JP5347353B2 - シリカ配合ジエン系ゴム組成物の製造法 - Google Patents
シリカ配合ジエン系ゴム組成物の製造法 Download PDFInfo
- Publication number
- JP5347353B2 JP5347353B2 JP2008179715A JP2008179715A JP5347353B2 JP 5347353 B2 JP5347353 B2 JP 5347353B2 JP 2008179715 A JP2008179715 A JP 2008179715A JP 2008179715 A JP2008179715 A JP 2008179715A JP 5347353 B2 JP5347353 B2 JP 5347353B2
- Authority
- JP
- Japan
- Prior art keywords
- silica
- weight
- diene rubber
- parts
- rubber composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims description 70
- 239000000377 silicon dioxide Substances 0.000 title claims description 35
- 229920003244 diene elastomer Polymers 0.000 title claims description 30
- 239000000203 mixture Substances 0.000 title claims description 26
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- -1 disulfide compound Chemical class 0.000 claims description 26
- 238000002156 mixing Methods 0.000 claims description 16
- 244000043261 Hevea brasiliensis Species 0.000 claims description 15
- 229920003052 natural elastomer Polymers 0.000 claims description 15
- 229920001194 natural rubber Polymers 0.000 claims description 15
- YCLSOMLVSHPPFV-UHFFFAOYSA-N 3-(2-carboxyethyldisulfanyl)propanoic acid Chemical compound OC(=O)CCSSCCC(O)=O YCLSOMLVSHPPFV-UHFFFAOYSA-N 0.000 claims description 8
- LEVWYRKDKASIDU-IMJSIDKUSA-N L-cystine Chemical compound [O-]C(=O)[C@@H]([NH3+])CSSC[C@H]([NH3+])C([O-])=O LEVWYRKDKASIDU-IMJSIDKUSA-N 0.000 claims description 7
- 239000004158 L-cystine Substances 0.000 claims description 7
- 235000019393 L-cystine Nutrition 0.000 claims description 7
- 229960003067 cystine Drugs 0.000 claims description 7
- AJQLEJAVGARHGQ-UHFFFAOYSA-N dithiosalicylic acid Chemical compound OC1=CC=CC=C1C(S)=S AJQLEJAVGARHGQ-UHFFFAOYSA-N 0.000 claims description 4
- BIHJEIFLAWVSQP-UHFFFAOYSA-N n-(anilinodisulfanyl)aniline Chemical compound C=1C=CC=CC=1NSSNC1=CC=CC=C1 BIHJEIFLAWVSQP-UHFFFAOYSA-N 0.000 claims description 4
- 238000012360 testing method Methods 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 17
- 229920003048 styrene butadiene rubber Polymers 0.000 description 16
- 239000002174 Styrene-butadiene Substances 0.000 description 15
- 238000005259 measurement Methods 0.000 description 13
- 229920001971 elastomer Polymers 0.000 description 10
- 239000005060 rubber Substances 0.000 description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- 238000005299 abrasion Methods 0.000 description 9
- 229910052717 sulfur Inorganic materials 0.000 description 8
- 239000011593 sulfur Substances 0.000 description 8
- 238000009864 tensile test Methods 0.000 description 8
- 239000006087 Silane Coupling Agent Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000005096 rolling process Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000004073 vulcanization Methods 0.000 description 7
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 229920000459 Nitrile rubber Polymers 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 125000003277 amino group Chemical group 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 230000003712 anti-aging effect Effects 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 230000020169 heat generation Effects 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 239000004636 vulcanized rubber Substances 0.000 description 3
- DLLMHEDYJQACRM-UHFFFAOYSA-N 2-(carboxymethyldisulfanyl)acetic acid Chemical compound OC(=O)CSSCC(O)=O DLLMHEDYJQACRM-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229920005549 butyl rubber Polymers 0.000 description 2
- 150000002019 disulfides Chemical class 0.000 description 2
- 229920003049 isoprene rubber Polymers 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 125000005372 silanol group Chemical group 0.000 description 2
- 238000005987 sulfurization reaction Methods 0.000 description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 description 1
- VMTVUDJOOMHKPO-UHFFFAOYSA-N 8-(7-carboxyheptyldisulfanyl)octanoic acid Chemical compound OC(=O)CCCCCCCSSCCCCCCCC(O)=O VMTVUDJOOMHKPO-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 125000005370 alkoxysilyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- OOTFVKOQINZBBF-UHFFFAOYSA-N cystamine Chemical compound CCSSCCN OOTFVKOQINZBBF-UHFFFAOYSA-N 0.000 description 1
- 229940099500 cystamine Drugs 0.000 description 1
- UFULAYFCSOUIOV-UHFFFAOYSA-N cysteamine Chemical compound NCCS UFULAYFCSOUIOV-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229960003151 mercaptamine Drugs 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- ASAOXGWSIOQTDI-UHFFFAOYSA-N triethoxy-[2-(2-triethoxysilylethyltetrasulfanyl)ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCSSSSCC[Si](OCC)(OCC)OCC ASAOXGWSIOQTDI-UHFFFAOYSA-N 0.000 description 1
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
- JTTSZDBCLAKKAY-UHFFFAOYSA-N trimethoxy-[3-(3-trimethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CO[Si](OC)(OC)CCCSSSSCCC[Si](OC)(OC)OC JTTSZDBCLAKKAY-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008179715A JP5347353B2 (ja) | 2008-07-10 | 2008-07-10 | シリカ配合ジエン系ゴム組成物の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008179715A JP5347353B2 (ja) | 2008-07-10 | 2008-07-10 | シリカ配合ジエン系ゴム組成物の製造法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010018691A JP2010018691A (ja) | 2010-01-28 |
| JP2010018691A5 JP2010018691A5 (enExample) | 2011-09-15 |
| JP5347353B2 true JP5347353B2 (ja) | 2013-11-20 |
Family
ID=41703914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008179715A Expired - Fee Related JP5347353B2 (ja) | 2008-07-10 | 2008-07-10 | シリカ配合ジエン系ゴム組成物の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5347353B2 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2517898A1 (de) | 2011-04-29 | 2012-10-31 | Lanxess Deutschland GmbH | Kieselsäurehaltige Kautschukmischungen mit schwefelhaltigen Additiven |
| EP2671727A1 (de) * | 2012-06-06 | 2013-12-11 | LANXESS Deutschland GmbH | Kieselsäurehaltige Kautschukmischungen mit schwefelhaltigen Additiven |
| RU2015115271A (ru) * | 2012-09-24 | 2016-11-20 | ЛЕНКСЕСС Дойчланд ГмбХ | Полисульфидные добавки, способ их получения и их применение в резиновых смесях |
| EP2711198A1 (de) * | 2012-09-24 | 2014-03-26 | LANXESS Deutschland GmbH | Polysulfid-Additive, Verfahren zu deren Herstellung und deren Verwendung in Kautschukmischungen |
| JP6147585B2 (ja) * | 2013-06-25 | 2017-06-14 | 東洋ゴム工業株式会社 | ゴム組成物及び空気入りタイヤ |
| JP6285214B2 (ja) * | 2013-11-27 | 2018-02-28 | 住友ゴム工業株式会社 | 冬用空気入りタイヤ |
| JP6314576B2 (ja) * | 2014-03-24 | 2018-04-25 | 横浜ゴム株式会社 | ゴムの製造方法 |
| US10308788B2 (en) | 2014-05-21 | 2019-06-04 | Bridgestone Corporation | Rubber compound to produce tyres |
| WO2016009776A1 (ja) * | 2014-07-15 | 2016-01-21 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物の製造方法および空気入りタイヤ |
| EP3348600B1 (en) * | 2015-10-27 | 2022-11-16 | Sumitomo Rubber Industries, Ltd. | Method for producing rubber composition for tires, and method for producing tire |
| KR102818100B1 (ko) | 2023-07-18 | 2025-06-11 | 금호타이어 주식회사 | 타이어 트레드용 고무조성물 및 이를 포함하는 타이어 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9226384D0 (en) * | 1992-12-18 | 1993-02-10 | Robinson Bros Ltd | Compositions and agents for vulcanising rubber |
| JP3665225B2 (ja) * | 1999-04-01 | 2005-06-29 | 倉敷化工株式会社 | 未加硫ゴム組成物の製造方法 |
| JP5021968B2 (ja) * | 2006-07-14 | 2012-09-12 | 東洋ゴム工業株式会社 | ゴム組成物及びその製造方法 |
| JP5065663B2 (ja) * | 2006-12-07 | 2012-11-07 | 東洋ゴム工業株式会社 | 天然ゴム組成物の製造方法 |
| JP5269504B2 (ja) * | 2008-07-10 | 2013-08-21 | 東洋ゴム工業株式会社 | ゴム組成物の製造方法 |
-
2008
- 2008-07-10 JP JP2008179715A patent/JP5347353B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2010018691A (ja) | 2010-01-28 |
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