JP6161472B2 - シアンを含む溶液の処理設備及び処理方法、並びに該方法によるシアンイオンを低減した溶液の製造方法 - Google Patents
シアンを含む溶液の処理設備及び処理方法、並びに該方法によるシアンイオンを低減した溶液の製造方法 Download PDFInfo
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- JP6161472B2 JP6161472B2 JP2013182104A JP2013182104A JP6161472B2 JP 6161472 B2 JP6161472 B2 JP 6161472B2 JP 2013182104 A JP2013182104 A JP 2013182104A JP 2013182104 A JP2013182104 A JP 2013182104A JP 6161472 B2 JP6161472 B2 JP 6161472B2
- Authority
- JP
- Japan
- Prior art keywords
- solution
- polysulfide
- gas containing
- containing oxygen
- oxidation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000000034 method Methods 0.000 title claims description 26
- 238000004519 manufacturing process Methods 0.000 title description 4
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 title 2
- 229920001021 polysulfide Polymers 0.000 claims description 60
- 239000005077 polysulfide Substances 0.000 claims description 60
- 150000008117 polysulfides Polymers 0.000 claims description 60
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 54
- 239000001301 oxygen Substances 0.000 claims description 54
- 229910052760 oxygen Inorganic materials 0.000 claims description 54
- 239000007789 gas Substances 0.000 claims description 51
- 239000003054 catalyst Substances 0.000 claims description 39
- 150000002500 ions Chemical class 0.000 claims description 26
- 239000007788 liquid Substances 0.000 claims description 26
- 230000033116 oxidation-reduction process Effects 0.000 claims description 26
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 25
- 238000010129 solution processing Methods 0.000 claims description 24
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 14
- 239000002440 industrial waste Substances 0.000 claims description 12
- 238000003672 processing method Methods 0.000 claims description 12
- 238000007664 blowing Methods 0.000 claims description 11
- 238000006477 desulfuration reaction Methods 0.000 claims description 10
- 230000023556 desulfurization Effects 0.000 claims description 10
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical group OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 claims description 9
- 239000003295 industrial effluent Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 55
- 239000002994 raw material Substances 0.000 description 23
- 239000002699 waste material Substances 0.000 description 17
- 238000003756 stirring Methods 0.000 description 14
- -1 rhodan ion Chemical class 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 10
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 9
- ZLCCLBKPLLUIJC-UHFFFAOYSA-L disodium tetrasulfane-1,4-diide Chemical compound [Na+].[Na+].[S-]SS[S-] ZLCCLBKPLLUIJC-UHFFFAOYSA-L 0.000 description 9
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 9
- 150000004763 sulfides Chemical class 0.000 description 9
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 239000002737 fuel gas Substances 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 4
- 235000019645 odor Nutrition 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 239000010802 sludge Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000002341 toxic gas Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OLPXIHXXKBDZES-UHFFFAOYSA-L 37488-76-9 Chemical compound [Na+].[Na+].[S-]S[S-] OLPXIHXXKBDZES-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- NJYFRQQXXXRJHK-UHFFFAOYSA-N (4-aminophenyl) thiocyanate Chemical compound NC1=CC=C(SC#N)C=C1 NJYFRQQXXXRJHK-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- YJGLJZCJQQYDRF-UHFFFAOYSA-L [K+].[K+].[S-]S[S-] Chemical compound [K+].[K+].[S-]S[S-] YJGLJZCJQQYDRF-UHFFFAOYSA-L 0.000 description 1
- LTJSXGVQCAVSJW-UHFFFAOYSA-N [K+].[K+].[S-][S-] Chemical compound [K+].[K+].[S-][S-] LTJSXGVQCAVSJW-UHFFFAOYSA-N 0.000 description 1
- QZMHULNGRFPBIB-UHFFFAOYSA-L [S-]SS[S-].[Ca+2] Chemical compound [S-]SS[S-].[Ca+2] QZMHULNGRFPBIB-UHFFFAOYSA-L 0.000 description 1
- GADCCAIZPYMHDO-UHFFFAOYSA-L [S-]S[S-].[Ca+2] Chemical compound [S-]S[S-].[Ca+2] GADCCAIZPYMHDO-UHFFFAOYSA-L 0.000 description 1
- DRHYDSJKKDNMCR-UHFFFAOYSA-N [S-][S-].[Ca+2] Chemical compound [S-][S-].[Ca+2] DRHYDSJKKDNMCR-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 238000009841 combustion method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- SITRHDNMHBAUKP-UHFFFAOYSA-N diammonium trisulphide Chemical compound [NH4+].[NH4+].[S-]S[S-] SITRHDNMHBAUKP-UHFFFAOYSA-N 0.000 description 1
- DVBRNDGHBLXMCR-UHFFFAOYSA-L dipotassium tetrasulfide Chemical compound [K+].[K+].[S-]SS[S-] DVBRNDGHBLXMCR-UHFFFAOYSA-L 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000005949 ozonolysis reaction Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- MNWBNISUBARLIT-UHFFFAOYSA-N sodium cyanide Chemical compound [Na+].N#[C-] MNWBNISUBARLIT-UHFFFAOYSA-N 0.000 description 1
- SRRKNRDXURUMPP-UHFFFAOYSA-N sodium disulfide Chemical compound [Na+].[Na+].[S-][S-] SRRKNRDXURUMPP-UHFFFAOYSA-N 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/70—Treatment of water, waste water, or sewage by reduction
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/74—Treatment of water, waste water, or sewage by oxidation with air
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
- C02F2101/18—Cyanides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Removal Of Specific Substances (AREA)
- Treating Waste Gases (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013182104A JP6161472B2 (ja) | 2013-09-03 | 2013-09-03 | シアンを含む溶液の処理設備及び処理方法、並びに該方法によるシアンイオンを低減した溶液の製造方法 |
KR20130113595A KR20150026671A (ko) | 2013-09-03 | 2013-09-25 | 시안을 포함하는 용액의 처리 설비 및 처리 방법, 및 상기 방법에 의한 시안 이온을 감소시킨 용액의 제조 방법 |
CN201410409609.4A CN104418449A (zh) | 2013-09-03 | 2014-08-19 | 含有氰的溶液的处理设备及处理方法、以及利用该方法的减少氰离子的溶液的制造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013182104A JP6161472B2 (ja) | 2013-09-03 | 2013-09-03 | シアンを含む溶液の処理設備及び処理方法、並びに該方法によるシアンイオンを低減した溶液の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015047580A JP2015047580A (ja) | 2015-03-16 |
JP6161472B2 true JP6161472B2 (ja) | 2017-07-12 |
Family
ID=52698058
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2013182104A Active JP6161472B2 (ja) | 2013-09-03 | 2013-09-03 | シアンを含む溶液の処理設備及び処理方法、並びに該方法によるシアンイオンを低減した溶液の製造方法 |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP6161472B2 (ko) |
KR (1) | KR20150026671A (ko) |
CN (1) | CN104418449A (ko) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107126828A (zh) * | 2017-06-16 | 2017-09-05 | 长春黄金研究院 | 一种黄金冶炼厂制酸烟气的综合利用方法 |
CN109336288A (zh) * | 2018-11-02 | 2019-02-15 | 长春黄金研究院有限公司 | 一种含氰废水循环利用的方法 |
CN111983134B (zh) * | 2019-05-24 | 2022-08-05 | 中国石油天然气股份有限公司 | 液体硫磺中硫化氢和多硫化氢含量的测定方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4863966A (ko) * | 1971-12-09 | 1973-09-05 | ||
JPS523499B2 (ko) * | 1972-05-22 | 1977-01-28 | ||
JPS55106591A (en) * | 1979-02-13 | 1980-08-15 | Toray Ind Inc | Method of treating coke-oven gas desulfurization waste liquid |
JPS58289A (ja) * | 1981-06-25 | 1983-01-05 | Sumikin Coke Co Ltd | ガス液から硫化水素およびシアン化水素を除去する方法 |
US4737289A (en) * | 1986-11-26 | 1988-04-12 | Radian Corporation | Process for wastewater treatment |
JPH01123692A (ja) * | 1987-11-03 | 1989-05-16 | Radian Corp | 廃水処理方法 |
US5015396A (en) * | 1990-09-11 | 1991-05-14 | The Boc Group, Inc. | Removal of cyanide from aqueous streams |
JPH05285491A (ja) * | 1992-04-14 | 1993-11-02 | Nippon Steel Corp | コークス炉安水の処理方法 |
DE4344598A1 (de) * | 1993-12-24 | 1995-06-29 | Degussa | Verfahren zur Steuerung der Entgiftung cyanidischer Abwässer |
JP4043648B2 (ja) * | 1999-06-29 | 2008-02-06 | Jfeケミカル株式会社 | コークス炉ガス脱硫液再生時の廃空気の処理方法およびコークス炉ガス脱硫設備 |
JP2004025039A (ja) * | 2002-06-26 | 2004-01-29 | Jfe Chemical Corp | 硫化水素含有ガスの硫化水素除去方法 |
CN103253755A (zh) * | 2013-05-17 | 2013-08-21 | 招金矿业股份有限公司金翅岭金矿 | 一种去除金精矿氰化废水中氰化物的方法 |
-
2013
- 2013-09-03 JP JP2013182104A patent/JP6161472B2/ja active Active
- 2013-09-25 KR KR20130113595A patent/KR20150026671A/ko not_active Application Discontinuation
-
2014
- 2014-08-19 CN CN201410409609.4A patent/CN104418449A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
KR20150026671A (ko) | 2015-03-11 |
JP2015047580A (ja) | 2015-03-16 |
CN104418449A (zh) | 2015-03-18 |
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R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |