JP4825207B2 - ビニルアルコールとイタコン酸のコポリマー、及びその使用 - Google Patents
ビニルアルコールとイタコン酸のコポリマー、及びその使用 Download PDFInfo
- Publication number
- JP4825207B2 JP4825207B2 JP2007525796A JP2007525796A JP4825207B2 JP 4825207 B2 JP4825207 B2 JP 4825207B2 JP 2007525796 A JP2007525796 A JP 2007525796A JP 2007525796 A JP2007525796 A JP 2007525796A JP 4825207 B2 JP4825207 B2 JP 4825207B2
- Authority
- JP
- Japan
- Prior art keywords
- mol
- itaconic acid
- less
- present
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 title claims description 46
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 title claims description 35
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 title claims description 12
- 229920001577 copolymer Polymers 0.000 title description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 229920001897 terpolymer Polymers 0.000 claims description 24
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 20
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 15
- 150000002596 lactones Chemical class 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 8
- 239000012459 cleaning agent Substances 0.000 claims description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 37
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 30
- 229920002451 polyvinyl alcohol Polymers 0.000 description 26
- 239000004372 Polyvinyl alcohol Substances 0.000 description 25
- 229920000642 polymer Polymers 0.000 description 14
- 239000003599 detergent Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 229920002689 polyvinyl acetate Polymers 0.000 description 7
- 239000011118 polyvinyl acetate Substances 0.000 description 7
- 230000007062 hydrolysis Effects 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 150000007942 carboxylates Chemical class 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 238000005809 transesterification reaction Methods 0.000 description 4
- 238000009463 water soluble packaging Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000005022 packaging material Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- -1 i.e. Substances 0.000 description 2
- 238000007273 lactonization reaction Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 238000010669 acid-base reaction Methods 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000010816 packaging waste Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
- C08F216/04—Acyclic compounds
- C08F216/06—Polyvinyl alcohol ; Vinyl alcohol
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Wrappers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Bag Frames (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60048304P | 2004-08-10 | 2004-08-10 | |
| US60/600,483 | 2004-08-10 | ||
| PCT/US2005/028583 WO2006020785A1 (en) | 2004-08-10 | 2005-08-10 | Copolymers of vinyl alcohol and itaconic acid and uses thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008510039A JP2008510039A (ja) | 2008-04-03 |
| JP2008510039A5 JP2008510039A5 (https=) | 2008-09-25 |
| JP4825207B2 true JP4825207B2 (ja) | 2011-11-30 |
Family
ID=35466059
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007525796A Expired - Fee Related JP4825207B2 (ja) | 2004-08-10 | 2005-08-10 | ビニルアルコールとイタコン酸のコポリマー、及びその使用 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7767282B2 (https=) |
| EP (1) | EP1786845B1 (https=) |
| JP (1) | JP4825207B2 (https=) |
| CN (1) | CN101023109B (https=) |
| WO (1) | WO2006020785A1 (https=) |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE602004031257D1 (https=) * | 2003-12-15 | 2011-03-10 | Du Pont | |
| ES2580152T3 (es) * | 2006-05-01 | 2016-08-19 | Monosol, Llc | Composición resistente a halógenos |
| US7913759B2 (en) * | 2008-09-29 | 2011-03-29 | E. I. Du Pont De Nemours And Company | Method for enhanced recovery of oil from oil reservoirs |
| US20180163325A1 (en) | 2016-12-09 | 2018-06-14 | Robert Wayne Glenn, Jr. | Dissolvable fibrous web structure article comprising active agents |
| CN103025930B (zh) | 2010-07-02 | 2014-11-12 | 宝洁公司 | 递送活性剂的方法 |
| BR112013000101A2 (pt) | 2010-07-02 | 2016-05-17 | Procter & Gamble | filamentos compreendendo mantas de não tecido com agente ativo e métodos de fabricação dos mesmos |
| CN102971126B (zh) | 2010-07-02 | 2016-03-23 | 宝洁公司 | 由非织造纤维网制备膜的方法 |
| MX345025B (es) | 2010-07-02 | 2017-01-12 | Procter & Gamble | Producto detergente. |
| WO2012087821A1 (en) * | 2010-12-22 | 2012-06-28 | Sekisui Specialty Chemicals America, Llc | Cold water soluble polyvinyl alcohol/alkyl acrylate copolymers and films thereof |
| US10808210B2 (en) * | 2013-03-15 | 2020-10-20 | Monosol, Llc | Water-soluble film for delayed release |
| KR101820677B1 (ko) | 2016-01-14 | 2018-01-22 | 욱성화학주식회사 | 생분해성 고흡수성 폴리비닐알코올-그라프트-폴리이타콘산 그라프트 공중합체 및 그의 제조방법 |
| RU2760028C2 (ru) | 2016-04-13 | 2021-11-22 | МОНОСОЛ, ЭлЭлСи | Водорастворимая пленка, пакеты из пленки и способы их получения и применения |
| WO2017218414A1 (en) | 2016-06-13 | 2017-12-21 | Monosol, Llc | Use of a first film and a second film to improve seal strength of a water-soluble |
| CN109311574A (zh) | 2016-06-13 | 2019-02-05 | 蒙诺苏尔有限公司 | 水溶性小包装 |
| HUE068143T2 (hu) | 2016-06-13 | 2024-12-28 | Procter & Gamble | Különbözõ filmek kombinációjából készült, vízoldható, háztartási tisztítókészítményeket tartalmazó egyadagos termékek |
| WO2017218443A1 (en) | 2016-06-13 | 2017-12-21 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| US10479965B2 (en) | 2016-06-13 | 2019-11-19 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| WO2017218408A1 (en) | 2016-06-13 | 2017-12-21 | Monosol, Llc | Water-soluble unit dose articles made from a combination of different films |
| MX380853B (es) | 2017-01-27 | 2025-03-12 | Procter & Gamble | Composiciones en la forma de estructuras solidas solubles |
| PL3676360T3 (pl) * | 2017-08-30 | 2022-01-24 | Dow Global Technologies Llc | Kompozycja do automatycznego mycia naczyń z polimerem dyspergującym |
| US11142730B2 (en) | 2018-01-26 | 2021-10-12 | The Procter & Gamble Company | Water-soluble articles and related processes |
| US20190233785A1 (en) | 2018-01-26 | 2019-08-01 | The Procter & Gamble Company | Water-soluble unit dose articles comprising perfume |
| CN111556891B (zh) | 2018-01-26 | 2021-11-05 | 宝洁公司 | 包含酶的水溶性单位剂量制品 |
| US11053466B2 (en) | 2018-01-26 | 2021-07-06 | The Procter & Gamble Company | Water-soluble unit dose articles comprising perfume |
| WO2019168829A1 (en) | 2018-02-27 | 2019-09-06 | The Procter & Gamble Company | A consumer product comprising a flat package containing unit dose articles |
| US10982176B2 (en) | 2018-07-27 | 2021-04-20 | The Procter & Gamble Company | Process of laundering fabrics using a water-soluble unit dose article |
| US12234431B2 (en) | 2018-10-03 | 2025-02-25 | The Procter & Gamble Company | Water-soluble unit dose articles comprising water-soluble fibrous structures and particles |
| WO2020159860A1 (en) | 2019-01-28 | 2020-08-06 | The Procter & Gamble Company | Recycleable, renewable, or biodegradable package |
| JP7513623B2 (ja) | 2019-03-19 | 2024-07-09 | ザ プロクター アンド ギャンブル カンパニー | 布地上の悪臭を低減する方法 |
| EP3712237A1 (en) | 2019-03-19 | 2020-09-23 | The Procter & Gamble Company | Fibrous water-soluble unit dose articles comprising water-soluble fibrous structures |
| CN114206307B (zh) | 2019-06-28 | 2024-08-23 | 宝洁公司 | 包含阴离子表面活性剂的可溶性固体纤维制品 |
| MX2023001042A (es) | 2020-07-31 | 2023-02-16 | Procter & Gamble | Bolsa fibrosa soluble en agua que contiene granulos para el cuidado del cabello. |
| JP7605842B2 (ja) | 2020-08-19 | 2024-12-24 | ザ プロクター アンド ギャンブル カンパニー | 直接添加マイクロカプセルを含有する可撓性多孔質溶解性固体シート物品及びそれを作製するための方法 |
| WO2023034763A1 (en) | 2021-08-30 | 2023-03-09 | The Procter & Gamble Company | Dissolvable solid structure comprising first and second polymeric structurants |
| CN116003670B (zh) * | 2021-10-21 | 2024-07-23 | 中国石油化工股份有限公司 | 有机碱在改善聚乙烯醇成型性中的应用 |
| MX2024005474A (es) | 2021-12-17 | 2024-05-22 | Procter & Gamble | Articulos de champu fibroso solido disoluble que contienen sales. |
| MX2024010903A (es) | 2022-03-10 | 2024-09-17 | Procter & Gamble | Estructura solida disoluble que tiene primera y segunda capas. |
| EP4296342B1 (en) * | 2022-06-22 | 2024-10-23 | The Procter & Gamble Company | Household cleaning composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0359059A (ja) * | 1989-07-28 | 1991-03-14 | Lion Corp | 洗剤包装用フィルム |
| JPH0688004A (ja) * | 1992-09-07 | 1994-03-29 | Kao Corp | ポリビニルアルコール系フィルム |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1143974A (en) | 1965-04-27 | 1969-02-26 | Kurashiki Rayon Kk | Binder for pigment coating consisting of polyvinyl alcohol derivative containing carboxyl group |
| JPS57117697A (en) | 1981-01-09 | 1982-07-22 | Nippon Synthetic Chem Ind | Paper treatment |
| JPH0234371B2 (ja) | 1981-11-10 | 1990-08-02 | Fuji Photo Film Co Ltd | Shashiningashoshijitai |
| US4747976A (en) * | 1987-05-14 | 1988-05-31 | The Clorox Company | PVA films with nonhydrolyzable anionic comonomers for packaging detergents |
| US4885105A (en) | 1987-05-14 | 1989-12-05 | The Clorox Company | Films from PVA modified with nonhydrolyzable anionic comonomers |
| JP2849401B2 (ja) | 1989-06-22 | 1999-01-20 | 株式会社クラレ | 無機質繊維板の製造方法 |
| JPH03234754A (ja) | 1990-02-08 | 1991-10-18 | Kuraray Co Ltd | 組成物および紙用コーテイング剤 |
| US5057570A (en) | 1990-06-13 | 1991-10-15 | Air Products And Chemicals, Inc. | Polyvinyl alcohol resin soluble in high solids aqueous paper coating compositions without exernal heating |
| EP0656054A2 (en) | 1992-08-20 | 1995-06-07 | Kao Corp | ALIQUOTE PACKAGING DETERGENT USING A WATER-SOLUBLE FILM. |
| JP3228564B2 (ja) | 1992-08-20 | 2001-11-12 | 花王株式会社 | ポリビニルアルコール組成物及びそれを用いてなるフィルム |
| US5387638A (en) | 1992-09-07 | 1995-02-07 | Kuraray Co., Ltd. | Emulsion composition |
| TW285695B (https=) * | 1993-08-20 | 1996-09-11 | Kuraray Co | |
| US5612412A (en) * | 1994-09-30 | 1997-03-18 | Daicel Chemical Industries, Ltd. | Lactone-modified polyvinyl alcohol, a process for the preparation thereof |
| JP2649023B2 (ja) | 1995-03-27 | 1997-09-03 | 日本合成化学工業株式会社 | ポリビニルアルコール系ポリマーおよびその製造法 |
| US7022656B2 (en) | 2003-03-19 | 2006-04-04 | Monosol, Llc. | Water-soluble copolymer film packet |
| DE602004031257D1 (https=) | 2003-12-15 | 2011-03-10 | Du Pont |
-
2005
- 2005-08-09 US US11/199,881 patent/US7767282B2/en not_active Expired - Fee Related
- 2005-08-10 JP JP2007525796A patent/JP4825207B2/ja not_active Expired - Fee Related
- 2005-08-10 CN CN200580027228.9A patent/CN101023109B/zh not_active Expired - Fee Related
- 2005-08-10 EP EP05792828A patent/EP1786845B1/en not_active Ceased
- 2005-08-10 WO PCT/US2005/028583 patent/WO2006020785A1/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0359059A (ja) * | 1989-07-28 | 1991-03-14 | Lion Corp | 洗剤包装用フィルム |
| JPH0688004A (ja) * | 1992-09-07 | 1994-03-29 | Kao Corp | ポリビニルアルコール系フィルム |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1786845B1 (en) | 2012-11-14 |
| US20060035042A1 (en) | 2006-02-16 |
| EP1786845A1 (en) | 2007-05-23 |
| CN101023109A (zh) | 2007-08-22 |
| WO2006020785A1 (en) | 2006-02-23 |
| US7767282B2 (en) | 2010-08-03 |
| CN101023109B (zh) | 2010-06-23 |
| JP2008510039A (ja) | 2008-04-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4825207B2 (ja) | ビニルアルコールとイタコン酸のコポリマー、及びその使用 | |
| US7642226B2 (en) | Polyvinyl alcohol copolymer film for packaging liquid products and having an improved shelf-life | |
| US6166117A (en) | Water-soluble film | |
| JP5629056B2 (ja) | 耐ホウ酸塩フィルム | |
| JP5851948B2 (ja) | 水性分散液および溶融押出成形品に使用するビニルアルコールコポリマー | |
| JP4338117B2 (ja) | アルカリ性物質包装用ポリビニルアルコール系フィルム | |
| CN101910214B (zh) | 乙烯醇系聚合物及含有其的膜 | |
| JP2005179390A (ja) | 水溶性フィルム | |
| US20160369072A1 (en) | Water-soluble film for packaging chemicals and water-soluble film package | |
| JP3609894B2 (ja) | ホウ酸系物質包装用フィルム | |
| JPS63168437A (ja) | アルカリ性物質包装用のポリビニルアルコ−ルフイルム | |
| JPH09272773A (ja) | 水溶性のフィルム | |
| JP2006063242A (ja) | フィルム | |
| JP4311806B2 (ja) | ガスバリア性フィルムおよびその製造方法 | |
| EP1694918B1 (en) | Terpolymers for use in paper coatings | |
| JP2001247625A (ja) | ビニルアルコール系重合体およびこれを使用した冷水易溶性フィルム | |
| NO161860B (no) | Fremgangsmaate til fremstilling av et smelteklebestoff paa basis av polyvinylalkohol. | |
| JP4346714B2 (ja) | 積層フィルム | |
| JPH11279210A (ja) | 低温粘度安定性の優れたポリビニルアルコールの製造方法 | |
| TWI338697B (en) | Process for the preparation of low shear-thinning polyvinyl acetals | |
| JP7365806B2 (ja) | 接着剤 | |
| JPS62179550A (ja) | 冷水易溶性フイルム | |
| JPH0517597A (ja) | 冷水易溶性フイルム | |
| JPH05155919A (ja) | 末端イオン変性エチレン−ビニルアルコール系共重合体およびその水性分散液 | |
| JP4540807B2 (ja) | ポリビニルアルコール系水溶性フィルム |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080808 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080808 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110426 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110509 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110809 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20110905 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20110909 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4825207 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140916 Year of fee payment: 3 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| LAPS | Cancellation because of no payment of annual fees |