 (en) * | 2002-04-24 | 2003-11-06 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, complexes, catalysts and processes for polymerizing and poymers therefrom |
| US20080051537A1 (en) | 2004-08-09 | 2008-02-28 | Carnahan Edmund M | Supported Bis(Hydroxylarylaryloxy) Catalysts For Manufacture Of Polymers |
| CA2652551A1 (en) | 2006-05-17 | 2007-11-29 | Dow Global Technologies Inc. | Polyolefin solution polymerization process and polymer |
| CN101918463B (zh) | 2007-11-19 | 2012-09-05 | 陶氏环球技术有限责任公司 | 长链支化丙烯-α-烯烃共聚物 |
| EP2328944B1 (en) | 2008-09-16 | 2018-01-24 | Dow Global Technologies LLC | Polymeric compositions and foams, methods of making the same, and articles prepared from the same |
| WO2011002998A1 (en) | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylenic polymer and its use |
| WO2011002986A1 (en) | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylenic polymer and its use |
| SG177650A1 (en) | 2009-07-15 | 2012-03-29 | Dow Global Technologies Llc | Polymer compositions, methods of making the same, and articles prepared from the same |
| KR101865645B1 (ko) * | 2010-08-25 | 2018-06-11 | 다우 글로벌 테크놀로지스 엘엘씨 | 중합성 올레핀의 중합 방법 및 그를 위한 촉매 |
| KR101938440B1 (ko) * | 2011-12-13 | 2019-01-14 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌-프로필렌-디엔 혼성중합체 조성물 |
| WO2013096573A1 (en) | 2011-12-20 | 2013-06-27 | Dow Global Technologies Llc | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
-
2012
- 2012-12-20 WO PCT/US2012/070859 patent/WO2013096573A1/en not_active Ceased
- 2012-12-20 BR BR112014014855-4A patent/BR112014014855B1/pt active IP Right Grant
- 2012-12-20 EP EP12815929.0A patent/EP2794693B1/en active Active
- 2012-12-20 IN IN4444CHN2014 patent/IN2014CN04444A/en unknown
- 2012-12-20 ES ES12815929T patent/ES2835807T3/es active Active
- 2012-12-20 US US14/367,478 patent/US9422383B2/en active Active
- 2012-12-20 CN CN201280063427.5A patent/CN104169313B/zh active Active
- 2012-12-20 JP JP2014548874A patent/JP6189325B2/ja active Active
- 2012-12-20 KR KR1020147016448A patent/KR101989206B1/ko active Active
Also Published As
| Publication number | Publication date |
|---|---|
| IN2014CN04444A (cg-RX-API-DMAC10.html) | 2015-09-04 |
| CN104169313B (zh) | 2016-09-21 |
| KR20140107263A (ko) | 2014-09-04 |
| JP2015500920A (ja) | 2015-01-08 |
| US9422383B2 (en) | 2016-08-23 |
| WO2013096573A1 (en) | 2013-06-27 |
| BR112014014855A2 (pt) | 2017-06-13 |
| BR112014014855B1 (pt) | 2022-01-11 |
| KR101989206B1 (ko) | 2019-09-24 |
| US20150322185A1 (en) | 2015-11-12 |
| ES2835807T3 (es) | 2021-06-23 |
| EP2794693B1 (en) | 2020-09-23 |
| CN104169313A (zh) | 2014-11-26 |
| EP2794693A1 (en) | 2014-10-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6189325B2 (ja) | エチレン/アルファオレフィン/非共役ポリエン共重合体およびその形成方法 | |
| RU2643149C2 (ru) | Способы полимеризации для высокомолекулярных полиолефинов | |
| KR101688253B1 (ko) | 이중- 또는 다중-헤드 사슬 이동제 및 그의 블록 공중합체의 제조에서의 용도 | |
| JP7523447B2 (ja) | 不飽和ポリオレフィンを含む硬化性組成物 | |
| JP7610511B2 (ja) | テレケリックポリオレフィンおよびこれを調製するための方法 | |
| KR102880619B1 (ko) | 텔레켈릭 폴리올레핀을 포함하는 경화성 조성물 | |
| EP3827033B1 (en) | Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom | |
| KR20190013901A (ko) | 에틸렌/알파-올레핀/다이엔 혼성중합체 | |
| CN111868166A (zh) | 具有改进的长期热老化性能的乙烯/α-烯烃互聚物组合物 | |
| JP6180517B2 (ja) | アルキル化フェノールを使用してエチレン系ポリマーを作製するためのフリーラジカルプロセス | |
| KR102671695B1 (ko) | 우수한 용융 특성을 지닌 폴리프로필렌 수지 및 그 제조 방법 | |
| KR102916971B1 (ko) | 텔레켈릭 폴리올레핀 및 이의 제조 방법 | |
| KR20250118802A (ko) | 폴리에틸렌 조성물 및 이를 포함하는 이축 연신 필름 | |
| KR20220073962A (ko) | 용융 특성이 향상된 폴리프로필렌 중합 방법 및 상기 방법에 의해 제조된 폴리프로필렌 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RD03 | Notification of appointment of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7423 Effective date: 20140617 |
|
| RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20150121 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20150929 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20160721 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160802 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20161101 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20170110 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170510 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20170517 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20170704 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20170802 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6189325 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |