JP6080062B2 - 封止材フィルム - Google Patents
封止材フィルム Download PDFInfo
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- JP6080062B2 JP6080062B2 JP2015549274A JP2015549274A JP6080062B2 JP 6080062 B2 JP6080062 B2 JP 6080062B2 JP 2015549274 A JP2015549274 A JP 2015549274A JP 2015549274 A JP2015549274 A JP 2015549274A JP 6080062 B2 JP6080062 B2 JP 6080062B2
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- ethylene
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- 239000008393 encapsulating agent Substances 0.000 title claims description 23
- 239000003566 sealing material Substances 0.000 claims description 96
- -1 unsaturated silane compound Chemical class 0.000 claims description 78
- 239000000758 substrate Substances 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 37
- 238000003475 lamination Methods 0.000 claims description 33
- 125000003277 amino group Chemical group 0.000 claims description 32
- 229920001577 copolymer Polymers 0.000 claims description 32
- 230000005693 optoelectronics Effects 0.000 claims description 29
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 27
- 229910052710 silicon Inorganic materials 0.000 claims description 27
- 125000000217 alkyl group Chemical group 0.000 claims description 25
- 229910052739 hydrogen Inorganic materials 0.000 claims description 25
- 239000001257 hydrogen Substances 0.000 claims description 25
- 239000011521 glass Substances 0.000 claims description 22
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 22
- 239000000126 substance Substances 0.000 claims description 21
- 125000003118 aryl group Chemical group 0.000 claims description 19
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 16
- 125000005372 silanol group Chemical group 0.000 claims description 14
- 125000002252 acyl group Chemical group 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 125000002947 alkylene group Chemical group 0.000 claims description 11
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 claims description 10
- 229910052736 halogen Inorganic materials 0.000 claims description 8
- 150000002367 halogens Chemical class 0.000 claims description 8
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 8
- 125000004434 sulfur atom Chemical group 0.000 claims description 8
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
- 238000004383 yellowing Methods 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims 4
- 239000000565 sealant Substances 0.000 claims 1
- 239000004711 α-olefin Substances 0.000 description 91
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 85
- 238000004519 manufacturing process Methods 0.000 description 80
- 229920005672 polyolefin resin Polymers 0.000 description 80
- 239000010408 film Substances 0.000 description 54
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 49
- 239000005977 Ethylene Substances 0.000 description 49
- 239000004594 Masterbatch (MB) Substances 0.000 description 43
- 230000000052 comparative effect Effects 0.000 description 42
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 40
- 229920005989 resin Polymers 0.000 description 31
- 239000011347 resin Substances 0.000 description 31
- 230000001070 adhesive effect Effects 0.000 description 30
- 239000011342 resin composition Substances 0.000 description 30
- 239000000853 adhesive Substances 0.000 description 29
- 125000004432 carbon atom Chemical group C* 0.000 description 24
- 239000000654 additive Substances 0.000 description 14
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 14
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 12
- 238000002834 transmittance Methods 0.000 description 12
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 11
- 238000005259 measurement Methods 0.000 description 11
- 125000000524 functional group Chemical group 0.000 description 10
- 239000003999 initiator Substances 0.000 description 10
- 150000003254 radicals Chemical class 0.000 description 10
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 9
- 230000000996 additive effect Effects 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 8
- 125000003545 alkoxy group Chemical group 0.000 description 7
- 150000003973 alkyl amines Chemical class 0.000 description 7
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000005038 ethylene vinyl acetate Substances 0.000 description 6
- 150000002430 hydrocarbons Chemical group 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 6
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
- 239000006096 absorbing agent Substances 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 5
- 238000005102 attenuated total reflection Methods 0.000 description 5
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000010432 diamond Substances 0.000 description 5
- 229910003460 diamond Inorganic materials 0.000 description 5
- 239000012760 heat stabilizer Substances 0.000 description 5
- 239000004611 light stabiliser Substances 0.000 description 5
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 5
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical group [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 239000002033 PVDF binder Substances 0.000 description 4
- 230000002411 adverse Effects 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000007774 longterm Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 125000004423 acyloxy group Chemical group 0.000 description 3
- 150000001343 alkyl silanes Chemical class 0.000 description 3
- 125000004414 alkyl thio group Chemical group 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000005357 flat glass Substances 0.000 description 3
- 229920002313 fluoropolymer Polymers 0.000 description 3
- 239000004811 fluoropolymer Substances 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000010030 laminating Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000012780 transparent material Substances 0.000 description 3
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 3
- PFNQVRZLDWYSCW-UHFFFAOYSA-N (fluoren-9-ylideneamino) n-naphthalen-1-ylcarbamate Chemical compound C12=CC=CC=C2C2=CC=CC=C2C1=NOC(=O)NC1=CC=CC2=CC=CC=C12 PFNQVRZLDWYSCW-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000012963 UV stabilizer Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000005840 aryl radicals Chemical class 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002620 polyvinyl fluoride Polymers 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- SBIBMFFZSBJNJF-UHFFFAOYSA-N selenium;zinc Chemical compound [Se]=[Zn] SBIBMFFZSBJNJF-UHFFFAOYSA-N 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 description 1
- ZICNIEOYWVIEQJ-UHFFFAOYSA-N (2-methylbenzoyl) 2-methylbenzenecarboperoxoate Chemical compound CC1=CC=CC=C1C(=O)OOC(=O)C1=CC=CC=C1C ZICNIEOYWVIEQJ-UHFFFAOYSA-N 0.000 description 1
- FVQMJJQUGGVLEP-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOOC(C)(C)C FVQMJJQUGGVLEP-UHFFFAOYSA-N 0.000 description 1
- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 1
- KDGNCLDCOVTOCS-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy propan-2-yl carbonate Chemical compound CC(C)OC(=O)OOC(C)(C)C KDGNCLDCOVTOCS-UHFFFAOYSA-N 0.000 description 1
- RSGZQYVTVPJMTG-UHFFFAOYSA-N (5-benzoylperoxy-2,5-dimethylhex-3-yn-2-yl) benzenecarboperoxoate Chemical compound C=1C=CC=CC=1C(=O)OOC(C)(C)C#CC(C)(C)OOC(=O)C1=CC=CC=C1 RSGZQYVTVPJMTG-UHFFFAOYSA-N 0.000 description 1
- RIPYNJLMMFGZSX-UHFFFAOYSA-N (5-benzoylperoxy-2,5-dimethylhexan-2-yl) benzenecarboperoxoate Chemical compound C=1C=CC=CC=1C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C1=CC=CC=C1 RIPYNJLMMFGZSX-UHFFFAOYSA-N 0.000 description 1
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 description 1
- ZDKPIHMFWCOHRD-UHFFFAOYSA-N 1-[[4-[4-bis(2,4-ditert-butylphenoxy)phosphorylphenyl]phenyl]-(2,4-ditert-butylphenoxy)phosphoryl]oxy-2,4-ditert-butylbenzene Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(=O)(C=1C=CC(=CC=1)C=1C=CC(=CC=1)P(=O)(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C ZDKPIHMFWCOHRD-UHFFFAOYSA-N 0.000 description 1
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- AKUNSTOMHUXJOZ-UHFFFAOYSA-N 1-hydroperoxybutane Chemical compound CCCCOO AKUNSTOMHUXJOZ-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- LAZHUUGOLCHESB-UHFFFAOYSA-N 2,3-dimethylbicyclo[2.2.1]hept-5-ene Chemical compound C1C2C(C)C(C)C1C=C2 LAZHUUGOLCHESB-UHFFFAOYSA-N 0.000 description 1
- UYZGVYVJIFOZPY-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)hex-3-yne Chemical compound CC(C)(C)OOC(C)C#CC(C)OOC(C)(C)C UYZGVYVJIFOZPY-UHFFFAOYSA-N 0.000 description 1
- JGBAASVQPMTVHO-UHFFFAOYSA-N 2,5-dihydroperoxy-2,5-dimethylhexane Chemical compound OOC(C)(C)CCC(C)(C)OO JGBAASVQPMTVHO-UHFFFAOYSA-N 0.000 description 1
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
- NGOCAPPEAVAHQM-UHFFFAOYSA-N 2-fluoroprop-1-ene Chemical compound CC(F)=C NGOCAPPEAVAHQM-UHFFFAOYSA-N 0.000 description 1
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 1
- BIISIZOQPWZPPS-UHFFFAOYSA-N 2-tert-butylperoxypropan-2-ylbenzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1 BIISIZOQPWZPPS-UHFFFAOYSA-N 0.000 description 1
- TXBZITDWMURSEF-UHFFFAOYSA-N 3,3-dimethylpent-1-ene Chemical compound CCC(C)(C)C=C TXBZITDWMURSEF-UHFFFAOYSA-N 0.000 description 1
- XVEASTGLHPVZNA-UHFFFAOYSA-N 3,4-dichlorobut-1-ene Chemical compound ClCC(Cl)C=C XVEASTGLHPVZNA-UHFFFAOYSA-N 0.000 description 1
- WFHXQNMTMDKVJG-UHFFFAOYSA-N 3,4-dimethylpent-1-ene Chemical compound CC(C)C(C)C=C WFHXQNMTMDKVJG-UHFFFAOYSA-N 0.000 description 1
- AIBRSVLEQRWAEG-UHFFFAOYSA-N 3,9-bis(2,4-ditert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP1OCC2(COP(OC=3C(=CC(=CC=3)C(C)(C)C)C(C)(C)C)OC2)CO1 AIBRSVLEQRWAEG-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- MZWXWSVCNSPBLH-UHFFFAOYSA-N 3-(3-aminopropyl-methoxy-methylsilyl)oxypropan-1-amine Chemical compound NCCC[Si](C)(OC)OCCCN MZWXWSVCNSPBLH-UHFFFAOYSA-N 0.000 description 1
- HXLAEGYMDGUSBD-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]propan-1-amine Chemical compound CCO[Si](C)(OCC)CCCN HXLAEGYMDGUSBD-UHFFFAOYSA-N 0.000 description 1
- ZYAASQNKCWTPKI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propan-1-amine Chemical compound CO[Si](C)(OC)CCCN ZYAASQNKCWTPKI-UHFFFAOYSA-N 0.000 description 1
- QCMKXHXKNIOBBC-UHFFFAOYSA-N 3-fluoroprop-1-ene Chemical compound FCC=C QCMKXHXKNIOBBC-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- ZZFSVZSLTOWVQU-UHFFFAOYSA-N 3-silyloxyperoxypropan-1-amine Chemical compound NCCCOOO[SiH3] ZZFSVZSLTOWVQU-UHFFFAOYSA-N 0.000 description 1
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 1
- SUWJESCICIOQHO-UHFFFAOYSA-N 4-methylhex-1-ene Chemical compound CCC(C)CC=C SUWJESCICIOQHO-UHFFFAOYSA-N 0.000 description 1
- UDOJACSDSIHAAT-UHFFFAOYSA-N 5-benzylbicyclo[2.2.1]hept-2-ene Chemical compound C1C(C=C2)CC2C1CC1=CC=CC=C1 UDOJACSDSIHAAT-UHFFFAOYSA-N 0.000 description 1
- QHJIJNGGGLNBNJ-UHFFFAOYSA-N 5-ethylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(CC)CC1C=C2 QHJIJNGGGLNBNJ-UHFFFAOYSA-N 0.000 description 1
- PCBPVYHMZBWMAZ-UHFFFAOYSA-N 5-methylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C)CC1C=C2 PCBPVYHMZBWMAZ-UHFFFAOYSA-N 0.000 description 1
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- SGCFZHOZKKQIBU-UHFFFAOYSA-N tributoxy(ethenyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)C=C SGCFZHOZKKQIBU-UHFFFAOYSA-N 0.000 description 1
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- AZSKHRTUXHLAHS-UHFFFAOYSA-N tris(2,4-di-tert-butylphenyl) phosphate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(=O)(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C AZSKHRTUXHLAHS-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
- C08F230/085—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/13—Phenols; Phenolates
- C08K5/132—Phenols containing keto groups, e.g. benzophenones
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/541—Silicon-containing compounds containing oxygen
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Description
[製造例1]
密度が0.870g/cm3であり、MFRが190℃、2.16kgの荷重下で、5g/10分のエチレン/α−オレフィン共重合体95.01重量部、ビニルトリメトキシシラン(vinyltrimethoxysilane;VTMS)4.79重量部、3−アミノプロピルトリメトキシシラン(3−aminopropyltrimethoxysilane;APTMS)0.1重量部及び2,5−ビス(t−ブチルペルオキシ)−2,5−ジメチルヘキサン(2,5−Bis(tert−butylperoxy)−2,5−dimethylhexane、Luperox(登録商標) 101)0.1重量部を、二軸押出機を使用して220℃の温度で180rpmでグラフト反応押出(加熱溶融撹拌)し、変性エチレン/α−オレフィン共重合体のマスターバッチを製造した(全体100重量部を基準で、各々の重量部はwt%を示す)。
製造例1で使用したビニルトリメトキシシラン及び3−アミノプロピルトリメトキシシランの含量を下記表1で示したように変更したこと以外は、製造例1と同一に実施して変性エチレン/α−オレフィン共重合体のマスターバッチを製造した。
製造例3で使用した3−アミノプロピルトリメトキシシランの代わりに、各々3−アミノプロピルトリエトキシシラン(3−aminopropyltriethoxysilane;APTES)及びN−[3−(トリメトキシシリル)プロピル]エチレンジアミン(N−[3−(Trimethoxysilyl)propyl]ethylenediamine;DAS)を使用したこと以外は、製造例3と同一に実施して変性エチレン/α−オレフィン共重合体のマスターバッチを製造した。
各々製造例1及び製造例3で使用したエチレン/α−オレフィン共重合体の代わりに、密度が0.882g/cm3であり、MFRが190℃、2.16kgの荷重下で、3g/10分のエチレン/α−オレフィン共重合体を使用したこと以外は、製造例1及び製造例3と同一に実施して変性エチレン/α−オレフィン共重合体のマスターバッチを製造した。
各々製造例1及び製造例3で使用したエチレン/α−オレフィン共重合体の代わりに、密度が0.902g/cm3であり、MFRが190℃、2.16kgの荷重下で、3g/10分のエチレン/α−オレフィン共重合体を使用したこと以外は、製造例1及び製造例3と同一に実施して変性エチレン/α−オレフィン共重合体のマスターバッチを製造した。
製造例1で使用した3−アミノプロピルトリメトキシシランを使わないで、ビニルトリメトキシシランを4.89重量部で使用したこと以外は、製造例1と同一に実施してシラン変性エチレン/α−オレフィン共重合体のマスターバッチを製造した。
製造例3で使用した3−アミノプロピルトリメトキシシランの代わりに、各々ドデシルアミン(dodecylamine;DA)及びトリメトキシプロピルシラン(Trimethoxypropylsilane;TMS)を使用したこと以外は、製造例3と同一に実施してシラン変性エチレン/α−オレフィン共重合体のマスターバッチを製造した。
比較製造例1で使用したエチレン/α−オレフィン共重合体の代わりに、密度が0.882g/cm3であり、MFRが190℃、2.16kgの荷重下で、3g/10分のエチレン/α−オレフィン共重合体を使用したこと以外は、比較製造例1と同一に実施してシラン変性エチレン/α−オレフィン共重合体のマスターバッチを製造した。
比較製造例1で使用したエチレン/α−オレフィン共重合体の代わりに、密度が0.902g/cm3であり、MFRが190℃、2.16kgの荷重下で、3g/10分のエチレン/α−オレフィン共重合体を使用したこと以外は、比較製造例1と同一に実施してシラン変性エチレン/α−オレフィン共重合体のマスターバッチを製造した。
製造例1で使用したビニルトリメトキシシランを使わないで、3−アミノプロピルトリメトキシシランを各々4.89重量部及び0.49重量部で使用したこと以外は、製造例1と同一に実施してエチレン/α−オレフィン共重合体のマスターバッチを製造した。
製造例1で使用したビニルトリメトキシシラン4.79重量部及び3−アミノプロピルトリメトキシシラン0.1重量部の代りに、ビニルトリメトキシシラン2.44重量部と3−アミノプロピルトリメトキシシランを2.45重量部で使用したこと以外は、製造例1と同一に実施して変性エチレン/α−オレフィン共重合体のマスターバッチを製造した。
[実施例1〜実施例5]
各々前記製造例1〜製造例5で製造された変性エチレン/α−オレフィン共重合体のマスターバッチと、密度が0.870g/cm3であり、MFRが190℃、2.16kgの荷重下で、5g/10分のエチレン/α−オレフィン共重合体を各々200g及び400gを準備して1:2の割合で混合した混合樹脂に、最終シート内で光安定剤(Uvinul 5050H)1000ppm、UV吸収剤(TINUVIN UV531)1000ppm、酸化防止剤1(Irganox1010)500ppm及び酸化防止剤2(Irgafos168)500ppmを含むようにする添加剤マスターバッチ18gを添加して混合した後、これを二軸押出機(φ19mm)及びTダイス(幅:200mm)を有するフィルム成形機のホッパーに投入し、押出温度180℃、取出速度3m/minで加工して、厚さ約500μmのシート状封止材を製造した。
実施例1で使用した変性エチレン/α−オレフィン共重合体のマスターバッチとエチレン/α−オレフィン共重合体の混合樹脂の代わりに、各々前記製造例6及び製造例7で製造された変性エチレン/α−オレフィン共重合体のマスターバッチと、密度が0.882g/cm3であり、MFRが190℃、2.16kgの荷重下で3g/10分のエチレン/α−オレフィン共重合体を、各々200g及び400gを準備して1:2の割合で混合した樹脂を使用したこと以外は、実施例1と同一に実施してシート状封止材及び光電池モジュールを製作した。
実施例1で使用した変性エチレン/α−オレフィン共重合体のマスターバッチとエチレン/α−オレフィン共重合体の混合樹脂の代わりに、各々前記製造例8及び製造例9で製造された変性エチレン/α−オレフィン共重合体のマスターバッチと、密度が0.902g/cm3であり、MFRが190℃、2.16kgの荷重下で3g/10分のエチレン/α−オレフィン共重合体を、各々200g及び400gを準備して1:2の割合で混合した樹脂を使用したこと以外は、実施例1と同一に実施してシート状封止材及び光電池モジュールを製作した。
実施例1で使用した変性エチレン/α−オレフィン共重合体のマスターバッチとエチレン/α−オレフィン共重合体の混合樹脂の代わりに、前記製造例3で製造された変性エチレン/α−オレフィン共重合体のマスターバッチと、密度が0.870g/cm3であり、MFRが190℃、2.16kgの荷重下で、5g/10分のエチレン/α−オレフィン共重合体を、各々100g及び500gを準備して1:5の割合で混合した樹脂を使用したこと以外は、実施例1と同一に実施してシート状封止材及び光電池モジュールを製作した。
実施例1で使用した変性エチレン/α−オレフィン共重合体のマスターバッチとエチレン/α−オレフィン共重合体の混合樹脂の代わりに、前記製造例3で製造された変性エチレン/α−オレフィン共重合体のマスターバッチと、密度が0.870g/cm3であり、MFRが190℃、2.16kgの荷重下で、5g/10分のエチレン/α−オレフィン共重合体を、各々54.5g及び545.5gを準備して1:10の割合で混合した樹脂を使用したこと以外は、実施例1と同一に実施してシート状封止材及び光電池モジュールを製作した。
実施例1で使用した変性エチレン/α−オレフィン共重合体のマスターバッチとエチレン/α−オレフィン共重合体の混合樹脂の代わりに、前記製造例10で製造された変性エチレン/α−オレフィン共重合体のマスターバッチと、密度が0.870g/cm3であり、MFRが190℃、2.16kgの荷重下で、3g/10分のエチレン/α−オレフィン共重合体を各々200g及び400gを準備して1:2の割合で混合した樹脂を使用したこと以外は、実施例1と同一に実施してシート状封止材及び光電池モジュールを製作した。
実施例1で使用した変性エチレン/α−オレフィン共重合体のマスターバッチの代わりに、各々前記比較製造例1〜比較製造例3で製造されたシラン変性エチレン/α−オレフィン共重合体のマスターバッチを使用したこと以外は、実施例1と同一に実施してシート状封止材及び光電池モジュールを製作した。
実施例1で使用した変性エチレン/α−オレフィン共重合体のマスターバッチとエチレン/α−オレフィン共重合体の混合樹脂の代わりに、前記比較製造例4で製造されたシラン変性エチレン/α−オレフィン共重合体のマスターバッチと、密度が0.882g/cm3であり、MFRが190℃、2.16kgの荷重下で、3g/10分のエチレン/α−オレフィン共重合体を、各々200g及び400gを準備して1:2の割合で混合した樹脂を使用したこと以外は、実施例1と同一に実施してシート状封止材及び光電池モジュールを製作した。
実施例1で使用した変性エチレン/α−オレフィン共重合体のマスターバッチとエチレン/α−オレフィン共重合体の混合樹脂の代わりに、前記比較製造例5で製造されたシラン変性エチレン/α−オレフィン共重合体のマスターバッチと、密度が0.902g/cm3であり、MFRが190℃、2.16kgの荷重下で、3g/10分のエチレン/α−オレフィン共重合体を各々200g及び400gを準備して1:2の割合で混合した樹脂を使用したこと以外は、実施例1と同一に実施してシート状封止材及び光電池モジュールを製作した。
実施例1で使用した変性エチレン/α−オレフィン共重合体のマスターバッチの代わりに、各々前記比較製造例6及び比較製造例7で製造されたエチレン/α−オレフィン共重合体のマスターバッチを使用したこと以外は、実施例1と同一に実施してシート状封止材及び光電池モジュールを製作した。
実施例1で使用した変性エチレン/α−オレフィン共重合体のマスターバッチとエチレン/α−オレフィン共重合体の混合樹脂の代わりに、前記比較製造例8で製造された変性エチレン/α−オレフィン共重合体のマスターバッチと、密度が0.870g/cm3であり、MFRが190℃、2.16kgの荷重下で、3g/10分のエチレン/α−オレフィン共重合体を、各々200g及び400gを準備して1:2の割合で混合した樹脂を使用したこと以外は、実施例1と同一に実施してシート状封止材及び光電池モジュールを製作した。
[1.90度の剥離強度の測定]
前記実施例1〜実施例12、比較例1〜比較例8で製造された封止材の剥離強度を測定するために、製造された光電池モジュールと類似な試片を別に製造した。試片は、板ガラス(厚さ:約3mm)、前記製造された厚さ500μmの封止材及び裏面シート(厚さ20μmのポリフッ化ビニル樹脂シート、厚さ250μmのポリエチレンテレフタレート及び厚さ20μmのポリフッ化ビニル樹脂シートの積層シート;PVDF/PET/PVDF)を順に積層し、真空ラミネートで150℃で15分30秒間ラミネーションして製造した。製造された試片の下部ガラス板を固定した後、ASTM D1897に準拠して、裏面シートのみに接着された封止材を裏面シートと同時に15mm幅の直四角形、50mm/minの引張速度及び90度の剥離角度で剥離しながら測定した剥離強度を下記表3に示した。
実験例1で実施例1及び実施例3の封止材を使用して製造した光電池モジュールと類似な試片の製作時に、ラミネーション条件を下記表5に示したように変更して、110℃、130℃、140℃、150℃、160℃で各々6分30秒、10分30秒、15分30秒の間実行したこと以外は、実験例1と同一に実施して測定した90度の剥離強度を下記表5に示し、ラミネーション温度による接着強度を測定したグラフを図3に示した。
実施例及び比較例で製造された光電子装置用封止材フィルムを、ASTM 1925に準拠して、Colorflex(Hunter lab)を利用して400nm〜700nm領域の反射率を測定し、これを利用してYI値(黄色度:Yellowness Index)を得た(下記式2参照)。
変性マスターバッチ内で一部シリル基の炭化水素基がヒドロキシ基に転換された部分を含みながらもアミン官能基を有する部分も一緒に含む分枝を検出し、前記封止材フィルムのラミネーション過程で、アミノシラン化合物により加水分解が促進されてメトキシシリル基(Si−O−CH3)がシラノール基(Si−OH)に転換された程度を測定するために、製造例1〜製造例3及び比較製造例1の変性マスターバッチと実施例1〜実施例3及び比較例1で製造された封止材フィルムに対して、前記変性マスターバッチ及び封止材内のメチレン基(CH2)とシラノール基(Si−OH)及びアミン基(NH2)の各ピークの面積を各々測定した。前記各ピークの面積は、次のような方法及び下記条件で測定した。
調査回数:32
分解能:4
前記実施例3及び比較例1で製造された封止材の光透過度を測定するために、別途の試片を製造した。試片は、2個の光学顕微鏡用スライドガラス(厚さ:約1mm)間に前記製造された厚さ500μmの封止材を2枚重なって入れて、真空ラミネートでラミネーション温度を下記表9の条件と同一に相違にしてラミネーションして製造するが、ガイドを使用して2枚の重なった封止材シートの厚さの和が約500±50μmになるように製造し、ヘイズメーター(Hazemeter)を使用して前記試片の550nmの波長の光に対する全光線透過率及びヘイズ値を測定して、下記表9に示した。この場合、透過率及びヘイズ値は、前記試片を試片ホルダーに入れて3回測定した後、これらの平均値を求めて、JIS K 7105の規格条件で測定された。ラミネーション工程時間は、5分 真空/30秒 圧力/10分 残留圧力で固定した。
Slit width:32nm
Detector unit: External (2D detectors)
Time constant:0.2秒
Claims (12)
- ATR法によってFT−IRで測定した、波数が705cm−1〜735cm−1領域でのメチレン基のピーク面積(Sm)に対する、波数が3100cm−1〜3600cm−1領域でのシラノール基及びアミン基のピーク面積(Sa)の割合Sa/Smが0.6以上である封止材フィルムであって、
オレフィン系単量体の重合単位を含む主鎖;並びに前記主鎖に結合され、重合された形態の不飽和シラン化合物及びアミノシラン化合物を含む分岐を含む共重合体であって、
前記アミノシラン化合物はシラン化合物100重量部に対して1〜40重量部の含量で含まれ、
前記分岐は下記化学式1で表示される、共重合体を含むことを特徴とする、封止材フィルム。
−SiR 1 l R 2 (2−l) R 3 化学式1
前記化学式1で、R 1 及びR 2 は、各々独立的に珪素原子に結合されているハロゲン、アミン基、−R 4 R 5 または−R 5 を示し、
R 4 は、酸素または硫黄原子であり、
R 5 は、水素、アルキル基、アリール基、アラルキル基またはアシル基を示し、
lは、1または2の整数であり、
R 3 は、珪素原子に結合されている−OSiR 6 m R 7 (2−m) R 8 を示し、
R 6 及びR 7 は、各々独立的に珪素原子に結合されているハロゲン、アミン基、−R 9 R 10 または−R 10 を示し、
R 9 は、酸素または硫黄原子であり、
R 10 は、水素、アルキル基、アリール基、アラルキル基またはアシル基を示し、
R 8 は、珪素原子に結合されている−(CH 2 ) n NR 11 R 12 を示し、
R 11 及びR 12 は、各々独立的に窒素原子に結合されている水素またはR 13 NH 2 を示し、
R 13 は、アルキレン基を示し、
mは、1または2の整数であり、
nは、0以上の整数である。 - メチレン基のピーク面積(Sm)に対するシラノール基及びアミン基のピーク面積(Sa)の割合Sa/Smが0.9以上であることを特徴とする請求項1に記載の封止材フィルム。
- 下記式1を満足することを特徴とする請求項1に記載の封止材フィルム。
P=α1(TL−100)+β1 式1
前記式1で、Pは、90゜の剥離角度及び50mm/minの剥離速度で測定されたガラス基板に対する封止材の剥離力を示し、TLは、封止材とガラス基板のラミネーション温度を示し、α1は、1以上であり、β1は、40以上であり、
T L は100以上であり、
Pの単位はN/15mmであり、T L の単位は℃であり、α 1 の単位はN/((15mm)・℃)であり、β 1 の単位はN/15mmである。 - α1は、1.5〜4であり、β1は、50〜150であることを特徴とする請求項3に記載の封止材フィルム。
- α1は、2.3〜3.3であり、β1は、70〜130であることを特徴とする請求項3に記載の封止材フィルム。
- 封止材フィルムを110℃の温度でガラス基板にラミネートした後に、90゜の剥離角度及び50mm/minの剥離速度で測定したガラス基板に対する封止材フィルムの剥離力が50N/15mm以上であることを特徴とする請求項1に記載の封止材フィルム。
- ASTM D1925に準拠して、UV/Visスペクトロメーターを利用して400nm〜700nmの波長領域の反射率を測定し、これを利用して下記式2により計算された黄変度(YI)値が0.5〜2.5であることを特徴とする請求項1に記載の封止材フィルム。
YI=[100(1.28XCIE − 1.06ZCIE)]/YCIE 式2
前記式2で、YIは、UV/VIS/NIRスペクトロメーターで色差分析プログラムを利用して計算された値であり、XCIE、YCIE、ZCIEは、各々赤色、緑色、青色座標が示す相対的な値である。 - 黄変度(YI)値が1.0〜1.5であることを特徴とする請求項7に記載の封止材フィルム。
- R1及びR2は、ヒドロキシ基を示し、R3は、珪素原子に結合されている−OSiR6 mR7 (2−m)R8を示し、R6及びR7は、ヒドロキシ基を示し、R8は、珪素原子に結合されている−(CH2)nNR11R12を示し、R11は、水素を示し、R12は、R13NH2を示し、R13は、アルキレンを示すことを特徴とする請求項1に記載の封止材フィルム。
- 共重合体は、主鎖に結合されて下記化学式2で表示される分枝をさらに含むことを特徴とする請求項1に記載の封止材フィルム。
−SiR14 oR15 (3−o) 化学式2
前記化学式2で、R14及びR15は、各々独立的に珪素原子に結合されているハロゲン、アミン基、−R16R17または−R17を示し、R16は、酸素または硫黄原子であり、R17は、水素、アルキル基、アリール基、アラルキル基またはアシル基を示し、oは、1〜3の整数である。 - R14及びR15は、各々独立的に珪素原子に結合されているヒドロキシ基または−R16R17を示し、R16は、酸素であり、R17は、アルキル基を示すことを特徴とする請求項10に記載の封止材フィルム。
- 前面基板、裏面シート、前記前面基板と裏面シートとの間に積層された請求項1に記載の封止材フィルム及び前記封止材フィルムによりカプセル化された光電子素子を含むことを特徴とする光電子装置。
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