JP5655976B1 - プリプレグ、繊維強化複合材料および熱可塑性樹脂粒子 - Google Patents
プリプレグ、繊維強化複合材料および熱可塑性樹脂粒子 Download PDFInfo
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- JP5655976B1 JP5655976B1 JP2014504103A JP2014504103A JP5655976B1 JP 5655976 B1 JP5655976 B1 JP 5655976B1 JP 2014504103 A JP2014504103 A JP 2014504103A JP 2014504103 A JP2014504103 A JP 2014504103A JP 5655976 B1 JP5655976 B1 JP 5655976B1
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
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| JP2014504103A JP5655976B1 (ja) | 2013-01-28 | 2014-01-24 | プリプレグ、繊維強化複合材料および熱可塑性樹脂粒子 |
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| PCT/JP2014/051520 WO2014115844A1 (ja) | 2013-01-28 | 2014-01-24 | プリプレグ、繊維強化複合材料および熱可塑性樹脂粒子 |
| JP2014504103A JP5655976B1 (ja) | 2013-01-28 | 2014-01-24 | プリプレグ、繊維強化複合材料および熱可塑性樹脂粒子 |
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| JP5655976B1 true JP5655976B1 (ja) | 2015-01-21 |
| JPWO2014115844A1 JPWO2014115844A1 (ja) | 2017-01-26 |
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| US (1) | US9676936B2 (de) |
| EP (1) | EP2949689A4 (de) |
| JP (1) | JP5655976B1 (de) |
| KR (1) | KR20150113015A (de) |
| CN (1) | CN104955883B (de) |
| WO (1) | WO2014115844A1 (de) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016125779A1 (ja) * | 2015-02-05 | 2016-08-11 | 東レ株式会社 | プリフォーム、繊維強化複合材料および繊維強化複合材料の製造方法 |
| WO2018016138A1 (ja) | 2016-07-19 | 2018-01-25 | ダイセル・エボニック株式会社 | ポリアミド粒子及びその製造方法、樹脂組成物並びに成形品 |
| KR20180112877A (ko) | 2015-10-07 | 2018-10-12 | 다이셀에보닉 주식회사 | 섬유 강화 수지 및 그의 제조 방법, 및 성형품 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP3031860B1 (de) * | 2013-08-07 | 2019-09-25 | Toray Industries, Inc. | Epoxidharzzusammensetzung-basiertes prepreg und faserverstärktes verbundmaterial |
| US9776107B1 (en) * | 2016-06-16 | 2017-10-03 | Wichita State University | System and method for recycling of pre-impregnated composite fibers |
| US10731014B2 (en) * | 2016-06-22 | 2020-08-04 | Hexcel Corporation | Matrix resins toughened with hybrid polyamide particles |
| CN109563684B (zh) * | 2016-08-04 | 2021-06-18 | 艾斯登强生股份有限公司 | 用于工业纺织品的加强构件 |
| CN110612205B (zh) * | 2017-03-07 | 2022-05-03 | 塞特工业公司 | 具有结构和阻燃能力的复合材料 |
| WO2018181254A1 (ja) * | 2017-03-29 | 2018-10-04 | 東レ株式会社 | プリプレグおよび繊維強化複合材料 |
| JP6558498B2 (ja) * | 2017-05-12 | 2019-08-14 | 東レ株式会社 | ポリアミド微粒子の製造方法 |
| KR20200001625U (ko) | 2019-01-14 | 2020-07-22 | 김은희 | 안마 거꾸리 |
| WO2020235486A1 (ja) * | 2019-05-23 | 2020-11-26 | 東レ株式会社 | プリプレグ、積層体および成形品 |
| JP2022539778A (ja) * | 2019-07-03 | 2022-09-13 | ヘクセル コーポレイション | ハイブリッドポリアミド粒子で強化されたマトリックス樹脂 |
| US11485833B2 (en) * | 2019-10-23 | 2022-11-01 | Hexcel Corporation | Thermoplastic toughened matrix resins containing nanoparticles |
| EP4074765A4 (de) * | 2019-12-11 | 2023-12-20 | Toray Industries, Inc. | Prepreg, laminat und integrierter formkörper |
| US20230017689A1 (en) * | 2019-12-11 | 2023-01-19 | Toray Industries, Inc. | Prepreg, laminate, and integrated product |
| EP4063457A4 (de) * | 2019-12-23 | 2023-12-13 | Toray Industries, Inc. | Wärmehärtende harzzusammensetzung, gehärtetes produkt aus wärmehärtendem harz, prepreg und faserverstärktes verbundmaterial |
| BR112023022503A2 (pt) | 2021-04-30 | 2024-01-16 | Basf Se | Mistura de polímeros, composição de moldagem termoplástica, processo para preparar uma mistura de polímeros, processo para preparar uma composição de moldagem termoplástica, uso de uma mistura de polímeros e peça moldada ou extrudada |
| WO2023190319A1 (ja) * | 2022-03-30 | 2023-10-05 | 東レ株式会社 | 炭素繊維強化複合材料およびプリプレグ |
| CN116215046A (zh) * | 2022-12-31 | 2023-06-06 | 中复神鹰(上海)科技有限公司 | 一种耐冲击型及环境适应性纤维增强树脂基复合材料及其预浸料制造方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009221460A (ja) * | 2008-02-19 | 2009-10-01 | Toray Ind Inc | ポリアミド微粒子、プリプレグ及び炭素繊維強化複合材料 |
| JP2010525102A (ja) * | 2007-04-17 | 2010-07-22 | ヘクセル コーポレイション | 改善された性能を有するプレ含浸コンポジット材料 |
| JP2011144358A (ja) * | 2009-12-17 | 2011-07-28 | Sanyo Chem Ind Ltd | 樹脂粒子 |
| JP2012229396A (ja) * | 2010-11-12 | 2012-11-22 | Sanyo Chem Ind Ltd | ウレタン樹脂粒子 |
| WO2013122008A1 (ja) * | 2012-02-15 | 2013-08-22 | 東レ株式会社 | 複合ポリアミド微粒子およびその製造方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63170428A (ja) | 1987-01-07 | 1988-07-14 | Toray Ind Inc | プリプレグの製造方法 |
| EP0274899B1 (de) | 1986-12-25 | 1994-02-09 | Toray Industries, Inc. | Zähe Verbundmaterialien |
| JPS63170427A (ja) | 1987-01-07 | 1988-07-14 | Toray Ind Inc | 繊維強化プリプレグの製造方法 |
| JPS6426651A (en) | 1987-01-06 | 1989-01-27 | Toray Industries | Production of prepreg |
| EP0616013B1 (de) * | 1993-03-19 | 1999-06-02 | Mitsubishi Chemical Corporation | Thermoplastische Harzzusammensetzung |
| JPH0741576A (ja) | 1993-07-30 | 1995-02-10 | Toray Ind Inc | プリプレグおよび繊維強化樹脂 |
| GB0619401D0 (en) | 2006-10-02 | 2006-11-08 | Hexcel Composites Ltd | Composite materials with improved performance |
| WO2008053911A1 (fr) * | 2006-11-01 | 2008-05-08 | Mitsubishi Engineering-Plastics Corporation | Mélange de granules d'une composition de résine de polyamide, article moulé et procédé de production du mélange de granules |
| EP2540755B1 (de) | 2007-04-17 | 2014-09-24 | Hexcel Corporation | Matériau composite à mélange de particules thermoplastiques |
| TWI435887B (zh) * | 2008-02-26 | 2014-05-01 | Toray Industries | 環氧樹脂組成物、預浸透物及纖維強化複合材料 |
| WO2011122631A1 (ja) * | 2010-03-30 | 2011-10-06 | 東レ株式会社 | プリプレグ、繊維強化複合材料およびプリプレグの製造方法 |
| US10072377B2 (en) * | 2011-07-27 | 2018-09-11 | Toray Industries, Inc. | Prepreg and fiber-reinforced composite material |
-
2014
- 2014-01-24 JP JP2014504103A patent/JP5655976B1/ja not_active Expired - Fee Related
- 2014-01-24 EP EP14743437.7A patent/EP2949689A4/de not_active Withdrawn
- 2014-01-24 KR KR1020157021912A patent/KR20150113015A/ko active Search and Examination
- 2014-01-24 WO PCT/JP2014/051520 patent/WO2014115844A1/ja active Application Filing
- 2014-01-24 US US14/759,570 patent/US9676936B2/en active Active
- 2014-01-24 CN CN201480005958.8A patent/CN104955883B/zh not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010525102A (ja) * | 2007-04-17 | 2010-07-22 | ヘクセル コーポレイション | 改善された性能を有するプレ含浸コンポジット材料 |
| JP2009221460A (ja) * | 2008-02-19 | 2009-10-01 | Toray Ind Inc | ポリアミド微粒子、プリプレグ及び炭素繊維強化複合材料 |
| JP2011144358A (ja) * | 2009-12-17 | 2011-07-28 | Sanyo Chem Ind Ltd | 樹脂粒子 |
| JP2012229396A (ja) * | 2010-11-12 | 2012-11-22 | Sanyo Chem Ind Ltd | ウレタン樹脂粒子 |
| WO2013122008A1 (ja) * | 2012-02-15 | 2013-08-22 | 東レ株式会社 | 複合ポリアミド微粒子およびその製造方法 |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016125779A1 (ja) * | 2015-02-05 | 2016-08-11 | 東レ株式会社 | プリフォーム、繊維強化複合材料および繊維強化複合材料の製造方法 |
| US10792869B2 (en) | 2015-02-05 | 2020-10-06 | Toray Industries, Inc. | Preform, fiber-reinforced composite material, and method of manufacturing fiber-reinforced composite material |
| KR20180112877A (ko) | 2015-10-07 | 2018-10-12 | 다이셀에보닉 주식회사 | 섬유 강화 수지 및 그의 제조 방법, 및 성형품 |
| EP3467015A1 (de) | 2015-10-07 | 2019-04-10 | Daicel-Evonik Ltd. | Verfahren zur herstellung einer harzzusammensetzung |
| US10370509B2 (en) | 2015-10-07 | 2019-08-06 | Daicel-Evonik Ltd. | Fiber-reinforced resin, process for producing same, and molded article |
| US11407864B2 (en) | 2015-10-07 | 2022-08-09 | Daicel-Evonik Ltd. | Fiber-reinforced resin, process for producing same, and molded article |
| WO2018016138A1 (ja) | 2016-07-19 | 2018-01-25 | ダイセル・エボニック株式会社 | ポリアミド粒子及びその製造方法、樹脂組成物並びに成形品 |
| KR20190031268A (ko) | 2016-07-19 | 2019-03-25 | 다이셀에보닉 주식회사 | 폴리아미드 입자 및 그의 제조 방법, 수지 조성물 그리고 성형품 |
| US11142613B2 (en) | 2016-07-19 | 2021-10-12 | Daicel-Evonik Ltd. | Polyamide particles, production process therefor, resin composition, and molded article |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2949689A1 (de) | 2015-12-02 |
| WO2014115844A1 (ja) | 2014-07-31 |
| CN104955883B (zh) | 2018-03-13 |
| US20150344686A1 (en) | 2015-12-03 |
| EP2949689A4 (de) | 2016-09-07 |
| US9676936B2 (en) | 2017-06-13 |
| CN104955883A (zh) | 2015-09-30 |
| JPWO2014115844A1 (ja) | 2017-01-26 |
| KR20150113015A (ko) | 2015-10-07 |
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