JP4829122B2 - 少量のフッ素化界面活性剤を有するポリテトラフルオロエチレンの水性分散液 - Google Patents
少量のフッ素化界面活性剤を有するポリテトラフルオロエチレンの水性分散液 Download PDFInfo
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- JP4829122B2 JP4829122B2 JP2006541153A JP2006541153A JP4829122B2 JP 4829122 B2 JP4829122 B2 JP 4829122B2 JP 2006541153 A JP2006541153 A JP 2006541153A JP 2006541153 A JP2006541153 A JP 2006541153A JP 4829122 B2 JP4829122 B2 JP 4829122B2
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- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- CVMIVKAWUQZOBP-UHFFFAOYSA-L manganic acid Chemical compound O[Mn](O)(=O)=O CVMIVKAWUQZOBP-UHFFFAOYSA-L 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical group FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/18—Homopolymers or copolymers of tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/16—Purification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03078598A EP1533325B1 (en) | 2003-11-17 | 2003-11-17 | Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant |
| EP03078598.4 | 2003-11-17 | ||
| PCT/US2004/033478 WO2005052013A1 (en) | 2003-11-17 | 2004-10-12 | Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2007511657A JP2007511657A (ja) | 2007-05-10 |
| JP2007511657A5 JP2007511657A5 (enExample) | 2009-01-22 |
| JP4829122B2 true JP4829122B2 (ja) | 2011-12-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| JP2006541153A Expired - Fee Related JP4829122B2 (ja) | 2003-11-17 | 2004-10-12 | 少量のフッ素化界面活性剤を有するポリテトラフルオロエチレンの水性分散液 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US7041728B2 (enExample) |
| EP (1) | EP1533325B1 (enExample) |
| JP (1) | JP4829122B2 (enExample) |
| CN (1) | CN100509874C (enExample) |
| AT (1) | ATE529451T1 (enExample) |
| RU (1) | RU2006116761A (enExample) |
| WO (1) | WO2005052013A1 (enExample) |
Families Citing this family (147)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1134286C (zh) | 1996-12-20 | 2004-01-14 | Usf过滤分离集团公司 | 净化方法 |
| AUPR143400A0 (en) * | 2000-11-13 | 2000-12-07 | Usf Filtration And Separations Group Inc. | Modified membranes |
| AUPR421501A0 (en) | 2001-04-04 | 2001-05-03 | U.S. Filter Wastewater Group, Inc. | Potting method |
| AUPR584301A0 (en) * | 2001-06-20 | 2001-07-12 | U.S. Filter Wastewater Group, Inc. | Membrane polymer compositions |
| AUPR692401A0 (en) | 2001-08-09 | 2001-08-30 | U.S. Filter Wastewater Group, Inc. | Method of cleaning membrane modules |
| US7279522B2 (en) * | 2001-09-05 | 2007-10-09 | 3M Innovative Properties Company | Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant |
| US7247238B2 (en) | 2002-02-12 | 2007-07-24 | Siemens Water Technologies Corp. | Poly(ethylene chlorotrifluoroethylene) membranes |
| AUPS300602A0 (en) | 2002-06-18 | 2002-07-11 | U.S. Filter Wastewater Group, Inc. | Methods of minimising the effect of integrity loss in hollow fibre membrane modules |
| WO2004033078A1 (en) | 2002-10-10 | 2004-04-22 | U.S. Filter Wastewater Group, Inc. | Backwash method |
| AU2002953111A0 (en) | 2002-12-05 | 2002-12-19 | U. S. Filter Wastewater Group, Inc. | Mixing chamber |
| AU2003903507A0 (en) | 2003-07-08 | 2003-07-24 | U. S. Filter Wastewater Group, Inc. | Membrane post-treatment |
| CA2535360C (en) | 2003-08-29 | 2013-02-12 | U.S. Filter Wastewater Group, Inc. | Backwash |
| ATE502062T1 (de) * | 2003-10-24 | 2011-04-15 | 3M Innovative Properties Co | Wässrige dispersionen von polytetrafluorethylenteilchen |
| CA2544626C (en) | 2003-11-14 | 2016-01-26 | U.S. Filter Wastewater Group, Inc. | Closed aeration and backwash device for use with membrane filtration module |
| EP1533325B1 (en) * | 2003-11-17 | 2011-10-19 | 3M Innovative Properties Company | Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant |
| US20070155891A1 (en) * | 2003-12-09 | 2007-07-05 | Daikin Industries, Ltd. | Water base dispersion of fluorinated polymer and process for producing the same |
| PL1570917T3 (pl) * | 2004-03-01 | 2009-10-30 | 3M Innovative Properties Co | Sposób powlekania substratu dyspersją fluoropolimeru |
| WO2005092799A1 (en) | 2004-03-26 | 2005-10-06 | U.S. Filter Wastewater Group, Inc. | Process and apparatus for purifying impure water using microfiltration or ultrafiltration in combination with reverse osmosis |
| AU2005240524C1 (en) | 2004-04-22 | 2009-12-24 | Evoqua Water Technologies Llc | Filtration apparatus comprising a membrane bioreactor and a treatment vessel for digesting organic materials |
| CA2571498A1 (en) | 2004-07-02 | 2006-01-12 | U.S. Filter Wastewater Group, Inc. | Gas transfer membrane |
| JP2008505197A (ja) | 2004-07-05 | 2008-02-21 | シーメンス・ウォーター・テクノロジーズ・コーポレーション | 親水性膜 |
| US7304101B2 (en) * | 2004-07-19 | 2007-12-04 | 3M Innovative Properties Company | Method of purifying a dispersion of ionic fluoropolymer |
| US7790041B2 (en) * | 2004-08-11 | 2010-09-07 | E.I. Du Pont De Nemours And Company | Removing fluorosurfactant from aqueous fluoropolymer dispersions |
| US20070023360A1 (en) * | 2005-08-01 | 2007-02-01 | Noelke Charles J | Removing fluorosurfactant from aqueous fluoropolymer dispersion using sorbent pouches |
| NZ588094A (en) | 2004-08-20 | 2012-04-27 | Siemens Water Tech Corp | Potting head for hollow fibre filter module |
| US8790515B2 (en) | 2004-09-07 | 2014-07-29 | Evoqua Water Technologies Llc | Reduction of backwash liquid waste |
| NZ553742A (en) | 2004-09-14 | 2010-09-30 | Siemens Water Tech Corp | Methods and apparatus for removing solids from a membrane module |
| US8377305B2 (en) | 2004-09-15 | 2013-02-19 | Siemens Industry, Inc. | Continuously variable aeration |
| US7591950B2 (en) | 2004-11-02 | 2009-09-22 | Siemens Water Technologies Corp. | Submerged cross-flow filtration |
| MY141919A (en) | 2004-12-03 | 2010-07-30 | Siemens Water Tech Corp | Membrane post treatment |
| CA2591408C (en) | 2004-12-24 | 2015-07-21 | Siemens Water Technologies Corp. | Cleaning in membrane filtration systems |
| NZ555987A (en) | 2004-12-24 | 2009-08-28 | Siemens Water Tech Corp | Simple gas scouring method and apparatus |
| ITMI20042554A1 (it) * | 2004-12-30 | 2005-03-30 | Solvay Solexis Spa | Procedimento per la preparazione di dispersioni di fluoropolimeri |
| US20060178472A1 (en) * | 2005-02-10 | 2006-08-10 | Johnson David W | Process for producing low fluorosurfactant-containing aqueous fluoropolymer dispersions with controlled pH |
| WO2006116797A1 (en) | 2005-04-29 | 2006-11-09 | Siemens Water Technologies Corp. | Chemical clean for membrane filter |
| US7214740B2 (en) | 2005-05-03 | 2007-05-08 | 3M Innovative Properties Company | Fluorinated ionomers with reduced amounts of carbonyl end groups |
| US8814861B2 (en) | 2005-05-12 | 2014-08-26 | Innovatech, Llc | Electrosurgical electrode and method of manufacturing same |
| US7147634B2 (en) | 2005-05-12 | 2006-12-12 | Orion Industries, Ltd. | Electrosurgical electrode and method of manufacturing same |
| US7514484B2 (en) * | 2005-06-06 | 2009-04-07 | Asahi Glass Company, Limited | Aqueous dispersion of polytetrafluoroethylene and process for its production |
| US8080621B2 (en) * | 2005-06-10 | 2011-12-20 | Arkema Inc. | Aqueous process for making fluoropolymers |
| US8765890B2 (en) | 2005-06-10 | 2014-07-01 | Arkema Inc. | Aqueous process for making fluoropolymers |
| US20060281845A1 (en) * | 2005-06-10 | 2006-12-14 | Ramin Amin-Sanayei | Aqueous process for making fluoropolymers |
| US8338518B2 (en) | 2005-06-10 | 2012-12-25 | Arkema Inc. | Aqueous process for making a stable fluoropolymer dispersion |
| JP4956925B2 (ja) * | 2005-07-13 | 2012-06-20 | 旭硝子株式会社 | ポリテトラフルオロエチレン水性分散液およびその製造方法 |
| KR20080031956A (ko) | 2005-07-14 | 2008-04-11 | 지멘스 워터 테크놀로지스 코포레이션 | 막의 모노퍼술페이트 처리 방법 |
| GB0525978D0 (en) * | 2005-12-21 | 2006-02-01 | 3M Innovative Properties Co | Fluorinated Surfactants For Making Fluoropolymers |
| US20080015304A1 (en) | 2006-07-13 | 2008-01-17 | Klaus Hintzer | Aqueous emulsion polymerization process for producing fluoropolymers |
| US20070015937A1 (en) * | 2005-07-15 | 2007-01-18 | 3M Innovative Properties Company | Process for recovery of fluorinated carboxylic acid surfactants from exhaust gas |
| GB0514387D0 (en) * | 2005-07-15 | 2005-08-17 | 3M Innovative Properties Co | Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant |
| GB0523853D0 (en) * | 2005-11-24 | 2006-01-04 | 3M Innovative Properties Co | Fluorinated surfactants for use in making a fluoropolymer |
| GB0514398D0 (en) * | 2005-07-15 | 2005-08-17 | 3M Innovative Properties Co | Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant |
| JP4792873B2 (ja) * | 2005-08-19 | 2011-10-12 | 旭硝子株式会社 | 精製ポリテトラフルオロエチレン水性分散液の製造方法 |
| EP1945333B1 (en) | 2005-08-22 | 2011-06-08 | Siemens Industry, Inc. | An assembly for water filtration to minimise backwash volume |
| WO2007044415A2 (en) | 2005-10-05 | 2007-04-19 | Siemens Water Technologies Corp. | Method and apparatus for treating wastewater |
| US7563363B2 (en) | 2005-10-05 | 2009-07-21 | Siemens Water Technologies Corp. | System for treating wastewater |
| JP5141256B2 (ja) * | 2005-10-20 | 2013-02-13 | 旭硝子株式会社 | ポリテトラフルオロエチレン水性分散液およびその製品 |
| JP5343355B2 (ja) * | 2005-10-26 | 2013-11-13 | 旭硝子株式会社 | 含フッ素乳化剤の残留量が少ないフッ素樹脂およびその製造方法 |
| EP2527397A1 (en) * | 2005-10-31 | 2012-11-28 | Daikin Industries, Ltd. | Method for molding polytetrafluoroethylene, polytetrafluoroethylene molded body, crosslinkable polytetrafluoroethylene, powdered polytetrafluoroethylene crosslinked body, resin blend composition of matter and resin blend molded body |
| US7455765B2 (en) | 2006-01-25 | 2008-11-25 | Siemens Water Technologies Corp. | Wastewater treatment system and method |
| EP1845116A1 (en) | 2006-04-11 | 2007-10-17 | Solvay Solexis S.p.A. | Fluoropolymer dispersion purification |
| US7754795B2 (en) * | 2006-05-25 | 2010-07-13 | 3M Innovative Properties Company | Coating composition |
| US20070276103A1 (en) * | 2006-05-25 | 2007-11-29 | 3M Innovative Properties Company | Fluorinated Surfactants |
| US7666929B2 (en) | 2006-05-31 | 2010-02-23 | E.I. Du Pont De Nemours And Company | Process for reducing fluorosurfactant content of fluropolymer dispersions using anionic surfactant-treated anion exchange resin |
| US7666928B2 (en) * | 2006-05-31 | 2010-02-23 | E.I. Du Pont De Nemours And Company | Staged addition of non-fluorinated anionic surfactant to reduced fluorosurfactant fluoropolymer dispersion |
| JP5251013B2 (ja) * | 2006-06-29 | 2013-07-31 | ダイキン工業株式会社 | フッ素樹脂水性分散液の製造方法 |
| JP5050442B2 (ja) * | 2006-07-12 | 2012-10-17 | 旭硝子株式会社 | ポリテトラフルオロエチレン水性分散液 |
| US8119750B2 (en) * | 2006-07-13 | 2012-02-21 | 3M Innovative Properties Company | Explosion taming surfactants for the production of perfluoropolymers |
| US20080057298A1 (en) * | 2006-08-29 | 2008-03-06 | Surmodics, Inc. | Low friction particulate coatings |
| WO2008051546A2 (en) | 2006-10-24 | 2008-05-02 | Siemens Water Technologies Corp. | Infiltration/inflow control for membrane bioreactor |
| WO2008060463A1 (en) * | 2006-11-09 | 2008-05-22 | E. I. Du Pont De Nemours And Company | Aqueous polymerization of fluorinated monomers using polymerization agent comprising fluoropolyether acid or salt and hydrocarbon surfactant |
| US8322754B2 (en) * | 2006-12-01 | 2012-12-04 | Tenaris Connections Limited | Nanocomposite coatings for threaded connections |
| US20080146757A1 (en) * | 2006-12-19 | 2008-06-19 | Lyons Donald F | Process for producing fluoroelastomers |
| EP2129629A1 (en) | 2007-04-02 | 2009-12-09 | Siemens Water Technologies Corp. | Improved infiltration/inflow control for membrane bioreactor |
| US9764288B2 (en) | 2007-04-04 | 2017-09-19 | Evoqua Water Technologies Llc | Membrane module protection |
| US20080264864A1 (en) | 2007-04-27 | 2008-10-30 | 3M Innovative Properties Company | PROCESS FOR REMOVING FLUORINATED EMULSIFIER FROM FLUOROPOLMER DISPERSIONS USING AN ANION-EXCHANGE RESIN AND A pH-DEPENDENT SURFACTANT AND FLUOROPOLYMER DISPERSIONS CONTAINING A pH-DEPENDENT SURFACTANT |
| KR20100017848A (ko) * | 2007-05-23 | 2010-02-16 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 플루오르화 계면활성제의 수성 조성물 및 그의 사용 방법 |
| CN106040002B (zh) | 2007-05-29 | 2020-01-10 | 懿华水处理技术有限责任公司 | 使用脉冲气提泵的膜清洗 |
| CN101679569A (zh) * | 2007-06-06 | 2010-03-24 | 3M创新有限公司 | 氟化醚组合物以及使用该组合物的方法 |
| JP5077350B2 (ja) | 2007-07-24 | 2012-11-21 | ダイキン工業株式会社 | 新規化合物、その製造方法及びフルオロポリマーの製造方法 |
| WO2010009191A2 (en) * | 2008-07-18 | 2010-01-21 | 3M Innovative Properties Company | Fluorinated ether compounds and methods of using the same |
| CA2731774A1 (en) | 2008-07-24 | 2010-01-28 | Siemens Water Technologies Corp. | Frame system for membrane filtration modules |
| US20100036073A1 (en) * | 2008-08-08 | 2010-02-11 | E. I. Du Pont De Nemours And Company | Non-Melt-Flowable Perfluoropolymer Comprising Repeating Units Arising From Tetrafluoroethylene and a Monomer Having a Functional Group and a Polymerizable Carbon-Carbon Double Bond |
| US8652331B2 (en) | 2008-08-20 | 2014-02-18 | Siemens Water Technologies Llc | Membrane system backwash energy efficiency |
| US7816468B2 (en) * | 2008-09-18 | 2010-10-19 | Dupont Performance Elastomers Llc | Coagulation of fluoroelastomer dispersions with polyethylene oxide |
| US20110232530A1 (en) * | 2008-11-25 | 2011-09-29 | Dams Rudolf J | Fluorinated ether urethanes and methods of using the same |
| US8629089B2 (en) | 2008-12-18 | 2014-01-14 | 3M Innovative Properties Company | Method of contacting hydrocarbon-bearing formations with fluorinated ether compositions |
| US8835547B2 (en) * | 2008-12-23 | 2014-09-16 | E I Du Pont De Nemours And Company | Fluoropolymer particles having a nucleus of fluorinated ionomer |
| US8153738B2 (en) * | 2008-12-23 | 2012-04-10 | E I Du Pont De Nemours And Company | Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer |
| JP2012513533A (ja) * | 2008-12-23 | 2012-06-14 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | フッ素化イオノマーの分散した微粒子を使用する水性重合によって製造されるフッ素化イオノマー |
| US8436053B2 (en) * | 2008-12-23 | 2013-05-07 | E.I. Du Pont De Nemours And Company | Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer |
| US8058376B2 (en) * | 2008-12-23 | 2011-11-15 | E. I. Du Pont De Nemours And Company | Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated lonomer produced in situ |
| US8436054B2 (en) * | 2008-12-23 | 2013-05-07 | E I Du Pont De Nemours And Company | Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer produced in situ |
| AU2010101488B4 (en) | 2009-06-11 | 2013-05-02 | Evoqua Water Technologies Llc | Methods for cleaning a porous polymeric membrane and a kit for cleaning a porous polymeric membrane |
| RU2522749C2 (ru) | 2009-07-31 | 2014-07-20 | Зм Инновейтив Пропертиз Компани | Соединения фторполимера, содержащие многоатомные соединения, и способы из производства |
| WO2011046186A1 (ja) * | 2009-10-16 | 2011-04-21 | 旭硝子株式会社 | 凝析加工用ポリテトラフルオロエチレン水性分散液の製造方法及び凝析加工用ポリテトラフルオロエチレン水性分散液 |
| CN101709102B (zh) * | 2009-12-15 | 2012-11-14 | 山东华夏神舟新材料有限公司 | 高交换容量全氟树脂及其制备方法和用途 |
| HUE045642T2 (hu) | 2010-04-30 | 2020-01-28 | Evoqua Water Tech Llc | Folyadékáramlás elosztó készülék |
| CN103118766B (zh) | 2010-09-24 | 2016-04-13 | 伊沃夸水处理技术有限责任公司 | 膜过滤系统的流体控制歧管 |
| CN103201300B (zh) * | 2010-11-09 | 2016-11-09 | 纳幕尔杜邦公司 | 使用烃表面活性剂的含氟单体的含水聚合 |
| JP6030562B2 (ja) * | 2010-11-09 | 2016-11-24 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | 水性分散体フルオロモノマーの重合における炭化水素含有界面活性剤のテロゲン性挙動の低下 |
| WO2012064846A1 (en) * | 2010-11-09 | 2012-05-18 | E. I. Du Pont De Nemours And Company | Nucleation in aqueous polymerization of fluoromonomer |
| US9389525B2 (en) | 2011-03-09 | 2016-07-12 | Fuji Xerox Co., Ltd. | Fluorine-containing resin particle dispersion, method for preparing fluorine-containing resin particle dispersion, coating liquid which contains fluorine-containing resin particles, method for preparing coating film which contains fluorine-containing resin particles, coating film which contains fluorine-containing resin particles, molded body, electrophotographic photoreceptor, method for preparing electrophotographic photoreceptor, image forming apparatus, and process cartridge |
| KR101304893B1 (ko) * | 2011-04-12 | 2013-09-06 | (주)이지켐 | Ptfe 수분산체의 제조 및 이의 농축방법 |
| US9580590B2 (en) * | 2011-08-25 | 2017-02-28 | Daikin Industries, Ltd. | Method for producing aqueous polytetrafluoroethylene dispersion |
| KR101964484B1 (ko) | 2011-09-30 | 2019-04-01 | 에보쿠아 워터 테크놀로지스 엘엘씨 | 개선된 매니폴드 배열 |
| CN103958034B (zh) | 2011-09-30 | 2017-03-22 | 伊沃夸水处理技术有限责任公司 | 隔离阀 |
| JP5983633B2 (ja) * | 2012-02-02 | 2016-09-06 | 旭硝子株式会社 | ポリテトラフルオロエチレンファインパウダーの製造方法 |
| AU2013280452B2 (en) | 2012-06-28 | 2017-07-20 | Evoqua Water Technologies Llc | A potting method |
| CN102775617B (zh) * | 2012-07-18 | 2014-12-31 | 浙江巨圣氟化学有限公司 | 一种彩色聚四氟乙烯树脂的制备方法 |
| JP6371032B2 (ja) * | 2012-08-01 | 2018-08-08 | スリーエム イノベイティブ プロパティズ カンパニー | 反射防止ハードコートおよび反射防止物品 |
| WO2014023611A1 (en) | 2012-08-10 | 2014-02-13 | Solvay Specialty Polymers Italy S.P.A. | Allyl-bearing fluorinated ionomers |
| WO2014043315A1 (en) | 2012-09-14 | 2014-03-20 | Evoqua Water Technologies Llc | A polymer blend for membranes |
| US9764289B2 (en) | 2012-09-26 | 2017-09-19 | Evoqua Water Technologies Llc | Membrane securement device |
| AU2013231145B2 (en) | 2012-09-26 | 2017-08-17 | Evoqua Water Technologies Llc | Membrane potting methods |
| US9815027B2 (en) | 2012-09-27 | 2017-11-14 | Evoqua Water Technologies Llc | Gas scouring apparatus for immersed membranes |
| EP2803690B1 (en) | 2013-05-17 | 2016-12-14 | 3M Innovative Properties Company | Method for reducing fluorinated emulsifiers from aqueous fluoropolymer dispersions using sugar-based emulsifiers |
| EP2803691B1 (en) | 2013-05-17 | 2016-04-20 | 3M Innovative Properties Company | Fluoropolymer compositions containing a polyhydroxy surfactant |
| EP3052533B1 (en) * | 2013-09-30 | 2019-06-26 | Arkema, Inc. | Heat stabilized polyvinylidene fluoride polymer composition |
| HUE061765T2 (hu) | 2013-10-02 | 2023-08-28 | Rohm & Haas Electronic Mat Singapore Pte Ltd | Berendezés membrán filtrációs modul javítására |
| EP3074430B1 (en) | 2013-11-26 | 2019-02-20 | The Chemours Company FC, LLC | Employing polyalkylene oxides for nucleation in aqueous polymerization of fluoromonomer |
| EP2902424B1 (en) * | 2014-01-31 | 2020-04-08 | 3M Innovative Properties Company | Tetrafluoroethene polymer dispersions stabilized with aliphatic non-ionic surfactants |
| AR100953A1 (es) | 2014-02-19 | 2016-11-16 | Tenaris Connections Bv | Empalme roscado para una tubería de pozo de petróleo |
| CN104151566A (zh) * | 2014-07-11 | 2014-11-19 | 中昊晨光化工研究院有限公司 | 含氟聚合物浓缩分散液的制备方法 |
| CN104448348A (zh) * | 2014-12-11 | 2015-03-25 | 福建三农化学农药有限责任公司 | 一种ptfe乳液的浓缩方法 |
| EP3103836A1 (en) | 2015-06-12 | 2016-12-14 | 3M Innovative Properties Company | Fluoropolymer with improved transparency |
| WO2017011068A1 (en) | 2015-07-14 | 2017-01-19 | Evoqua Water Technologies Llc | Aeration device for filtration system |
| CN105294915B (zh) * | 2015-12-01 | 2018-04-03 | 上海三爱富新材料股份有限公司 | 透明乙烯‑四氟乙烯四元共聚物 |
| US11179886B2 (en) | 2016-01-21 | 2021-11-23 | 3M Innovative Properties Company | Additive processing of fluoropolymers |
| CN106582565A (zh) * | 2016-11-22 | 2017-04-26 | 西南交通大学 | 综合调控环境温湿度的复合吸附材料及其制备方法 |
| CN113717300B (zh) * | 2017-03-31 | 2023-11-17 | 大金工业株式会社 | 含氟聚合物的制造方法、聚合用表面活性剂和表面活性剂的使用 |
| WO2018229659A1 (en) | 2017-06-13 | 2018-12-20 | 3M Innovative Properties Company | Modified polytetrafluoroethylene and aqueous dispersion containing the same |
| DE202017003084U1 (de) | 2017-06-13 | 2017-09-19 | 3M Innovative Properties Company | Fluorpolymerdispersion |
| EP3655471A2 (en) | 2017-07-19 | 2020-05-27 | 3M Innovative Properties Company | Method of making polymer articles and polymer composites by additive processing and polymer and composite articles |
| SG11202000538PA (en) | 2017-07-19 | 2020-02-27 | 3M Innovative Properties Co | Additive processing of fluoropolymers |
| CN117986414A (zh) * | 2017-08-10 | 2024-05-07 | 大金工业株式会社 | 精制聚四氟乙烯水性分散液的制造方法、改性聚四氟乙烯粉末的制造方法、聚四氟乙烯成型体的制造方法以及组合物 |
| US11851519B2 (en) | 2017-08-10 | 2023-12-26 | Daikin Industries, Ltd. | Method for producing purified polytetrafluoroethylene aqueous dispersion liquid, method for producing modified polytetrafluoroethylene powder, method for producing polytetrafluoroethylene molded body, and composition |
| EP3527634A1 (en) | 2018-02-15 | 2019-08-21 | 3M Innovative Properties Company | Fluoropolymers and fluoropolymer dispersions |
| EP3765177A4 (en) * | 2018-03-15 | 2021-12-15 | Entegris, Inc. | FLUORINE FILTERING MEMBRANE, FILTERS AND PROCESSES |
| WO2019208707A1 (ja) * | 2018-04-27 | 2019-10-31 | Agc株式会社 | 変性ポリテトラフルオロエチレンの製造方法、変性ポリテトラフルオロエチレン粉末の製造方法、延伸多孔体の製造方法 |
| JP7277799B2 (ja) * | 2018-10-03 | 2023-05-19 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法 |
| CN109988322A (zh) * | 2019-02-21 | 2019-07-09 | 中国乐凯集团有限公司 | 水性含氟聚合物乳液、制备方法及其应用 |
| CN118146601A (zh) * | 2019-07-23 | 2024-06-07 | 大金工业株式会社 | 含氟聚合物的制造方法、聚四氟乙烯组合物和聚四氟乙烯粉末 |
| JP7586090B2 (ja) * | 2019-10-29 | 2024-11-19 | Agc株式会社 | ポリテトラフルオロエチレン水性分散液の製造方法 |
| WO2021229472A1 (en) * | 2020-05-14 | 2021-11-18 | 3M Innovative Properties Company | Method of reducing the perfluoroalkanoic acid content of fluoropolymer compositions |
| JP7311825B2 (ja) * | 2020-09-07 | 2023-07-20 | ダイキン工業株式会社 | 変性ポリテトラフルオロエチレン水性分散液 |
| CN113278332B (zh) * | 2021-04-27 | 2022-08-05 | 浙江吉利控股集团有限公司 | 一种甲醇发动机用气门油封涂装材料、气门油封及汽车 |
| CN116199905B (zh) * | 2022-11-11 | 2024-05-14 | 中昊晨光化工研究院有限公司 | 一种聚四氟乙烯浓缩分散液 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5679110A (en) * | 1979-11-30 | 1981-06-29 | Asahi Glass Co Ltd | Preparation of modified polytetrafluoroethylene |
| JPH04154842A (ja) * | 1990-10-19 | 1992-05-27 | Daikin Ind Ltd | ポリテトラフルオロエチレン微粒子および粉末 |
| WO2000002935A1 (fr) * | 1998-07-13 | 2000-01-20 | Daikin Industries, Ltd. | Fine poudre de polytetrafluoroethylene modifie et procede de fabrication |
| JP2002532583A (ja) * | 1998-12-11 | 2002-10-02 | ダイネオン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング・ウント・コンパニー・コマンディトゲゼルシャフト | フルオロポリマーの水性分散液 |
| JP2005501956A (ja) * | 2001-09-05 | 2005-01-20 | スリーエム イノベイティブ プロパティズ カンパニー | 低分子量フッ素化界面活性剤を全くまたは殆ど含まないフルオロポリマー分散 |
Family Cites Families (110)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2037953A (en) | 1930-08-08 | 1936-04-21 | Pure Oil Co | Method of converting hydrocarbon oils |
| US2434058A (en) | 1946-06-18 | 1948-01-06 | Walter J Stenzel | Rocking horse |
| GB642025A (en) | 1947-10-31 | 1950-08-23 | Du Pont | Electrodecantation of dilute suspensions |
| US2567011A (en) | 1949-01-10 | 1951-09-04 | Minnesota Mining & Mfg | Fluorocarbon acids and derivatives |
| US2732398A (en) | 1953-01-29 | 1956-01-24 | cafiicfzsojk | |
| US2965595A (en) | 1955-12-05 | 1960-12-20 | Du Pont | Process for polymerizing tetrafluoroethylene in the presence of polymerstabilizing agents |
| US2809990A (en) | 1955-12-29 | 1957-10-15 | Minnesota Mining & Mfg | Fluorocarbon acids and derivatives |
| US3142665A (en) | 1960-07-26 | 1964-07-28 | Du Pont | Novel tetrafluoroethylene resins and their preparation |
| US3037953A (en) | 1961-04-26 | 1962-06-05 | Du Pont | Concentration of aqueous colloidal dispersions of polytetrafluoroethylene |
| US3345317A (en) | 1963-04-04 | 1967-10-03 | Thiokol Chemical Corp | Emulsion polymerization of tetrafluoroethylene using trifluorotrichloroethane as emulsion stabilizer |
| GB1051175A (enExample) | 1963-05-27 | |||
| JPS4928026B1 (enExample) | 1965-01-12 | 1974-07-23 | ||
| US3489595A (en) | 1966-12-22 | 1970-01-13 | Du Pont | Coating compositions containing perfluorohalocarbon polymer,phosphoric acid and aluminum oxide,boron oxide or aluminum phosphate |
| JPS4611031Y1 (enExample) | 1967-06-15 | 1971-04-16 | ||
| US3642742A (en) | 1969-04-22 | 1972-02-15 | Du Pont | Tough stable tetrafluoroethylene-fluoroalkyl perfluorovinyl ether copolymers |
| US3635926A (en) | 1969-10-27 | 1972-01-18 | Du Pont | Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers |
| US3692569A (en) | 1970-02-12 | 1972-09-19 | Du Pont | Surface-activated fluorocarbon objects |
| GB1291936A (en) | 1970-11-19 | 1972-10-04 | Asahi Glass Co Ltd | Process for producing a copolymer of tetrafluoroethylene and propylene |
| US3876654A (en) | 1970-12-23 | 1975-04-08 | Du Pont | Fluoroelastomer composition |
| JPS497058B1 (enExample) | 1970-12-30 | 1974-02-18 | ||
| US4025481A (en) | 1971-01-28 | 1977-05-24 | Produits Chimiques Ugine Kuhlmann | Method for the preparation of aqueous dispersions of polytetrafluoroethylene with halogenated hydrocarbon as stabilizing agent |
| US4000356A (en) | 1972-06-19 | 1976-12-28 | Dynamit Nobel Aktiengesellschaft | Process for the preparation of thermoplastically workable fluoro-olefin polymers |
| US3855191A (en) | 1973-04-04 | 1974-12-17 | Du Pont | Polytetrafluoroethylene molding powders of tetrafluoroethylene and perfluoro (alkyl vinyl ether) copolymer |
| US4277586A (en) | 1974-11-20 | 1981-07-07 | Asahi Glass Company, Ltd. | Process for preparing a propylene-tetrafluoroethylene copolymer |
| US4035565A (en) | 1975-03-27 | 1977-07-12 | E. I. Du Pont De Nemours And Company | Fluoropolymer containing a small amount of bromine-containing olefin units |
| DE2523570C3 (de) | 1975-05-28 | 1978-12-07 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Polymerisation von Tetrafluoräthylen |
| US4029868A (en) | 1976-03-10 | 1977-06-14 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene terpolymers |
| JPS539848A (en) | 1976-07-16 | 1978-01-28 | Asahi Glass Co Ltd | Heat treatment of fluorine-containing elastomers |
| DE2639109A1 (de) | 1976-08-31 | 1978-03-09 | Hoechst Ag | Copolymerisate des tetrafluoraethylens und verfahren zu deren herstellung |
| JPS53125491A (en) | 1977-04-08 | 1978-11-01 | Daikin Ind Ltd | Fluorine-containing polymer easily curable and its curable composition |
| US4342675A (en) | 1978-06-16 | 1982-08-03 | E. I. Du Pont De Nemours And Company | Process for preparing aqueous dispersion of polytetrafluoroethylene |
| US4219910A (en) | 1979-01-05 | 1980-09-02 | American Cyanamid Company | Clamping device for sheet materials |
| DE2903981A1 (de) * | 1979-02-02 | 1980-08-07 | Hoechst Ag | Rueckgewinnung fluorierter emulgatorsaeuren aus basischen anionenaustauschern |
| US4233421A (en) | 1979-02-26 | 1980-11-11 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition containing sulfonium curing agents |
| DE2908001C2 (de) | 1979-03-01 | 1981-02-19 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung konzentrierter Dispersionen von Fluorpolymeren |
| US4353950A (en) | 1979-07-06 | 1982-10-12 | E. I. Du Pont De Nemours And Company | Stain-resistant cookware multi-layer coating system comprising pigments and a transluscent outer layer |
| DE2949907A1 (de) | 1979-12-12 | 1981-06-19 | Hoechst Ag, 6230 Frankfurt | Fluorpolymere mit schalenmodifizierten teilchen und verfahren zu deren herstellung |
| US4463144A (en) | 1980-09-10 | 1984-07-31 | Asahi Glass Company Ltd. | Process for producing propylene-tetrafluoroethylene copolymer |
| DE3135598A1 (de) | 1981-09-09 | 1983-03-17 | Hoechst Ag, 6000 Frankfurt | "kontinuierliches verfahren zur agglomerierung von ptee-pulvern im fluessigen medium und damit gewonnenes modifiziertes ptee-pulver" |
| JPS58174407A (ja) | 1982-03-08 | 1983-10-13 | Daikin Ind Ltd | 押出性の改良された含フツ素共重合体 |
| US4588796A (en) | 1984-04-23 | 1986-05-13 | E. I. Du Pont De Nemours And Company | Fluoroolefin polymerization process using fluoroxy compound solution as initiator |
| US4623487A (en) | 1985-03-14 | 1986-11-18 | E. I. Du Pont De Nemours & Company | Process for recovery of fluorosurfactants |
| DE3662142D1 (en) | 1985-03-28 | 1989-03-30 | Daikin Ind Ltd | Novel fluorovinyl ether and copolymer comprising the same |
| IT1187684B (it) | 1985-07-08 | 1987-12-23 | Montefluos Spa | Procedimento per la preparazione di fluoroelastomeri vulcanizzabili e prodotti cosi' ottenuti |
| JPS62260807A (ja) | 1986-05-07 | 1987-11-13 | Nippon Mektron Ltd | 含フッ素重合体の製造方法 |
| IT1204903B (it) * | 1986-06-26 | 1989-03-10 | Ausimont Spa | Processo di polimerizzazione in dispersione acquosa di monomeri florati |
| US5039389A (en) | 1986-12-19 | 1991-08-13 | The Dow Chemical Company | Membrane/electrode combination having interconnected roadways of catalytically active particles |
| US4940525A (en) | 1987-05-08 | 1990-07-10 | The Dow Chemical Company | Low equivalent weight sulfonic fluoropolymers |
| GB8728884D0 (en) | 1987-12-10 | 1988-01-27 | Ici Plc | Aqueous-based fluoropolymer compositions |
| US4861845A (en) | 1988-03-10 | 1989-08-29 | E. I. Du Pont De Nemours And Company | Polymerization of fluoroolefins |
| DE4124134A1 (de) | 1991-07-20 | 1993-01-21 | Hoechst Ag | Konzentrierte, waessrige dispersionen von tetrafluorethylen-polymeren, verfahren zu deren herstellung und deren verwendung |
| JP3198542B2 (ja) | 1991-07-24 | 2001-08-13 | ダイキン工業株式会社 | 変性ポリテトラフルオロエチレン被覆用組成物 |
| DE4213154C1 (enExample) | 1992-04-22 | 1993-06-17 | Hoechst Ag, 6230 Frankfurt, De | |
| US5453477A (en) | 1992-05-01 | 1995-09-26 | Alliedsignal Inc. | Process of polymerizing chloroetrifluoroethylene with alkyl hydroperoxide and metal metabisulfite |
| US5229480A (en) | 1992-09-03 | 1993-07-20 | E. I. Du Pont De Nemours And Company | Vinyl fluoride polymerization |
| BR9307793A (pt) | 1992-12-23 | 1995-11-21 | Du Pont | Composição aquosa de revestimento substratos revestidos e processo de revestimento de substrato |
| DE4305619A1 (de) | 1993-02-24 | 1994-08-25 | Hoechst Ag | Feinteilige Dispersionen von thermoplastischen Fluorpolymeren |
| US5285002A (en) * | 1993-03-23 | 1994-02-08 | Minnesota Mining And Manufacturing Company | Fluorine-containing polymers and preparation and use thereof |
| IT1271136B (it) | 1993-03-23 | 1997-05-27 | Ausimont Spa | Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati |
| IT1265067B1 (it) | 1993-05-18 | 1996-10-30 | Ausimont Spa | Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati |
| DE4402694A1 (de) | 1993-06-02 | 1995-08-03 | Hoechst Ag | Verfahren zur Rückgewinnung von fluorierten Carbonsäuren |
| US5608022A (en) | 1993-10-12 | 1997-03-04 | Asahi Kasei Kogyo Kabushiki Kaisha | Perfluorocarbon copolymer containing functional groups and a method for producing it |
| IT1271422B (it) * | 1993-10-15 | 1997-05-28 | Ausimont Spa | Procedimento per la preparazione di copolimeri del tetrafluoroetilene con altri monomeri perfluorurati |
| DE4335705A1 (de) | 1993-10-20 | 1995-04-27 | Hoechst Ag | Herstellung eines modifizierten Polytetrafluorethylens und seine Verwendung |
| DE4340943A1 (de) * | 1993-12-01 | 1995-06-08 | Hoechst Ag | Wäßrige Dispersion von Fluorpolymerisaten, ihre Herstellung und Verwendung für Beschichtungen |
| IT1265461B1 (it) | 1993-12-29 | 1996-11-22 | Ausimont Spa | Fluoroelastomeri comprendenti unita' monomeriche derivanti da una bis-olefina |
| JP2829706B2 (ja) | 1994-07-11 | 1998-12-02 | 三井・デュポンフロロケミカル株式会社 | フルオロポリマー水性エマルジョン及びその製造方法 |
| JP3298321B2 (ja) | 1994-08-31 | 2002-07-02 | ダイキン工業株式会社 | ビニリデンフルオライド系共重合体水性分散液、ビニリデンフルオライド系シード重合体水性分散液およびそれらの製法 |
| IT1270703B (it) | 1994-11-17 | 1997-05-07 | Ausimont Spa | Microemulsioni di fluoropoliossialchileni in miscela con idrocarburi, e loro uso in processi di (co)polimerizzazione di monomeri fluorurati |
| US5895799A (en) | 1995-01-18 | 1999-04-20 | W. L. Gore & Associates, Inc. | Microemulsion polymerization process for the production of small polytetrafluoroethylene polymer particles |
| US5478905A (en) | 1995-02-06 | 1995-12-26 | E. I. Du Pont De Nemours And Company | Amorphous tetrafluoroethylene/hexafluoropropylene copolymers |
| WO1996024622A1 (en) | 1995-02-10 | 1996-08-15 | Alliedsignal Inc. | Production of fluoropolymers, fluoropolymer suspension and polymer formed therefrom |
| EP0731081B1 (de) | 1995-03-09 | 1998-04-15 | Dyneon GmbH | Rückgewinnung hochfluorierter Carbonsäuren aus der Gasphase |
| JP3346090B2 (ja) | 1995-03-31 | 2002-11-18 | ダイキン工業株式会社 | ポリテトラフルオロエチレン水性分散液組成物及びその用途 |
| JP3626202B2 (ja) * | 1995-08-31 | 2005-03-02 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | 重合方法 |
| US5688884A (en) | 1995-08-31 | 1997-11-18 | E. I. Du Pont De Nemours And Company | Polymerization process |
| IT1276072B1 (it) | 1995-10-31 | 1997-10-24 | Ausimont Spa | Processo di (co)polimerizzazione di monomeri fluorurati per ottenere polimeri contenenti idrogeno |
| US5955556A (en) | 1995-11-06 | 1999-09-21 | Alliedsignal Inc. | Method of manufacturing fluoropolymers |
| JPH108041A (ja) | 1996-06-21 | 1998-01-13 | Daikin Ind Ltd | 水分散型フッ素系撥水撥油剤 |
| IT1295535B1 (it) | 1996-07-01 | 1999-05-12 | Ausimont Spa | Processo di polimerizzazione di vinilidenfluoruro (vdf) |
| US5763552A (en) | 1996-07-26 | 1998-06-09 | E. I. Du Pont De Nemours And Company | Hydrogen-containing flourosurfacant and its use in polymerization |
| US5936060A (en) * | 1996-11-25 | 1999-08-10 | E. I. Du Pont De Nemours And Company | Perfluoroelastomer composition having improved processability |
| IT1290428B1 (it) | 1997-03-21 | 1998-12-03 | Ausimont Spa | Grassi fluorurati |
| US6403740B1 (en) * | 1997-04-15 | 2002-06-11 | E. I. Du Pont De Nemours And Company | Vinyl fluoride interpolymers |
| DE19726802C1 (de) | 1997-06-24 | 1998-06-10 | Dyneon Gmbh | Wäßrige Dispersion von Fluorpolymeren unterschiedlicher Teilchengröße |
| DE19824615A1 (de) | 1998-06-02 | 1999-12-09 | Dyneon Gmbh | Verfahren zur Rückgewinnung von fluorierten Alkansäuren aus Abwässern |
| DE19824614A1 (de) | 1998-06-02 | 1999-12-09 | Dyneon Gmbh | Verfahren zur Rückgewinnung von fluorierten Alkansäuren aus Abwässern |
| US6103844A (en) | 1998-06-08 | 2000-08-15 | E. I. Du Pont De Nemours And Company | Polymerization of fluoromonomers in carbon dioxide |
| ITMI981519A1 (it) | 1998-07-02 | 2000-01-02 | Ausimont Spa | Processodi polimerizzazione del tfe |
| ITMI981520A1 (it) | 1998-07-02 | 2000-01-02 | Ausimont Spa | Dispersioni di fluoropolimeri |
| CN1215085C (zh) * | 1998-10-13 | 2005-08-17 | 大金工业株式会社 | 含氟聚合物的制造方法 |
| WO2000032655A1 (en) | 1998-11-30 | 2000-06-08 | E.I. Du Pont De Nemours And Company | Fluoromonomer polymerization |
| WO2000047641A1 (en) | 1999-02-15 | 2000-08-17 | Daikin Industries, Ltd. | Process for producing fluoropolymer |
| US6395848B1 (en) * | 1999-05-20 | 2002-05-28 | E. I. Du Pont De Nemours And Company | Polymerization of fluoromonomers |
| US6429258B1 (en) | 1999-05-20 | 2002-08-06 | E. I. Du Pont De Nemours & Company | Polymerization of fluoromonomers |
| ITMI991269A1 (it) | 1999-06-08 | 2000-12-08 | Ausimont Spa | Miscele di dispersioni di fluoropolimeri |
| ITMI991516A1 (it) | 1999-07-09 | 2001-01-09 | Ausimont Spa | Sintesi dei copolimeri peralogenati termoprocesabili del clorotrifluoroetilene |
| DE19932771A1 (de) | 1999-07-14 | 2001-01-18 | Dyneon Gmbh | Verfahren zur Eluierung fluorierter Emulgatoren |
| DE19933696A1 (de) | 1999-07-17 | 2001-01-18 | Dyneon Gmbh | Verfahren zur Rückgewinnung fluorierter Emulgatoren aus wässrigen Phasen |
| DE10018853C2 (de) | 2000-04-14 | 2002-07-18 | Dyneon Gmbh | Herstellung wässriger Dispersionen von Fluorpolymeren |
| US6720437B2 (en) | 2001-02-07 | 2004-04-13 | E. I. Du Pont De Nemours And Company | Fluorinated carboxylic acid recovery and reuse |
| EP1377617B1 (en) | 2001-03-13 | 2004-10-06 | E.I. Dupont De Nemours And Company | High build dispersions |
| US6761964B2 (en) | 2001-04-02 | 2004-07-13 | E. I. Du Pont De Nemours And Company | Fluoropolymer non-stick coatings |
| CA2445998A1 (en) | 2001-05-02 | 2002-11-07 | 3M Innovative Properties Company | Emulsifier free aqueous emulsion polymerization process for making fluoropolymers |
| ITMI20012744A1 (it) | 2001-12-21 | 2003-06-21 | Ausimont Spa | Processo di polimerizzazione di monomeri solfonici |
| CN1315898C (zh) * | 2002-01-04 | 2007-05-16 | 纳幕尔杜邦公司 | 芯-壳含氟聚合物分散体 |
| JP4207442B2 (ja) | 2002-03-20 | 2009-01-14 | 旭硝子株式会社 | ポリテトラフルオロエチレン水性分散液組成物の製造方法 |
| EP1364972B1 (en) | 2002-05-22 | 2006-08-30 | 3M Innovative Properties Company | Process for reducing the amount of fluorinated surfactant in aqueous fluoropolymer dispersions |
| JP2006504844A (ja) | 2002-10-31 | 2006-02-09 | スリーエム イノベイティブ プロパティズ カンパニー | フッ化オレフィンと炭化水素オレフィンとのコポリマーを製造するための、乳化剤非含有水性乳化重合 |
| EP1533325B1 (en) | 2003-11-17 | 2011-10-19 | 3M Innovative Properties Company | Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant |
-
2003
- 2003-11-17 EP EP03078598A patent/EP1533325B1/en not_active Expired - Lifetime
- 2003-11-17 AT AT03078598T patent/ATE529451T1/de not_active IP Right Cessation
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2004
- 2004-10-12 US US10/962,633 patent/US7041728B2/en not_active Expired - Fee Related
- 2004-10-12 CN CNB2004800337683A patent/CN100509874C/zh not_active Expired - Fee Related
- 2004-10-12 RU RU2006116761/04A patent/RU2006116761A/ru not_active Application Discontinuation
- 2004-10-12 JP JP2006541153A patent/JP4829122B2/ja not_active Expired - Fee Related
- 2004-10-12 WO PCT/US2004/033478 patent/WO2005052013A1/en not_active Ceased
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5679110A (en) * | 1979-11-30 | 1981-06-29 | Asahi Glass Co Ltd | Preparation of modified polytetrafluoroethylene |
| JPH04154842A (ja) * | 1990-10-19 | 1992-05-27 | Daikin Ind Ltd | ポリテトラフルオロエチレン微粒子および粉末 |
| WO2000002935A1 (fr) * | 1998-07-13 | 2000-01-20 | Daikin Industries, Ltd. | Fine poudre de polytetrafluoroethylene modifie et procede de fabrication |
| JP2002532583A (ja) * | 1998-12-11 | 2002-10-02 | ダイネオン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング・ウント・コンパニー・コマンディトゲゼルシャフト | フルオロポリマーの水性分散液 |
| JP2005501956A (ja) * | 2001-09-05 | 2005-01-20 | スリーエム イノベイティブ プロパティズ カンパニー | 低分子量フッ素化界面活性剤を全くまたは殆ど含まないフルオロポリマー分散 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20050107518A1 (en) | 2005-05-19 |
| US7294668B2 (en) | 2007-11-13 |
| JP2007511657A (ja) | 2007-05-10 |
| US20060128872A1 (en) | 2006-06-15 |
| EP1533325A1 (en) | 2005-05-25 |
| US7041728B2 (en) | 2006-05-09 |
| CN1882617A (zh) | 2006-12-20 |
| ATE529451T1 (de) | 2011-11-15 |
| CN100509874C (zh) | 2009-07-08 |
| RU2006116761A (ru) | 2007-12-27 |
| WO2005052013A1 (en) | 2005-06-09 |
| EP1533325B1 (en) | 2011-10-19 |
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