JP6169215B2 - 塩素バイパスダスト及び排ガスの処理方法 - Google Patents
塩素バイパスダスト及び排ガスの処理方法 Download PDFInfo
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- JP6169215B2 JP6169215B2 JP2016078557A JP2016078557A JP6169215B2 JP 6169215 B2 JP6169215 B2 JP 6169215B2 JP 2016078557 A JP2016078557 A JP 2016078557A JP 2016078557 A JP2016078557 A JP 2016078557A JP 6169215 B2 JP6169215 B2 JP 6169215B2
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- Prior art keywords
- chlorine bypass
- exhaust gas
- dust
- slurry
- solid
- Prior art date
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- 239000000460 chlorine Substances 0.000 title claims description 80
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims description 75
- 229910052801 chlorine Inorganic materials 0.000 title claims description 75
- 239000000428 dust Substances 0.000 title claims description 73
- 238000000034 method Methods 0.000 title claims description 12
- 239000007789 gas Substances 0.000 claims description 75
- 239000002002 slurry Substances 0.000 claims description 55
- 239000004568 cement Substances 0.000 claims description 46
- 239000000706 filtrate Substances 0.000 claims description 14
- 239000000567 combustion gas Substances 0.000 claims description 6
- 230000018044 dehydration Effects 0.000 claims description 4
- 238000006297 dehydration reaction Methods 0.000 claims description 4
- 238000004090 dissolution Methods 0.000 description 48
- 239000007788 liquid Substances 0.000 description 39
- 238000006243 chemical reaction Methods 0.000 description 28
- 239000000843 powder Substances 0.000 description 25
- 229910001385 heavy metal Inorganic materials 0.000 description 16
- 239000011575 calcium Substances 0.000 description 14
- 238000000605 extraction Methods 0.000 description 12
- 238000000926 separation method Methods 0.000 description 12
- 229910052602 gypsum Inorganic materials 0.000 description 11
- 239000010440 gypsum Substances 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- 239000000523 sample Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 150000004683 dihydrates Chemical class 0.000 description 6
- 238000007730 finishing process Methods 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- VVJRSSJSRXEOQL-UHFFFAOYSA-N calcium;potassium;sulfuric acid;hydrate Chemical compound O.[K].[K].[Ca].OS(O)(=O)=O.OS(O)(=O)=O VVJRSSJSRXEOQL-UHFFFAOYSA-N 0.000 description 5
- 238000006477 desulfuration reaction Methods 0.000 description 5
- 230000023556 desulfurization Effects 0.000 description 5
- 238000003672 processing method Methods 0.000 description 5
- 229940043430 calcium compound Drugs 0.000 description 4
- 150000001674 calcium compounds Chemical class 0.000 description 4
- 150000001805 chlorine compounds Chemical class 0.000 description 4
- 238000009434 installation Methods 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000004065 wastewater treatment Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/80—Semi-solid phase processes, i.e. by using slurries
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/16—Waste materials; Refuse from building or ceramic industry
- C04B18/162—Cement kiln dust; Lime kiln dust
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/43—Heat treatment, e.g. precalcining, burning, melting; Cooling
- C04B7/436—Special arrangements for treating part or all of the cement kiln dust
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/60—Methods for eliminating alkali metals or compounds thereof, e.g. from the raw materials or during the burning process; methods for eliminating other harmful components
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
- F27D17/008—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases cleaning gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0233—Other waste gases from cement factories
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
- F27D2017/009—Cyclone for separating fines from gas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Civil Engineering (AREA)
- Public Health (AREA)
- Toxicology (AREA)
- Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- Treating Waste Gases (AREA)
- Combined Means For Separation Of Solids (AREA)
- Gas Separation By Absorption (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Processing Of Solid Wastes (AREA)
Description
中の重金属濃度が増加することもない。
するために備えられる。
2 セメントキルン
3 プローブ
4 サイクロン
5 熱交換器
6 バグフィルタ
7 分級機
8 ダストタンク 9 溶解反応槽
10 調整槽
11 固液分離機
31 塩素バイパス設備
32 セメントキルン
33 プローブ
34、35 冷却ファン
36 サイクロン
37 冷却器
38 バグフィルタ
39 ダストタンク
40 分級機
41 第1の溶解槽
42 第1の固液分離機
44 第2の溶解槽
45 ファン
46 溶解反応槽
47 第2の固液分離機
48 塩回収装置
Claims (3)
- セメントキルンの窯尻から最下段サイクロンに至るまでのキルン排ガス流路より燃焼ガスの一部を冷却しながら抽気し、該抽気ガスから塩素バイパスダストを回収する塩素バイパス設備において、
前記回収された塩素バイパスダストをスラリー化した後、該スラリーを脱水し、
脱水により得られたケークを再溶解させ、K+濃度及びCl-濃度が各々6質量%以下のスラリーを生成させ、
該ケークが再溶解したスラリーを該塩素バイパス設備の排ガスに接触させて、該排ガスの脱硫を行うことを特徴とする塩素バイパスダスト及び排ガスの処理方法。 - 前記ケークが再溶解したスラリーは、SO4 2-濃度が10000mg/L以下であることを特徴とする請求項1に記載の塩素バイパスダスト及び排ガスの処理方法。
- 前記塩素バイパス設備の排ガスと接触した前記ケークが再溶解したスラリーを、ケーキとろ液とに固液分離することを特徴とする請求項1又は2に記載の塩素バイパスダスト及び排ガスの処理方法。
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010179104 | 2010-08-10 | ||
JP2010179104 | 2010-08-10 | ||
JP2010238089 | 2010-10-25 | ||
JP2010238089 | 2010-10-25 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2012528655A Division JP5943388B2 (ja) | 2010-08-10 | 2011-08-04 | 塩素バイパスダスト及び排ガスの処理方法及び処理装置 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2016188167A JP2016188167A (ja) | 2016-11-04 |
JP6169215B2 true JP6169215B2 (ja) | 2017-07-26 |
Family
ID=45567660
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012528655A Active JP5943388B2 (ja) | 2010-08-10 | 2011-08-04 | 塩素バイパスダスト及び排ガスの処理方法及び処理装置 |
JP2016078557A Active JP6169215B2 (ja) | 2010-08-10 | 2016-04-11 | 塩素バイパスダスト及び排ガスの処理方法 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
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JP2012528655A Active JP5943388B2 (ja) | 2010-08-10 | 2011-08-04 | 塩素バイパスダスト及び排ガスの処理方法及び処理装置 |
Country Status (7)
Country | Link |
---|---|
US (1) | US8623304B2 (ja) |
EP (1) | EP2604586A4 (ja) |
JP (2) | JP5943388B2 (ja) |
KR (1) | KR20130096227A (ja) |
CN (1) | CN103052607B (ja) |
TW (1) | TWI552796B (ja) |
WO (1) | WO2012020691A1 (ja) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5680450B2 (ja) * | 2011-03-09 | 2015-03-04 | 太平洋セメント株式会社 | 塩素バイパス排ガスの処理装置及び処理方法 |
US9422193B2 (en) | 2013-08-12 | 2016-08-23 | Certainteed Gypsum, Inc. | Struvite-K and syngenite composition for use in building materials |
US10479728B2 (en) | 2013-08-12 | 2019-11-19 | Certainteed Gypsum, Inc. | Struvite-K and Syngenite composition for use in building materials |
JP6357009B2 (ja) * | 2014-05-20 | 2018-07-11 | 太平洋セメント株式会社 | 有価金属精錬用原料及び有価金属精錬用原料回収方法 |
JP6327943B2 (ja) * | 2014-05-20 | 2018-05-23 | 太平洋セメント株式会社 | 廃棄物中の有価金属回収方法 |
EP2975009A1 (de) * | 2014-07-14 | 2016-01-20 | A TEC Holding GmbH | Verfahren zur Behandlung und Verwertung von Bypassstäuben und Bypassgasen aus einer Industrieanlage |
DE102014116532A1 (de) * | 2014-11-12 | 2016-05-12 | Thyssenkrupp Ag | Verfahren zur Verminderung eines Schadstoffgehalts eines bei einer thermischen Behandlung eines Materials entstehenden oder genutzten Abgasstroms |
CN104587826A (zh) * | 2015-02-09 | 2015-05-06 | 安徽海螺建材设计研究院 | 新型干法水泥窑窑尾烟气脱硫系统及其脱硫工艺 |
WO2019068084A2 (en) | 2017-09-30 | 2019-04-04 | Certaineed Gypsum, Inc. | STRUVITE-K / SYNGENITE CONSTRUCTION COMPOSITIONS COMPRISING SILICATE MATERIALS AND CONSTRUCTION ARTICLES SUCH AS WALL PANELS MANUFACTURED THEREFROM |
EP3843878A1 (en) * | 2018-08-29 | 2021-07-07 | FLSmidth A/S | A method and apparatus for reduction of hci emission from cement plants using cement raw meal as absorber |
CN110052158B (zh) * | 2019-06-06 | 2023-12-22 | 天津水泥工业设计研究院有限公司 | 一种基于水泥熟料生产线钙循环干法脱硫系统 |
CN113800790B (zh) * | 2021-10-12 | 2022-08-12 | 武汉理工大学 | 一种水泥熟料及其制备方法 |
Family Cites Families (19)
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US4065320A (en) * | 1975-05-13 | 1977-12-27 | Allis-Chalmers Corporation | System for handling high sulfur materials |
JP4210456B2 (ja) | 1997-07-14 | 2009-01-21 | 太平洋セメント株式会社 | セメント原料化処理方法 |
JP3304300B2 (ja) | 1997-07-14 | 2002-07-22 | 太平洋セメント株式会社 | セメント原料化処理方法 |
US6331207B1 (en) * | 1999-02-10 | 2001-12-18 | Ronald Frank Gebhardt | Method of treating cement kiln dust for recovery and recycle |
JP4434361B2 (ja) | 1999-06-11 | 2010-03-17 | 太平洋セメント株式会社 | 塩素バイパスダストの処理方法及びその装置 |
JP2003002611A (ja) * | 2001-06-15 | 2003-01-08 | Fuji Kikai Kk | 灰洗浄濾液の処理方法 |
JP2003236503A (ja) * | 2002-02-19 | 2003-08-26 | Taiheiyo Cement Corp | 鉛分を含む廃棄物の処理方法 |
US7947242B2 (en) * | 2002-12-11 | 2011-05-24 | Taiheiyo Cement Corporation | Cement kiln chlorine/sulfur bypass system |
KR20060029135A (ko) * | 2003-07-10 | 2006-04-04 | 다이헤이요 세멘토 가부시키가이샤 | 연소 배기 가스 처리 장치 및 처리 방법 |
DK1795510T3 (da) * | 2004-09-29 | 2014-06-16 | Taiheiyo Cement Corp | System og fremgangsmåde til behandling af gasstøv udtaget fra cementovnsforbrændingsgas |
JP2006347831A (ja) * | 2005-06-17 | 2006-12-28 | Tokuyama Corp | セメント工場から排出されるダストの処理方法 |
JP5063885B2 (ja) * | 2005-10-27 | 2012-10-31 | 太平洋セメント株式会社 | 鉛回収装置及び方法 |
JP5114227B2 (ja) * | 2008-01-28 | 2013-01-09 | 住友大阪セメント株式会社 | 水溶性塩素含有廃棄物の処理方法及び処理装置 |
EP2287126A4 (en) * | 2008-06-17 | 2014-03-26 | Taiheiyo Cement Corp | APPARATUS AND METHOD FOR TREATING GAS DISCHARGED FROM CEMENT OVEN |
JP5068698B2 (ja) * | 2008-06-19 | 2012-11-07 | 太平洋セメント株式会社 | セメントキルン抽気ガスの処理システム及び処理方法 |
JP5172728B2 (ja) | 2009-02-03 | 2013-03-27 | 太平洋セメント株式会社 | セメント製造方法及び製造装置 |
JP5213126B2 (ja) | 2009-02-27 | 2013-06-19 | 太平洋セメント株式会社 | 塩素バイパスシステム |
CN201439512U (zh) * | 2009-07-16 | 2010-04-21 | 太平洋水泥株式会社 | 焚烧灰的处理设备 |
KR101822025B1 (ko) * | 2010-06-22 | 2018-01-25 | 다이헤이요 세멘토 가부시키가이샤 | 염소 바이패스 더스트의 처리 방법 및 처리 장치 |
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2011
- 2011-08-04 US US13/811,197 patent/US8623304B2/en active Active
- 2011-08-04 CN CN201180038127.7A patent/CN103052607B/zh active Active
- 2011-08-04 KR KR1020137002191A patent/KR20130096227A/ko not_active Application Discontinuation
- 2011-08-04 JP JP2012528655A patent/JP5943388B2/ja active Active
- 2011-08-04 WO PCT/JP2011/067861 patent/WO2012020691A1/ja active Application Filing
- 2011-08-04 EP EP11816357.5A patent/EP2604586A4/en not_active Withdrawn
- 2011-08-09 TW TW100128364A patent/TWI552796B/zh active
-
2016
- 2016-04-11 JP JP2016078557A patent/JP6169215B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
JP2016188167A (ja) | 2016-11-04 |
JPWO2012020691A1 (ja) | 2013-10-28 |
TWI552796B (zh) | 2016-10-11 |
CN103052607B (zh) | 2016-06-22 |
KR20130096227A (ko) | 2013-08-29 |
EP2604586A4 (en) | 2015-04-22 |
US20130202514A1 (en) | 2013-08-08 |
EP2604586A1 (en) | 2013-06-19 |
CN103052607A (zh) | 2013-04-17 |
WO2012020691A1 (ja) | 2012-02-16 |
TW201210678A (en) | 2012-03-16 |
US8623304B2 (en) | 2014-01-07 |
JP5943388B2 (ja) | 2016-07-05 |
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