JP6176891B2 - 新規鉄含有アルミノケイ酸塩ゼオライト、ならびにその作製方法および使用方法 - Google Patents

新規鉄含有アルミノケイ酸塩ゼオライト、ならびにその作製方法および使用方法 Download PDF

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JP6176891B2
JP6176891B2 JP2010521012A JP2010521012A JP6176891B2 JP 6176891 B2 JP6176891 B2 JP 6176891B2 JP 2010521012 A JP2010521012 A JP 2010521012A JP 2010521012 A JP2010521012 A JP 2010521012A JP 6176891 B2 JP6176891 B2 JP 6176891B2
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iron
zeolite
containing aluminosilicate
silica
aluminosilicate zeolite
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JP2010536692A5 (OSRAM
JP2010536692A (ja
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ホン−シン・リ
ビョルン・モデン
ウィリアム・イー・コーミアー
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ピーキュー コーポレイション
ピーキュー コーポレイション
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/14—Iron group metals or copper
    • B01J29/146—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • B01J29/24—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/26—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/00—Catalysts comprising molecular sieves
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B01J29/66—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing iron group metals, noble metals or copper
    • B01J29/68—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B01J29/69—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/7215—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/7615—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/7815—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/88—Ferrosilicates; Ferroaluminosilicates
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    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
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    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
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    • B01J37/02—Impregnation, coating or precipitation
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    • B01J37/0246—Coatings comprising a zeolite
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • F01N3/0222—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
JP2010521012A 2007-08-13 2008-08-13 新規鉄含有アルミノケイ酸塩ゼオライト、ならびにその作製方法および使用方法 Active JP6176891B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US93543607P 2007-08-13 2007-08-13
US60/935,436 2007-08-13
PCT/US2008/009653 WO2009023202A2 (en) 2007-08-13 2008-08-13 Novel iron-containing aluminosilicate zeolites and methods of making and using same

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JP2015107726A Division JP2015205270A (ja) 2007-08-13 2015-05-27 新規鉄含有アルミノケイ酸塩ゼオライト、ならびにその作製方法および使用方法

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JP2010536692A JP2010536692A (ja) 2010-12-02
JP2010536692A5 JP2010536692A5 (OSRAM) 2014-06-26
JP6176891B2 true JP6176891B2 (ja) 2017-08-09

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JP2015107726A Pending JP2015205270A (ja) 2007-08-13 2015-05-27 新規鉄含有アルミノケイ酸塩ゼオライト、ならびにその作製方法および使用方法

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US (2) US8541331B2 (OSRAM)
EP (2) EP2192982A2 (OSRAM)
JP (2) JP6176891B2 (OSRAM)
CN (2) CN102764590B (OSRAM)
WO (1) WO2009023202A2 (OSRAM)

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US7998423B2 (en) 2007-02-27 2011-08-16 Basf Corporation SCR on low thermal mass filter substrates
PL2117707T5 (pl) * 2007-02-27 2019-01-31 Basf Corporation Katalizatory zeolit cha -miedź
US10384162B2 (en) * 2007-03-26 2019-08-20 Pq Corporation High silica chabazite for selective catalytic reduction, methods of making and using same
MX2009011443A (es) 2007-04-26 2010-01-18 Johnson Matthey Plc Catalizadores de reduccion catalitica selectiva de metal de transicion/zeolita.
US20090196812A1 (en) 2008-01-31 2009-08-06 Basf Catalysts Llc Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure
JP5670320B2 (ja) * 2008-06-06 2015-02-18 トタル リサーチ アンド テクノロジー フエリユイ 結晶質メタロシリケートの製造方法
EP2161242A1 (en) * 2008-08-29 2010-03-10 Total Petrochemicals Research Feluy Method for Preparing Crystalline Metalloaluminophosphate (MeAPO) Molecular Sieve from Amorphous Materials
US10583424B2 (en) * 2008-11-06 2020-03-10 Basf Corporation Chabazite zeolite catalysts having low silica to alumina ratios
KR101251499B1 (ko) * 2008-12-05 2013-04-05 오덱(주) 질소 산화물 제거용 제올라이트 촉매, 이의 제조 방법 및 이를 이용한 질소 산화물 제거 방법
CN104876237A (zh) * 2009-06-18 2015-09-02 巴斯夫欧洲公司 生产沸石材料的无有机模板合成方法
US8865121B2 (en) 2009-06-18 2014-10-21 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material
GB2475740B (en) * 2009-11-30 2017-06-07 Johnson Matthey Plc Catalysts for treating transient NOx emissions
US8293198B2 (en) * 2009-12-18 2012-10-23 Basf Corporation Process of direct copper exchange into Na+-form of chabazite molecular sieve, and catalysts, systems and methods
US8293199B2 (en) * 2009-12-18 2012-10-23 Basf Corporation Process for preparation of copper containing molecular sieves with the CHA structure, catalysts, systems and methods
JP5594121B2 (ja) * 2009-12-22 2014-09-24 東ソー株式会社 新規メタロシリケート及び窒素酸化物浄化触媒
WO2011078149A1 (ja) 2009-12-22 2011-06-30 東ソー株式会社 新規メタロシリケート、その製造方法、窒素酸化物浄化触媒、その製造方法、及びそれを用いた窒素酸化物浄化方法
JP5609620B2 (ja) * 2009-12-25 2014-10-22 東ソー株式会社 新規メタロシリケート
US8440586B2 (en) * 2010-02-26 2013-05-14 Corning Incorporated Low pressure drop extruded catalyst filter
JP5882238B2 (ja) * 2010-03-11 2016-03-09 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ ＮＯｘの選択触媒還元のための無秩序なモレキュラーシーブ担体
US9352307B2 (en) * 2010-04-08 2016-05-31 Basf Corporation Cu-CHA/Fe-MFI mixed zeolite catalyst and process for the treatment of NOx in gas streams
CA2795614C (en) * 2010-04-08 2018-03-06 Basf Se Cu-cha/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same
KR101852143B1 (ko) * 2010-05-21 2018-04-25 피큐 코포레이션 ＮＯｘ 환원을 위한 신규한 금속―함유 제올라이트 베타
FR2962923B1 (fr) * 2010-07-22 2015-01-02 Peugeot Citroen Automobiles Sa Composition catalytique et dispositif de traitement des gaz comprenant une telle composition
US8987162B2 (en) 2010-08-13 2015-03-24 Ut-Battelle, Llc Hydrothermally stable, low-temperature NOx reduction NH3-SCR catalyst
US8987161B2 (en) * 2010-08-13 2015-03-24 Ut-Battelle, Llc Zeolite-based SCR catalysts and their use in diesel engine emission treatment
EP2441513B1 (en) * 2010-10-13 2013-08-07 Ibiden Co., Ltd. Honeycomb catalyst body and method for manufacturing honeycomb catalyst body
JP5625735B2 (ja) * 2010-10-22 2014-11-19 東ソー株式会社 高耐熱水性ｓｃｒ触媒及びその製造方法
CN102464326B (zh) * 2010-11-04 2013-10-09 中国石油化工股份有限公司 合成高硅丝光沸石的方法
DE112011103996T8 (de) * 2010-12-02 2013-12-19 Johnson Matthey Public Limited Company Metall-enthaltender Zeolithkatalysator
US20120251422A1 (en) * 2011-04-04 2012-10-04 Pq Corporation Fe-SAPO-34 CATALYST AND METHODS OF MAKING AND USING THE SAME
CN103561865B (zh) * 2011-04-18 2016-09-07 Pq公司 大晶体、不含有机物的菱沸石以及制造和使用其的方法
US9539565B2 (en) 2011-05-17 2017-01-10 Tosoh Corporation B-type iron silicate composition and method for reducing nitrogen oxides
EP2753578B1 (en) * 2011-09-09 2020-07-29 Basf Se Process for the organotemplate-free synthetic production of a zeolitic material using recycled mother liquor
JP5821540B2 (ja) * 2011-11-07 2015-11-24 いすゞ自動車株式会社 尿素ｓｃｒ触媒の製造方法
JP5817522B2 (ja) * 2011-12-28 2015-11-18 いすゞ自動車株式会社 尿素ｓｃｒ触媒の製造方法
JP5970927B2 (ja) * 2012-04-05 2016-08-17 いすゞ自動車株式会社 尿素ｓｃｒ触媒の製造方法
JP5988743B2 (ja) * 2012-07-18 2016-09-07 ユニゼオ株式会社 Ｆｅ（ＩＩ）置換ベータ型ゼオライト、それを含むガス吸着剤及びその製造方法、並びに一酸化窒素及びハイドロカーボンの除去方法
JP6028195B2 (ja) * 2012-07-19 2016-11-16 株式会社ゼオライト・アーティフィシャル ゼオライト金属塩複合体及びその製造方法
JP6127232B2 (ja) * 2012-07-19 2017-05-17 株式会社 Ａｃｒ 抗シンタリング触媒
DK2755764T3 (en) 2012-08-17 2016-11-28 Johnson Matthey Plc Zeolite promoted V / TI / W CATALYST
EP2908946B1 (en) 2012-10-19 2020-09-09 BASF Corporation 8-ring small pore molecular sieve as high temperature scr catalyst
MX2015004814A (es) 2012-10-19 2015-10-22 Basf Corp Tamiz molecular de poro pequeño de 8 anillos con promotor para mejorar el rendimiento a bajas temperaturas.
JP6058433B2 (ja) 2013-03-12 2017-01-11 ユニゼオ株式会社 ハイドロカーボンリフォーマトラップ材及びハイドロカーボンの除去方法
JP6153196B2 (ja) * 2013-06-14 2017-06-28 ユニゼオ株式会社 Ｍｎ＋置換ベータ型ゼオライト、それを含むガス吸着剤及びその製造方法、並びに一酸化窒素の除去方法
EP3074350A4 (en) 2013-11-25 2017-08-09 University Of Idaho Biochar water treatment
GB201421333D0 (en) * 2013-12-02 2015-01-14 Johnson Matthey Plc Mixed template synthesis of high silica cu-cha
US20150231620A1 (en) * 2014-02-19 2015-08-20 Ford Global Technologies, Llc IRON-ZEOLITE CHABAZITE CATALYST FOR USE IN NOx REDUCTION AND METHOD OF MAKING
US20150231617A1 (en) * 2014-02-19 2015-08-20 Ford Global Technologies, Llc Fe-SAPO-34 CATALYST FOR USE IN NOX REDUCTION AND METHOD OF MAKING
JP2017512630A (ja) * 2014-02-28 2017-05-25 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃ Ｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ 低温性能が改善されたｓｃｒ触媒及びその製造ならびに使用方法
US20150290632A1 (en) * 2014-04-09 2015-10-15 Ford Global Technologies, Llc IRON AND COPPER-CONTAINING CHABAZITE ZEOLITE CATALYST FOR USE IN NOx REDUCTION
JP6126141B2 (ja) * 2014-05-30 2017-05-10 トヨタ自動車株式会社 排ガス浄化用触媒の製造方法
WO2016036780A1 (en) 2014-09-03 2016-03-10 Corning Incorporated Exhaust filter with active plugs
JP2018503578A (ja) * 2014-11-14 2018-02-08 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ Ａｆｘゼオライト
CN107406265A (zh) 2015-01-29 2017-11-28 庄信万丰股份有限公司 铁络合物直接引入sapo‑34(cha)类型材料中
CN105032163A (zh) * 2015-07-02 2015-11-11 黄立维 一种从气流中去除氮氧化物和二氧化硫的方法及其装置
WO2017109705A1 (en) * 2015-12-22 2017-06-29 Basf Corporation Process for preparing iron(iii)-exchanged zeolite composition
WO2017134006A1 (en) * 2016-02-01 2017-08-10 Haldor Topsøe A/S Method for the direct synthesis of iron-containing aei-zeolite catalyst
CN105921170A (zh) * 2016-05-03 2016-09-07 新疆大学 用于烟气脱硝的新型纳米级FeZSM-5催化剂的技术方法
KR101679793B1 (ko) * 2016-06-08 2016-11-25 한국건설기술연구원 철성분 함유 다공성 제올라이트의 제조방법 및 이에 의해 제조된 다공성 제올라이트
CN106187595A (zh) * 2016-07-12 2016-12-07 山东胜伟园林科技有限公司 一种基于脱硫石膏的盐碱地改良肥的配方
BR112019001997B1 (pt) * 2016-08-05 2023-04-18 Basf Corporation Artigo de redução catalítica seletiva, sistemas de tratamento de gases de exaustão e método para tratar uma corrente de exaustão
JP2020526388A (ja) * 2017-07-11 2020-08-31 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒およびその使用方法
CN110831695A (zh) * 2017-07-11 2020-02-21 国际壳牌研究有限公司 催化剂和其使用方法
CN107899608B (zh) * 2017-11-24 2020-07-28 中国科学院长春应用化学研究所 一种自支撑金属改性Beta分子筛的制备方法及其在合成异戊二烯中的应用
CN108217681B (zh) * 2018-01-19 2021-07-06 山东齐鲁华信高科有限公司 一种高铁含量的Fe-ZSM-5分子筛的制备方法
US11267717B2 (en) 2018-03-21 2022-03-08 Basf Corporation CHA zeolite material and related method of synthesis
US20190321761A1 (en) * 2018-04-18 2019-10-24 Kohler Co. Filter member and method of making same
JP7176717B2 (ja) * 2018-05-02 2022-11-22 公立大学法人北九州市立大学 ゼオライト構造体・ゼオライト担持白金構造体とゼオライト構造体の製造方法、１，３－ブタジエンの製造方法
CN108751335A (zh) * 2018-05-04 2018-11-06 中山大学 一种光-芬顿体系协同催化氧化降解水环境中抗生素的方法
US11278874B2 (en) * 2018-11-30 2022-03-22 Johnson Matthey Public Limited Company Enhanced introduction of extra-framework metal into aluminosilicate zeolites
GB201900484D0 (en) * 2019-01-14 2019-02-27 Johnson Matthey Catalysts Germany Gmbh Iron-loaded small pore aluminosilicate zeolites and method of making metal loaded small pore aluminosilicate zeolites
CN115788628A (zh) * 2019-01-18 2023-03-14 康明斯排放处理公司 具有增强的抗硫性的经处理的scr催化剂
EP3962644A2 (en) * 2019-04-27 2022-03-09 Sud Chemie India Pvt. Ltd. Methods of preparation of metal exchanged zeolites
BR112022001106A2 (pt) * 2019-08-29 2022-05-03 Basf Corp Método para formar um catalisador de redução catalítica seletiva (scr), zeólito promovido por ferro, composição do catalisador de redução catalítica seletiva (scr), sistema de tratamento de gases de exaustão de motor e método de remoção de óxidos de nitrogênio
EP4061770A1 (en) 2019-11-19 2022-09-28 BASF Corporation Zeolite synthesis
US20240174524A1 (en) * 2022-11-29 2024-05-30 Saudi Arabian Oil Company Method for synthesizing nano-sized zeolite beta
CN118047392A (zh) * 2024-01-08 2024-05-17 黄冈师范学院 一种Fe-Beta分子筛、制备及作为脱硝催化剂的应用

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5185136A (en) * 1985-08-08 1993-02-09 Exxon Research And Engineering Co. Trivalent transition-metal-aluminosilicate hydrocarbon conversion catalysts having mazzite-like structures, ECR-23-T (C-2491)
US4952385A (en) 1987-03-02 1990-08-28 Georgia Tech Research Corp. Ferrisilicate molecular sieve and use as a catalyst
DD281172A5 (de) * 1988-03-28 1990-08-01 Akad Wissenschaften Ddr Zeolithischer katalysator und verfahren zu seiner herstellung
US4961917A (en) 1989-04-20 1990-10-09 Engelhard Corporation Method for reduction of nitrogen oxides with ammonia using promoted zeolite catalysts
JP2659840B2 (ja) * 1990-02-05 1997-09-30 三菱重工業株式会社 窒素酸化物含有排ガスの浄化方法
JPH05305240A (ja) * 1992-04-27 1993-11-19 N E Chemcat Corp 排気ガス浄化用触媒
US5451387A (en) 1994-07-07 1995-09-19 Mobil Oil Corporation Selective catalytic reduction of nitrogen oxides using an iron impregnated zeolite catalyst
US5676912A (en) * 1995-02-22 1997-10-14 Mobil Oil Corporation Process for exhaust gas NOx, CO, and hydrocarbon removal
JP3839565B2 (ja) * 1997-01-20 2006-11-01 日本碍子株式会社 高シリカ珪酸塩系分子篩の合成方法
FR2789911B1 (fr) 1999-02-18 2001-05-04 Grande Paroisse Sa Procede pour abattre simultanement les oxydes nitriques et le protoxyde d'azote dans les gaz qui en contiennent
DE10020100A1 (de) * 2000-04-22 2001-10-31 Dmc2 Degussa Metals Catalysts Verfahren und Katalysator zur Reduktion von Stickoxiden
US6689709B1 (en) 2000-11-15 2004-02-10 Engelhard Corporation Hydrothermally stable metal promoted zeolite beta for NOx reduction
US6914026B2 (en) * 2001-09-07 2005-07-05 Engelhard Corporation Hydrothermally stable metal promoted zeolite beta for NOx reduction
WO2004047960A1 (en) 2002-11-25 2004-06-10 Yara International Asa Method for preparation and activation of multimetallic zeolite catalysts, a catalyst composition and application for n2o abatement
FR2869894B1 (fr) * 2004-05-10 2007-02-23 Inst Francais Du Petrole Methode de synthese de metalloaluminosilicate cristallise par synthese directe
JP4957176B2 (ja) * 2006-10-24 2012-06-20 東ソー株式会社 窒素酸化物浄化触媒及び窒素酸化物浄化方法

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