JP6150404B2 - 透明導電性フィルム - Google Patents
透明導電性フィルム Download PDFInfo
- Publication number
- JP6150404B2 JP6150404B2 JP2015529650A JP2015529650A JP6150404B2 JP 6150404 B2 JP6150404 B2 JP 6150404B2 JP 2015529650 A JP2015529650 A JP 2015529650A JP 2015529650 A JP2015529650 A JP 2015529650A JP 6150404 B2 JP6150404 B2 JP 6150404B2
- Authority
- JP
- Japan
- Prior art keywords
- fluorene
- transparent conductive
- conductive film
- refractive layer
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000010410 layer Substances 0.000 claims description 114
- 239000002245 particle Substances 0.000 claims description 35
- 229910044991 metal oxide Inorganic materials 0.000 claims description 31
- 150000004706 metal oxides Chemical class 0.000 claims description 31
- 239000008199 coating composition Substances 0.000 claims description 29
- 150000002220 fluorenes Chemical class 0.000 claims description 29
- 239000011347 resin Substances 0.000 claims description 27
- 229920005989 resin Polymers 0.000 claims description 27
- -1 9,9-bis (3,4-dicarboxyphenyl) fluorene anhydride Chemical class 0.000 claims description 20
- 239000000758 substrate Substances 0.000 claims description 19
- 239000004925 Acrylic resin Substances 0.000 claims description 17
- 239000011247 coating layer Substances 0.000 claims description 14
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- CZIHNRWJTSTCEX-UHFFFAOYSA-N 2 Acetylaminofluorene Chemical compound C1=CC=C2C3=CC=C(NC(=O)C)C=C3CC2=C1 CZIHNRWJTSTCEX-UHFFFAOYSA-N 0.000 claims description 6
- NUDSREQIJYWLRA-UHFFFAOYSA-N 4-[9-(4-hydroxy-3-methylphenyl)fluoren-9-yl]-2-methylphenol Chemical compound C1=C(O)C(C)=CC(C2(C3=CC=CC=C3C3=CC=CC=C32)C=2C=C(C)C(O)=CC=2)=C1 NUDSREQIJYWLRA-UHFFFAOYSA-N 0.000 claims description 6
- YWFPGFJLYRKYJZ-UHFFFAOYSA-N 9,9-bis(4-hydroxyphenyl)fluorene Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C2=CC=CC=C21 YWFPGFJLYRKYJZ-UHFFFAOYSA-N 0.000 claims description 6
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 6
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 claims description 6
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 6
- 229920001155 polypropylene Polymers 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 4
- RIRYGERFWHUZBT-UHFFFAOYSA-N 1-(7-acetyl-9h-fluoren-2-yl)ethanone Chemical compound CC(=O)C1=CC=C2C3=CC=C(C(=O)C)C=C3CC2=C1 RIRYGERFWHUZBT-UHFFFAOYSA-N 0.000 claims description 3
- IBASEVZORZFIIH-UHFFFAOYSA-N 1-(9h-fluoren-2-yl)ethanone Chemical compound C1=CC=C2C3=CC=C(C(=O)C)C=C3CC2=C1 IBASEVZORZFIIH-UHFFFAOYSA-N 0.000 claims description 3
- NQXNYVAALXGLQT-UHFFFAOYSA-N 2-[4-[9-[4-(2-hydroxyethoxy)phenyl]fluoren-9-yl]phenoxy]ethanol Chemical compound C1=CC(OCCO)=CC=C1C1(C=2C=CC(OCCO)=CC=2)C2=CC=CC=C2C2=CC=CC=C21 NQXNYVAALXGLQT-UHFFFAOYSA-N 0.000 claims description 3
- KIFDSGGWDIVQGN-UHFFFAOYSA-N 4-[9-(4-aminophenyl)fluoren-9-yl]aniline Chemical compound C1=CC(N)=CC=C1C1(C=2C=CC(N)=CC=2)C2=CC=CC=C2C2=CC=CC=C21 KIFDSGGWDIVQGN-UHFFFAOYSA-N 0.000 claims description 3
- HYQXNCDBSALQLB-UHFFFAOYSA-N 9-bromo-9-phenylfluorene Chemical compound C12=CC=CC=C2C2=CC=CC=C2C1(Br)C1=CC=CC=C1 HYQXNCDBSALQLB-UHFFFAOYSA-N 0.000 claims description 3
- AHCDKANCCBEQJJ-UHFFFAOYSA-N 9-bromo-9h-fluorene Chemical compound C1=CC=C2C(Br)C3=CC=CC=C3C2=C1 AHCDKANCCBEQJJ-UHFFFAOYSA-N 0.000 claims description 3
- SNCJAJRILVFXAE-UHFFFAOYSA-N 9h-fluorene-2,7-diamine Chemical compound NC1=CC=C2C3=CC=C(N)C=C3CC2=C1 SNCJAJRILVFXAE-UHFFFAOYSA-N 0.000 claims description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 3
- 229920012266 Poly(ether sulfone) PES Polymers 0.000 claims description 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 3
- VUGKXJFTPZXBTJ-UHFFFAOYSA-N [2-hydroxy-3-[4-[9-[4-(2-hydroxy-3-prop-2-enoyloxypropoxy)phenyl]fluoren-9-yl]phenoxy]propyl] prop-2-enoate Chemical compound C1=CC(OCC(COC(=O)C=C)O)=CC=C1C1(C=2C=CC(OCC(O)COC(=O)C=C)=CC=2)C2=CC=CC=C2C2=CC=CC=C21 VUGKXJFTPZXBTJ-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- XBZBRCVCSVLJJZ-UHFFFAOYSA-N n-(7-acetamido-9h-fluoren-2-yl)acetamide Chemical compound CC(=O)NC1=CC=C2C3=CC=C(NC(=O)C)C=C3CC2=C1 XBZBRCVCSVLJJZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 239000004417 polycarbonate Substances 0.000 claims description 3
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- 239000011112 polyethylene naphthalate Substances 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 3
- 229910001887 tin oxide Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 description 25
- 239000011248 coating agent Substances 0.000 description 23
- 238000000576 coating method Methods 0.000 description 23
- 238000004519 manufacturing process Methods 0.000 description 17
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- 230000000704 physical effect Effects 0.000 description 10
- 238000002834 transmittance Methods 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 230000003287 optical effect Effects 0.000 description 7
- 238000005530 etching Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
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- 125000004386 diacrylate group Chemical group 0.000 description 3
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- NJWGQARXZDRHCD-UHFFFAOYSA-N 2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC=C3C(=O)C2=C1 NJWGQARXZDRHCD-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 2
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 2
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 2
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
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- 238000000016 photochemical curing Methods 0.000 description 2
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- 238000012360 testing method Methods 0.000 description 2
- RLUFBDIRFJGKLY-UHFFFAOYSA-N (2,3-dichlorophenyl)-phenylmethanone Chemical compound ClC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1Cl RLUFBDIRFJGKLY-UHFFFAOYSA-N 0.000 description 1
- NNNLYDWXTKOQQX-UHFFFAOYSA-N 1,1-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OC(CC)(OC(=O)C=C)OC(=O)C=C NNNLYDWXTKOQQX-UHFFFAOYSA-N 0.000 description 1
- GZBSIABKXVPBFY-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO GZBSIABKXVPBFY-UHFFFAOYSA-N 0.000 description 1
- GIMQKKFOOYOQGB-UHFFFAOYSA-N 2,2-diethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)(OCC)C(=O)C1=CC=CC=C1 GIMQKKFOOYOQGB-UHFFFAOYSA-N 0.000 description 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- JFLLVQSDQRKXML-UHFFFAOYSA-N 2,4-diethyloxane Chemical compound CCC1CCOC(CC)C1 JFLLVQSDQRKXML-UHFFFAOYSA-N 0.000 description 1
- LCHAFMWSFCONOO-UHFFFAOYSA-N 2,4-dimethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC(C)=C3SC2=C1 LCHAFMWSFCONOO-UHFFFAOYSA-N 0.000 description 1
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Application Number | Priority Date | Filing Date | Title |
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KR1020120097120A KR101525286B1 (ko) | 2012-09-03 | 2012-09-03 | 고굴절층 코팅용 조성물 및 이를 포함하는 투명 도전성 필름 |
KR10-2012-0097120 | 2012-09-03 | ||
PCT/KR2013/000116 WO2014035018A1 (ko) | 2012-09-03 | 2013-01-08 | 고굴절층 코팅용 조성물 및 이를 포함하는 투명 도전성 필름 |
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JP2015535859A JP2015535859A (ja) | 2015-12-17 |
JP6150404B2 true JP6150404B2 (ja) | 2017-06-21 |
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JP2015529650A Expired - Fee Related JP6150404B2 (ja) | 2012-09-03 | 2013-01-08 | 透明導電性フィルム |
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WO (1) | WO2014035018A1 (ko) |
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JP6419610B2 (ja) * | 2015-03-12 | 2018-11-07 | リンテック株式会社 | 透明導電膜積層用フィルム、その製造方法および透明導電性フィルム |
KR20160150499A (ko) * | 2015-06-22 | 2016-12-30 | 주식회사 엘지화학 | 도전성 필름 |
KR102159491B1 (ko) * | 2016-05-09 | 2020-09-24 | 주식회사 엘지화학 | 도전성 투광 필름 |
WO2017196034A1 (ko) * | 2016-05-09 | 2017-11-16 | 주식회사 엘지화학 | 도전성 투광 필름 |
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WO2007105627A1 (ja) * | 2006-03-10 | 2007-09-20 | Toyo Ink Mfg. Co., Ltd. | 光学部材用ハードコート性樹脂組成物 |
JP2009133880A (ja) * | 2006-03-10 | 2009-06-18 | Toyo Ink Mfg Co Ltd | 樹脂組成物 |
JP2007277467A (ja) * | 2006-04-10 | 2007-10-25 | Sony Chemical & Information Device Corp | 硬化性樹脂組成物 |
CN101454351B (zh) * | 2006-05-29 | 2013-09-04 | 东洋油墨制造株式会社 | 金属氧化物组合物、固化膜及层叠体 |
CN101134818A (zh) * | 2006-08-30 | 2008-03-05 | 三洋电机株式会社 | 有机无机复合体形成用材料、有机无机复合体和使用该复合体的光学元件 |
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US7981986B2 (en) * | 2008-04-29 | 2011-07-19 | 3M Innovative Properties Company | Optical films comprising fluorenol (meth)acrylate monomer |
KR101099031B1 (ko) * | 2009-06-05 | 2011-12-26 | 한화엘앤씨 주식회사 | 터치 패널용 투명 도전성 필름 및 그 제조방법 |
CN102034565B (zh) * | 2009-10-06 | 2014-01-29 | 日油株式会社 | 透明导电性膜 |
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JP5760522B2 (ja) * | 2011-03-07 | 2015-08-12 | 帝人株式会社 | 光硬化性樹脂組成物及びその硬化皮膜を有する物品、その製造方法 |
JP5815304B2 (ja) * | 2011-06-29 | 2015-11-17 | 日揮触媒化成株式会社 | 光学薄膜形成用塗料および光学薄膜 |
JP5991063B2 (ja) * | 2012-07-31 | 2016-09-14 | 東洋インキScホールディングス株式会社 | 樹脂組成物、ならびにそれを用いた塗膜 |
JP5885585B2 (ja) * | 2012-05-21 | 2016-03-15 | 昭和電工株式会社 | 硬化性組成物およびその硬化物 |
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KR101525286B1 (ko) | 2015-06-02 |
TW201410814A (zh) | 2014-03-16 |
KR20140030666A (ko) | 2014-03-12 |
WO2014035018A1 (ko) | 2014-03-06 |
TWI491688B (zh) | 2015-07-11 |
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