JP5164229B2 - 色安定性を有する超吸収性ポリマー組成物 - Google Patents
色安定性を有する超吸収性ポリマー組成物 Download PDFInfo
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- JP5164229B2 JP5164229B2 JP2010516971A JP2010516971A JP5164229B2 JP 5164229 B2 JP5164229 B2 JP 5164229B2 JP 2010516971 A JP2010516971 A JP 2010516971A JP 2010516971 A JP2010516971 A JP 2010516971A JP 5164229 B2 JP5164229 B2 JP 5164229B2
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- superabsorbent polymer
- polymer composition
- superabsorbent
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- HVCNQTCZNBPWBV-UHFFFAOYSA-N 2-hydroxy-2-sulfinoacetic acid Chemical compound OC(=O)C(O)S(O)=O HVCNQTCZNBPWBV-UHFFFAOYSA-N 0.000 claims description 6
- CEFDWZDNAJAKGO-UHFFFAOYSA-N 2-hydroxy-2-sulfoacetic acid Chemical compound OC(=O)C(O)S(O)(=O)=O CEFDWZDNAJAKGO-UHFFFAOYSA-N 0.000 claims description 6
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- LBSPZZSGTIBOFG-UHFFFAOYSA-N bis[2-(4,5-dihydro-1h-imidazol-2-yl)propan-2-yl]diazene;dihydrochloride Chemical compound Cl.Cl.N=1CCNC=1C(C)(C)N=NC(C)(C)C1=NCCN1 LBSPZZSGTIBOFG-UHFFFAOYSA-N 0.000 claims description 3
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- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 claims 2
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- VXYADVIJALMOEQ-UHFFFAOYSA-K tris(lactato)aluminium Chemical compound CC(O)C(=O)O[Al](OC(=O)C(C)O)OC(=O)C(C)O VXYADVIJALMOEQ-UHFFFAOYSA-K 0.000 description 2
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- AYMDJPGTQFHDSA-UHFFFAOYSA-N 1-(2-ethenoxyethoxy)-2-ethoxyethane Chemical compound CCOCCOCCOC=C AYMDJPGTQFHDSA-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/56—Wetness-indicators or colourants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/103—Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
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- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Veterinary Medicine (AREA)
- Hematology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Dispersion Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
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|---|---|---|---|
| US11/778,372 | 2007-07-16 | ||
| US11/778,372 US7816426B2 (en) | 2007-07-16 | 2007-07-16 | Superabsorbent polymer compositions having color stability |
| PCT/US2007/089047 WO2009011717A1 (en) | 2007-07-16 | 2007-12-28 | Superabsorbent polymer compositions having color stability |
Publications (3)
| Publication Number | Publication Date |
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| JP2010533766A JP2010533766A (ja) | 2010-10-28 |
| JP2010533766A5 JP2010533766A5 (enExample) | 2011-01-20 |
| JP5164229B2 true JP5164229B2 (ja) | 2013-03-21 |
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| JP2010516971A Active JP5164229B2 (ja) | 2007-07-16 | 2007-12-28 | 色安定性を有する超吸収性ポリマー組成物 |
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| Country | Link |
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| US (3) | US7816426B2 (enExample) |
| EP (1) | EP2167552B1 (enExample) |
| JP (1) | JP5164229B2 (enExample) |
| KR (1) | KR101474229B1 (enExample) |
| CN (1) | CN101802029B (enExample) |
| TW (1) | TWI406875B (enExample) |
| WO (1) | WO2009011717A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011503282A (ja) * | 2007-11-08 | 2011-01-27 | エフォニック ストックハウゼン ゲーエムベーハー | 向上した色安定性を有する吸水性ポリマー構造体 |
| US12491495B2 (en) | 2021-01-14 | 2025-12-09 | Lg Chem, Ltd. | Method for preparing super absorbent polymer |
Families Citing this family (91)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1808152B1 (en) | 2003-02-12 | 2012-08-29 | The Procter and Gamble Company | Absorbent Core for an Absorbent Article |
| EP1911425B1 (en) | 2003-02-12 | 2014-01-15 | The Procter and Gamble Company | Absorbent core for an absorbent article |
| US7169843B2 (en) * | 2003-04-25 | 2007-01-30 | Stockhausen, Inc. | Superabsorbent polymer with high permeability |
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| JP5940655B2 (ja) | 2011-06-10 | 2016-06-29 | ザ プロクター アンド ギャンブル カンパニー | 使い捨て吸収性物品のための吸収性コア |
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| EP2532328B1 (en) | 2011-06-10 | 2014-02-26 | The Procter and Gamble Company | Method and apparatus for making absorbent structures with absorbent material |
| WO2012170781A1 (en) | 2011-06-10 | 2012-12-13 | The Procter & Gamble Company | Disposable diapers |
| DE102011086522A1 (de) * | 2011-11-17 | 2013-05-23 | Evonik Degussa Gmbh | Superabsorbierende Polymere für hochgefüllte oder faserfreie Hygieneartikel |
| US8871880B2 (en) * | 2012-03-22 | 2014-10-28 | Evonik Corporation | Superabsorbent copolymer |
| KR20140142740A (ko) * | 2012-03-30 | 2014-12-12 | 바스프 에스이 | 색 안정적 초흡수체 |
| US10111002B1 (en) * | 2012-08-03 | 2018-10-23 | Amazon Technologies, Inc. | Dynamic audio optimization |
| KR102226473B1 (ko) * | 2012-08-27 | 2021-03-12 | 가부시키가이샤 닛폰 쇼쿠바이 | 입자상 흡수제 및 그의 제조 방법 |
| WO2014064176A1 (de) | 2012-10-24 | 2014-05-01 | Evonik Degussa Gmbh | Geruchs- und farbstabile wasserabsorbierende zusammensetzung |
| GB2510665C (en) | 2012-11-13 | 2017-01-25 | Procter & Gamble | Absorbent articles with channels and signals |
| EP2740452B1 (en) | 2012-12-10 | 2021-11-10 | The Procter & Gamble Company | Absorbent article with high absorbent material content |
| US9216116B2 (en) | 2012-12-10 | 2015-12-22 | The Procter & Gamble Company | Absorbent articles with channels |
| EP2740450A1 (en) | 2012-12-10 | 2014-06-11 | The Procter & Gamble Company | Absorbent core with high superabsorbent material content |
| US9216118B2 (en) | 2012-12-10 | 2015-12-22 | The Procter & Gamble Company | Absorbent articles with channels and/or pockets |
| US10639215B2 (en) | 2012-12-10 | 2020-05-05 | The Procter & Gamble Company | Absorbent articles with channels and/or pockets |
| PL2740449T3 (pl) | 2012-12-10 | 2019-07-31 | The Procter & Gamble Company | Artykuł chłonny o wysokiej zawartości materiału chłonnego |
| JP5952431B2 (ja) | 2013-01-29 | 2016-07-13 | 株式会社日本触媒 | 吸水性樹脂材料及びその製造方法 |
| US9599970B2 (en) * | 2013-03-27 | 2017-03-21 | The United States Of America As Represented By The Secretary Of The Navy | Safety critical control system that includes control logic or machine readable instructions that selectively locks or enables the control system based on one or more machine implemented state machines that includes states associated with detection or matching of one or more predetermined signals on distinct conduction paths between elements of the control system and related methods |
| US9375507B2 (en) | 2013-04-10 | 2016-06-28 | Evonik Corporation | Particulate superabsorbent polymer composition having improved stability |
| US9302248B2 (en) | 2013-04-10 | 2016-04-05 | Evonik Corporation | Particulate superabsorbent polymer composition having improved stability |
| PL3254656T3 (pl) | 2013-06-14 | 2022-01-10 | The Procter & Gamble Company | Wyrób chłonny i wkład chłonny tworzący kanały w stanie mokrym |
| US9950308B2 (en) | 2013-08-01 | 2018-04-24 | Lg Chem, Ltd. | Superabsorbent polymer |
| KR101527585B1 (ko) * | 2013-08-13 | 2015-06-09 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
| JP6334705B2 (ja) | 2013-08-27 | 2018-05-30 | ザ プロクター アンド ギャンブル カンパニー | チャネルを有する吸収性物品 |
| US9987176B2 (en) | 2013-08-27 | 2018-06-05 | The Procter & Gamble Company | Absorbent articles with channels |
| JP6169800B2 (ja) | 2013-09-16 | 2017-07-26 | ザ プロクター アンド ギャンブル カンパニー | チャネルと標識を持つ吸収性物品 |
| EP2851048B1 (en) * | 2013-09-19 | 2018-09-05 | The Procter and Gamble Company | Absorbent cores having material free areas |
| JP6151790B2 (ja) | 2013-10-09 | 2017-06-21 | 株式会社日本触媒 | 吸水性樹脂を主成分とする粒子状吸水剤及びその製造方法 |
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| KR101700907B1 (ko) * | 2013-12-10 | 2017-01-31 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
| US9937482B2 (en) * | 2013-12-11 | 2018-04-10 | Lg Chem, Ltd. | Super absorbent polymer resin and method for preparing same |
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| PL2886092T3 (pl) | 2013-12-19 | 2017-03-31 | The Procter And Gamble Company | Wkłady chłonne z obszarami tworzącymi kanały i zgrzewami osłony c |
| EP2905001B1 (en) | 2014-02-11 | 2017-01-04 | The Procter and Gamble Company | Method and apparatus for making an absorbent structure comprising channels |
| JP6154412B2 (ja) | 2014-03-05 | 2017-06-28 | エボニック デグサ ゲーエムベーハーEvonik Degussa GmbH | 改善された臭気抑制性能を有する超吸収性ポリマー及びその製造方法 |
| WO2015163523A1 (en) * | 2014-04-25 | 2015-10-29 | Songwon Industrial Co., Ltd. | Production of water-absorbent polymer particles employing a blowing agent and surface-crosslinking |
| EP2949300B1 (en) | 2014-05-27 | 2017-08-02 | The Procter and Gamble Company | Absorbent core with absorbent material pattern |
| JP2016030832A (ja) | 2014-07-25 | 2016-03-07 | エボニック デグサ ゲーエムベーハーEvonik Degussa GmbH | 付着防止加工助剤並びに吸水性粒子の製造におけるその使用 |
| KR101782501B1 (ko) * | 2014-12-10 | 2017-09-27 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
| KR101949455B1 (ko) * | 2015-01-07 | 2019-02-18 | 주식회사 엘지화학 | 내고화성이 향상된 고흡수성 수지 및 그 제조 방법 |
| RU2017133027A (ru) | 2015-03-16 | 2019-04-16 | Дзе Проктер Энд Гэмбл Компани | Абсорбирующие изделия повышенной прочности |
| US10322040B2 (en) | 2015-03-16 | 2019-06-18 | The Procter & Gamble Company | Absorbent articles with improved cores |
| CN107592805B (zh) | 2015-05-12 | 2021-07-06 | 宝洁公司 | 具有改善的芯与底片粘合剂的吸收制品 |
| CN107683126A (zh) | 2015-05-29 | 2018-02-09 | 宝洁公司 | 具有槽和润湿指示标记的吸收制品 |
| CN109563210B (zh) * | 2016-08-10 | 2021-10-08 | 巴斯夫欧洲公司 | 制备超吸收剂的方法 |
| MY186384A (en) * | 2016-12-13 | 2021-07-21 | L Bruggemann Gmbh & Co Kg | Mixed salts of hydroxyalkane sulfinic acid |
| KR102075733B1 (ko) | 2016-12-13 | 2020-02-10 | 주식회사 엘지화학 | 고흡수성 수지 및 이의 제조 방법 |
| KR102093352B1 (ko) | 2016-12-19 | 2020-03-25 | 주식회사 엘지화학 | 고흡수성 수지의 제조 방법 |
| JP6979770B2 (ja) * | 2017-02-16 | 2021-12-15 | Sdpグローバル株式会社 | 吸水性樹脂粒子及びその製造方法 |
| CN110016324B (zh) * | 2018-01-10 | 2021-08-17 | 中国石油化工股份有限公司 | 一种耐高温水基钻井液提切剂及其制备方法 |
| EP3781108B1 (en) * | 2018-04-20 | 2023-11-29 | Basf Se | Process for producing superabsorbents |
| KR102457232B1 (ko) * | 2018-09-27 | 2022-10-20 | 주식회사 엘지화학 | 고흡수성 수지 시트의 제조 방법 |
| WO2021162085A1 (ja) | 2020-02-14 | 2021-08-19 | 株式会社日本触媒 | 吸水性樹脂およびその製造方法 |
| CN115667335A (zh) * | 2020-04-30 | 2023-01-31 | 金伯利-克拉克环球有限公司 | 基于多种带电单体的共聚物的超吸收聚合物 |
| KR102584470B1 (ko) * | 2021-05-28 | 2023-10-05 | 욱성화학주식회사 | 가압흡수성이 우수한 생분해성 기반의 고흡수성 수지 및 그의 제조방법 |
| CN118414370A (zh) * | 2021-12-21 | 2024-07-30 | 住友精化株式会社 | 包覆树脂粒子、吸水性树脂组合物及吸收体 |
Family Cites Families (68)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51125468A (en) * | 1975-03-27 | 1976-11-01 | Sanyo Chem Ind Ltd | Method of preparing resins of high water absorbency |
| DE2706135C2 (de) | 1977-02-14 | 1982-10-28 | Chemische Fabrik Stockhausen GmbH, 4150 Krefeld | Verdickungsmittel für ausgeschiedenen Darminhalt und Harn |
| US4131576A (en) | 1977-12-15 | 1978-12-26 | National Starch And Chemical Corporation | Process for the preparation of graft copolymers of a water soluble monomer and polysaccharide employing a two-phase reaction system |
| US4286082A (en) * | 1979-04-06 | 1981-08-25 | Nippon Shokubai Kagaku Kogyo & Co., Ltd. | Absorbent resin composition and process for producing same |
| JPS6025045B2 (ja) * | 1980-03-19 | 1985-06-15 | 製鉄化学工業株式会社 | 塩水吸収能のすぐれたアクリル酸重合体の製造方法 |
| JPS60163956A (ja) | 1984-02-04 | 1985-08-26 | Arakawa Chem Ind Co Ltd | 吸水性樹脂の製法 |
| US4863989A (en) | 1986-06-04 | 1989-09-05 | Seitetsu Kagaku Co., Ltd. | Water-absorbent resin composition |
| DE3713601A1 (de) | 1987-04-23 | 1988-11-10 | Stockhausen Chem Fab Gmbh | Verfahren zur herstellung eines stark wasserabsorbierenden polymerisats |
| DE3926169A1 (de) | 1989-08-08 | 1991-02-14 | Basf Ag | Verfahren zur verbesserung der wasseraufnahmekapazitaet von vernetzten, wasserquellbaren polymeren |
| DE4020780C1 (enExample) | 1990-06-29 | 1991-08-29 | Chemische Fabrik Stockhausen Gmbh, 4150 Krefeld, De | |
| JP2902201B2 (ja) | 1991-03-18 | 1999-06-07 | ストックハウゼン ルイジアナ リミティド | 超吸収性ポリマーの残留アクリル酸含量を低下させる方法 |
| DE4244548C2 (de) * | 1992-12-30 | 1997-10-02 | Stockhausen Chem Fab Gmbh | Pulverförmige, unter Belastung wäßrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung in textilen Konstruktionen für die Körperhygiene |
| DE4418818C2 (de) | 1993-07-09 | 1997-08-21 | Stockhausen Chem Fab Gmbh | Pulverförmige, vernetzte, wäßrige Flüssigkeiten und/oder Körperflüssigkeiten absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Anwendung |
| IL110134A (en) * | 1993-07-09 | 1998-07-15 | Stockhausen Chem Fab Gmbh | Polymers capable of absorbing aqueous liquids and body fluids their preparation and use |
| US5451613A (en) * | 1993-09-17 | 1995-09-19 | Nalco Chemical Company | Superabsorbent polymer having improved absorption rate and absorption under pressure |
| DE4333056C2 (de) * | 1993-09-29 | 1998-07-02 | Stockhausen Chem Fab Gmbh | Pulverförmige, wäßrige Flüssigkeiten absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung als Absorptionsmittel |
| DE69505398T2 (de) | 1994-08-12 | 1999-03-11 | Kao Corp., Tokio/Tokyo | Verfahren zur herstellung von verbesserten superabsorbierenden polymeren |
| EP0733648A1 (en) * | 1995-03-23 | 1996-09-25 | Kao Corporation | Process for producing polymer particles |
| DE19529348C2 (de) * | 1995-08-09 | 1997-11-20 | Stockhausen Chem Fab Gmbh | Absorptionsmittel für Wasser und wäßrige Flüssigkeiten auf Polyacrylatbasis sowie Verfahren zu ihrer Herstellung und Verwendung |
| DE19743759A1 (de) | 1997-10-02 | 1999-04-08 | Brueggemann L Kg | Sulfinsäurederivate und deren Herstellung und Verwendung |
| IL137034A0 (en) | 1998-01-07 | 2001-06-14 | Procter & Gamble | Absorbent polymer compositions having high sorption capacities under an applied pressure |
| DE60014054T2 (de) | 1999-03-12 | 2005-02-03 | Basf Ag | Farbstabile superabsorbierende polymerzusammensetzung |
| JP2001282009A (ja) * | 2000-03-31 | 2001-10-12 | Ricoh Co Ltd | 中間転写ベルトの製造方法及び中間転写ベルト、並びに、該中間転写ベルトを用いた画像形成装置 |
| DE10053858A1 (de) * | 2000-10-30 | 2002-05-08 | Stockhausen Chem Fab Gmbh | Absorbierendes Gebilde mit verbesserten Blockingeigenschaften |
| US20020115971A1 (en) | 2000-12-20 | 2002-08-22 | Holmes Lori Tassone | Thin, high capacity multi-layer absorbent core |
| JP3987348B2 (ja) * | 2001-01-26 | 2007-10-10 | 株式会社日本触媒 | 吸水剤の製法 |
| JP2003052742A (ja) * | 2001-08-09 | 2003-02-25 | San-Dia Polymer Ltd | 吸収剤及びこれを使用した吸収性構造体 |
| US6906131B2 (en) * | 2001-09-17 | 2005-06-14 | Stockhausen Gmbh & Co. Kg | Cellulose material with improved absorbency |
| JP3939988B2 (ja) * | 2002-01-16 | 2007-07-04 | 住友精化株式会社 | 吸水性樹脂の製造方法 |
| DE10218147B4 (de) * | 2002-04-23 | 2005-12-22 | Stockhausen Gmbh | Wasserabsorbierende, die Zersetzung von Körperflüssigkeiten verzögernde Polymerteilchen, deren Herstellung und Verwendung |
| DE10241481B4 (de) * | 2002-09-07 | 2006-07-06 | Celanese Emulsions Gmbh | Verfahren zum Herstellen von wässrigen Polymerdispersionen mit sehr niedrigen Restmonomergehalten und deren Verwendung |
| DE10249821A1 (de) | 2002-10-25 | 2004-05-13 | Stockhausen Gmbh & Co. Kg | Absorbierende Polymergebilde mit verbesserter Rententionskapazität und Permeabilität |
| AU2003274077A1 (en) * | 2002-10-25 | 2004-05-13 | Stockhausen Gmbh | Two-stage mixing method for producing an absorbent polymer |
| JP2004210924A (ja) | 2002-12-27 | 2004-07-29 | Sumitomo Seika Chem Co Ltd | 吸水性樹脂組成物 |
| TW200500046A (en) | 2003-03-26 | 2005-01-01 | Basf Ag | Color-stable superabsorbent polymer composition |
| US7169843B2 (en) | 2003-04-25 | 2007-01-30 | Stockhausen, Inc. | Superabsorbent polymer with high permeability |
| DE10334286B4 (de) | 2003-07-25 | 2006-01-05 | Stockhausen Gmbh | Pulverförmige,wasserabsorbierende Polymere mit mittels thermoplastischen Klebstoffen gebundenen Feinteilchen, Verfahren zu deren Herstellung sowie diese beinhaltende chemische Produkte und Verbunde |
| DE10338447A1 (de) * | 2003-08-21 | 2005-03-31 | Basf Ag | Verwendung von 2-Hydroxy-2-sulfinatoessigsäure oder deren Salzen als Initiator in W/O-Emulsionen |
| US7163969B2 (en) * | 2003-10-14 | 2007-01-16 | Stockhausen, Inc. | Superabsorbent polymer aqueous paste and coating |
| US7291674B2 (en) * | 2003-10-28 | 2007-11-06 | Stockhausen, Inc. | Superabsorbent polymer |
| US7173086B2 (en) | 2003-10-31 | 2007-02-06 | Stockhausen, Inc. | Superabsorbent polymer with high permeability |
| US7579402B2 (en) * | 2003-11-12 | 2009-08-25 | Evonik Stockhausen, Inc. | Superabsorbent polymer having delayed free water absorption |
| WO2005054356A1 (de) | 2003-12-03 | 2005-06-16 | Basf Aktiengesellschaft | Mindestens ein sterisch gehindertes einwertiges und/oder mehrwertiges phenol enthaltende superabsorber |
| DE102004028002A1 (de) * | 2004-06-09 | 2006-01-05 | Stockhausen Gmbh | Verfahren zur Herstellung von hydrophilen Polymeren unter Verwendung eines rechnererzeugten Modells |
| EP1769004B1 (de) * | 2004-06-21 | 2017-08-09 | Evonik Degussa GmbH | Wasserabsorbierendes polysaccharid sowie ein verfahren zu seiner herstellung |
| TWI522092B (zh) * | 2005-02-28 | 2016-02-21 | 贏創德固賽有限責任公司 | 丙烯酸和基於可再生原料之吸水聚合物結構及二者之製備方法 |
| DE102005010198A1 (de) * | 2005-03-05 | 2006-09-07 | Degussa Ag | Hydrolysestabile, nachvernetzte Superabsorber |
| US8481664B2 (en) | 2005-04-12 | 2013-07-09 | Nippon Shokubai Co., Ltd. | Particulate water absorbing agent including polyacrylic acid (polyacrylate) based water absorbing resin as a principal component, method for production thereof, water-absorbent core and absorbing article in which the particulate water absorbing agent is used |
| DE102005018922A1 (de) * | 2005-04-22 | 2006-10-26 | Stockhausen Gmbh | Mit Polykationen oberflächenbehandeltes wasserabsorbierendes Polymergebilde |
| JP5222721B2 (ja) * | 2005-04-22 | 2013-06-26 | エフォニック ストックハウゼン ゲーエムベーハー | 高吸収性を有する吸水性ポリマー構造体 |
| DE102005018924A1 (de) * | 2005-04-22 | 2006-10-26 | Stockhausen Gmbh | Wasserabsorbierende Polymergebilde mit verbesserten Absorptionseigenschaften |
| CN2819951Y (zh) | 2005-06-16 | 2006-09-27 | 千宝实业股份有限公司 | 远红外线能量垫体 |
| DE102005055497A1 (de) * | 2005-11-18 | 2007-05-31 | Stockhausen Gmbh | Geruchsbindende superabsorbierende Zusammensetzung |
| US7335713B2 (en) * | 2005-12-02 | 2008-02-26 | Stockhausen, Inc. | Method for preparing a flexible superabsorbent binder polymer composition |
| US7312286B2 (en) * | 2005-12-02 | 2007-12-25 | Stockhausen, Inc. | Flexible superabsorbent binder polymer composition |
| US7812082B2 (en) * | 2005-12-12 | 2010-10-12 | Evonik Stockhausen, Llc | Thermoplastic coated superabsorbent polymer compositions |
| US8829107B2 (en) * | 2006-02-28 | 2014-09-09 | Evonik Degussa Gmbh | Biodegradable superabsorbent polymer composition with good absorption and retention properties |
| WO2007121937A2 (de) * | 2006-04-21 | 2007-11-01 | Evonik Stockhausen Gmbh | Oberflächennachvernetzte superabsorber behandelt mit aluminiumlactat und optional aluminiumsulfat |
| DE102006019157A1 (de) * | 2006-04-21 | 2007-10-25 | Stockhausen Gmbh | Herstellung von hochpermeablen, superabsorbierenden Polymergebilden |
| DE102006060156A1 (de) * | 2006-12-18 | 2008-06-19 | Evonik Stockhausen Gmbh | Wasserabsorbierende Polymergebilde, welche unter Einsatz von Polymerdispersionen hergestellt wurden |
| US8236884B2 (en) * | 2007-03-23 | 2012-08-07 | Evonik Stockhausen, Llc | High permeability superabsorbent polymer compositions |
| US7816426B2 (en) * | 2007-07-16 | 2010-10-19 | Evonik Stockhausen, Llc | Superabsorbent polymer compositions having color stability |
| DE102007045724B4 (de) * | 2007-09-24 | 2012-01-26 | Evonik Stockhausen Gmbh | Superabsorbierende Zusammensetzung mit Tanninen zur Geruchskontrolle, Verfahren zu deren Herstellung und Verwendung |
| DE102007053619A1 (de) | 2007-11-08 | 2009-05-20 | Evonik Stockhausen Gmbh | Wasserabsorbierende Polymergebilde mit verbesserter Farbstabilität |
| US8318306B2 (en) * | 2008-01-30 | 2012-11-27 | Evonik Stockhausen, Llc | Superabsorbent polymer compositions having a triggering composition |
| US8222477B2 (en) * | 2008-10-20 | 2012-07-17 | Evonik Stockhausen, Llc | Superabsorbent polymer containing clay, particulate, and method of making same |
| US7910688B2 (en) * | 2008-10-22 | 2011-03-22 | Evonik Stockhausen Inc. | Recycling superabsorbent polymer fines |
| US8361926B2 (en) * | 2008-11-25 | 2013-01-29 | Evonik Stockhausen, Llc | Water-absorbing polysaccharide and method for producing the same |
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2007
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- 2007-12-28 CN CN2007800537912A patent/CN101802029B/zh active Active
- 2007-12-28 KR KR1020107001034A patent/KR101474229B1/ko active Active
- 2007-12-28 EP EP07866086.7A patent/EP2167552B1/en not_active Not-in-force
- 2007-12-28 WO PCT/US2007/089047 patent/WO2009011717A1/en not_active Ceased
- 2007-12-28 JP JP2010516971A patent/JP5164229B2/ja active Active
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011503282A (ja) * | 2007-11-08 | 2011-01-27 | エフォニック ストックハウゼン ゲーエムベーハー | 向上した色安定性を有する吸水性ポリマー構造体 |
| US12491495B2 (en) | 2021-01-14 | 2025-12-09 | Lg Chem, Ltd. | Method for preparing super absorbent polymer |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2010533766A (ja) | 2010-10-28 |
| US8063118B2 (en) | 2011-11-22 |
| US20120083411A1 (en) | 2012-04-05 |
| TW200911849A (en) | 2009-03-16 |
| CN101802029A (zh) | 2010-08-11 |
| TWI406875B (zh) | 2013-09-01 |
| KR20100040858A (ko) | 2010-04-21 |
| CN101802029B (zh) | 2012-10-10 |
| EP2167552B1 (en) | 2018-02-07 |
| WO2009011717A1 (en) | 2009-01-22 |
| EP2167552A1 (en) | 2010-03-31 |
| KR101474229B1 (ko) | 2014-12-18 |
| US7816426B2 (en) | 2010-10-19 |
| US20110009841A1 (en) | 2011-01-13 |
| US8236876B2 (en) | 2012-08-07 |
| US20090023848A1 (en) | 2009-01-22 |
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