JP5803265B2 - 炭化珪素基板および炭化珪素インゴットの製造方法 - Google Patents
炭化珪素基板および炭化珪素インゴットの製造方法 Download PDFInfo
- Publication number
- JP5803265B2 JP5803265B2 JP2011113341A JP2011113341A JP5803265B2 JP 5803265 B2 JP5803265 B2 JP 5803265B2 JP 2011113341 A JP2011113341 A JP 2011113341A JP 2011113341 A JP2011113341 A JP 2011113341A JP 5803265 B2 JP5803265 B2 JP 5803265B2
- Authority
- JP
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- Prior art keywords
- silicon carbide
- region
- ingot
- substrate
- nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 title claims description 395
- 229910010271 silicon carbide Inorganic materials 0.000 title claims description 387
- 239000000758 substrate Substances 0.000 title claims description 354
- 238000000034 method Methods 0.000 title claims description 78
- 238000004519 manufacturing process Methods 0.000 title claims description 53
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 426
- 229910052757 nitrogen Inorganic materials 0.000 claims description 310
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 191
- 238000002834 transmittance Methods 0.000 claims description 59
- 230000002093 peripheral effect Effects 0.000 claims description 20
- 238000011144 upstream manufacturing Methods 0.000 claims description 11
- 230000001154 acute effect Effects 0.000 claims description 7
- 229910021421 monocrystalline silicon Inorganic materials 0.000 claims description 6
- 230000005540 biological transmission Effects 0.000 claims description 2
- 239000013078 crystal Substances 0.000 description 55
- 239000010410 layer Substances 0.000 description 51
- 230000000052 comparative effect Effects 0.000 description 17
- 238000005259 measurement Methods 0.000 description 17
- 238000010438 heat treatment Methods 0.000 description 12
- 238000009826 distribution Methods 0.000 description 11
- 238000000227 grinding Methods 0.000 description 11
- 239000004065 semiconductor Substances 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 239000011295 pitch Substances 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 238000005520 cutting process Methods 0.000 description 7
- 238000012986 modification Methods 0.000 description 7
- 230000004048 modification Effects 0.000 description 7
- 238000012805 post-processing Methods 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 238000010586 diagram Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 238000001004 secondary ion mass spectrometry Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 238000007517 polishing process Methods 0.000 description 2
- 239000006061 abrasive grain Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000013507 mapping Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000000191 radiation effect Effects 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 238000001226 reprecipitation Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000005092 sublimation method Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B23/00—Single-crystal growth by condensing evaporated or sublimed materials
- C30B23/02—Epitaxial-layer growth
- C30B23/025—Epitaxial-layer growth characterised by the substrate
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/36—Carbides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/21—Circular sheet or circular blank
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
- Y10T428/24322—Composite web or sheet
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011113341A JP5803265B2 (ja) | 2011-05-20 | 2011-05-20 | 炭化珪素基板および炭化珪素インゴットの製造方法 |
| CN2012800193499A CN103476975A (zh) | 2011-05-20 | 2012-03-30 | 碳化硅衬底、碳化硅锭以及制造碳化硅衬底和碳化硅锭的方法 |
| PCT/JP2012/058527 WO2012160872A1 (ja) | 2011-05-20 | 2012-03-30 | 炭化珪素基板、炭化珪素インゴットおよびそれらの製造方法 |
| DE112012002192.4T DE112012002192T5 (de) | 2011-05-20 | 2012-03-30 | Siliziumcarbidsubstrat, Ingot aus Siliziumcarbid, und Verfahren zur Herstellung eines Siliziumcarbidsubstrats und eines Ingots aus Siliziumcarbid |
| US13/472,922 US20120294790A1 (en) | 2011-05-20 | 2012-05-16 | Silicon carbide substrate, silicon carbide ingot, and methods for manufacturing silicon carbide substrate and silicon carbide ingot |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011113341A JP5803265B2 (ja) | 2011-05-20 | 2011-05-20 | 炭化珪素基板および炭化珪素インゴットの製造方法 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015172850A Division JP6036947B2 (ja) | 2015-09-02 | 2015-09-02 | 炭化珪素基板および炭化珪素インゴットの製造方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012240892A JP2012240892A (ja) | 2012-12-10 |
| JP2012240892A5 JP2012240892A5 (https=) | 2014-02-27 |
| JP5803265B2 true JP5803265B2 (ja) | 2015-11-04 |
Family
ID=47175050
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011113341A Expired - Fee Related JP5803265B2 (ja) | 2011-05-20 | 2011-05-20 | 炭化珪素基板および炭化珪素インゴットの製造方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20120294790A1 (https=) |
| JP (1) | JP5803265B2 (https=) |
| CN (1) | CN103476975A (https=) |
| DE (1) | DE112012002192T5 (https=) |
| WO (1) | WO2012160872A1 (https=) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5857986B2 (ja) | 2013-02-20 | 2016-02-10 | 株式会社デンソー | 炭化珪素単結晶および炭化珪素単結晶の製造方法 |
| JP6233058B2 (ja) * | 2013-09-25 | 2017-11-22 | 住友電気工業株式会社 | 炭化珪素半導体基板の製造方法 |
| JP2015098420A (ja) * | 2013-11-20 | 2015-05-28 | 住友電気工業株式会社 | 炭化珪素インゴットおよび炭化珪素基板の製造方法 |
| US10711369B2 (en) | 2014-12-05 | 2020-07-14 | Showa Denko K.K. | Method for producing silicon carbide single crystal and silicon carbide single crystal substrate |
| KR102106722B1 (ko) | 2015-07-29 | 2020-05-04 | 쇼와 덴코 가부시키가이샤 | 에피택셜 탄화규소 단결정 웨이퍼의 제조 방법 |
| JP6729605B2 (ja) * | 2016-02-09 | 2020-07-22 | 住友電気工業株式会社 | 炭化珪素単結晶基板 |
| JP7406914B2 (ja) * | 2018-07-25 | 2023-12-28 | 株式会社デンソー | SiCウェハ及びSiCウェハの製造方法 |
| CN112513348B (zh) | 2018-07-25 | 2023-11-14 | 株式会社电装 | SiC晶片和SiC晶片的制造方法 |
| JP7393900B2 (ja) * | 2019-09-24 | 2023-12-07 | 一般財団法人電力中央研究所 | 炭化珪素単結晶ウェハ及び炭化珪素単結晶インゴットの製造方法 |
| KR102234002B1 (ko) * | 2019-10-22 | 2021-03-29 | 에스케이씨 주식회사 | 탄화규소 잉곳, 이의 제조방법 및 탄화규소 웨이퍼의 제조방법 |
| CN114264652B (zh) * | 2021-12-09 | 2024-11-29 | 浙江大学杭州国际科创中心 | 碳化硅中位错产生及演变的逆向分析方法 |
| JP2024053501A (ja) * | 2022-10-03 | 2024-04-15 | 一般財団法人電力中央研究所 | 炭化珪素単結晶の製造方法及び炭化珪素単結晶インゴット |
| WO2024162069A1 (ja) * | 2023-02-02 | 2024-08-08 | 住友電気工業株式会社 | 炭化珪素基板、炭化珪素エピタキシャル基板の製造方法および炭化珪素半導体装置の製造方法 |
| JP7852690B2 (ja) * | 2023-12-28 | 2026-04-28 | 株式会社レゾナック | SiCインゴット及びSiC基板の製造方法 |
| JP7852691B2 (ja) * | 2023-12-28 | 2026-04-28 | 株式会社レゾナック | SiCインゴット、SiC基板の製造方法およびSiCインゴットの評価方法 |
| KR20250103414A (ko) * | 2023-12-28 | 2025-07-07 | 가부시끼가이샤 레조낙 | SiC 잉곳 및 SiC 기판의 제조 방법 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10247017B4 (de) * | 2001-10-12 | 2009-06-10 | Denso Corp., Kariya-shi | SiC-Einkristall, Verfahren zur Herstellung eines SiC-Einkristalls, SiC-Wafer mit einem Epitaxiefilm und Verfahren zur Herstellung eines SiC-Wafers, der einen Epitaxiefilm aufweist |
| JP3764462B2 (ja) * | 2003-04-10 | 2006-04-05 | 株式会社豊田中央研究所 | 炭化ケイ素単結晶の製造方法 |
| EP1619276B1 (en) * | 2004-07-19 | 2017-01-11 | Norstel AB | Homoepitaxial growth of SiC on low off-axis SiC wafers |
| JP4926556B2 (ja) * | 2006-06-20 | 2012-05-09 | 新日本製鐵株式会社 | 炭化珪素単結晶インゴットの製造方法及び炭化珪素単結晶基板 |
| JP2008071896A (ja) * | 2006-09-13 | 2008-03-27 | Nippon Steel Corp | 金属−絶縁膜−炭化珪素半導体構造 |
-
2011
- 2011-05-20 JP JP2011113341A patent/JP5803265B2/ja not_active Expired - Fee Related
-
2012
- 2012-03-30 CN CN2012800193499A patent/CN103476975A/zh active Pending
- 2012-03-30 WO PCT/JP2012/058527 patent/WO2012160872A1/ja not_active Ceased
- 2012-03-30 DE DE112012002192.4T patent/DE112012002192T5/de not_active Withdrawn
- 2012-05-16 US US13/472,922 patent/US20120294790A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CN103476975A (zh) | 2013-12-25 |
| US20120294790A1 (en) | 2012-11-22 |
| JP2012240892A (ja) | 2012-12-10 |
| DE112012002192T5 (de) | 2014-03-13 |
| WO2012160872A1 (ja) | 2012-11-29 |
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