JP4852820B2 - 化粧シート - Google Patents
化粧シート Download PDFInfo
- Publication number
- JP4852820B2 JP4852820B2 JP2003434925A JP2003434925A JP4852820B2 JP 4852820 B2 JP4852820 B2 JP 4852820B2 JP 2003434925 A JP2003434925 A JP 2003434925A JP 2003434925 A JP2003434925 A JP 2003434925A JP 4852820 B2 JP4852820 B2 JP 4852820B2
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- Japan
- Prior art keywords
- weight
- layer
- decorative sheet
- resin
- ppm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000012964 benzotriazole Substances 0.000 claims description 18
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- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 9
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- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
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- 125000003118 aryl group Chemical group 0.000 description 2
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 2
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Images
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- Laminated Bodies (AREA)
Description
1. ポリオレフィン系樹脂からなる透明性基材シートの裏側に絵柄模様層及び着色隠蔽層が順に形成されており、基材シートのおもて側に透明樹脂層が形成されている化粧シートであって、
前記透明樹脂層は、分子中にイソシアネート基を有する硬化剤を含むインキにより形成されており、
前記基材シートが、ポリオレフィン系樹脂フィルムを3層積層した構造からなり、中間層がベンゾトリアゾール系紫外線吸収剤500〜2000重量ppm及びヒンダードアミン系光安定剤100〜1000重量ppmを含有し、中間層を挟む両端の2層はそれらを含有しないものであり、
前記ベンゾトリアゾール系紫外線吸収剤が、2−(2’−ヒドロキシ−3’−tert−ブチル−5’−メチルフェニル)−5−クロロベンゾトリアゾールであって、
前記ヒンダードアミン系光安定剤が、ビス(2,2,6,6,−テトラメチル−4−ピペリジニル)セバケートである、
化粧シート。
2. 分子中にイソシアネート基を有する硬化剤が、1,6−ヘキサメチレンジイソシアネートである上記項1に記載の化粧シート。
3. 化粧シートを構成する層の少なくとも1種が、水性組成物から形成されている上記項1又は2に記載の化粧シート。
4. 基材シートの片面又は両面が、水性組成物から形成されたプライマー層を有する上記項1〜3のいずれかに記載の化粧シート。
5. 透明樹脂層が、紫外線吸収剤100〜10000重量ppm及び/又はヒンダードアミン系光安定剤100〜10000重量ppmを含有する上記項1〜4のいずれかに記載の化粧シート。
6. 上記項1〜5のいずれかに記載の化粧シートの着色隠蔽層上に被着体を積層してなる化粧板。
本発明の化粧シートでは、ポリオレフィン系樹脂からなる透明性基材シートを用いる。
(i)特開平9−111055号公報記載のもの。これは、エチレン、プロピレン及びブテンの三元共重合体によるランダム共重合体である。単量体成分の重量比はプロピレンが90重量%以上である。メルトフローレートは、230℃、2.16kgで1〜50g/10分のものが好適である。そして、このような三元ランダム共重合体100重量部に対して、燐酸アリールエステル化合物を主成分とする透明造核剤を0.01〜50重量部、炭素数12〜22の脂肪酸アミド0.003〜0.3重量部を、熔融混練することにより得られる。
(ii)特開平5−77371号公報記載のもの。これは、エチレン、プロピレン、1−ブテンの三元共重合体であって、プロピレン成分含有率が50重量%以上の非晶質重合体20〜100重量%に、結晶質ポリプロピレン80〜0重量%添加することにより得られる。
(iii)特開平7−316358号公報記載のもの。これは、エチレン、プロピレン、1−ブテンの三元共重合体であって、プロピレン及び/又は1−ブテン含有率が50重量%以上の低結晶質重合体20〜100重量%に対して、アイソタクチックポリプロピレン等の結晶質ポリオレフィン80〜0重量%を混合した組成物に対して、N−アシルアミノ酸アミン塩、N−アシルアミノ酸エステル等の油ゲル化剤を0.5重量%添加することにより得られる。
基材シートの裏側(被着体と接合される側)には、絵柄模様層が形成される。
絵柄模様層を形成後、さらに着色隠蔽層が形成される。着色隠蔽層は、化粧シートと被着体とを接合した際に被着体の地色を隠蔽できればよく、通常は絵柄模様層を被覆するように形成すればよい。
基材シートのおもて側には、透明樹脂層が形成される。
本発明の化粧シートでは、基材シート以外の層にも、必要に応じて、耐候剤を添加してもよい。添加する層としては、特に透明樹脂層が好ましい。耐候剤としては、特に紫外線吸収剤及びヒンダードアミン系光安定剤の少なくとも1種を好適に使用できる。
(紫外線吸収剤)
紫外線吸収剤としては、特に塩基性成分(特にヒドロキシル基)を有するものが好ましい。例えば、2−(2’−ヒドロキシ−3’,5’−ジ−tert−ブチルフェニル)−5−クロロベンゾトリアゾール、2−(2’−ヒドロキシ−3’−tert−ブチル−5’−メチルフェニル)−5−クロロベンゾトリアゾール、2−(2’−ヒドロキシ−3’−tert−アミル−5’−イソブチルフェニル)−5−クロロベンゾトリアゾール、2−(2’−ヒドロキシ−3’−イソブチル−5’−メチルフェニル)−5−クロロベンゾトリアゾール、2−(2’−ヒドロキシ−3’−イソブチル−5’−プロピルフェニル)−5−クロロベンゾトリアゾール、2−(2’−ヒドロキシ−3’,5’−ジ−tert−ブチルフェニル)−5−クロロベンゾトリアゾール等の、2’−ヒドロキシフェニル−5−クロロベンゾトリアゾール系紫外線吸収剤類、2−(2’−ヒドロキシ−3’,5’−ジ−tert−ブチルフェニル)ベンゾトリアゾール、2−(2’−ヒドロキシ−5’−メチルフェニル)ベンゾトリアゾール、2−(2’−ヒドロキシ−5’−tert−ブチルフェニル)ベンゾトリアゾール、2−(2’−ヒドロキシ−5’−tert−オクチルフェニル)ベンゾトリアゾール、2−(2’−ヒドロキシ−4’−オクトキシフェニル)ベンゾトリアゾール、2−(2’−ヒドロキシ−3’,5’−ジ−tert−ブチルフェニル)ベンゾトリアゾール、2−(2’−ヒドロキシ−3’,5’−ジ−tert−アミルフェニル)ベンゾトリアゾール、2−(2’−ヒドロキシ−3’−ドデシル−5’−メチルフェニル)ベンゾトリアゾール、2−(2’−ヒドロキシ−3’,5’−ビス(α,α−ジメチルベンジル)フェニルベンゾトリアゾール、2−[2’−ヒドロキシ−3’−(3’’,4’’,5’’,6’’−テトラフタルイミドメチル)−5’−メチルフェニル]ベンゾトリアゾール等の、2’−ヒドロキシフェニルベンゾトリアゾール系紫外線吸収剤類等、その他2,2’−メチレンビス[4−(1,1,3,3−テトラメチルブチル)−6−(2H−ベンゾトリアゾール−2−イル)フェノール]等のベンゾトリアゾール系紫外線吸収剤、2,2’−ジヒドロキシ−4−メトキシベンゾフェノン、2,2’−ジヒドロキシ−4,4’−ジメトキシベンゾフェノン、2,2’,4,4’−テトラヒドロキシベンゾフェノン等の、2,2’−ジヒドロキシベンゾフェノン系紫外線吸収剤類、2−ヒドロキシ−4−メトキシベンゾフェノン、2,4−ジヒドロキシベンゾフェノン等の、2ヒドロキシベンゾフェノン系紫外線吸収剤類、等のベンゾフェノン系紫外線吸収剤、サリチル酸フェニル、4−tert−ブチル−フェニル−サリシレート等のサリチル酸エステル系紫外線吸収剤が用いられる。その他に、ベンゾトリアゾール骨格にアクリロイル基又はメタクリロイル基を導入した反応性紫外線吸収剤等も用いられる。なお、これら紫外線吸収剤の添加量は、樹脂分に対して、通常0.1〜5質量%程度である。
(ヒンダードアミン系光安定剤)
紫外線による各層の劣化をさらに防止し、耐候性を向上させるためには、他の耐候剤としてヒンダードアミン系光安定剤を添加することが好ましい。例えば、ビス−(2,2,6,6−テトラメチル−4−ピペリジニル)セバケート、ビス−(N−メチル−2,2,6,6−テトラメチル−4−ピペリジニル)セバケート、1,1’−(1,2−エタンジイル)ビス(3,3,5,5−テトラメチルピペラジンオン)、ビス−(N−メチル−2,2,6,6−テトラメチル−4−ピペリジニル)セバケート、ビス−(1,2,2,6,6−ペンタメチル−4−ピペリジル)−2−(3,5−ジ−tert−ブチル−4−ヒドロキシベンジル)−2−n−ブチルマロネート、1,2,3,4−ブタンカルボン酸と2,2,6,6−テトラメチル−4−ピペリジノールとトリデシルアルコールとの縮合物等、その他、例えば特公平4−82625号公報に開示されている化合物等が挙げられる。これらの光安定剤の添加量は特に限定されないが、通常、樹脂分に対して0.1〜5重量%程度である。
本発明の化粧シートは、各種被着体と接合することにより、化粧板とできる。被着体の材質は特に限定されず、例えば、無機非金属系、金属系、木質系、プラスチック系等の材質が挙げられる。
図1に示される構成の化粧シートを作製した。
ベンゾトリアゾール系紫外線吸収剤の含有量を1000重量ppmから100重量ppm(実施例2)及び10000重量ppm(実施例3)に変えたほかは、実施例1と同様にして化粧シートを作製した。
図2に示される構成の化粧シートを作製した。
ヒンダードアミン系光安定剤の含有量を1000重量ppm(実施例5)及び10000重量ppm(実施例6)に変えたほかは、実施例4と同様にして化粧シートを作製した。
基材シート中の耐候剤を、2−(2’−ヒドロキシ−3’−tert−ブチル−5’−メチルフェニル)−5−ベンゾトリアゾール1000重量ppmとビス(2,2,6,6,−テトラメチル−4−ピペリジニル)セバケート100重量ppmとの混合物としたほかは、実施例4と同様にして化粧シートを作製した。
ベンゾトリアゾール系紫外線吸収剤の含有量を1000重量ppmから50重量ppm(比較例1)及び15000重量ppm(比較例2)に変えたほかは、実施例1と同様にして化粧シートを作製した。
ヒンダードアミン系光安定剤の含有量を30重量ppm(比較例3)及び15000重量ppm(比較例4)に変えたほかは、実施例4と同様にして化粧シートを作製した。
実施例1において、ベンゾトリアゾール系紫外線吸収剤の種類を、下記表1に示すように変えたほかは、実施例1と同様にして化粧シートを作製した。
実施例4において、ヒンダードアミン系光安定剤の種類を、下記表1に示すように変えたほかは、実施例4と同様にして化粧シートを作製した。
各実施例、比較例及び参考例により得られた化粧シートに対し、カーボンアーク燈型サンシャインウェザーメーターで、ブラックパネル温度が63℃、降雨時間が120分中18分の条件下にて、1000時間照射した。
Claims (6)
- ポリオレフィン系樹脂からなる透明性基材シートの裏側に絵柄模様層及び着色隠蔽層が順に形成されており、基材シートのおもて側に透明樹脂層が形成されている化粧シートであって、
前記透明樹脂層は、分子中にイソシアネート基を有する硬化剤を含むインキにより形成されており、
前記基材シートが、ポリオレフィン系樹脂フィルムを3層積層した構造からなり、中間層がベンゾトリアゾール系紫外線吸収剤500〜2000重量ppm及びヒンダードアミン系光安定剤100〜1000重量ppmを含有し、中間層を挟む両端の2層はそれらを含有しないものであり、
前記ベンゾトリアゾール系紫外線吸収剤が、2−(2’−ヒドロキシ−3’−tert−ブチル−5’−メチルフェニル)−5−クロロベンゾトリアゾールであって、
前記ヒンダードアミン系光安定剤が、ビス(2,2,6,6,−テトラメチル−4−ピペリジニル)セバケートである、
化粧シート。 - 分子中にイソシアネート基を有する硬化剤が、1,6−ヘキサメチレンジイソシアネートである請求項1に記載の化粧シート。
- 化粧シートを構成する層の少なくとも1種が、水性組成物から形成されている請求項1又は2に記載の化粧シート。
- 基材シートの片面又は両面が、水性組成物から形成されたプライマー層を有する請求項1〜3のいずれかに記載の化粧シート。
- 透明樹脂層が、紫外線吸収剤100〜10000重量ppm及び/又はヒンダードアミン系光安定剤100〜10000重量ppmを含有する請求項1〜4のいずれかに記載の化粧シート。
- 請求項1〜5のいずれかに記載の化粧シートの着色隠蔽層上に被着体を積層してなる化粧板。
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