JP5008399B2 - 有機チタン化物及び／又は有機ジルコン化物を含有する水性分散液の形態である防錆塗料組成物 - Google Patents
有機チタン化物及び／又は有機ジルコン化物を含有する水性分散液の形態である防錆塗料組成物 Download PDFInfo
- Publication number
- JP5008399B2 JP5008399B2 JP2006552720A JP2006552720A JP5008399B2 JP 5008399 B2 JP5008399 B2 JP 5008399B2 JP 2006552720 A JP2006552720 A JP 2006552720A JP 2006552720 A JP2006552720 A JP 2006552720A JP 5008399 B2 JP5008399 B2 JP 5008399B2
- Authority
- JP
- Japan
- Prior art keywords
- organic
- rust
- metal
- coating
- titanate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims description 85
- 239000008199 coating composition Substances 0.000 title claims description 47
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims description 26
- 230000003449 preventive effect Effects 0.000 title claims description 13
- 239000006185 dispersion Substances 0.000 title claims description 7
- 239000000203 mixture Substances 0.000 claims description 107
- 229910052751 metal Inorganic materials 0.000 claims description 71
- 239000002184 metal Substances 0.000 claims description 71
- 229910000077 silane Inorganic materials 0.000 claims description 57
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 53
- 238000000576 coating method Methods 0.000 claims description 51
- 239000011248 coating agent Substances 0.000 claims description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 47
- 239000000758 substrate Substances 0.000 claims description 45
- 239000012074 organic phase Substances 0.000 claims description 37
- 125000000524 functional group Chemical group 0.000 claims description 18
- 150000003839 salts Chemical class 0.000 claims description 17
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 16
- 229910052782 aluminium Inorganic materials 0.000 claims description 15
- 239000003973 paint Substances 0.000 claims description 15
- 229910052725 zinc Inorganic materials 0.000 claims description 15
- 239000011701 zinc Substances 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- 239000011230 binding agent Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- 230000007797 corrosion Effects 0.000 claims description 13
- 238000005260 corrosion Methods 0.000 claims description 13
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 12
- 239000003960 organic solvent Substances 0.000 claims description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 11
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 11
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 10
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 8
- 229910000831 Steel Inorganic materials 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 239000010959 steel Substances 0.000 claims description 8
- 239000003623 enhancer Substances 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 230000006698 induction Effects 0.000 claims description 7
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical group CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000002562 thickening agent Substances 0.000 claims description 6
- 150000003609 titanium compounds Chemical class 0.000 claims description 6
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 claims description 6
- 229910052727 yttrium Inorganic materials 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- 239000000080 wetting agent Substances 0.000 claims description 5
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 4
- RWLALWYNXFYRGW-UHFFFAOYSA-N 2-Ethyl-1,3-hexanediol Chemical compound CCCC(O)C(CC)CO RWLALWYNXFYRGW-UHFFFAOYSA-N 0.000 claims description 3
- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 claims description 3
- YQGOWXYZDLJBFL-UHFFFAOYSA-N dimethoxysilane Chemical group CO[SiH2]OC YQGOWXYZDLJBFL-UHFFFAOYSA-N 0.000 claims description 3
- 229960005082 etohexadiol Drugs 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims description 3
- 230000002401 inhibitory effect Effects 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- XPGAWFIWCWKDDL-UHFFFAOYSA-N propan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCC[O-].CCC[O-].CCC[O-].CCC[O-] XPGAWFIWCWKDDL-UHFFFAOYSA-N 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 claims description 2
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- 229910001018 Cast iron Inorganic materials 0.000 claims description 2
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims description 2
- ZXPDYFSTVHQQOI-UHFFFAOYSA-N diethoxysilane Chemical compound CCO[SiH2]OCC ZXPDYFSTVHQQOI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 2
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical group O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 2
- 230000002265 prevention Effects 0.000 claims description 2
- 239000011135 tin Substances 0.000 claims description 2
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 claims description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 2
- 238000010981 drying operation Methods 0.000 claims 3
- VPJOGDPLXNTKAZ-UHFFFAOYSA-N 2-methylpropanoic acid;2,2,4-trimethylpentane-1,3-diol Chemical compound CC(C)C(O)=O.CC(C)C(O)C(C)(C)CO VPJOGDPLXNTKAZ-UHFFFAOYSA-N 0.000 claims 1
- QPLNUHHRGZVCLQ-UHFFFAOYSA-K aluminum;[oxido(phosphonooxy)phosphoryl] phosphate Chemical group [Al+3].OP([O-])(=O)OP([O-])(=O)OP(O)([O-])=O QPLNUHHRGZVCLQ-UHFFFAOYSA-K 0.000 claims 1
- 238000005119 centrifugation Methods 0.000 claims 1
- 125000003827 glycol group Chemical group 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 238000005728 strengthening Methods 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- 239000008346 aqueous phase Substances 0.000 description 26
- -1 zircon compound Chemical class 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000010936 titanium Substances 0.000 description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 11
- 238000006460 hydrolysis reaction Methods 0.000 description 8
- 239000003595 mist Substances 0.000 description 7
- 230000007062 hydrolysis Effects 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
- 229910052845 zircon Inorganic materials 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- XGZNHFPFJRZBBT-UHFFFAOYSA-N ethanol;titanium Chemical compound [Ti].CCO.CCO.CCO.CCO XGZNHFPFJRZBBT-UHFFFAOYSA-N 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 229920000847 nonoxynol Polymers 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 239000004115 Sodium Silicate Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical group [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 3
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- WECIKJKLCDCIMY-UHFFFAOYSA-N 2-chloro-n-(2-cyanoethyl)acetamide Chemical compound ClCC(=O)NCCC#N WECIKJKLCDCIMY-UHFFFAOYSA-N 0.000 description 2
- PUMRUSBKNSBTAL-UHFFFAOYSA-N 3,4-dihydro-2h-chromene-2-carbaldehyde Chemical compound C1=CC=C2OC(C=O)CCC2=C1 PUMRUSBKNSBTAL-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910001111 Fine metal Inorganic materials 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 210000004534 cecum Anatomy 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- XAVMMNWPOYCFPU-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanolate;propan-2-olate;titanium(4+) Chemical compound [Ti+4].CC(C)[O-].CC(C)[O-].OCCN(CCO)CC[O-].OCCN(CCO)CC[O-] XAVMMNWPOYCFPU-UHFFFAOYSA-N 0.000 description 1
- XDVOLDOITVSJGL-UHFFFAOYSA-N 3,7-dihydroxy-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B(O)OB2OB(O)OB1O2 XDVOLDOITVSJGL-UHFFFAOYSA-N 0.000 description 1
- HYIZUMWJUAITFM-UHFFFAOYSA-N 5,5-dimethylhexane-1,3-diol 2-methylpropanoic acid Chemical compound C(C(C)C)(=O)O.CC(CC(CCO)O)(C)C HYIZUMWJUAITFM-UHFFFAOYSA-N 0.000 description 1
- KGYXYKHTHJPEBX-UHFFFAOYSA-N 5-ethoxy-3-ethoxycarbonyl-3-hydroxy-5-oxopentanoic acid Chemical compound CCOC(=O)CC(O)(CC(O)=O)C(=O)OCC KGYXYKHTHJPEBX-UHFFFAOYSA-N 0.000 description 1
- 229910002019 Aerosil® 380 Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 229910000914 Mn alloy Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical group [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 125000000466 oxiranyl group Chemical group 0.000 description 1
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical class [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229910000048 titanium hydride Inorganic materials 0.000 description 1
- JPJZHBHNQJPGSG-UHFFFAOYSA-N titanium;zirconium;tetrahydrate Chemical compound O.O.O.O.[Ti].[Zr] JPJZHBHNQJPGSG-UHFFFAOYSA-N 0.000 description 1
- PZJJKWKADRNWSW-UHFFFAOYSA-N trimethoxysilicon Chemical group CO[Si](OC)OC PZJJKWKADRNWSW-UHFFFAOYSA-N 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- QSGNKXDSTRDWKA-UHFFFAOYSA-N zirconium dihydride Chemical compound [ZrH2] QSGNKXDSTRDWKA-UHFFFAOYSA-N 0.000 description 1
- 229910000568 zirconium hydride Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C09D201/10—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing hydrolysable silane groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/14—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
- C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/086—Organic or non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/58—Metal-containing linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0401349 | 2004-02-11 | ||
| FR0401349A FR2866029B1 (fr) | 2004-02-11 | 2004-02-11 | Composition de revetement anti-corrosion en dispersion aqueuse comprenant un titanate et/ou un zirconate organique |
| PCT/IB2005/000488 WO2005078026A1 (en) | 2004-02-11 | 2005-02-10 | Anticorrosion coating composition in aqueous dispersion comprising an organic titanate and/or zirconate |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012010358A Division JP5383834B2 (ja) | 2004-02-11 | 2012-01-20 | 有機チタン化物及び／又は有機ジルコン化物を含有する水性分散液の形態である防錆塗料組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007534794A JP2007534794A (ja) | 2007-11-29 |
| JP5008399B2 true JP5008399B2 (ja) | 2012-08-22 |
Family
ID=34778680
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006552720A Expired - Lifetime JP5008399B2 (ja) | 2004-02-11 | 2005-02-10 | 有機チタン化物及び／又は有機ジルコン化物を含有する水性分散液の形態である防錆塗料組成物 |
| JP2012010358A Expired - Lifetime JP5383834B2 (ja) | 2004-02-11 | 2012-01-20 | 有機チタン化物及び／又は有機ジルコン化物を含有する水性分散液の形態である防錆塗料組成物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012010358A Expired - Lifetime JP5383834B2 (ja) | 2004-02-11 | 2012-01-20 | 有機チタン化物及び／又は有機ジルコン化物を含有する水性分散液の形態である防錆塗料組成物 |
Country Status (19)
Families Citing this family (68)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2866029B1 (fr) | 2004-02-11 | 2006-05-26 | Dacral | Composition de revetement anti-corrosion en dispersion aqueuse comprenant un titanate et/ou un zirconate organique |
| US9243150B2 (en) * | 2005-04-21 | 2016-01-26 | The United States Of America As Represented By The Secretary Of The Navy | Oxide coated metal pigments and film-forming compositions |
| RU2426818C2 (ru) * | 2005-08-31 | 2011-08-20 | Кастрол Лимитед | Композиции и способ нанесения на поверхности металлов алкоксисилановых покрытий |
| US8748007B2 (en) * | 2006-05-02 | 2014-06-10 | Ppg Industries Ohio, Inc. | Coating compositions exhibiting corrosion resistance properties, related coated articles and methods |
| US20070256590A1 (en) * | 2006-05-02 | 2007-11-08 | Scott Matthew S | Coating compositions exhibiting corrosion resistance properties, related coated articles and methods |
| US20070259172A1 (en) * | 2006-05-02 | 2007-11-08 | Scott Matthew S | Coating compositions exhibiting corrosion resistance properties, related coated articles and methods |
| US8592042B2 (en) * | 2006-11-09 | 2013-11-26 | The Boeing Company | Sol-gel coating method and composition |
| KR101286776B1 (ko) † | 2008-01-24 | 2013-07-17 | 유껜 고교 가부시기가이샤 | 방청 도료 조성물 및 그 조성물을 사용한 방청 도포막을 갖는 부재의 제조 방법 |
| JP4431840B2 (ja) † | 2008-01-24 | 2010-03-17 | ユケン工業株式会社 | 耐食性塗膜を有する部材、その製造方法、およびそれを製造するための塗料組成物 |
| JP5319929B2 (ja) * | 2008-02-08 | 2013-10-16 | マツモトファインケミカル株式会社 | 水系表面処理組成物 |
| JP5479684B2 (ja) * | 2008-02-08 | 2014-04-23 | 日本ペイント株式会社 | 水系表面処理組成物 |
| JP2009185363A (ja) * | 2008-02-08 | 2009-08-20 | Matsumoto Fine Chemical Co Ltd | 表面処理組成物 |
| KR20090098582A (ko) | 2008-03-14 | 2009-09-17 | 삼성전기주식회사 | 방열판 표면개질용 조성물 및 이를 이용한 인쇄회로기판용방열판의 표면 처리 방법 |
| FR2933424B1 (fr) * | 2008-07-07 | 2011-03-25 | Alcan Rhenalu | Procede de preparation avant soudage de produits en alliage aluminium-lithium |
| WO2010062436A1 (en) | 2008-10-31 | 2010-06-03 | University Of Florida Research Foundation, Inc. | Transparent inorganic-organic hybrid materials via aqueous sol-gel processing |
| KR100939165B1 (ko) * | 2009-08-10 | 2010-01-28 | 김정태 | 부식방지용 도료 조성물 및 이의 제조방법 |
| DE102010030114B4 (de) | 2009-08-11 | 2021-11-04 | Evonik Operations Gmbh | Wässriges Silansystem für den Blankkorrosionsschutz, Verfahren zu dessen Herstellung, dessen Verwendung sowie mit diesem behandelte Gegenstände und Korrosionsschutzschicht |
| EP2510061A2 (en) * | 2009-12-11 | 2012-10-17 | Tata Steel UK Limited | Environmentally friendly protective coatings for substrates |
| KR100970462B1 (ko) * | 2010-02-09 | 2010-07-16 | 엘베스트지에이티 주식회사 | 에너지 절감형 방식용 금속도막 조성물 및 그 제조방법 |
| KR100970461B1 (ko) * | 2010-02-09 | 2010-07-16 | 엘베스트지에이티 주식회사 | 유무기 하이브리드 방식 코팅제 조성물 및 그 제조방법 |
| EP2536668B1 (en) | 2010-02-16 | 2021-07-28 | Ferro Corporation | MATERIALS FOR IMPROVED ADHESION RELATING TO FUNCTIONAL COLD END COATINGS (CECs) AND METHODS OF DETECTING SAME |
| US9481935B2 (en) * | 2010-10-27 | 2016-11-01 | Chemetall Gmbh | Aqueous composition for pretreating a metal surface before applying another coating or for treating said surface |
| JP5612460B2 (ja) * | 2010-12-24 | 2014-10-22 | 日油株式会社 | 構造体 |
| WO2012106739A1 (de) | 2011-02-11 | 2012-08-16 | Helmut Buchberger | Inhalatorkomponente |
| AT510837B1 (de) | 2011-07-27 | 2012-07-15 | Helmut Dr Buchberger | Inhalatorkomponente |
| CN102181853B (zh) * | 2011-04-08 | 2012-11-07 | 广州立铭环保科技有限公司 | 一种铝合金无铬钝化处理液 |
| CN102268199B (zh) * | 2011-06-01 | 2013-11-27 | 张华� | 一种用于延缓电力系统接地网腐蚀的涂层及其制备方法 |
| KR101114549B1 (ko) * | 2011-08-05 | 2012-02-27 | (주)고려소재연구소 | 저마찰 코팅 조성물 및 그 제조방법 |
| JP5891666B2 (ja) * | 2011-09-14 | 2016-03-23 | 熱研化学工業株式会社 | 水系エマルジョン塗料および塗装方法 |
| US10767070B2 (en) | 2012-06-06 | 2020-09-08 | Dow Global Technologies Llc | Process for preparing multi-color dispersions and multi-color dispersions made thereof |
| JP2014019037A (ja) * | 2012-07-17 | 2014-02-03 | Daihatsu Motor Co Ltd | パイプおよびその製造方法 |
| BR112015002158B1 (pt) * | 2012-08-01 | 2021-05-25 | The United States Of America, As Represented By The Secretary Of The Navy | composição eletroquimicamente resistente à corrosão |
| JP2013129846A (ja) * | 2013-03-08 | 2013-07-04 | Matsumoto Fine Chemical Co Ltd | 水系表面処理組成物 |
| RU2545302C1 (ru) * | 2013-11-28 | 2015-03-27 | Закрытое акционерное общество "Научно-производственное предприятие "Спектр" | Антикоррозионный состав для покрытий |
| JP6264904B2 (ja) * | 2014-01-30 | 2018-01-24 | コニカミノルタ株式会社 | 情報処理装置、情報処理装置の制御方法、および情報処理装置の制御プログラム |
| US9562000B2 (en) * | 2014-02-14 | 2017-02-07 | Prc-Desoto International, Inc. | Amino alcohol treatment for sol-gel conversion coatings, substrates including the same, and methods of making the substrates |
| CN103924247B (zh) * | 2014-04-12 | 2016-06-08 | 冯智勇 | 一种高效的燃煤锅炉缓蚀剂 |
| EP2933355B1 (de) | 2014-04-16 | 2019-07-03 | Ewald Dörken AG | Verfahren zum Herstellen einer dunklen Korrosionsschutzbeschichtung |
| GB2533135B (en) | 2014-12-11 | 2020-11-11 | Nicoventures Holdings Ltd | Aerosol provision systems |
| AU2015389013B2 (en) | 2015-03-31 | 2020-08-27 | Dow Global Technologies Llc | A binder composition and a paint formulation made thereof |
| BR112017021307B1 (pt) * | 2015-04-07 | 2022-10-11 | Chemetall Gmbh | Método para ajustar especificamente a condutividade elétrica de um revestimento de conversão, e, superfície metálica revestida por conversão |
| FR3034774B1 (fr) * | 2015-04-08 | 2017-04-07 | Soc Now Des Couleurs Zinciques | Pigments anti-corrosion a base de polyphosphate d'aluminium et de terre rare |
| LU92802B1 (en) * | 2015-08-19 | 2017-03-01 | Luxembourg Patent Co | Sol-gel formulations enhancing corrosion resistance and lubrication properties of pressure equipment |
| FR3040641B1 (fr) * | 2015-09-07 | 2020-05-08 | Nof Metal Coatings Europe | Procede d'application d'un revetement anticorrosion sur une piece metallique, composition de revetement aqueux, revetement anticorrosion de pieces metalliques et piece metallique revetue |
| CN106544654B (zh) * | 2015-09-23 | 2019-04-19 | 比亚迪股份有限公司 | 一种处理液及其应用以及金属化产品和方法 |
| GB2542838B (en) | 2015-10-01 | 2022-01-12 | Nicoventures Trading Ltd | Aerosol provision system |
| JP6471358B2 (ja) * | 2016-01-04 | 2019-02-20 | 高橋 寿庭 | 防錆膜付き基材構造、防錆加工仕様車両、防錆加工仕様機械器具、および防錆膜付き基材構造形成方法 |
| EP3243878A1 (de) | 2016-05-10 | 2017-11-15 | Rembrandtin Lack GmbH Nfg.KG | Korrosionsschutz |
| JP6794023B2 (ja) * | 2016-08-04 | 2020-12-02 | 株式会社青山製作所 | ねじ部品用防錆処理液、防錆処理されたねじ部品の製造方法及び防錆処理されたねじ部品 |
| CN108130722B (zh) * | 2016-11-30 | 2020-03-31 | 比亚迪股份有限公司 | 一种金属化产品和金属化的方法 |
| CN107400883B (zh) * | 2017-08-03 | 2019-08-27 | 浙江五源科技股份有限公司 | 镀锌板涂装前硅烷/锆复合处理剂及其制备方法 |
| JP6820033B2 (ja) * | 2017-10-11 | 2021-01-27 | ユケン工業株式会社 | 金属粉末分散組成物および水系コーティング組成物 |
| CN107858677A (zh) * | 2017-11-22 | 2018-03-30 | 五河县绍峰电器有限公司 | 一种用于织物透气测量仪钢质工件表面处理的钝化液 |
| FR3074186B1 (fr) * | 2017-11-28 | 2021-04-02 | Nof Metal Coatings Europe | Liants deshydrates, sous forme solide, leur procede d'obtention et leur procede de rehydratation |
| FR3074185B1 (fr) * | 2017-11-28 | 2021-04-09 | Nof Metal Coatings Europe | Compositions de revetement deshydratees, sous forme solide, leur procede d'obtention et leur procede de rehydratation |
| US20200407567A1 (en) | 2018-02-26 | 2020-12-31 | Nof Metal Coatings Europe | Finish coat composition for corrosion-resistant coating of a metal part, wet-on-wet method for applying a finish coat, corrosion-resistant coating of metal parts, and coated metal part |
| CN108410237A (zh) * | 2018-03-28 | 2018-08-17 | 上海志育新材料科技有限公司 | 一种添加石墨烯的 Galfan 合金防腐添加剂以及防腐漆 |
| FR3096051B1 (fr) | 2019-05-17 | 2021-06-04 | Nof Metal Coatings Europe | Composition de revetement deshydratee, sous forme solide, son procede d’obtention et son procede de rehydratation |
| DE102019135827A1 (de) | 2019-12-27 | 2021-07-01 | Cooper-Standard Automotive (Deutschland) Gmbh | Überwurfschraube für mit wenigstens einem Bördel versehene Rohrleitungen, insbesondere Bremsrohre |
| EP3868846B1 (de) * | 2020-02-20 | 2022-11-02 | Epg-F | Dekorative und schützende beschichtungszusammensetzung für metall-, glas- und kunststoff-substrate |
| CN111249922B (zh) * | 2020-03-21 | 2024-02-23 | 安泰环境工程技术有限公司 | 一种Fe-Al系金属膜及其制备方法 |
| WO2021252837A1 (en) * | 2020-06-12 | 2021-12-16 | Swimc Llc | Coating composition for beverage containers |
| MX2023006301A (es) | 2020-12-02 | 2023-06-14 | Nof Metal Coatings Asia Pacific Co Ltd | Composicion de revestimiento para evitar la oxidacion, pelicula y articulo para evitar la oxidacion y particulas de compuesto a base de zinc y composicion que contienen particulas de compuesto a base de zinc. |
| CN113292078A (zh) * | 2021-04-20 | 2021-08-24 | 西安理工大学 | 一种二氧化钛气凝胶的制备方法 |
| MX2021005111A (es) * | 2021-04-30 | 2022-11-01 | Controladora Mabe Sa De Capital Variable | Recubrimiento ceramico a base de tungstatos y molibdatos para proteccion de superficies metalicas, procedimiento de preparacion y uso del mismo. |
| EP4365245A4 (en) * | 2021-06-30 | 2025-06-25 | Chugoku Marine Paints, Ltd. | Rust preventive coating composition |
| JPWO2023013482A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 2021-08-04 | 2023-02-09 | ||
| DE102021210995A1 (de) | 2021-09-30 | 2023-03-30 | Federal-Mogul Nürnberg GmbH | Oxidationsschutz-Schicht für Motorkolben aus Stahl oder einer eisenbasierten Legierung |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3687882A (en) * | 1971-04-29 | 1972-08-29 | Nexcel Corp | Silane-titanate dispersions for coating aluminum |
| BE793557A (fr) | 1971-12-30 | 1973-06-29 | Stauffer Chemical Co | Compositions de revetement fournissant une protection galvanique |
| US4224213A (en) | 1978-06-09 | 1980-09-23 | Cook Paint And Varnish Company | Single package inorganic zinc rich paints having a silicate and titanate ester copolymer binder |
| JPS5741766A (en) | 1980-08-22 | 1982-03-09 | Fujitsu Ltd | Remote monitor system of automatic transaction system |
| US4495156A (en) | 1983-01-05 | 1985-01-22 | American Can Company | Primary system |
| US4741778A (en) * | 1986-03-22 | 1988-05-03 | Nippon Telegraph & Telephone Corporation | Thermal control coating composition |
| US5316855A (en) * | 1990-07-13 | 1994-05-31 | Virginia Tech Intellectual Properties, Inc. | High abrasion resistance coating materials from organic/inorganic hybrid materials produced by the sol-gel method |
| US5200237A (en) * | 1990-10-01 | 1993-04-06 | Associated Universities, Inc. | Solid-gel precursor solutions and methods for the fabrication of polymetallicsiloxane coating films |
| US5232783A (en) * | 1991-09-10 | 1993-08-03 | General Electric Company | Abrasion resistant coatings for glass articles |
| US5807430A (en) * | 1995-11-06 | 1998-09-15 | Chemat Technology, Inc. | Method and composition useful treating metal surfaces |
| US5868819A (en) * | 1996-05-20 | 1999-02-09 | Metal Coatings International Inc. | Water-reducible coating composition for providing corrosion protection |
| US6605365B1 (en) * | 1996-11-04 | 2003-08-12 | The Boeing Company | Pigmented alkoxyzirconium sol |
| CN1171961C (zh) * | 1998-04-10 | 2004-10-20 | 松下电工株式会社 | 亲水性无机涂膜的形成方法及无机涂料组合物 |
| KR100793623B1 (ko) | 2000-05-11 | 2008-01-11 | 다우 코닝 코포레이션 | 피복 조성물 |
| US7078076B2 (en) * | 2001-02-14 | 2006-07-18 | Metal Coatings International Inc. | Particulate metal alloy coating for providing corrosion protection |
| US20040206266A1 (en) | 2001-02-14 | 2004-10-21 | Metal Coatings International Inc. | Particulate metal alloy coating for providing corrosion protection |
| EP1397443B1 (en) * | 2001-05-01 | 2019-07-24 | Dow Silicones Corporation | Protective coating composition |
| DE10308237B4 (de) * | 2003-02-25 | 2014-01-16 | Chemetall Gmbh | Verfahren zur Beschichtung von metallischen Oberflächen, zugehörige Zusammensetzung und ihre Verwendung |
| EP1599615B1 (de) * | 2003-02-25 | 2012-04-11 | Chemetall GmbH | Verfahren zur beschichtung von metallischen oberflächen mit einer silan-reichen zusammensetzung |
| US7247386B2 (en) * | 2003-12-23 | 2007-07-24 | 3M Innovative Properties Company | Composition of an oligomeric fluorosilane and surface treatment of retroreflective sheet |
| FR2866029B1 (fr) | 2004-02-11 | 2006-05-26 | Dacral | Composition de revetement anti-corrosion en dispersion aqueuse comprenant un titanate et/ou un zirconate organique |
| US7081508B2 (en) * | 2004-06-25 | 2006-07-25 | Shin-Etsu Chemical Co., Ltd. | Primer composition |
| JP4431840B2 (ja) * | 2008-01-24 | 2010-03-17 | ユケン工業株式会社 | 耐食性塗膜を有する部材、その製造方法、およびそれを製造するための塗料組成物 |
| JP5741766B2 (ja) | 2012-03-08 | 2015-07-01 | 日産自動車株式会社 | タイヤ空気圧モニター装置 |
-
2004
- 2004-02-11 FR FR0401349A patent/FR2866029B1/fr not_active Expired - Lifetime
-
2005
- 2005-02-04 TW TW94103492A patent/TWI359178B/zh not_active IP Right Cessation
- 2005-02-07 MY MYPI20050464A patent/MY152932A/en unknown
- 2005-02-10 EP EP20050708604 patent/EP1713869B1/en not_active Expired - Lifetime
- 2005-02-10 ES ES08103218T patent/ES2370055T3/es not_active Expired - Lifetime
- 2005-02-10 JP JP2006552720A patent/JP5008399B2/ja not_active Expired - Lifetime
- 2005-02-10 AT AT05708604T patent/ATE527322T1/de not_active IP Right Cessation
- 2005-02-10 EP EP08103218A patent/EP1930383B1/en not_active Expired - Lifetime
- 2005-02-10 PT PT05708604T patent/PT1713869E/pt unknown
- 2005-02-10 AU AU2005213540A patent/AU2005213540B2/en not_active Expired
- 2005-02-10 US US10/589,040 patent/US20070134503A1/en not_active Abandoned
- 2005-02-10 CA CA 2555321 patent/CA2555321C/en not_active Expired - Lifetime
- 2005-02-10 RU RU2006132345A patent/RU2396299C2/ru not_active Application Discontinuation
- 2005-02-10 PT PT08103218T patent/PT1930383E/pt unknown
- 2005-02-10 WO PCT/IB2005/000488 patent/WO2005078026A1/en active Application Filing
- 2005-02-10 PL PL05708604T patent/PL1713869T3/pl unknown
- 2005-02-10 AT AT08103218T patent/ATE526375T1/de not_active IP Right Cessation
- 2005-02-10 CN CN2005800047666A patent/CN1918248B/zh not_active Expired - Lifetime
- 2005-02-10 KR KR1020067018536A patent/KR101157534B1/ko not_active Expired - Lifetime
- 2005-02-10 PL PL08103218T patent/PL1930383T3/pl unknown
- 2005-02-10 ES ES05708604T patent/ES2371551T3/es not_active Expired - Lifetime
- 2005-02-10 BR BRPI0507517A patent/BRPI0507517B1/pt active IP Right Grant
- 2005-02-11 AR ARP050100494 patent/AR047612A1/es active IP Right Grant
-
2010
- 2010-12-29 US US12/980,749 patent/US8628827B2/en active Active
-
2012
- 2012-01-20 JP JP2012010358A patent/JP5383834B2/ja not_active Expired - Lifetime
- 2012-02-10 IN IN1247DEN2012 patent/IN2012DN01247A/en unknown
-
2013
- 2013-11-25 US US14/088,911 patent/US9150733B2/en not_active Expired - Lifetime
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5008399B2 (ja) | 有機チタン化物及び／又は有機ジルコン化物を含有する水性分散液の形態である防錆塗料組成物 | |
| JP5567266B2 (ja) | エポキシシランオリゴマー及びそれを含有するコーティング組成物 | |
| CA2323730C (en) | Water-reducible coating composition for providing corrosion protection | |
| JP2009518503A (ja) | エポキシシランオリゴマー及びそれを含有するコーティング組成物 | |
| HUP0200514A2 (en) | In a given case chrome-free coating composition, a corrosion-resistant coated substrate coated by said composition and a method of preparing the coated substrate | |
| JP4938167B2 (ja) | 錆止めを施すための水−希釈可能なコーティング組成物 | |
| EP1199339B1 (en) | Water-reducible coating composition for providing corrosion protection | |
| JP2004256696A (ja) | 含ケイ素ジンクリッチハイブリッド漆組成物 | |
| JP2018534125A (ja) | 金属部品への耐腐食性塗膜を施す方法、水性塗装組成物、金属部品用の耐腐食性塗膜、及び塗装された金属部品 | |
| MXPA06009190A (en) | Anticorrosion coating composition in aqueous dispersion comprising an organic titanate and/or zirconate | |
| HK1097288B (en) | Anticorrosion coating composition in aqueous dispersion comprising an organic titanate and/or zirconate | |
| MXPA00011396A (es) | Composicion de revestimiento reducible en agua para proporcionar proteccion contra la corrosion. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080118 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20101203 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20110216 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20110401 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20110407 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20110408 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110428 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20111021 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20111128 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20120511 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20120529 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5008399 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150608 Year of fee payment: 3 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| EXPY | Cancellation because of completion of term |