JP4857309B2 - 硬質表面を処理するための両性重合体の使用法 - Google Patents
硬質表面を処理するための両性重合体の使用法 Download PDFInfo
- Publication number
- JP4857309B2 JP4857309B2 JP2008155651A JP2008155651A JP4857309B2 JP 4857309 B2 JP4857309 B2 JP 4857309B2 JP 2008155651 A JP2008155651 A JP 2008155651A JP 2008155651 A JP2008155651 A JP 2008155651A JP 4857309 B2 JP4857309 B2 JP 4857309B2
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- Prior art keywords
- acid
- water
- weight
- cleaning composition
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229920000642 polymer Polymers 0.000 title claims description 31
- 229920001577 copolymer Polymers 0.000 claims abstract description 52
- 239000000178 monomer Substances 0.000 claims abstract description 50
- 150000001875 compounds Chemical class 0.000 claims abstract description 16
- 230000002378 acidificating effect Effects 0.000 claims abstract description 8
- 230000007935 neutral effect Effects 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 148
- 238000004140 cleaning Methods 0.000 claims description 58
- 239000003599 detergent Substances 0.000 claims description 43
- -1 brighteners Substances 0.000 claims description 42
- 239000004094 surface-active agent Substances 0.000 claims description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 17
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 239000004615 ingredient Substances 0.000 claims description 7
- 230000005923 long-lasting effect Effects 0.000 claims description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 7
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
- 102000004190 Enzymes Human genes 0.000 claims description 5
- 108090000790 Enzymes Proteins 0.000 claims description 5
- 150000007513 acids Chemical class 0.000 claims description 5
- 239000002671 adjuvant Substances 0.000 claims description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 5
- 239000003205 fragrance Substances 0.000 claims description 5
- 239000003752 hydrotrope Substances 0.000 claims description 5
- PRAMZQXXPOLCIY-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethanesulfonic acid Chemical compound CC(=C)C(=O)OCCS(O)(=O)=O PRAMZQXXPOLCIY-UHFFFAOYSA-N 0.000 claims description 4
- GQTFHSAAODFMHB-UHFFFAOYSA-N 2-prop-2-enoyloxyethanesulfonic acid Chemical compound OS(=O)(=O)CCOC(=O)C=C GQTFHSAAODFMHB-UHFFFAOYSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 239000007844 bleaching agent Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- 239000011976 maleic acid Substances 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 239000002689 soil Substances 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- KFNGWPXYNSJXOP-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)OCCCS(O)(=O)=O KFNGWPXYNSJXOP-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 3
- 230000000844 anti-bacterial effect Effects 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000001530 fumaric acid Substances 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- FQOWJGGXNSRNJS-YFKPBYRVSA-N (2s)-2-(2-methylprop-2-enoylamino)propanoic acid Chemical compound OC(=O)[C@H](C)NC(=O)C(C)=C FQOWJGGXNSRNJS-YFKPBYRVSA-N 0.000 claims description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- STVDIZSDTABYLF-UHFFFAOYSA-N 2-[hydroxy(prop-2-enoyl)amino]acetic acid Chemical compound OC(=O)CN(O)C(=O)C=C STVDIZSDTABYLF-UHFFFAOYSA-N 0.000 claims description 2
- PSZAEHPBBUYICS-UHFFFAOYSA-N 2-methylidenepropanedioic acid Chemical compound OC(=O)C(=C)C(O)=O PSZAEHPBBUYICS-UHFFFAOYSA-N 0.000 claims description 2
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 claims description 2
- YYPNJNDODFVZLE-UHFFFAOYSA-N 3-methylbut-2-enoic acid Chemical compound CC(C)=CC(O)=O YYPNJNDODFVZLE-UHFFFAOYSA-N 0.000 claims description 2
- NYUTUWAFOUJLKI-UHFFFAOYSA-N 3-prop-2-enoyloxypropane-1-sulfonic acid Chemical compound OS(=O)(=O)CCCOC(=O)C=C NYUTUWAFOUJLKI-UHFFFAOYSA-N 0.000 claims description 2
- WNYWRRLHDUIGOL-UHFFFAOYSA-N 3-prop-2-enoyloxypropylphosphonic acid Chemical compound OP(O)(=O)CCCOC(=O)C=C WNYWRRLHDUIGOL-UHFFFAOYSA-N 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
- IYXICJAHDDVGRX-UHFFFAOYSA-N C(C=C)(=O)OCCCP(=O)=O Chemical compound C(C=C)(=O)OCCCP(=O)=O IYXICJAHDDVGRX-UHFFFAOYSA-N 0.000 claims description 2
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 claims description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 125000004103 aminoalkyl group Chemical group 0.000 claims description 2
- 239000003899 bactericide agent Substances 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 claims description 2
- 229940018557 citraconic acid Drugs 0.000 claims description 2
- 239000000417 fungicide Substances 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims description 2
- 239000000077 insect repellent Substances 0.000 claims description 2
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 claims description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 claims description 2
- 239000003605 opacifier Substances 0.000 claims description 2
- 239000011049 pearl Substances 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- 239000000375 suspending agent Substances 0.000 claims description 2
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims 2
- YIYBQIKDCADOSF-UHFFFAOYSA-N alpha-Butylen-alpha-carbonsaeure Natural products CCC=CC(O)=O YIYBQIKDCADOSF-UHFFFAOYSA-N 0.000 claims 2
- 230000003373 anti-fouling effect Effects 0.000 claims 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims 1
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical compound OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims 1
- 230000007423 decrease Effects 0.000 claims 1
- 239000011888 foil Substances 0.000 claims 1
- HVAMZGADVCBITI-UHFFFAOYSA-N pent-4-enoic acid Chemical compound OC(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-N 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 230000002265 prevention Effects 0.000 claims 1
- 238000009472 formulation Methods 0.000 description 28
- 239000011521 glass Substances 0.000 description 20
- 238000005406 washing Methods 0.000 description 20
- 235000014113 dietary fatty acids Nutrition 0.000 description 16
- 239000000194 fatty acid Substances 0.000 description 16
- 229930195729 fatty acid Natural products 0.000 description 16
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- 239000002736 nonionic surfactant Substances 0.000 description 14
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 13
- 239000007787 solid Substances 0.000 description 13
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 239000000919 ceramic Substances 0.000 description 11
- 150000004665 fatty acids Chemical class 0.000 description 11
- 239000000654 additive Substances 0.000 description 10
- 239000003945 anionic surfactant Substances 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 9
- 239000003999 initiator Substances 0.000 description 8
- 150000001340 alkali metals Chemical class 0.000 description 7
- 125000000129 anionic group Chemical group 0.000 description 7
- 239000000344 soap Substances 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 239000002280 amphoteric surfactant Substances 0.000 description 6
- 125000002091 cationic group Chemical group 0.000 description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 244000303965 Cyamopsis psoralioides Species 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 5
- 229920006317 cationic polymer Polymers 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
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- 239000006260 foam Substances 0.000 description 5
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- 235000011007 phosphoric acid Nutrition 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
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- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
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- 150000008051 alkyl sulfates Chemical class 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 239000003093 cationic surfactant Substances 0.000 description 4
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- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
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- 150000001298 alcohols Chemical class 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
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- 230000000052 comparative effect Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
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- 239000003906 humectant Substances 0.000 description 3
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- 238000005259 measurement Methods 0.000 description 3
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
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- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
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- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 241000282372 Panthera onca Species 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
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- 239000004480 active ingredient Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
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- 238000010189 synthetic method Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical group C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- 239000008170 walnut oil Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3796—Amphoteric polymers or zwitterionic polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/24—Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Detergent Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Chemically Coating (AREA)
- Paints Or Removers (AREA)
- Paper (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Description
・陽イオン性単量体、特にジメチルジアリルアンモニウムクロリド(ジアリルジメチルアンモニウムクロリドに対しては、DADMAC)、
・陰イオン性単量体、特にアクリル酸、
・非イオン性単量体、特にアクリルアミド、
を含む両性三元重合体について記載している。
(a)一般式I:
・R1及びR4は互いに独立して、水素原子又は線状若しくは分岐状C1〜C6アルキル基を表わし、
・R2及びR3は互いに独立して、アルキル、ヒドロキシアルキル又はアミノアルキル基(ここで、アルキル基は線状又は分岐状C1〜C6鎖、好ましくはメチル基を表わす)を表わし、
・n及びmは1〜3の整数であり、
・Xは同種又は異種であってよく、そして重合体の水溶性又は水分散性と相容性である対イオンを表わす]の少なくとも1種の単量体化合物、
(b)(a)と共重合可能であり且つ適用媒体中においてイオン化することができる酸性の機能を有する少なくとも1種の親水性単量体、
(c)エチレン性不飽和を含有し、中性電荷を有し、1個又はそれ以上の親水性基を有し、且つ(a)及び(b)と共重合可能な、随意成分としての少なくとも1種の親水性単量体化合物、
を含み、しかも(a)/(b)モル比が60/40〜5/95であることからなる水溶性又は水分散性共重合体を使用することよりなる。
・R1は水素を表わし、
・R2はメチルを表わし、
・R3はメチルを表わし、
・R4は水素を表わし、そして
・m及びnは1である。
・DADMAC/アクリル酸/アクリルアミド共重合体、
・DADMAC/マレイン酸共重合体、
・DADMAC/スルホン酸共重合体、
が特に最も好ましく、そしてDADMAC/酸性単量体モル比は60/40〜5/95好ましくは50/50〜10/90である。
・式:R−CH(SO3M)−COOR’[式中、Rは、C8〜C20好ましくはC10〜C16アルキル基を表わし、R’はC1〜C6好ましくはC1〜C3アルキル基を表わし、そしてMはアルカリ金属(ナトリウム、カリウム又はリチウム)陽イオン、置換又は非置換アンモニウム(メチル−、ジメチル−、トリメチル−、テトラメチルアンモニウム、ジメチルピペリジニウムなど)又はアルカノールアミン(モノエタノールアミン、ジエタノールアミン、トリエタノールアミンなど)誘導体を表わす]のアルキルエステルスルホネート、ここで最も特には、R基がC14〜C16であるメチルエチルスルホネートを挙げることができる、
・式:ROSO3M[式中、Rは、C5〜C24好ましくはC10〜C18アルキル又はヒドロキシアルキル基を表わし、Mは水素原子又は先に記載したと同じ規定の陽イオン、並びに平均して0.5〜30そして好ましくは0.5〜10個のEO及び/又はPO単位を含有するそれらのエトキシレン化(EO)及び/又はプロポキシレン化(PO)誘導体を表わす]のアルキルサルフェート、
・式:RCONHR’OSO3M[式中、Rは、C2〜C22好ましくはC6〜C20アルキル基を表わし、R’はC2〜C3アルキル基を表わし、Mは水素原子又は先に記載したと同じ規定の陽イオン、並びに平均して0.5〜60個のEO及び/又はPO単位を含有するそれらのエトキシレン化(EO)及び/又はプロポキシレン化(PO)誘導体を表わす]のアルキルアミドサルフェート、
・飽和又は不飽和C8〜C24好ましくはC14〜C20脂肪酸、C9〜C20アルキルベンゼンスルホネート、第一又は第二C8〜C20アルキルスルホネート、アルキルグリセリルスルホネート、GB−A−1082179に記載されるスルホン化ポリカルボン酸、パラフィンスルホネート、N−アシル−N−アルキルトーレート、アルキルホスフェート、アセチオネート、アルキルスクシンナメート、アルキルスルホスクシネート、スルホスクシネートモノエステル又はジエステル、N−アシルサルコシネート、アルキルグリコシドサルフェート及びポリエトキシカルボキシレートの塩、ここで陽イオンはアルカリ金属(ナトリウム、カリウム又はリチウム)、置換又は非置換アンモニウム残基(メチル−、ジメチル−、トリメチル−、テトラメチルアンモニウム、ジメチルピペリジニウムなど)又はアルカノールアミン(モノエタノールアミン、ジエタノールアミン、トリエタノールアミンなど)誘導体を表わす、
・ロディア社によって製造販売される商品名「Rhodafac RA600」、「Rhodafac PA15」又は「Rhodafac PA23」の如きアルキル又はアルキルアリールホスフェートエステル、
である。
・5〜25個のオキシアルキレン単位を含有するポリオキシアルキレン化(ポリエトキシエチレン化、ポリオキシプロピレン化又はポリオキシブチレン化)アルキルフェノール(ここで、アルキル置換基はC6〜C12である)、一例として、ローム・アンド・ハース社によって製造販売される商品名「Triton X-45」、「Triton X-114」、「Triton X-100」又は「Triton X-102」を挙げることができる、
・グルコサミド、グルカミド及びグリセロールアミド、
・1〜25個のオキシアルキレン(オキシエチレン又はオキシプロピレン)単位を含有するポリオキシアルキレン化C8〜C22脂肪族アルコール、一例として、ユニオン・カーバイド社によって製造販売される商品名「Tergitol 15-S-9」及び「Tergitol 24-L-6 NMW」、シェル・ケミカル社によって製造販売される商品名「Neodol 45-9」、「Neodol 23-65」、「Neodol 45-7」及び「Neodol 45-4」、並びにロディア社によって製造販売される商品名「Rhodasurf IDO 60」、「Rhodasurf LA 90」及び「Rhodasurf ITO 70」を挙げることができる、
・(C10〜C18)アルキルジメチルアミンオキシド及び(C8〜C22)アルコキシエチルジヒドロキシエチルアミンオキシド、
・US−A−4565647に記載されるアルキルポリグリコシド、
・C8〜C20脂肪酸アミド、
・エトキシル化脂肪酸、
・エトキシル化アミン、
を挙げることができる。
R1R2R3R4N+X-
[式中、
・X-は、ハロゲン化物、CH3SO4 -又はC2H5SO4 -イオンを表わし、
・R1及びR2は同種又は異種であって、そしてC1〜C20アルキル基、又はアリール若しくはベンジル基を表わし、
・R3及びR4は同種又は異種であって、そしてC1〜C20アルキル基、アリール若しくはベンジル基、又はエチレンオキシド及び/又はプロピレンオキシド縮合基(CH2CH2O)x−(CH2CHCH3O)y−Hを表わし、ここでx及びyは0〜30であって、両方とも0にはならない]、
のアルキルアンモニウム塩であり、例えば、ロディア社によって製造販売される商品名「Rhodaquat TFR」のセチルトリメチルアンモニウムブロミドである。
・ロディア社によって製造販売される商品名「Mirataine CBC」の如きアルキルジメチルベタイン、アルキルアミドプロピルジメチルベタイン、アルキルジメチルスルホベタイン又はアルキルアミドプロピルジメチルスルホベタイン、並びに脂肪酸とタンパク質加水分解物との縮合生成物、
・アルキルアンホアセテート又はアルキルアンホジアセテート(ここで、アルキル基は6〜20個の炭素原子を含有する)、
・ロディア社によって製造販売される商品名「Amphionic XL」及びベロル・ノベル社によって製造販売される商品名「Ampholac 7C/X」の如きアルキルポリアミンの両性誘導体、
が好ましい。
・*特に食器洗浄機での洗浄用
−有機“ビルダー”(界面活性剤の表面特性を向上させるための洗剤補助剤)、例えば、
・有機ホスホネート、例えばモンサント社からの商品名「Dequest」のもの(食器洗浄機用組成物の場合には、洗剤組成物の総重量に対して、固形物として表わして0〜2%の割合で)、
・ポリカルボン酸又はその水溶性塩、及びカルボン酸重合体又は共重合体の水溶性塩、例えば、
・ポリカルボキシレート又はヒドロキシポリカルボキシレートエーテル、
・ポリ酢酸又はその塩(ニトリロ酢酸、N,N−ジカルボキシメチル−2−アミノペンタンジ酸、エチレンジアミンテトラ酢酸、ジエチレントリアミンペンタ酢酸、エチレンジアミンテトラアセテート、ニトリロトリアセテート、例えばロディア社によって製造販売される商品名「Nervanaid NTA Na3」、及びN−(2−ヒドロキシエチル)ニトリロジアセテート)(食器洗浄機用組成物の場合には、洗剤組成物の総重量に対して、固形物として表わして0〜10%の割合で)
・(C5〜C20)アルキルコハク酸の塩、
・カルボン酸ポリアセタールエステル、
・ポリアスパラギン酸又はポリグルタミン酸、
・クエン酸、グルコン酸若しくは酒石酸又はそれらの塩(食器洗浄機用組成物の場合には、洗剤組成物の総重量に対して、固形物として表わして0〜10%の割合で)、
−無機“ビルダー”(界面活性剤の表面特性を向上させるための洗剤補助剤)、例えば、
・アルカノールアミン、アンモニウム又はアルカリ金属ポリホスフェート、例えばロディア社によって製造販売される商品名「Rhodiaphos HPA3.5」、(食器洗浄機用組成物の場合には、洗剤組成物の総重量に対して、固形物として表わして0〜70%の割合で)、
・ピロ燐酸アルカリ金属、
・ゼオライト、
・シリケート(食器洗浄機用組成物の場合には、洗剤組成物の総重量に対して、固形物として表わして約50%までにわたってよい割合で)、
・アルカリ金属又はアルカリ土類金属の硼酸塩、炭酸塩、重炭酸塩及びセスキ炭酸塩(食器洗浄機用組成物の場合には、洗剤組成物の総重量に対して、固形物として表わして約50%までにわたってよい割合で)、
・EP−A−488868に記載される水和珪酸アルカリ金属と炭酸アルカリ金属(ナトリウム又はカリウム)との共顆粒、例えばロディア社によって製造販売される商品名「Nabion 15」(食器洗浄機用組成物の場合には、洗剤組成物の総重量に対して、固形物として表わして約50%までにわたってよい割合で)、
(有機及び/又は無機“ビルダー”の総量は、食器洗浄機用組成物の場合には、固形物として表わして洗剤組成物の総重量の90%までを占めることが可能である)、
−N,N,N’,N’−テトラアセチルエチレンジアミン(TAED)、又はクロルイソシアヌレートのような塩素化化合物又は次亜塩素酸アルカリ金属のような塩素化化合物の如きアセチル化漂白活性剤と随意に組み合わされる過硼酸塩又は過炭酸塩の如き漂白剤(食器洗浄機用組成物の場合には、洗剤組成物の総重量に対して、固形物として表わして0〜30%の割合で)、
−アクリル酸と無水マレイン酸との共重合体又はアクリル酸単独重合体の如き補助洗剤(食器洗浄機用組成物の場合には、洗剤組成物の総重量に対して、固形物として表わして0〜10%の割合で)、
−硫酸ナトリウム又は塩化ナトリウムの如き充填剤(洗剤組成物の総重量に対して、固形物として表わして0〜50%の割合で)、
−他の各種添加剤、例えば洗剤組成物のpHに影響を及ぼす薬剤、特に、洗浄媒体中に可溶性の塩基化用添加剤(アルカリ金属の燐酸塩、炭酸塩、過硼酸塩又は水酸化物)又は洗浄媒体中に可溶性の酸性化用添加剤(カルボン酸又はポリカルボン酸、アルカリ金属重炭酸塩及びセスキ炭酸塩、燐酸、ポリ燐酸、スルホン酸など)、又は酵素若しくは香料、着色剤又は金属腐食抑制剤、
*特に手によって洗浄を行うためのもの
−合成陽イオン性重合体、例えばロディア社によって製造販売される商品名「Mirapol A550」及び「Mirapol A15」、並びにカルゴン社によって製造販売される商品名「Merquat 550」、
−混合物の粘度及び/又は使用時に形成される気泡の安定性を制御するのに使用される重合体、例えばセルロース又はグアル誘導体(カルボキシメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルグアル、カルボキシエチルグアル、カルボキシメチルヒドロキシプロピルグアルなど)、
−ヒドロトロープ剤、例えばC2〜C8短鎖アルコール、特にエタノール、ジオール及びグリコール、例えばジエチレングリコール、ジプロピレングリコールなど、
−皮膚用の加湿剤又は湿潤剤、例えばグリセロール若しくは尿素、又は皮膚保護剤、例えばタンパク質又はタンパク質加水分解物、及び陽イオン性重合体、例えば陽イオン性グアル誘導体(ロディア社によって製造販売される商品名「Jaguar C13S」、「Jaguar C162」及び「Hicare 1000」)、
を挙げることができる。
・アミンオキシド、アルキルグルカミド、脂肪アルコールのオキシアルキレン化誘導体、アルキルアミド、アルカノールアミド、及び両性又は双性界面活性剤の如き非イオン性界面活性剤、
・トリクロサン(triclosan)の如き非陽イオン性殺菌剤又は消毒剤、
・合成陽イオン性重合体、
・混合物の粘度及び/又は使用時に形成される気泡の安定性を制御するための重合体、
・ヒドロトロープ剤、
・加湿剤若しくは湿潤剤又は皮膚保護剤、
・先に記載したような着色剤、香料、保存剤など、
を含有することができる。
・0.001重量%〜10重量%そして好ましくは0.005重量%〜3重量%の、先に規定した如き少なくとも1種の水溶性又は水分散性共重合体、
・0.005重量%〜20重量%そして好ましくは0.5重量%〜10重量%の少なくとも1種の非イオン性界面活性剤(例えば、アミンオキシド)及び/又は陰イオン性界面活性剤、及び
・残部の水、及び/又は当分野において慣用される各種添加剤、
を含む。
−0〜10%そして有益には0.5〜5%の両性界面活性剤、
−0〜30%そして有益には0.5〜15%のアルコールの如き溶剤、及び
−残部の水及び慣用添加剤(特に、香料)、
を含むこともできる。
−非イオン性界面活性剤(処方物の0〜30%そして好ましくは0.5〜15%の割合で)、
−両性及び/又は双性界面活性剤(処方物の0〜30%そして好ましくは0.5〜15%の割合で)、
−陽イオン性界面活性剤(処方物の0〜30%そして好ましくは0.5〜15%の割合で)、
−陰イオン性界面活性剤(処方物の0〜30%そして好ましくは0.5〜15%の割合で)、
−有機又は無機洗剤補助剤(“ビルダー”)、
−ヒドロトロープ剤、
−充填剤、pH調節剤など、
を含む。
− 0.05〜5重量%の本発明の共重合体、
− 0.1〜1重量%のキサンタンガムの如き増稠剤、
− 10〜40重量%の炭酸カルシウム又はシリカの如き研磨剤、
− 0〜7重量%のブチルジグリコールの如きグリコール、
− 1〜10重量%の非イオン性界面活性剤、
− 0.1〜3重量%のシリコーンタイプの共重合体、
− 随意成分としての塩基化剤又は金属イオン封鎖剤、
を含む。
エタノールで予備浄化した寸法が2.5×7.5cmの顕微鏡スライドよりなるガラス表面を使用する。その組成を以下に示す。
Si:21〜43重量%
Ca:2.8〜5.8重量%
Mg:1.6〜3.4重量%
Na:6.8〜14.2重量%
Al:0.3〜0.7重量%
・重合体と界面活性剤との溶液をガラススライドに付着させること、
・ガラススライドを1500rpmで30秒間回転させること、
の条件に付着させる。
・ガラススライドを精製水中に15秒間浸漬する工程、
・スライドを回転塗布器による1500rpmで30秒間の回転によって乾燥させる工程、
を要件とする。
ガラスパネルを洗浄するための洗浄用組成物
以下の表は、ガラスパネルを洗浄するのに使用される3種の洗浄用処方物の組成を示す。
タイル、セラミック、台所の流し台及び浴槽の如き硬質表面用の洗浄用処方物
以下の表は、硬質表面を洗浄するための洗浄用処方物を示す。
自動食器洗浄機用の洗剤処方物
以下の表に記載した化合物からベース洗剤処方物を調製する。
自動食器洗浄機で陶器類を濯ぎ洗浄するための処方物
手によって洗浄を行なうための処方物
硬質表面(タイル、台所の流し台、浴槽)を洗浄するための洗剤処方物
Claims (13)
- 浴槽及び台所の流し台の洗浄用組成物であって、
・前記洗浄用組成物の総重量に対して0.02重量%〜5重量%の、乾燥後の水滴跡の残存を回避するための、並びに/又は長期間持続型の防汚性、水滴跡残存防止性及び/若しくは曇り防止性を硬質表面に与えるための親水性付与剤、
・前記洗浄用組成物の総重量に対して、0〜30重量%の少なくとも1種の界面活性剤、
・前記洗浄用組成物の総重量に対して、0.1重量%〜25重量%の少なくとも1種の有機又は無機洗剤補助剤(“ビルダー”)、
・随意成分としての気泡調節剤、
・随意成分としてのpH調節剤、着色剤、増白剤、汚れ懸濁剤、洗剤酵素、相容性漂白剤、ゲル形成調節剤、氷解安定剤、殺菌剤、保存剤、溶剤、殺カビ剤、昆虫忌避剤、ヒドロトロープ剤、香料、不透明剤及び真珠箔剤、
を含み、
前記親水性付与剤は、水溶性又は水分散性共重合体から成り、
前記水溶性又は水分散性共重合体の重合単位が、
(a)一般式I:
・R1及びR4は互いに独立して、水素原子又は線状若しくは分岐状C1〜C6アルキル基を表わし、
・R2及びR3は互いに独立して、アルキル、ヒドロキシアルキル又はアミノアルキル基(ここで、アルキル基は線状又は分岐状C1〜C6鎖を表わす)を表わし、
・n及びmは1〜3の整数であり、
・X-は同種又は異種であってよく、そして重合体の水溶性又は水分散性と相容性である対イオンを表わす]の少なくとも1種の単量体化合物、
(b)(a)と共重合可能であり且つ適用媒体中においてイオン化することができる酸性の機能を有する少なくとも1種の親水性単量体、
(c)エチレン性不飽和を含有し、中性電荷を有し、1個又はそれ以上の親水性基を有し、且つ(a)及び(b)と共重合可能な、随意成分としての少なくとも1種の親水性単量体化合物、
を含み、かつ(a)/(b)モル比が60/40〜5/95である洗浄用組成物。 - 単量体(b)が、モノエチレン性不飽和を含有するC3〜C8カルボン酸、スルホン酸、硫酸、ホスホン酸及び燐酸から選択される請求項1又は2記載の洗浄用組成物。
- 単量体(b)が、アクリル酸、メタクリル酸、α−エタクリル酸、β,β−ジメチルアクリル酸、メチレンマロン酸、ビニル酢酸、アリル酢酸、エチリデン酢酸、プロピリデン酢酸、クロトン酸、マレイン酸、フマル酸、イタコン酸、シトラコン酸、メサコン酸、N−メタクリロイルアラニン、N−アクリロイルヒドロキシグリシン、アクリル酸スルホプロピル、アクリル酸スルホエチル、メタクリル酸スルホエチル、メタクリル酸スルホプロピル、スチレンスルホン酸、ビニルスルホン酸、ビニルホスホン酸、アクリル酸スルホエチル、アクリル酸スルホノエチル、アクリル酸ホスホプロピル、アクリル酸ホスホノプロピル、メタクリル酸スルホエチル、メタクリル酸スルホノエチル、メタクリル酸スルホプロピル及びメタクリル酸スルホノプロピル、並びにこれらの酸のアンモニウム及びアルカリ金属塩から選択される請求項1〜3のいずれか一項記載の洗浄用組成物。
- 単量体(c)が、アクリルアミド、ビニルアルコール、アクリル酸及びメタクリル酸のC1〜C4アルキルエステル、アクリル酸及びメタクリル酸のC1〜C4ヒドロキシアルキルエステル、並びにアクリル酸及びメタクリル酸のポリアルコキシル化エステルから選択される請求項1〜4のいずれか一項記載の洗浄用組成物。
- X-がハロゲン化物、硫酸塩、重硫酸塩、燐酸塩、クエン酸塩、ギ酸塩及び酢酸塩の陰イオンから選択される請求項1〜5のいずれか一項記載の洗浄用組成物。
- 前記水溶性又は水分散性共重合体が、
・5〜60モル%の単量体(a)、
・10〜95モル%の単量体(b)、
・0〜50モル%の単量体(c)、
の共重合によって得られることを特徴とする請求項1〜6のいずれか一項記載の洗浄用組成物。 - (a)/(b)モル比が50/50〜10/90であることを特徴とする請求項1〜7のいずれか一項記載の洗浄用組成物。
- 前記水溶性又は水分散性共重合体の分子量が少なくとも1,000であることを特徴とする請求項1〜8のいずれか一項記載の洗浄用組成物。
- 式Iの化合物が、総重量の0.001%〜10%に相当することを特徴とする組成物に使用する請求項1〜9のいずれか一項記載の洗浄用組成物。
- 式Iの化合物/界面活性剤の重量比が1/2〜1/100であることを特徴とする組成物に使用する請求項1〜10のいずれか一項記載の洗浄用組成物。
- 前記親水性付与剤が適用された表面の乾燥速度を追加的に低下させるための請求項1〜11のいずれか一項記載の洗浄用組成物。
- 前記親水性が、“流れ抵抗性”及び“曇り防止性”、並びに長期持続型“防汚性”及び“水滴跡残存防止性”の特性から選択されることを特徴とする請求項1記載の洗浄用組成物。
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US20030083223A1 (en) | 2003-05-01 |
JP2008266653A (ja) | 2008-11-06 |
DE60018068T2 (de) | 2005-12-29 |
BR0012499B1 (pt) | 2011-03-22 |
CA2378198C (fr) | 2012-09-04 |
US6593288B2 (en) | 2003-07-15 |
JP2003505535A (ja) | 2003-02-12 |
US20030203826A1 (en) | 2003-10-30 |
ATE288956T1 (de) | 2005-02-15 |
EP1196527B1 (fr) | 2005-02-09 |
FR2796390A1 (fr) | 2001-01-19 |
DE60018068D1 (de) | 2005-03-17 |
AU780845B2 (en) | 2005-04-21 |
US6767410B2 (en) | 2004-07-27 |
AU6449300A (en) | 2001-02-05 |
WO2001005921A1 (fr) | 2001-01-25 |
ES2234646T3 (es) | 2005-07-01 |
FR2796390B1 (fr) | 2001-10-26 |
EP1196527A1 (fr) | 2002-04-17 |
CA2378198A1 (fr) | 2001-01-25 |
JP4215982B2 (ja) | 2009-01-28 |
BR0012499A (pt) | 2002-04-02 |
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