JP5738317B2 - 脱硫装置及び燃料電池システム - Google Patents
脱硫装置及び燃料電池システム Download PDFInfo
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- JP5738317B2 JP5738317B2 JP2012550901A JP2012550901A JP5738317B2 JP 5738317 B2 JP5738317 B2 JP 5738317B2 JP 2012550901 A JP2012550901 A JP 2012550901A JP 2012550901 A JP2012550901 A JP 2012550901A JP 5738317 B2 JP5738317 B2 JP 5738317B2
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- desulfurization
- flow path
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
- C10L3/102—Removal of contaminants of acid contaminants
- C10L3/103—Sulfur containing contaminants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
- C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04014—Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
- H01M8/0675—Removal of sulfur
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Fuel Cell (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Description
Claims (4)
- 水素含有燃料を用いてセルスタックにより発電するとともに熱媒体を用いて前記セルスタックの排熱を回収する燃料電池システムに用いられる脱硫装置であって、
脱硫触媒を収容した脱硫流路を有し、前記水素含有燃料を流体入口から流体出口まで延びる前記脱硫流路に流通させて脱硫する脱硫部と、
前記脱硫部の側方を覆うように配置され、前記セルスタックの排熱を回収した後の前記熱媒体を流通させて前記熱媒体と前記脱硫部とを熱交換させる熱媒体流路を有する熱交換部と、を備え、
前記熱媒体流路の流体流通方向及び前記脱硫流路の流体流通方向が対向流となるように形成されており、
前記脱硫流路の内部において、前記流体入口側及び前記流体出口側に前記流体の流れを変更する邪魔板が設けられ、
前記流体入口側の前記邪魔板は、前記流体入口から離間して、前記脱硫触媒が収容されている部分の内部に配置され、
前記流体出口側の前記邪魔板は、前記流体出口から離間して、前記脱硫触媒が収容されている部分の内部に配置されており、
前記脱硫流路には、前記流体入口から一方側へ流通する前記水素含有燃料を一方側とは反対の他方側へ流通させる折返し部が形成され、前記流体入口から前記折返し部までの前記脱硫流路が、前記熱媒体流路と隣接するように配置されており、
前記流体入口から前記折返し部までの前記脱硫流路の流体流通方向と、前記熱媒体流路の流体流通方向及び前記折返し部から前記流体出口までの前記脱硫流路の流体流通方向とが、対向流となるように形成され、
前記脱硫流路の内部において、前記折返し部に前記流体の流れを変更する邪魔板が設けられていること、を特徴とする脱硫装置。 - 前記流体入口から前記折返し部までの前記脱硫流路は、前記脱硫部の外周壁及び前記脱硫部の内部に設けられた内壁によって画成され、
前記折返し部から前記流体出口までの前記脱硫流路は、前記内壁によって画成され、
前記内壁は、前記流体入口から前記折返し部までの前記脱硫流路と、前記折返し部から前記流体出口までの前記脱硫流路とが同一の体積となるように設けられている請求項1に記載の脱硫装置。 - 前記脱硫部は、円筒を呈し、前記脱硫部の半径と前記脱硫部に収容される所定の触媒量とに基づいて求まる表面積が最小値となるように設定された半径を有する請求項1又は2に記載の脱硫装置。
- 請求項1〜3の何れか一項に記載の脱硫装置を備え、脱硫後の水素含有燃料を用いて発電する燃料電池システム。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012550901A JP5738317B2 (ja) | 2010-12-27 | 2011-12-22 | 脱硫装置及び燃料電池システム |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010289943 | 2010-12-27 | ||
JP2010289943 | 2010-12-27 | ||
JP2012550901A JP5738317B2 (ja) | 2010-12-27 | 2011-12-22 | 脱硫装置及び燃料電池システム |
PCT/JP2011/079836 WO2012090864A1 (ja) | 2010-12-27 | 2011-12-22 | 脱硫装置及び燃料電池システム |
Publications (2)
Publication Number | Publication Date |
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JPWO2012090864A1 JPWO2012090864A1 (ja) | 2014-06-05 |
JP5738317B2 true JP5738317B2 (ja) | 2015-06-24 |
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JP2012550901A Active JP5738317B2 (ja) | 2010-12-27 | 2011-12-22 | 脱硫装置及び燃料電池システム |
Country Status (3)
Country | Link |
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JP (1) | JP5738317B2 (ja) |
TW (1) | TW201238133A (ja) |
WO (1) | WO2012090864A1 (ja) |
Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6454609U (ja) * | 1987-10-01 | 1989-04-04 | ||
JPH01188407A (ja) * | 1988-01-25 | 1989-07-27 | Fuji Electric Co Ltd | 一酸化炭素転化反応器 |
JPH02275203A (ja) * | 1989-04-18 | 1990-11-09 | Ube Ind Ltd | 流動床装置のガス分散板への付着物の付着防止方法およびそのガス分散板 |
JPH04298228A (ja) * | 1991-03-27 | 1992-10-22 | Tokyo Gas Co Ltd | 脱硫反応器 |
JPH06165916A (ja) * | 1992-11-27 | 1994-06-14 | Kawasaki Heavy Ind Ltd | 遠心流動層脱塵・脱硫・脱硝装置 |
JP2004051865A (ja) * | 2002-07-23 | 2004-02-19 | Idemitsu Kosan Co Ltd | 脱硫器及び脱硫方法。 |
JP2004082111A (ja) * | 2002-06-28 | 2004-03-18 | Idemitsu Kosan Co Ltd | 燃焼装置におけるn2o及びnoxの排出抑制方法 |
JP2006032046A (ja) * | 2004-07-14 | 2006-02-02 | Hagio Koatsu Yoki Kk | 脱硫器取付装置 |
JP2007218108A (ja) * | 2006-02-14 | 2007-08-30 | Hino Motors Ltd | 排気浄化装置 |
JP2008063448A (ja) * | 2006-09-07 | 2008-03-21 | Toshiba Fuel Cell Power Systems Corp | 液体燃料脱硫システムとその運転方法 |
JP2009079155A (ja) * | 2007-09-26 | 2009-04-16 | Toshiba Fuel Cell Power Systems Corp | 液体燃料脱硫装置及び液体燃料脱硫システム |
JP2010024402A (ja) * | 2008-07-23 | 2010-02-04 | Toshiba Fuel Cell Power Systems Corp | 燃料電池発電システムおよびそれに用いる脱硫器 |
JP2010067353A (ja) * | 2008-09-08 | 2010-03-25 | Honda Motor Co Ltd | 脱硫装置 |
JP2010272333A (ja) * | 2009-05-21 | 2010-12-02 | Jx Nippon Oil & Energy Corp | 燃料電池システム |
-
2011
- 2011-12-22 WO PCT/JP2011/079836 patent/WO2012090864A1/ja active Application Filing
- 2011-12-22 JP JP2012550901A patent/JP5738317B2/ja active Active
- 2011-12-27 TW TW100148979A patent/TW201238133A/zh unknown
Patent Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6454609U (ja) * | 1987-10-01 | 1989-04-04 | ||
JPH01188407A (ja) * | 1988-01-25 | 1989-07-27 | Fuji Electric Co Ltd | 一酸化炭素転化反応器 |
JPH02275203A (ja) * | 1989-04-18 | 1990-11-09 | Ube Ind Ltd | 流動床装置のガス分散板への付着物の付着防止方法およびそのガス分散板 |
JPH04298228A (ja) * | 1991-03-27 | 1992-10-22 | Tokyo Gas Co Ltd | 脱硫反応器 |
JPH06165916A (ja) * | 1992-11-27 | 1994-06-14 | Kawasaki Heavy Ind Ltd | 遠心流動層脱塵・脱硫・脱硝装置 |
JP2004082111A (ja) * | 2002-06-28 | 2004-03-18 | Idemitsu Kosan Co Ltd | 燃焼装置におけるn2o及びnoxの排出抑制方法 |
JP2004051865A (ja) * | 2002-07-23 | 2004-02-19 | Idemitsu Kosan Co Ltd | 脱硫器及び脱硫方法。 |
JP2006032046A (ja) * | 2004-07-14 | 2006-02-02 | Hagio Koatsu Yoki Kk | 脱硫器取付装置 |
JP2007218108A (ja) * | 2006-02-14 | 2007-08-30 | Hino Motors Ltd | 排気浄化装置 |
JP2008063448A (ja) * | 2006-09-07 | 2008-03-21 | Toshiba Fuel Cell Power Systems Corp | 液体燃料脱硫システムとその運転方法 |
JP2009079155A (ja) * | 2007-09-26 | 2009-04-16 | Toshiba Fuel Cell Power Systems Corp | 液体燃料脱硫装置及び液体燃料脱硫システム |
JP2010024402A (ja) * | 2008-07-23 | 2010-02-04 | Toshiba Fuel Cell Power Systems Corp | 燃料電池発電システムおよびそれに用いる脱硫器 |
JP2010067353A (ja) * | 2008-09-08 | 2010-03-25 | Honda Motor Co Ltd | 脱硫装置 |
JP2010272333A (ja) * | 2009-05-21 | 2010-12-02 | Jx Nippon Oil & Energy Corp | 燃料電池システム |
Also Published As
Publication number | Publication date |
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TW201238133A (en) | 2012-09-16 |
JPWO2012090864A1 (ja) | 2014-06-05 |
WO2012090864A1 (ja) | 2012-07-05 |
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