JP5001000B2 - 共役オレフィンのホモ重合又は共重合方法 - Google Patents

共役オレフィンのホモ重合又は共重合方法 Download PDF

Info

Publication number
JP5001000B2
JP5001000B2 JP2006503716A JP2006503716A JP5001000B2 JP 5001000 B2 JP5001000 B2 JP 5001000B2 JP 2006503716 A JP2006503716 A JP 2006503716A JP 2006503716 A JP2006503716 A JP 2006503716A JP 5001000 B2 JP5001000 B2 JP 5001000B2
Authority
JP
Japan
Prior art keywords
bis
hydrocarbyl
group
substituted hydrocarbyl
lithium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2006503716A
Other languages
English (en)
Japanese (ja)
Other versions
JP2006518742A5 (enExample
JP2006518742A (ja
Inventor
カー．ハー． チエル，スベン
Original Assignee
スティロン ヨーロッパ ゲゼルシャフト ミット ベシュレンクテル ハフツング
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by スティロン ヨーロッパ ゲゼルシャフト ミット ベシュレンクテル ハフツング filed Critical スティロン ヨーロッパ ゲゼルシャフト ミット ベシュレンクテル ハフツング
Publication of JP2006518742A publication Critical patent/JP2006518742A/ja
Publication of JP2006518742A5 publication Critical patent/JP2006518742A5/ja
Application granted granted Critical
Publication of JP5001000B2 publication Critical patent/JP5001000B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/046—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes polymerising vinyl aromatic monomers and isoprene, optionally with other conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0213—Complexes without C-metal linkages
    • B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/37—Lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38—Lanthanides other than lanthanum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2006503716A 2003-02-21 2004-02-18 共役オレフィンのホモ重合又は共重合方法 Expired - Fee Related JP5001000B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US44907703P 2003-02-21 2003-02-21
US44907603P 2003-02-21 2003-02-21
US60/449,077 2003-02-21
US60/449,076 2003-02-21
PCT/US2004/004941 WO2004076504A2 (en) 2003-02-21 2004-02-18 Process for homo- or copolymerization of conjugated olefines

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2011020777A Division JP5363515B2 (ja) 2003-02-21 2011-02-02 共役オレフィンのホモ重合又は共重合方法

Publications (3)

Publication Number Publication Date
JP2006518742A JP2006518742A (ja) 2006-08-17
JP2006518742A5 JP2006518742A5 (enExample) 2007-04-05
JP5001000B2 true JP5001000B2 (ja) 2012-08-15

Family

ID=32930501

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2006503716A Expired - Fee Related JP5001000B2 (ja) 2003-02-21 2004-02-18 共役オレフィンのホモ重合又は共重合方法
JP2011020777A Expired - Fee Related JP5363515B2 (ja) 2003-02-21 2011-02-02 共役オレフィンのホモ重合又は共重合方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2011020777A Expired - Fee Related JP5363515B2 (ja) 2003-02-21 2011-02-02 共役オレフィンのホモ重合又は共重合方法

Country Status (11)

Country Link
US (3) US7612009B2 (enExample)
EP (2) EP2267046B1 (enExample)
JP (2) JP5001000B2 (enExample)
KR (2) KR101092349B1 (enExample)
AU (1) AU2004215465A1 (enExample)
BR (1) BRPI0407665A (enExample)
CA (2) CA2516232C (enExample)
ES (1) ES2427626T3 (enExample)
MX (1) MXPA05008841A (enExample)
RU (1) RU2348653C2 (enExample)
WO (1) WO2004076504A2 (enExample)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0407665A (pt) 2003-02-21 2006-03-01 Dow Global Technology Inc catalisador de complexo metálico apropriado para polimerização ou copolimerização de monÈmeros de adição etilenicamente insaturados
FR2886937B1 (fr) * 2005-06-14 2007-08-10 Michelin Soc Tech Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene
US7825201B2 (en) * 2007-12-31 2010-11-02 Bridgestone Corporation Process for producing polydienes
US7741418B2 (en) * 2007-12-31 2010-06-22 Bridgestone Corporation Process for producing polydienes
EP2311889A1 (de) * 2009-10-16 2011-04-20 LANXESS Deutschland GmbH Neodym-katalysierte Polybutadiene
EP2599800B1 (en) * 2010-07-30 2017-06-21 Bridgestone Corporation Copolymer and manufacturing method for same
CN103140515B (zh) * 2010-07-30 2015-07-01 株式会社普利司通 共聚物、橡胶组合物、交联橡胶组合物和轮胎
EP2599808B1 (en) * 2010-07-30 2017-01-25 Bridgestone Corporation Method for controlling chain structure in copolymers
RU2537385C2 (ru) * 2010-07-30 2015-01-10 Бриджстоун Корпорейшн Сополимер, каучуковая композиция, сшитая каучуковая композиция и покрышка
RU2608312C2 (ru) * 2011-02-05 2017-01-17 Бриджстоун Корпорейшн Лантаноидный комплексный катализатор и способ полимеризации с его применением
US8680210B2 (en) * 2011-05-02 2014-03-25 Bridgestone Corporation Method for making functionalized polymer
CN103562246B (zh) * 2011-06-02 2015-07-15 株式会社普利司通 共聚物、橡胶组合物、交联橡胶组合物和轮胎
ITMI20111651A1 (it) * 2011-09-14 2013-03-15 Polimeri Europa Spa Complesso bis-immino piridinico di lantanidi, sistema catalitico comprendente detto complesso bis-immino piridinico e procedimento per la (co)polimerizzazione di dieni coniugati
ITMI20111650A1 (it) * 2011-09-14 2013-03-15 Polimeri Europa Spa Complesso bis-imminico di lantanidi, sistema catalitico comprendente detto complesso bis-imminico e procedimento per la (co)polimerizzazione di dieni coniugati
RU2487137C2 (ru) * 2011-10-04 2013-07-10 ОТКРЫТОЕ АКЦИОНЕРНОЕ ОБЩЕСТВО "СИБУР Холдинг" Способ получения разветвленных функционализированных диеновых (со)полимеров
CN104136238B (zh) * 2012-02-29 2017-07-04 盛禧奥欧洲有限责任公司 产生二烯聚合物的方法
CN104558451B (zh) * 2013-10-17 2017-02-15 中国石油化工股份有限公司 一种高顺式丁二烯‑异戊二烯嵌段共聚物及其制备方法
JP6665779B2 (ja) * 2014-07-09 2020-03-13 宇部興産株式会社 共役ジエン重合用触媒、共役ジエン重合体、変性共役ジエン重合体、及びポリブタジエン、並びに、それらを含む組成物
US10640589B2 (en) 2015-12-07 2020-05-05 Bridgestone Corporation Polybutadiene polymers and rubber compositions incorporating same for low temperature applications
JP7160620B2 (ja) * 2018-03-05 2022-10-25 株式会社ブリヂストン 共重合体、共重合体の製造方法、ゴム組成物及びタイヤ
EP3622843B1 (en) 2018-09-13 2023-01-25 The Goodyear Tire & Rubber Company Resin modified oil extended rubber

Family Cites Families (78)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1301491B (de) 1966-10-11 1969-08-21 Basf Ag Verfahren zur Herstellung von 1, 3-Dienpolymerisaten
CA1212932A (en) * 1982-04-01 1986-10-21 Derek K. Jenkins Polymerisation of conjugated dienes
FR2567135B1 (fr) * 1984-07-03 1989-01-13 Asahi Chemical Ind Polymere ou copolymere de butadiene et procede de preparation
US4575538A (en) * 1984-12-20 1986-03-11 Phillips Petroleum Company Olefin polymerization
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
WO1994000500A1 (en) 1992-06-26 1994-01-06 Exxon Chemical Patents Inc. Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers
ES2149262T3 (es) * 1993-01-29 2000-11-01 Dow Chemical Co Interpolimerizaciones de etileno.
EP0816386B1 (en) 1993-03-23 1998-12-16 Asahi Kasei Kogyo Kabushiki Kaisha Olefin polymerization catalyst having a multidentate ligand
IT1265049B1 (it) * 1993-08-06 1996-10-28 Eniricerche Spa Complessi alogenati dei lantanidi e loro uso nella polimerizzazione di monomeri insaturi
NL9400919A (nl) 1994-06-07 1996-01-02 Specs B V Nieuwe organometaalverbindingen en werkwijze voor het polymeriseren van alkenen onder toepassing van deze organonetaalverbindingen als katalysatoren.
WO1995033776A1 (en) 1994-06-07 1995-12-14 Specs And Biospecs B.V. Novel organo-metallic compounds, methods for preparing same, and a method for the polymerization of unsaturated hydrocarbons using said organo-metallic compounds as catalysts, as well as novel semi-products and catalyst preparations
ES2164774T3 (es) 1994-08-03 2002-03-01 Exxonmobil Chem Patents Inc Composicion catalitica ionica soportada.
US5495036A (en) * 1994-09-12 1996-02-27 The Dow Chemical Company Metal (III) complexes containing conjugated, non-aromatic anionic II-bound groups and addition polymerization catalysts therefrom
US5625087A (en) * 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
DE9415365U1 (de) 1994-09-22 1994-11-17 Renz Alfred Mehrteiliger Ring
DE4436059A1 (de) * 1994-10-10 1996-04-11 Bayer Ag Verfahren zur Herstellung von mittels Nd-Katalysatoren polymerisierten Dienkautschuken mit niedrigem cold-flow und geringem Eigengeruch
BR9604776A (pt) * 1995-03-10 1998-06-23 Dow Chemical Co Componente de catalisador sustentado catalisador sustentado processo para preparar um componente de catalisador sustentado e um catalisador sustentado aduto de um composto organometálico processo de polimerizaçao por adiç o composto complexo e método para preparar um composto complexo
DE19512127A1 (de) 1995-04-04 1996-10-10 Bayer Ag Neuer Katalysator für die Gasphasenpolymerisation von konjugierten Dienen
DE19512116A1 (de) 1995-04-04 1996-10-10 Bayer Ag Gasphasenpolymerisation von konjugierten Dienen in Gegenwart von Allylverbindungen der seltenen Erden
US5914377A (en) * 1995-04-04 1999-06-22 Bayer Ag Method for the production of diene rubbers in the gas phase
FI952098L (fi) 1995-05-02 1996-11-03 Borealis As LLDPE-polymeerien valmistusmenetelmä
DE19525866A1 (de) 1995-07-15 1997-01-16 Zahnradfabrik Friedrichshafen Flügelzellenpumpe mit einem Stromregelventil
US5610115A (en) * 1995-07-20 1997-03-11 Samsung General Chemicals Co., Ltd. Organic carrier supported metallocene catalyst for olefin polymerization
WO1997009348A2 (en) 1995-09-08 1997-03-13 Karo Bio Ab Orphan receptor
JPH0977819A (ja) 1995-09-11 1997-03-25 Daicel Chem Ind Ltd ポリオレフィン製造用触媒、およびポリオレフィンの製造方法
HU218360B (hu) 1995-10-27 2000-08-28 The Dow Chemical Company Könnyen hordozóra vihető fémkomplexek és eljárás alfa-olefinek polimerizálására
US6486089B1 (en) 1995-11-09 2002-11-26 Exxonmobil Oil Corporation Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution
PL326932A1 (en) 1995-11-27 1998-11-09 Dow Chemical Co Supported catalyst containing an activator capable to form "captured" cations
DE19548288A1 (de) 1995-12-22 1997-06-26 Hoechst Ag Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
WO1997024344A1 (en) 1995-12-27 1997-07-10 Shell Internationale Research Maatschappij B.V. Preparation of oxirane compounds with titanasilsesquioxane catalysts
US5856255A (en) 1996-01-22 1999-01-05 Albemarle Corporation Preparation of supported auxiliary catalysts at elevated temperature and pressure in a closed vessel
RU2111976C1 (ru) 1996-02-13 1998-05-27 Воронежский филиал Государственного предприятия "Научно-исследовательский институт синтетического каучука им.акад.С.В.Лебедева" Способ получения цис-1,4-полибутадиена
RU2109757C1 (ru) 1996-02-13 1998-04-27 Воронежский филиал Государственного предприятия "Научно-исследовательский институт синтетического каучука им.акад.С.В.Лебедева" Способ получения 1,2-полибутадиена
US5914289A (en) 1996-02-19 1999-06-22 Fina Research, S.A. Supported metallocene-alumoxane catalysts for the preparation of polyethylene having a broad monomodal molecular weight distribution
US6313239B1 (en) 1996-03-05 2001-11-06 Bayer Corporation Olefin polymerization with group 4 metal-containing organosilicon dendrimers
DE59712644D1 (de) 1996-08-13 2006-06-14 Basell Polyolefine Gmbh Geträgerte chemische Verbindung
EP0846696B1 (en) * 1996-12-09 2003-06-18 Mitsubishi Chemical Corporation Catalyst for polymerization of alpha-olefins
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
JP2001511831A (ja) 1997-02-17 2001-08-14 バイエル・アクチエンゲゼルシヤフト 新規な触媒系、ジエンの溶液重合、懸濁重合及び気相重合のためのその使用及びそれを使用して製造されたジエンゴムの使用
WO1998045039A1 (en) 1997-04-04 1998-10-15 The Regents Of The University Of California Polymerization catalysts containing electron-withdrawing amide ligands
DE19720171A1 (de) 1997-05-14 1998-11-19 Bayer Ag Verbindungen der Seltenen Erden und ihre Verwendung als Polymerisationskatalysatoren für ungesättigte Verbindungen
DE19728126A1 (de) 1997-07-02 1999-01-07 Bayer Ag Katalysatorsystem auf Basis von Monoazadien-Metallkomplexen
US6001478A (en) * 1997-08-08 1999-12-14 Union Carbide Chemicals & Plastics Technology Corporation Resin particle produced by diene polymerization with rare earth and transition metal catalysts
US5879805A (en) * 1997-09-09 1999-03-09 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization of vinylpolybutadiene
JP3680516B2 (ja) 1997-09-12 2005-08-10 宇部興産株式会社 共役ジエン重合用触媒及び共役ジエン重合体の製造方法
US6018007A (en) * 1997-09-22 2000-01-25 Bridgestone Corporation Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
DE19746266A1 (de) 1997-10-20 1999-04-22 Bayer Ag Katalysator auf Basis von Verbindungen der seltenen Erdmetalle für die Polymerisation von ungesättigten organischen Verbindungen
IT1296572B1 (it) 1997-11-27 1999-07-14 Enichem Spa Complessi catalitici a base di lantanidi per la (co)polimerizzazione di dieni coniugati
US6197713B1 (en) * 1997-12-19 2001-03-06 Bridgestone Corporation Use of Lewis acids for the breakdown of gelatinous rare earth compounds in hydrocarbon solutions
US6653430B1 (en) 1998-02-04 2003-11-25 Japan As Represented By Director General Of The Agency Of Industrial Science And Technology Butadiene polymers and process for producing conjugated diene polymers
KR100287955B1 (ko) 1998-06-08 2001-05-02 유현식 올레핀계 또는 스티렌계 중합용 신규 메탈로센 촉매 및 이를 이용한 중합방법
DE19832446A1 (de) 1998-07-18 2000-01-27 Bayer Ag Verfahren zur Polymerisation von konjugierten Diolefinen (Dienen) mit Katalysatoren der Seltenen Erden in Gegenwart vinylaromatischer Lösungsmittel
DE19832442A1 (de) 1998-07-18 2000-01-27 Bayer Ag Verfahren zur Polymerisation von konjugierten Diolefinen (Dienen) mit Katalysatoren auf Basis von Vanadin-Verbindungen in Gegenwart vinylaromatischer Lösungsmittel
US20030134999A1 (en) * 1998-07-18 2003-07-17 Heike Windisch Method for polymerizing conjugated diolefins (dienes) with rare earth catalysts in the presence of vinylaromatic solvents
DE19835785A1 (de) 1998-08-07 2000-02-17 Bayer Ag Verfahren zur Polymerisation von Dienen mittels chlorierter Titanverbindungen
WO2000018808A1 (en) * 1998-09-30 2000-04-06 Exxon Chemical Patents Inc. Cationic group 3 catalyst system
KR100365581B1 (ko) * 1999-02-25 2003-01-15 금호석유화학 주식회사 높은 1,4-시스 함량을 갖는 폴리부타디엔의 제조방법
WO2000052062A1 (fr) * 1999-03-04 2000-09-08 Riken Composition de catalyseur
US6825297B1 (en) * 1999-05-14 2004-11-30 The Dow Chemical Company Transition metal complexes and olefin polymerization process
EP1187862A1 (de) 1999-05-18 2002-03-20 Bayer Aktiengesellschaft Verfahren zur herstellung von thermoplastischen formmassen unter verwendung von kautschuklösungen
DE10001025A1 (de) 1999-05-18 2000-11-23 Bayer Ag Verfahren zur Herstellung von thermoplastischen Formmassen unter Verwendung von Kautschuklösungen
DE19922640A1 (de) 1999-05-18 2000-11-23 Bayer Ag Verfahren zur Herstellung von thermoplastischen Formmassen unter Verwendung von Kautschuklösungen
DE19926283A1 (de) 1999-06-09 2000-12-14 Basf Ag Verfahren zum Herstellen einer Lösung von Dienpolymerisaten in vinylaromatischen Verbindungen sowie zum Herstellen von schlagzähem Polystyrol durch Polymerisation dieser Lösung
DE19939842A1 (de) 1999-08-23 2001-03-01 Bayer Ag Verfahren zur Copolymerisation von konjugierten Diolefinen (Dienen) und vinylaromatischen Monomeren mit Katalysatoren der Seltenen Erden sowie die Verwendung der Copolymerisate in Kautschukmischungen für Reifenanwendungen
US6887824B1 (en) * 1999-09-21 2005-05-03 The Regents Of The University Of California Divalent lanthanide reduction catalysts
DE10022497A1 (de) 2000-05-09 2001-11-15 Bayer Ag Copolymerisation konjugierter Diene mit nichtkonjugierten Olefinen mittels Katalysatoren der Seltenen Erden
WO2002090394A1 (en) * 2001-05-04 2002-11-14 Dow Global Technologies Inc. Random or block co-or terpolymers produced by using of metal complex catalysts
DE10140202A1 (de) * 2001-08-16 2003-03-06 Bayer Ag Vanadium-Imido-Phosphoraniminato für die Olefinpolymerisation
US20050090383A1 (en) * 2001-10-12 2005-04-28 Thiele Sven K. Metal complex compositions and their use as catalysts to produce polydienes
EP1367069A1 (en) 2002-05-28 2003-12-03 Dow Global Technologies Inc. Process for homo-or copolymerization of conjugated diens
US6891006B2 (en) * 2002-06-21 2005-05-10 Exxonmobil Chemical Patents Inc. Yttrium-based ethylene polymerization catalysts with bulky amidinate ancillary ligands
ITBO20020694A1 (it) 2002-11-04 2004-05-05 Ica Spa Apparecchiatura per confezionare sacchetti
BRPI0407665A (pt) 2003-02-21 2006-03-01 Dow Global Technology Inc catalisador de complexo metálico apropriado para polimerização ou copolimerização de monÈmeros de adição etilenicamente insaturados

Also Published As

Publication number Publication date
JP2011093934A (ja) 2011-05-12
EP1597292A2 (en) 2005-11-23
US8153545B2 (en) 2012-04-10
US20060142145A1 (en) 2006-06-29
CA2516232C (en) 2013-05-14
US20100248947A1 (en) 2010-09-30
US20110160041A1 (en) 2011-06-30
JP5363515B2 (ja) 2013-12-11
WO2004076504A3 (en) 2005-01-27
CA2516232A1 (en) 2004-09-10
KR101126452B1 (ko) 2012-03-29
EP2267046B1 (en) 2013-08-07
KR101092349B1 (ko) 2011-12-09
AU2004215465A1 (en) 2004-09-10
US7915194B2 (en) 2011-03-29
ES2427626T3 (es) 2013-10-31
JP2006518742A (ja) 2006-08-17
EP2267046A1 (en) 2010-12-29
RU2348653C2 (ru) 2009-03-10
RU2005129337A (ru) 2006-03-20
CA2807874A1 (en) 2004-09-10
US7612009B2 (en) 2009-11-03
KR20110125676A (ko) 2011-11-21
WO2004076504A2 (en) 2004-09-10
KR20050103301A (ko) 2005-10-28
MXPA05008841A (es) 2005-10-18
BRPI0407665A (pt) 2006-03-01

Similar Documents

Publication Publication Date Title
JP5363515B2 (ja) 共役オレフィンのホモ重合又は共重合方法
RU2542992C2 (ru) Способ регулирования структуры цепи сополимера
US20050090383A1 (en) Metal complex compositions and their use as catalysts to produce polydienes
EP1367069A1 (en) Process for homo-or copolymerization of conjugated diens
KR20190060807A (ko) 사슬 왕복에 유용한 캡핑된 다중- 또는 이중-헤드형 조성물 및 이의 제조 방법
US20040241251A1 (en) Random or block co-or terpolymers produced by using of metal complex catalysts
KR20190077368A (ko) 체인 셔틀링에 유용한 다중 또는 이중 헤드 구성 요소 및 이를 준비하는 과정
WO2004044018A2 (en) Process for homo- or copolymerization of conjugated dienes and in situ formation of polymer blends and products made thereby
WO2004074333A2 (en) Process for homo- or copolymerizationof conjugated olefines
WO2003064484A1 (en) Metal complex compositions based on cobalt and their use as polymerization catalyst for olefins and dienes
JP2011127035A (ja) 共役ジエン重合体変性物及びその製造方法
WO2002090366A1 (en) Olefin polymerization catalysts containing a pyrrole bisimine ligand
AU2002340992A1 (en) Olefin polymerization catalysts containing a pyrrole bisimine ligand
JP4576126B2 (ja) アザボロリル４族金属錯体、触媒及びオレフィン重合方法
JP2004512341A (ja) 架橋イリド基を含む金属錯体
JP2022090555A (ja) 共重合体、ゴム組成物及び樹脂組成物
AU2002348526A1 (en) Metal complex compositions and their use as catalysts to produce polydienes
ZA200402408B (en) Metal complex compositions and their use as catalysts to produce polydienes.

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20070207

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20070207

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20101102

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110202

A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A711

Effective date: 20111212

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20111213

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20111212

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20120313

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20120417

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20120517

R150 Certificate of patent or registration of utility model

Ref document number: 5001000

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150525

Year of fee payment: 3

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

S533 Written request for registration of change of name

Free format text: JAPANESE INTERMEDIATE CODE: R313533

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees