JP4825207B2 - ビニルアルコールとイタコン酸のコポリマー、及びその使用 - Google Patents
ビニルアルコールとイタコン酸のコポリマー、及びその使用 Download PDFInfo
- Publication number
- JP4825207B2 JP4825207B2 JP2007525796A JP2007525796A JP4825207B2 JP 4825207 B2 JP4825207 B2 JP 4825207B2 JP 2007525796 A JP2007525796 A JP 2007525796A JP 2007525796 A JP2007525796 A JP 2007525796A JP 4825207 B2 JP4825207 B2 JP 4825207B2
- Authority
- JP
- Japan
- Prior art keywords
- mol
- itaconic acid
- less
- present
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 title claims description 46
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 title claims description 35
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 title claims description 12
- 229920001577 copolymer Polymers 0.000 title description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 229920001897 terpolymer Polymers 0.000 claims description 24
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 20
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 15
- 150000002596 lactones Chemical class 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 8
- 239000012459 cleaning agent Substances 0.000 claims description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 37
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 30
- 229920002451 polyvinyl alcohol Polymers 0.000 description 26
- 239000004372 Polyvinyl alcohol Substances 0.000 description 25
- 229920000642 polymer Polymers 0.000 description 14
- 239000003599 detergent Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 229920002689 polyvinyl acetate Polymers 0.000 description 7
- 239000011118 polyvinyl acetate Substances 0.000 description 7
- 230000007062 hydrolysis Effects 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 150000007942 carboxylates Chemical class 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 238000005809 transesterification reaction Methods 0.000 description 4
- 238000009463 water soluble packaging Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000005022 packaging material Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- -1 i.e. Substances 0.000 description 2
- 238000007273 lactonization reaction Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920013683 Celanese Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 238000010669 acid-base reaction Methods 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000010816 packaging waste Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
- C08F216/04—Acyclic compounds
- C08F216/06—Polyvinyl alcohol ; Vinyl alcohol
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Wrappers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Bag Frames (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60048304P | 2004-08-10 | 2004-08-10 | |
| US60/600,483 | 2004-08-10 | ||
| PCT/US2005/028583 WO2006020785A1 (en) | 2004-08-10 | 2005-08-10 | Copolymers of vinyl alcohol and itaconic acid and uses thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008510039A JP2008510039A (ja) | 2008-04-03 |
| JP2008510039A5 JP2008510039A5 (enExample) | 2008-09-25 |
| JP4825207B2 true JP4825207B2 (ja) | 2011-11-30 |
Family
ID=35466059
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007525796A Expired - Fee Related JP4825207B2 (ja) | 2004-08-10 | 2005-08-10 | ビニルアルコールとイタコン酸のコポリマー、及びその使用 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7767282B2 (enExample) |
| EP (1) | EP1786845B1 (enExample) |
| JP (1) | JP4825207B2 (enExample) |
| CN (1) | CN101023109B (enExample) |
| WO (1) | WO2006020785A1 (enExample) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2273010B1 (en) | 2003-12-15 | 2018-07-04 | Kuraray America Inc. | Paper coating composition |
| JP5532477B2 (ja) * | 2006-05-01 | 2014-06-25 | モノソル リミテッド ライアビリティ カンパニー | ハロゲン抵抗性組成物 |
| US7913759B2 (en) * | 2008-09-29 | 2011-03-29 | E. I. Du Pont De Nemours And Company | Method for enhanced recovery of oil from oil reservoirs |
| JP5859526B2 (ja) | 2010-07-02 | 2016-02-10 | ザ プロクター アンド ギャンブルカンパニー | 活性剤不織布ウェブを含むフィラメント及びその製造方法 |
| US20180163325A1 (en) | 2016-12-09 | 2018-06-14 | Robert Wayne Glenn, Jr. | Dissolvable fibrous web structure article comprising active agents |
| RU2607747C1 (ru) | 2010-07-02 | 2017-01-10 | Дзе Проктер Энд Гэмбл Компани | Способ получения пленок из нетканых полотен |
| MX382405B (es) | 2010-07-02 | 2025-03-13 | Procter & Gamble | Método para suministrar un agente activo. |
| EP3533908B1 (en) | 2010-07-02 | 2026-07-01 | The Procter & Gamble Company | NONWOVEN FABRIC COMPRISING ONE OR MORE ACTIVE AGENTS |
| JP5931088B2 (ja) * | 2010-12-22 | 2016-06-08 | セキスイ・スペシャルティ・ケミカルズ・アメリカ・エルエルシー | 冷水可溶性ポリビニルアルコール／アルキルアクリレートコポリマーおよびそれらのフィルム |
| US10808210B2 (en) * | 2013-03-15 | 2020-10-20 | Monosol, Llc | Water-soluble film for delayed release |
| KR101820677B1 (ko) | 2016-01-14 | 2018-01-22 | 욱성화학주식회사 | 생분해성 고흡수성 폴리비닐알코올-그라프트-폴리이타콘산 그라프트 공중합체 및 그의 제조방법 |
| EP3443030B1 (en) | 2016-04-13 | 2022-05-11 | Monosol, LLC | Water soluble film, packets employing the film, and methods of making and using same |
| EP3468888A1 (en) | 2016-06-13 | 2019-04-17 | Monosol, LLC | Water-soluble packets |
| EP4406873A3 (en) | 2016-06-13 | 2024-10-30 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| WO2017218408A1 (en) | 2016-06-13 | 2017-12-21 | Monosol, Llc | Water-soluble unit dose articles made from a combination of different films |
| JP6790126B2 (ja) | 2016-06-13 | 2020-11-25 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 異なるフィルムの組み合わせから製造され、家庭用ケア組成物を含有する、水溶性単位用量物品 |
| CN109312277B (zh) | 2016-06-13 | 2021-10-15 | 蒙诺苏尔有限公司 | 提高水溶性单位剂量制品的密封强度的第一薄膜和第二薄膜的用途 |
| CA3023508A1 (en) | 2016-06-13 | 2017-12-21 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| CN110191700A (zh) | 2017-01-27 | 2019-08-30 | 宝洁公司 | 可溶性固体结构形式的组合物 |
| WO2019045938A1 (en) * | 2017-08-30 | 2019-03-07 | Dow Global Technologies Llc | AUTOMATIC WASHING COMPOSITION OF THE DISHWASHER WITH A DISPERSING POLYMER |
| WO2019147532A1 (en) | 2018-01-26 | 2019-08-01 | The Procter & Gamble Company | Water-soluble unit dose articles comprising perfume |
| KR20200086739A (ko) | 2018-01-26 | 2020-07-17 | 더 프록터 앤드 갬블 캄파니 | 효소를 포함하는 수용성 단위 용량 물품 |
| US20190233785A1 (en) | 2018-01-26 | 2019-08-01 | The Procter & Gamble Company | Water-soluble unit dose articles comprising perfume |
| KR102433420B1 (ko) | 2018-01-26 | 2022-08-18 | 더 프록터 앤드 갬블 캄파니 | 수용성 물품 및 관련 방법 |
| WO2019168829A1 (en) | 2018-02-27 | 2019-09-06 | The Procter & Gamble Company | A consumer product comprising a flat package containing unit dose articles |
| US10982176B2 (en) | 2018-07-27 | 2021-04-20 | The Procter & Gamble Company | Process of laundering fabrics using a water-soluble unit dose article |
| US12234431B2 (en) | 2018-10-03 | 2025-02-25 | The Procter & Gamble Company | Water-soluble unit dose articles comprising water-soluble fibrous structures and particles |
| WO2020159860A1 (en) | 2019-01-28 | 2020-08-06 | The Procter & Gamble Company | Recycleable, renewable, or biodegradable package |
| EP3942010A1 (en) | 2019-03-19 | 2022-01-26 | The Procter & Gamble Company | Process of laundering fabrics |
| WO2020191166A1 (en) | 2019-03-19 | 2020-09-24 | The Procter & Gamble Company | Process of reducing malodors on fabrics |
| EP3712237A1 (en) | 2019-03-19 | 2020-09-23 | The Procter & Gamble Company | Fibrous water-soluble unit dose articles comprising water-soluble fibrous structures |
| JP7381613B2 (ja) | 2019-06-28 | 2023-11-15 | ザ プロクター アンド ギャンブル カンパニー | アニオン性界面活性剤を含有する溶解性固体繊維性物品 |
| WO2022027067A1 (en) | 2020-07-31 | 2022-02-03 | The Procter & Gamble Company | Water-soluble fibrous pouch containing prills for hair care |
| CN114867834A (zh) | 2020-08-19 | 2022-08-05 | 宝洁公司 | 含有直接添加的微胶囊的柔性多孔可溶性固体片材制品及其制备方法 |
| EP4395730A1 (en) | 2021-08-30 | 2024-07-10 | The Procter & Gamble Company | Dissolvable solid structure comprising first and second polymeric structurants |
| CN116003670B (zh) * | 2021-10-21 | 2024-07-23 | 中国石油化工股份有限公司 | 有机碱在改善聚乙烯醇成型性中的应用 |
| US12576013B2 (en) | 2021-12-17 | 2026-03-17 | The Procter & Gamble Company | Dissolvable solid fibrous shampoo articles containing salts |
| US12540238B2 (en) | 2022-03-10 | 2026-02-03 | The Procter & Gamble Company | Dissolvable solid structure having first and second layers |
| EP4296342B1 (en) | 2022-06-22 | 2024-10-23 | The Procter & Gamble Company | Household cleaning composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0359059A (ja) * | 1989-07-28 | 1991-03-14 | Lion Corp | 洗剤包装用フィルム |
| JPH0688004A (ja) * | 1992-09-07 | 1994-03-29 | Kao Corp | ポリビニルアルコール系フィルム |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1696221C3 (de) | 1965-04-27 | 1974-02-14 | Kuraray Co., Ltd., Kurashiki, Okayama (Japan) | Bindemittel für Papierstreichmassen auf Polyvinylalkohol-B3 747t |
| JPS57117697A (en) | 1981-01-09 | 1982-07-22 | Nippon Synthetic Chem Ind | Paper treatment |
| JPH0234371B2 (ja) | 1981-11-10 | 1990-08-02 | Fuji Photo Film Co Ltd | Shashiningashoshijitai |
| US4747976A (en) * | 1987-05-14 | 1988-05-31 | The Clorox Company | PVA films with nonhydrolyzable anionic comonomers for packaging detergents |
| US4885105A (en) | 1987-05-14 | 1989-12-05 | The Clorox Company | Films from PVA modified with nonhydrolyzable anionic comonomers |
| JP2849401B2 (ja) | 1989-06-22 | 1999-01-20 | 株式会社クラレ | 無機質繊維板の製造方法 |
| JPH03234754A (ja) | 1990-02-08 | 1991-10-18 | Kuraray Co Ltd | 組成物および紙用コーテイング剤 |
| US5057570A (en) * | 1990-06-13 | 1991-10-15 | Air Products And Chemicals, Inc. | Polyvinyl alcohol resin soluble in high solids aqueous paper coating compositions without exernal heating |
| JP3228564B2 (ja) | 1992-08-20 | 2001-11-12 | 花王株式会社 | ポリビニルアルコール組成物及びそれを用いてなるフィルム |
| EP0656054A2 (en) | 1992-08-20 | 1995-06-07 | Kao Corp | ALIQUOTE PACKAGING DETERGENT USING A WATER-SOLUBLE FILM. |
| US5387638A (en) | 1992-09-07 | 1995-02-07 | Kuraray Co., Ltd. | Emulsion composition |
| TW285695B (enExample) * | 1993-08-20 | 1996-09-11 | Kuraray Co | |
| US5612412A (en) * | 1994-09-30 | 1997-03-18 | Daicel Chemical Industries, Ltd. | Lactone-modified polyvinyl alcohol, a process for the preparation thereof |
| JP2649023B2 (ja) | 1995-03-27 | 1997-09-03 | 日本合成化学工業株式会社 | ポリビニルアルコール系ポリマーおよびその製造法 |
| US7022656B2 (en) * | 2003-03-19 | 2006-04-04 | Monosol, Llc. | Water-soluble copolymer film packet |
| EP2273010B1 (en) * | 2003-12-15 | 2018-07-04 | Kuraray America Inc. | Paper coating composition |
-
2005
- 2005-08-09 US US11/199,881 patent/US7767282B2/en not_active Expired - Fee Related
- 2005-08-10 CN CN200580027228.9A patent/CN101023109B/zh not_active Expired - Fee Related
- 2005-08-10 WO PCT/US2005/028583 patent/WO2006020785A1/en not_active Ceased
- 2005-08-10 JP JP2007525796A patent/JP4825207B2/ja not_active Expired - Fee Related
- 2005-08-10 EP EP05792828A patent/EP1786845B1/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0359059A (ja) * | 1989-07-28 | 1991-03-14 | Lion Corp | 洗剤包装用フィルム |
| JPH0688004A (ja) * | 1992-09-07 | 1994-03-29 | Kao Corp | ポリビニルアルコール系フィルム |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101023109A (zh) | 2007-08-22 |
| US7767282B2 (en) | 2010-08-03 |
| US20060035042A1 (en) | 2006-02-16 |
| CN101023109B (zh) | 2010-06-23 |
| EP1786845B1 (en) | 2012-11-14 |
| EP1786845A1 (en) | 2007-05-23 |
| JP2008510039A (ja) | 2008-04-03 |
| WO2006020785A1 (en) | 2006-02-23 |
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