JP5682947B2 - 反応染料組成物及びそれを用いる染色法 - Google Patents
反応染料組成物及びそれを用いる染色法 Download PDFInfo
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- JP5682947B2 JP5682947B2 JP2010121346A JP2010121346A JP5682947B2 JP 5682947 B2 JP5682947 B2 JP 5682947B2 JP 2010121346 A JP2010121346 A JP 2010121346A JP 2010121346 A JP2010121346 A JP 2010121346A JP 5682947 B2 JP5682947 B2 JP 5682947B2
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- dye
- formula
- reactive dye
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000985 reactive dye Substances 0.000 title claims description 196
- 239000000203 mixture Substances 0.000 title claims description 127
- 238000004043 dyeing Methods 0.000 title claims description 41
- 238000000034 method Methods 0.000 title claims description 30
- 239000000975 dye Substances 0.000 claims description 242
- 239000002253 acid Substances 0.000 claims description 46
- 239000003513 alkali Substances 0.000 claims description 16
- 229920003043 Cellulose fiber Polymers 0.000 claims description 14
- 239000000835 fiber Substances 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 3
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 3
- 238000005562 fading Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 20
- 238000009472 formulation Methods 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 10
- 229910000029 sodium carbonate Inorganic materials 0.000 description 10
- 235000017550 sodium carbonate Nutrition 0.000 description 10
- 238000005406 washing Methods 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 229920000742 Cotton Polymers 0.000 description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 239000003086 colorant Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- GCFAQSYBSUQUPL-UHFFFAOYSA-I pentasodium 5-[[4-chloro-6-[3-(2-sulfonatooxyethylsulfonyl)anilino]-1,3,5-triazin-2-yl]amino]-3-[(1,5-disulfonatonaphthalen-2-yl)diazenyl]-4-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].Oc1c(N=Nc2ccc3c(cccc3c2S([O-])(=O)=O)S([O-])(=O)=O)c(cc2cc(cc(Nc3nc(Cl)nc(Nc4cccc(c4)S(=O)(=O)CCOS([O-])(=O)=O)n3)c12)S([O-])(=O)=O)S([O-])(=O)=O GCFAQSYBSUQUPL-UHFFFAOYSA-I 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- -1 t-butoxy group Chemical group 0.000 description 5
- UIEBGVDTKLYGTN-UHFFFAOYSA-J tetrasodium;7-[[2-(carbamoylamino)-4-[[4-chloro-6-[3-(2-sulfonatooxyethylsulfonyl)anilino]-1,3,5-triazin-2-yl]amino]phenyl]diazenyl]naphthalene-1,3,6-trisulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].C=1C=C(N=NC=2C(=CC3=CC(=CC(=C3C=2)S([O-])(=O)=O)S([O-])(=O)=O)S([O-])(=O)=O)C(NC(=O)N)=CC=1NC(N=1)=NC(Cl)=NC=1NC1=CC=CC(S(=O)(=O)CCOS([O-])(=O)=O)=C1 UIEBGVDTKLYGTN-UHFFFAOYSA-J 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 0 O=C1O*23Oc4ccccc4[N+]2[N-]C(c2ccccc2)=NN3c2ccccc12 Chemical compound O=C1O*23Oc4ccccc4[N+]2[N-]C(c2ccccc2)=NN3c2ccccc12 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000001045 blue dye Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- NSDSIQGBHACTLY-UHFFFAOYSA-N Reactive Blue 5 Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S(O)(=O)=O)C=C1NC(C=1)=CC=C(S(O)(=O)=O)C=1NC(N=1)=NC(Cl)=NC=1NC1=CC=CC(S(O)(=O)=O)=C1 NSDSIQGBHACTLY-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000010014 continuous dyeing Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920000433 Lyocell Polymers 0.000 description 1
- 229920001407 Modal (textile) Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- VNUYTINZGPMAMQ-BSRQYYOTSA-N Oc(c(c(cc1S(O)(=O)=O)cc(S(O)(=O)=O)c2)c2Nc2nc(Cl)nc(Nc3ccccc3)n2)c1/N=N/c(ccc1c2cccc1S(O)(=O)=O)c2S(O)(=O)=O Chemical compound Oc(c(c(cc1S(O)(=O)=O)cc(S(O)(=O)=O)c2)c2Nc2nc(Cl)nc(Nc3ccccc3)n2)c1/N=N/c(ccc1c2cccc1S(O)(=O)=O)c2S(O)(=O)=O VNUYTINZGPMAMQ-BSRQYYOTSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229920006221 acetate fiber Polymers 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 125000002510 isobutoxy group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])O* 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000006606 n-butoxy group Chemical group 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003506 n-propoxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- HFIYIRIMGZMCPC-YOLJWEMLSA-J remazole black-GR Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(\N=N\C=3C=CC(=CC=3)S(=O)(=O)CCOS([O-])(=O)=O)C(O)=C2C(N)=C1\N=N\C1=CC=C(S(=O)(=O)CCOS([O-])(=O)=O)C=C1 HFIYIRIMGZMCPC-YOLJWEMLSA-J 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 238000007447 staining method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
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- Coloring (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010121346A JP5682947B2 (ja) | 2009-05-28 | 2010-05-27 | 反応染料組成物及びそれを用いる染色法 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009128750 | 2009-05-28 | ||
| JP2009128750 | 2009-05-28 | ||
| JP2010121346A JP5682947B2 (ja) | 2009-05-28 | 2010-05-27 | 反応染料組成物及びそれを用いる染色法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2011006671A JP2011006671A (ja) | 2011-01-13 |
| JP5682947B2 true JP5682947B2 (ja) | 2015-03-11 |
Family
ID=43225169
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010121346A Active JP5682947B2 (ja) | 2009-05-28 | 2010-05-27 | 反応染料組成物及びそれを用いる染色法 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP5682947B2 (zh) |
| CN (1) | CN101899226B (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101960807B1 (ko) * | 2017-11-07 | 2019-03-21 | (주)경인양행 | 친환경 반응성 염료 제조방법 |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5638908B2 (ja) * | 2010-10-08 | 2014-12-10 | 日本化薬株式会社 | 反応染料組成物及びそれを用いる染色法 |
| CN102358803B (zh) * | 2011-08-25 | 2013-09-11 | 浙江亿得化工有限公司 | 一种复合黑色活性染料 |
| CN104402781B (zh) * | 2014-12-11 | 2016-06-29 | 吴江桃源染料有限公司 | 一种活性土黄染料半成品的制备方法 |
| CN111032790B (zh) * | 2017-09-01 | 2021-11-23 | 日本化药株式会社 | 反应性染料组合物及使用该反应性染料组合物的染色法 |
| CN111253776B (zh) * | 2020-02-13 | 2022-03-04 | 浙江蓝天海纺织服饰科技有限公司 | 全棉与全棉混纺面料用藏青活性染料配方，及应用 |
| CN114621602B (zh) * | 2022-04-06 | 2023-06-30 | 浙江亿得新材料股份有限公司 | 一种适于复合纤维素纤维染色的活性藏青染料的复配方法及其产品和应用 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4378313B1 (en) * | 1979-06-01 | 1994-05-03 | Sumitomo Chemical Co | Reactive yellow dye having both monochlorotriazinyl and vinylsulfone type reactive groups |
| US4341699A (en) * | 1979-07-13 | 1982-07-27 | Sumitomo Chemical Company, Limited | Reactive red dye having both monochlorotriazinyl- and vinylsulfone-type reactive groups |
| DE2945537A1 (de) * | 1979-11-10 | 1981-05-21 | Hoechst Ag, 6000 Frankfurt | Kupferkomplex-formazanverbindungen, verfahren zu ihrer herstellung und ihre verwendung als farbstoffe |
| JPS56118974A (en) * | 1980-02-16 | 1981-09-18 | Sumitomo Chemical Co | Cheese dyeing of cellulosic fiber |
| JPS56128380A (en) * | 1980-03-14 | 1981-10-07 | Sumitomo Chemical Co | Dyeing of cellulosic fiber |
| JPS60215071A (ja) * | 1985-03-26 | 1985-10-28 | Sumitomo Chem Co Ltd | 繊維反応性ジスアゾ化合物 |
| US4841032A (en) * | 1986-09-19 | 1989-06-20 | Sumitomo Chemical Company, Limited | Fiber reactive monoazo compounds having two vinylsulfone type fiber reactive groups in the molecule |
| JPH0668083B2 (ja) * | 1987-07-22 | 1994-08-31 | 三菱化成株式会社 | 水溶性染料混合物 |
| JP3168624B2 (ja) * | 1991-08-02 | 2001-05-21 | 住友化学工業株式会社 | 反応染料組成物およびそれを用いる繊維材料の染色または捺染方法 |
| JP3198635B2 (ja) * | 1992-06-26 | 2001-08-13 | 住友化学工業株式会社 | 反応染料混合物及びそれを用いる染色又は捺染方法 |
| JP3226707B2 (ja) * | 1994-03-25 | 2001-11-05 | ダイスタージャパン株式会社 | 反応染料組成物 |
| CN1056636C (zh) * | 1993-10-15 | 2000-09-20 | 双星日本株式会社 | 染料组成物及使用该染料组成物的染色法 |
| JP3592779B2 (ja) * | 1994-04-07 | 2004-11-24 | ダイスタージャパン株式会社 | 反応染料組成物及びそれを用いた染色法 |
| TW347406B (en) * | 1994-12-02 | 1998-12-11 | Daistar Japan Kk | Blue reactive dye composition and dye composition prepared therefrom |
| DE19511689A1 (de) * | 1995-03-30 | 1996-10-02 | Hoechst Ag | Mischung von blaufärbenden faserreaktiven Farbstoffen und ihre Verwendung zum Färben von hydroxy- und/oder carbonamidgruppenhaltigem Fasermaterial |
| JP4218101B2 (ja) * | 1998-12-21 | 2009-02-04 | 住友化学株式会社 | 反応染料混合物及びそれを用いる染色又は捺染方法 |
| US6143039A (en) * | 1999-04-12 | 2000-11-07 | Dystar Textilfarben Gmbh & Co. | Blue dye mixtures of fiber-reactive copper complex formazan dyes |
| JP2003055570A (ja) * | 2001-08-21 | 2003-02-26 | Dystar Japan Ltd | 反応染料組成物及びこれを用いる染色法 |
| JP4614671B2 (ja) * | 2003-02-21 | 2011-01-19 | 日本化薬株式会社 | 反応染料組成物及びそれを用いる染色法 |
| WO2004074385A1 (ja) * | 2003-02-21 | 2004-09-02 | Nippon Kayaku Kabushiki Kaisha | 反応染料組成物及びそれを用いる染色法 |
| WO2005085368A1 (ja) * | 2004-03-03 | 2005-09-15 | Nippon Kayaku Kabushiki Kaisha | 反応染料組成物及びそれを用いる染色法 |
| JP4576924B2 (ja) * | 2004-08-09 | 2010-11-10 | 住友化学株式会社 | 反応染料組成物、及び該組成物を用いる染色又は捺染方法 |
-
2010
- 2010-05-27 JP JP2010121346A patent/JP5682947B2/ja active Active
- 2010-05-28 CN CN201010194202.6A patent/CN101899226B/zh active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101960807B1 (ko) * | 2017-11-07 | 2019-03-21 | (주)경인양행 | 친환경 반응성 염료 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101899226B (zh) | 2014-10-01 |
| CN101899226A (zh) | 2010-12-01 |
| JP2011006671A (ja) | 2011-01-13 |
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