JP5639661B2 - 悪臭制御成分を有する食器用洗剤組成物、及び食器類の洗浄方法 - Google Patents
悪臭制御成分を有する食器用洗剤組成物、及び食器類の洗浄方法 Download PDFInfo
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- JP5639661B2 JP5639661B2 JP2012544814A JP2012544814A JP5639661B2 JP 5639661 B2 JP5639661 B2 JP 5639661B2 JP 2012544814 A JP2012544814 A JP 2012544814A JP 2012544814 A JP2012544814 A JP 2012544814A JP 5639661 B2 JP5639661 B2 JP 5639661B2
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- acid
- composition
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- aldehyde
- alkyl
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- 239000000203 mixture Substances 0.000 title claims description 170
- 239000003599 detergent Substances 0.000 title claims description 49
- 238000004851 dishwashing Methods 0.000 title claims description 37
- 238000000034 method Methods 0.000 title claims description 13
- 150000001299 aldehydes Chemical class 0.000 claims description 74
- -1 Adokisaru Natural products 0.000 claims description 63
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 48
- 239000003377 acid catalyst Substances 0.000 claims description 28
- 150000001412 amines Chemical class 0.000 claims description 26
- 239000004094 surface-active agent Substances 0.000 claims description 26
- 229960003237 betaine Drugs 0.000 claims description 25
- 150000003839 salts Chemical class 0.000 claims description 23
- 239000002253 acid Substances 0.000 claims description 21
- 238000004140 cleaning Methods 0.000 claims description 15
- MZZRKEIUNOYYDF-UHFFFAOYSA-N 2,4-dimethylcyclohex-3-ene-1-carbaldehyde Chemical compound CC1C=C(C)CCC1C=O MZZRKEIUNOYYDF-UHFFFAOYSA-N 0.000 claims description 10
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 claims description 8
- 239000004615 ingredient Substances 0.000 claims description 8
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 claims description 8
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 claims description 7
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 claims description 6
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 6
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 claims description 6
- CNUDBTRUORMMPA-UHFFFAOYSA-N formylthiophene Chemical compound O=CC1=CC=CS1 CNUDBTRUORMMPA-UHFFFAOYSA-N 0.000 claims description 6
- 229940117916 cinnamic aldehyde Drugs 0.000 claims description 5
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 claims description 5
- BOPPSUHPZARXTH-UHFFFAOYSA-N ocean propanal Chemical compound O=CC(C)CC1=CC=C2OCOC2=C1 BOPPSUHPZARXTH-UHFFFAOYSA-N 0.000 claims description 5
- PKZJLOCLABXVMC-UHFFFAOYSA-N 2-Methoxybenzaldehyde Chemical compound COC1=CC=CC=C1C=O PKZJLOCLABXVMC-UHFFFAOYSA-N 0.000 claims description 4
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims description 4
- IOLQAHFPDADCHJ-UXBLZVDNSA-N 2-isopropyl-5-methyl-2-hexenal Chemical compound CC(C)C\C=C(/C=O)C(C)C IOLQAHFPDADCHJ-UXBLZVDNSA-N 0.000 claims description 4
- VAUMDUIUEPIGHM-UHFFFAOYSA-N 5-Methyl-2-thiophenecarboxaldehyde Chemical compound CC1=CC=C(C=O)S1 VAUMDUIUEPIGHM-UHFFFAOYSA-N 0.000 claims description 4
- AXMVYSVVTMKQSL-UHFFFAOYSA-N UNPD142122 Natural products OC1=CC=C(C=CC=O)C=C1O AXMVYSVVTMKQSL-UHFFFAOYSA-N 0.000 claims description 4
- ZHHYXNZJDGDGPJ-BSWSSELBSA-N (2e,4e)-nona-2,4-dienal Chemical compound CCCC\C=C\C=C\C=O ZHHYXNZJDGDGPJ-BSWSSELBSA-N 0.000 claims description 3
- QVEOSYKPYFNQAZ-XYOKQWHBSA-N (4e)-4,8-dimethyldeca-4,9-dienal Chemical compound C=CC(C)CC\C=C(/C)CCC=O QVEOSYKPYFNQAZ-XYOKQWHBSA-N 0.000 claims description 3
- CWRKZMLUDFBPAO-VOTSOKGWSA-N (e)-dec-4-enal Chemical compound CCCCC\C=C\CCC=O CWRKZMLUDFBPAO-VOTSOKGWSA-N 0.000 claims description 3
- HQQPOVNESMNPNH-UHFFFAOYSA-N 3-(4-propan-2-ylphenyl)butanal Chemical compound CC(C)C1=CC=C(C(C)CC=O)C=C1 HQQPOVNESMNPNH-UHFFFAOYSA-N 0.000 claims description 3
- NKZPGPZCKPODMT-UHFFFAOYSA-N 3-(4-tert-butylphenyl)butanal Chemical compound O=CCC(C)C1=CC=C(C(C)(C)C)C=C1 NKZPGPZCKPODMT-UHFFFAOYSA-N 0.000 claims description 3
- FZJUFJKVIYFBSY-UHFFFAOYSA-N bourgeonal Chemical compound CC(C)(C)C1=CC=C(CCC=O)C=C1 FZJUFJKVIYFBSY-UHFFFAOYSA-N 0.000 claims description 3
- 229940089454 lauryl aldehyde Drugs 0.000 claims description 3
- ORMHZBNNECIKOH-UHFFFAOYSA-N 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-1-carbaldehyde Chemical compound CC(C)(O)CCCC1=CCC(C=O)CC1 ORMHZBNNECIKOH-UHFFFAOYSA-N 0.000 claims description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 2
- 235000013922 glutamic acid Nutrition 0.000 claims description 2
- 239000004220 glutamic acid Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 229960003330 pentetic acid Drugs 0.000 claims description 2
- VCNGNQLPFHVODE-UHFFFAOYSA-N 5-methylthiophene-2-carboxylic acid Chemical compound CC1=CC=C(C(O)=O)S1 VCNGNQLPFHVODE-UHFFFAOYSA-N 0.000 claims 1
- QZEWCYLEALHBDX-UHFFFAOYSA-N CC1(C2CC=C(C1C2)CCC=O)C.C(C)=O Chemical compound CC1(C2CC=C(C1C2)CCC=O)C.C(C)=O QZEWCYLEALHBDX-UHFFFAOYSA-N 0.000 claims 1
- 229920000858 Cyclodextrin Polymers 0.000 claims 1
- HYBBIBNJHNGZAN-UHFFFAOYSA-N Furaldehyde Natural products O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 claims 1
- 150000001879 copper Chemical class 0.000 claims 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims 1
- 150000003751 zinc Chemical class 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 description 46
- 235000019645 odor Nutrition 0.000 description 37
- 239000007788 liquid Substances 0.000 description 33
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 23
- 150000001875 compounds Chemical class 0.000 description 22
- 125000004432 carbon atom Chemical group C* 0.000 description 19
- 229910052757 nitrogen Inorganic materials 0.000 description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- 229910052717 sulfur Inorganic materials 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 13
- 239000002738 chelating agent Substances 0.000 description 13
- 238000005187 foaming Methods 0.000 description 13
- 239000011593 sulfur Substances 0.000 description 13
- 239000002736 nonionic surfactant Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 10
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 230000004048 modification Effects 0.000 description 10
- 238000012986 modification Methods 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 150000001298 alcohols Chemical class 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 239000006260 foam Substances 0.000 description 9
- 239000003205 fragrance Substances 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 9
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 229920002873 Polyethylenimine Polymers 0.000 description 7
- 238000004458 analytical method Methods 0.000 description 7
- 150000004985 diamines Chemical class 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 6
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 125000003545 alkoxy group Chemical group 0.000 description 6
- 150000008051 alkyl sulfates Chemical class 0.000 description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 6
- 239000003752 hydrotrope Substances 0.000 description 6
- 125000004433 nitrogen atom Chemical group N* 0.000 description 6
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 6
- 150000003573 thiols Chemical class 0.000 description 6
- BYGQBDHUGHBGMD-UHFFFAOYSA-N 2-methylbutanal Chemical compound CCC(C)C=O BYGQBDHUGHBGMD-UHFFFAOYSA-N 0.000 description 5
- 235000011054 acetic acid Nutrition 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 5
- 239000003093 cationic surfactant Substances 0.000 description 5
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 238000006386 neutralization reaction Methods 0.000 description 5
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N pentanal Chemical compound CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 229920005646 polycarboxylate Polymers 0.000 description 5
- MBDOYVRWFFCFHM-SNAWJCMRSA-N (2E)-hexenal Chemical compound CCC\C=C\C=O MBDOYVRWFFCFHM-SNAWJCMRSA-N 0.000 description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
- MOQGCGNUWBPGTQ-UHFFFAOYSA-N 2,6,6-trimethyl-1-cyclohexene-1-carboxaldehyde Chemical compound CC1=C(C=O)C(C)(C)CCC1 MOQGCGNUWBPGTQ-UHFFFAOYSA-N 0.000 description 4
- FTZILAQGHINQQR-UHFFFAOYSA-N 2-Methylpentanal Chemical compound CCCC(C)C=O FTZILAQGHINQQR-UHFFFAOYSA-N 0.000 description 4
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical class OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 4
- 150000003863 ammonium salts Chemical class 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical compound CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 230000000873 masking effect Effects 0.000 description 4
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- SMQUZDBALVYZAC-UHFFFAOYSA-N salicylaldehyde Chemical compound OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 4
- YGFGZTXGYTUXBA-UHFFFAOYSA-N (±)-2,6-dimethyl-5-heptenal Chemical compound O=CC(C)CCC=C(C)C YGFGZTXGYTUXBA-UHFFFAOYSA-N 0.000 description 3
- MBDOYVRWFFCFHM-UHFFFAOYSA-N 2-hexenal Chemical compound CCCC=CC=O MBDOYVRWFFCFHM-UHFFFAOYSA-N 0.000 description 3
- NFAVNWJJYQAGNB-UHFFFAOYSA-N 2-methylundecanal Chemical compound CCCCCCCCCC(C)C=O NFAVNWJJYQAGNB-UHFFFAOYSA-N 0.000 description 3
- YGCZTXZTJXYWCO-UHFFFAOYSA-N 3-phenylpropanal Chemical compound O=CCCC1=CC=CC=C1 YGCZTXZTJXYWCO-UHFFFAOYSA-N 0.000 description 3
- 239000005711 Benzoic acid Substances 0.000 description 3
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical class OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 3
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- LMETVDMCIJNNKH-UHFFFAOYSA-N [(3,7-Dimethyl-6-octenyl)oxy]acetaldehyde Chemical compound CC(C)=CCCC(C)CCOCC=O LMETVDMCIJNNKH-UHFFFAOYSA-N 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 235000010233 benzoic acid Nutrition 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 238000010494 dissociation reaction Methods 0.000 description 3
- 230000005593 dissociations Effects 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229960000587 glutaral Drugs 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N isopropyl alcohol Natural products CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 238000005192 partition Methods 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical class NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Chemical class OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- WJUFSDZVCOTFON-UHFFFAOYSA-N veratraldehyde Chemical compound COC1=CC=C(C=O)C=C1OC WJUFSDZVCOTFON-UHFFFAOYSA-N 0.000 description 3
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 3
- 239000001893 (2R)-2-methylbutanal Substances 0.000 description 2
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 2
- NDFKTBCGKNOHPJ-AATRIKPKSA-N (E)-hept-2-enal Chemical compound CCCC\C=C\C=O NDFKTBCGKNOHPJ-AATRIKPKSA-N 0.000 description 2
- 239000001709 1,2-dimethylcyclohex-3-ene-1-carbaldehyde Substances 0.000 description 2
- UEGBWDUVDAKUGA-UHFFFAOYSA-N 2,6,10-trimethylundec-9-enal Chemical compound CC(C)=CCCC(C)CCCC(C)C=O UEGBWDUVDAKUGA-UHFFFAOYSA-N 0.000 description 2
- VHTFHZGAMYUZEP-UHFFFAOYSA-N 2,6,6-Trimethyl-1-cyclohexen-1-acetaldehyde Chemical compound CC1=C(CC=O)C(C)(C)CCC1 VHTFHZGAMYUZEP-UHFFFAOYSA-N 0.000 description 2
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 description 2
- LSKONYYRONEBKA-UHFFFAOYSA-N 2-Dodecanone Natural products CCCCCCCCCCC(C)=O LSKONYYRONEBKA-UHFFFAOYSA-N 0.000 description 2
- IDEYZABHVQLHAF-XQRVVYSFSA-N 2-Methyl-2-pentenal Chemical compound CC\C=C(\C)C=O IDEYZABHVQLHAF-XQRVVYSFSA-N 0.000 description 2
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- 238000007046 ethoxylation reaction Methods 0.000 description 1
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- 150000005826 halohydrocarbons Chemical class 0.000 description 1
- 150000002373 hemiacetals Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
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- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940116335 lauramide Drugs 0.000 description 1
- 229940094506 lauryl betaine Drugs 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
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- 229910001425 magnesium ion Inorganic materials 0.000 description 1
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- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 1
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- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 235000014593 oils and fats Nutrition 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
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- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
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- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
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- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
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- 238000005070 sampling Methods 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
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- UOGMZEGKCNHMBF-UHFFFAOYSA-N scentenal Chemical compound C12CC(C=O)CC2C2CC(OC)C1C2 UOGMZEGKCNHMBF-UHFFFAOYSA-N 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
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- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
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- 230000003068 static effect Effects 0.000 description 1
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- 125000001424 substituent group Chemical group 0.000 description 1
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- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 239000011975 tartaric acid Chemical class 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- UIERETOOQGIECD-ONEGZZNKSA-N tiglic acid Chemical compound C\C=C(/C)C(O)=O UIERETOOQGIECD-ONEGZZNKSA-N 0.000 description 1
- UAXOELSVPTZZQG-UHFFFAOYSA-N tiglic acid Natural products CC(C)=C(C)C(O)=O UAXOELSVPTZZQG-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000021081 unsaturated fats Nutrition 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
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- 238000005406 washing Methods 0.000 description 1
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- 239000004711 α-olefin Substances 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L15/00—Washing or rinsing machines for crockery or tableware
- A47L15/0002—Washing processes, i.e. machine working principles characterised by phases or operational steps
- A47L15/0005—Rinsing phases, e.g. pre-rinsing, intermediate rinsing, final rinsing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0068—Deodorant compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2096—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3481—Organic compounds containing sulfur containing sulfur in a heterocyclic ring, e.g. sultones or sulfolanes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Epidemiology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Detergent Compositions (AREA)
- Fats And Perfumes (AREA)
Description
食器用洗剤組成物は概して水性液体担体を30%〜95%、あるいは40%〜80%、あるいは50%〜75%含有し、その水性液体担体に他の必須及び任意の組成物成分が溶解、分散、又は懸濁されている。
本発明の組成物は、キーラントを組成物の総量の0.1重量%〜20%重量%、あるいは0.2重量%〜5重量%、あるいは0.2重量%〜3重量%の濃度で含む。
本発明の組成物は、アニオン性、非イオン性、カチオン性、両性、双極性、半極性、非イオン性界面活性剤、及びこれらの混合物から選択される界面活性剤を含んでもよい。組成物の界面活性剤は、10重量%超過、あるいは20重量%超過、あるいは30重量%超過、あるいは40重量%超過のアルキル鎖の平均分枝を有する。
非イオン性界面活性剤あるいは分枝状非イオン性界面活性剤を添加すると、食器表面の結晶膜の形成を効果的に防止し、表面の湿潤を改善し、その結果上品な輝きを与えることが見出された。
両性及び双極性界面活性剤は、組成物の0.01重量%〜20%重量%、あるいは0.2重量%〜15重量%、あるいは0.5重量%〜10重量%の濃度で存在してもよい。本発明の組成物は、アミンオキシド及び/又はベタインを更に含んでもよい。
式中、
R1は飽和又は不飽和C6〜22アルキル残基であり、あるいはC8〜18アルキル残基、特に飽和C10〜16アルキル残基であり、例えば飽和C12〜14アルキル残基であり、
XはNH、C1〜4アルキル残基R4を有するNR4、O、又はSであり、
nは1〜10の数、あるいは2〜5、特に3であり、
xは0又は1、あるいは1であり、
R2、R3は独立して、ヒドロキシエチル、あるいはメチルなどのヒドロキシ置換される可能性のあるC1〜4アルキル残基であり、
mは1〜4の数であり、特に1、2又は3であり、
yは0又は1であり、
YはCOO、SO3、OPO(OR5)O又はP(O)(OR5)Oであり、R5は水素原子Hであるか又はC1〜4アルキル残基である。
R1−N+(CH3)2−CH2COO- (Ia)
R1−CO−NH(CH2)3−N+(CH3)2−CH2COO- (Ib)
R1−N+(CH3)2−CH2CH(OH)CH2SO3− (Ic)
R1−CO−NH−(CH2)3−N+(CH3)2−CH2CH(OH)CH2SO3−(Id)式中、R11は式(I)中のものと同様のものを意味する。好適なベタインはカルボベタインであり
[式中、Y-=COO-]、特に式(Ia)及び(Ib)のカルボベタイン、あるいは式(Ib)のアルキルアミドベタインである。]
本発明の組成物及び方法で使用するのに好適なアニオン性界面活性剤はサルフェート、スルホサクシネート、スルホアセテート及び/又はスルホネートであり、あるいはアルキルサルフェート及び/又はアルキルエトキシサルフェートであり、あるいは組み合わせたエトキシル化度が5未満、あるいは3未満、あるいは2未満である、アルキルサルフェート及び/又はアルキルエトキシサルフェートの組み合わせである。
組成物に存在する場合、カチオン性界面活性剤は、有効量で、あるいは組成物の0.1重量%〜20重量%で存在する。好適なカチオン性界面活性剤は、第四級アンモニウム界面活性剤である。好適な第四級アンモニウム界面活性剤は、モノC6〜C16、あるいはC6〜C10 N−アルキル又はアルケニルアンモニウム界面活性剤からなる群から選択され、残りのN位はメチル、ヒドロキシエチル(hydroxyehthyl)、又はヒドロキシプロピル基によって置換される。別の好適なカチオン性界面活性剤は、第四級クロリンエステルのような、第四級アンモニウムアルコールのC6〜C18アルキル又はアルケニルエステルである。別の態様では、カチオン性界面活性剤は、式(V)を有する。
本発明の組成物は、1種以上のアルコキシル化ポリエチレンイミンポリマーを更に含み得る。組成物は、国際公開特許第2007/135645号の2頁33行目〜5頁5行目に記載され、及び5〜7頁の実施例1〜4に例示のように、組成物の0.01重量%〜10重量%、あるいは0.01重量%〜2重量%、あるいは0.1重量%〜1.5重量%、あるいは0.2重量%〜1.5重量%のアルコキシル化ポリエチレンイミンポリマーを含み得る。
塩及び溶媒は、一般に、溶解、濃度及び審美性に関して好ましい製品品質を確実にするため、及びより良好なプロセッシングを確実にするために使用される。塩類が含まれる場合、イオンは、マグネシウム、ナトリウム、カリウム、カルシウム、及び/又はマグネシウムから、あるいはナトリウム及びマグネシウムから選択可能であり、水酸化塩、クロリド塩、酢酸塩、硫酸塩、ギ酸塩、酸化物塩又は硝酸塩として本明細書の組成物に添加される。塩類は一般に、液体洗剤組成物の0.01重量%〜5重量%、あるいは0.015重量%〜3重量%、あるいは0.025重量%〜2.0重量%の活性濃度で存在する。一実施形態では、追加のマグネシウムイオンを回避してもよい。
本発明の食器用洗剤組成物は、液体洗剤組成物が水に適切に相溶するように、所望によりヒドロトロープを有効量で含んでもよい。本明細書で使用するのに好適なヒドロトロープとしては、アニオン型のヒドロトロープ、特にキシレンスルホン酸ナトリウム、キシレンスルホン酸カリウム、及びキシレンスルホン酸アンモニウム、トルエンスルホン酸ナトリウム、トルエンスルホン酸カリウム、及びトルエンスルホン酸アンモニウム、クメンスルホン酸ナトリウム、クメンスルホン酸カリウム、及びクメンスルホン酸アンモニウム、並びにこれらの混合物、並びに米国特許第3,915,903号に開示されている関連する化合物が挙げられる。
本発明の組成物は、高分子泡安定剤を任意に含有してもよい。これらの高分子泡安定剤は、液体洗剤組成物の起泡量及び起泡持続時間の増大をもたらす。これらの高分子泡安定剤は、(N,N−ジアルキルアミノ)アルキルエステル及び(N,N−ジアルキルアミノ)アルキルアクリレートエステルのホモポリマーから選択され得る。従来のゲル浸透クロマトグラフィーによって決定される高分子泡増進剤の重量平均分子量は、1,000〜2,000,000、あるいは5,000〜1,000,000、あるいは10,000〜750,000、あるいは20,000〜500,000であり、更に別の態様では35,000〜200,000である。高分子泡安定剤は所望により、無機又は有機の塩のいずれかの塩、例えば(N,N−ジメチルアミノ)アルキルアクリレートエステルのクエン酸塩、硫酸塩、又は硝酸塩の形態で存在できる。
本発明の組成物中の別の任意成分は、ジアミンである。液体洗剤組成物のユーザーの習慣及びやり方は著しいばらつきを示すので、本組成物は別の態様として組成物の0重量%〜15重量%、あるいは0.1重量%〜15重量%、あるいは0.2重量%〜10重量%、あるいは0.25重量%〜6重量%、あるいは0.5重量%〜1.5重量%の、少なくとも1種のジアミンを含有する。
本発明による食器用洗剤組成物は、組成物のすすぎの感触を向上させるために、直鎖若しくは環式カルボン酸又はその塩を含んでもよい。アニオン性界面活性剤の存在は、特に組成物の15〜35重量%の範囲で多量に存在すると、使用者の手及び食器にぬるりとした感触を与える組成物になる。
食器用洗剤組成物には悪臭制御成分が含まれている。悪臭制御成分は、少なくとも1種の揮発性アルデヒド及び酸触媒を含有していてもよい。悪臭制御成分は、純粋な悪臭中和を供給するように設計されており、臭気を単に隠す又は被覆することにより機能するものではない。純粋な悪臭中和は、感覚及び分析により測定可能(例えば、ガスクロマトグラフ)な悪臭の低減を供給する。したがって、悪臭制御成分が純粋な悪臭中和を供給する場合には、この組成物は気相及び/又は液相中の悪臭を低減する。
悪臭制御成分は、化学反応を介して気相及び/又は液相中の悪臭を中和する揮発性アルデヒドの混合物を含む。このような揮発性アルデヒドは、反応性アルデヒド(RA)とも呼ばれる。揮発性アルデヒドは、シッフ塩基形成経路に従ってアミン系臭気と反応し得る。揮発性アルデヒドは、イオウ系臭気とも反応し、気相及び/又は液相中にチオールアセタール、へミチオールアセタール及びチオールエステルを形成し得る。実質上、製品の所望の芳香特性に負の影響を全く有さないことが、これらの気相及び/又は液相揮発性アルデヒドにとって望ましいものであり得る。部分的に揮発性であるアルデヒドは、本明細書で使用される揮発性アルデヒドと考えられ得る。
本発明の悪臭制御成分は、イオウ系の悪臭を中和する有効量の酸触媒を含有してもよい。特定の弱酸は、液相及び気相中のチオールとのアルデヒド反応性に影響を有することが判明している。チオールとアルデヒドとの間の反応は、ヘミアセタール及びアセタール形成経路の機構に従う触媒反応であることが判明している。本悪臭制御成分が酸触媒を含有している場合は、イオウ系の悪臭に接触すると、揮発性アルデヒドがチオールと反応する。この反応は、チオールアセタール化合物を形成し、したがって、イオウ系臭気を中和し得る。酸触媒がないと、へミチオールのみが形成される。
本明細書の食器用洗剤組成物は、液状洗剤組成物に使用するのに適した他の数種の任意成分、例えば、ジプロピレングリコールメチルエーテル、3―メトキシ―3―メチル―1―ブタノールなどの希釈剤及びこれらの混合物;染料;パールエッセンス剤;乳白剤;酵素;防腐剤;消毒剤を更に含有することができ、pHバッファ手段とは、本明細書の液体洗剤組成物のpHが概して3〜14、あるいは6〜13、あるいは8〜11になることを意味する。組成物のpHは、当該技術分野で既知のpH調節成分を用いて調整することができる。
本発明の成分は、20s-1及び20℃において、50〜2000センチポアズ(50〜2000mPa.s)、あるいは100〜1500センチポアズ(100〜1500mPa.s)、あるいは500〜1300センチポアズ(500〜1300mPa.s)の粘度を有し得る。粘度は、従来の方法で測定できる。
本発明の方法は、洗浄剤及び悪臭制御成分を含んでなる、食器用洗剤組成物を用い、食器類を洗浄する工程を含む。食器洗いの作業は、前記組成物を典型的には希釈又は非希釈形態にて前記食器類に塗布する工程と、前記食器類又は表面から前記組成物をすすぐ工程、並びに食器類又は前記表面をすすがずに前記表面上の組成物を乾燥させる工程と、を含む。前記組成物を空気乾燥させて前記表面上に残す代わりに、キッチンタオルを用いてハンドドライすることもできる。食器洗浄操作時に、特に食器類に本組成物を塗布するとき及び/又は食器類から本組成物をすすぎ落とすときに、使用者の手及び皮膚は希釈又は非希釈形態の本組成物に曝露され得る。
本発明の洗剤組成物は、使用する液体洗剤組成物を送達するための何らかの好適なパッケージに詰めてもよい。別の態様では、前記パッケージは、ガラス製又はプラスチック製の透明なパッケージである。
(**)その他:染料、乳白剤、香料、防腐剤、ヒドロトロープ、加工助剤、塩、安定剤...
(1)グルタミン酸
(2)ジエチレントリアミンペンタメチルホスホン酸
(3)ジエチレントリアミン五酢酸
(4)メチルグリシン二酢酸
1mLのブチルアミン(アミン系悪臭)及びブタンチオール(イオウ系悪臭)を1.2リットルのガスサンプリングバッグの中にピペットで加えることにより、悪臭標準物質を調製する。次に、このバッグに窒素を容量まで充填し、少なくとも12時間にわたって静置して、平衡状態にする。
イオウ系悪臭における酸触媒の効果を試験するために、上記分析試験を、酸触媒を含有する試料を用いて繰り返す。特に、以下の対照及び酸触媒試料の各々の1μLアリコートを、二通り用意した個々の10mLシラン処理済みヘッドスペースバイアル瓶にピペットを用いて加える:対照としてのチオフェンカルボキシアルデヒド;チオフェンカルボキシアルデヒドとDPM中0.04%、DPM中0.10%、DPM中0.43%、DPM中1.02%及びDPM中2.04%での以下の酸触媒各々との50/50混合物:フェノール、メシチレン酸、カプリル酸、コハク酸、ピバル酸、チグリン酸及び安息香酸。
表8及び9の概要の通りに揮発性アルデヒド(又はRA)と酸触媒とを含有する試料配合物を用いて、上記分析試験を繰り返す。
Claims (5)
- 食器用洗剤組成物であって、
(a)グルタミン酸、ジエチレントリアミンペンタメチルホスホン酸、ジエチレントリアミン五酢酸、メチルグリシン二酢酸及びその混合物からなる群から選択される、組成物の総量の0.1重量%〜20重量%のキーラントと、
(b)アミンオキシド、ベタイン、又はこれらの混合物から選択される、組成物の総量の0.01重量%〜20重量%の界面活性剤と、
(c)悪臭制御成分であって、前記悪臭制御成分が、
(i)5−メチルチオフェンカルボン酸である酸触媒、及び
(ii)悪臭を中和するための2種以上の揮発性アルデヒドを含有し、前記2種以上の揮発性アルデヒドが、2−エトキシベンズアルデヒド、2−イソプロピル−5−メチル−2−ヘキセナール、5−メチルフルフラール、5−メチル−チオフェン−カルボキシアルデヒド、アドキサール、p−アニスアルデヒド、ベンズアルデヒド、ブルゲオナール[3−(4−tert−ブチルフェニル)プロパナール]、桂皮アルデヒド、サイマール[3−(4−プロパン−2−イルフェニル)ブタナール]、デシルアルデヒド、フローラルスーパー[(4E)−4,8−ジメチルデカ−4,9−ジエナール]、フロルヒドラル、ヘリオナール、ラウリルアルデヒド、リグストラール[2,4−ジメチルシクロヘキサ−3−エン−1−カルボアルデヒド]、リラール、メロナール、o−アニスアルデヒド、ピノアセトアルデヒド[3−(7,7−ジメチル−4−ビシクロ[3.1.1]ヘプト−3−エニル)プロパナール]、P.T.ブシナール[3−(4−tert−ブチルフェニル)ブタナール]、チオフェンカルボキシアルデヒド、トランス−4−デセナール、トランストランス2,4−ノナジエナール、ウンデシルアルデヒド及びこれらの混合物からなる群から選択される、悪臭制御成分と、
を含む、食器用洗剤組成物。 - 前記2種以上の揮発性アルデヒドが、フローラルスーパー[(4E)−4,8−ジメチルデカ−4,9−ジエナール]及びo−アニスアルデヒドを含む、請求項1に記載の組成物。
- 前記組成物が非錯体化型シクロデキストリンを更に含む、請求項1又は2に記載の組成物。
- 前記組成物が、亜鉛塩、銅塩及びこれらの混合物からなる群から選択される水溶性金属塩を更に含む、請求項1〜3のいずれか1項に記載の組成物。
- 食器類の洗浄方法であって、
(a)請求項1に記載の組成物を前記食器類に塗布する工程と、
(b)前記食器類から前記組成物をすすぎ落とす工程と、
を含む洗浄方法。
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2010
- 2010-09-20 US US12/885,884 patent/US20110150817A1/en not_active Abandoned
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