JP4774172B2 - アクリル樹脂の製造方法 - Google Patents
アクリル樹脂の製造方法 Download PDFInfo
- Publication number
- JP4774172B2 JP4774172B2 JP2001252853A JP2001252853A JP4774172B2 JP 4774172 B2 JP4774172 B2 JP 4774172B2 JP 2001252853 A JP2001252853 A JP 2001252853A JP 2001252853 A JP2001252853 A JP 2001252853A JP 4774172 B2 JP4774172 B2 JP 4774172B2
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- JP
- Japan
- Prior art keywords
- bis
- composition
- dimethylpropylperoxy
- same manner
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004925 Acrylic resin Substances 0.000 title claims description 58
- 229920000178 Acrylic resin Polymers 0.000 title claims description 58
- 238000004519 manufacturing process Methods 0.000 title claims description 17
- 239000000203 mixture Substances 0.000 claims description 89
- -1 2-methyl-2-hydroxypropyl group Chemical group 0.000 claims description 57
- 239000002904 solvent Substances 0.000 claims description 55
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- 239000003505 polymerization initiator Substances 0.000 claims description 39
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- 238000009835 boiling Methods 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 238000004821 distillation Methods 0.000 claims description 7
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- 238000006116 polymerization reaction Methods 0.000 description 42
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- KHPXOXSSGXGRIS-UHFFFAOYSA-N 2-methyl-2-[2-(2-methylpentan-2-ylperoxy)butan-2-ylperoxy]pentane Chemical compound CCCC(C)(C)OOC(C)(CC)OOC(C)(C)CCC KHPXOXSSGXGRIS-UHFFFAOYSA-N 0.000 description 4
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- KNOWKUDYKQIJGF-UHFFFAOYSA-N CCCCCCC(C)(OOC(C)(C)CC)OOC(C)(C)CC Chemical compound CCCCCCC(C)(OOC(C)(C)CC)OOC(C)(C)CC KNOWKUDYKQIJGF-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
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- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
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- 238000000113 differential scanning calorimetry Methods 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 4
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- 229920000642 polymer Polymers 0.000 description 4
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- IMYCVFRTNVMHAD-UHFFFAOYSA-N 1,1-bis(2-methylbutan-2-ylperoxy)cyclohexane Chemical compound CCC(C)(C)OOC1(OOC(C)(C)CC)CCCCC1 IMYCVFRTNVMHAD-UHFFFAOYSA-N 0.000 description 3
- OSBWZFJGFCCPPU-UHFFFAOYSA-N 2-methylbutan-2-yloxy 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOOC(C)(C)CC OSBWZFJGFCCPPU-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
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- IOSXSVZRTUWBHC-LBTVDEKVSA-N Quassin Chemical compound CC([C@@H]1CC(=O)O[C@@H]([C@]21C)C1)=C(OC)C(=O)[C@@H]2[C@]2(C)[C@@H]1[C@H](C)C=C(OC)C2=O IOSXSVZRTUWBHC-LBTVDEKVSA-N 0.000 description 3
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- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
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- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 2
- HXVNBWAKAOHACI-UHFFFAOYSA-N 2,4-dimethyl-3-pentanone Chemical compound CC(C)C(=O)C(C)C HXVNBWAKAOHACI-UHFFFAOYSA-N 0.000 description 2
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- 230000002378 acidificating effect Effects 0.000 description 2
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| JP2003064113A5 JP2003064113A5 (enExample) | 2008-10-02 |
| JP4774172B2 true JP4774172B2 (ja) | 2011-09-14 |
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| RU2352587C1 (ru) * | 2007-12-25 | 2009-04-20 | Институт органической химии им. Н.Д. Зелинского Российской академии наук | Способ получения полиметилметакрилата |
| FR2971510B1 (fr) * | 2011-02-10 | 2013-03-22 | Arkema France | Polymerisation radicalaire de l'ethylene amorcee par des peroxydes organiques a haute productivite |
| JP5861824B2 (ja) * | 2011-11-17 | 2016-02-16 | スリーボンドファインケミカル株式会社 | 熱硬化性組成物 |
| JP6168046B2 (ja) * | 2012-03-27 | 2017-07-26 | 日本ゼオン株式会社 | トナーの製造方法 |
| FR3041645B1 (fr) * | 2015-09-29 | 2017-09-08 | Arkema France | Polymerisation radicalaire de l'ethylene amorcee par un couple de peroxydes organiques a haute productivite |
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| JPS5791250A (en) * | 1980-11-28 | 1982-06-07 | Shin Etsu Chem Co Ltd | Preparation of conductive silicone rubber sponge |
| JPS63168415A (ja) * | 1987-01-02 | 1988-07-12 | ペンウオルト・コ−ポレ−シヨン | ｔ−アルキルヒドロペルオキシドを用いたアクリル酸誘導体モノマ−の溶液重合方法 |
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