FR3053350B1 - Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci - Google Patents

Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci Download PDF

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Publication number
FR3053350B1
FR3053350B1 FR1656099A FR1656099A FR3053350B1 FR 3053350 B1 FR3053350 B1 FR 3053350B1 FR 1656099 A FR1656099 A FR 1656099A FR 1656099 A FR1656099 A FR 1656099A FR 3053350 B1 FR3053350 B1 FR 3053350B1
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France
Prior art keywords
syrup
meth
impregnation process
polymer
relates
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FR1656099A
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FR3053350A1 (fr
Inventor
Pierre ESCALE
Pierre Gerard
Aline COUFFIN
Raber Inoubli
Philippe Hajji
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Arkema France SA
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Arkema France SA
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Priority to FR1656099A priority Critical patent/FR3053350B1/fr
Priority to PCT/EP2017/066201 priority patent/WO2018002260A1/fr
Priority to US16/311,760 priority patent/US11142619B2/en
Priority to EP17732953.9A priority patent/EP3478763A1/fr
Priority to CN201780053563.9A priority patent/CN109689776A/zh
Publication of FR3053350A1 publication Critical patent/FR3053350A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/02—Low molecular weight, e.g. <100,000 Da.
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17—Viscosity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/21—Rubbery or elastomeric properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2347/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Derivatives of such polymers

Abstract

La présente invention concerne une composition liquide comprenant un monomère, un polymère (méth) acrylique et un polymère à phases multiples. En particulier, la présente invention concerne une composition liquide comprenant un monomère, un polymère (méth) acrylique et un polymère à phases multiples qui peuvent être utilisés en tant que sirop et spécialement en tant que sirop pour imprégnation et pour la préparation de, ou pour renforcer la résistance aux chocs d'un matériau thermoplastique obtenu après polymérisation du sirop. L'invention concerne également un procédé de fabrication d'un tel sirop. L'invention concerne également un procédé d'imprégnation d'un substrat fibreux de fibres longues avec ledit sirop liquide visqueux. L'invention concerne également un substrat fibreux préimprégné avec ledit sirop qui est utile pour la fabrication de pièces composites. Plus particulièrement, la présente invention concerne également un procédé de préparation d'une composition liquide comprenant un monomère (méth) acrylique, un polymère (méth) acrylique et un polymère à phases multiples.
FR1656099A 2016-06-29 2016-06-29 Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci Active FR3053350B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR1656099A FR3053350B1 (fr) 2016-06-29 2016-06-29 Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci
PCT/EP2017/066201 WO2018002260A1 (fr) 2016-06-29 2017-06-29 Composition ou sirop liquide comprenant un polymère à couches multiples et un polymère (méth)acrylique, sirop destiné à un procédé d'imprégnation, procédé d'imprégnation destiné à un substrat fibreux, procédé de polymérisation et article structuré obtenu à partir de ce dernier
US16/311,760 US11142619B2 (en) 2016-06-29 2017-06-29 Liquid composition or syrup comprising a multistage polymer and a (meth)acrylic polymer, syrup for impregnation process, impregnation process for a fibrous substrate, a method of polymerization and structured article obtained thereof
EP17732953.9A EP3478763A1 (fr) 2016-06-29 2017-06-29 Composition ou sirop liquide comprenant un polymère à couches multiples et un polymère (méth)acrylique, sirop destiné à un procédé d'imprégnation, procédé d'imprégnation destiné à un substrat fibreux, procédé de polymérisation et article structuré obtenu à partir de ce dernier
CN201780053563.9A CN109689776A (zh) 2016-06-29 2017-06-29 包含多级聚合物和(甲基)丙烯酸类聚合物的液体组合物或浆液、用于浸渍法的浆液、用于纤维质基材的浸渍法、聚合方法及其获得的结构化制品

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1656099A FR3053350B1 (fr) 2016-06-29 2016-06-29 Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci
FR1656099 2016-06-29

Publications (2)

Publication Number Publication Date
FR3053350A1 FR3053350A1 (fr) 2018-01-05
FR3053350B1 true FR3053350B1 (fr) 2020-03-27

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FR1656099A Active FR3053350B1 (fr) 2016-06-29 2016-06-29 Composition liquide ou sirop comprenant un polymere a phases multiples et un polymere (meth)acrylique, sirop pour procede d'impregnation, procede d'impregnation pour un substrat fibreux, procede depolymerisation et article structure obtenu de celui-ci

Country Status (5)

Country Link
US (1) US11142619B2 (fr)
EP (1) EP3478763A1 (fr)
CN (1) CN109689776A (fr)
FR (1) FR3053350B1 (fr)
WO (1) WO2018002260A1 (fr)

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Publication number Priority date Publication date Assignee Title
FR3053045B1 (fr) * 2016-06-23 2020-06-19 Arkema France Preforme, son procede de preparation, son utilisation et composite comprenant celle-ci
JP7393367B2 (ja) 2018-06-26 2023-12-06 アルケマ フランス 多段ポリマーをベースとする硬化性組成物
GB2575056A (en) * 2018-06-27 2020-01-01 Hexcel Composites Ltd Curable compositions comprising filled multistage polymers
FR3086294A1 (fr) * 2018-09-25 2020-03-27 Arkema France Composition polymere pour vehicules nautiques, son utilisation et vehicule nautique comprenant celui-ci
CN114144163A (zh) 2019-07-31 2022-03-04 阿科玛法国公司 基于光固化性组合物的指甲涂层
EP3838936A1 (fr) * 2019-12-19 2021-06-23 Arkema France Compositions durcissables comprenant des polymères à plusieurs étages
FR3114100B1 (fr) * 2020-09-17 2023-05-12 Melchior Mat And Life Science France Composition fluide pour revetement de surface pour absorption et diffusion de composes volatils
FR3114099B1 (fr) * 2020-09-17 2023-05-26 Ceva Sante Animale Composition fluide pour revetement de surface pour absorption et diffusion de composes volatils

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FR3030546B1 (fr) * 2014-12-22 2018-04-06 Arkema France Sirop (meth)acrylique liquide, procede d'impregnation d'un substrat fibreux par ledit sirop, et materiau composite obtenu apres polymerisation dudit sirop d'impregnation
FR3046605B1 (fr) * 2016-01-11 2019-09-06 Arkema France Composition liquide comprenant un polymere a phases multiples, son procede de preparation et son utilisation
FR3046606B1 (fr) 2016-01-11 2019-09-06 Arkema France Composition (meth)acrylique liquide comprenant un polymere a phases multiples et un monomere (meth)acrylique, son procede de preparation et son utilisation

Also Published As

Publication number Publication date
CN109689776A (zh) 2019-04-26
WO2018002260A1 (fr) 2018-01-04
US11142619B2 (en) 2021-10-12
FR3053350A1 (fr) 2018-01-05
EP3478763A1 (fr) 2019-05-08
US20190233603A1 (en) 2019-08-01

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