JP5882667B2 - 水分散型アクリル系粘着剤組成物、及び粘着シート - Google Patents
水分散型アクリル系粘着剤組成物、及び粘着シート Download PDFInfo
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- JP5882667B2 JP5882667B2 JP2011230109A JP2011230109A JP5882667B2 JP 5882667 B2 JP5882667 B2 JP 5882667B2 JP 2011230109 A JP2011230109 A JP 2011230109A JP 2011230109 A JP2011230109 A JP 2011230109A JP 5882667 B2 JP5882667 B2 JP 5882667B2
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- SJPFBRJHYRBAGV-UHFFFAOYSA-N n-[[3-[[bis(oxiran-2-ylmethyl)amino]methyl]phenyl]methyl]-1-(oxiran-2-yl)-n-(oxiran-2-ylmethyl)methanamine Chemical compound C1OC1CN(CC=1C=C(CN(CC2OC2)CC2OC2)C=CC=1)CC1CO1 SJPFBRJHYRBAGV-UHFFFAOYSA-N 0.000 description 1
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- MDYPDLBFDATSCF-UHFFFAOYSA-N nonyl prop-2-enoate Chemical compound CCCCCCCCCOC(=O)C=C MDYPDLBFDATSCF-UHFFFAOYSA-N 0.000 description 1
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- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
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- 230000000087 stabilizing effect Effects 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- SZWHXXNVLACKBV-UHFFFAOYSA-N tetraethylphosphanium Chemical compound CC[P+](CC)(CC)CC SZWHXXNVLACKBV-UHFFFAOYSA-N 0.000 description 1
- YFZDLRVCXDBOPH-UHFFFAOYSA-N tetraheptylazanium Chemical compound CCCCCCC[N+](CCCCCCC)(CCCCCCC)CCCCCCC YFZDLRVCXDBOPH-UHFFFAOYSA-N 0.000 description 1
- DTIFFPXSSXFQCJ-UHFFFAOYSA-N tetrahexylazanium Chemical compound CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC DTIFFPXSSXFQCJ-UHFFFAOYSA-N 0.000 description 1
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- HOMONHWYLOPSLL-UHFFFAOYSA-N tributyl(ethyl)phosphanium Chemical compound CCCC[P+](CC)(CCCC)CCCC HOMONHWYLOPSLL-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- MEJYOZOPFBOWNM-UHFFFAOYSA-N triethyl(heptyl)azanium Chemical compound CCCCCCC[N+](CC)(CC)CC MEJYOZOPFBOWNM-UHFFFAOYSA-N 0.000 description 1
- TZWFFXFQARPFJN-UHFFFAOYSA-N triethyl(methyl)phosphanium Chemical compound CC[P+](C)(CC)CC TZWFFXFQARPFJN-UHFFFAOYSA-N 0.000 description 1
- WGYXSYLSCVXFDU-UHFFFAOYSA-N triethyl(propyl)azanium Chemical compound CCC[N+](CC)(CC)CC WGYXSYLSCVXFDU-UHFFFAOYSA-N 0.000 description 1
- NRZWQKGABZFFKE-UHFFFAOYSA-N trimethylsulfonium Chemical compound C[S+](C)C NRZWQKGABZFFKE-UHFFFAOYSA-N 0.000 description 1
- LAGQNGWYNLUQRI-UHFFFAOYSA-N trioctylmethylammonium bis(trifluoromethylsulfonyl)imide Chemical compound FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC LAGQNGWYNLUQRI-UHFFFAOYSA-N 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
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- 238000001771 vacuum deposition Methods 0.000 description 1
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- 238000009736 wetting Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/08—Anhydrides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
- C09J9/02—Electrically-conducting adhesives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0075—Antistatics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/19—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
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Description
[式(A)中のRaは、炭素数4から20の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよく、RbおよびRcは、同一または異なって、水素または炭素数1から16の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよい。但し、窒素原子が2重結合を含む場合、Rcはない。]
[式(B)中のRdは、炭素数2から20の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよく、Re、Rf、およびRgは、同一または異なって、水素または炭素数1から16の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよい。]
[式(C)中のRhは、炭素数2から20の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよく、Ri、Rj、およびRkは、同一または異なって、水素または炭素数1から16の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよい。]
[式(D)中のZは、窒素、硫黄、またはリン原子を表し、Rl、Rm、Rn、およびRoは、同一または異なって、炭素数1から20の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよい。但しZが硫黄原子の場合、Roはない。]
[式(E)中のRPは、炭素数1から18の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよい。]
[式(a)中のR1は、水素または炭素数1から3の炭化水素基を表し、R2は、水素または炭素数1から5の炭化水素基を表す。]
[式(b)中のR3は、水素または炭素数1から3の炭化水素基を表し、R4は、水素または炭素数1から5の炭化水素基を表す。]
[式(c)中のR5は、水素または炭素数1から3の炭化水素基を表し、R6は、水素または炭素数1から5の炭化水素基を表す。]
[式(d)中のR7は、水素または炭素数1から3の炭化水素基を表し、R8は、水素または炭素数1から5の炭化水素基を表す。]
前記アクリルエマルション系重合体は、原料モノマーとして、(メタ)アクリル酸アルキルエステルを70〜99.5重量%、及びカルボキシル基含有不飽和モノマーを0.5〜10重量%から構成される重合体である。前記アクリルエマルション系重合体は、単独で又は2種以上組み合わせて使用することができる。なお、本発明では、「(メタ)アクリル」とは「アクリル」及び/又は「メタクリル」のことをいう。
本発明の水分散型アクリル系粘着剤組成物は、HLB(Hydrophile−Lipophile−Blance)値が13未満のアセチレンジオール系化合物、及び/又は、その誘導体(以下、「アセチレンジオール系化合物等」という場合がある。)を、必須成分として含有する。本発明の水分散型アクリル系粘着剤組成物において必須成分である非水溶性(疎水性)イオン液体は、通常、水分散した際に、均一な混合分散がし難く、非水溶性(疎水性)イオン液体が不均一に点在した状態となり、被着体への汚染を引き起こし易くなるが、前記アセチレンジオール系化合物等を含有することにより、それらの問題発生を防止することができる。また、疎水性の非水溶性架橋剤を用いる場合には、非水溶性架橋剤との親和性が増し、非水溶性架橋剤の分散性が向上し、分散不良による凹みを減少させることができる。これらアセチレンジオール系化合物等は、単独で又は2種以上組み合わせて使用することができる。
前記の本発明のアクリルエマルション系重合体のエマルション重合に用いる乳化剤としては、分子中にラジカル重合性官能基が導入された反応性乳化剤(ラジカル重合性官能基を含む反応性乳化剤)を用いることが好ましい。これらの乳化剤は単独でまたは2種以上が用いられる。
アクリルエマルション系重合体約0.1gを採取し、平均孔径0.2μmの多孔質テトラフルオロエチレンシート(商品名「NTF1122」、日東電工株式会社製)に包んだ後、凧糸で縛り、その際の重量を測定し、該重量を浸漬前重量とする。なお、該浸漬前重量は、アクリルエマルション系重合体(上記で採取したもの)と、テトラフルオロエチレンシートと、凧糸の総重量である。また、テトラフルオロエチレンシートと凧糸の合計重量も測定しておき、該重量を包袋重量とする。
溶剤不溶分(重量%)=(a−b)/(c−b)×100 (1)
(式(1)において、aは浸漬後重量であり、bは包袋重量であり、cは浸漬前重量である。)
GPC測定は、東ソー株式会社製GPC装置「HLC−8220GPC」を用いて行い、ポリスチレン換算値にて分子量を求める。測定条件は下記の通りである。
サンプル濃度:0.2重量%(THF溶液)
サンプル注入量:10μl
溶離液:THF
流速:0.6ml/min
測定温度:40℃
カラム:
サンプルカラム;TSKguardcolumn SuperHZ−H 1本+TSKgel SuperHZM−H 2本
リファレンスカラム;TSKgel SuperH−RC 1本
検出器:示差屈折計
特に、本発明においては、架橋剤として、非水溶性架橋剤を使用することが好ましい。なお、前記非水溶性架橋剤とは、非水溶性の化合物であり、分子中(1分子中)にカルボキシル基と反応しうる官能基を2個以上(例えば、2〜6個)有する化合物である。1分子中のカルボキシル基と反応しうる官能基の個数は3〜5個が好ましい。1分子中のカルボキシル基と反応しうる官能基の個数が多くなるほど、粘着剤組成物が密に架橋する(即ち、粘着剤層を形成するポリマーの架橋構造が密になる)。このため、粘着剤層形成後の粘着剤層のぬれ広がりを防ぐことが可能となる。また、粘着剤層を形成するポリマーが拘束されるため、粘着剤層中の官能基(カルボキシル基)が被着体面に偏析して、粘着剤層と被着体との剥離力(粘着力)が経時で上昇することを防ぐことが可能となる。一方、1分子中のカルボキシル基と反応しうる官能基の個数が6個を超えて多すぎる場合には、ゲル化物が生じる場合がある。
同重量の水(25℃)と架橋剤を、攪拌機を用いて回転数300rpm、10分の条件で混合し、遠心分離により水相と油相に分ける。次いで、水相を採取し120℃で1時間乾燥して、乾燥減量から水相中の不揮発分(水100重量部に対する不揮発成分の重量部)を求める。
非水溶性架橋剤の有するカルボキシル基と反応しうる官能基のモル数=[非水溶性架橋剤の配合量(配合量)]/[官能基当量]=4/110
例えば、非水溶性架橋剤として、エポキシ当量が110(g/eq)のエポキシ系架橋剤を4g添加(配合)する場合、エポキシ系架橋剤の有するエポキシ基のモル数は、例えば、以下のように算出できる。
エポキシ系架橋剤の有するエポキシ基のモル数=[エポキシ系架橋剤の配合量(配合量)]/[エポキシ当量]=4/110
本発明の水分散型アクリル系粘着剤組成物は、非水溶性(疎水性)イオン液体を必須成分として含有する。前記非水溶性(疎水性)イオン液体を含有することにより、得られる粘着剤層(粘着シート)を被着体(被保護体)に貼付後、剥離する際に、帯電防止が図られていない被着体に対して、帯電防止性を付与することができる。また、前記非水溶性(疎水性)イオン液体は、前記アクリルエマルション系重合体との相溶性、及びバランスの良い相互作用が期待できる。なお、非水溶性(疎水性)イオン液体とは、25℃で液状を呈する溶融塩(イオン性化合物)をいい、10重量%水溶液を作製した際に、分離・白濁するものを意味する。
N,N−ジエチル−N−メチル−N−ヘプチルアンモニウムビス(トリフルオロメタンスルホニル)イミド、N,N−ジエチル−N−プロピル−N−ペンチルアンモニウムビス(トリフルオロメタンスルホニル)イミド、トリエチルプロピルアンモニウムビス(トリフルオロメタンスルホニル)イミド、トリエチルペンチルアンモニウムビス(トリフルオロメタンスルホニル)イミド、トリエチルヘプチルアンモニウムビス(トリフルオロメタンスルホニル)イミド、N,N−ジプロピル−N−メチル−N−エチルアンモニウムビス(トリフルオロメダンスルホニル)イミド、N,N−ジプロピル−N−メチル−N−ペンチルアンモニウムビス(トリフルオロメタンスルホニル)イミド、N,N−ジプロピル−N−ブチル−N−へキシルアンモニウムビス(トリフルオロメタンスルホニル)イミド、N,N−ジプロピル−N,N−ジヘキシルアンモニウムビス(トリフルオロメタンスルホニル)イミド、N,N−ジブチル−N−メチル−N−ペンチルアンモニウムビス(トリフルオロメタンスルホニル)イミド、N,N−ジブチル−N−メチル−N−ヘキシルアンモニウムビス(トリフルオロメタンスルホニル)イミド、トリオクチルメチルアンモニウムビス(トリフルオロメタンスルホニル)イミド、N−メチル−N−エチル−N−プロピル−N−ペンチルアンモニウムビス(トリフルオロメタンスルホニル)イミド、1−ブチルピリジニウム(トリフルオロメタンスルホニル)トリフルオロアセトアミド、1−ブチル−3−メチルピリジニウム(トリフルオロメタンスルホニル)トリフルオロアセトアミド、1−エチル−3−メチルイミダゾリウム(トリフルオロメタンスルホニル)トリフルオロアセトアミド、1−メチル−1−プロピルピロリジニウムビス(フルオロスルホニル)イミド、1−メチル−1−プロピルピロリジニウムビス(フルオロスルホニル)イミド、1−メチル−1−プロピルピペリジニウムビス(フルオロスルホニル)イミドなどであり、構造的な特徴としては、アニオン成分としてビス(トリフルオロメタンスルホニル)イミド、ビス(ペンタフルオロエタンスルホニル)イミド、ビス(フルオロスルホニル)イミド、トリス(トリフルオロメタンスルホニル)メチド、(トリフルオロメタンスルホニル)トリフルオロアセトアミド、ビス(フルオロスルホニル)イミドを有すものが挙げられる。
本発明の水分散型アクリル系粘着剤組成物は、以下に示す特定の構造を有するポリエーテル型消泡剤を含有することができる。前記ポリエーテル型消泡剤は、下記式(III)で表される化合物である。
HO−(PO)n1(EO)m1−H (III)
HO−(PO)a−(EO)b−(PO)c−H (IV)
本発明の水分散型アクリル系粘着剤組成物(粘着剤組成物)は、上述の通り、本発明のアクリルエマルション系重合体、非水溶性(疎水性)イオン液体、および特定のHLB値を有するアセチレンジオール系化合物等を必須の成分として含有する。さらに、必要に応じて、その他の各種添加剤を含有してよい。
粘着剤組成物を、シリコーンで表面処理したPETフィルム(三菱樹脂(株)製、「MRF38」)のシリコーン処理面上に、乾燥後の厚さが50μmとなるようにコーティングして、その後、熱風循環式オーブンで120℃で2分間乾燥させて、50℃で3日間養生を行い、架橋後のアクリル系粘着剤皮膜を得た。
次いで、前記架橋皮膜(架橋後のアクリル系粘着剤皮膜)を丸めて、円柱状のサンプル(長さ50mm、断面積(底面積)1mm2)を作製した。
引張試験機を用いて、23℃、50%RHの環境下、測定を行った。測定の初期長(初期のチャック間隔)が10mmとなるように、チャックを設定し、引張速度50mm/minの条件で引張試験を行い、破断点の伸び[破断伸び(破断点伸度)]を測定した。
なお、破断伸び(破断点伸度)は、引張試験で、試験片(架橋皮膜の円柱状サンプル)が破断したときの伸びを表し、下記の式で計算される。
「破断伸び(破断点伸度)」(%)=100×(「破断時の試験片の長さ(破断時のチャック間隔)」−「初期長(10mm)」)/(「初期長(10mm)」)
本発明の粘着剤層(粘着シート)は、前記水分散型アクリル系粘着剤組成物により形成される。粘着剤層の形成方法は特に限定されず、公知慣用の粘着剤層の形成方法を用いることができる。粘着剤層の形成は、基材又は剥離フィルム(剥離ライナー、セパレータ)上に、前記粘着剤組成物を塗布した後、乾燥することより形成することができる。なお、粘着剤層を剥離(離型)フィルムに形成した場合には、前記粘着剤層を、基材に貼り合せて転写する。
次に、前記の架橋皮膜をテトラフルオロエチレンシートで包み、凧糸で縛ったもの(「サンプル」と称する)を、酢酸エチルで満たした50ml容器に入れ、23℃にて7日間静置した。その後、容器からサンプル(酢酸エチル処理後)を取り出して、アルミニウム製カップに移し、130℃で2時間、乾燥機中で乾燥して酢酸エチルを除去した後、重量を測定し、該重量を浸漬後重量とした。そして、下記の式から溶剤不溶分を算出した。
溶剤不溶分(重量%)=(d−e)/(f−e)×100
(前記の式において、dは浸漬後重量であり、eは包袋重量であり、fは浸漬前重量である。)
本発明の水分散型アクリル系粘着剤組成物は、帯電防止性、粘着性(接着性)、及び、再剥離性(軽剥離性、易剥離性)に優れ、再剥離が可能な粘着剤層を形成しうる粘着剤組成物であり、再剥離される用途に用いられる粘着剤層を形成するために用いられる。即ち、前記粘着剤層を有する粘着シートは再剥離される用途[例えば、建築養生用マスキングテープ、自動車塗装用マスキングテープ、電子部品(リードフレーム、プリント基板等)用マスキングテープ、サンドブラスト用マスキングテープなどのマスキングテープ類、アルミサッシ用表面保護フィルム、光学プラスチック用表面保護フィルム、光学ガラス用表面保護フィルム、自動車保護用表面保護フィルム、金属板用表面保護フィルムなどの表面保護フィルム類、バックグラインドテープ、ペリクル固定用テープ、ダイシング用テープ、リードフレーム固定用テープ、クリーニングテープ、除塵用テープ、キャリアテープ、カバーテープなどの半導体・電子部品製造工程用粘着テープ類、電子機器や電子部品の梱包用テープ類、輸送時の仮止めテープ類、結束用テープ類、ラベル類]等に好ましく用いられる。
(アクリルエマルション系重合体の調製)
容器に、水90重量部、及び、表1に示すように、アクリル酸2−エチルヘキシル(2EHA)96重量部、アクリル酸(AA)4重量部、反応性ノニオンアニオン系乳化剤[(株)ADEKA製、商品名「アデカリアソープSE−10N」]3重量部を配合した後、ホモミキサーにより攪拌混合し、モノマーエマルションを調製した。
前記アクリルエマルション系重合体の水分散液に、アクリルエマルション系重合体(固形分)100重量部に対して、非水溶性架橋剤であるエポキシ系架橋剤[三菱ガス化学(株)製、商品名「TETRAD−C」、1,3−ビス(N,N−ジグリシジルアミノメチル)シクロヘキサン、エポキシ当量:110、官能基数:4]3重量部、HLB値が13未満のアセチレンジオール系化合物[エアープロダクツ社製、商品名「サーフィノール104PG−50、HLB値:4、有効成分50重量% ]1重量部、非水溶性イオン液体[日本カーリット(株)製、商品名「CIL−312」、N−ブチル−3−メチルピリジニウムビス(トリフルオロメタンスルホニル)イミド]1重量部を、攪拌機を用いて、23℃、300rpm、10分の攪拌条件で攪拌混合し、水分散型アクリル系粘着剤組成物を調製した。
さらに、前記水分散型アクリル系粘着剤組成物を、PETフィルム(東洋紡績(株)製、商品名「E7415」、厚さ:38μm)のコロナ処理面上に、テスター産業(株)製アプリケーターを用いて、乾燥後の厚さが15μmとなるように塗布(コーティング)し、その後、熱風循環式オーブンで、120℃で2分間乾燥させ、さらにその後、室温で1週間養生(エージング)して、粘着シートを得た。
表1及び2に示すように、原料モノマー及びイオン液体等の種類、配合量等を変更し、実施例1と同様にして、モノマーエマルションを調製した。なお、表中に記載のない添加剤については、実施例1と同様の配合量で調製した。また、前記モノマーエマルションを用い、実施例1と同様にして、水分散型アクリル系粘着剤組成物および粘着シートを得た。
実施例および比較例で得られた水分散型アクリル系粘着剤組成物および粘着シートについて、下記の測定方法又は評価方法により評価を行った。なお、評価結果については、表1及び2に示した。
作製した粘着シートを幅70mm、長さ130mmのサイズにカットし、セパレータを剥離した後、あらかじめ除電しておいたアクリル板(三菱レイヨン社製、アクリライト、厚み:1mm、幅:70mm、長さ:100mm)に貼り合わせた偏光板(日東電工(株)製、商品名「SEG1425DU」表面に、片方の端部が30mmはみ出すようにハンドローラーにて圧着した。続いて、23℃×24±2%RHの環境下に一日放置した後、図1に示すように所定の位置にサンプルをセットする。30mmはみ出した片方の端部を自動巻取り機に固定し、剥離角度150°、剥離速度10m/minとなるように剥離した。このときに発生する偏光板表面の電位を所定の位置に固定してある電位測定機(春日電機社製、KSD−0103)にて測定した。サンプルと電位測定機との距離はアクリル板表面測定時100mmとした。なお、測定は23℃×24±2%RHの環境下で行った。
(初期剥離力)
作製した粘着シートを幅25mm、長さ100mmのサイズにカットし、セパレータを剥離した後、貼り合わせ機(テスター産業(株)製、小型貼り合わせ機)を用いて、偏光板(日東電工社製、SEG1425DU、幅:70mm、長さ:100mm)に0.25MPa、0.3m/minの条件でラミネートし、評価サンプルを作製した。
ラミネート後、23℃×50%RHの環境下に30分間放置した後、万能引張試験機にて剥離速度0.3m/min、剥離角度180°で剥離したときの剥離力(粘着力)(N/25mm)を測定し、「初期剥離力」とした。測定は23℃×50%RHの環境下で行った。
また、前記の粘着シートと、偏光板との貼り合わせサンプルを、40℃の環境下に、1週間保存した後、23℃50%RHの環境下に2時間放置した後、剥離速度0.3m/minにて180°剥離試験を行い、粘着シートの偏光板に対する剥離力(粘着力)(N/25mm)を測定し、「経時剥離力」とした。
実施例および比較例で得られた粘着シート(サンプルサイズ:25mm幅×100mm長さ)を、貼り合わせ機(テスター産業(株)製、小型貼り合せ機)を用いて、0.25MPa、0.3m/minの条件で、偏光板(日東電工(株)製、商品名「SEG1425DU」、サイズ:70mm幅×120mm長さ)上に貼り合わせた。
低汚染性良好(○):粘着シートを貼付した部分と貼付していない部分で変化が見られなかった。
低汚染性不良(×):粘着シートを貼付した部分に白化が見られた。
実施例および比較例で得られた粘着シートの、粘着剤層表面の状態を目視で観察した。縦10cm×横10cmの観察範囲内の欠点(凹み及びゲル物)の個数を測定し、以下の基準で評価した。
欠点個数が0〜100個:外観が良好である(○)。
欠点個数が101個以上:外観が悪い(×)。
2EHA:アクリル酸2−エチルヘキシル
AA:アクリル酸
MMA:メタクリル酸メチル
DAAM:ダイアセトンアクリルアミド
SE−10N:(株)ADEKA製、商品名「アデカリアソープSE−10N」(反応性ノニオンアニオン系乳化剤)
TETRAD−C:三菱ガス化学(株)製、商品名「TETRAD−C」(1,3−ビス(N,N−ジグリシジルアミノメチル)シクロヘキサン、エポキシ当量:110、官能基数:4)(非水溶性架橋剤)
アジピン酸ヒドラジド:東京化成工業(株)製(水溶性架橋剤)
サーフィノール104H:エアープロダクツ社製、商品名「サーフィノール104H」(HLB値:4、有効成分75重量%、アセチレンジオール系化合物)
サーフィノール104PG−50:エアープロダクツ社製、商品名「サーフィノール104PG−50」(HLB値:4、有効成分50重量%、アセチレンジオール系化合物)
サーフィノール420:エアープロダクツ社製、商品名「サーフィノール420」(HLB値:4、有効成分100重量%、アセチレンジオール系化合物)
サーフィノール440:エアープロダクツ社製、商品名「サーフィノール440」(HLB値:8、有効成分100重量%、アセチレンジオール系化合物)
サーフィノール465:エアープロダクツ社製、商品名「サーフィノール465」(HLB値:13、有効成分100重量%、アセチレンジオール系化合物)
CIL−312:日本カーリット(株)製、N−ブチル−3−メチルピリジニウムビス(トリフルオロメタンスルホニル)イミド(非水溶性)
IL−120:第一工業製薬(株)製、1−メチル−1−プロピルピロリジニウムビス(フルオロスルホニル)イミド(非水溶性)
IL−210:第一工業製薬(株)製、1−エチル−3−メチルイミダゾリウムビス(トリフルオロメタンスルホニル)イミド(非水溶性)
IL−230:第一工業製薬(株)製、1−メチル−1−プロピルピペリジニウムビス(トリフルオロメタンスルホニル)イミド(非水溶性)
25R−2:(株)ADEKA製、商品名「アデカプルロニック25R−2」(PO含有率:80重量%、数平均分子量:3000、ポリエーテル型消泡剤)
17R−3:(株)ADEKA製、商品名「アデカプルロニック17R−3」(PO含有率:70重量%、数平均分子量:2200、ポリエーテル型消泡剤)
2 粘着シート
3 偏光板
4 アクリル板
5 サンプル固定台
Claims (12)
- 水分散型アクリル系粘着剤組成物を用いて形成された粘着剤層であって、
前記水分散型アクリル系粘着剤組成物が、(メタ)アクリル酸アルキルエステル70〜99.5重量%、及び、カルボキシル基含有不飽和モノマー0.5〜10重量%を、モノマー成分として構成されるアクリルエマルション系重合体、非水溶性イオン液体、及び、HLB値が13未満のアセチレンジオール系化合物、及び/又は、その誘導体を含有し、
前記粘着剤層のゲル分率が、90重量%以上であることを特徴とする粘着剤層。 - 前記アクリルエマルション系重合体の固形分100重量部に対して、前記アセチレンジオール系化合物、及び/又は、その誘導体を0.01〜10重量部含有することを特徴とする請求項1に記載の粘着剤層。
- 前記イオン液体が、フッ素を含むことを特徴とする請求項1又は2に記載の粘着剤層。
- 前記イオン液体が、イミド塩であることを特徴とする請求項1〜3のいずれかに記載の粘着剤層。
- 前記イオン液体が、下記式(A)〜(E)で表わされるカチオンからなる群より選択される少なくとも1種のカチオンを含有することを特徴とする請求項1〜4のいずれかに記載の粘着剤層。
[式(A)中のRaは、炭素数4から20の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよく、RbおよびRcは、同一または異なって、水素または炭素数1から16の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよい。但し、窒素原子が2重結合を含む場合、Rcはない。]
[式(B)中のRdは、炭素数2から20の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよく、Re、Rf、およびRgは、同一または異なって、水素または炭素数1から16の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよい。]
[式(C)中のRhは、炭素数2から20の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよく、Ri、Rj、およびRkは、同一または異なって、水素または炭素数1から16の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよい。]
[式(D)中のZは、窒素、硫黄、またはリン原子を表し、Rl、Rm、Rn、およびRoは、同一または異なって、炭素数1から20の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよい。但しZが硫黄原子の場合、Roはない。]
[式(E)中のRPは、炭素数1から18の炭化水素基を表し、前記炭化水素基の一部がヘテロ原子で置換された官能基であってもよい。] - 前記イオン液体が、下記一般式(a)〜(d)で表される1種以上のカチオンを含むことを特徴とする請求項1〜5のいずれかに記載の粘着剤層。
[式(a)中のR1は、水素または炭素数1から3の炭化水素基を表し、R2は、水素または炭素数1から5の炭化水素基を表す。]
[式(b)中のR3は、水素または炭素数1から3の炭化水素基を表し、R4は、水素または炭素数1から5の炭化水素基を表す。]
[式(c)中のR5は、水素または炭素数1から3の炭化水素基を表し、R6は、水素または炭素数1から5の炭化水素基を表す。]
[式(d)中のR7は、水素または炭素数1から3の炭化水素基を表し、R8は、水素または炭素数1から5の炭化水素基を表す。] - 前記アクリルエマルション系重合体の固形分100重量部に対して、前記イオン液体を4.9重量部以下含有することを特徴とする請求項1〜6のいずれかに記載の粘着剤層。
- 前記アクリルエマルション系重合体が、分子中にラジカル重合性官能基を含む反応性乳化剤を用いて重合された重合体であることを特徴とする請求項1〜7のいずれかに記載の粘着剤層。
- 更に、分子中にカルボキシル基と反応し得る官能基を2個以上有する非水溶性架橋剤を含有することを特徴とする請求項1〜8のいずれかに記載の粘着剤層。
- 基材の少なくとも片面側に、請求項1〜9のいずれかに記載の粘着剤層を有することを特徴とする粘着シート。
- 光学部材用の表面保護フィルムであることを特徴とする請求項10に記載の粘着シート。
- 前記粘着剤層の偏光板に対する、23℃×50%RH条件下で、剥離速度0.3m/min、剥離角度180°で剥離したときの初期剥離力が、0.03〜0.5N/25mmであることを特徴とする請求項10又は11に記載の粘着シート。
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JP5561539B2 (ja) * | 2009-09-09 | 2014-07-30 | Dic株式会社 | 粘着テープ |
JP5967688B2 (ja) * | 2009-09-16 | 2016-08-10 | Dic株式会社 | 遮光性粘着剤組成物及び遮光性粘着テープ |
JP5561543B2 (ja) * | 2009-09-24 | 2014-07-30 | Dic株式会社 | 粘着テープ |
JP5561544B2 (ja) * | 2009-09-30 | 2014-07-30 | Dic株式会社 | 粘着テープ |
JP6133109B2 (ja) * | 2013-04-09 | 2017-05-24 | 日東電工株式会社 | 粘着剤組成物、及び粘着シート |
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2011
- 2011-10-19 JP JP2011230109A patent/JP5882667B2/ja active Active
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- 2012-10-12 CN CN201280044185.5A patent/CN103781866B/zh active Active
- 2012-10-12 US US14/352,435 patent/US20140255690A1/en not_active Abandoned
- 2012-10-12 KR KR1020147002397A patent/KR101951499B1/ko active IP Right Grant
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TWI564358B (zh) | 2017-01-01 |
US20140255690A1 (en) | 2014-09-11 |
WO2013058187A1 (ja) | 2013-04-25 |
KR101951499B1 (ko) | 2019-02-22 |
KR20140079352A (ko) | 2014-06-26 |
CN103781866B (zh) | 2017-07-28 |
CN103781866A (zh) | 2014-05-07 |
TW201335308A (zh) | 2013-09-01 |
JP2013087227A (ja) | 2013-05-13 |
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