JP4860971B2 - 有機ケイ素化合物を基礎とする架橋可能なコンパウンド - Google Patents
有機ケイ素化合物を基礎とする架橋可能なコンパウンド Download PDFInfo
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- JP4860971B2 JP4860971B2 JP2005276114A JP2005276114A JP4860971B2 JP 4860971 B2 JP4860971 B2 JP 4860971B2 JP 2005276114 A JP2005276114 A JP 2005276114A JP 2005276114 A JP2005276114 A JP 2005276114A JP 4860971 B2 JP4860971 B2 JP 4860971B2
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- 150000001875 compounds Chemical class 0.000 title claims description 70
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
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- HTDJPCNNEPUOOQ-UHFFFAOYSA-N hexamethylcyclotrisiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 HTDJPCNNEPUOOQ-UHFFFAOYSA-N 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
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- JJPWJEGNCRGGGA-UHFFFAOYSA-N 4-[[2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]acetyl]amino]benzoic acid Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)NC1=CC=C(C(=O)O)C=C1 JJPWJEGNCRGGGA-UHFFFAOYSA-N 0.000 description 1
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- CQQXCSFSYHAZOO-UHFFFAOYSA-L [acetyloxy(dioctyl)stannyl] acetate Chemical compound CCCCCCCC[Sn](OC(C)=O)(OC(C)=O)CCCCCCCC CQQXCSFSYHAZOO-UHFFFAOYSA-L 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 1
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- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- ZUEKXCXHTXJYAR-UHFFFAOYSA-N tetrapropan-2-yl silicate Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)OC(C)C ZUEKXCXHTXJYAR-UHFFFAOYSA-N 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Description
(HO)aRbSiO(4−a−b)/2 (I)
[式中、
Rは同一又は異なってよく、かつ置換又は非置換の一価の炭化水素基を意味し、前記基はヘテロ原子によって中断されていてよく、
aは0又は1であり、かつ
bは0、1、2又は3であるが、但し、
該有機ケイ素化合物はa=1の式(I)の単位を1つ有し、かつ25℃で5〜1000mPa・sの粘度を有する]の単位からの有機ケイ素化合物を使用して製造できる架橋可能なコンパウンドである。
OH(R2SiO)nSiR3 (II)
[式中、
Rは前記の意味を有し、nについての平均値は、式(II)の化合物が25℃で測定して5〜1000mPa・sの粘度を有するように選択される]のジオルガノポリシロキサンである。
(A)少なくとも2個のヒドロキシル基又は少なくとも2個の加水分解可能な基を有する有機ケイ素化合物、
(B)式(I)の単位からの有機ケイ素化合物、及び
(C)架橋剤
の使用下に製造可能なコンパウンドである。
Y3−cR1 cSiO−[R1 2SiO]d−SiR1 cY3−c (III)
[式中、
cは0、1又は2であり、
R1は同一又は異なってよく、かつRについて示した意味を有し、
Yは同一又は異なってよく、かつヒドロキシル基又は加水分解可能な基を意味し、かつ
dは200〜10000の整数、有利には300〜3000の整数、特に有利には400〜2000の整数である]の有機ケイ素化合物である。
(MeCOO)2MeSiO[SiMe2O]200−2000SiMe(OOCMe)2、
(OH)Me2SiO[SiMe2O]200−2000SiMe2(OH)、
(MeCOO)2EtSiO[SiMe2O]200−2000SiEt(OOCMe)2、及び
(MeCOO)2ViSiO[SiMe2O]200−2000SiVi(OOCMe)2
であり、その際、Meはメチル基を意味し、Etはエチル基を意味し、かつViはビニル基を意味する。
Teilcohydrolysate)、すなわち少なくとも2種の異なる種類の有機ケイ素化合物の部分加水分解物でもよい。
(A)式(III)の有機ケイ素化合物、
(B)式(I)の単位からの有機ケイ素化合物、場合により
(C)架橋剤、場合により
(D)触媒、場合により
(E)可塑剤、場合により
(F)充填剤、場合により
(G)定着剤、及び場合により
(H)添加剤
を使用して製造できるコンパウンドである。
粘度80000mPa・sを有するα,ω−ジヒドロキシポリジメチルシロキサン1400g、粘度100mPa・sを有するトリメチルシリル末端封鎖されたポリジメチルシロキサン707g、100mPa・sのα−ヒドロキシ,ω−トリメチルシリル−ポリジメチルシロキサン17gを遊星型ミキサ中でエチルトリアセトキシシラン76g及びメチルトリアセトキシシラン33gと5分間混合した。引き続き比表面積150m2/gを有する熱分解法ケイ酸(商標名HDK(R)V15としてWacker−Chemie GmbH社(D−ミュンヘン在)で購入できる)182gを導入した。真空中で20分間均質化した後に、ジブチルスズジアセテート0.24gを真空下に混入した。製造された生成物を湿気密な市販のPE製カートリッジに詰め替えた。
実施例1に記載した方法を繰り返すが、α−ヒドロキシ,ω−トリメチルシリル−ポリジメチルシロキサン17g及びトリメチルシリル末端封鎖されたポリジメチルシロキサン706gの代わりに、ここではα−ヒドロキシ,ω−トリメチルシリル−ポリジメチルシロキサン28g及びトリメチルシリル末端封鎖されたポリジメチルシロキサン696gを使用した。
実施例1に記載した方法を繰り返すが、α−ヒドロキシ,ω−トリメチルシリル−ポリジメチルシロキサン17g及びトリメチルシリル末端封鎖されたポリジメチルシロキサン706gの代わりに、ここではα−ヒドロキシ,ω−トリメチルシリル−ポリジメチルシロキサン39g及びトリメチルシリル末端封鎖されたポリジメチルシロキサン685gを使用した。
実施例1に記載した方法を繰り返すが、α−ヒドロキシ,ω−トリメチルシリル−ポリジメチルシロキサン17g及びトリメチルシリル末端封鎖されたポリジメチルシロキサン706gの代わりに、ここではα−ヒドロキシ,ω−トリメチルシリル−ポリジメチルシロキサン51g及びトリメチルシリル末端封鎖されたポリジメチルシロキサン673gを使用した。
実施例1に記載した方法を繰り返すが、α−ヒドロキシ,ω−トリメチルシリル−ポリジメチルシロキサン17g及びトリメチルシリル末端封鎖されたポリジメチルシロキサン706gの代わりに、ここではα−ヒドロキシ,ω−トリメチルシリル−ポリジメチルシロキサン62g及びトリメチルシリル末端封鎖されたポリジメチルシロキサン662gを使用した。
粘度100mPa・sを有するα−ヒドロキシ,ω−トリメチルシリル−ポリジメチルシロキサン17gを研究室用溶解機中でエチルトリアセトキシシラン26g及びメチルトリアセトキシシラン13gと5分間混合し、その際、Si−OH基と架橋剤分子との可逆的な末端封鎖反応によって酢酸が遊離する(前混合物)。
Claims (2)
- 以下の
(A)少なくとも2個のヒドロキシル基又は少なくとも2個の加水分解可能な基を有する、一般式
Y3−cR1 cSiO−[R1 2SiO]d−SiR1 cY3−c (III)
[式中、
cは0、1又は2であり、
R1は同一又は異なってよく、かつ置換又は非置換の一価の炭化水素基を意味し、前記基はヘテロ原子によって中断されていてよく、
Yは同一又は異なってよく、かつヒドロキシル基又は加水分解可能な基を意味し、かつ
dは200〜10000の整数である]の有機ケイ素化合物、
(B)式
OH(R2SiO)nSiR3 (II)
[式中、
Rはメチル基を意味し、nについての平均値は、式(II)の化合物が25℃で測定して10〜500mm2/秒の粘度を有するように選択される]の実質的に直鎖状のジオルガノシロキサン、及び
(C)6個までのケイ素原子を有する架橋剤、
(D)触媒、
(E)可塑剤、
(F)充填剤、
(G)グリシドキシプロピル基、アミノプロピル基又はメタクリルオキシプロピル基を有するシラン及びオルガノポリシロキサン並びにテトラアルコキシシランからなる群から選択される定着剤及び
(H)顔料、着色剤、香料、酸化防止剤、導電性カーボンブラック、難燃剤、光保護剤、SiC結合したメルカプトアルキル基を有するシラン、発泡剤、熱安定剤及びチキソトロピー剤及び有機溶剤からなる群から選択される添加剤
からなり[但し、架橋剤(C)は、グリシドキシプロピル基、アミノプロピル基又はメタクリルオキシプロピル基を有するシラン及びSiC結合したメルカプトアルキル基を有するシラン並びにテトラアルコキシシランからなる群から選択されるものではない]、使用される式(II)の単位から構成される有機ケイ素化合物(B)が、25℃で10〜500mm2/秒の粘度を有し、かつ式(II)の単位から構成される有機ケイ素化合物(B)を、架橋可能なコンパウンド100質量部に対して、0.1〜15質量部の量で含有し、触媒(D)を、有機ケイ素化合物(A)100質量部に対して、0〜3質量部の量で含有し、可塑剤(E)を、有機ケイ素化合物(A)100質量部に対して、0〜300質量部の量で含有し、充填剤(F)を、有機ケイ素化合物(A)100質量部に対して、0〜300質量部の量で含有し、定着剤(G)を、有機ケイ素化合物(A)100質量部に対して、0〜50質量部の量で含有し、かつ添加剤(H)を、有機ケイ素化合物(A)100質量部に対して、0〜100質量部の量で含有する架橋可能なコンパウンド。 - 請求項1記載のコンパウンドの架橋によって製造される成形体。
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JP2005162974A (ja) | 2003-12-05 | 2005-06-23 | Ge Toshiba Silicones Co Ltd | 室温硬化性オルガノポリシロキサン組成物 |
JP5247969B2 (ja) * | 2003-12-25 | 2013-07-24 | 東レ・ダウコーニング株式会社 | 木用接着剤、該接着剤を用いる接着方法、並びに、該接着剤を用いた複合体 |
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2004
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- 2005-09-14 DE DE200550000926 patent/DE502005000926D1/de active Active
- 2005-09-14 EP EP20050020006 patent/EP1640416B1/de active Active
- 2005-09-22 JP JP2005276114A patent/JP4860971B2/ja active Active
- 2005-09-23 CN CNB2005101069109A patent/CN100378175C/zh active Active
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DE102004046179A1 (de) | 2006-03-30 |
CN100378175C (zh) | 2008-04-02 |
JP2006089746A (ja) | 2006-04-06 |
EP1640416B1 (de) | 2007-06-27 |
US7820770B2 (en) | 2010-10-26 |
US20060063895A1 (en) | 2006-03-23 |
CN1752146A (zh) | 2006-03-29 |
DE502005000926D1 (de) | 2007-08-09 |
EP1640416A1 (de) | 2006-03-29 |
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