JP5339015B1 - 樹脂被覆難燃性繊維糸及び樹脂被覆難燃性繊維織物 - Google Patents
樹脂被覆難燃性繊維糸及び樹脂被覆難燃性繊維織物 Download PDFInfo
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Abstract
Description
前記日射遮蔽係数は遮熱性の指標であり、JIS R 3106に準拠した方法により測定できる。また、前記可視光透過率は透光性の指標であり、JIS R 3106に準拠した方法により測定できる。日射遮蔽係数及び可視光透過率の測定には、例えば、日立ハイテク社製U‐4000形自記分光光度計を用いることができる。
また、本発明の樹脂被覆難燃性繊維織物は、難燃性繊維糸としてガラス繊維束を用いた、樹脂被覆ガラス繊維織物であることが好ましい。ガラス繊維束は不燃性であり、線膨張係数が低く寸法安定性に優れ、かつ入手が容易であるので、樹脂被覆ガラス繊維織物は、遮熱性と透光性が求められるブラインド等の建材用途に特に好適である。
3420に準拠して測定した引張強度により表される数値としての結束強度が7.4N以上の範囲である。また、樹脂被覆ガラス繊維束は、一端部に100gの分銅を取着した前記樹脂被覆ガラス繊維束を直径1mmのステンレス棒に掛けて上下に往復運動させたときに切断するまでの往復回数で示される数値としての摩擦強度が50回以上である。
本実施例では、まず、難燃性繊維糸2として、Eガラス製の直径7μmのガラスフィラメントを400本集束し、45.0texの質量のガラス繊維束を準備した。次に、ガラス繊維束を250m/分の速度で搬送しながら、第1の樹脂溶液が収容されている槽内を連続的に通過させることにより、ガラス繊維束に第1の樹脂溶液を含浸させた。ここで、第1の樹脂溶液は、溶媒としてアセトン溶媒160質量部に、塩化ビニル−酢酸ビニル共重合体樹脂(株式会社カネカ製、商品名:カネビラックL−EY)42.3質量部を混合したものである。
本実施例では、第2の樹脂被覆層を形成する第2の樹脂溶液の塩化ビニル樹脂組成物、2種の二酸化チタン粒子の比率を変えた以外は、実施例1と同様に樹脂被覆ガラス繊維束を作成した。用いた第2の樹脂被覆層の塩化ビニル樹脂組成物と2種の二酸化チタンの比率は、塩化ビニル樹脂組成物86.8質量%と、二酸化チタンとしての第1の粒子11.3質量%と、第2の粒子1.9質量%である。本実施例で得られた樹脂被覆ガラス繊維束の組成を表1に示す。
本実施例では、第2の樹脂被覆層を形成する第2の樹脂溶液の塩化ビニル樹脂組成物、2種の二酸化チタン粒子の比率を変えた以外は、実施例1と同様に樹脂被覆ガラス繊維束を作成した。用いた第2の樹脂被覆層の塩化ビニル樹脂組成物と2種の二酸化チタンの比率は、塩化ビニル樹脂組成物83.6質量%と、二酸化チタンとしての第1の粒子14.6質量%と、第2の粒子1.8質量%である。本実施例で得られた樹脂被覆ガラス繊維束の組成を表1に示す。
本実施例では、第2の樹脂被覆層を形成する第2の樹脂溶液の塩化ビニル樹脂組成物、2種の二酸化チタン粒子の比率を変えた以外は、実施例1と同様に樹脂被覆ガラス繊維束を作成した。用いた第2の樹脂被覆層の塩化ビニル樹脂組成物と2種の二酸化チタンの比率は、塩化ビニル樹脂組成物90.1質量%と、二酸化チタンとしての第1の粒子7.9質量%と、第2の粒子2.0質量%である。本実施例で得られた樹脂被覆ガラス繊維束の組成を表1に示す。
本実施例では、第2の樹脂被覆層を形成する第2の樹脂溶液の塩化ビニル樹脂組成物、2種の二酸化チタン粒子の比率を変えた以外は、実施例1と同様に樹脂被覆ガラス繊維束を作成した。用いた第2の樹脂被覆層の塩化ビニル樹脂組成物と2種の二酸化チタンの比率は、塩化ビニル樹脂組成物93.8質量%と、二酸化チタンとしての第1の粒子4.1質量%と、第2の粒子2.1質量%である。本実施例で得られた樹脂被覆ガラス繊維束の組成を表1に示す。
本比較例では、第2の樹脂被覆層を形成する第2の樹脂溶液の塩化ビニル樹脂組成物、2種の二酸化チタン粒子の比率を変えた以外は、実施例1と同様に樹脂被覆ガラス繊維束を作成した。用いた第2の樹脂被覆層の塩化ビニル樹脂組成物と2種の二酸化チタンの比率は、塩化ビニル樹脂組成物80.6質量%と、二酸化チタンとしての第1の粒子17.6質量%と、第2の粒子1.8質量%である。本比較例で得られた樹脂被覆ガラス繊維束の組成を表1に示す。
本比較例では、第2の樹脂被覆層を形成する第2の樹脂溶液に、第1の二酸化チタン粒子を含有させず、塩化ビニル樹脂組成物、二酸化チタン粒子で構成した以外は、実施例1と同様に樹脂被覆ガラス繊維束を作成した。用いた第2の樹脂被覆層の塩化ビニル樹脂組成物と第2の二酸化チタンの比率は、塩化ビニル樹脂組成物98.6質量%と、二酸化チタンとしての第2の粒子1.4質量%である。比較例で得られた樹脂被覆ガラス繊維束の組成を表1に示す。
Claims (9)
- 難燃性繊維糸を被覆する樹脂被覆層を備える樹脂被覆難燃性繊維糸において、
該樹脂被覆層は、該樹脂被覆難燃性繊維糸の全質量に対し4〜12質量%の範囲の二酸化チタン粒子を含み、
該二酸化チタン粒子は個数平均粒子径0.6〜1.5μmの範囲の第1の粒子と、個数平均粒子径0.2〜0.4μmの範囲の第2粒子の粒子とを、第1の粒子/第2の粒子=6/4〜9/1の範囲の質量比で含むことを特徴とする樹脂被覆難燃性繊維糸。 - 請求項1記載の樹脂被覆難燃性繊維糸において、前記難燃性繊維糸がガラス繊維束であることを特徴とする樹脂被覆難燃性繊維糸。
- 請求項1又は2記載の樹脂被覆難燃性繊維糸において、
前記樹脂被覆層は第1と第2からなり前記難燃性繊維糸を被覆し、
第1の樹脂被覆層は、前記二酸化チタン粒子を含まず、難燃性繊維糸と第2の樹脂被覆層とを接着する樹脂被覆層であり、
第2の樹脂被覆層は第1の樹脂被覆層上に形成され、前記二酸化チタン粒子を含む樹脂被覆層であることを特徴とする樹脂被覆難燃性繊維糸。 - 請求項3記載の樹脂被覆難燃性繊維糸において、前記難熱性繊維糸は、7.4N以上の範囲の結節強度を備えることを特徴とする樹脂被覆難燃性繊維糸。
- 請求項3又は請求項4記載の樹脂被覆耐熱性繊維糸において、前記難熱性繊維糸は、一端部に100gの分銅を取着した前記樹脂被覆難燃性繊維糸を直径1mmのステンレス棒に掛けて上下に往復運動させたときに切断するまでの往復回数で示される数値として、50回以上の範囲の摩擦強度を備えることを特徴とする樹脂被覆難燃性繊維糸。
- 難燃性繊維糸を被覆する樹脂被覆層を備える樹脂被覆難燃性繊維糸であって、該樹脂被覆層は、該樹脂被覆難燃性繊維糸の全質量に対し4〜12質量%の範囲の二酸化チタン粒子を含み、該二酸化チタン粒子は個数平均粒子径0.6〜1.5μmの範囲の第1の粒子と、個数平均粒子径0.2〜0.4μmの範囲の第2粒子の粒子とを、第1の粒子/第2の粒子=6/4〜9/1の範囲の質量比で含む樹脂被覆難燃性繊維糸を経糸及び緯糸として製織してなることを特徴とする樹脂被覆難燃性繊維織物。
- 請求項6記載の樹脂被覆難燃性繊維織物において、前記樹脂被覆難燃性織物は、9〜18%の範囲の可視光透過率を備えることを特徴とする樹脂被覆難燃性繊維織物。
- 請求項6又は請求項7記載の樹脂被覆難燃性繊維織物において、前記樹脂被覆難燃性繊維織物は、0.150以下の範囲の日射遮蔽係数を備えることを特徴とする樹脂被覆難燃性繊維織物。
- 請求項6から請求項8のいずれか1項に記載の樹脂被覆難燃性繊維織物において、前記難燃性繊維糸がガラス繊維束であることを特徴とする樹脂被覆難燃性繊維織物。
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