JP4919578B2 - プロトン伝導性ポリマー膜およびその使用 - Google Patents

プロトン伝導性ポリマー膜およびその使用 Download PDF

Info

Publication number
JP4919578B2
JP4919578B2 JP2002579927A JP2002579927A JP4919578B2 JP 4919578 B2 JP4919578 B2 JP 4919578B2 JP 2002579927 A JP2002579927 A JP 2002579927A JP 2002579927 A JP2002579927 A JP 2002579927A JP 4919578 B2 JP4919578 B2 JP 4919578B2
Authority
JP
Japan
Prior art keywords
acid
membrane
aromatic
heteroaromatic
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2002579927A
Other languages
English (en)
Japanese (ja)
Other versions
JP2005536569A5 (enExample
JP2005536569A (ja
Inventor
ゴードン カルンダン
マイケル ジェイ サンソン
オメエル ウエンサル
ジョアキム キエフェル
Original Assignee
ベーアーエスエフ フューエル セル ゲーエムベーハー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ベーアーエスエフ フューエル セル ゲーエムベーハー filed Critical ベーアーエスエフ フューエル セル ゲーエムベーハー
Publication of JP2005536569A publication Critical patent/JP2005536569A/ja
Publication of JP2005536569A5 publication Critical patent/JP2005536569A5/ja
Application granted granted Critical
Publication of JP4919578B2 publication Critical patent/JP4919578B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/0605—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
    • C08G73/0616—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
    • C08G73/0633—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only two nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
    • C08G73/0638—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with at least three nitrogen atoms in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/0683—Polycondensates containing six-membered rings, condensed with other rings, with nitrogen atoms as the only ring hetero atoms
    • C08G73/0688—Polycondensates containing six-membered rings, condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only one nitrogen atom in the ring, e.g. polyquinolines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/18—Polybenzimidazoles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086—After-treatment of the membrane other than by polymerisation
    • H01M8/109—After-treatment of the membrane other than by polymerisation thermal other than drying, e.g. sintering
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Conductive Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Fuel Cell (AREA)
  • Silicon Polymers (AREA)
JP2002579927A 2001-04-09 2002-04-09 プロトン伝導性ポリマー膜およびその使用 Expired - Fee Related JP4919578B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10117687A DE10117687A1 (de) 2001-04-09 2001-04-09 Protonenleitende Membran und deren Verwendung
DE10117687.2 2001-04-09
PCT/EP2002/003901 WO2002081547A1 (de) 2001-04-09 2002-04-09 Protonenleitende membran und deren verwendung

Publications (3)

Publication Number Publication Date
JP2005536569A JP2005536569A (ja) 2005-12-02
JP2005536569A5 JP2005536569A5 (enExample) 2011-12-15
JP4919578B2 true JP4919578B2 (ja) 2012-04-18

Family

ID=7680969

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2002579927A Expired - Fee Related JP4919578B2 (ja) 2001-04-09 2002-04-09 プロトン伝導性ポリマー膜およびその使用

Country Status (12)

Country Link
US (1) US7235320B2 (enExample)
EP (2) EP2270068B1 (enExample)
JP (1) JP4919578B2 (enExample)
KR (1) KR100897728B1 (enExample)
CN (1) CN100489011C (enExample)
AT (1) ATE493459T1 (enExample)
BR (1) BR0208728A (enExample)
CA (1) CA2443849C (enExample)
DE (2) DE10117687A1 (enExample)
DK (1) DK1379572T3 (enExample)
MX (1) MXPA03009187A (enExample)
WO (1) WO2002081547A1 (enExample)

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10117686A1 (de) * 2001-04-09 2002-10-24 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
DE10129458A1 (de) * 2001-06-19 2003-01-02 Celanese Ventures Gmbh Verbesserte Polymerfolien auf Basis von Polyazolen
KR100407793B1 (ko) * 2001-09-04 2003-12-01 한국과학기술연구원 분리능이 있는 수소 이온 교환 복합막, 복합 용액, 그제조방법 및 이를 포함하는 연료전지
DE10209419A1 (de) * 2002-03-05 2003-09-25 Celanese Ventures Gmbh Verfahren zur Herstellung einer Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
US20050118478A1 (en) * 2002-03-06 2005-06-02 Joachim Kiefer Mixture comprising sulphonic acid containing vinyl, polymer electrolyte membrane comprising polyvinylsulphonic acid and the use thereof in fuel cells
DE50308216D1 (de) 2002-03-06 2007-10-31 Pemeas Gmbh Protonenleitende elektrolytmembran mit geringer methanoldurchlässigkeit und deren anwendung in brennstoffzellen
DE10213540A1 (de) * 2002-03-06 2004-02-19 Celanese Ventures Gmbh Lösung aus Vinylphosphonsäure, Verfahren zur Herstellung einer Polymerelektrolytmembran aus Polyvinylphosphaonsäure und deren Anwendung in Brennstoffzellen
JP4638220B2 (ja) * 2002-04-25 2011-02-23 ビーエーエスエフ フューエル セル ゲゼルシャフト ミット ベシュレンクテル ハフツング 多層電解質膜
DE10228657A1 (de) 2002-06-27 2004-01-15 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
DE10230477A1 (de) 2002-07-06 2004-01-15 Celanese Ventures Gmbh Funktionalisierte Polyazole, Verfahren zu ihrer Herstellung sowie ihre Verwendung
ATE314735T1 (de) 2002-08-02 2006-01-15 Protonenleitende polymembran, welche sulfonsäuregruppen enthaltende polymere umfasst, und deren anwendung in brennstoffzellen
DE10235360A1 (de) 2002-08-02 2004-02-19 Celanese Ventures Gmbh Membran-Elektrodeneinheiten mit langer Lebensdauer
DE10235358A1 (de) * 2002-08-02 2004-02-12 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Phosphonsäuregruppen enthaltende Polymere und deren Anwendung in Brennstoffzellen
JP2005537384A (ja) 2002-08-29 2005-12-08 ペメアス ゲーエムベーハー プロトン伝導性ポリマー膜の製造方法、改良されたポリマー膜、および燃料電池におけるその使用
DE10239701A1 (de) * 2002-08-29 2004-03-11 Celanese Ventures Gmbh Polymerfolie auf Basis von Polyazolen und deren Verwendung
DE10242708A1 (de) 2002-09-13 2004-05-19 Celanese Ventures Gmbh Protonenleitende Membranen und deren Verwendung
DE10246459A1 (de) 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Phosphonsäuregruppen enthaltende Polyazole und deren Anwendung in Brennstoffzellen
DE10246461A1 (de) * 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran enthaltend Polyazolblends und deren Anwendung in Brennstoffzellen
DE10246373A1 (de) 2002-10-04 2004-04-15 Celanese Ventures Gmbh Protonenleitende Polymermembran umfassend Sulfonsäuregruppen enthaltende Polyazole und deren Anwendung in Brennstoffzellen
DE10246372A1 (de) * 2002-10-04 2004-04-15 Celanese Ventures Gmbh Mit einer Katalysatorschicht beschichtete protonenleitende Polymermembran enthaltend Polyazole und deren Anwendung in Brennstoffzellen
DE10301810A1 (de) 2003-01-20 2004-07-29 Sartorius Ag Membran-Elektroden-Einheit, Polymermembranen für eine Membran-Elektroden-Einheit und Polymerelektrolyt-Brennstoffzellen sowie Verfahren zur Herstellung derselben
ES2217957B1 (es) * 2003-01-31 2006-03-01 Consejo Sup. Investig. Cientificas Membranas conductoras protonicas basadas en polimeros de tipo polibencimidazol y materiales hibridos y nanocompuestos derivados de los mismos.
EP1652259A2 (de) 2003-07-27 2006-05-03 Pemeas GmbH Protonenleitende membran und deren verwendung
JP4979179B2 (ja) * 2003-08-22 2012-07-18 株式会社豊田中央研究所 固体高分子型燃料電池およびその製造方法
DE10361833A1 (de) * 2003-12-30 2005-08-04 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
DE10361932A1 (de) 2003-12-30 2005-07-28 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
DE10361832A1 (de) 2003-12-30 2005-07-28 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung
DE102004008628A1 (de) 2004-02-21 2005-09-08 Celanese Ventures Gmbh Membran-Elektroden-Einheit mit hoher Leistung und deren Anwendung in Brennstoffzellen
CN1997690A (zh) 2004-05-14 2007-07-11 佩密斯股份有限公司 各向异性成型体及其生产方法和用途
US7259230B2 (en) * 2004-06-07 2007-08-21 Battelle Energy Alliance, Llc Polybenzimidazole compounds, polymeric media, and methods of post-polymerization modifications
US7309758B2 (en) 2004-06-07 2007-12-18 Battelle Energy Alliance, Llc Polybenzimidazole compounds, polymeric media, and methods of post-polymerization modifications
DE102004034139A1 (de) 2004-07-15 2006-02-02 Pemeas Gmbh Verfahren zur Herstellung von Membran-Elektroden-Einheiten
DE102004035309A1 (de) 2004-07-21 2006-02-16 Pemeas Gmbh Membran-Elektrodeneinheiten und Brennstoffzellen mit erhöhter Lebensdauer
EP1788654B1 (en) * 2004-09-09 2011-11-16 Asahi Kasei Chemicals Corporation Solid polymer electrolyte membrane and method for producing same
FR2876222A1 (fr) * 2004-10-06 2006-04-07 Renault Sas Pile a combustible a membrane non-fluoree ou partiellement fluoree et procede de preparation de ladite membrane
US7736782B2 (en) * 2004-10-20 2010-06-15 Samsung Sdi Co., Ltd. Proton conductive solid polymer electrolyte and fuel cell
KR100647307B1 (ko) * 2004-12-23 2006-11-23 삼성에스디아이 주식회사 양성자 전도체와 이를 이용한 전기화학장치
DE102005020604A1 (de) * 2005-05-03 2006-11-16 Pemeas Gmbh Brennstoffzellen mit geringerem Gewicht und Volumen
KR100819676B1 (ko) 2005-11-14 2008-04-03 주식회사 엘지화학 브랜치된 멀티블록 폴리벤즈이미다졸-벤즈아마이드공중합체 및 제조방법, 이를 이용한 전해질막 및 전해질페이스트/겔
DE102005058578A1 (de) * 2005-12-08 2007-06-28 Sartorius Ag Membranen aus Polyazolen, Verfahren zu ihrer Herstellung und Brennstoffzellen unter Verwendung derartiger Membranen
DE102006040749A1 (de) * 2006-08-31 2008-03-06 Daimler Ag Oxidationsstabilisierte Polymer-Elektrolyt-Membranen für Brennstoffzellen
RU2364439C1 (ru) * 2008-01-10 2009-08-20 ООО "Объединенный центр исследований и разработок" Полимерная композиция для изготовления протонпроводящих мембран
RU2382672C2 (ru) * 2008-01-25 2010-02-27 Общество с ограниченной ответственностью "Национальная инновационная компания "Новые энергетические проекты" (ООО "Национальная инновационная компания "НЭП") Протонпроводящая мембрана
US8299202B2 (en) * 2008-01-30 2012-10-30 Doetze Jakob Sikkema Phenol compounds and (co)polymers thereof
EP2247651A1 (en) * 2008-02-27 2010-11-10 SOLVAY (Société Anonyme) Polymer composition, polymer membrane comprising the polymer composition, process for preparing it and fuel cell comprising the membrane
DE102009001137A1 (de) 2008-10-29 2010-05-06 Volkswagen Ag Polymerelektrolytmembran für Brennstoffzellen und Verfahren zu ihrer Herstellung
DE102009001141A1 (de) 2008-10-29 2010-05-06 Volkswagen Ag Verfahren zur Herstellung einer Polymerelektrolytmembran
WO2010063489A1 (de) * 2008-12-06 2010-06-10 Basf Se Verfahren zur herstellung einer protonenleitenden membran
KR101144398B1 (ko) * 2009-01-15 2012-05-10 서울대학교산학협력단 염기성 치환기를 갖는 폴리벤즈이미다졸계 고분자 및 이를 포함하는 전해질막
EP2228857A1 (de) 2009-03-06 2010-09-15 Basf Se Verbesserte Membran-Elektrodeneinheiten
DE102009028758A1 (de) 2009-08-20 2011-02-24 Volkswagen Ag Langzeitstabile Polymerelektrolytmembran für HT-Brennstoffzellen und Verfahren zu ihrer Herstellung
KR101317510B1 (ko) * 2009-09-15 2013-10-15 서울대학교산학협력단 하이드라지늄 설페이트가 분산된 폴리벤즈이미다졸계 복합막 및 이를 사용하는 연료전지용 전해질막
US9048478B2 (en) 2010-04-22 2015-06-02 Basf Se Polymer electrolyte membrane based on polyazole
US8673183B2 (en) 2010-07-06 2014-03-18 National Research Council Of Canada Tetrazine monomers and copolymers for use in organic electronic devices
JP5279771B2 (ja) * 2010-08-06 2013-09-04 ベーアーエスエフ フューエル セル ゲーエムベーハー プロトン伝導性ポリマー膜
CN102206342B (zh) * 2011-03-31 2012-10-17 南京大学 导电聚合物及其合成方法、表面覆盖有所述导电聚合物的电活性电极
US8758955B2 (en) * 2011-04-07 2014-06-24 Daimler Ag Additives to mitigate catalyst layer degradation in fuel cells
DE102012007178A1 (de) 2011-04-14 2012-10-18 Basf Se Verbesserte Membran-Elektrodeneinheiten und Brennstoffzellen mit langer Lebensdauer
US9325025B2 (en) 2011-04-14 2016-04-26 Basf Se Membrane electrode assemblies and fuel cells with long lifetime
CN102775606A (zh) * 2011-05-12 2012-11-14 北京化工大学 一种聚苯并咪唑树脂的制备
US9812725B2 (en) 2012-01-17 2017-11-07 Basf Se Proton-conducting membrane and use thereof
US20130183603A1 (en) 2012-01-17 2013-07-18 Basf Se Proton-conducting membrane, method for their production and their use in electrochemical cells
CN102623734B (zh) * 2012-04-16 2014-10-15 上海锦众信息科技有限公司 一种燃料电池用高性能复合质子交换膜的制备方法
CN102643426A (zh) * 2012-05-11 2012-08-22 北京化工大学 一种新型聚苯并咪唑树脂的制备
DE102014000630A1 (de) * 2013-08-02 2015-02-26 Forschungszentrum Jülich GmbH Materialprüfung von Membranen für Polymerelektrolytbrennstoffzellen
DK2869382T3 (en) 2013-10-30 2019-04-01 Basf Se Improved diaphragm electrode devices
DE102016008597A1 (de) * 2015-07-24 2017-01-26 Daimler Ag Protonenleitfähiger Verbund-Elektrolyt mit verbesserten Additiven für Brennstoffzellen
EP3945104A1 (en) * 2020-07-27 2022-02-02 Andreas Stihl AG & Co. KG A polymer and a product or article comprising or consisting of the polymer

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1000525A (en) * 1962-07-20 1965-08-04 Teijin Ltd Process for preparation of polybenzimidazoles
US4191618A (en) 1977-12-23 1980-03-04 General Electric Company Production of halogens in an electrolysis cell with catalytic electrodes bonded to an ion transporting membrane and an oxygen depolarized cathode
US4212714A (en) 1979-05-14 1980-07-15 General Electric Company Electrolysis of alkali metal halides in a three compartment cell with self-pressurized buffer compartment
US4333805A (en) 1980-05-02 1982-06-08 General Electric Company Halogen evolution with improved anode catalyst
US5525436A (en) * 1994-11-01 1996-06-11 Case Western Reserve University Proton conducting polymers used as membranes
JP2000273214A (ja) * 1999-03-29 2000-10-03 Toray Ind Inc ポリベンザゾールフィルム及びそれを用いた磁気記録媒体
JP3925764B2 (ja) 1999-10-19 2007-06-06 株式会社豊田中央研究所 高耐久性固体高分子電解質
DE10109829A1 (de) 2001-03-01 2002-09-05 Celanese Ventures Gmbh Polymermembran, Verfahren zu deren Herstellung sowie deren Verwendung
DE10117686A1 (de) 2001-04-09 2002-10-24 Celanese Ventures Gmbh Protonenleitende Membran und deren Verwendung

Also Published As

Publication number Publication date
US20040127588A1 (en) 2004-07-01
CN100489011C (zh) 2009-05-20
US7235320B2 (en) 2007-06-26
CA2443849A1 (en) 2002-10-17
EP1379572B1 (de) 2010-12-29
EP2270068B1 (de) 2012-08-22
EP1379572A1 (de) 2004-01-14
EP2270068A1 (de) 2011-01-05
KR100897728B1 (ko) 2009-05-15
CN1511170A (zh) 2004-07-07
WO2002081547A1 (de) 2002-10-17
BR0208728A (pt) 2004-07-20
DE50214833D1 (de) 2011-02-10
DK1379572T3 (da) 2011-04-04
KR20040011496A (ko) 2004-02-05
CA2443849C (en) 2008-07-29
JP2005536569A (ja) 2005-12-02
DE10117687A1 (de) 2002-10-17
MXPA03009187A (es) 2004-02-17
ATE493459T1 (de) 2011-01-15

Similar Documents

Publication Publication Date Title
JP4919578B2 (ja) プロトン伝導性ポリマー膜およびその使用
JP4663215B2 (ja) プロトン伝導性ポリマー膜
JP5468051B2 (ja) プロトン伝導性膜およびその使用
US8277983B2 (en) Proton-conducting membrane and its use
JP4537199B2 (ja) プロトン伝導性膜およびその使用
EP2804889B1 (en) Proton-conducting membrane, method for their production and their use in electrochemical cells
US9812725B2 (en) Proton-conducting membrane and use thereof
US8846133B2 (en) Method for producing a proton-conducting membrane
JP5279771B2 (ja) プロトン伝導性ポリマー膜

Legal Events

Date Code Title Description
A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A711

Effective date: 20050916

RD03 Notification of appointment of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7423

Effective date: 20050916

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20070222

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20070228

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20070328

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20070419

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20070822

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20080319

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20080819

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20111026

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20111026

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20111028

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20120131

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150210

Year of fee payment: 3

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees