JP5565832B2 - シャンプー組成物 - Google Patents
シャンプー組成物 Download PDFInfo
- Publication number
- JP5565832B2 JP5565832B2 JP2010024884A JP2010024884A JP5565832B2 JP 5565832 B2 JP5565832 B2 JP 5565832B2 JP 2010024884 A JP2010024884 A JP 2010024884A JP 2010024884 A JP2010024884 A JP 2010024884A JP 5565832 B2 JP5565832 B2 JP 5565832B2
- Authority
- JP
- Japan
- Prior art keywords
- chloride
- shampoo composition
- mol
- hair
- methacryloylethyldimethylbetaine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 38
- 239000002453 shampoo Substances 0.000 title claims description 37
- -1 polyoxyethylene Polymers 0.000 claims description 45
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 28
- 239000000194 fatty acid Substances 0.000 claims description 28
- 229930195729 fatty acid Natural products 0.000 claims description 28
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 26
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 20
- AMFZXVSYJYDGJD-UHFFFAOYSA-M ethyl-dimethyl-(3-methyl-2-oxobut-3-enyl)azanium;chloride Chemical compound [Cl-].CC[N+](C)(C)CC(=O)C(C)=C AMFZXVSYJYDGJD-UHFFFAOYSA-M 0.000 claims description 20
- 235000002639 sodium chloride Nutrition 0.000 claims description 20
- 150000004665 fatty acids Chemical class 0.000 claims description 19
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 14
- 229920001577 copolymer Polymers 0.000 claims description 13
- 235000011187 glycerol Nutrition 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 13
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 11
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 11
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 10
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 10
- 229920002907 Guar gum Polymers 0.000 claims description 9
- 239000001913 cellulose Substances 0.000 claims description 9
- 229920002678 cellulose Polymers 0.000 claims description 9
- 239000000665 guar gum Substances 0.000 claims description 9
- 235000010417 guar gum Nutrition 0.000 claims description 9
- 229960002154 guar gum Drugs 0.000 claims description 9
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 8
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 8
- 239000000213 tara gum Substances 0.000 claims description 8
- 235000010491 tara gum Nutrition 0.000 claims description 8
- 239000011780 sodium chloride Substances 0.000 claims description 7
- 239000002280 amphoteric surfactant Substances 0.000 claims description 6
- 229960003237 betaine Drugs 0.000 claims description 6
- 239000001103 potassium chloride Substances 0.000 claims description 5
- 235000011164 potassium chloride Nutrition 0.000 claims description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 239000001110 calcium chloride Substances 0.000 claims description 4
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 4
- 235000011148 calcium chloride Nutrition 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 4
- 235000011147 magnesium chloride Nutrition 0.000 claims description 4
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 4
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 4
- YOMFVLRTMZWACQ-UHFFFAOYSA-N ethyltrimethylammonium Chemical compound CC[N+](C)(C)C YOMFVLRTMZWACQ-UHFFFAOYSA-N 0.000 claims description 2
- VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 claims description 2
- 238000005406 washing Methods 0.000 description 17
- 239000000284 extract Substances 0.000 description 12
- 238000005187 foaming Methods 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 11
- 238000001035 drying Methods 0.000 description 10
- 238000002156 mixing Methods 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- 239000004166 Lanolin Substances 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 5
- 238000013329 compounding Methods 0.000 description 5
- 235000019388 lanolin Nutrition 0.000 description 5
- 229940039717 lanolin Drugs 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 240000007594 Oryza sativa Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 4
- DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Polymers OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 4
- 229910017053 inorganic salt Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 3
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 3
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 3
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 3
- 235000019482 Palm oil Nutrition 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 229940074052 glyceryl isostearate Drugs 0.000 description 3
- 230000037308 hair color Effects 0.000 description 3
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 3
- 239000002540 palm oil Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- YBJHBAHKTGYVGT-ZKWXMUAHSA-N (+)-Biotin Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)O)SC[C@@H]21 YBJHBAHKTGYVGT-ZKWXMUAHSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 2
- 241000371652 Curvularia clavata Species 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 235000019774 Rice Bran oil Nutrition 0.000 description 2
- 108010013296 Sericins Proteins 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 229920006322 acrylamide copolymer Polymers 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 229940024606 amino acid Drugs 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 2
- 235000013736 caramel Nutrition 0.000 description 2
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 229940075468 lauramidopropyl betaine Drugs 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 2
- 239000003346 palm kernel oil Substances 0.000 description 2
- 235000019865 palm kernel oil Nutrition 0.000 description 2
- 229960004063 propylene glycol Drugs 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 239000008165 rice bran oil Substances 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 description 1
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- KZRXPHCVIMWWDS-AWEZNQCLSA-N (4S)-4-amino-5-dodecanoyloxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCC(=O)OC(=O)[C@@H](N)CCC(O)=O KZRXPHCVIMWWDS-AWEZNQCLSA-N 0.000 description 1
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
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- BMUDPLZKKRQECS-UHFFFAOYSA-K 3-[18-(2-carboxyethyl)-8,13-bis(ethenyl)-3,7,12,17-tetramethylporphyrin-21,24-diid-2-yl]propanoic acid iron(3+) hydroxide Chemical compound [OH-].[Fe+3].[N-]1C2=C(C)C(CCC(O)=O)=C1C=C([N-]1)C(CCC(O)=O)=C(C)C1=CC(C(C)=C1C=C)=NC1=CC(C(C)=C1C=C)=NC1=C2 BMUDPLZKKRQECS-UHFFFAOYSA-K 0.000 description 1
- WGVGLSURTKMQQC-UHFFFAOYSA-N 3-aminopropyl-ethyl-dimethylazanium Chemical compound CC[N+](C)(C)CCCN WGVGLSURTKMQQC-UHFFFAOYSA-N 0.000 description 1
- JQEBZBUGQPSANC-UHFFFAOYSA-N 3-methoxy-2-methylprop-2-enoic acid Chemical compound COC=C(C)C(O)=O JQEBZBUGQPSANC-UHFFFAOYSA-N 0.000 description 1
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- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- HBTAOSGHCXUEKI-UHFFFAOYSA-N 4-chloro-n,n-dimethyl-3-nitrobenzenesulfonamide Chemical compound CN(C)S(=O)(=O)C1=CC=C(Cl)C([N+]([O-])=O)=C1 HBTAOSGHCXUEKI-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 1
- RWHRFHQRVDUPIK-UHFFFAOYSA-N 50867-57-7 Chemical compound CC(=C)C(O)=O.CC(=C)C(O)=O RWHRFHQRVDUPIK-UHFFFAOYSA-N 0.000 description 1
- 240000002234 Allium sativum Species 0.000 description 1
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Landscapes
- Cosmetics (AREA)
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Description
(A)メタクリロイルエチルジメチルベタインが25〜75モル%、塩化メタクリロイルエチルトリメチルアンモニウムが75〜25%、メタクリル酸メトキシポリエチレングルコールが0〜10%で構成される(メタクリロイルエチルジメチルベタイン/塩化メタクリロイルエチルトリメチルアンモニウム/メタクリル酸メトキシポリエチレングルコール
)コポリマー
(B)エーテル硫酸塩型アニオン性界面活性剤及び/又はベタイン型両性界面活性剤
(C)塩化ナトリウム、塩化カリウム、塩化マグネシウム、塩化カルシウム及び硫酸マグネシウムから選ばれる水溶性無機塩の1種又は2種以上
(D)カチオン化タラガム及び/又はカチオン化グアガム
(A)メタクリロイルエチルジメチルベタインが25〜45モル%、塩化メタクリロイルエチルトリメチルアンモニウムが70〜45モル%、メタクリル酸メトキシポリエチレングルコールが5〜10モル%で構成される(メタクリロイルエチルジメチルベタイン/塩化メタクリロイルエチルトリメチルアンモニウム/メタクリル酸メトキシポリエチレングルコール)コポリマー
(B)エーテル硫酸塩型アニオン性界面活性剤及び/又はベタイン型両性界面活性剤
(C)塩化ナトリウム、塩化カリウム、塩化マグネシウム、塩化カルシウム及び硫酸マグネシウムから選ばれる水溶性無機塩の1種又は2種以上
(D)カチオン化タラガム及び/又はカチオン化グアガム
合量の範囲であれば洗髪時及びすすぎ時の指通り性に優れ、また乾燥後の仕上がり感触においても好ましく、良好な安定性を有する。
ン化セルロースの配合量は特に限定されるものではないが、シャンプー組成物全体に対して0.01〜2%が好ましく、特に0.05〜1.0%が好ましい。この配合量の範囲であれば、洗髪時及びすすぎ時の指通り性に優れ、また乾燥後の仕上がり感触においても好ましい。
ー、卵黄油、馬脂等の油脂類、ホホバ油、カルナウバロウ、キャンデリラロウ、ラノリン、ミツロウ等のロウ類、オゾケライト、流動パラフィン、スクワレン、ワセリン等の炭化水素類、イソステアリルアルコール、オクチルドデカノール、ラノリンアルコール、フィトステロール、セタノール、オレイルアルコール等の高級アルコール類、ミリスチン酸イソプロピル、オレイン酸エチル、ステアリン酸オクチル、2−エチルヘキサン酸セチル、イソノナン酸イソノニル、パルミチン酸オクチル、ジオレイン酸エチレングリコール、トリイソステアリン酸グリセリル、乳酸セチル、アジピン酸ジイソプロピル、イソステアリン酸コレステリル等のエステル油類等、プロピレングリコール、ジプロピレングリコール、ポリプロピレングリコール、ポリエチレングリコール、グリセリン、グリコシルトレハロース、ジグリセリン、イソプレングリコール、1,3−ブチレングリコール等の多価アルコール、エチルアルコール、イソプロパノール等の低級アルコール、キサンタンガム、グアガム、デンプン等の天然高分子及びその誘導体、ヒドロキシプロピルメチルセルロース、ヒドロキシエチルセルロース、メチルセルロース等のセルロール系高分子、カルボキシビニルポリマーやポリビニルピロリドン等の合成高分子等、ジステアリン酸エチレングリコール、ジステアリン酸トリエチレングリコール等のパール化剤、カオリン、無水ケイ酸、ケイ酸アルミニウムマグネシウム、タルク、マイカ、セルロース末、シルク末、デンプン、ポリエチレン末、ナイロン末、架橋ポリスチレン等の顔料、防腐剤、金属イオン封鎖剤、噴射剤、無機塩、有機酸及びその塩、ピロリドンカルボン酸及びその塩、ヒアルロン酸及びその塩、ソルビトールやマルチトールやトレハロース等の糖類、トリメチルグリシン等の保湿剤、塩化ベンザルコニウム、塩化ベンゼトニウム、イソプロピルメチルフェノール、ピロクトンオラミン、クララエキス、ジンクピリチオン、ヒノキチオール等の殺菌剤、その他、センブリエキス、塩化カプロニウム、セファランチン、サリチル酸、イノシット、ヨウ化ニンニクエキス、レゾルシン、エストラジオール、エチニルエストラジオール、オキセンドロン、パントテン酸及びその誘導体、プラセンタエキス、ビオチン、モノニトログアヤコール、感光素301、ウシヘマチン、グリチルリチン酸ジカリウム、塩酸ピリドキシン、冷感剤、温感剤、動植物抽出物、ビタミン、紫外線吸収剤、アミノ酸及びその誘導体、タンパク質及びその誘導体、酸化防止剤、着色剤、香料等である。
1,000mL容器の攪拌機つき円筒形シリンダーに、実施例及び比較例のシャンプー組成物の5%水溶液を50mL入れ、5,000rpmで1分間攪拌した後の泡容積を測定した。また、評価の基準を次のように設定した。
◎:泡立ち極めて良好 泡容積600mL以上
○:泡立ち良好 泡容積500mL以上,600mL未満
△:泡立ち普通 泡容積400mL以上,500mL未満
×:泡立ち不良 泡容積400mL未満
10名の専門パネルにより、実施例及び比較例のシャンプー組成物を使用し、洗髪中の指通り、すすぎ時の指通り、すすぎ後のきしみの有無を官能評価した。尚、評価基準は以下の通りである。
[洗髪中の指通り]
◎:極めて良好 洗髪中の指通りが良いと答えた被験者の数が8人以上
○:良好 洗髪中の指通りが良いと答えた被験者の数が6人以上、8人未満
△:やや悪い 洗髪中の指通りが良いと答えた被験者の数が4人以上、6人未満
×:悪い 洗髪中の指通りが良いと答えた被験者の数が4人未満
[すすぎ時の指通り]
◎:極めて良好 すすぎ時の指通りが良いと答えた被験者の数が8人以上
○:良好 すすぎ時の指通りが良いと答えた被験者の数が6人以上、8人未満
△:やや悪い すすぎ時の指通りが良いと答えた被験者の数が4人以上、6人未満
×:悪い すすぎ時の指通りが良いと答えた被験者の数が4人未満
[すすぎ後のきしみ]
◎:極めて良好 きしまないと答えた被験者の数が8人以上
○:良好 きしまないと答えた被験者の数が6人以上、8人未満
△:やや悪い きしまないと答えた被験者の数が4人以上、6人未満
×:悪い きしまないと答えた被験者の数が4人未満
10名の専門パネルが前記と同様の方法で洗髪した後、毛髪を乾燥させ、毛髪のぱさつき、まとまり易さの良否等の仕上がり具合を官能評価した。評価の基準を次のように設定した。
[ぱさつき]
◎:極めて良好 ぱさつきがないと答えた被験者の数が8人以上
○:良好 ぱさつきがないと答えた被験者の数が6人以上、8人未満
△:やや悪い ぱさつきがないと答えた被験者の数が4人以上、6人未満
×:悪い ぱさつきがないと答えた被験者の数が4人未満
[まとまり]
◎:極めて良好 髪のまとまりが良いと答えた被験者の数が8人以上
○:良好 髪のまとまりが良いと答えた被験者の数が6人以上、8人未満
△:やや悪い 髪のまとまりが良いと答えた被験者の数が4人以上、6人未満
×:悪い 髪のまとまりが良いと答えた被験者の数が4人未満
実施例及び比較例のシャンプー組成物に対し、調製翌日の外観を目視で判定した。測定温度30℃で測定した。判断基準は以下の通りである。
○:沈殿なし
×:沈殿有り
表1に示す組成のシャンプー組成物を調製し、これらを使用したときの起泡性、洗髪時の指通り、すすぎ時の指通り、乾燥後のぱさつき及びまとまり、外観について調べ、その結果を表1に示した。なお、以下の全ての実施例及び比較例における配合量は全て質量%である。
(1)ラウレス硫酸ナトリウム 10.0
(2)ラウラミドプロピルベタイン 3.0
(3)ヤシ油脂肪酸モノエタノールアミド 2.0
(4)(メタクリロイルエチルジメチルベタイン
/塩化メタクリロイルエチルトリメチルアンモニウム
/メタクリル酸メトキシポリエチレングルコール)コポリマー
(45/45/10) 1.0
(5)塩化ナトリウム 1.5
(6)カチオン化セルロース(電荷密度:1.3meq/g) 0.2
(7)カチオン化タラガム(電荷密度:1.5meq/g) 0.2
(8)カチオン化グアガム(電荷密度:1.1meq/g) 0.1
(9)ポリオキシエチレン(7)ヤシ油脂肪酸グリセリン 4.0
(10)塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体 0.1
(11)ジステアリン酸エチレングリコール 2.0
(12)桃葉エキス 0.5
(13)海藻エキス 0.1
(14)海水 0.5
(15)セリシン 0.1
(16)アロエベラ葉エキス 0.1
(17)グリコシルトレハロース 0.5
(18)D−パントテニルアルコール 0.1
(19)加水分解コラーゲン液 0.5
(20)ヒアルロン酸ナトリウム 0.1
(21)シルクエキス 0.5
(22)加水分解コムギ 0.1
(23)セリシン 0.1
(24)L−アルギニン 0.1
(25)グルタミン酸ナトリウム 0.5
(26)L−プロリン 0.1
(27)ラウロイルグルタミン酸ジ(フィトステリル/オクチルドデシル) 0.1
(28)ポリクオタニウム−64 0.1
(29)加水分解カラスムギタンパク 0.2
(30)クエン酸 0.4
(31)安息香酸ナトリウム 0.5
(32)EDTA 0.1
(33)カラメル 0.2
(34)香料 0.5
(35)精製水 バランス
(1)ラウラミドプロピルベタイン 8.0
(2)パーム核油脂肪酸アミドプロピルベタイン 7.0
(3)(メタクリロイルエチルジメチルベタイン
/塩化メタクリロイルエチルトリメチルアンモニウム
/メタクリル酸メトキシポリエチレングルコール)コポリマー
(25/70/5) 1.5
(4)塩化ナトリウム 1.5
(5)カチオン化セルロース(電荷密度:1.3meq/g) 0.2
(6)カチオン化セルロース(電荷密度:0.8meq/g) 0.2
(7)カチオン化タラガム(電荷密度:1.5meq/g) 0.1
(8)カチオン化グアガム(電荷密度:1.1meq/g) 0.2
(9)ポリオキシエチレン(7)ヤシ油脂肪酸グリセリン 6.0
(10)ラウラミドMIPA 1.0
(11)セテアレス−60ミリスチルグリコール 0.5
(12)ジステアリン酸エチレングリコール 2.0
(13)ムクロジエキス 0.5
(14)ヒオウギエキス 0.1
(15)ツバキエキス 0.1
(16)黒米エキス(商品名:黒米エキス−PC〔オリザ油化製〕) 0.1
(17)コメヌカエキス 0.1
(18)コメ胚芽油 0.1
(19)加水分解コメタンパク 0.5
(20)コメヌカ油脂肪酸フィトステリル 0.1
(21)クエン酸 0.2
(22)安息香酸ナトリウム 0.2
(23)EDTA 0.1
(24)カラメル 0.1
(25)香料 0.5
(26)精製水 バランス
Claims (3)
- 下記(A)〜(D)成分を含有し、成分(A)と成分(C)の質量比が(A)/(C)=1/5〜5/1の範囲にあることを特徴とするシャンプー組成物。
(A)メタクリロイルエチルジメチルベタインが25〜45モル%、塩化メタクリロイルエチルトリメチルアンモニウムが70〜45モル%、メタクリル酸メトキシポリエチレングルコールが5〜10モル%で構成される(メタクリロイルエチルジメチルベタイン/塩化メタクリロイルエチルトリメチルアンモニウム/メタクリル酸メトキシポリエチレングルコール)コポリマー
(B)エーテル硫酸塩型アニオン性界面活性剤及び/又はベタイン型両性界面活性剤
(C)塩化ナトリウム、塩化カリウム、塩化マグネシウム、塩化カルシウム及び硫酸マグネシウムから選ばれる水溶性無機塩の1種又は2種以上
(D)カチオン化タラガム及び/又はカチオン化グアガム - 更に(E)カチオン化セルロースを含有する請求項1記載のシャンプー組成物
- 更に(F)25℃で液状のポリオキシエチレン脂肪酸グリセリンを含有する請求項1又は2記載のシャンプー組成物
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